US2529873A - Manufacture of carbon black - Google Patents
Manufacture of carbon black Download PDFInfo
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- US2529873A US2529873A US2399A US239948A US2529873A US 2529873 A US2529873 A US 2529873A US 2399 A US2399 A US 2399A US 239948 A US239948 A US 239948A US 2529873 A US2529873 A US 2529873A
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- burner
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/50—Furnace black ; Preparation thereof
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- This invention relates to an improved blast burner of especial utility where very high rates of combustion are required as, for example, in the manufacture of carbon black by a process employing a highly turbulent, high velocity blast ame such, for instance, as described in patent No. 2,378,055, grantedJune 12, 1945, on an application of Wiegand and Braendle.
- a vi'- olently turbulent stream of blast ilame gases is projected at highA velocity into one end of an elongated, unobstructed chamber anda stream; or streams, of hydrocarbon gas to be decomposed to form the carbon black separatelyy and force'- fully injected into the hot, highly'turbulent blast flame gases.
- the blast name is; with advantage, produced by blasting a combustible mixture of fuel gas and air through a plurality of ports, advantageously of substantially uniform transverse section over a major portionof'their depth, extending through aburner blockof substantial depth,csay 9 to; 12 inches thick, positioned inzthe upstream end of the chamberVand burning-the mixture as it enters the chamber.
- a particularly advantageous method of'mixing andinjecting the combustible mixture'into the chamber is to force air under pressure through the burner ports from a so-called wind-box enclosing-,the upstream end of the burner ports and separately j ettingy a stream of fuel gas into each of the air.- streams ,i
- YMy present invention provides ⁇ improved apparatus for carrying out, and an .improved method of starting-up, an operation such as there devthe'streams ofcombustion air. as the latter pass i through the-early or mid portion of the burner port.
- a largel number'of burner'ports leading into the reaction chamber from a common winds-box is usually employed, each equipped with a fuel'gas jet, or socalled spud, connected in: groups to; a. common fuel gas'manifoldzor header; Most eiective operation is'usually'attained.where these spuds are positioned; duringi normalL operaticnn,u not more than about one-quarter of the way through the burner ports, generally somewhat further upstream, and coaxially positioned with respect to the burner-ports.
- My present invention provides a' methodr and means for lighting and starting-up a cold: furnace, whereby diculty-in operations'of thetype described is avoided; I have discovered thatA if in starting a cold furnace, the fuel-gas be injected intol the'air streamsat a point nearA the downstream end of-the burner block ports,.this diiculty is entirely avoided. Under such ⁇ conditions, the flame front' has been' found'to be a substantial distancedownstream from the burner blockl face,v as in starting the furnace with: the spudsv in the normal operating position, neverthelless, the previously described explosionsl are avoided',
- the fueligas injection spuds are moved forward from their normal operating position to a position at least half-way through the por-ts and usually toa point at approximately the outlet end of the ports and kept in that position until the. face of the burner block has been heated to above the ignition temperature of the combustible mixture; Thereafter, thaspuds'are 3 retracted, advantageously gradually, back through the burner block ports, with a resultant drawing of the flame back against the face of the burner block.
- My invention provides the safety and convenience of Ian inspirator type burner with the eciency of a premixed air and gas burner and provides an improved blast burner adapted to efficient operation over wide ranges of load and ratios of air to gas not heretofore attainable.
- the invention provides an improved burner head adapted to the carrying out of the starting-up operation as well as the normal operation of the furnace.
- the spuds are of substantially smaller diameter than the smallest diameter of the burner block ports and are connected to a fuel gas manifold by tubes, or similar rigid conduits, of a length substantially greater than the depth of the burner block, so as to permit their forward movement through the burner block ports to va position near the outlet end thereof without undue interference by the fuel gas manifold with the iiow of air into the ports from the wind-box.
- the spuds and connecting lines are, with advantage, rigidly supported solely by the fuel gas manifold, though additional supports may be supplied, providing they do not interfere with the free ow of air to the ports.
- the fuel gas manifold is, with advantage, positioned Within the wind-box and is so constructed and arranged as to be movable back and forthY through the wind-box soas to adjust the positions of the spuds.
- the burner block ports should not exceed 2 inches in diameter rand are with advantage Within the range of 1 to 1% inches i. d.
- the depth of the ports should be at least four times their diameter and, advantageously, five to twelve times their diameter.
- the discharge end of the ports may be ared somewhat to allow some decrease in velocity vat the point of combustion, but it is advantageous that atl least 50% of the area of the burner block face be a relatively plane'A surface.
- the ports should be at least 4 inches in depth.
- the spuds are, with advantage, of an over-all diameter not exceeding one-half that of the burner ports .with an inside diameter of about 1/8 to @se inch, and so designed as to project a gaseous cone of fuel gas of less than 30 included angle, advantageously, 19 to 20.
- Theblast burner of the present invention is not to be confused with burners of the inspirator type which involvey the jetting of a stream of fuel into and through an'air inlet, usually iiared or bell-shaped, which is open to the atmosphere at its upstream end and through which the fuel stream sucks in an amount of air Vrequired for combustion.
- the efliciency of inspiration and mixing is recognized to be a ⁇ function of the position of the fuel nozzle with respect to the air inlet.
- the present invention relates to improvements in burners of a distinctly different type in which ythe air forcombustion Yisfsupplied through a wind-box under super-atmospheric pressure Yindependently'of inspiration by the fuel stream.
- FIG. l represents, conventionally :and somewhat diagrammatically, a fragmentary vertical, longitudinal sectional view of a carbon black furnace of rectangular cross-section and having a blast burner head with 39 burner ports;
- Figure 2 is a somewhat enlarged vertical section of the blast burner head of Figure 1 along the line 2 2 of Figure 3;V
- Figure 3 is an enlarged end view of the burner head looking toward the furnace
- Figure 5 is aside view of the manifold of Figure 4.
- Figure 6 is a plan view of the manifold of Figure 4.
- Figure 7 is a fragmentary vertical sectional view along line 'I-I of Figure 8 of a modified form of a burner head including means for injecting the make gas into the furnace;
- Figure 8 is an end view of the burner block of Figure 7 from the furnace end.
