US2682702A - Carbonyl metal plated product - Google Patents
Carbonyl metal plated product Download PDFInfo
- Publication number
- US2682702A US2682702A US85941A US8594149A US2682702A US 2682702 A US2682702 A US 2682702A US 85941 A US85941 A US 85941A US 8594149 A US8594149 A US 8594149A US 2682702 A US2682702 A US 2682702A
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- US
- United States
- Prior art keywords
- coating
- metal
- base
- carbonyl
- nickel
- Prior art date
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- Expired - Lifetime
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0272—Deposition of sub-layers, e.g. to promote the adhesion of the main coating
- C23C16/0281—Deposition of sub-layers, e.g. to promote the adhesion of the main coating of metallic sub-layers
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/16—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal carbonyl compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/923—Physical dimension
- Y10S428/924—Composite
- Y10S428/926—Thickness of individual layer specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/938—Vapor deposition or gas diffusion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12021—All metal or with adjacent metals having metal particles having composition or density gradient or differential porosity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12479—Porous [e.g., foamed, spongy, cracked, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12639—Adjacent, identical composition, components
- Y10T428/12646—Group VIII or IB metal-base
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/1275—Next to Group VIII or IB metal-base component
Definitions
- This invention deals with a method of platin metals, and particularly with a method based on the decomposition of gaseous metal carbonyls.
- the disadvantage heretofore has frequently been encountered of the coating not sufficiently adhering to the base metal. Moreover, the metal coating would become blistered if the object so coated was raised to elevated temperatures, for example, a heat treatment process.
- a very thin porous film is applied to the metallic base by decomposing gaseous metal carbonyl.
- the invention is not restricted to this particular range.
- the coated article is heat treated. While applicant does not wish to be bound by theory, it is believed that the heat-treatment step effects desorption of gas while the coating is still in a porous state.
- the heat-treatment in no way involves heating to temperatures which cause formation of alloys between the base and the metal coating. Microscopic examinations show no penetration into, for example, a copper base-by a nickel coating heated to 800 F.
- metal-oxide films must be removed from bases such as copper and aluminum. This film may be removed in the cleaning or by contact within the plating chamber with reducing gases, for example, hydrogen, prior to introduction of decomposable carbonyl gases.
- the pre-coating cleaning is not accountable for the difference in the adhering character of the deposits.
- Gases may be desorbed from the thinly coated bases by heating to a temperature in the range of 500 F. to 1200 F. depending upon the temperature which can be applied to the base without softening or destroying some characteristic such as temper or can be applied to the coating.
- lead patterns should not be heated much above 550 F. while, on the other hand, alloy steels withstand temperatures in .excess of 1200 F. At the lower temperatures the heating is continued for a longer time in order to effect comparative completeness of desorption.
- Heating periods of 2 to 30 minutes have been found to be satisfactory.
- a treatment at a temperature of 800 to 900 F..for about 15 minutes was found most advantageous.
- the intermediate heat-treatment may be carried out in a chamber under non-oxidizing, but
- drogen natural gas, commercial brazing furnace gas, or mixtures of the above gases or other gases known in the art are suitable for this purpose.
- Base materials which may be coated are, for example, copper, aluminum, lead, cast iron, alloy steels, low carbon steels, non-ferrous alloys, such as bronze, brass, magnesium, and the like.
- the process of this invention is applicable for plating with all metals which form gaseous carbonyls.
- plating with chromium, iron, tungsten, cobalt, molybdenum, tellurium, rhenium, and other metals may be successfully carried out by the method described.
- Each of these metal carbonyls has a temperature at which decomposition is complete. However, decomposition does take place slowly at lower temperatures. For this reason it is preferred that the carbonyl be brought into contact quickly with the base metal heated to a temperature in the optimum decomposition range for each material.
- tungsten nickel, chromium, iron
- a temperature in the range of 350 F. to 425 F., although temperatures below and above this range may be utilized and still accomplish plating by decomposition of carbonyl.
- a metal coating of the desired thickness is applied to the pretreated base by decomposing metal carbonyls.
