US262124A - Coating metals with zinc - Google Patents

Coating metals with zinc Download PDF

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US262124A
US262124A US262124DA US262124A US 262124 A US262124 A US 262124A US 262124D A US262124D A US 262124DA US 262124 A US262124 A US 262124A
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wiping
wires
zinc
box
wool
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/22Removing excess of molten coatings; Controlling or regulating the coating thickness by rubbing, e.g. using knives, e.g. rubbing solids

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  • Theinventionappliesto thecoatingofwires ordinarily so called, whether round or flat, and also to extended lengths in various other forms, as hoop-iron, &c.
  • the zinc there is a tendency of the zinc to become deteriorated in quality by a long subjection to the passage of the wire or analogous length of the iron or other metal to be coated.
  • I will describe the process as applied to thetreatment of common round wires, which I will assume are drawn down from rolled rods of Bessemer steel; but itmay be understood that any metal capable of being coated with 'zinc or analogous metal may be substituted,
  • wires may be flat, round, or of various other sections, and that they may be known as wires" or by the various other technical names, as hoop-iron, bale-ties, or the like.
  • I provide a long bath of melted zinc, with the heating-fires around the exterior, and the bottom relatively cool for the subsidence of what is known as dross.
  • I provide the ordinary surtace-coating of sal-ammoniac and the ordinary immersing-sinker, beneath which the wires are passed through the bath in order to insure their long and uniform immersion.
  • I provide peculiarly-efficient means for wiping off the surplus metal and for insuring a succession of fresh surfaces ofthe wiping material. I attain this end by leading the wires in an inclined direction upward from the bath through a mass of suitable wiping material, which is constantly moved in a direction opposite to that of the wires.
  • the wiping being effected in this manner and immediately on the emergence of the wires from the melted bath I can reduce the consumption of zinc to a minimum, and insure that it is left with more than ordinary uniformity of thickness. I have also improved the wiping by the application of a material hitherto unused for the purpose. It is what is known as slag-wool or silicate cottona silky, fibrous matter produced by the treatment of cinder from a blast-furnace by blowing out with a current of steam at high pressure. It is highly elastic and soft, and is not destroyed by the heat, has a just sufficient property of adhesion to the melted metal or wiping power, and is sufficiently mobile in itsof the ordinary and long-approved character.
  • Figure 1 is a vertical section through the entire apparatus.
  • Fig. 2 is a plan view of the same. Theremainingfigures representdetails detached.
  • Fig. 3 is a central vertical section of my improved wiping-box.
  • Fig. 4 is a plan view of a portion of the same, showing the ends of the agitating-rolls, their operatinggear, and the partition-space at the side.
  • A is the reel, from which the wire at is delivered; B, the acid bath; 0, a quantity of broken stone therein; D, a series of rolls, some of which are preferably turned by power to aid the movement of the wire; E, a guiding-sheave; F, tubes through the drying-furnace G; and H, a series of guiding-sheaves, from which the wire is plunged directly into the bath I of melted metal.
  • the wires On emerging from the metal bath I the wires are led up through slots in the bottom of a partially-overhanging box, K, which contains a liberal supply of the slag-wool 7c, which serves as the wiping material, and should be kept damp with water or tungstate of soda.
  • the wires are led in an inclined direction through this box, and emerge with just a sufiicient coating of zinc.
  • the required circulating movement of the wiping material is attained by rollers L, mounted in the wiping-box, and turned by gearing in the directions indicated by thearrows.
  • the surfaces of the several rolls are armed with projections l, which engage with a just suflieient quantity of the slag-wool, and drag it along in the direction opposite to the movement of the wires m.
  • rollers are turned slowly-only about one revolution in two seconds. They agitate the slagwool and continually present new surfaces thereof to the steadily-moving wires.
  • the general tendency of the rollers is to move the slag-wool gradually from the back to the front of the wiping-box, or, in other words, toward that side of the wiping-box which overhangs the tank.