- the part indicated by the reference numeral I is a horizontally elongated, rectangular furnace chamber, lined with firebrick 2. Surrounding the layer of rebrick are two outer layers of insulating material 3 and 4, respectively, all encased in a sheet metal shell 5. Positioned at the forward end of chamber I is the blast burner head 6, more clearly shown 'in Figure 2 of the drawings, the burner block I of the burner head being coextensive Vvv'iththe transverse area of the chamber and of such dimension as to slide into the forward end of the chamber I and is sealed therein by conventional means.
- a mixture of fuel gas and air is passed at high velocity into the upstream end of chamber I, as hereinafter more fully described, and is ignited and burned therein to form a violently turbulent blast llame.
- the hydrocarbon to be decomposed to form carbon black herein designated make gas, is passed from a suitable source and under super-atmospheric pressure, into manifold 8 which is connected with the interior of the chamber by a plurality of tubes 9 projecting inwardly through the furnace walls.
- the make gas is thus forcefully injected through tubes 9 into the violently turbulent stream of blast iiame ⁇ gases coursing through the chamber, is quickly and thoroughly mixed with the hot blast ame gases and is decomposed by heat containedtherein.
- Chamber I is of substantial length, sufficient to provide the-necessary decomposition time factor, say 5 to 10 feet, is free from'obstructions, and is of substantially uniform transverse dimensions S' black from the eilluent furnace gases.
- the chamber I is likewise lined with frebrick Ia and is encased by the sheet metal casing I2.
- the burner head 6, more clearly shown in Figure 2 of the drawings, is secured to the furnace structure by means of a front metal plate I3, which is, in turn, fastened to the metal casing 5 of the furnace-by flanges or angle irons indicated at I4.l
- the burner block 'I is of refractory material and extending therethrough is a plurality of substantially cylindrical burner ports I5, the respective ports being somewhat flared at their downstream end and so positioned and constructed as to leave a substantial burner kblock facevarea I6 between the ports.
- the respective burner ports are provided' with metal tubes I1, slightly flared at their inlet end and securely held in the burner ports by means of metal plate I8 to which they are fastened, as by welding.
- the tubes Il are also, with advantage, cemented into the burner ports so as to secure a tight fit. It will be understood that subsequent reference herein to the burner ports or burner block ports is intended to include the metal tubes I'I, as well as the ports I5 extending through the burner block proper.
- the burner ports open at their upstream end into the wind-box I9. Air for supporting combustionis forced under super-atmospheric pressure into the upstream end of the wind-box through air inlet 20, which is connected with a blower, or the like and metering system not shown, by means of flanges 2 I. Air is thus forced at high velocity through the respective burner ports.
- the wind-box is provided with a plurality of vanes 22 and adjustable dampers 23 for directing the air flow uniformly to higher and lower Zones within the windbox.
- Tubes 21 are of vsubstantially greater length than the depth of the yburner ports, so that the respective manifolds may be moved yforward to a position such that l the spuds are at, or near, the downstream end of the burner ports without substantial interference by the manifold with the flow of air into and through the burner ports.
- the manifolds 24 are adapted to roll freely backward and forward over the tracks 2'6, by fmeans of the carriages 25, equipped with flanged rollers 29, withouty departure from the horizontal or other twisting which might result in the throwing of the spuds out of alignment with the burner ports.
- Tubes 2l should'be sufhciently rigid to avoid sagging, or other dislocation with respect to the axis of the burner ports.
- Each of the manifolds is connected to a fuel gas supply line 3l, extending to the rear through the vanes and the rear wall of the wind-box through a packing gland 3l.
- the line isA calibrated just without the windboX so that in cooperation with the indicator linger 32 the position of the spuds with respect to the burner ports may be readily determined.
- the inlet end of tube 36 is connected to a source of fuel gas supply, under pressure,.through flexible .conduit-33 so as to permit the backward and forward movement of the tube 30.
- Each of the kmanifolds r24 is also provided with a rearwardly extending shaft 34 adapted to the adjusting of the position of the manifolds.
- the shafts 34 are threaded, as indicated at 35, adapted to engage the female threaded member 36 and to be turned by means of hand wheels 31.
- the inner end of the shaft 34 will be connected with a swivel 3B, which is, in turn, connected to a bracket 3S fastened to the manifold, as by welding.
- the dampers 23 are supported by shafts 4U adapted to be turned to adjust the position of the damper by hand wheels 4I, shown in Figure 3.
- Access to the interior of the wind-box is readily attained by removing the upstream end of the box which is removably attached to the remainder of the wind-box as by means of flanges 42.
- the entire wind-box is removably attached to ythe front plate of the furnace by means of flanges '43, which also support the plate I8.
- the make gas is injected into the'furnace through make gas injection tubes 44 extending through the burner block into the furnace chamber in a direction parallel to the burner ports.
- the make gas inlet tubes 44 are, with advantage, so positioned as to be flanked by the burner ports, as more clearly appears from Figure 8 of the drawings, so that the injected stream of make gas is surrounded by a substantially uniform pattern of blast flames.
- the tubes 44 should be of refractory material and are, with advantage, so fitted intoA the burner block as to permit them to be moved forward or backward to adjust their outlet end with respect to the burner block face.
- tubes 44v are connected by tubes 45 with the make gas manifold 46, also positioned within the wind-box and ⁇ connected by tube 41 with a source of make gas under pres'- sure.
- Tubes 44 and 45 are, with advantage, connected by a sliding fit to permit the adjustment of the former.
- burner ports need not be flared at their ends, as shown.
- vIt is, however, important that they be of substantial depth and advantageous that they be of substantially Vuniform cross-section over the major portion of their length.
- a further highly desirable feature of my burner head is that the ports be so arranged as to leave a substantial area of relatively flat surface-'on the downstream face of the burlner block,l usually not less than about as previously noted.
- the burnerrof my invention is designed especially for extremely high burner port lvelocities andlfI have found that a much steadienmor'e uniform the manifolds 24.