- the product thus obtained is characterized by an excellent bond and a very uniform and smooth surface structure.
- a second heat treating step may be applied. However, this is not obligatory. Sometimes an after-treatment is utilized to increase the ductility of the coating layer.
- Example I A copper plate was first mechanically cleaned by sanding. Thereafter the copper metal was heated to approximately 375 F. in an atmosphere containing approximately 1.4 percent by volume of nickel carbonyl and diluted with carbon dioxide gas. The rate of gas flow was approximately 4 l. per minute at a temperature of 78 F.
- the copper was exposed to this atmosphere for about 2 minutes after which time a film of 0.00007" thickness had formed on the copper base. Thereafter the metal was heated in an atmosphere of natural gas to a temperature of about 800 F. for approximately 15 minutes.
- the coating proper was performed by subjecting the metal to the same conditions and gases as in the preliminary film-forming step. This second step was carried out for about 15 minutes when a coating of 0.0004" had formed.
- Example II A lead pattern may be coated in the equipment utilized in the plating operation of Exampie 1.
- the lead pattern may be coated with iron deposited from iron carbonyl.
- the base may be heated to approximately 360 F. in an atmosphere of nitrogen containing about 2 percent by volume of iron carbonyl. After exposure of the pattern to this atmosphere for about 2 minutes, the temperature of the pattern may be raised to 525 F. and held there for 20 minutes.
- the final filmforming step may be performed under the same conditions as is maintained in the preliminary coating step.
- Example III An aluminum radar antenna may be coated in the same equipment as is used in Examples I and II.
- the aluminum may be treated with acid and then buffed to prepare clean surfaces.
- the aluminum may be coated with nickel by heating the base to approximately 375 F. in one minute with a feed rate of approximately 50 cubic feet per hour of nickel carbonyl vapor diluted with hydrogen.
- the initially coated base may be heat treated at 750 F. for 20 minutes to desorb gas.
- the final coating and heat treating may follow exactly the pattern of Example I.
- Example IV An SAE 1020 steel plate may be treated under similar conditions to Example I to plate the steel base with chrominum deposited at a temperature of about 400 F.
- the coatings obtained by the process of this invention on each of the bases of the examples are uniform in structure, free from blisters, and well adhering to the base metal. Heat-treatment does not form blisters and impair the firm bond between the coating and the base metal.
- apparatus such as the radar antenna of Example III, have been subjected to special tests under which the base suffered a 15 percent elongation and withstood tensile strain of 90,000 pounds per square inch before breaking. Up to the breaking point, the adhering coating of nickel exhibited no checking or breaking tendency and the coating parted in line with the point of failure of the base material.
- a multi-layer metal product which is resistant to blistering and separation of the layers upon heating of the metal product at elevated temperatures comprising an aluminum metal base, a thin layer of nickel adhered to said aluminum base by exposing the base to an atmosphere of gaseous carbonyl formed from nickel and having a thickness of between about 0.00001 and 0.00025 inch, said thin layer of nickel being of greater porosity than said aluminum metal base and having the gas desorbed therefrom, and a second layer of nickel disposed over said thin porous layer by exposing said thin layer to an atmosphere of gaseous carbonyl formed from nickel, said second layer being substantially greater in thickness and higher in density than said thin layer of nickel.
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Description
Patented July 6, 1954 UNITED STATES PATENT OFFICE CARBONYL METAL PLATED PRODUCT No Drawing. Application April 6, 1949, Serial No. 85,941
1 Claim. 1
This invention deals with a method of platin metals, and particularly with a method based on the decomposition of gaseous metal carbonyls.
This application is a continuation in part of my co-pending application, Serial No. 665,318, filed April 26, 1946, now Patent No. 2,475,601, issued July 12, 1949 entitled Bonding of Metal Carbonyl Deposits.
In coatings obtained from metal carbonyls,
the disadvantage heretofore has frequently been encountered of the coating not sufficiently adhering to the base metal. Moreover, the metal coating would become blistered if the object so coated was raised to elevated temperatures, for example, a heat treatment process.
It is an object of this invention to provide a method by which the above mentioned disadvantages are overcome.
