US2552570A - Oxidation resisting hydrocarbon products - Google Patents

Oxidation resisting hydrocarbon products Download PDF

Info

Publication number
US2552570A
US2552570A US788670A US78867047A US2552570A US 2552570 A US2552570 A US 2552570A US 788670 A US788670 A US 788670A US 78867047 A US78867047 A US 78867047A US 2552570 A US2552570 A US 2552570A
Authority
US
United States
Prior art keywords
oil
alcohols
oils
alcohol
products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US788670A
Other languages
English (en)
Inventor
John G Mcnab
Niilo V Hakala
John P Mcdermott
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL72745D priority Critical patent/NL72745C/xx
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Priority to US788670A priority patent/US2552570A/en
Priority to GB22971/48A priority patent/GB670077A/en
Priority to FR971155D priority patent/FR971155A/fr
Application granted granted Critical
Publication of US2552570A publication Critical patent/US2552570A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/10—Thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
    • C10L1/265—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen and/or sulfur bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2691—Compounds of uncertain formula; reaction of organic compounds (hydrocarbons acids, esters) with Px Sy, Px Sy Halz or sulfur and phosphorus containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/20—Natural rubber; Natural resins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/027—Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/08—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/146—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/044—Acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/20—Containing nitrogen-to-oxygen bonds
    • C10M2215/202—Containing nitrogen-to-oxygen bonds containing nitro groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088—Neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089—Overbased salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C10M2223/121—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy of alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/06—Groups 3 or 13
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/30—Refrigerators lubricants or compressors lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/32—Wires, ropes or cables lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/34—Lubricating-sealants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/38—Conveyors or chain belts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/40—Generators or electric motors in oil or gas winning field
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/42—Flashing oils or marking oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/44—Super vacuum or supercritical use
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/50—Medical uses
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/04—Oxidation, e.g. ozonisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Definitions

