US2775970A - Cigarette paper - Google Patents
Cigarette paper Download PDFInfo
- Publication number
- US2775970A US2775970A US435359A US43535954A US2775970A US 2775970 A US2775970 A US 2775970A US 435359 A US435359 A US 435359A US 43535954 A US43535954 A US 43535954A US 2775970 A US2775970 A US 2775970A
- Authority
- US
- United States
- Prior art keywords
- paper
- sodium chloride
- cigarette
- hydroxyethyl cellulose
- carboxymethylcellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000019504 cigarettes Nutrition 0.000 title claims description 25
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 34
- 239000011780 sodium chloride Substances 0.000 claims description 17
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 10
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 9
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 5
- 244000215068 Acacia senegal Species 0.000 claims description 4
- 241000416162 Astragalus gummifer Species 0.000 claims description 4
- 229920000084 Gum arabic Polymers 0.000 claims description 4
- 229920003091 Methocel™ Polymers 0.000 claims description 4
- 229920001615 Tragacanth Polymers 0.000 claims description 4
- 235000010489 acacia gum Nutrition 0.000 claims description 4
- 239000000205 acacia gum Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229920000161 Locust bean gum Polymers 0.000 claims description 3
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
- 235000010420 locust bean gum Nutrition 0.000 claims description 3
- 239000000711 locust bean gum Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 238000007792 addition Methods 0.000 description 8
- 239000002956 ash Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000779 smoke Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 244000061176 Nicotiana tabacum Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- 241001536352 Fraxinus americana Species 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
- D21H5/14—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of cellulose fibres only
- D21H5/16—Tobacco or cigarette paper
Definitions
- fly ash small particles of partially burned paper, commonly called fly ash, will fall from a burning cigarette at frequent intervals. Sometimes theseparticles are not fully consumed, but are still burning when they land on carpets, upholstered furniture, the smokers clothing, or the like. They are, thus, a fire hazard and also a nuisance.
- a paper particularly suitable as a cigarette paper may be produced by treating the paper with sodium chloride, preferably in combination with a fire retarding compound, such as carboxymethyl cellulose. It has heretofore been proposed to treat cigarette paper with various materials including inorganic salts to decrease the inflammability of the paper. But when the sodium chloride is added to paper in an amount equal to 0.5 to 2% of the weight of the paper, it increases the burning rate of the paper. This increase, while not sufiicient to preclude the use of sodium chloride, might be objectionable and I, therefore, propose to add another material to the paper which will ofiset the acceleration of burning rate proposed by the salt addition without affecting the beneficial efiects of its additions. Various compounds may be used for this purpose. Thus, I propose to add about 0.2% of carboxymethylcellulose with the sodium chloride.
- the carboxymethylcellulose may be added in amounts from 0.1% to 1.0% by weight.
- Other materials which will offset the acceleration of burning rate when sodium chloride is added to the paper in the proportions stated are gum arabic, hydroxyethyl cellulose, locust bean, tragacanth, sodium alginate, Methocel X-2602 (a water soluble hydroxpropyl methylcellulose ether) and carboxymethyl hydroxyethyl cellulose. These may be used in the proportions stated above, that is, 0.1% to 1.0%.
- paper for use in cigarette manufacture was impregnated with substantially 1% of sodium chloride and substantially 0.2% of carboxymethylcellulose by means of rolls arranged approximately midway of the drying section of a paper-making machine.
- the solution is applied to one of the rolls by passing the roll through a tank in which it is placed, and the paper is then fed between the moistened roll and a second roll.
- concentration of sodium chloride and the retardent may be controlled by varying the strength of the solution. Where the paper is passed between a pair of rolls, one of the rolls is felt-covered. In this instance the concentration of the addition materials can be further controlled by adjustment of the roll-pressure.
- Paper treated as heretofore described forms a white ash as it burns, and this ash shrinks around the tobacco ash forming a solid band. It produces a more pleasing appearance than that produced by the dark gray ash which is formed when the cigarettes are made of untreated paper.
- the shrinkage of the paper ash strength ens the whole ash on the end of the cigarette and almost completely prevents the dropping of fly ash.
- the better burning qualities are the only noticeable difference between cigarettes made with the paper of the present invention and cigarettes made with other papers.
- the sodium chloride additions in amounts of from 0.5% to 2% by weight do not increase the burning rate a suflicient amount to require the retardent. But when it does, one of the retardents may be used in the amount necessary to reduce the burning rate to that of untreated paper.
- cigarettes made with sodium chloride impregnated paper produced a milder and more pleasant smoke than that of similar cigarettes made with untreated paper.
- a fire retardent selected from the group consisting of carboxymethylcellulose, gum arabic, hydroxyethyl cellulose, locust bean gum, gum tragacanth, sodium algmate, Methocel X-2602 (a water soluble hydroxypropyl methylcellulose ether) and carboxyrnethyl hydroxyethyl cellulose.