In particular, it is an object of this invention to provide a method for metal plating by which a firmly adhering metal coating is obtained.
It is another object of this invention to provide a method of producing metal coating which can withstand elevated temperatures without blistering.
It is still another object of this invention to provide a method of producing metal coatings which may be subjected to a heat-treatment process without thereby impairing the adherence of the coating.
It is still another object of this invention to provide a product whose base material is provided with a uniform deposited coat consisting of two separately deposited layers.
These and other objects are accomplished by carrying out the metal deposition in two stages in between which the base metal and its coating are subjected to a de-gasification treatment carried out by subjecting the material to heat.
In the first or initial step, only a very thin porous film is applied to the metallic base by decomposing gaseous metal carbonyl. A layer of 0.00001 to 0.00025", preferably of 0.00005" to 0.00015" in depth, was found most satisfactory for this initial coating. However, the invention is not restricted to this particular range.
After this first layer has been applied, the coated article is heat treated. While applicant does not wish to be bound by theory, it is believed that the heat-treatment step effects desorption of gas while the coating is still in a porous state.
Since the porosity of a coating varies inversely as to thickness, and since heat treatment of.
thick coatings applied at one time blisters and deforms the coating, rendering the coating nonadhering, it is believed the theory developed of coatings encountered heretofore.
The heat-treatment in no way involves heating to temperatures which cause formation of alloys between the base and the metal coating. Microscopic examinations show no penetration into, for example, a copper base-by a nickel coating heated to 800 F.
The various methods of cleaning a'base metal surface as by acid, alkali, boiling, and the like, apparently differ little in effect 'as regards the adherence of the coating. If the base to be coated is clean, the coatings will have an adherence characteristic quickly determinable by simple tests showing whether the single coating method or the double coating method of this invention was the plating system utilized.
In addition to grease, metal-oxide films must be removed from bases such as copper and aluminum. This film may be removed in the cleaning or by contact within the plating chamber with reducing gases, for example, hydrogen, prior to introduction of decomposable carbonyl gases.
Inasmuch as identical cleaning steps have been used for identical bases which have been coated in one step and by the two step method of this invention, the pre-coating cleaning is not accountable for the difference in the adhering character of the deposits.
Gases may be desorbed from the thinly coated bases by heating to a temperature in the range of 500 F. to 1200 F. depending upon the temperature which can be applied to the base without softening or destroying some characteristic such as temper or can be applied to the coating.
For example, lead patterns should not be heated much above 550 F. while, on the other hand, alloy steels withstand temperatures in .excess of 1200 F. At the lower temperatures the heating is continued for a longer time in order to effect comparative completeness of desorption.
Heating periods of 2 to 30 minutes have been found to be satisfactory. When heating a copper base covered with an initial coating of nickel, a treatment at a temperature of 800 to 900 F..for about 15 minutes was found most advantageous.
The intermediate heat-treatment may be carried out in a chamber under non-oxidizing, but
preferably under reducing atmosphere conditions;
drogen, natural gas, commercial brazing furnace gas, or mixtures of the above gases or other gases known in the art are suitable for this purpose.
One of the features of well bonded coatings is their ability to withstand compression and expansion without breaking free from the base. Thus, any metal base which will withstand gas desorbing temperatures may be coated by this carbonyl decomposition process.
Base materials which may be coated are, for example, copper, aluminum, lead, cast iron, alloy steels, low carbon steels, non-ferrous alloys, such as bronze, brass, magnesium, and the like.
The process of this invention is applicable for plating with all metals which form gaseous carbonyls. Thus, plating with chromium, iron, tungsten, cobalt, molybdenum, tellurium, rhenium, and other metals may be successfully carried out by the method described.
Each of these metal carbonyls has a temperature at which decomposition is complete. However, decomposition does take place slowly at lower temperatures. For this reason it is preferred that the carbonyl be brought into contact quickly with the base metal heated to a temperature in the optimum decomposition range for each material.
In the case of tungsten, nickel, chromium, iron, we prefer to utilize a temperature in the range of 350 F. to 425 F., although temperatures below and above this range may be utilized and still accomplish plating by decomposition of carbonyl.
