US2599091A - Forming pigment in cellulose fiber and paper containing the pigmented fiber - Google Patents

Description

Patented June 3, 1952 UNITED STATES GFFHZE FoRiviINdi GMENT IN emtiet AND PAPER CONTAINING THE PIGMENTED FIBER S em 1% tiiiiiii. (01. 92-3) .dt'Tll'i ngillven relates to. impliovements. in Pa er menu ae m'e and, includes. anew {composite mfintegivsheet of paper and an improved metho p tspr duction, ,o w o. e, o W .flhewnewypape flof the. pr.esent\,inventionois a pi m n p per made x1.111.la ely.of. untreated ,09 ofi r lai e w th, 1a. reg lated...amount... of ee il .lni me tednmod fied stock .containing the pigmentwitlqin as well as on and around the fibexspftbe. modified t09k., Y

vpresent imgeption is basedupon thesd'is- 11 that 9a. ortion ofnthe cellulnsic. fib t EQQK weemicel fiem -ch mical; .Ql-lnechanieal P1 I iified inn aking epe ckm fle t vfiqh ce .pul u h s kraftnsulfi ebsoda ul ve c ns particularly emnndwood. ,(ligno- 961 1105?) fibers gmechen elpulp), .Q nbe e in the .iqn .of ,avsu ns on in wa st- 6 1 with, ealciun; chloride in th e form; 0f a. .stron solution to modify the cellulose or the ligneeceh lulpse e nd that the so nlcditled.,,ce llulosic fibers can then be treated with ai jqlutionoofanoluble em es o miu erb n e r ita e an m oq l P ment, fi Qh; e v:ta cium carbonate Wit in. 9 P9991 181 fi ers asewelldas conten rb i qet e.m difi clhfibexs; end thatthe .re'sulte lwdi g and p men d t c nceneadvam t'i ebusly. beel d d, wfilxnnedmixea witheune treated s. 0.01; to produce an improved composite le iefel 9 1 .3 a relat ye fisma lpmportion of th q elh o q mt 9i 1. 111 or; etec; used inomeki'n' fifi ws s bf e to thetr etmentwitheale st ng: calci m. hl zi deesqlut p ie e tt ut m r n em iiythete m o e- 111 1c m chlorideec c e 5 salt:

, H 5 1 1 to 20%, more or less ofcalcium chlofide. en flli orqals mn. cele i e isr 0mm chloride to modify thfihelqs, and with,

diumearbonage to precipitate ,ce1pium, cagbon'a'te e fi ff ui i tli Qeber I'hachine in making the new en wee e 79 91 v v mien afnount of adrmxed, long fiber cellulose stoclij.

e ewe Which' b te thceltn t e to' m'ddifi and pigment the fibers include'long actidnistobring"aboutjdprofound cliang k. borete, .e,,g., in the form ofsa' 10%.s01i1ti0n in suf- 60 ficientemount to reactywith the calcium chlbiide emltprfitinita e .imelublemigmnt e e Y.,.--;c.a1= ciuzmcerbonete ormalcium borateu intend on-Lthe modified fiberse The w em cm ;r 1t ...0f addedsoluble salt i s equel to, or, somewhat,more orhless than the amount which is suflicient to react with all of the calcium chloride used. With cellulose fibers the amount of soluble salt is advantageously slightly in excess of that required to react with all of the calcium chloride; but with groundwood fibers care should in general be taken to avoid any excess of the alkali salt which would darken or otherwise affect the stock; and with such stock the calcium chloride and sodium carbonate are used in exact reacting proportions or with a slight excess of calcium chloride to avoid any excess of sodium carbonate.

The resulting treated and pigmented stock is highly hydrated and has little strength, or relatively much less strength than the untreated stock, but it carries the precipitated pigment dis. tributed throughout the hydrated stock while pigment is also precipitated on the hydrated stock and in the water in which the stock is suspended.