- the fuel gas manifolds are advanced to a point such that the spuds 28 are positioned at, or near, the, burner port exits, at least past the mid point of the ports. This is accomplished by turning the hand wheels 3l and the position of the spuds is indicated by the graduated scale on pipe 30. Air is forced, under pressure, into the wind-box through inlet 20 and fuel gas is passed, under pressure through pipe 3U into The combustion mixture entering the furnace chamber through the burner ports is ignited by usual means, not shown, afnd is burned with the spuds in the advanced position until the walls of the furnace and the face of the burner block have been highly heated.
- make gas is injected-into the chamber through the make gas injection tubes 9 of Figure 1, or tubes 44 of Figure 7 of the drawings, becomes rapidly mixed with the hot, highly turbulent blast lexcessively critical but should be adjusted to obtain the most efficient premixing of the air and fuel gas passing through the burner ports.
- the ratio of fuel gas velocity to the burner port throat velocity of the air is, with advantage, about 6:1, the air velocity advantageously being about 80 to 100 feet per second.
- the respective burner ports should not exceed Vabout 1 to 1% inches in diameter and' should be so distributed vover the face of the burner block as to leave a substantial area of plane surface 'of burner block face between and around the exit 'of the burner ports, advantageously 50% or more of the entire area of the face of the block.
- This plane surface is, with advantage, of a somewhat rough, vporous character. It has been found that the conditions just described materially assist in retaining the flame front against the face of the 'burner block when operating at full load.
- My invention also provides means for adjustying the position of the spuds during normal opferation.
- the spuds will be positioned at, or near, the entrance of the burner port, not more than about halfway -through the burner port.
- the spuds will rarely, if ever, be left at a position downstream from the mid point of the burner ports.
- the invention has been particularly described .with reference to a burner head adapted for use with a furnace of rectangular cross-section.
- Ay blast burner comprising a burner block of substantial thickness, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the vpassing of air under pressure to the windbox, a plurality of substantially parallel burner ports extending through said block, the outer ends of the respective ports opening into the wind-box, a fuel gas manifold within the windbox, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with the respective burner ports, said fuel gas manifold being so constructed and arranged within the wind-box as to be adapted to be moved therein toward and away from the burner block without altering the alignment of the spuds with the axis of the respective burner ports, and a connection for supplying fuel gas under pressure to the manifold.
- a blast burner comprising a burner block of substantial thickness, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the wind; box, a plurality of substantially parallel burner ports, not exceeding 2 inches in diameter and of a depth not less than 4 diameters, extending through said burner block, the outer ends of the respective ports opening into the wind-box, a fuel gas manifold within the Wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with respect to the burner ports, said fuel gas manifold being so.
- a blast burner comprising a burner block of substantial thickness, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not exceeding 2 inches in diameter and of a depth not less than 4 Y diameters, extending through said burner block, the outer ends of the ⁇ respective ports opening into the wind-box, a fuel gas manifold within the wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the Yburner ports, the spuds and connecting tubes being positioned coaxially with respect to the burner ports, air distributing means within'the wind-box adapted to distribute the air uniformly to the respective ports, said fuel gas manifold being so constructed and arranged within the wind-box as to be adapted to be moved therein toward and away from the burner block without alteringithe alignment of the spud
- a blast burner comprisingI a burner block of :substantial thicknessiawind-box adapted to conltain -air under super-atmospheric pressure secured -to the burner block, a connection adapted toithe passing .of air under pressure to the'windbox, apluralityof Vsubstantially parallel burner ports of af diameter of 1 to 1% inch and of a depth from f5 l.to 12 .times Ltheir diameter extending 'through said burner-block, the outer ends of the respective ports openingy into the wind-box, a fuel :gas manifold r.within the wind-box, a plurality of 'fuelgas spuds each connected with the mani- 'foldby a tube of alengthasubstantially greater 'than .the depth of the'burner ports, the spuds and connectingtubes'being positioned coaxially -.With ⁇ respect to-the'
- a blast burner comprising a burner block of substantial thickness,..a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted ⁇ tothe passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not 0ver.2 inches in diameter and of a depth not less than 4 diameters, extending through said block and uniformly spaced over the surface of said blockpthenumber and size :.ofsai'd burner ports .being such that not less than -:50% Aof the .area of the burner block face Lisfplane surfaceytheouter ends of therespective ports-.opening intothewind-box, a fuelgas manifold Within-the .wind-box, a plurality of vfuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds connecting tubes being positioned coaxially with the respective burner ⁇ ports, said fuel gas manifold
- a furnace for the production of carbon black which comprises an elongated, unobstructed and unrestricted heat insulated chamber, a burner block of substantial thickness coextensive with the transverse area of the chamber and positioned in one end thereof, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not over 2 inches in diameter and of a depth not less than 4 diameters, extending through said block and uniformly spaced over the surface of said block, the number and size of said burner ⁇ ports being such that not less than 50% of the area of the burner block face is plane surface, the outer ends of the respective ports opening into the wind-box, a fuel gas manifold within the wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with
- said'fuelgas manifold being so constructed and .arranged-:within the wind-box as to be adapted to be movedrtherein toward and away from the burner block without altering the alignment of the spuds .with the axis of the respective burner ports, and-a connection adapted to the injection plurality of elongated substantially parallel 'burner Vports extending through a burner vblock of substantial thickness into the combustion zone of aifurnace and fuel gas is jetted into each air ⁇ stream as it passes through the respective ports from a Spud coaxially .positioned with respect to the burner port, the; method'.
- a furnace for the production of carbon black which comprises an elongated, unobstructed l l and unrestricted heat insulated chamber, a burner block of substantial thickness coextensive with the transverse area of the chamber and positioned in one end thereof, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not over 2 inches in diameter and of a depth not less than 4 diameters, extending through said block and uniformly spaced over the surface of said block, the number and size of said burner ports being such that not less than 50% of the area of the burner block face is plane surface, the outer ends.
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Description
4 Sheets-Sheet 1 INVENTOR GEORGE L` HELLER ATTORNEYS G. L. HELLER MANUFACTURE 0F CARBON BLACK Nov. 14, 1950 Filed Jan. 15, 1948 G. L. HELLER MANUACTURE 0F CARBON BLACK 4 Sheets-Sheet 2 Filed Jan.
