US2613179A - Silver plating - Google Patents

Silver plating Download PDF

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Publication number
US2613179A
US2613179A US755738A US75573847A US2613179A US 2613179 A US2613179 A US 2613179A US 755738 A US755738 A US 755738A US 75573847 A US75573847 A US 75573847A US 2613179 A US2613179 A US 2613179A
Authority
US
United States
Prior art keywords
potassium
electrolyte
selenite
silver
cathode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US755738A
Other languages
English (en)
Inventor
Wolfson Henry
Thomson Bernard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Standard Electric Corp
Original Assignee
International Standard Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Standard Electric Corp filed Critical International Standard Electric Corp
Application granted granted Critical
Publication of US2613179A publication Critical patent/US2613179A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/46Electroplating: Baths therefor from solutions of silver
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S29/00Metal working
    • Y10S29/012Method or apparatus with electroplating

Definitions

  • Electrolyte-E a Electrolyte li are obtained at current densitieszof 1'8.-,-27la./ gogas im cy m 2g a i w oassumnl re. s. z' from a solution the essential feature of...which 1s Potassiumlselldite; :7 I M the addition of selemum (as seleniteytoa 'cy: Current density "amp/it 20-1130 Room temperature: Moderate agitation. Anodes-silver. two to four times area of cathode, or more.
  • Electrolyte A appears to yield a deposit of slightly superior quality to Electrolyte B: on the other hand Electrolyte B has a rather wider range of current density.
  • the ratio between the areas of the anode and cathode of a bath using an electrolyte according to the invention should be greater than that normally accepted, as otherwise anode dissolution might be impaired at the high current densities employed.
  • Sodium salts or other alkali metal salts may be used wholly or partly in place of potassium from which we are able to produce excellent salts on an equivalent basis.
  • bright deposits of silver at current densities some Substantial increase of speed of deposition can four to six times greater than could be used with be obtained with a stationary cathode and withaconventional plating solution. out any form of agitation of the solution, an The formulae for our preferred solutions were node having an area about twice that of the evolved after a number of experiments aimed at cathode, and a current density of th order of determining the most useful concentration of the 10 amp/ftF, but the full advantage of the intwo addition agents.
  • An argentocyanide electrolyte'foruse in electrodepositing bright silver plate'athigh current densities of at least 10 amp/ft. of cathode area that consists essentially of an aqueous solution of the following substances in substantially the proportions indicated:
  • An argentocyanide electrolyte for use in electrodepositing bright silverplate at high current densities of at least 10 amp/ft. of cathode area that consists essentially of anaqueous solution of the following substances in substantially the proportions indicated:
  • a process for electrodepositing a bright'silver plate upon an article that comprises making the article the cathode during electrolysis at a current density of at least 10 amp/ft. of cathode area, of an electrolyte that consists essentially of an aqueou solution of the following substances in substantially the indicated proportions.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
US755738A 1946-06-20 1947-06-19 Silver plating Expired - Lifetime US2613179A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2613179X 1946-06-20

Publications (1)

Publication Number Publication Date
US2613179A true US2613179A (en) 1952-10-07

Family

ID=10911654

Family Applications (1)

Application Number Title Priority Date Filing Date
US755738A Expired - Lifetime US2613179A (en) 1946-06-20 1947-06-19 Silver plating

Country Status (2)

Country Link
US (1) US2613179A (de)
FR (1) FR954614A (de)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2732336A (en) * 1956-01-24 Electroplating composition for copper
US2771380A (en) * 1954-08-02 1956-11-20 Burgess Battery Co Method of plating copper particles with silver
US2777810A (en) * 1956-10-03 1957-01-15 Elechem Corp Bath for electroplating silver
US3458408A (en) * 1962-11-16 1969-07-29 Monsanto Co Method for making an inductive heating element for zone refining apparatus
US4155817A (en) * 1978-08-11 1979-05-22 American Chemical And Refining Company, Inc. Low free cyanide high purity silver electroplating bath and method
WO2014137638A1 (en) * 2013-03-06 2014-09-12 Macdermid Acumen, Inc. High speed copper plating process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2440672A (en) * 1942-10-24 1948-05-04 Gen Motors Corp Electroplating bath for silver
US2449726A (en) * 1945-07-12 1948-09-21 Arthur F Cutten Direct coating of silver on iron or steel

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2440672A (en) * 1942-10-24 1948-05-04 Gen Motors Corp Electroplating bath for silver
US2449726A (en) * 1945-07-12 1948-09-21 Arthur F Cutten Direct coating of silver on iron or steel

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2732336A (en) * 1956-01-24 Electroplating composition for copper
US2771380A (en) * 1954-08-02 1956-11-20 Burgess Battery Co Method of plating copper particles with silver
US2777810A (en) * 1956-10-03 1957-01-15 Elechem Corp Bath for electroplating silver
US3458408A (en) * 1962-11-16 1969-07-29 Monsanto Co Method for making an inductive heating element for zone refining apparatus
US4155817A (en) * 1978-08-11 1979-05-22 American Chemical And Refining Company, Inc. Low free cyanide high purity silver electroplating bath and method
WO2014137638A1 (en) * 2013-03-06 2014-09-12 Macdermid Acumen, Inc. High speed copper plating process

Also Published As

Publication number Publication date
FR954614A (de) 1950-01-04

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