The specially treated and modified and pigmented stockis highly pigmented. An amount of pigment can be combined with the stock which is considerably in excess of the weight of the stock treated (dry basis). Thus cellulose fibers can be modified and pigmented to give a proportion of pigment to stock (dry basis) of up to around two to one or more. Groundwood stock can be pigmented to a much greater extent, up to around 4 parts of pigment to l of fiber (dry basis) or even higher.

According to the present invention the highly pigmented and hydrated modified stock is admixed with untreated stock and the resulting composite or admixed stocks are used in the paper machine for making the new sheet of paper,

The proportions of pigmented modified stock and of untreated stock which are admixed to form the new sheet of paper can be somewhat varied. In general, it is advantageous to subject only a relatively small proportion or percentage of the total stock used to the modifying and pigmenting treatment and to admix it with a large proportion of untreated stock. In this way the final sheet of paper will have a desirable strength,

due to the large proportion of unmodified fibers used, but the entire sheet will be pigmented by the admixed small amount of heavily pigmented modified stock.

The stock after treatment with the calcium chloride and with the soluble sodium salt will contain sodium chloride in solution. In general, this is undesirable and is removed by washing the treated stock'to remove the sodium chloride or the greaterportion of it before the modified pigmented stock is admixed with the untreated stock and fed to the paper machine. The washing of the treated stock can be carried out by decantation or by washing in pulp washers with replacement of the sodium chloride solution with fresh water, care being taken that the water drawn off is clear or relatively clear water to avoid or minimize loss of finely suspended pigment during the washing operation.

The main portion of the stock with which the modified pigmented stock is admixed may be stock which is prepared, e. g., in the beater in the ordinary way and which may be sized and prepared for paper making before the treated stock is added. The stocks are thoroughtly admixed together before the composite stock goes to the paper machine; and, in making a sized sheet, or when using mechanical stock, the admixing is advantageously carried out at a point close to the paper machine such as the machine 4 chest or later with sufficient mixing to insure uniformity of the stock fed to the machine.

Rosin soap and alum are commonly added to the untreated stock for sizing. If the stocks after admixture are not sufficiently acid a further amount of alum is advantageously added at the timeof mixing or before the admixed stocks go on the paper machine. The main portion of the stock may thus be ordinary stock prepared in the beater and which may be sized and prepared for paper making before the specially treated and pigmented stock is admixed therewith to form the composite pigmented stock for the paper machine.

Where the paper is to be made from admixed groundwood and chemically cooked cellulose pulp. either a portion of the cellulose stock or of the groundwood stock may be specially treated to modify and pigment it before admixing with the remainder of the stock. In many cases it is more advantageous to treat a portion of the groundwood stock because of the increased amount of pigment which can be incorporated in it and retained by it, care being taken, as above explained, to avoid excess of alkali in the treatment which would tend to darken or otherwise affect the groundwood stock treated.

The paper can be made from the admixed stocks on Fourdrinier or cylinder machines and various kinds of paper can be made including book paper, magazine paper, newsprint, and other printing papers which are directly prepared as pigmented papers. The present invention enables a sheet of paper to be produced approaching a precoated sheet on a paper machine. Paper can thus be made with up to 40% carbonate pigment included in the composite furnish to give a pre-- coated sheet, and only a small proportion of the stock, e. g., 10% of groundwood stock, need be treated to give a highly pigmented composite sheet.

Newsprint is commonly made from groundwood pulp with around, e. g., 8 to 12% of long fiber sulfite pulp. In general, only a small percentage of the total stock will be treated to modify it and pigment it so that most of the stock will be untreated stock which retains its full strength. The treatment of a small portion of the stock tends to gelatinize the fiber and cause loss of strength of the fibers treated, but by heavily treating a small amount of the fiber and mixing it with a large amount of untreated fiber there is obtained a strong sheet which is pigmented by the gelatinizing and pigmentin treatment of the small portion of pulp.