After the heat-treatment step a metal coating of the desired thickness is applied to the pretreated base by decomposing metal carbonyls.
The product thus obtained is characterized by an excellent bond and a very uniform and smooth surface structure. After the deposition of the coating layer proper a second heat treating step may be applied. However, this is not obligatory. Sometimes an after-treatment is utilized to increase the ductility of the coating layer.
In the following, the process is described as applied to the coating of various metal bases with a number of metals deposited from volatile metal carbon ls:
y Example I A copper plate was first mechanically cleaned by sanding. Thereafter the copper metal was heated to approximately 375 F. in an atmosphere containing approximately 1.4 percent by volume of nickel carbonyl and diluted with carbon dioxide gas. The rate of gas flow was approximately 4 l. per minute at a temperature of 78 F.
and 125 mm. Hg. The copper was exposed to this atmosphere for about 2 minutes after which time a film of 0.00007" thickness had formed on the copper base. Thereafter the metal was heated in an atmosphere of natural gas to a temperature of about 800 F. for approximately 15 minutes.
After these preliminary steps the coating proper was performed by subjecting the metal to the same conditions and gases as in the preliminary film-forming step. This second step was carried out for about 15 minutes when a coating of 0.0004" had formed.
In order to increase the ductility of the coating, I subjected the metal to an additional heating step. This step consisted in heating for 15 minutes to a temperature of from 800 F. to 900 F. in an atmosphere of natural gas.
Example II A lead pattern may be coated in the equipment utilized in the plating operation of Exampie 1.
The lead pattern may be coated with iron deposited from iron carbonyl. The base may be heated to approximately 360 F. in an atmosphere of nitrogen containing about 2 percent by volume of iron carbonyl. After exposure of the pattern to this atmosphere for about 2 minutes, the temperature of the pattern may be raised to 525 F. and held there for 20 minutes.
After these preliminary steps the final filmforming step may be performed under the same conditions as is maintained in the preliminary coating step.
Example III An aluminum radar antenna may be coated in the same equipment as is used in Examples I and II.
The aluminum may be treated with acid and then buffed to prepare clean surfaces. The aluminum may be coated with nickel by heating the base to approximately 375 F. in one minute with a feed rate of approximately 50 cubic feet per hour of nickel carbonyl vapor diluted with hydrogen.
The initially coated base may be heat treated at 750 F. for 20 minutes to desorb gas. Followin the heat treatment, the final coating and heat treating may follow exactly the pattern of Example I.
Example IV An SAE 1020 steel plate may be treated under similar conditions to Example I to plate the steel base with chrominum deposited at a temperature of about 400 F.
The coatings obtained by the process of this invention on each of the bases of the examples are uniform in structure, free from blisters, and well adhering to the base metal. Heat-treatment does not form blisters and impair the firm bond between the coating and the base metal.
In addition, apparatus such as the radar antenna of Example III, have been subjected to special tests under which the base suffered a 15 percent elongation and withstood tensile strain of 90,000 pounds per square inch before breaking. Up to the breaking point, the adhering coating of nickel exhibited no checking or breaking tendency and the coating parted in line with the point of failure of the base material.
It will be understood that this invention is not to be restricted to the examples given in the specification, but that it is susceptible to various modifications and changes which come within the spirit of the disclosure and the scope of the appended claim.
I claim:
A multi-layer metal product which is resistant to blistering and separation of the layers upon heating of the metal product at elevated temperatures comprising an aluminum metal base, a thin layer of nickel adhered to said aluminum base by exposing the base to an atmosphere of gaseous carbonyl formed from nickel and having a thickness of between about 0.00001 and 0.00025 inch, said thin layer of nickel being of greater porosity than said aluminum metal base and having the gas desorbed therefrom, and a second layer of nickel disposed over said thin porous layer by exposing said thin layer to an atmosphere of gaseous carbonyl formed from nickel, said second layer being substantially greater in thickness and higher in density than said thin layer of nickel.