Nov. 14, 1950 Nav. 14, 1950 G. L. HELLER MANUFACTURE oF CARBON mx Filed Jem.v 15'. 1921s#` 4 Sheets-Sheet 5 INVENTOR GEORGE L. HELLER Nov. 14, 1950 G. L. HELLER MANUFACTURE oF CARBON BLACK Filed Jan.v 15, V1948 4 Sheets-Sheet 4 xvr @CCB INVENTOR GEORGE L. HEI-LER BY zmpulfdfmndnmoenamaw ATTORNEYS Patented Nov. 14, 1950 OFFICE lvIANUFACTURE OF CARBON BLACK George L. Heller, Monroe, La., assignor to Columbian Carbon Company Applicationanuary 15, 1948, Serial No. 2,399
(Cl. .Z3-209.8)
11 Claims.
This invention relates to an improved blast burner of especial utility where very high rates of combustion are required as, for example, in the manufacture of carbon black by a process employing a highly turbulent, high velocity blast ame such, for instance, as described in patent No. 2,378,055, grantedJune 12, 1945, on an application of Wiegand and Braendle.
In the process'described inv said'patent, a vi'- olently turbulent stream of blast ilame gases is projected at highA velocity into one end of an elongated, unobstructed chamber anda stream; or streams, of hydrocarbon gas to be decomposed to form the carbon black separatelyy and force'- fully injected into the hot, highly'turbulent blast flame gases. The blast name is; with advantage, produced by blasting a combustible mixture of fuel gas and air through a plurality of ports, advantageously of substantially uniform transverse section over a major portionof'their depth, extending through aburner blockof substantial depth,csay 9 to; 12 inches thick, positioned inzthe upstream end of the chamberVand burning-the mixture as it enters the chamber. A particularly advantageous method of'mixing andinjecting the combustible mixture'into the chamber is to force air under pressure through the burner ports from a so-called wind-box enclosing-,the upstream end of the burner ports and separately j ettingy a stream of fuel gas into each of the air.- streams ,i
as it enters the burner port, or in an early'stage of its passage through the port..
YMy present invention provides` improved apparatus for carrying out, and an .improved method of starting-up, an operation such as there devthe'streams ofcombustion air. as the latter pass i through the-early or mid portion of the burner port.
, In large commercial sized apparatus, a largel number'of burner'ports leading into the reaction chamber from a common winds-box is usually employed, each equipped with a fuel'gas jet, or socalled spud, connected in: groups to; a. common fuel gas'manifoldzor header; Most eiective operation is'usually'attained.where these spuds are positioned; duringi normalL operaticnn,u not more than about one-quarter of the way through the burner ports, generally somewhat further upstream, and coaxially positioned with respect to the burner-ports.
It has been recognized that some leeway is permissible with respect to the positioning' of the spud relative to the inlet to the burner port, but most advantageousv operation with respect to character and yield-of theproduct hasbeen attained withthe spuds in the position#- just described.
In operation, thev described processY has been found to proceed smoothly; with infrequent interruption, though'so'me minoradjustment of the position of. the spuds may from timeto' time be desirable.A However, in lighting and starting-up a' cold furnacaand before the burnerv block face and furnace walls havey become adequately heated,` considerable. difficultyl has been experience'd. Frequently,ya series of minor explosions will occur which rather violently shake thefurnace and tend toV weaken its structure. It' appears that,l under relatively cold furnace condi'- tions, the. highfvelocity off theentering combus+ tion mixture-caused the-combustion gas to travel a substantial ldistance:from the burner block` face beforeigniting. Within the chambertotherear of the flame lfront,.there is a relatively large-volurne of a combustible mixture of fuel gas` and air' whichappears per-iodicallyV tob ignite with violence.
My present invention provides a' methodr and means for lighting and starting-up a cold: furnace, whereby diculty-in operations'of thetype described is avoided; I have discovered thatA if in starting a cold furnace, the fuel-gas be injected intol the'air streamsat a point nearA the downstream end of-the burner block ports,.this diiculty is entirely avoided. Under such` conditions, the flame front' has been' found'to be a substantial distancedownstream from the burner blockl face,v as in starting the furnace with: the spudsv in the normal operating position, neverthelless, the previously described explosionsl are avoided',
Predicated upon iny'discoveryy in starting a cold furnace, in accordance with my. present invention, the fueligas injection spuds are moved forward from their normal operating position to a position at least half-way through the por-ts and usually toa point at approximately the outlet end of the ports and kept in that position until the. face of the burner block has been heated to above the ignition temperature of the combustible mixture; Thereafter, thaspuds'are 3 retracted, advantageously gradually, back through the burner block ports, with a resultant drawing of the flame back against the face of the burner block. After the spuds have thus been returned to their normal operating position, normal operation of the process is carried My invention provides the safety and convenience of Ian inspirator type burner with the eciency of a premixed air and gas burner and provides an improved blast burner adapted to efficient operation over wide ranges of load and ratios of air to gas not heretofore attainable.
In advancing the spuds to the starting position, in accordance with the present invention, undue interference with the flow of air through theV burner block ports must be avoided. The invention provides an improved burner head adapted to the carrying out of the starting-up operation as well as the normal operation of the furnace. In this Aimproved apparatus, the spuds are of substantially smaller diameter than the smallest diameter of the burner block ports and are connected to a fuel gas manifold by tubes, or similar rigid conduits, of a length substantially greater than the depth of the burner block, so as to permit their forward movement through the burner block ports to va position near the outlet end thereof without undue interference by the fuel gas manifold with the iiow of air into the ports from the wind-box. f
The spuds and connecting lines are, with advantage, rigidly supported solely by the fuel gas manifold, though additional supports may be supplied, providing they do not interfere with the free ow of air to the ports. The fuel gas manifold is, with advantage, positioned Within the wind-box and is so constructed and arranged as to be movable back and forthY through the wind-box soas to adjust the positions of the spuds.
The burner block ports should not exceed 2 inches in diameter rand are with advantage Within the range of 1 to 1% inches i. d. The depth of the ports should be at least four times their diameter and, advantageously, five to twelve times their diameter. The discharge end of the ports may be ared somewhat to allow some decrease in velocity vat the point of combustion, but it is advantageous that atl least 50% of the area of the burner block face be a relatively plane'A surface. The ports should be at least 4 inches in depth. f r The spuds are, with advantage, of an over-all diameter not exceeding one-half that of the burner ports .with an inside diameter of about 1/8 to @se inch, and so designed as to project a gaseous cone of fuel gas of less than 30 included angle, advantageously, 19 to 20.