- the step which comprises adding not less than 0.5 and not more than 2% by weight of sodium chloride and not less than 0.1% and not more than 1% by Weight of a fire retardent select- 3 ed from the group consisting of carboxy mcthylcellulose, gum arabic, hydroxyethyl cellulose, locust bean gum, gum tragacanth, sodium alginate, Methocel X-2602 (a water soluble hydroxypropyl methylcellulose ether) and carboxymethyl hydroxyethyl cellulose to the paper.
- a fire retardent select- 3 ed from the group consisting of carboxy mcthylcellulose, gum arabic, hydroxyethyl cellulose, locust bean gum, gum tragacanth, sodium alginate, Methocel X-2602 (a water soluble hydroxypropyl methylcellulose ether) and carboxymethyl hydroxyethyl cellulose to the paper.
Landscapes
- Paper (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL196391D NL196391A (OSRAM) | 1954-06-08 | ||
| BE537531D BE537531A (OSRAM) | 1954-06-08 | ||
| NL103244D NL103244C (OSRAM) | 1954-06-08 | ||
| US435359A US2775970A (en) | 1954-06-08 | 1954-06-08 | Cigarette paper |
| GB9716/55A GB768408A (en) | 1954-06-08 | 1955-04-04 | Improvements in cigarette paper |
| FR1122773D FR1122773A (fr) | 1954-06-08 | 1955-04-18 | Papier à cigarettes |
| CH328762D CH328762A (fr) | 1954-06-08 | 1955-04-27 | Papier à cigarettes |
| ES0221619A ES221619A1 (es) | 1954-06-08 | 1955-05-06 | MEJORAS INTRODUCIDAS EN LA PRODUCCIoN DE PAPEL PARA CIGARRILLOS |
| DEA22816A DE1001107B (de) | 1954-06-08 | 1955-06-08 | Zigarettenpapier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US435359A US2775970A (en) | 1954-06-08 | 1954-06-08 | Cigarette paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2775970A true US2775970A (en) | 1957-01-01 |
Family
ID=23728074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US435359A Expired - Lifetime US2775970A (en) | 1954-06-08 | 1954-06-08 | Cigarette paper |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US2775970A (OSRAM) |
| BE (1) | BE537531A (OSRAM) |
| CH (1) | CH328762A (OSRAM) |
| DE (1) | DE1001107B (OSRAM) |
| ES (1) | ES221619A1 (OSRAM) |
| FR (1) | FR1122773A (OSRAM) |
| GB (1) | GB768408A (OSRAM) |
| NL (2) | NL103244C (OSRAM) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3013936A (en) * | 1958-01-07 | 1961-12-19 | Du Pont | Synthetic fiber papers |
| FR2550423A1 (fr) * | 1983-08-08 | 1985-02-15 | Kimberly Clark Co | Enveloppe pour article a fumer a tendance d'inflammation reduite et article a fumer tel que cigarette fabrique avec cette enveloppe |
| EP0193607A4 (en) * | 1984-09-03 | 1987-06-03 | Japan Tobacco Inc | CIGARETTE. |
| US5849153A (en) * | 1995-08-09 | 1998-12-15 | Mishima Paper Co., Ltd. | Water-dispersible sheet and cigarette using the same |
| US5878753A (en) * | 1997-03-11 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article without affecting smoking characteristics |
| US5878754A (en) * | 1997-03-10 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article |
| US6645605B2 (en) | 2001-01-15 | 2003-11-11 | James Rodney Hammersmith | Materials and method of making same for low ignition propensity products |
| US20040123874A1 (en) * | 2001-03-28 | 2004-07-01 | Zawadzki Michael A. | Reduced ignition propensity smoking article with a polysaccharide treated wrapper |
| US20040255966A1 (en) * | 2002-01-23 | 2004-12-23 | Kraker Thomas A. | Smoking articles with reduced ignition proclivity characteristics |
| EP2071965A1 (en) * | 2007-12-20 | 2009-06-24 | Reemtsma Cigarettenfabriken GmbH | Smoking article with improved extinguishing characteristics |
| US9181659B2 (en) | 2011-10-17 | 2015-11-10 | Cp Kelco Oy | Compositions having increased concentrations of carboxymethylcellulose |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2998012A (en) * | 1957-01-23 | 1961-08-29 | William R Lamm | Cigarette and wrapper therefor |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US671548A (en) * | 1900-12-22 | 1901-04-09 | Isaac Gordon | Composition for fireproofing paper. |
| US1605085A (en) * | 1926-03-26 | 1926-11-02 | Unger Louis | Cigarette paper |
| US1641478A (en) * | 1922-09-06 | 1927-09-06 | Paraffine Co Inc | Process of treating paper |
| GB331079A (en) * | 1929-06-14 | 1930-06-26 | William Edwin Frith | Improvements in cigarettes |
| US2329927A (en) * | 1938-04-28 | 1943-09-21 | Joseph B Morton | Method of and composition for treating cigarettes, cigarette paper, and tobacco |
| US2613672A (en) * | 1946-07-11 | 1952-10-14 | Int Cigar Mach Co | Tobacco sheet material and method of producing the same |
