US2702242A - Method of preparing diazo photolithographic plates - Google Patents

Method of preparing diazo photolithographic plates Download PDF

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US2702242A
US2702242A US213679A US21367951A US2702242A US 2702242 A US2702242 A US 2702242A US 213679 A US213679 A US 213679A US 21367951 A US21367951 A US 21367951A US 2702242 A US2702242 A US 2702242A
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light
foil
ink
diazo
exposure
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US213679A
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Neugebauer Wilhelm
Barthenheier Jakob
Rebenstock August
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Azoplate Corp
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Azoplate Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B39/00—Other azo dyes prepared by diazotising and coupling
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26—Processing photosensitive materials; Apparatus therefor
    • G03F7/30—Imagewise removal using liquid means
    • G03F7/32—Liquid compositions therefor, e.g. developers

Definitions

  • This invention relates to a process for fixing lithographic plates.
  • the fixing process of the present invention relates particularly to the fixing of lithographic plates prepared from a type of light sensitive material which has been put on the market only recently.
  • This light sensitive material consists of a layer of a light sensitive diazo compound coated on a base.
  • the light sensitive material is exposed to light through a master.
  • the diazo compound is decomposed into a greasy ink receptive substance in the light struck areas.
  • positive ink receptive images are obtained from negative masters and vice versa negative ink receptive images are obtained from positive masters.
  • Diazo compounds which are especially suitable in the light sensitive layer for this type of photosensitive material are the condensation products of diazo-dlarylamines with formaldehyde.
  • Cellulose acetate foils which have been saponified on their surface may be used as the base material. It is not necessary to add hardenable colloids such as glue to the light sensitive layer since the light decomposition products of these diazo compounds are in themselves ink receptive.
  • the undecomposed diazo compounds are not ink receptive but nevertheless it is necessary to remove them from the areas which have not been struck by light or to fix the plate in some other manner. If this is not done, the diazo compound in these areas will become partially decomposed during use of the plate so that these areas will gradually scum up and accept more and more of the greasy" ink. It has been the practice to wash the undecomposed diazo compound from these lithographic printing plates with water. Treatment with sodium throsulfate has also been proposed. These procedures have not, however, proven fully satisfactory in practice. The removal of the last remnants of the undecomposed diazo compound by washing with water is difiicult, and even washing for a long time does not guarantee the complete removal of the undecomposed diazo compound. Neither does the treatment with thiosulfate result in an entirely satisfactory fixation. In these cases a strong tendency to scum develops more or less quickly during printing operations.
  • Azo coupling components containing sulfonic groups are especially well suited for this procedure.
  • Those coupling components of high coupling energy are of particular advantage, since such energy permits their coupling to form azo dyes without the use of alkali.
  • sulfonic acids of compounds belonging to the pyrazolone series or their salts are very suitable; e. g. 1-(4'-sulfophenyl)-3-methyl-pyrazolone-(5), or its salts.
  • hydrophilic azo coupling components to be used according to this invention are generally applied in the form of aqueous solutions.
  • Other ingredients may be added to these solutions, for example, coupling-accelerating agents, buffer salts, glycerin, triethylene glycol, and other water-soluble softeners.
  • a superficially saponified cellulose acetate foil, saponified to a depth of 5 to 7 microns is coated with an aqueous solution containing three percent of the zinc chloride double salt of the condensation product of 1 mol of 4-diaZodiphenyl-amine with 1 mol of formaldehyde and dried.
  • This condensation product may be produced in sulfuric acid of 60 B.
  • the light sensitive material is exposed to light under a negative master.
  • the exposed material is then treated with a solution of a pH of about 6.8 that has been produced by dissolving in cc. of water, 5 g. of 1-(4'-sulfophenyl)-3-methylpyrazolone-(S), 5 g. of trisodium phosphate, and 10 g.
  • Example 2 A superficially saponified cellulose acetate foil, rendered light sensitive as described in Example 1, is exposed to light under a negative master and then washed with water. In order to achieve a complete coupling of the remaining diazo compound there is applied an aqueous solution of a pH of about 8.4 containing five percent of sodium 2,3 dihydroxynaphthalene 6 sulfonate, one half percent of soda, and ten percent of glycerin. The plate is finally prepared for the press according to the procedure of Example 1.
  • the fixing of the plate can also be carried out after the plate has been installed on the press.
  • One method of doing this is to add the coupling component to the fountain solution.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)

