US2628561A - Propellant powder grain for rocket motors - Google Patents
Propellant powder grain for rocket motors Download PDFInfo
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- US2628561A US2628561A US479538A US47953843A US2628561A US 2628561 A US2628561 A US 2628561A US 479538 A US479538 A US 479538A US 47953843 A US47953843 A US 47953843A US 2628561 A US2628561 A US 2628561A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02K—JET-PROPULSION PLANTS
- F02K9/00—Rocket-engine plants, i.e. plants carrying both fuel and oxidant therefor; Control thereof
- F02K9/08—Rocket-engine plants, i.e. plants carrying both fuel and oxidant therefor; Control thereof using solid propellants
- F02K9/10—Shape or structure of solid propellant charges
Definitions
- This invention relates to double-base powder grains and more particularly to a novel grain of this character which is resistant to fissuring and has improved burning qualities, and to a new method by which the grain may be made expeditiously at low cost.
- the powder grain of the invention has various uses but may be employed to particular advantage for purposes requiring relatively large grain sizes, as, for example, for the propellant charge in a jet propulsion rocket. Accordingly, for illustrative purposes the invention will be described and illustrated in the form of a rocket propellant charge, although it will be understood that the invention is not limited to this use.
- Jet propulsion rockets have been employed heretofore in which the propellant charge is in the form of a single powder grain made from sheet stock of a double base powder, such as ballistite.
- a powder grain having neutral or slightly regressive burning characteristics and which does not produce excessive pressures.
- grains made from ordinary ballistite sheet stock exhibit a marked fissuring and dis- ;integration resulting in a substantial increase in burning rate and pressure as the reaction
- One object of the present invention theregrain which is resistant to fissuring and disintegration during combustion and burns at a substantially uniform rate over its entire surface.
- Another object of the invention is to provide a new method of making powder grains by extruding sheet stock which is treated prior to the extrusion to render the finished product resistant to fissuring.
- a further object of the invention resides in the provision of a novel powder grain of generally cylindrical form which is extruded with integral, longitudinal ribs on its cylindrical surface for strengthening the grain and for providing external combustion spaces between the ribs when the grain is mounted in a rocket motor body.
- Fig. 2 is an end view of the powder grain shown in Fig. 1.
- the powder grain is generally cylin drical in form and has an axial passage extending through the grain, and a set of radial openings l I spaced along its length in a helix, as disclosed in a copending application of C. C. Lauritsen, Ser. No. 481,644, filed April 2, 1943, now Patent No. 2,464,181, issued March 8, 1949.
- the grain is extruded from sheet stock of ballistite, or the like, and the die of the extrusion press is constructed so as to form the grain with integral, longitudinal ribs I2 on its outer cylindrical surface, the ribs being spaced circumferentially around the grain.
- the ribs l2 serve to strengthen the grain and also support it in the rocket motor body so as to provide external combustion spaces between the ribs, as disclosed in the above-identified application.
- Powder grains extruded from ordinary sheet stock are translucent. Even though they appear from visual examination to be relatively homogeneous, they do not have uniform deflagrating characteristics, as evidenced by the fact that partially burned samples have substantial fissures resembling worm holes and show sharp edges, in contrast to the rounded contours inherent in grains which burn uniformly. As a result of the disintegration of these grains, they produce widely varying pressures and undergo progressive burning, which is undesirable in rocket motors and other applications. The conditions under which the grains are extruded appear to have little or no effect on their burning characteristics, and reextrusion of the grains results in very irregular reactions.
- a mixture of nitrocellulose and nitroglycerin is subjected to a colloiding action, usually with the aid of a blending agent, such as a gelatinizer or a gelatinizing accelerator," which remains in the finished powder.
- a suitable stabilizer may also be added, such as diphenylamine, to take up nitrogen oxides which may form in the powder.
- the emulsion then undergoes a drying operation, as by pressing or centrifuging, and the mass is rolled, molded or otherwise formed into blocks, sheets, strips, etc. While many improvements have been made in the art of colloiding nitrocellulose and. nitroglycerin mixture, it is practically impossible to obtain commercially a perfectly uniform colloid.
- the finished powder includes minute particles which are more sensitive to combustion than the other parts, and these more sensitive particles are dispersed throughout any grain which is extruded from the powder.