| US2708175A (en) * | 1954-05-28 | 1955-05-10 | Max M Samfield | Composition of matter consisting chiefly of fragmented tobacco and galactomannan plant gum |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2580608A (en) * | 1946-04-25 | 1952-01-01 | Ecusta Paper Corp | Forming cigarette paper |
| GB646020A (en) * | 1947-01-13 | 1950-11-15 | Robinson Emmons Matthews | Improvements in cigarette paper |
-
0
- NL NL196391D patent/NL196391A/xx unknown
- BE BE537531D patent/BE537531A/xx unknown
- NL NL103244D patent/NL103244C/xx active
-
1954
- 1954-06-08 US US435359A patent/US2775970A/en not_active Expired - Lifetime
-
1955
- 1955-04-04 GB GB9716/55A patent/GB768408A/en not_active Expired
- 1955-04-18 FR FR1122773D patent/FR1122773A/fr not_active Expired
- 1955-04-27 CH CH328762D patent/CH328762A/fr unknown
- 1955-05-06 ES ES0221619A patent/ES221619A1/es not_active Expired
- 1955-06-08 DE DEA22816A patent/DE1001107B/de active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US671548A (en) * | 1900-12-22 | 1901-04-09 | Isaac Gordon | Composition for fireproofing paper. |
| US1641478A (en) * | 1922-09-06 | 1927-09-06 | Paraffine Co Inc | Process of treating paper |
| US1605085A (en) * | 1926-03-26 | 1926-11-02 | Unger Louis | Cigarette paper |
| GB331079A (en) * | 1929-06-14 | 1930-06-26 | William Edwin Frith | Improvements in cigarettes |
| US2329927A (en) * | 1938-04-28 | 1943-09-21 | Joseph B Morton | Method of and composition for treating cigarettes, cigarette paper, and tobacco |
| US2613672A (en) * | 1946-07-11 | 1952-10-14 | Int Cigar Mach Co | Tobacco sheet material and method of producing the same |
| US2708175A (en) * | 1954-05-28 | 1955-05-10 | Max M Samfield | Composition of matter consisting chiefly of fragmented tobacco and galactomannan plant gum |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3013936A (en) * | 1958-01-07 | 1961-12-19 | Du Pont | Synthetic fiber papers |
| FR2550423A1 (fr) * | 1983-08-08 | 1985-02-15 | Kimberly Clark Co | Enveloppe pour article a fumer a tendance d'inflammation reduite et article a fumer tel que cigarette fabrique avec cette enveloppe |
| EP0133575A1 (en) * | 1983-08-08 | 1985-02-27 | Kimberly-Clark Corporation | Reduced ignition proclivity smoking article wrapper and smoking article |
| EP0193607A4 (en) * | 1984-09-03 | 1987-06-03 | Japan Tobacco Inc | CIGARETTE. |
| US5849153A (en) * | 1995-08-09 | 1998-12-15 | Mishima Paper Co., Ltd. | Water-dispersible sheet and cigarette using the same |
| US5878754A (en) * | 1997-03-10 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article |
| US5878753A (en) * | 1997-03-11 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article without affecting smoking characteristics |
| US6645605B2 (en) | 2001-01-15 | 2003-11-11 | James Rodney Hammersmith | Materials and method of making same for low ignition propensity products |
| US20040123874A1 (en) * | 2001-03-28 | 2004-07-01 | Zawadzki Michael A. | Reduced ignition propensity smoking article with a polysaccharide treated wrapper |
| US20040255966A1 (en) * | 2002-01-23 | 2004-12-23 | Kraker Thomas A. | Smoking articles with reduced ignition proclivity characteristics |
| US8863757B2 (en) | 2002-01-23 | 2014-10-21 | Schweitzer-Mauduit International, Inc. | Smoking articles with reduced ignition proclivity characteristics |
| US10028525B2 (en) | 2002-01-23 | 2018-07-24 | Schweitzer-Mauduit International, Inc. | Smoking articles with reduced ignition proclivity characteristics |
| EP2071965A1 (en) * | 2007-12-20 | 2009-06-24 | Reemtsma Cigarettenfabriken GmbH | Smoking article with improved extinguishing characteristics |
| US20090159090A1 (en) * | 2007-12-20 | 2009-06-25 | Reemtsma Cigarettenfabriken Gmbh | Smoking article with improved extinguishing characteristcs |
| US9181659B2 (en) | 2011-10-17 | 2015-11-10 | Cp Kelco Oy | Compositions having increased concentrations of carboxymethylcellulose |
| US9963558B2 (en) | 2011-10-17 | 2018-05-08 | Cp Kelco Oy | Compositions having increased concentrations of carboxymethylcellulose |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1001107B (de) | 1957-01-17 |
| CH328762A (fr) | 1958-03-31 |
| BE537531A (OSRAM) | |
| NL196391A (OSRAM) | |
| NL103244C (OSRAM) | |
| ES221619A1 (es) | 1956-01-01 |
| GB768408A (en) | 1957-02-13 |
| FR1122773A (fr) | 1956-09-12 |
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