Description

United States Patent 9 lVlETHOD OF PREPARING DIAZO PHOTO- LITHOGRAPHIC PLATES Wilhelm Neugebauer, Wiesbaden-Biebrich, Jakob Barthenheier, Eddersheim on Main, and August Rebenstock, Wiesbaden-Biebrich, Germany, assignors, by mesne assignments, to Azoplate Corporafion, Summit, N. 1., a corporation of New Jersey No Drawing. Application March 2, 1951, Serial No. 213,679
Claims priority, application Germany August 12, 1950 13 Claims. (Cl. 955.4)
This invention relates to a process for fixing lithographic plates. The fixing process of the present invention relates particularly to the fixing of lithographic plates prepared from a type of light sensitive material which has been put on the market only recently. This light sensitive material consists of a layer of a light sensitive diazo compound coated on a base. To form the lithographic plates, the light sensitive material is exposed to light through a master. The diazo compound is decomposed into a greasy ink receptive substance in the light struck areas. Thus positive ink receptive images are obtained from negative masters and vice versa negative ink receptive images are obtained from positive masters.
Diazo compounds which are especially suitable in the light sensitive layer for this type of photosensitive material are the condensation products of diazo-dlarylamines with formaldehyde. Cellulose acetate foils which have been saponified on their surface may be used as the base material. It is not necessary to add hardenable colloids such as glue to the light sensitive layer since the light decomposition products of these diazo compounds are in themselves ink receptive.
The undecomposed diazo compounds are not ink receptive but nevertheless it is necessary to remove them from the areas which have not been struck by light or to fix the plate in some other manner. If this is not done, the diazo compound in these areas will become partially decomposed during use of the plate so that these areas will gradually scum up and accept more and more of the greasy" ink. It has been the practice to wash the undecomposed diazo compound from these lithographic printing plates with water. Treatment with sodium throsulfate has also been proposed. These procedures have not, however, proven fully satisfactory in practice. The removal of the last remnants of the undecomposed diazo compound by washing with water is difiicult, and even washing for a long time does not guarantee the complete removal of the undecomposed diazo compound. Neither does the treatment with thiosulfate result in an entirely satisfactory fixation. In these cases a strong tendency to scum develops more or less quickly during printing operations.
It has now been found that it is possible to fix lithographic plates which have been produced from light sensitive materials of the type described by treating the material, after its exposure behind a master, with a solution of a water soluble azo coupling component which contains hydrophilic groups and which will react with the remaining undecomposed diazo compound to form a hydrophilic azo dye which does not accept the greasy ink. It may be desirable to Wash the exposed plate with water before treating it with the fixing solution which contains an azo coupling component in order to remove some or most of the undecomposed diazo compound.
It is advantageous using a solution of pH not greater than 9.0 because more alkaline solutions tend to soften the saponified surface of cellulose acetate foils so that they are more subject to damage. Furthermore, if the solution is not strongly alkaline, it is not necessary to wash it off the plate before installing the plate on the press and running the plate on the press with the fountain solution which is generally acid.
2,702,242 Patented Feb. 15, 1955 The new fixing process renders innocuous the remnants of the diazo compound which were not decomposed during the exposure by reason of their having been protected by the opaque parts of the master.
Azo coupling components containing sulfonic groups are especially well suited for this procedure. Those coupling components of high coupling energy are of particular advantage, since such energy permits their coupling to form azo dyes without the use of alkali. For example, sulfonic acids of compounds belonging to the pyrazolone series or their salts are very suitable; e. g. 1-(4'-sulfophenyl)-3-methyl-pyrazolone-(5), or its salts. Good results are also obtained for example with 2,3-dihydroxynaphthalene 6 sulfonic acid, 1,8 dihydroxynaphthalene 4 sulfonic acid, 1,5 dihydroxynaphthalene 3,7 disulfonic acid, 1,8 dihydroxy -naphthalene- 3,6 disulfonic acid, 1 amino 8 dihydroxynaphthalene 3,6 disulfonic acid (H-acid), or with the salts of these acids. Although it does not contain a sulfonic group, phloroglucinol may also be used as an azo coupling component according to the present invention. However, it should preferably be used in the form of a freshly prepared solution.
The hydrophilic azo coupling components to be used according to this invention are generally applied in the form of aqueous solutions. Other ingredients may be added to these solutions, for example, coupling-accelerating agents, buffer salts, glycerin, triethylene glycol, and other water-soluble softeners.
The following examples are inserted to illustrate the present invention:
(1) A superficially saponified cellulose acetate foil, saponified to a depth of 5 to 7 microns is coated with an aqueous solution containing three percent of the zinc chloride double salt of the condensation product of 1 mol of 4-diaZodiphenyl-amine with 1 mol of formaldehyde and dried. This condensation product may be produced in sulfuric acid of 60 B. The light sensitive material is exposed to light under a negative master. The exposed material is then treated with a solution of a pH of about 6.8 that has been produced by dissolving in cc. of water, 5 g. of 1-(4'-sulfophenyl)-3-methylpyrazolone-(S), 5 g. of trisodium phosphate, and 10 g. of triethylene glycol. Finally, the fixed plate is inked on an offset lithographic printing machine. A positive printing plate is thus obtained which is not affected by further exposure to light. It is not necessary to rinse or wash oif the plate after treatment with the fixing solution because the pH of the fixing solution is on the acid side of the neutral point.
(2) A superficially saponified cellulose acetate foil, rendered light sensitive as described in Example 1, is exposed to light under a negative master and then washed with water. In order to achieve a complete coupling of the remaining diazo compound there is applied an aqueous solution of a pH of about 8.4 containing five percent of sodium 2,3 dihydroxynaphthalene 6 sulfonate, one half percent of soda, and ten percent of glycerin. The plate is finally prepared for the press according to the procedure of Example 1.
The fixing of the plate can also be carried out after the plate has been installed on the press. One method of doing this is to add the coupling component to the fountain solution.
Having thus described our invention what is claimed is:
1. The process of forming lithographic printing plates from a saponified acetate foil coated with an ink repellent diazo compound which decomposes into a greasy ink receptive substance upon exposure to light said compound being obtained by the condensation of diazo-diarylamine with formaldehyde, comprising the steps of exposing said foil to a light image, treating the foil after exposure to light with an aqueous solution containing a water soluble azo coupling component of high coupling energy containing hydrophilic groups which couples with the undecomposed diazo compound in the unexposed areas to form an ink repellent dye, and thereafter apply ing ink in the presence of water to said foil.