The percentage of the total stock to be treated in making a sheet of paper can be somewhat varied. For various grades of paper an amount of around 10% of the stock can advantageously be treated. The small proportion of the stock treated can be heavily pigmented so that it will contain, e. g., in the case of chemical cellulose pulp up to around twice as much pigment as fibers (dry basis) or more, and in the case of groundwood pulp up to around four times as much pigment as fiber (dry basis) or more. By admixing, e. g., 10% of treated stock heavily pigmented with an amount of pigment considerably in excess of the weight of the stock treated and admixing the treated stock with the remaining of untreated stock and using the resulting mixed stock in making paper, a pigmented stock of good strength can be directly produced in the paper machine.

The proportion of stock to be treated before cium. chloride (74% CaClz) are added and mixed thoroughly and dissolved and the agitation is continued for about 10 minutes to efiect thorough treatment and gelling of the stock by the action of calcium chloride. A sodium carbonate solution is made by dissolving 300 pounds of soda ash in water to form a solution of about 10%. This solution is pumped into the calcium chloride treated stock and allowed to mix therewith, with continued agitation, until complete precipitation has occurred. The resulting treated stock in the.

form of a fibrous precipitate is pumped to storage tanks and allowed to settle without agitation. After settling, the top liquor (sodium chloride solution) is drawn off and replaced with fresh water to give a treated stock ready for blending with the untreated stock.

The untreated stock is prepared as aregular beater furnish from 9600 parts of groundwood of 2.5 consistency (240 parts dry basis), 9600 parts of unbleached sulfite of 2.5% consistency,(240

parts dry basis), 9 parts of titanium dioxideand 9 parts of alum. This furnish prepared in a heater is passed through a Jordan and the specially treated stock is then admixed therewith in the paper making machine at the mixing, box, with thorough intermixture. Alum is added to the mixing box to keep the stock acid.

This stock is then passed to the Fourdrinier.

machine and formed into a sheet of paperwhich can be calendered or super-calendered. Sheets of paper so produced contained around 26% of calcium carbonate filler as computed from ash. A sheet of paper so produced showed a Mullen test of 14.6, a tensile of 6.4-3.6, and a tear of -32.

In such a composite sheet of paper the specially I treated and gelatinized and pigmented stock forms a valuable pigmenting filler stock for admixing with the regular beater furnish. While the treated stock if used by itself to make acellulose pulp can be used in making papers of different kinds and in some cases the paper may be made entirely of cellulose pulp or mixtures of cellulose pulps with little or no admixed groundwood. Similarly paper such as newsprint.

can be made mainly of groundwood with only small amounts of admixed long fiber chemical stock. It is thus possible to produce a wide range of pigmented papers including book paper, magazine paper, newsprint, and other types of paper which are pigmented in a particularly advantageous manner.

The special treatment of a portion of the pulp to be pigmented results in the precipitation of the pigment within the fibers of the stock as well as on and around the fibers and enables a much larger weight of pigment to be incorporated in the pulp so treated than the weight (dry basis) of the fibers treated. The modified and pigmented pulp may thus be considered in the na: ture of a fibrous pigment with the pigment intimately combined with a lesser weight of the modified and gelatinized stock. Theadmixture of this modified and pigmented stock with the untreated stdck' results in distribution of the pig-' ment or fibrous pigment or pigmented fibers through the composite pulp so that a pigmented sheet of paper can be directly produced with the pigment contained within as well as on and around the fibers. Although the pigmented portion of the stock is only a relatively small portion of the total stock from which the paper is made, yet by heavily pigmenting the treated portion a sheet of paper can be produced with a high pigment content and with other desirable properties.

It will thus be seen that the present invention provides a new sheet of paper made up largely or mainly of untreated fibers admixed with a relatively small proportion of highly pigmented fibers pigmented by a process in which the carbonate is precipitated both in and on and around the fibers and with the fibers of the treated portion of the stock themselves highly hydrated or gelatinized by the treatment.

It will further be seen that the improved process of the present invention involves treating only a part of the stock to modify it and pigment it followed by admixing of this pigmented and modified stock with a large proportion of untreated stock.

It will further be seen that the treatment of a portion of the stock with strong calcium chloride solution brings about a modification and gelatinizing or hydration of the stock so treated and that the precipitation of the calcium chloride with, e. g., sodium carbonate or sodium borate gives a pigment precipitate, e. g., of calcium carbonate or calcium borate within the fibers so treated as well as on and around the fibers so treated.