Theblast burner of the present invention is not to be confused with burners of the inspirator type which involvey the jetting of a stream of fuel into and through an'air inlet, usually iiared or bell-shaped, which is open to the atmosphere at its upstream end and through which the fuel stream sucks in an amount of air Vrequired for combustion. In Ysuch burners, the efliciency of inspiration and mixing is recognized to be a `function of the position of the fuel nozzle with respect to the air inlet.
The present invention relates to improvements in burners of a distinctly different type in which ythe air forcombustion Yisfsupplied through a wind-box under super-atmospheric pressure Yindependently'of inspiration by the fuel stream.
The invention will be further described and illustrated by reference to the accompanying drawings which represent a particularly advantageous embodiment of the invention in apparatus comprising three separately adjustable banks of spuds. It will be understood, however, that the invention is not so restricted, but is applicable generally to high velocity blast burner heads employing a plurality of burner ports.
Referring to the drawings- Figure l represents, conventionally :and somewhat diagrammatically, a fragmentary vertical, longitudinal sectional view of a carbon black furnace of rectangular cross-section and having a blast burner head with 39 burner ports;
Figure 2 is a somewhat enlarged vertical section of the blast burner head of Figure 1 along the line 2 2 of Figure 3;V
Figure 3 is an enlarged end view of the burner head looking toward the furnace;
' kFigurell is an enlarged detailed end view of the fuel gas manifold;
Figure 5 is aside view of the manifold of Figure 4;
Figure 6 is a plan view of the manifold of Figure 4;
Figure 7 is a fragmentary vertical sectional view along line 'I-I of Figure 8 of a modified form of a burner head including means for injecting the make gas into the furnace; and
Figure 8 is an end view of the burner block of Figure 7 from the furnace end.
Referring more particularly to Figure l of the drawings, the part indicated by the reference numeral I is a horizontally elongated, rectangular furnace chamber, lined with firebrick 2. Surrounding the layer of rebrick are two outer layers of insulating material 3 and 4, respectively, all encased in a sheet metal shell 5. Positioned at the forward end of chamber I is the blast burner head 6, more clearly shown 'in Figure 2 of the drawings, the burner block I of the burner head being coextensive Vvv'iththe transverse area of the chamber and of such dimension as to slide into the forward end of the chamber I and is sealed therein by conventional means.
In operation, a mixture of fuel gas and air is passed at high velocity into the upstream end of chamber I, as hereinafter more fully described, and is ignited and burned therein to form a violently turbulent blast llame. The hydrocarbon to be decomposed to form carbon black, herein designated make gas, is passed from a suitable source and under super-atmospheric pressure, into manifold 8 which is connected with the interior of the chamber by a plurality of tubes 9 projecting inwardly through the furnace walls.
The make gas is thus forcefully injected through tubes 9 into the violently turbulent stream of blast iiame` gases coursing through the chamber, is quickly and thoroughly mixed with the hot blast ame gases and is decomposed by heat containedtherein.
Chamber I is of substantial length, sufficient to provide the-necessary decomposition time factor, say 5 to 10 feet, is free from'obstructions, and is of substantially uniform transverse dimensions S' black from the eilluent furnace gases. The chamber I is likewise lined with frebrick Ia and is encased by the sheet metal casing I2.
The burner head 6, more clearly shown in Figure 2 of the drawings, is secured to the furnace structure by means ofa front metal plate I3, which is, in turn, fastened to the metal casing 5 of the furnace-by flanges or angle irons indicated at I4.l
.The burner block 'I is of refractory material and extending therethrough is a plurality of substantially cylindrical burner ports I5, the respective ports being somewhat flared at their downstream end and so positioned and constructed as to leave a substantial burner kblock facevarea I6 between the ports. At their upstream end, the respective burner ports are provided' with metal tubes I1, slightly flared at their inlet end and securely held in the burner ports by means of metal plate I8 to which they are fastened, as by welding. The tubes Il are also, with advantage, cemented into the burner ports so as to secure a tight fit. It will be understood that subsequent reference herein to the burner ports or burner block ports is intended to include the metal tubes I'I, as well as the ports I5 extending through the burner block proper.
The burner ports, open at their upstream end into the wind-box I9. Air for supporting combustionis forced under super-atmospheric pressure into the upstream end of the wind-box through air inlet 20, which is connected with a blower, or the like and metering system not shown, by means of flanges 2 I. Air is thus forced at high velocity through the respective burner ports. In order to secure more uniform distribution of the combustion air, the wind-box is provided with a plurality of vanes 22 and adjustable dampers 23 for directing the air flow uniformly to higher and lower Zones within the windbox.
Also within the wind-box are three fuel gas manifolds 24, supported by carriages 25 and tracks 26. Extending downstream from the respective manifolds, coaxia'lly with the burner ports, is a.
plurality of tubes 21, each tipped at its downstream end by a jet or spud 28. Tubes 21 are of vsubstantially greater length than the depth of the yburner ports, so that the respective manifolds may be moved yforward to a position such that l the spuds are at, or near, the downstream end of the burner ports without substantial interference by the manifold with the flow of air into and through the burner ports.
The manifolds 24 are adapted to roll freely backward and forward over the tracks 2'6, by fmeans of the carriages 25, equipped with flanged rollers 29, withouty departure from the horizontal or other twisting which might result in the throwing of the spuds out of alignment with the burner ports. Tubes 2l should'be sufhciently rigid to avoid sagging, or other dislocation with respect to the axis of the burner ports. Y
Each of the manifolds is connected to a fuel gas supply line 3l, extending to the rear through the vanes and the rear wall of the wind-box through a packing gland 3l. Advantageously, the line isA calibrated just without the windboX so that in cooperation with the indicator linger 32 the position of the spuds with respect to the burner ports may be readily determined. The inlet end of tube 36 is connected to a source of fuel gas supply, under pressure,.through flexible .conduit-33 so as to permit the backward and forward movement of the tube 30.