- the grain When the grain is ignited, it burns first on its exposed surfaces, and since the grain is translucent the resulting radiation penetrates the interior of the grain and initiates combustion of the more sensitive particles inside the grain, whereby the fissures or worm holes are. formed, the burning area is substantially increased, and the adverse results of progressive burning are obtained.
- a powder grain made in accordance with the present invention is characterized by the .iact that the normal translucency of the powder is reduced to thepoint where the grain is opaque or substantially opaque.
- We have 'found that a grain of this character is extremely resistant to fissuring and disintegration, exhibits neutral'or slightly regressive burning qualities, and burns uniformly without widely varying pressures, apparentiy for the reason that the opacityof the grain inhibits radiation of light to the more sensitive particles within the grain during combustion.
- the powder is subjected to a darkening operation to obtain the desired opacity.
- the powder is rendered substantially opaque by exposing sheet stock of the powder to the action of light radiation of the shorter wave lengths, as by subjecting the sheet for a substantial period of time to sunlight, which is contrary to the usual practice in powder manufacture.
- the irradiation causes a rapid darkening and discoloring of the sheet stock, apparently due to chemical decomposition resulting in the liberation of one or more of the oxide of nitrogen and in their possible recombination with the stabilizer in the powder.
- the darkening process is continued until the light which the sheet transmits is reduced to substantially i5 oi the light initially transmitted by the sheet.
- Such darkening may be obtained by placing the sheet in bright sunlight fora period of ten minutes or more, exposing first one side 01 the sheet and then the other sidefi
- the time required to darken the sheet may vary, depending upon the intensity of the light, the composition of the powder and the initial color of the sheet. After the sheet has been darkened, it is placed in an'extrusion press and extruded into a grain of the desired size. It will be understood that while we prefer to darken the powder stock before it is extruded, the stock may be extruded first and then darkened.
- powder grains having the desired burning characteristics have been made from sheet stock of solventiess ballistite of .025 inch thickness and of the following composition expressed as percentages of the total weight: nitrocellulose, 51.42; nitroglycerin, 43.62; diethylphthalate, 3.49; potassium nitrate, 1.41; diphenylarnine, .66.
- the untreated sheet was lightyellow in color and translucent, yielding-a straw-colored grain when extruded, and the grain burned progressively with 1 an irregular reaction in which a large number of fissures, crevices and indentations developed.
- Powder grains extruded from irradiated stock in accordance with our invention have physical properties compel is to those of grains extruded from nonirradiated stock. More particularly; the tensile strength, hardness, and spontaneous ignition'temperature are not substantially affected bythe irradiation treatment, and the conditions required for extrusion remain-substantially the same, except that a considerably greater pressure is required to'obtain the same extrusion rates with the noni'rra'diated stock. With respect to'the burning characteristics, however, it has been established by test that while grains'extrud ed from the irradiated material yield uniformly good results, the results with grains made from nonirradiated material are almost as uniformly poor.
- the darkening of the powder grains may be effected by mean other than irradiation, as, forexample, by the addition the desired combustion characteristics for rocket use are obtained by spacing each opening I i from the adjacent opening a distance equal'subst'antially to twice the diameter of the axial passage iii, and making each opening of a diameter equal substantially to half the web thickness of the grain, that is, to substantially one-half the difference between the internal and external diameters of the grain.
- the radial openings ii in the grain tend to improve its combustion characteristics, providing more uniform burning and more constant pressure.
- a propellant for rocket motors which comprises a generallyeylindrical powder grain of ballistite having an axial passage and radial openings extending through the grain from said passage and each having a diameter equal to substantially one half the web thickness of the grain, the openings being spaced along the length of the grain and each opening being spaced from the adjacent opening a distance equal substantially to twice the diameter of said passage.
- a propellant for rocket motors which comprises a generally cylindrical powder grain of ballistite having an axial passage and radial openings extending through the grain from said passage and each having a diameter equal substantially to one-half the web thickness of the grain, the openings being spaced along the length of thegrain in a generally helical series andeach opening being spaced from the adjacent opening a distance equal substantially to twice the diameter of said passage.
- a propellant for rocket motors comprising a generally cylindrical powder grain which is darkened to render the grain substantially opaque and thereby inhibit the transmission of radiant energy into the interior of the grain during deflagration thereof, said grain having an axial passage and radial openings extending through the grain from said passage, the openings being spaced along the length of the grain and each opening being spaced from the adjacent opening a distance equal substantially to twice the diameter of said passage.