  • the slag-wool is in its nature a good non-conductor. Its temperature is soon raised by the working, so that it approximates closely to that of the melted zinc, except that the upper stratum is kept wet and relatively cool by sprinkling with water, either ordinary fresh water or preferably a solution of tungstate of soda.
  • the aflinity or adhesion of the melted metal to the earthy wool is very slight.
  • each roller of each pair carries the slag-wool toward the tank on one side, where it effects the wiping, and away from it on the other side, where it is-returning idly.
  • P is an additional roll, of which I can use more than one, if necessary but my experiments do not indicate such need to aid in transferring the fibrous material from that end of the box toward the back or more distant side of the box.
  • the result is a constant agitation of the wiping material, and a presentation of afresh surface to the melted metal coating on the wire, also a movement of the material between the rolls toward the receiving side of the box, and thence upward and backward to the other side of the box, where it is again moved forward.
  • thelowermost rollers of each pair also carry a liberal current of the slag-wool downward, and move it backward in the base of the box; but of this I have not so well assured myself.
  • Mineral wool is just sufiiciently elastic and glassy in its nature.
  • the action of the rolls not only presents fresh surfaces, and presents them with a motion opposite to that of the wires, so as to insure an effective wiping, but also tends to induce a quite compact condition of the fibrous material at the base of the receiving side of the wiping-box. It tends the better to express any particles of melted metal which have been brought with it from the other portions of the box. I esteem this a marked advantage.
  • the journals of the several rollers L l are of considerable length, and project through two walls, which I provide in each end of the wiping-box, with an air-space between. This facilitates access for examination and oiling, and tends to prevent the induction of heat.
  • the lower portion of the side of the wipingbox nearest to the tank of melted metal is made in a separate piece from the rest, and can be removed on taking out the screws, which are inserted through lugs in the upper portion of the side. This facilitates the removal of the finely-broken wiping material which tends to accumulate there.
  • the dotted circles represent the gearing bywhich the rolls L are turned. I have not deemed it necessary to represent the belt through which the motion is received. I mount them in two independent trains, in order that I can, if preferred, after the operation has fairly commenced, arrest the motion ot'the rolls which are farthest from the metal bath and operate the remainder.
  • the mineral wool which I employ possesses the same capacity for wiping off the surplus metal from the wire as the various fibrous materials heretofore employed for that purpose, and it acts as efliciently, while, by reason of its mineral character and its capacity to endure a high temperature, it is not destroyed or seriously affected by the hot zinc, and can perform indefinitely for a long period.
  • the movement of the mineral wool loaded with the metal toward the tank, with the provisions for its easy escape therefrom to fall into the tank I claim as my improvement in zinc-coating wires- Themethodot'removingthesurplusofmelted metal from the wires on emerging from the bath by working the wiping material k, so as 20 to present constantly fresh surfaces, substantially as herein specified.

Description

2 Sheets -Sheet 1.
(No Model.)
H. ROBERTS.
COATING METALS WITH ZINC.
Patented Aug. 1, 1882.
N. PEIERS. Pholo ljlhugnphcn wmhm mm n.c.
ATENT F FICEQ HENRY ROBERTS, OF JOHNSTOWN, PENNSYLVANIA.
COATING METALS WITH ZINC.
SPECIFICATION forming part of Letters Patent No, 262,124, dated August 1, 1882, Application filed December 17,1880. (No model.)
To all whom it may concern:
Be it known that I, HENRY ROBERTS, a citizen of the United States, residing at Johnstown, Gambria county, in the State of Pennsylvania, have invented certain new and useful Improvements relating to Coating Metals with Zinc, of which the following is a specification.