  • the present invention relates to the improvement of hydrocarbon products and in particular to the improvementof mineral lubricating oil compositions by the incorporation therein of a class of additives which impart oxidation resist-'- ing properties to such products.
  • cuprous salts more-specifically the cuprous salts of organo-thiophosphorio acids, have the property ofinhibiting the oxidation of hydrocarbons to a marked degree.
  • the class of compounds comprising the antioxidant additives of the present invention are more accurately defined as the compounds having the general formula where R and R. are hydrocarbon radicals, more free from copper staining characteristics.
  • aliphatic specifically alkyl, alkenyl, cycloaliphatic, alkaryl, or aralkyl radicals, and in general any radicals, whether aliphatic or aromatic, which contain a total of at least 10 carbon atoms in the combined aliphatic groups, whether or not attached to aromatic nuclei.
  • aliphatic is intended to include, both open chain and closed chain groups, saturated or unsaturated, straight chain or branched.
  • the invention also includes compounds of the above type which contain substituted halogen atoms or nitro groups. Compounds of the aliphatic radical type, that is, those having no aromatic nuclei, are generally preferred.
  • cuprous salts of the class described above may be readily prepared by treating an organothiophosphoric acid with cuprous oxide, preferably in the presence of a small amount of a reducin agent, such as sodium hydrosulfite, which appears to give a product of lighter color and
  • a reducin agent such as sodium hydrosulfite
  • the organo-thiophosphoric acid may be prepared by known means, such as by reacting a suitable alcohol with phosphorus pentasulfide;
  • mercaptans or thiophenols may be employed in the original preparation of the thiophosphoric acid. Acids pre pared by the reaction of phosphorus pentasulfide with mercaptans or thiophenols will have sulfur atoms linking the phosphorus atomswith the organic groups.
  • alcohols falling within the general class described may be employed, such as the normal straight-chain alcohols, alcohols derived from natural waxes, alcohols pro prised by the oxidation of petroleum hydrocarbon products, laur yl alcohol, stearyl alcohol, oleyl alcohol, naturally occurring alcohols such as those found in wool fat, sperm oil, and the like.
  • mixtures of alcohols may be employed as Well as single alcohols.
  • a mixture of isop'r'opanol and Z-ethylheXanol is particularly satisfactory.
  • alkylated phenols are amyl phenols, octyl phenols, waxalkylated phenols, petroleum phenols, and like products, including mixtures of phenols.
  • the amount of the additives will range from about 0.02% to about 3%, and the particular amount in individual cases will be selected in accordance with the requirements of the case and in view of the properties of the base stock employed. Since c-uprous org'anothiophosphates prepared from C2 alcohols or higher are completely miscible with lubricating oil, it is convenient for commercial purposes to prepare concentrates containing from '25 to 75% by weight of the additive in mineral lubricating oil, and to transport and blend the additives in the form of such concentrates. Concentrates containing about 40% of the additive are very conveniently prepared.
  • Example 1 Pr'epa.mtio'n of cup'rou's z-ethylhexyl thiophosph-ate A mixture of 520.8 g. (4 mols) of Z-ethylhexanol and 222 g. (1 mol) of P285 was heated for 1 hours at 90 C. in a 3-necked, 2-l-iter flask equipped with a stirrer, reflux condenser and thermometer. The product was then filtered to remove a small amount of insoluble material.
  • the thiophosphoric acid was then added dropwise, with stirring, to a slurry of 143 g. (1 mol) of Cu2O and 17.4 g. of sodium hydrosulfite in 600 cc. of benzene over a period of 3%, hours (maximum temperature 40 C.). After stirring for an additional hour, the product was filtered. The clear dark brown filtrate was mixed with enough "of a light SAE 10 grade mineral oil to give as a final product a 40% concentrate. This solution was then placed on a steam bath with nitrogen blowing for 24 hours to remove the benzene and water. Upon analysis, this concentrate was found to contain 5.8% copper and 5.7% sulfur; theoretical values were 6.1% copper and 6.1% sulfur.