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- Engineering & Computer Science (AREA)
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- Combustion & Propulsion (AREA)
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- Medicinal Preparation (AREA)
Description
Feb. 17, 1953 B. H. SAGE ETAL a 2,628,561
PROPELLANT POWDER GRAIN FOR RocKET MOTORS Filed March 17, 195
FIG. I.
av W/LL/ 41%4405) M NM Patented Feb. 17, 1953 PROPELLANT POWDER GRAIN FOR ROCKET MOTORS Bruce H. Sage and William N. Lacey, Altadena,
Califi, assignors to the United States of America as represented by the Secretary of the Navy 7 Application March 1'7, 1943, Serial No. 479,538
3 Claims.
This invention relates to double-base powder grains and more particularly to a novel grain of this character which is resistant to fissuring and has improved burning qualities, and to a new method by which the grain may be made expeditiously at low cost. The powder grain of the invention has various uses but may be employed to particular advantage for purposes requiring relatively large grain sizes, as, for example, for the propellant charge in a jet propulsion rocket. Accordingly, for illustrative purposes the invention will be described and illustrated in the form of a rocket propellant charge, although it will be understood that the invention is not limited to this use.
Jet propulsion rockets have been employed heretofore in which the propellant charge is in the form of a single powder grain made from sheet stock of a double base powder, such as ballistite. In such rockets, it is desirable to use a powder grain having neutral or slightly regressive burning characteristics and which does not produce excessive pressures. However, we have found that grains made from ordinary ballistite sheet stock exhibit a marked fissuring and dis- ;integration resulting in a substantial increase in burning rate and pressure as the reaction One object of the present invention, theregrain which is resistant to fissuring and disintegration during combustion and burns at a substantially uniform rate over its entire surface.
Another object of the invention is to provide a new method of making powder grains by extruding sheet stock which is treated prior to the extrusion to render the finished product resistant to fissuring.
A further object of the invention resides in the provision of a novel powder grain of generally cylindrical form which is extruded with integral, longitudinal ribs on its cylindrical surface for strengthening the grain and for providing external combustion spaces between the ribs when the grain is mounted in a rocket motor body.
These and other objects of the invention may be better understood from the following detailed description, in which reference is made to the accompanying drawing illustrating one form of the new powder grain. In the drawing Fig. 1 is a side View of the powder grain, and
Fig. 2 is an end view of the powder grain shown in Fig. 1.
The powder grain, as shown, is generally cylin drical in form and has an axial passage extending through the grain, and a set of radial openings l I spaced along its length in a helix, as disclosed in a copending application of C. C. Lauritsen, Ser. No. 481,644, filed April 2, 1943, now Patent No. 2,464,181, issued March 8, 1949. Preferably, the grain is extruded from sheet stock of ballistite, or the like, and the die of the extrusion press is constructed so as to form the grain with integral, longitudinal ribs I2 on its outer cylindrical surface, the ribs being spaced circumferentially around the grain. The ribs l2 serve to strengthen the grain and also support it in the rocket motor body so as to provide external combustion spaces between the ribs, as disclosed in the above-identified application.
Powder grains extruded from ordinary sheet stock are translucent. Even though they appear from visual examination to be relatively homogeneous, they do not have uniform deflagrating characteristics, as evidenced by the fact that partially burned samples have substantial fissures resembling worm holes and show sharp edges, in contrast to the rounded contours inherent in grains which burn uniformly. As a result of the disintegration of these grains, they produce widely varying pressures and undergo progressive burning, which is undesirable in rocket motors and other applications. The conditions under which the grains are extruded appear to have little or no effect on their burning characteristics, and reextrusion of the grains results in very irregular reactions.
We have found that the formation of fissures or "worm holes during combustion of the powder grains may be inhibited to a substantial degree by rendering the grains relatively opaque. The reason for the decrease in fissuring with an increase in the opacity of the rain is not certain, but the following is offered as a possible explanation, it being understood that the invention is not in any way limited thereby or dependent thereon.