Theinventionappliesto thecoatingofwires, ordinarily so called, whether round or flat, and also to extended lengths in various other forms, as hoop-iron, &c. There is a tendency of the zinc to become deteriorated in quality by a long subjection to the passage of the wire or analogous length of the iron or other metal to be coated. I will describe the process as applied to thetreatment of common round wires, which I will assume are drawn down from rolled rods of Bessemer steel; but itmay be understood that any metal capable of being coated with 'zinc or analogous metal may be substituted,
and that the wires may be flat, round, or of various other sections, and that they may be known as wires" or by the various other technical names, as hoop-iron, bale-ties, or the like.
I provide a long bath of melted zinc, with the heating-fires around the exterior, and the bottom relatively cool for the subsidence of what is known as dross. I provide the ordinary surtace-coating of sal-ammoniac and the ordinary immersing-sinker, beneath which the wires are passed through the bath in order to insure their long and uniform immersion. I provide peculiarly-efficient means for wiping off the surplus metal and for insuring a succession of fresh surfaces ofthe wiping material. I attain this end by leading the wires in an inclined direction upward from the bath through a mass of suitable wiping material, which is constantly moved in a direction opposite to that of the wires. The wiping being effected in this manner and immediately on the emergence of the wires from the melted bath I can reduce the consumption of zinc to a minimum, and insure that it is left with more than ordinary uniformity of thickness. I have also improved the wiping by the application of a material hitherto unused for the purpose. It is what is known as slag-wool or silicate cottona silky, fibrous matter produced by the treatment of cinder from a blast-furnace by blowing out with a current of steam at high pressure. It is highly elastic and soft, and is not destroyed by the heat, has a just sufficient property of adhesion to the melted metal or wiping power, and is sufficiently mobile in itsof the ordinary and long-approved character.
The accompanying drawings form a part of this specification, and represent what I consider the best means of carrying out the invention.
Figure 1 is a vertical section through the entire apparatus. Fig. 2 is a plan view of the same. Theremainingfigures representdetails detached. Fig. 3 is a central vertical section of my improved wiping-box. Fig. 4 is a plan view of a portion of the same, showing the ends of the agitating-rolls, their operatinggear, and the partition-space at the side.
Similar letters of reference indicate like parts in all the figures.
I have shown but one wire.
A is the reel, from which the wire at is delivered; B, the acid bath; 0, a quantity of broken stone therein; D, a series of rolls, some of which are preferably turned by power to aid the movement of the wire; E, a guiding-sheave; F, tubes through the drying-furnace G; and H, a series of guiding-sheaves, from which the wire is plunged directly into the bath I of melted metal.
J J 'are sinkers in the melted metal, so placed that the wires in passing under these sinkers are certain of being immersed to the proper depth. The tank is of sufficient length to insure auniformity of temperature between the wires and the bath before the wires emerge. I have in my experiments made the metaltank I about twelve (12) feet long, and caused the wires to traverse a little over a foot per second. The sinkers J are peculiar. There is one of these for each wire. Each has at its upper end an outwardly-projecting lug, which is just the right size to engage in graduated holes in a bridge or piece spanning the end of the tank. On emerging from the metal bath I the wires are led up through slots in the bottom of a partially-overhanging box, K, which contains a liberal supply of the slag-wool 7c, which serves as the wiping material, and should be kept damp with water or tungstate of soda. The wires are led in an inclined direction through this box, and emerge with just a sufiicient coating of zinc. The required circulating movement of the wiping material is attained by rollers L, mounted in the wiping-box, and turned by gearing in the directions indicated by thearrows. The surfaces of the several rolls are armed with projections l, which engage with a just suflieient quantity of the slag-wool, and drag it along in the direction opposite to the movement of the wires m. The
. rollers are turned slowly-only about one revolution in two seconds. They agitate the slagwool and continually present new surfaces thereof to the steadily-moving wires. The general tendency of the rollers is to move the slag-wool gradually from the back to the front of the wiping-box, or, in other words, toward that side of the wiping-box which overhangs the tank. The slag-wool is in its nature a good non-conductor. Its temperature is soon raised by the working, so that it approximates closely to that of the melted zinc, except that the upper stratum is kept wet and relatively cool by sprinkling with water, either ordinary fresh water or preferably a solution of tungstate of soda. The melted zinc removed by the particles of slag-wool, and moved actively toward the receiving side of the box, is deposited in that edge of the box and dropped through the slots there provided into the tank. The aflinity or adhesion of the melted metal to the earthy wool is very slight.