  • Emmple 2.-Preparation of cuprous nonyl thiophosphate This preparation was carried out in the same manner as that described in Example 1, using 576 g. of nonyl alcohol (a branched chain C9 alcohol prepared by reacting diisobutyl'ene, carbon monoxide and hydrogen and hydrogenating the product), 222 g. of P235, 143 g. of 01120, and 17.4 g. of sodium hydro'sulfite.
  • nonyl alcohol a branched chain C9 alcohol prepared by reacting diisobutyl'ene, carbon monoxide and hydrogen and hydrogenating the product
  • 222 g. of P235 a branched chain C9 alcohol prepared by reacting diisobutyl'ene, carbon monoxide and hydrogen and hydrogenating the product
  • 222 g. of P235 a branched chain C9 alcohol prepared by reacting diisobutyl'ene, carbon monoxide and hydrogen and hydrogenating the product
  • 222 g. of P235 a branche
  • the 40% oil concentrate was found to contain 6.3% copper and 7.0% sulfur; theoretical values were 6.3% copper and 6.4% sulfur.
  • Example 3- Prepcmt'iovz of cuprous bowl rhiophos hate A mixture of 520 g. (4 mols) of octyl alcohol (a branched chain Ga alcohol prepared by reacting a C1 olefin polymer, carbon monoxide and hydrogen and hydrogenating the product), and 222 g. (1 mol) of P285 was heated for 1 hours at C., in a -3-necked, -2-liter flask equipped with a stirrer, reflux condenser, and thermometer. The thiophosphoric acid was then poured into a 4- liter beaker containing 1126 g. of diluent oil (a light lubricating oil of approximately SAE 10 grade).
  • diluent oil a light lubricating oil of approximately SAE 10 grade
  • Example '4.P1epd'rdtiofi of cuprous methylcycZohEti Z thiophospha'te A 3-'necked, 1-'-'-litefr flask, equipped with a stirrer, reflu-x condenser and thermometer, was charged with 228 g. (2 mols) of inethylcyclohexa'nol 'and 111 g. mol) or'rzss. This mixture was heated with stirring at C., 'for 30 minutes, after which the resulting thiophosphoric acid was poured into a 3-li'ter beaker containing 514 g.
  • Example 5 Prep'aiation of cuproas isopropyl ethylheryl thiophosphate
  • the isoprcpyl-ethylhexyl thiophosphoric acid mixture was prepared as described in Example 1, using a mixture of 907g. (1.5 mol) of isopropanol and 130 g. (1 mol) of ethylhexanol.
  • the acid mixture was poured into 561 g. of a light lubri cating oil of approximately SAE grade, and after heating to 50 0., 88.7 g; of C1120 was added in small portions over a period of about 30 minutes.
  • Example 6 Preparatz'on of cuprous ClZ-Clfi alkyl-seconolary batyl thiopho'sphate This preparation was carried out in the same manner as that described in Example 5, using a Example 7.Preparation of calcium ethylhezcyl thiophosphate The ethylhexyl thiophosphoric acid was prepared as described in Example 1. The calcium salt was then prepared in the same manner as described in Example 5, using CaO as the neutralizing agent.
  • Example 8 Preparatzon of potassium ethylheryl thiophosphate This preparation was carried out in the same manner as that described in Example 7, using KOH as the neutralizing agent. Upon cooling this concentrate to room temperature, a considerable amount of the potassium salt precipitated out of solution.
  • Example 9 Preparation of sodiumpthylhexyl thiophosphate v This preparation was carried out in the same manner as that described in Example 7, using NaO-H as the neutralizing agent.
  • Example 10 Preparation of zinc ethylhea cyl thiophosphate This preparation was carried out in the same manner as that described in Example 7, using ZnO' as the neutralizing agent.
  • Example 11 Laboratory bearing corrosion tests Blends containing 0.25% each of various 011-, prous salts prepared as described in preceding examples in an extracted Mid-Continent lubrieating oil of parafiinic SAE 20 grade and a sample of the unblended base oil were submitted to a laboratory test 'designedto measure the;
  • Oil Blend Example 12.Lauson engine tests Blends containing 0.6% each of various products prepared as described in the foregoing examples in a solvent extracted Mid-Continent parafiinic lubricating oil of SAE 10 grade and a sample of the unblended base oil were employed as crankcase lubricants in tests with a Lauson engine operating at 300 F. jacket temperature, 295 F. oil temperature, 1800 R. P. M. speed, and 1.5 indicated kilowatt load, the tests being conducted for 20 hours each. The loss in weight of the copper-lead bearing and the varnish demerit were determined in each test.