2. The process of forming lithographic printing plates from a saponified acetate foil coated with an ink repellent diazo compound obtained by the condensation of a diazo-diarylamine with formaldehyde and which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said foil to a light image, treating the plate after exposure to light with an aqueous solution containing an azo coupling component of the pyrazolone series of high coupling energy containing hydrophilic groups which couples with the undecomposed diazo compound in the unexposed areas to form an ink repellant dye, and thereafter applying ink in the presence of water to said foil.
3. The process of forming lithographic printing plates from a saponified acetate foil coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said material to a light image, treating the plate after exposure to light with an aqueous solution containing an azo coupling component selected from the group consisting of compounds of the pyrazolone series of high coupling energy containing a sulfonic acid group and their salts which couples with the undecomposed diazo compound in the unexposed areas to form an ink repellant dye, and thereafter applying ink in the presence of water to said foil.
4. The process of forming lithographic printing plates from a saponified acetate foil coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said material to a light image, treating the plate after exposure to light with an aqueous solu' tion containing an azo coupling component selected from the group consisting of high energy components containing a sulfonic acid group and their salts which couples with the undecomposed diazo compound in the unexposed areas to form an ink repellant dye, and thereafter applying ink in the presence of Water to said foil.
5. The process of forming lithographic printing plates from a saponified acetate foil coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said material to a light image, treating the plate after exposure to light with an aqueous solution containing an azo coupling component selected from the group consisting of dihydroxy-naphthalene sulfonic acids and their salts which couples with the undecomposed diazo compound in the unexposed areas to form an ink repellant dye, and thereafter applying ink in the presence of water to said foil.
6. The process of forming lithographic printing plates from a saponified acetate foil coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said material to a light image, treating the plate after exposure to light with an aqueous solution containing an azo coupling component selected from the group consisting of 2,3-dihydroxynaphthalene-6-sulfonic acid and its salts which couples with the undecomposed diazo compound in the unexposed areas to form an ink repellant dye, and thereafter applying ink in the presence of water to said foil.
7. The process of forming lithographic printing plates from a saponified acetate foil coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said material to a light image, treating the plate after exposure to light with an aqueous solution containing an azo coupling component selected from the group consisting of 1,5-dihydroxynaphthalene-3,7-disulfonic acid and its salts, and thereafter applying ink in the presence of water to said foil.
8. The process of forming lithographic printing plates from a saponified acetate foil coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said material to a light image, treating the plate after exposure to light with an aqueous solution containing an azo coupling component selected from the group consisting of 1,8-dihydroxynaphthalene-3,6-disulfonic acid and its salts, and thereafter applying ink in the presence of water to said foil.
9. The process of forming lithographic printing plates from a saponified acetate foil coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde which decomposes into a greasy ink receptive substance upon exposure to light comprising the steps of, exposing said material to a light image, treating the plate after exposure to light with an aqueous solution containing an azo coupling component selected from the group consisting of l,8-dihydroxynaphthalene-4-sulfonic acid and its salts, and thereafter applying ink in the presence of water to said foil.
10. The process of forming a lithographic printing plate from a saponified acetate foil having a surface thereof coated with an ink repellent diazo compound which decomposes into a greasy ink receptive substance upon exposure to light obtained by the condensation of a diazodiarylamine with formaldehyde comprising the steps of exposing the coated surface of said foil to a light image, after exposure treating said coated surface with an aqueous solution containing a sulfonated phenylmethyl pyrazolone which couples with the undecomposed diazo compound in the unexposed areas to form an ink repellant dye, and thereafter applying ink on said coated surface in the presence of water.
11. The process of forming a lithographic printing plate from a saponified acetate foil having a surface thereof coated with an ink repellent diazo compound obtained by the condensation of a diazo-diarylamine with formaldehyde comprising the steps of, exposing the coated surface of said foil to a light image whereby those areas of said coated surface which are struck by light become ink receptive and the remaining areas of said coated surface are unafiected, treating at least said remaining areas with an aqueous solution of a sulfonated phenylmethyl pyrazolone to prevent said remaining areas from becoming ink receptive and thereafter applying ink in the presence of water on said areas struck by light.
12. The process of forming a lithographic printing plate from a saponified acetate foil having a surface thereof coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde comprising the steps of, exposing the coated surface of said foil to a light image whereby those areas of said coated surface Which are struck by light become ink receptive and the remaining areas of said coated surface are unaffected, treating the plate after exposure to light with an aqueous solution containing an azo coupling component selected from the groups consisting of the sulfonic acids of the pyrazolone series, the sulfonic acids of p'oly-hydroxynaphthalenes and the sulfonic acids of amino-hydroxynaphthalene to prevent said remaining areas from becoming ink receptive, and thereafter applying ink in the presence of water on said areas struck by light.
13. The process of forming a lithographic printing plate from a saponified acetate foil having a surface thereof coated with the condensation product of an ink repellent diazo-diarylamine with formaldehyde comprising the steps of, exposing the coated surface of said foil to a light image whereby those areas of said coated surface which are struck by light become ink receptive and the remaining areas of said coated surface are unalfected, treating at least said remaining areas with an aqueous solution containing an azo coupling component selected from the group consisting of 1-(4'-sulfophenyl)- 3-methyl pyrazolone-(5)- and its salts to prevent said remaining areas from becoming ink receptive, and thereafter applying ink in the presence of water on said areas struck by light.
References Cited in the file of this patent UNITED STATES PATENTS 2,063,631 Schmidt Dec. 8, 1936 FOREIGN PATENTS 337,868 Great Britain Nov. 13, 1930 402,737 Great Britain 1933 624,472 Great Britain Iune'9, 1949 904,255 France Oct. 31, 1945