(References on following page) References Cited in the file of this patent Number UNITED STATES PATENTS Number Name Date 2:447:930 1,207,218 Roux Dec. 1916 5 2 75 01 1,975,818 Work Oct. 9, 1934 2490543 2,063,596 Feiler Dec. s, 1936 2,241,095 Marvin May 6, 1941 2,251,410 Koehring Aug. '5, 1941 Number 2,304,182 Lang Dec. 8, 1942 10 487,854 2,332,309 Drummond Oct. 19, 1943 Name Date Schwarzkopf Mar. 27, 1945 Mudge Dec. 4, 1945 Hensel Aug. 24, 1948 Fink July 12, 1949 Robertson Dec. 6, 1949 FOREIGN PATENTS Country Date Great Britain Sept. 22, 1936
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US85941A US2682702A (en) | 1949-04-06 | 1949-04-06 | Carbonyl metal plated product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US85941A US2682702A (en) | 1949-04-06 | 1949-04-06 | Carbonyl metal plated product |
GB764254A GB751523A (en) | 1954-03-16 | 1954-03-16 | Carbonyl-metal plated product |
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US2682702A true US2682702A (en) | 1954-07-06 |
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US85941A Expired - Lifetime US2682702A (en) | 1949-04-06 | 1949-04-06 | Carbonyl metal plated product |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2746134A (en) * | 1953-05-22 | 1956-05-22 | Ohio Commw Eng Co | Duplex metal sheet or article |
US2752268A (en) * | 1951-08-04 | 1956-06-26 | Whitfield & Sheshunoff Inc | Process of making alluminum coated ferrous bodies |
US2800707A (en) * | 1951-08-04 | 1957-07-30 | Whitfield & Sheshunoff Inc | Aluminum coated ferrous bodies and processes of making them |
US2821505A (en) * | 1954-04-01 | 1958-01-28 | John G Beach | Process of coating metals with bismuth or bismuth-base alloys |
US2911708A (en) * | 1955-06-27 | 1959-11-10 | Borg Warner | Babbitt-bronze-aluminum bonding process |
US2982019A (en) * | 1953-05-22 | 1961-05-02 | Union Carbide Corp | Method of protecting magnesium with a coating of titanium or zirconium |
US2982017A (en) * | 1953-05-22 | 1961-05-02 | Union Carbide Corp | Method of protecting magnesium with a coating of titanium |
US3000755A (en) * | 1956-10-11 | 1961-09-19 | Gen Motors Corp | Oxidation-resistant turbine blades |
US3045333A (en) * | 1951-10-18 | 1962-07-24 | Rem Cru Titanium Inc | Titanium coated article |
US3055087A (en) * | 1954-06-07 | 1962-09-25 | Union Carbide Corp | Carbonyl metal plated product |
US3089228A (en) * | 1957-07-26 | 1963-05-14 | Post Office | Magnetic strip material |
US3173202A (en) * | 1961-08-10 | 1965-03-16 | S W Farber Inc | Aluminum cladding |
US3193362A (en) * | 1958-09-25 | 1965-07-06 | Burroughs Corp | Magnetic materials |
US3268358A (en) * | 1962-08-20 | 1966-08-23 | Dow Chemical Co | Diffusion cladding |
US5966825A (en) * | 1996-10-10 | 1999-10-19 | Biemont; Paul | Adjustable front sight for small arms |
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US1975818A (en) * | 1932-08-24 | 1934-10-09 | Aluminum Co Of America | Coating for pistons |
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US2241095A (en) * | 1940-02-01 | 1941-05-06 | Gen Motors Corp | Method of making porous metal structures |
US2251410A (en) * | 1939-04-27 | 1941-08-05 | Gen Motors Corp | Composite metal structure and method of making same |
US2304182A (en) * | 1939-06-19 | 1942-12-08 | Sigmund Cohn | Method of forming metallic films |
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US2390452A (en) * | 1942-11-26 | 1945-12-04 | Int Nickel Co | Method of producing composite metal stock |