In the manufacture of solventless double base powders, a mixture of nitrocellulose and nitroglycerin is subjected to a colloiding action, usually with the aid of a blending agent, such as a gelatinizer or a gelatinizing accelerator," which remains in the finished powder. A suitable stabilizer may also be added, such as diphenylamine, to take up nitrogen oxides which may form in the powder. The emulsion then undergoes a drying operation, as by pressing or centrifuging, and the mass is rolled, molded or otherwise formed into blocks, sheets, strips, etc. While many improvements have been made in the art of colloiding nitrocellulose and. nitroglycerin mixture, it is practically impossible to obtain commercially a perfectly uniform colloid. As a result, the finished powder includes minute particles which are more sensitive to combustion than the other parts, and these more sensitive particles are dispersed throughout any grain which is extruded from the powder. When the grain is ignited, it burns first on its exposed surfaces, and since the grain is translucent the resulting radiation penetrates the interior of the grain and initiates combustion of the more sensitive particles inside the grain, whereby the fissures or worm holes are. formed, the burning area is substantially increased, and the adverse results of progressive burning are obtained.
A powder grain made in accordance with the present invention is characterized by the .iact that the normal translucency of the powder is reduced to thepoint where the grain is opaque or substantially opaque. We have 'found that a grain of this character is extremely resistant to fissuring and disintegration, exhibits neutral'or slightly regressive burning qualities, and burns uniformly without widely varying pressures, apparentiy for the reason that the opacityof the grain inhibits radiation of light to the more sensitive particles within the grain during combustion.
In accordance with the method of the invention, the powder is subjected to a darkening operation to obtain the desired opacity. In one form of the new method, the powder is rendered substantially opaque by exposing sheet stock of the powder to the action of light radiation of the shorter wave lengths, as by subjecting the sheet for a substantial period of time to sunlight, which is contrary to the usual practice in powder manufacture. The irradiation causes a rapid darkening and discoloring of the sheet stock, apparently due to chemical decomposition resulting in the liberation of one or more of the oxide of nitrogen and in their possible recombination with the stabilizer in the powder. Preferably, the darkening process is continued until the light which the sheet transmits is reduced to substantially i5 oi the light initially transmitted by the sheet. Such darkening may be obtained by placing the sheet in bright sunlight fora period of ten minutes or more, exposing first one side 01 the sheet and then the other sidefi The time required to darken the sheet may vary, depending upon the intensity of the light, the composition of the powder and the initial color of the sheet. After the sheet has been darkened, it is placed in an'extrusion press and extruded into a grain of the desired size. It will be understood that while we prefer to darken the powder stock before it is extruded, the stock may be extruded first and then darkened.
As one example of the practice of our invention, powder grains having the desired burning characteristics have been made from sheet stock of solventiess ballistite of .025 inch thickness and of the following composition expressed as percentages of the total weight: nitrocellulose, 51.42; nitroglycerin, 43.62; diethylphthalate, 3.49; potassium nitrate, 1.41; diphenylarnine, .66. The untreated sheet was lightyellow in color and translucent, yielding-a straw-colored grain when extruded, and the grain burned progressively with 1 an irregular reaction in which a large number of fissures, crevices and indentations developed. When a sheet of the powder stock, prior to extrusion, was placed in sunlight, the exposed surface appeared oily in :the first few minutes, and
4 after exposure for a period of approximately minutes, the stock darkened perceptibly and yielded a black extruded grain which appeared slightly more homogeneous than the grain extruded from the untreated stock. A tubular powder grain having an outside diameter of 1.7 inches and an inside diameter of .6 of an inch was extruded from the darkened stock and burned smoothly at a substantially uniform rate over its entire surface, even to the point where 'the'remaining web was less than .1 of an inch in thickness.
In the darkening of the sheet stock, it appears that radiation'of wave lengths shorter than apti'onal'to the time-of exposure. No lower limit to the eiiective wave length has been found, but it is probable that as the wave length is decreased a minimum in effectiveness is reached. In con- I nection with the chemical decomposition which presumably produces the darkening of the irradiated stock, it should be noted that exposure to radiation of relatively frequency ha 'been found to cause spontaneous decomposition of nitrocellulose explosives, especially those containing nitroglycerin, and it appears that double-base powder when exposed to radiation of a short wave length undergoes an accelerated decomposition. v j
Powder grains extruded from irradiated stock in accordance with our invention have physical properties compel is to those of grains extruded from nonirradiated stock. More particularly; the tensile strength, hardness, and spontaneous ignition'temperature are not substantially affected bythe irradiation treatment, and the conditions required for extrusion remain-substantially the same, except that a considerably greater pressure is required to'obtain the same extrusion rates with the noni'rra'diated stock. With respect to'the burning characteristics, however, it has been established by test that while grains'extrud ed from the irradiated material yield uniformly good results, the results with grains made from nonirradiated material are almost as uniformly poor.
