US2775560A - Corrosion inhibitting lubricating compositions - Google Patents
Corrosion inhibitting lubricating compositions Download PDFInfo
- Publication number
- US2775560A US2775560A US438350A US43835054A US2775560A US 2775560 A US2775560 A US 2775560A US 438350 A US438350 A US 438350A US 43835054 A US43835054 A US 43835054A US 2775560 A US2775560 A US 2775560A
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- United States
- Prior art keywords
- acid
- acids
- oil
- vapor phase
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims description 32
- 230000007797 corrosion Effects 0.000 title claims description 22
- 238000005260 corrosion Methods 0.000 title claims description 22
- 230000001050 lubricating effect Effects 0.000 title claims description 5
- 239000002253 acid Substances 0.000 claims description 41
- 239000012808 vapor phase Substances 0.000 claims description 19
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 16
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 13
- 230000002401 inhibitory effect Effects 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 5
- 239000010688 mineral lubricating oil Substances 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 description 15
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 13
- 239000002480 mineral oil Substances 0.000 description 13
- 235000010446 mineral oil Nutrition 0.000 description 13
- 229920005573 silicon-containing polymer Polymers 0.000 description 12
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 10
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 10
- -1 aliphatic monocarboxylicacids Chemical class 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000003112 inhibitor Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 7
- 239000000314 lubricant Substances 0.000 description 5
- 239000010687 lubricating oil Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000010723 turbine oil Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- ZPJDFKVKOFGAFV-UHFFFAOYSA-N 2-octadecylbutanedioic acid Chemical compound CCCCCCCCCCCCCCCCCCC(C(O)=O)CC(O)=O ZPJDFKVKOFGAFV-UHFFFAOYSA-N 0.000 description 2
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- SKHXHUZZFVMERR-UHFFFAOYSA-N 1-Isopropyl citrate Chemical compound CC(C)OC(=O)CC(O)(C(O)=O)CC(O)=O SKHXHUZZFVMERR-UHFFFAOYSA-N 0.000 description 1
- XRUGBBIQLIVCSI-UHFFFAOYSA-N 2,3,4-trimethylphenol Chemical compound CC1=CC=C(O)C(C)=C1C XRUGBBIQLIVCSI-UHFFFAOYSA-N 0.000 description 1
- NWMWIZWLHXMUGJ-UHFFFAOYSA-N 2-[2-(2-ethylhexoxy)-2-oxoethyl]-2-hydroxybutanedioic acid Chemical compound CCCCC(CC)COC(=O)CC(O)(C(O)=O)CC(O)=O NWMWIZWLHXMUGJ-UHFFFAOYSA-N 0.000 description 1
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 1
- OILUAKBAMVLXGF-UHFFFAOYSA-N 3,5,5-trimethyl-hexanoic acid Chemical compound OC(=O)CC(C)CC(C)(C)C OILUAKBAMVLXGF-UHFFFAOYSA-N 0.000 description 1
- MMDLMUNFUUBTFB-UHFFFAOYSA-N 3-decoxycarbonyl-5-methylhex-4-enoic acid Chemical compound CCCCCCCCCCOC(=O)C(CC(=O)O)C=C(C)C MMDLMUNFUUBTFB-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N cinnamic acid group Chemical class C(C=CC1=CC=CC=C1)(=O)O WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical class OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- WZHCOOQXZCIUNC-UHFFFAOYSA-N cyclandelate Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C(O)C1=CC=CC=C1 WZHCOOQXZCIUNC-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N linoleic acid group Chemical group C(CCCCCCC\C=C/C\C=C/CCCCC)(=O)O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 1
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000010731 rolling oil Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
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- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
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- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/146—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/22—Acids obtained from polymerised unsaturated acids
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- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C10N2040/247—Stainless steel
Definitions
- This invention relates to new and improved corrosion inhibiting compositions having excellent lubricating properties.
- a minor amount of a particular type-of vapor phase corrosion inhibiting agent selected from low molecular weight aliphatic monocarboxylicacids containing from 8.to carbon atoms in the molecule can be .bestraightchain, branched, saturated or unsaturated, aliphatic monocarboxylic acids of which the C3 to C10 straightchain aliphatic monocarboxylic acids are preferred.
- the saturated aliphatic monocarboxylic ac1ds such as the straight-chain, octanoic, nonanoic, decanoic, acids; branched chain aliphatic acids such as isononanoic acid and 3,5,5-trimethyl hexanoic acid and the like.
- the straightchain aliphatic monocarboxylic acids are preferred, namely, the n-octanoic, n-nonanoic andn-decanoic acids.