Each of the kmanifolds r24 is also provided with a rearwardly extending shaft 34 adapted to the adjusting of the position of the manifolds. Advantageously, the shafts 34 are threaded, as indicated at 35, adapted to engage the female threaded member 36 and to be turned by means of hand wheels 31. With this arrangement, the inner end of the shaft 34 will be connected with a swivel 3B, which is, in turn, connected to a bracket 3S fastened to the manifold, as by welding.
The dampers 23 are supported by shafts 4U adapted to be turned to adjust the position of the damper by hand wheels 4I, shown in Figure 3.
Access to the interior of the wind-box is readily attained by removing the upstream end of the box which is removably attached to the remainder of the wind-box as by means of flanges 42. The entire wind-box is removably attached to ythe front plate of the furnace by means of flanges '43, which also support the plate I8.
Referring to the modification of vthe burner head shown in Figures 7 and 8, in this arrangement the make gas is injected into the'furnace through make gas injection tubes 44 extending through the burner block into the furnace chamber in a direction parallel to the burner ports. The make gas inlet tubes 44 are, with advantage, so positioned as to be flanked by the burner ports, as more clearly appears from Figure 8 of the drawings, so that the injected stream of make gas is surrounded by a substantially uniform pattern of blast flames. The tubes 44 should be of refractory material and are, with advantage, so fitted intoA the burner block as to permit them to be moved forward or backward to adjust their outlet end with respect to the burner block face. The upstream ends of the tubes 44v are connected by tubes 45 with the make gas manifold 46, also positioned within the wind-box and `connected by tube 41 with a source of make gas under pres'- sure. Tubes 44 and 45 are, with advantage, connected by a sliding fit to permit the adjustment of the former.
Other parts of the burner head',l represented by Figure '7, are substantially identical with those of Figure 2 and are indicated by like reference numerals. v
Instead of the vane and damper arrangements shown, other known means for uniformly distributing the air in the Wind-box may be employed, for instance, baflles or perforated plates. Though some arrangement of the sort is desirable, particularly in large apparatus having a number of burner ports, it may frequently be omitted, especially in smaller size apparatus. y
Likewise, other arrangements may be used for supporting the fuel gas manifolds. It is, however, advantageous, that they be rigidly though adjustably supported so as to ymaintainv the spuds in accurate alignment with the burner ports.
Also, the burner ports need not be flared at their ends, as shown. vIt is, however, important that they be of substantial depth and advantageous that they be of substantially Vuniform cross-section over the major portion of their length.
A further highly desirable feature of my burner head is that the ports be so arranged as to leave a substantial area of relatively flat surface-'on the downstream face of the burlner block,l usually not less than about as previously noted. The burnerrof my invention is designed especially for extremely high burner port lvelocities andlfI have found that a much steadienmor'e uniform the manifolds 24.
7 flame condition in normal operation is attained where extensive flat surface is provided at the burner block face between the exits of the burner ports.
In starting a cold furnace, in accordance with the present invention, the fuel gas manifolds are advanced to a point such that the spuds 28 are positioned at, or near, the, burner port exits, at least past the mid point of the ports. This is accomplished by turning the hand wheels 3l and the position of the spuds is indicated by the graduated scale on pipe 30. Air is forced, under pressure, into the wind-box through inlet 20 and fuel gas is passed, under pressure through pipe 3U into The combustion mixture entering the furnace chamber through the burner ports is ignited by usual means, not shown, afnd is burned with the spuds in the advanced position until the walls of the furnace and the face of the burner block have been highly heated.
After the furnace has been highly heated the manifolds and the spuds attached thereto are retracted, advantageously quite gradually, until the flames issuing from thev burner ports have been drawn back to the face of the burner block. Having established the desired blast flame condition, make gas is injected-into the chamber through the make gas injection tubes 9 of Figure 1, or tubes 44 of Figure 7 of the drawings, becomes rapidly mixed with the hot, highly turbulent blast lexcessively critical but should be adjusted to obtain the most efficient premixing of the air and fuel gas passing through the burner ports. The ratio of fuel gas velocity to the burner port throat velocity of the air is, with advantage, about 6:1, the air velocity advantageously being about 80 to 100 feet per second.
Where operation atsuch great loads is intended, the respective burner ports should not exceed Vabout 1 to 1% inches in diameter and' should be so distributed vover the face of the burner block as to leave a substantial area of plane surface 'of burner block face between and around the exit 'of the burner ports, advantageously 50% or more of the entire area of the face of the block. This plane surface is, with advantage, of a somewhat rough, vporous character. It has been found that the conditions just described materially assist in retaining the flame front against the face of the 'burner block when operating at full load.
My invention also provides means for adjustying the position of the spuds during normal opferation. Usually in normaloperation, the spuds will be positioned at, or near, the entrance of the burner port, not more than about halfway -through the burner port. Some latitude is permissible in this respect, as previously noted, but
in normal operation in the production of carbon black according to the process herein described, the spuds will rarely, if ever, be left at a position downstream from the mid point of the burner ports.
The invention has been particularly described .with reference to a burner head adapted for use with a furnace of rectangular cross-section.
v'It will be understood, however, that the invention .is readily adaptable to burner heads of circular cross-section and such burner heads are within the contemplation of my invention.
Further, though my improved burner has been described with particular reference to its use in the production of carbon black, it will be understood that its utility is not so restricted.
I claim:
1. Ay blast burner comprising a burner block of substantial thickness, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the vpassing of air under pressure to the windbox, a plurality of substantially parallel burner ports extending through said block, the outer ends of the respective ports opening into the wind-box, a fuel gas manifold within the windbox, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with the respective burner ports, said fuel gas manifold being so constructed and arranged within the wind-box as to be adapted to be moved therein toward and away from the burner block without altering the alignment of the spuds with the axis of the respective burner ports, and a connection for supplying fuel gas under pressure to the manifold.