Claims (1)

1. THE PROCESS OF FORMING LITHOGRAPHIC PRINTING PLATES FROM A SAPONIFIED ACETATE FOIL COATED WITH AN INK REPELLENT DIAZO COMPOUND WHICH DECOMPOSES INTO A GREASY INK RECEPTIVE SUBSTANCES UPON EXPOSURE TO LIGHT SAID COMPOUND BEING OBTAINED BY THE CONDENSATION OF DIAZO-DIARYLAMINE WITH FORMALDEHYDE, COMPRISING THE STEPS OF EXPOSIING SAID FOIL TO A LIGHT IMAGE, TREATING THE FOIL AFTER EXPOSURE TO LIGHT WITH AN AQUEOUS SOLUTION CONTAINING A WATER SOLUBLE AZO COUPLING COMPONENT OF HIGH COUPLING ENERGY CONTAINING HYDROPHILIC GROUPS WHICH COUPLES WITH THE UNDECOMPOSED DIAZO COMPOUND IN THE UNEXPOSED AREAS TO FORM AN INK REPELLENT DYE, AND THEREAFTER APPLYING INK IN THE PRESENCE OF WATER TO SAID FOIL.
US213679A 1950-08-13 1951-03-02 Method of preparing diazo photolithographic plates Expired - Lifetime US2702242A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEO968A DE857739C (en) 1950-08-13 1950-08-13 Process for fixing printing forms which are produced with the aid of diazo compounds
GB20539/51A GB708446A (en) 1950-08-13 1951-08-30 A process for the preparation of lithographic printing plates produced by the photographic diazotype process