- vapor phase corrosion inhibiting acids are effective when added torvarious types of lubricating oils but are particularly useful in compounded lubricating oils containing as active agents one or more of the following class of compounds (a) oil-soluble sulfur-containing compounds such as sulfurized oils and derivatives thereof such as sulfurized fatty oils and sulfurized fatty acids, examplified by sulfurized sperm or whale oils and sulfurized oleic, linoleic and dimerized 'linoleic acids; (b) oil-soluble phenolic compounds such as alkylated phenols which are illustrated by 2,6-ditertiarybutyl-4-methyl phenol, 2,4,6 -.trimethylphenol, 2,4.-.dimethyl-6-tertiarybutyl phenol; 2,2'-methylene bis(4-methyl-6-tertiarybutyl phenol); (c) oil-soluble aliphatic polycarboxylic acids and/or amides or partial esters of said acids such as monoor polyalkylor alkeny
- Such acids include oil-soluble C6 to C36 and preferably C8 to C18 alkylor alkenyl-malonic, succinic, glutaric, adipic, pimelic, sebac-ic, azelaic, tartaric, citric, ma-leic, citraconic acids, of which the preferred acids are C16- alkenylsuccinic acid, Cra-alkeny-lsuccinic acid, Cas-alkenylsuccinic acid, and corresponding alkylsuccinic acids, Cm-Cm-alkyltartaric acid, Cin-Cia-alkylmalonic acid.
- Partial or full amides and/or the partial esters of these acids can be used, and include alkylsuccinic acid monoamide or monoo'leyl alkenylsuccinate, monooctyl alkylsebacate, monobutyl alkyltartrate, monoisopropyl citrate, mono 2-ethylhexyl citrate, ester of wax phenol and alkenylsuccinic acid, ethyl decanylsuccinate, decyl isobutenylsuccinate, alkenylsuccinic acid mono (-dicyclohexyl)amide, Cm-alkenylsuccinic acid mono (Z-ethylhexyl)amide, C1sa1kenylsuccinic acid monoamide; alkenylthiosuccinic acid, alkenylthiotartaric acid, 2-(1- thiotridecyl)succinic acid, 2-(1-thiodecy
- the vapor phase corrosion inhibitors of this invention are activated by the class of compounds and mixtures thereof as enumerated in classes a, b and c.
- the manner in which this is accomplished is not understood but nevertheless a synergistic efiect is produced when (a), (b) and/ or (c) are used in combination with the vapor phase inhibitors of this invention.
- "By means of this invention metal parts which are not in direct contact with the lubricant are equally protected against rust and corrosion.
- the base for additives of this invention can be a hydrocarbon oil obtained from a parafiinic, naphthenic, Mid-continent or Coastal stock and/0r mixtures thereof and preferably base stocks which have been highly refined.
- the viscosity of these oils may vary over a wide range such as from 50 SUS at F. to 100 SUS at 210 F.
- the vapor phase corrosion inhibitors namely, the C3 to C10 aliphatic monocarboxylic acids as well as any additional agents which can be present can each be used in amounts of from 0.001% to about 5% and preferably from 0.01% to 1% depending upon the base oil and additive present in said base oil.
- compositions of this invention are illustrated by the following examples:
- COMPOSITION A Octadecylsuccinic acid percent wt 0.015 2,6-ditertiarybutyl-4-methyl phenol do 0.5 Sulfurized oleic acid do 0.02 n-Nonanoic acid do 0.05 Dimethyl silicone polymer p. p. m 5 Mineral oil Balance COMPOSITION B Cm-alkenylsuccinic acid percent wt 0.015 2, 6-ditertiarybutyl-4-methyl phenol do 0.5 Sulfurized oleic acid do 0.02 n-Nonanoic acid do 0.05 Dimethyl silicone polymer p. p.
- a vapor phase modification f the AST M turbine oil rust test A water cooled one-inch diameter freshly polished SAE 1020 steel disk is set in a rabbeted hole drilled through the plastic beaker lid. Water is added to the test oil and during a 20 hour period the rust accumulated on the surface not in contact with the oil is noted.
- Vapor phase hot plate reflux test To evaluate vapor phase rust inhibitors in this test a flask containing 10 milliliters of water and milliliters of the test oil and an iron specimen suspended in the vapor phase is placed on a hot plate and the liquid gently refiuxed. Time for initial rusting is observed as well as the condition of the iron specimen after 20 hours,
- Composition B None None Not tested. CompositionD do Trace. Composition E---" Do. Composition F d 3 Do. Minegal Oi1+0.05% of n-octanoio aci Minegal Oil- ⁇ 005% of n-decanoic Do.
- compositions of this invention can be added to compositions of this invention such as oiliness agents, extreme pressure agents, anti-clogging agents and the like, in amounts of from 0.001% to 5% by weight.
- compositions of this invention can be utilized as hydraulic oils, cutting fluids, drawing and rolling oils and the like.