2. A blast burner comprising a burner block of substantial thickness, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the wind; box, a plurality of substantially parallel burner ports, not exceeding 2 inches in diameter and of a depth not less than 4 diameters, extending through said burner block, the outer ends of the respective ports opening into the wind-box, a fuel gas manifold within the Wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with respect to the burner ports, said fuel gas manifold being so. constructed and arranged within the wind-box as to be adapted to be moved therein toward and away from the burner block without altering the alignment of the spuds with the axis of the respective burner ports, and a connection for supplying the fuel gas under pressure to the manifold. I
3. A blast burner comprising a burner block of substantial thickness, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not exceeding 2 inches in diameter and of a depth not less than 4 Y diameters, extending through said burner block, the outer ends of the `respective ports opening into the wind-box, a fuel gas manifold within the wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the Yburner ports, the spuds and connecting tubes being positioned coaxially with respect to the burner ports, air distributing means within'the wind-box adapted to distribute the air uniformly to the respective ports, said fuel gas manifold being so constructed and arranged within the wind-box as to be adapted to be moved therein toward and away from the burner block without alteringithe alignment of the spuds .with the axis of the respective burner ports, and a connection-:for :supplying thefuel gas. under pres- "sure'tozthemanifold 4. A blast burner comprisingI a burner block of :substantial thicknessiawind-box adapted to conltain -air under super-atmospheric pressure secured -to the burner block, a connection adapted toithe passing .of air under pressure to the'windbox, apluralityof Vsubstantially parallel burner ports of af diameter of 1 to 1% inch and of a depth from f5 l.to 12 .times Ltheir diameter extending 'through said burner-block, the outer ends of the respective ports openingy into the wind-box, a fuel :gas manifold r.within the wind-box, a plurality of 'fuelgas spuds each connected with the mani- 'foldby a tube of alengthasubstantially greater 'than .the depth of the'burner ports, the spuds and connectingtubes'being positioned coaxially -.With `respect to-the'burner ports, said'fuel gas .manifold being so constructed and arranged with- -zin the .wind-box as to `be adapted to be moved :therein: toward and away from theburner block withoutalteringthe alignment of the spuds with vthe yaxis ofthe respective burner ports, vand a .connection for supplyingv the fuel gas under pres'- lsure'to the manifold. Y v
5. A blast burner comprisinga burner block of substantial thickness,..a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted `tothe passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not 0ver.2 inches in diameter and of a depth not less than 4 diameters, extending through said block and uniformly spaced over the surface of said blockpthenumber and size :.ofsai'd burner ports .being such that not less than -:50% Aof the .area of the burner block face Lisfplane surfaceytheouter ends of therespective ports-.opening intothewind-box, a fuelgas manifold Within-the .wind-box, a plurality of vfuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds connecting tubes being positioned coaxially with the respective burner` ports, said fuel gas manifold being so constructed and arranged within the windbox as to be adapted to be moved therein toward and away from the burner block without altering the alignment of the spuds with the axis of the respective burner ports, and a connection for supplying fuel gas under pressure to the manifold,
6. A furnace for the production of carbon black which comprises an elongated, unobstructed and unrestricted heat insulated chamber, a burner block of substantial thickness coextensive with the transverse area of the chamber and positioned in one end thereof, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not over 2 inches in diameter and of a depth not less than 4 diameters, extending through said block and uniformly spaced over the surface of said block, the number and size of said burner` ports being such that not less than 50% of the area of the burner block face is plane surface, the outer ends of the respective ports opening into the wind-box, a fuel gas manifold within the wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with the Ai u lthe'mid point of thelburner ports.'
f8." 'In theoperation 'herein described wherein plurality 'of elongated respective fburner'ports, a .connection for sup.-
-plying 'fuel'gas under pressure to the manifold,
said'fuelgas manifold being so constructed and .arranged-:within the wind-box as to be adapted to be movedrtherein toward and away from the burner block without altering the alignment of the spuds .with the axis of the respective burner ports, and-a connection adapted to the injection plurality of elongated substantially parallel 'burner Vports extending through a burner vblock of substantial thickness into the combustion zone of aifurnace and fuel gas is jetted into each air `stream as it passes through the respective ports from a Spud coaxially .positioned with respect to the burner port, the; method'. of starting acold yfurnace which comprises advancing the spuds through the ports to a position beyond themid pointlthereof, burning the resultant streams` of combustible mixturev in the furnace until the walls ofthe furnace andthe face of the burnery lblockhave' been heated toy the ignition temperature of fthe combustible mixture and thereafter retr'acting the spuds to a positionlto the rear of air for-l'combustion fisforced under super-atmospheric `.pressure i-n:separate streams through a substantially 'parallel burner ports extending through aburner block 4of substantial thickness into the combustion zone oflal'furnacefand fuel gas 'is'jettedy into each air stream as it passes through the respective ports from.' Ya spud coaxially positioned with respect to -theburner port, the method ofstarting' a cold `,furnace which comprises advancing the Yspuds through lthe ports to apositionnear the lexit end thereof so that the fuel gas is jetted into the air streams as the latter pass from the ports, burning the resultant streams of combustible mixture in the furnace until the walls of the furnace and the face of the burner block have been heated to the ignition temperature of the combustible mixture, and thereafter retracting the spuds to a position near the inlet end of the burner ports.
9. In the operation herein described wherein air for combustion is forced under super-atmospheric pressure in separate streams through a plurality of elongated substantially parallel burner ports extending through a burner` block of substantial thickness into the combustion zone of a furnace and fuel gas is jetted into each air stream as it passes through the respective ports from a spud coaxially positioned with respect to the burner port, the method of starting a cold furnace which comprises advancing the spuds through the ports to a position near the exit and thereof so that the fuel gas is jetted into the air streams as the latter pass from the ports, burning the resultant streams of combustible mixture in the furnace until the walls of the furnace and the face of the burner block have been heated to the ignition temperature of the combustible mixture, the name front being a substantial distance downstream from the face of thev burner block, then gradually retracting the spuds until the flame front has been drawn back to the face of the burner block.