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DE (1) DE857739C (en)
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3100703A (en) * 1961-03-13 1963-08-13 Horizons Inc Photographic process utilizing cyanine dye bases
US3102810A (en) * 1961-04-05 1963-09-03 Horizons Inc Print-out cyanine and styryl dye bases and process of producing litho masters and the like therewith
US3113023A (en) * 1961-07-25 1963-12-03 Polychrome Corp Photosensitive lithographic plate comprising photosensitive diazo resins and method for preparing same
US3300309A (en) * 1963-09-06 1967-01-24 Polychrome Corp Moisture-resistant planographic plates and methods of producing same
US3607271A (en) * 1968-01-12 1971-09-21 Oce Van Der Grinten Nv Phloroglucinol developer for lingt-sensitive planographic plates
US4248959A (en) * 1978-12-07 1981-02-03 American Hoechst Corporation Preparation of diazo printing plates using laser exposure
US4296193A (en) * 1980-01-16 1981-10-20 Kimoto & Co., Ltd. Photosensitive positive diazo material with copolymer of acrylamide and diacetoneacrylamide and a process for developing to form color relief image

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA804933B (en) * 1979-08-20 1981-07-29 Vickers Ltd Lithographic printing plates

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB337868A (en) * 1929-08-24 1930-11-13 Humphrey Desmond Murray Improvements in and relating to the manufacture of sensitized bases for photographic purposes
GB402737A (en) * 1932-03-04 1933-12-07 Kalle & Co Ag Manufacture of negative copies
US2063631A (en) * 1932-05-23 1936-12-08 Kalle & Co Ag Diazo compounds and a process of preparing them
FR904255A (en) * 1943-01-14 1945-10-31 Kalle & Co Ag Process for the production of printing plates
GB624472A (en) * 1946-03-20 1949-06-09 Gen Aniline & Film Corp 2.8-dihydroxynaphthalene-6-sulphonic acid as the azo coupling component for diazotype prints

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB337868A (en) * 1929-08-24 1930-11-13 Humphrey Desmond Murray Improvements in and relating to the manufacture of sensitized bases for photographic purposes
GB402737A (en) * 1932-03-04 1933-12-07 Kalle & Co Ag Manufacture of negative copies
US2063631A (en) * 1932-05-23 1936-12-08 Kalle & Co Ag Diazo compounds and a process of preparing them
FR904255A (en) * 1943-01-14 1945-10-31 Kalle & Co Ag Process for the production of printing plates
GB624472A (en) * 1946-03-20 1949-06-09 Gen Aniline & Film Corp 2.8-dihydroxynaphthalene-6-sulphonic acid as the azo coupling component for diazotype prints

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3100703A (en) * 1961-03-13 1963-08-13 Horizons Inc Photographic process utilizing cyanine dye bases
US3102810A (en) * 1961-04-05 1963-09-03 Horizons Inc Print-out cyanine and styryl dye bases and process of producing litho masters and the like therewith
US3113023A (en) * 1961-07-25 1963-12-03 Polychrome Corp Photosensitive lithographic plate comprising photosensitive diazo resins and method for preparing same
US3300309A (en) * 1963-09-06 1967-01-24 Polychrome Corp Moisture-resistant planographic plates and methods of producing same
US3607271A (en) * 1968-01-12 1971-09-21 Oce Van Der Grinten Nv Phloroglucinol developer for lingt-sensitive planographic plates
US4248959A (en) * 1978-12-07 1981-02-03 American Hoechst Corporation Preparation of diazo printing plates using laser exposure
US4296193A (en) * 1980-01-16 1981-10-20 Kimoto & Co., Ltd. Photosensitive positive diazo material with copolymer of acrylamide and diacetoneacrylamide and a process for developing to form color relief image

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GB708446A (en) 1954-05-05
DE857739C (en) 1952-12-01
FR1041494A (en) 1953-10-23

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