US2447980A (en) * | 1945-01-29 | 1948-08-24 | Mallory & Co Inc P R | Method of making porous bearing surfaces |
US2475601A (en) * | 1946-04-26 | 1949-07-12 | Ohio Commw Eng Co | Bonding of metal carbonyl deposits |
US2490543A (en) * | 1945-06-27 | 1949-12-06 | Gen Motors Corp | Method of making composite stock |
-
1949
- 1949-04-06 US US85941A patent/US2682702A/en not_active Expired - Lifetime
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US1207218A (en) * | 1914-01-19 | 1916-12-05 | L Aluminium Francais Soc | Process of producing metallic deposits. |
US2063596A (en) * | 1932-02-19 | 1936-12-08 | Ig Farbenindustrie Ag | Thermal treatment of carbon compounds |
US1975818A (en) * | 1932-08-24 | 1934-10-09 | Aluminum Co Of America | Coating for pistons |
GB487854A (en) * | 1935-10-11 | 1938-06-24 | Carl Trenzen | Improvements in and relating to the production of metal coatings on objects |
US2251410A (en) * | 1939-04-27 | 1941-08-05 | Gen Motors Corp | Composite metal structure and method of making same |
US2304182A (en) * | 1939-06-19 | 1942-12-08 | Sigmund Cohn | Method of forming metallic films |
US2241095A (en) * | 1940-02-01 | 1941-05-06 | Gen Motors Corp | Method of making porous metal structures |
US2332309A (en) * | 1940-05-20 | 1943-10-19 | Ohio Commw Eng Co | Gaseous metal deposition |
US2372607A (en) * | 1940-11-23 | 1945-03-27 | American Electro Metal Corp | Method of making layered armors |
US2390452A (en) * | 1942-11-26 | 1945-12-04 | Int Nickel Co | Method of producing composite metal stock |
US2447980A (en) * | 1945-01-29 | 1948-08-24 | Mallory & Co Inc P R | Method of making porous bearing surfaces |
US2490543A (en) * | 1945-06-27 | 1949-12-06 | Gen Motors Corp | Method of making composite stock |
US2475601A (en) * | 1946-04-26 | 1949-07-12 | Ohio Commw Eng Co | Bonding of metal carbonyl deposits |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2752268A (en) * | 1951-08-04 | 1956-06-26 | Whitfield & Sheshunoff Inc | Process of making alluminum coated ferrous bodies |
US2800707A (en) * | 1951-08-04 | 1957-07-30 | Whitfield & Sheshunoff Inc | Aluminum coated ferrous bodies and processes of making them |
US3045333A (en) * | 1951-10-18 | 1962-07-24 | Rem Cru Titanium Inc | Titanium coated article |
US2982017A (en) * | 1953-05-22 | 1961-05-02 | Union Carbide Corp | Method of protecting magnesium with a coating of titanium |
US2746134A (en) * | 1953-05-22 | 1956-05-22 | Ohio Commw Eng Co | Duplex metal sheet or article |
US2982019A (en) * | 1953-05-22 | 1961-05-02 | Union Carbide Corp | Method of protecting magnesium with a coating of titanium or zirconium |
US2821505A (en) * | 1954-04-01 | 1958-01-28 | John G Beach | Process of coating metals with bismuth or bismuth-base alloys |
US3055087A (en) * | 1954-06-07 | 1962-09-25 | Union Carbide Corp | Carbonyl metal plated product |
US2911708A (en) * | 1955-06-27 | 1959-11-10 | Borg Warner | Babbitt-bronze-aluminum bonding process |
US3000755A (en) * | 1956-10-11 | 1961-09-19 | Gen Motors Corp | Oxidation-resistant turbine blades |
US3089228A (en) * | 1957-07-26 | 1963-05-14 | Post Office | Magnetic strip material |
US3193362A (en) * | 1958-09-25 | 1965-07-06 | Burroughs Corp | Magnetic materials |
US3173202A (en) * | 1961-08-10 | 1965-03-16 | S W Farber Inc | Aluminum cladding |
US3268358A (en) * | 1962-08-20 | 1966-08-23 | Dow Chemical Co | Diffusion cladding |
US5966825A (en) * | 1996-10-10 | 1999-10-19 | Biemont; Paul | Adjustable front sight for small arms |
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