- a vapor phase and liquid phase corrosion inhibiting lubricating composition comprising 0.015% Ora-alkenylsuccinic acid, 0.5% 2,6-ditertiarybutyl-4-methyl phenol, 0.02% sulfurized oleic acid, 0.05% n-nonanoic acid and the balance being a mineral lubricating oil.
- a corrosion inhibiting lubricating oil composition exhibiting both vapor phase and liquid phase corrosion inhibiting properties comprising a major amount of a mineral lubricating oil, a minor efiective antioxidant amount of an oil-soluble alkylphenol antioxidant, a minor liquid phase corrosion inhibiting amount of an oil-soluble aliphatic hydrocarbon polycarboxylic acid and a minor effective vapor phase corrosion inhibiting amount of from about 0.001 to about 5% of n-nonanoic acid.
- a vapor phase and liquid phase corrosion inhibiting lubricating oil composition comprising a major amount of a mineral lubricating oil and from 0.01% to about 1% each of Cm-alkenylsuccinic acid, 2,6-ditertiary butyl-4-- methyl phenol, sulfurized oleic acid and n-nonanoic acid.
- composition in accordance with claim 3 containing additionally about 5 parts per million of dimethyl silicone polymer.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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NL99849D NL99849C (enrdf_load_stackoverflow) | 1954-06-21 | ||
NL198202D NL198202A (enrdf_load_stackoverflow) | 1954-06-21 | ||
BE539124D BE539124A (enrdf_load_stackoverflow) | 1954-06-21 | ||
US438350A US2775560A (en) | 1954-06-21 | 1954-06-21 | Corrosion inhibitting lubricating compositions |
FR1133514D FR1133514A (fr) | 1954-06-21 | 1955-06-20 | Compositions lubrifiantes |
GB17758/55A GB781341A (en) | 1954-06-21 | 1955-06-20 | Lubricating compositions |
DEN10814A DE962466C (de) | 1954-06-21 | 1955-06-21 | Schmieroelmischung |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US438350A US2775560A (en) | 1954-06-21 | 1954-06-21 | Corrosion inhibitting lubricating compositions |
Publications (1)
Publication Number | Publication Date |
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US2775560A true US2775560A (en) | 1956-12-25 |
Family
ID=23740304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US438350A Expired - Lifetime US2775560A (en) | 1954-06-21 | 1954-06-21 | Corrosion inhibitting lubricating compositions |
Country Status (6)
Country | Link |
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US (1) | US2775560A (enrdf_load_stackoverflow) |
BE (1) | BE539124A (enrdf_load_stackoverflow) |
DE (1) | DE962466C (enrdf_load_stackoverflow) |
FR (1) | FR1133514A (enrdf_load_stackoverflow) |
GB (1) | GB781341A (enrdf_load_stackoverflow) |
NL (2) | NL99849C (enrdf_load_stackoverflow) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1144865B (de) * | 1959-11-02 | 1963-03-07 | Exxon Research Engineering Co | Turbinenschmieroel |
US3084183A (en) * | 1958-12-31 | 1963-04-02 | Standard Oil Co | Alkyl phenol lactates |
US3265620A (en) * | 1963-08-29 | 1966-08-09 | Donald K Heiman | Cutting fluid |
US4107054A (en) * | 1977-06-27 | 1978-08-15 | Continental Oil Company | Lubricating oil compositions |
US4508637A (en) * | 1980-02-28 | 1985-04-02 | Petrolite Corporation | Mixtures of alkyl and alkenyl succinic acids and polymer acids |
US5021174A (en) * | 1986-05-27 | 1991-06-04 | Euron S.P.A. | Compounds useful as detergent additives for lubricants and lubricating compositions |
US5064546A (en) * | 1987-04-11 | 1991-11-12 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
US5273672A (en) * | 1987-03-02 | 1993-12-28 | Idemitsu Kosan Company Limited | Lubricating oil composition containing a partial ester of a polyhydric alcohol and a substituted succinic acid ester |
US5549847A (en) * | 1991-04-24 | 1996-08-27 | Ciba-Geigy Corporation | Flowable aqueous dispersions of polycarboxylic acid corrosion inhibitors |
US5681506A (en) * | 1992-10-30 | 1997-10-28 | Castrol Limited | Corrosion inhibiting lubricant composition |
US5726130A (en) * | 1994-05-24 | 1998-03-10 | Idemitsu Kosan Co., Ltd. | Cutting or grinding oil composition |
US20040102330A1 (en) * | 2001-02-13 | 2004-05-27 | Jian Zhou | Viscoelastic compositions |