Although the treatment of a portion of the stock reduces the strength of the fibers and even though the treated stock would have little strength if used by itself in making paper, yet when this treated stock is admixed'with a large proportion of untreated stock it blends therewith to give an improved sheet of paper of good tensile strength and which can be highly pigmented and produced directly as a pigmented paper as a part of the paper making process.

The new sheet of paper will contain the large proportion of untreated fibers intimately combined and admixed with the pigmented and gelatinized and modified fibers. The paper will accordingly retain the desirable characteristics of paper made from untreated fibers but will in addition have modified and improved properties due to the presence therein of the modified and pigmented fibers and the pigment formed during the treatment of such fibers so that the paper as a whole is a new and valuable pigmented paper directly produced on the paper making machine.

This application is a continuation-in-part of my prior application Serial No. 643,961, filed J anuary 28, 1946, now abandoned, describing the production of fibrous pigments by treating cellulose fibers (chemical pulp) with a strong solution of calcium chloride to modify, hydrate and gelatinize the fibers followed by treatment with sodium carbonate to precipitate a large amount of calcium carbonate pigment in and on and around the fibers, and largely within the fibers; and the use of such fibrous pigment in the outer layer or liner of multiply paper and board.

My companion application Serial No. 666,199,

filed April 30, 1946, relates more broadly to the production of multiply layer paper and board with the use of such highly pigmented fibers or fibrous pigments, either alone or admixed :with

a smaller amount of unpigmented fibers in torming the outer layer or liner of multiply paper and board.

I claim:

1. The method of producing a pigmented and gelatinized cellulosic fibrous stock particularly adapted for admixture with unpigmented cellulosic fibrous stock in the manufacture of paper which comprises subjecting, at ordinary temperatures, an aqueous suspension of cellulosic fibers to the action of a strong solution of calcium chloride until the calcium chloride brings about a gelatinization of the cellulosic fibers, and adding a soluble salt which will react with the calcium chloride to precipitate a calcium compound pigment in and on the gelatinized cellulosic fibers,the amount of calcium chloride in the solution being sufiicient that the amount of precipitated calcium compound remaining in and on the fibers is in excess of the weight of the fibers.

2. The method according to claim 1, in which the cellulosic fibers treated are groundwood fibers.

3. The method according to claim 1, in which the cellulosic fibers treated are chemically-treated fibrous pulp.

4. The method according to claim 1, in which sodium carbonate is reacted with the calcium chloride to precipitate a finely-divided calcium carbonate pigment in and on the gelatinized c:

cellulosic fibers.

5. The method according to claim 1, in which the cellulosic fibers are groundwood fibers, in which the calcium chloride solution contains from about 15% to 20% of calcium chloride and in which sodium carbonate is added to react with the calcium chloride to precipitate a finelydivided calcium carbonate pigment in and on the gelatinized cellulosic fibers.

6. The method of making pigmented paper on a papermaking machine, which comprises admixing the gelatinized and pigmented fibers produced in accordance with the method of claim 1, in amount of from about 5% to 25%, with unpigmented cellulosic fibers and forming a pigmented sheet of paper from the resulting admixed fibers.

7. The method according to claim 6, in which the unpigmented cellulosic fibers are chemicallytreated fibrous pulp.

8. The method of making pigmented paper on r a papermaking machine from a furnish which includes groundwood fibers and chemicallytreated fibers in which from about 5% to 25% 01' the fibers are treated in accordance with the method of claim 1 and the resulting gelatinized and pigmented fibers are admixed with the unpigmented portion of the fibers and the resulting mixture is formed into a sheet of paper on a paper machine.

9. The method of making pigmented paper on a papermaking machine, which comprises admixing the gelatinized and pigmented fibers pro- Marsh, published by Chapman and 10 duced in accordance with the method of claim 4. inamount of from about 5% to 25%, with unpigmented fibers and forming a pigmented sheet of paper from the resulting admixed fiber.