  • the varnish demerit rating was based upon a method of rating in which a perfectly clean piston surface is given a rating of 0 and a demerit of 10 is given to the worst condition which could be expected to exist of that surface. The results of these observations are as follows:
  • the additives of the present invention are very effective in reducing bearing corrosion as well as being somewhat effective in also reducing varnish formation on the piston surface. It may also be observed that the cuprous salts are generally more effective than the alkali metal salts. Although the potassium ethylhexyl thiophosphate reduced the bearing corrosion to the same extent as the corresponding cuprous salt in the Lauson engine test, it will be observed that the potassium salt caused a greater amount of varnish formation than the unblended base oil, while the cuprous salt reduced the varnish formation.
  • the new additives of the present invention while effective in inhibiting bearing corrosion, do not always inhibit the tendency of the oil to deposit varnish on engine parts to the desired .extent, and it is accordingly advantageous to employ in combination with these additives other additives which have a detergent action.
  • these additives include metal phenates, sulfurized metal phenates, .sulfurized metal salts of phenol sulfides, reaction products .of metal phenates and metal salts of phenol sulfide with sulfides of phosphorus, metal carboxylates, metal sulfonates, and the like.
  • the following example illustrates the advantages realized in employing a combination .of additives.
  • Example '14.Chem'oZet engine tests of additive combinations in lubricating oil Blends were prepared containing cu-prous ethylhexyl thiophosphate (prepared as in Example 1) alone and in combination with certain detergent additives as shown in the table below. Tests were also made of the base oil, which was a solvent extracted Mid-Continent paraflinic SAE 10 oil which was of a different lot and higher sulfur content from the oil employed in the tests of Example 13. Tests were also made with a blend of this oil with a typical detergent additive alone. The tests were conducted in the manner described in Example 13, while the varnish demerit ratings were made according to the system described in Example 12. The results of these tests are as follows:
  • the products of the present invention may be employed not only in ordinary hydrocarbon lubricating oils but also in the heavy duty type r of lubricating oils which have been compounded with such detergent type additives as metal soaps, metal petroleum sulfonates, metal phenates, metal alcoholates, metal alkyl phenol sulfides, metal organo phosphates, thiophosphates, phosphites and thiophosphites, metal salicylates, metal xanthates and thioxanthates, metal thiocarbamates, amines and amine derivatives, reaction products of metal phenates and sulfur, reaction products.
  • detergent type additives as metal soaps, metal petroleum sulfonates, metal phenates, metal alcoholates, metal alkyl phenol sulfides, metal organo phosphates, thiophosphates, phosphites and thiophosphites, metal salicylates, metal xanthates and thioxanthat
  • additives of the present invention may be used in lubricating oils containing such other addition agents as barium tert.octy1phenol sulfide, calcium tert.-amylphenol sulfide, nickel oleate, barium octadecylate, calcium phenyl stearate, zinc .diisopropyl salicylate, aluminum naphthenate, calcium cetyl phosphate, barium di-tert.-amylphenol sulfide, calcium petroleum sulfonate, zinc methyl cyclohexyl thiophosphate, calcium dichlorostearate, etc.
  • Other types of additives, such as phenols and phenol sulfides may be employed.
  • the lubricating oil base stocks used in the compositions of this invention may be straight mineral lubricating oils or distillates derived from parafiinic, naphthenic, asphaltic, or mixed base crudes, or, if desired, various blended oils may be employed as well as residuals, particularly those from which asphaltic constituents have been carefully removed.
  • the oils may be refined by conventional methods using acid, alkali and/or clay or other agents such as aluminum chloride, or they vmay be extracted oils produced, for example, by solvent extraction with solvents of the type of phenol, sulfur dioxide, furfural, dichlorodiethyl ether, nitrobenzene, crotonaldehyde, etc.