It is to be understood that the darkening of the powder grains may be effected by mean other than irradiation, as, forexample, by the addition the desired combustion characteristics for rocket use are obtained by spacing each opening I i from the adjacent opening a distance equal'subst'antially to twice the diameter of the axial passage iii, and making each opening of a diameter equal substantially to half the web thickness of the grain, that is, to substantially one-half the difference between the internal and external diameters of the grain. With this construction, the radial openings ii in the grain tend to improve its combustion characteristics, providing more uniform burning and more constant pressure.
We claim:
A propellant for rocket motors, which comprises a generallyeylindrical powder grain of ballistite having an axial passage and radial openings extending through the grain from said passage and each having a diameter equal to substantially one half the web thickness of the grain, the openings being spaced along the length of the grain and each opening being spaced from the adjacent opening a distance equal substantially to twice the diameter of said passage.
2. A propellant for rocket motors, which comprises a generally cylindrical powder grain of ballistite having an axial passage and radial openings extending through the grain from said passage and each having a diameter equal substantially to one-half the web thickness of the grain, the openings being spaced along the length of thegrain in a generally helical series andeach opening being spaced from the adjacent opening a distance equal substantially to twice the diameter of said passage.
3. A propellant for rocket motors, comprising a generally cylindrical powder grain which is darkened to render the grain substantially opaque and thereby inhibit the transmission of radiant energy into the interior of the grain during deflagration thereof, said grain having an axial passage and radial openings extending through the grain from said passage, the openings being spaced along the length of the grain and each opening being spaced from the adjacent opening a distance equal substantially to twice the diameter of said passage.
BRUCE H. SAGE. WILLIAM N. LACEY.
6 REFERENCES orrnn The following references are of record in the file of this patent:
UNITED STATES PATENTS 2,408,252 Ganahl Sept. 24, 1946 OTHER REFERENCES Berthelot et al. in Comptes Rendus (1911), vol. 153, pp. 1220 and 1223.
Goddard, Method of Reaching Extreme Altitudes, Smithsonian Miscellaneous Collections, vol. 71, pp. 13 and 14, circa 1919, as reprinted by American Rocket Society, 1946, under the title Rockets by R. H. Goddard.
Sanger, Raketenflugtechnik, Munich and Berlin, 1933, pp. 54-67.
Ellis, Chemical Action of Ultra-Violet Rays," Reinhold, New York, 1941, Revised Edit. pp. 461- 463.
Chem. and Met. Engineering, May 1943, pp. 206, 208.
Oldenbourg,
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US479538A US2628561A (en) | 1943-03-17 | 1943-03-17 | Propellant powder grain for rocket motors |
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US479538A US2628561A (en) | 1943-03-17 | 1943-03-17 | Propellant powder grain for rocket motors |
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Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2920443A (en) * | 1955-05-25 | 1960-01-12 | Higginson John | Rocket propellant grain with helically grooved perforation |
US2933041A (en) * | 1954-04-12 | 1960-04-19 | Phillips Petroleum Co | Rocket grain |
US2942964A (en) * | 1955-04-26 | 1960-06-28 | Standard Oil Co | Stable gas-generating composition |
US2952876A (en) * | 1957-12-26 | 1960-09-20 | Phillips Petroleum Co | Extrusion of solid rocket grains |
US3008417A (en) * | 1959-09-14 | 1961-11-14 | Phillips Petroleum Co | Modular construction of solid rocket fuel charges |
US3046829A (en) * | 1959-06-22 | 1962-07-31 | Olin Mathieson | Composite propellent grains |
US3048112A (en) * | 1959-02-06 | 1962-08-07 | Phillips Petroleum Co | Gas generator |
DE1140028B (en) * | 1959-11-13 | 1962-11-22 | Rheinmetall Gmbh | Solid rocket propellant |