10. The method of making pigmented paper on a papermaking machine from a furnish, which includes groundwood fibers and chemicallytreated fibers in which from about 5% to 25% of the fibers are treated in accordance with the method of claim 4 and the resulting gelatinized and pigmented fibers are admixed with the unpigmented portion of the fibers and the resulting mixture is formed into a sheet of paper on a papermaking machine.

11. Highly pigmented gelatinized cellulosic fibers produced in accordance with the method of claim 1 and containing an amount of finelydivided precipitated calcium compound pigment in excess of the dry weight of the fibers.

12. Highly pigmented gelatinized cellulosic fibers as defined in claim 11, in which the weight of the finely divided precipitated pigment is more than twice the weight of the fibers.

13. Highly pigmented gelatinized cellulosic fibers as defined in claim 11, in which the finelydivided precipitated pigment is calcium carbonate.

14. A new sheet of paper made of admixed fibers, from 5% to 25% of which are highly pigmented gelatinized cellulosic fibers as defined in claim 11, and the remainder of the fibers are ungelatinized cellulosic fibers.

15. A new sheet of paper of admixed fibers. from 5% to 25% of which are highly pigmented gelatinized cellulosic fibers as defined in claim 11 and are pigmented with calcium carbonate, and the remainder of the fibers are ungelatinized cellulosic fibers.

WILLIAM LUTTON CRAIG.

REFERENCES CITED The following references are of record in the file 01 this patent:

UNITED STATES PATENTS Number Name Date 123,747 Tieman Feb. 13, 1872 157,198 Duemling Nov. 24, 1874 354,477 Just et al Dec. 14, 1886 2,173,167 Hovey Sept. 19, 1939 2,315,892 Booth Apr. 6, 1943 2,457,797 Craig Jan. 4, 1949 FOREIGN PATENTS Number Country Date 404 Great Britain of 1869 5,776 Great Britain of 1899 516,162 Great Britain Dec. 22, 1939 OTHER REFERENCES Introduction to the Chemistry of Cellulose by Hall, Ltd., London (1938), page 73.

Claims (3)

1. THE METHOD OF PRODUCING A PIGMENTED AND GELATINIZED CELLULOSIC FIBROUS STOCK PARTICLUARLY ADAPED FOR ADMIXTURE WITH UNPIGMENTED CELLULOSIC FIBROUS STOCK IN THE MANUFACTURTE OF PAPER WHICH COMPRISES SUBJECTING, AT ORDINARY TEMPERATURES, AN AQUEOUS SUSPENSION OF CELLULOSIC FIBERS TO THE ACTION OF A STRONG SOLUTION OF CALCIUM EHLORIDE UNTIL THE CALCIUM CHLORIDE BRINGS ABOUT A GELATINIZATION OF THE CELLULOSIC FIBERS, AND ADDING A SOLUBLE SALT WHICH WILL REACT WITH THE CALCIUM CHLORIDE TO PRECIPITATE A CALCIUM COMPOUND PIGMENT IN AND ON THE GELATINIZED CELLULOSIC FIBERS, THE AMOUNT OF CLACIUM CHLORIDE IN THE SOLUTION BEING SUFFICIENT THAT THE AMOUNT OF PRECIPITATED CALCIUM COMPOUND REMAINING IN AND ON THE FIBERS IS IN EXCESS OF THE WEIGHT OF THE FIBERS.

11. HIGHLY PIGMENTED GELATINIZED CELLULOSIC FIBERS PRODUCED IN ACCORDANCE WITH THE METHOD OF CLAIM 1 AND CONTAINING AN AMOUNT OF FINELYDIVIDED PRECIPITATED CALCIUM COMPOUND PIGMENT IN EXCESS OF THE DRY WEIGHT OF THE FIBERS.

14. A NEW SHEET OF PAPER MADE OF ADMIXED FIBERS, FROM 5% TO 25% OF WHICH ARE HIGHLY PIGMENTED GELATINIZED CELLULOSIC FIBERS AS DEFINED IN CLAIM 11, AND THE REMAINDER OF THE FIBERS ARE UNGELATINZED CELLULOSIC FIBERS.