  • Hydrogenated oils or white oils may be employed as well as synthetic oils prepared, for example, by the polymerization of olefins or by the reaction of oxides of carbon with hydrogen or by the hydrogenation of coal or its products.
  • cracking coil tar fractions and coal tar or shale oil distillates may also be used.
  • animal, vegetable or fish oils or their hydrogenated or yoltolized products may be employed in admixture with mineral oils.
  • the base stock chosen should normally be that oil which without the new additive present gives the optimum performance in the service contemplated.
  • the oil must possess the viscosity and volatility characteristics known to be required for the service contemplated.
  • the oil must be a satisfactory solvent for the additive, although in some cases auxiliary solvent agents may be used.
  • the lubricating oils may vary considerably in viscosity and other properties depending upon the particular use for which they are desired, but they usually range from about 40 to 150 seconds Saybolt viscosity at 210 F.
  • oils of higher viscosity index are often preferred, for example, up to 75 to 100, or even higher, viscosity index.
  • agents may also be used such as dyes, pour depressors, heat thickened fatty oils, sulfurized fatty oils, organometallic compounds, metallic or other soaps, sludge dispersers, antioxidants, thickeners, viscosity index improvers, oiliness agent, resins, rubber olefinpolymers, voltolized fats, voltolized mineral oils, and/or voltolized waxes and colloidal solids such as graphite or zinc oxide, etc.
  • Solvents and assisting agents such as esters, ketones, alcohols, aldehydes, halogenated or nitrated compounds, and the like may also be employed.
  • Assisting agents which are particularly desirable as plasticizers and defoamers are the higher alcohols having eight or more carbon atoms and preferably 12 to 20 carbon atoms.
  • the alcohols may be saturated straight and branched chain aliphatic alcohols such as octyl alcohol (CsHrzOH) lauryl alcohol (C12H25OH), cetyl alcohol (CmHasOI-I) stearyl alcohol, sometimes referred to as octadecyl alcohol, (UmHsvOI-I), heptadecyl alcohol (C17H35OH), and the like; the corresponding olefinic alcohols such as oleyl alcohol; cyclic alcohols such as naphthenic alcohols; and aryl substituted alkyl alcohols, for instance, phenyl octyl alcohol, or octadecyl benzyl alcohol; or mixtures of these various alcohols, which may be pure or substantially pure synthetic alcohols.
  • Products prepared synthetically by chemical processes may also be used, such as alcohols prepared by the oxidation of petroleum hydrocarbons, e. g. paraffin wax, petrolatum, etc.
  • the additives of the present invention may also be used in extreme pressure lubricants, engine flushing oils, industrial oils, general machinery oils, process oils, rust preventive compositions and greases.
  • the additive of the present invention may be employed as antioxidant or stabilizing agents not only in mineral lubricating oils, but also in petroleum hydrocarbon products generally, where improved resistance to oxidation is desired.
  • the products may be added to motor oils, Diesel fuels, kerosene, waxes, hydrocarbon polymers, natural and synthetic rubbers, and the like.
  • a composition consisting essentially of a hydrocarbon oil containing 0.02 to 3% of a compound of the approximate formula the reaction product of the barium salt of tert.- octyl phenol sulfide and phosphorus pentasulfide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
US788670A 1947-11-28 1947-11-28 Oxidation resisting hydrocarbon products Expired - Lifetime US2552570A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
NL72745D NL72745C (de) 1947-11-28
US788670A US2552570A (en) 1947-11-28 1947-11-28 Oxidation resisting hydrocarbon products
GB22971/48A GB670077A (en) 1947-11-28 1948-08-31 Improved oxidation resisting compositions comprising mineral lubricating oils, and hydrocarbon polymers, synthetic rubbers and waxes
FR971155D FR971155A (fr) 1947-11-28 1948-09-08 Hydrocarbures résistant à l'oxydation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US788670A US2552570A (en) 1947-11-28 1947-11-28 Oxidation resisting hydrocarbon products