US3066139A (en) * | 1958-03-18 | 1962-11-27 | Zhivadinovich Milka Radoicich | High energy fuel and explosive |
US3069843A (en) * | 1958-05-29 | 1962-12-25 | Phillips Petroleum Co | Ignition of solid propellants |
US3073113A (en) * | 1959-10-06 | 1963-01-15 | Westinghouse Electric Corp | Propulsion apparatus |
US3093523A (en) * | 1955-10-24 | 1963-06-11 | Eli D Besser | Process for making extrudable propellant |
US3099963A (en) * | 1950-12-11 | 1963-08-06 | Dobrin Saxe | Outward burning neutral granulation for cast propellants |
US3130672A (en) * | 1959-04-07 | 1964-04-28 | Hexcel Products Inc | Rocket grain construction |
US3143446A (en) * | 1959-11-27 | 1964-08-04 | Gen Electric | Propellant charge containing fluid encapsulations |
US3144829A (en) * | 1958-12-16 | 1964-08-18 | Phillips Petroleum Co | Solid propellant charge |
US3228815A (en) * | 1966-01-11 | Doublexbase p propellants |
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US778788A (en) * | 1901-03-21 | 1904-12-27 | Hudson Maxim | Motive-power combustible for automobile torpedoes. |
US1397915A (en) * | 1921-02-07 | 1921-11-22 | Atlas Powder Co | Process of treating nitrocellulose and to a valuable nitrocellulose product resulting therefrom |
US2267261A (en) * | 1940-11-06 | 1941-12-23 | Hercules Powder Co Ltd | Smokeless powder |
US2408252A (en) * | 1942-12-23 | 1946-09-24 | Kaiser Cargo Inc | Ammunition |
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- 1943-03-17 US US479538A patent/US2628561A/en not_active Expired - Lifetime
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US175735A (en) * | 1876-04-04 | Improvement in gelatinated explosive compounds | ||
US273209A (en) * | 1883-02-27 | Iii iii iii | ||
US440921A (en) * | 1890-11-18 | Explosive | ||
US726901A (en) * | 1899-05-27 | 1903-05-05 | George Whitman Mcmullen | Explosive charge. |
US677528A (en) * | 1899-08-24 | 1901-07-02 | Hudson Maxim | Cartridge. |
US778788A (en) * | 1901-03-21 | 1904-12-27 | Hudson Maxim | Motive-power combustible for automobile torpedoes. |
US1397915A (en) * | 1921-02-07 | 1921-11-22 | Atlas Powder Co | Process of treating nitrocellulose and to a valuable nitrocellulose product resulting therefrom |
US2267261A (en) * | 1940-11-06 | 1941-12-23 | Hercules Powder Co Ltd | Smokeless powder |
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Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3228815A (en) * | 1966-01-11 | Doublexbase p propellants | ||
US3099963A (en) * | 1950-12-11 | 1963-08-06 | Dobrin Saxe | Outward burning neutral granulation for cast propellants |
US2933041A (en) * | 1954-04-12 | 1960-04-19 | Phillips Petroleum Co | Rocket grain |
US2942964A (en) * | 1955-04-26 | 1960-06-28 | Standard Oil Co | Stable gas-generating composition |
US2920443A (en) * | 1955-05-25 | 1960-01-12 | Higginson John | Rocket propellant grain with helically grooved perforation |
US3093523A (en) * | 1955-10-24 | 1963-06-11 | Eli D Besser | Process for making extrudable propellant |
US2952876A (en) * | 1957-12-26 | 1960-09-20 | Phillips Petroleum Co | Extrusion of solid rocket grains |
US3066139A (en) * | 1958-03-18 | 1962-11-27 | Zhivadinovich Milka Radoicich | High energy fuel and explosive |
US3069843A (en) * | 1958-05-29 | 1962-12-25 | Phillips Petroleum Co | Ignition of solid propellants |
US3144829A (en) * | 1958-12-16 | 1964-08-18 | Phillips Petroleum Co | Solid propellant charge |
US3048112A (en) * | 1959-02-06 | 1962-08-07 | Phillips Petroleum Co | Gas generator |
US3130672A (en) * | 1959-04-07 | 1964-04-28 | Hexcel Products Inc | Rocket grain construction |
US3046829A (en) * | 1959-06-22 | 1962-07-31 | Olin Mathieson | Composite propellent grains |
US3008417A (en) * | 1959-09-14 | 1961-11-14 | Phillips Petroleum Co | Modular construction of solid rocket fuel charges |
US3073113A (en) * | 1959-10-06 | 1963-01-15 | Westinghouse Electric Corp | Propulsion apparatus |
DE1140028B (en) * | 1959-11-13 | 1962-11-22 | Rheinmetall Gmbh | Solid rocket propellant |
US3143446A (en) * | 1959-11-27 | 1964-08-04 | Gen Electric | Propellant charge containing fluid encapsulations |
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