Instead of accumulating and becoming densely compacted in the receiving side of the wiping-box, I take measures to produce a circulation of the material. It is worked under and over the several rollers. Each roller of each pair carries the slag-wool toward the tank on one side, where it effects the wiping, and away from it on the other side, where it is-returning idly.
P is an additional roll, of which I can use more than one, if necessary but my experiments do not indicate such need to aid in transferring the fibrous material from that end of the box toward the back or more distant side of the box. The result is a constant agitation of the wiping material, and a presentation of afresh surface to the melted metal coating on the wire, also a movement of the material between the rolls toward the receiving side of the box, and thence upward and backward to the other side of the box, where it is again moved forward. I believe that thelowermost rollers of each pair also carry a liberal current of the slag-wool downward, and move it backward in the base of the box; but of this I have not so well assured myself. Mineral wool is just sufiiciently elastic and glassy in its nature. The action of the rolls not only presents fresh surfaces, and presents them with a motion opposite to that of the wires, so as to insure an effective wiping, but also tends to induce a quite compact condition of the fibrous material at the base of the receiving side of the wiping-box. It tends the better to express any particles of melted metal which have been brought with it from the other portions of the box. I esteem this a marked advantage.
The journals of the several rollers L l are of considerable length, and project through two walls, which I provide in each end of the wiping-box, with an air-space between. This facilitates access for examination and oiling, and tends to prevent the induction of heat.
The lower portion of the side of the wipingbox nearest to the tank of melted metal is made in a separate piece from the rest, and can be removed on taking out the screws, which are inserted through lugs in the upper portion of the side. This facilitates the removal of the finely-broken wiping material which tends to accumulate there.
Modifications may be made in the forms and proportions of the details.
I have worked successfully with the wipingbox only about two (2) feet wide, so as to give a wiping traverse of only two (2) feet; but this may be varied. I believe that little gain would result from an increase of the wipingtraverse, because wires of small size become rapidly cooled. For very large wires a wider wiping-box would be expedient.
Instead of slots to receive the wires in the overhanging portion ofthe wiping-box K, I can use plain round holes; but I esteem slots preferable. There is a tendency of the slag-wool to become worn, abraded, or broken, so as to accumulate a fine dust in the bottom. When this has become too fine I replace it with fresh. No particular ditficulty is experienced if considerable of the broken earthy matter falls upon the melted zine.
The dotted circles represent the gearing bywhich the rolls L are turned. I have not deemed it necessary to represent the belt through which the motion is received. I mount them in two independent trains, in order that I can, if preferred, after the operation has fairly commenced, arrest the motion ot'the rolls which are farthest from the metal bath and operate the remainder.
The mineral wool which I employ possesses the same capacity for wiping off the surplus metal from the wire as the various fibrous materials heretofore employed for that purpose, and it acts as efliciently, while, by reason of its mineral character and its capacity to endure a high temperature, it is not destroyed or seriously affected by the hot zinc, and can perform indefinitely for a long period. The movement of the mineral wool loaded with the metal toward the tank, with the provisions for its easy escape therefrom to fall into the tank I claim as my improvement in zinc-coating wires- Themethodot'removingthesurplusofmelted metal from the wires on emerging from the bath by working the wiping material k, so as 20 to present constantly fresh surfaces, substantially as herein specified.
In testimony whereofI have hereunto set my hand, at New York city, this 7th day of December, 1880, in the presence of two subscrib- 2 ing witnesses.
HENRY ROBERTS. Witnesses:
W. OoLBoRNE BROOKS, H. A. J onns'ronn.
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