Publications (1)

Publication Number Publication Date
US2552570A true US2552570A (en) 1951-05-15

Family

ID=25145198

Family Applications (1)

Application Number Title Priority Date Filing Date
US788670A Expired - Lifetime US2552570A (en) 1947-11-28 1947-11-28 Oxidation resisting hydrocarbon products

Country Status (4)

Country Link
US (1) US2552570A (de)
FR (1) FR971155A (de)
GB (1) GB670077A (de)
NL (1) NL72745C (de)

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2618597A (en) * 1951-02-27 1952-11-18 Standard Oil Dev Co Oxidation resisting hydrocarbon products
US2678262A (en) * 1950-03-28 1954-05-11 Gulf Research Development Co Stable fuel oil compositions
US2739122A (en) * 1953-07-29 1956-03-20 American Cyanamid Co Antioxidant compositions
US2739123A (en) * 1953-07-29 1956-03-20 American Cyanamid Co Antioxidant compositions
US2783160A (en) * 1953-03-30 1957-02-26 Jolly J Taylor Film forming oil stabilized with dibasic lead phosphite
US2784169A (en) * 1954-06-14 1957-03-05 Monsanto Chemicals Acrylonitrile polymers stabilized with salts of vinyl phosphonates
US2786044A (en) * 1953-04-14 1957-03-19 Gen Tire & Rubber Co Hydrazone stabilized plastic film
US2798880A (en) * 1953-12-29 1957-07-09 Fmc Corp Metallo-organic phosphorus compounds
US2813076A (en) * 1953-08-11 1957-11-12 Int Nickel Co Hydrocarbon oils having improved oxidation resistance
US2884405A (en) * 1957-06-17 1959-04-28 Monsanto Chemicals Nickel salts of dialkyl dithiophosphoric acid and butadiene-styrene
US2895973A (en) * 1955-02-09 1959-07-21 Exxon Research Engineering Co Metal salts of dithiophosphoric acids
US2987410A (en) * 1958-03-13 1961-06-06 Lubrizol Corp Asphaltic compositions
US3041311A (en) * 1958-12-03 1962-06-26 Union Carbide Corp Polypropylene stabilized with a dithiophosphate metal salt
US3060080A (en) * 1957-06-24 1962-10-23 Bayer Ag Method of combatting insects employing thiopyrophosphoric acid esters
US3065065A (en) * 1960-03-29 1962-11-20 Shell Oil Co Gasoline composition
US3066478A (en) * 1951-11-30 1962-12-04 Standard Oil Co Organic trithiophosphites as rocket propellants
US3070619A (en) * 1953-10-19 1962-12-25 Union Carbide Corp Production of 2-mercapto-2-thiono-derivatives of heterocyclic phosphoruscontaining compounds
US3089850A (en) * 1957-05-08 1963-05-14 Eastman Kodak Co Phosphorothiolothionates derived from glycols
US3135694A (en) * 1953-08-07 1964-06-02 American Cyanamid Co Alkoxymethyl esters of 2-mercapto 2-thiono 1, 3, 2-dioxaphosphorinane acids
US3210275A (en) * 1963-04-01 1965-10-05 Continental Oil Co Lubricating composition containing metal salts of hindered phosphorodithioates
US3218275A (en) * 1961-04-17 1965-11-16 Sun Oil Co Polypropylene stabilized with nickel stearate and dithiocarbamates
US3360463A (en) * 1965-04-15 1967-12-26 Albright & Wilson Mfg Ltd Lubricants containing synergistic wear inhibitors
US3428662A (en) * 1965-07-16 1969-02-18 Texaco Inc Method of preparing metal dihydrocarbyl dithiophosphates
EP0024146A1 (de) * 1979-08-13 1981-02-25 Exxon Research And Engineering Company Schmiermittelzusammensetzungen
US4582920A (en) * 1984-08-21 1986-04-15 Mobil Oil Corporation Method of making a copper O,O-dihydrocarbyl phosphorodithioate
US4664822A (en) * 1985-12-02 1987-05-12 Amoco Corporation Metal-containing lubricant compositions
US4767551A (en) * 1985-12-02 1988-08-30 Amoco Corporation Metal-containing lubricant compositions
US5013465A (en) * 1987-12-23 1991-05-07 Exxon Chemical Patents, Inc. Dithiophosphates
US5013467A (en) * 1987-09-16 1991-05-07 Exxon Chemical Patents Inc. Novel oleaginous composition additives for improved rust inhibition
US5015402A (en) * 1986-11-07 1991-05-14 The Lubrizol Corporation Basic metal dihydrocarbylphosphorodithioates
EP0475141A1 (de) * 1990-08-28 1992-03-18 Idemitsu Kosan Company Limited Zusatz für Schmieröl und diesen Zusatz enthaltende Schmierölzusammensetzung
EP0480875A1 (de) * 1990-10-08 1992-04-15 Ciba-Geigy Ag Schmierstoffzusammensetzung
US5171461A (en) * 1987-04-13 1992-12-15 The Lubrizol Corporation Sulfur and copper-containing lubricant compositions
US5178782A (en) * 1985-03-12 1993-01-12 The Lubrizol Corporation Metal salts of mixed aromatic/aliphatic phosphorodithioic acids
US5520830A (en) * 1991-10-11 1996-05-28 Akzo Nobel N.V. Composition and process for retarding lubricant oxidation using copper additive
US5739089A (en) * 1987-11-24 1998-04-14 Exxon Chemical Patents Inc. Dihydrocarbyl dithiophosphates

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL93069C (de) * 1951-07-27
GB708017A (en) * 1951-08-23 1954-04-28 Standard Oil Dev Co Lubricating oil composition
GB801151A (en) * 1955-01-27 1958-09-10 Lubrizol Corp Gear lubricant improving agents