US8785355B2 (en) | 2001-02-13 | 2014-07-22 | Schlumberger Technology Corporation | Viscoelastic compositions |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3350309A (en) * | 1965-07-14 | 1967-10-31 | Mobil Oil Corp | Stabilization of silicone fluids with an iron compound and a polycarboxylic acid |
DE3134954A1 (de) * | 1981-09-03 | 1983-03-10 | Lucas Industries Ltd., Birmingham, West Midlands | Hydraulikfluessigkeit, insbesondere bremsfluessigkeit |
GB2296714B (en) * | 1994-12-15 | 1998-03-25 | Abbey | Coating composition |
DE19605162C1 (de) * | 1996-02-13 | 1997-09-18 | Elf Oil Deutschland Gmbh | Synthetisches Schmieröl und dessen Verwendung |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2281676A (en) * | 1939-07-08 | 1942-05-05 | Tide Water Associated Oil Comp | Turbine oil |
US2349044A (en) * | 1941-07-21 | 1944-05-16 | Sheil Dev Company | Corrosion protective composition |
US2375007A (en) * | 1943-04-15 | 1945-05-01 | Shell Dev | Antifoaming composition |
US2459718A (en) * | 1946-01-25 | 1949-01-18 | Shell Dev | Lubricating composition |
US2481372A (en) * | 1946-09-27 | 1949-09-06 | Shell Dev | Rust protective lubricants |
-
0
- BE BE539124D patent/BE539124A/xx unknown
- NL NL198202D patent/NL198202A/xx unknown
- NL NL99849D patent/NL99849C/xx active
-
1954
- 1954-06-21 US US438350A patent/US2775560A/en not_active Expired - Lifetime
-
1955
- 1955-06-20 GB GB17758/55A patent/GB781341A/en not_active Expired
- 1955-06-20 FR FR1133514D patent/FR1133514A/fr not_active Expired
- 1955-06-21 DE DEN10814A patent/DE962466C/de not_active Expired
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2281676A (en) * | 1939-07-08 | 1942-05-05 | Tide Water Associated Oil Comp | Turbine oil |
US2349044A (en) * | 1941-07-21 | 1944-05-16 | Sheil Dev Company | Corrosion protective composition |
US2375007A (en) * | 1943-04-15 | 1945-05-01 | Shell Dev | Antifoaming composition |
US2459718A (en) * | 1946-01-25 | 1949-01-18 | Shell Dev | Lubricating composition |
US2481372A (en) * | 1946-09-27 | 1949-09-06 | Shell Dev | Rust protective lubricants |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3084183A (en) * | 1958-12-31 | 1963-04-02 | Standard Oil Co | Alkyl phenol lactates |
DE1144865B (de) * | 1959-11-02 | 1963-03-07 | Exxon Research Engineering Co | Turbinenschmieroel |
US3265620A (en) * | 1963-08-29 | 1966-08-09 | Donald K Heiman | Cutting fluid |
US4107054A (en) * | 1977-06-27 | 1978-08-15 | Continental Oil Company | Lubricating oil compositions |
US4508637A (en) * | 1980-02-28 | 1985-04-02 | Petrolite Corporation | Mixtures of alkyl and alkenyl succinic acids and polymer acids |
US5021174A (en) * | 1986-05-27 | 1991-06-04 | Euron S.P.A. | Compounds useful as detergent additives for lubricants and lubricating compositions |
US5273672A (en) * | 1987-03-02 | 1993-12-28 | Idemitsu Kosan Company Limited | Lubricating oil composition containing a partial ester of a polyhydric alcohol and a substituted succinic acid ester |
US5064546A (en) * | 1987-04-11 | 1991-11-12 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
US5549847A (en) * | 1991-04-24 | 1996-08-27 | Ciba-Geigy Corporation | Flowable aqueous dispersions of polycarboxylic acid corrosion inhibitors |
US5681506A (en) * | 1992-10-30 | 1997-10-28 | Castrol Limited | Corrosion inhibiting lubricant composition |
US5726130A (en) * | 1994-05-24 | 1998-03-10 | Idemitsu Kosan Co., Ltd. | Cutting or grinding oil composition |
US20040102330A1 (en) * | 2001-02-13 | 2004-05-27 | Jian Zhou | Viscoelastic compositions |
US7704926B2 (en) * | 2001-02-13 | 2010-04-27 | Schlumberger Technology Corporation | Viscoelastic compositions |
US8785355B2 (en) | 2001-02-13 | 2014-07-22 | Schlumberger Technology Corporation | Viscoelastic compositions |
Also Published As
Publication number | Publication date |
---|---|
NL99849C (enrdf_load_stackoverflow) | |
BE539124A (enrdf_load_stackoverflow) | |
GB781341A (en) | 1957-08-21 |
DE962466C (de) | 1957-04-25 |
NL198202A (enrdf_load_stackoverflow) | |
FR1133514A (fr) | 1957-03-28 |
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