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2261047A (en) * 1941-07-28 1941-10-28 Lubri Zol Corp Lubricant
US2364283A (en) * 1941-10-21 1944-12-05 Union Oil Co Modified lubricating oil
US2364154A (en) * 1942-10-22 1944-12-05 Wilson Cabinet Company Milk cooler
US2378820A (en) * 1942-02-14 1945-06-19 Union Oil Co Lubricating oil
US2389527A (en) * 1942-06-30 1945-11-20 Texas Co Lubricants
US2420893A (en) * 1944-01-04 1947-05-20 Standard Oil Dev Co Compounded lubricating oil

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2261047A (en) * 1941-07-28 1941-10-28 Lubri Zol Corp Lubricant
US2364283A (en) * 1941-10-21 1944-12-05 Union Oil Co Modified lubricating oil
US2378820A (en) * 1942-02-14 1945-06-19 Union Oil Co Lubricating oil
US2389527A (en) * 1942-06-30 1945-11-20 Texas Co Lubricants
US2364154A (en) * 1942-10-22 1944-12-05 Wilson Cabinet Company Milk cooler
US2420893A (en) * 1944-01-04 1947-05-20 Standard Oil Dev Co Compounded lubricating oil

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2678262A (en) * 1950-03-28 1954-05-11 Gulf Research Development Co Stable fuel oil compositions
US2618597A (en) * 1951-02-27 1952-11-18 Standard Oil Dev Co Oxidation resisting hydrocarbon products
US3066478A (en) * 1951-11-30 1962-12-04 Standard Oil Co Organic trithiophosphites as rocket propellants
US2783160A (en) * 1953-03-30 1957-02-26 Jolly J Taylor Film forming oil stabilized with dibasic lead phosphite
US2786044A (en) * 1953-04-14 1957-03-19 Gen Tire & Rubber Co Hydrazone stabilized plastic film
US2739123A (en) * 1953-07-29 1956-03-20 American Cyanamid Co Antioxidant compositions
US2739122A (en) * 1953-07-29 1956-03-20 American Cyanamid Co Antioxidant compositions
US3135694A (en) * 1953-08-07 1964-06-02 American Cyanamid Co Alkoxymethyl esters of 2-mercapto 2-thiono 1, 3, 2-dioxaphosphorinane acids
US2813076A (en) * 1953-08-11 1957-11-12 Int Nickel Co Hydrocarbon oils having improved oxidation resistance
US3070619A (en) * 1953-10-19 1962-12-25 Union Carbide Corp Production of 2-mercapto-2-thiono-derivatives of heterocyclic phosphoruscontaining compounds
US2798880A (en) * 1953-12-29 1957-07-09 Fmc Corp Metallo-organic phosphorus compounds
US2784169A (en) * 1954-06-14 1957-03-05 Monsanto Chemicals Acrylonitrile polymers stabilized with salts of vinyl phosphonates
US2895973A (en) * 1955-02-09 1959-07-21 Exxon Research Engineering Co Metal salts of dithiophosphoric acids
US3089850A (en) * 1957-05-08 1963-05-14 Eastman Kodak Co Phosphorothiolothionates derived from glycols
US2884405A (en) * 1957-06-17 1959-04-28 Monsanto Chemicals Nickel salts of dialkyl dithiophosphoric acid and butadiene-styrene
US3060080A (en) * 1957-06-24 1962-10-23 Bayer Ag Method of combatting insects employing thiopyrophosphoric acid esters
US2987410A (en) * 1958-03-13 1961-06-06 Lubrizol Corp Asphaltic compositions
US3041311A (en) * 1958-12-03 1962-06-26 Union Carbide Corp Polypropylene stabilized with a dithiophosphate metal salt
US3065065A (en) * 1960-03-29 1962-11-20 Shell Oil Co Gasoline composition
US3218275A (en) * 1961-04-17 1965-11-16 Sun Oil Co Polypropylene stabilized with nickel stearate and dithiocarbamates
US3210275A (en) * 1963-04-01 1965-10-05 Continental Oil Co Lubricating composition containing metal salts of hindered phosphorodithioates
US3360463A (en) * 1965-04-15 1967-12-26 Albright & Wilson Mfg Ltd Lubricants containing synergistic wear inhibitors
US3428662A (en) * 1965-07-16 1969-02-18 Texaco Inc Method of preparing metal dihydrocarbyl dithiophosphates
US4867890A (en) * 1979-08-13 1989-09-19 Terence Colclough Lubricating oil compositions containing ashless dispersant, zinc dihydrocarbyldithiophosphate, metal detergent and a copper compound
EP0024146A1 (de) * 1979-08-13 1981-02-25 Exxon Research And Engineering Company Schmiermittelzusammensetzungen
US4582920A (en) * 1984-08-21 1986-04-15 Mobil Oil Corporation Method of making a copper O,O-dihydrocarbyl phosphorodithioate
US5178782A (en) * 1985-03-12 1993-01-12 The Lubrizol Corporation Metal salts of mixed aromatic/aliphatic phosphorodithioic acids
US4664822A (en) * 1985-12-02 1987-05-12 Amoco Corporation Metal-containing lubricant compositions
US4767551A (en) * 1985-12-02 1988-08-30 Amoco Corporation Metal-containing lubricant compositions
US5015402A (en) * 1986-11-07 1991-05-14 The Lubrizol Corporation Basic metal dihydrocarbylphosphorodithioates
US5171461A (en) * 1987-04-13 1992-12-15 The Lubrizol Corporation Sulfur and copper-containing lubricant compositions
US5013467A (en) * 1987-09-16 1991-05-07 Exxon Chemical Patents Inc. Novel oleaginous composition additives for improved rust inhibition
US5739089A (en) * 1987-11-24 1998-04-14 Exxon Chemical Patents Inc. Dihydrocarbyl dithiophosphates
US5013465A (en) * 1987-12-23 1991-05-07 Exxon Chemical Patents, Inc. Dithiophosphates
EP0475141A1 (de) * 1990-08-28 1992-03-18 Idemitsu Kosan Company Limited Zusatz für Schmieröl und diesen Zusatz enthaltende Schmierölzusammensetzung
EP0480875A1 (de) * 1990-10-08 1992-04-15 Ciba-Geigy Ag Schmierstoffzusammensetzung
US5520830A (en) * 1991-10-11 1996-05-28 Akzo Nobel N.V. Composition and process for retarding lubricant oxidation using copper additive

Also Published As

Publication number Publication date
GB670077A (en) 1952-04-16
NL72745C (de)
FR971155A (fr) 1951-01-15

Similar Documents

Publication Publication Date Title
US2552570A (en) Oxidation resisting hydrocarbon products
US2526497A (en) Mineral lubricating oil containing polysulfides of thiophosphorous and thiophosphoric acid esters
US2409687A (en) Sulfur and metal containing compound
US2591577A (en) Lubricating oil containing disulfide derivatives of organo-substituted thiophosphoric acids
US2471115A (en) Lubricating oil
US2443264A (en) Compounded lubricating oil
US2418894A (en) Compounded lubricating oil
US2645657A (en) Thiophosphate esters
US2526506A (en) Hydrocarbon lubricant containing sulfurized aliphatic borates as stabilizers
US2406564A (en) Compounded lubricating oil
US2451346A (en) Compounded lubricating oil
US2783204A (en) Corrosion preventing agent
US2758971A (en) Blending agents for mineral oils
US2743235A (en) Mineral oil composition
US2689258A (en) Reaction of terpenes with thiophosphorous acid esters and products thereof
US2783202A (en) Corrosion preventing agent
US2420893A (en) Compounded lubricating oil
US2506310A (en) Lubricating oil composition
US2623855A (en) Lubricating compositions
US2483505A (en) Compounded lubricating oil
US2599341A (en) New phosphorus containing compounds
US2545158A (en) Oxidation resisting hydrocarbon products
US2599350A (en) Oxidation inhibitor
US2844616A (en) Process for reacting di-organo substituted dithiophosphoric acid compounds and epoxides
US2783203A (en) Corrosion preventing agent