l0. A furnace for the production of carbon black which comprises an elongated, unobstructed l l and unrestricted heat insulated chamber, a burner block of substantial thickness coextensive with the transverse area of the chamber and positioned in one end thereof, a wind-box adapted to contain air under super-atmospheric pressure secured to the burner block, a connection adapted to the passing of air under pressure to the windbox, a plurality of substantially parallel burner ports, not over 2 inches in diameter and of a depth not less than 4 diameters, extending through said block and uniformly spaced over the surface of said block, the number and size of said burner ports being such that not less than 50% of the area of the burner block face is plane surface, the outer ends. of the respective ports opening into the Wind-box, a fuel gas manifold within the Wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with the respective burner ports, a connection for supplying fuel gas under pressure to the manifold, said fuel gas manifold being so constructed and arranged within the wind-box as to be adapted to be moved therein toward and away from the burner block Without altering the alignment of the spuds with the axis of the respective burner ports, and a connection adapted to the injection of a gaseous medium into that end of the chamsecured to the burner block, a connection adapted to the passing of air under pressure to the Wind-V box, a plurality of substantially parallel burner ports, not over 2 inches in diameter and of a depth not less than 4 diameters, extending through said block and uniformly spaced over the surface of said block, the number and size of said burner ports being such that not less than 50% of the area of the burner block face is plane surface, the outer ends of the respective ports opening into the wind-box, a fuel gas manifold within the Wind-box, a plurality of fuel gas spuds each connected with the manifold by a tube of a length substantially greater than the depth of the burner ports, the spuds and connecting tubes being positioned coaxially with the respective burner ports, a connection for supplying fuel gas under pressure to the manifold, said fuel gas manifold being so constructed and arranged within the wind-box as to be adapted to be moved therein toward and away from the burner block without altering the alignment of the spuds ber adjacent the burner block, said connection with the axis of the respective burner ports, 'and a tubular connection extending inwardly through the chamber wall and adapted to the injection of a gaseous medium therein. I l
GEORGE L. HELLER.
REFERENCES CITED The following references are of record inthe le of this patent:
UNITED'v STATES PATENTS Date -1
Claims (1)
- 6. A FURNACE FOR THE PRODUCTION OF CARBON BLACK WHICH COMPRISES AN ELONGATED, UNOBSTRUCTED AND UNRESTRICTED HEAT INSULATED CHAMBER, A BURNER BLOCK OF SUBSTANTIAL THICKNESS COEXTENSIVE WITH THE TRANSVERSE AREA OF THE CHAMBER AND POSITIONED IN ONE END THEREOF, A WIND-BOX ADAPTED TO CONTAIN AIR UNDER SUPER-ATMOSPHERIC PRESSURE SECURED TO THE BURNER BLOCK, A CONNECTION ADAPTED TO THE PASSING OF AIR UNDER PRESSURE TO THE WINDBOX, A PLURALITY OF SUBSTANTIALLY PARALLEL BURNER PORTS, NOT OVER 2 INCHES IN DIAMETER AND OF A DEPTH NOT LESS THAN 4 DIAMETERS, EXTENDING THROUGH SAID BLOCK AND UNIFORMLY SPACED OVER THE SURFACE OF SAID BLOCK, THE NUMBER AND SIZE OF SAID BURNER PORTS BEING SUCH THAT NOT LESS THAN 50% OF THE AREA OF THE BURNER BLOCK FACE IS PLANE SURFACE, THE OUTER ENDS OF THE RESPECTIVE PORTS OPENING INTO THE WIND-BOX, A FUEL GAS MANIFOLD WITHIN THE WIND-BOX, A PLURALITY OF FUEL GAS SPUDS EACH CONNECTED WITH THE MANIFOLD BY A
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US2399A US2529873A (en) | 1948-01-15 | 1948-01-15 | Manufacture of carbon black |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2399A US2529873A (en) | 1948-01-15 | 1948-01-15 | Manufacture of carbon black |
Publications (1)
Publication Number | Publication Date |
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US2529873A true US2529873A (en) | 1950-11-14 |
Family
ID=21700578
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US2399A Expired - Lifetime US2529873A (en) | 1948-01-15 | 1948-01-15 | Manufacture of carbon black |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2592899A (en) * | 1949-06-11 | 1952-04-15 | Robert C Hopkins | Burner equipment for rotary driers for aggregates |
US2686560A (en) * | 1950-11-27 | 1954-08-17 | United Carbon Company Inc | Gas injector |
US2705190A (en) * | 1951-07-31 | 1955-03-29 | Columbian Carbon | Apparatus for carbon black manufacture |
US2781250A (en) * | 1952-02-18 | 1957-02-12 | Phillips Petroleum Co | Carbon black reactor |
US2825632A (en) * | 1952-04-08 | 1958-03-04 | Cabot Godfrey L Inc | Process of making furnace carbon black and burner therefor |
DE1036221B (en) * | 1951-06-04 | 1958-08-14 | Thann Fab Prod Chem | Process for the production of finely divided metal oxides or silicon dioxide |
US2851337A (en) * | 1951-08-22 | 1958-09-09 | Columbian Carbon | Carbon black process |
US2897062A (en) * | 1954-02-05 | 1959-07-28 | Phillips Petroleum Co | Gas reactor |
US2985232A (en) * | 1958-10-01 | 1961-05-23 | Lennox Ind Inc | Furnace gas manifold and clamping structure |
US3023083A (en) * | 1957-05-27 | 1962-02-27 | Knapsack Ag | Process for producing an alkali phosphate from an aqueous ortho-phosphate |
DE2261129A1 (en) * | 1972-11-10 | 1974-05-16 | Frossblacks Int Process Ets | PROCESS AND PLANT FOR PRODUCING SOOT FROM LIQUID AND / OR GASY HYDROCARBONS |
US4585644A (en) * | 1984-06-04 | 1986-04-29 | Phillips Petroleum Company | Changing oil tubes in a carbon black reactor |
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US1112484A (en) * | 1914-03-03 | 1914-10-06 | William E Groll | Gas-heated water-heater. |
US1482258A (en) * | 1922-04-01 | 1924-01-29 | Semet Solvay Co | Gas burner |
US2136449A (en) * | 1935-03-18 | 1938-11-15 | Lena Belle F Loeffler | Gas burner |
US2392822A (en) * | 1944-05-24 | 1946-01-15 | Riley Stoker Corp | Gas burner |
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US1112484A (en) * | 1914-03-03 | 1914-10-06 | William E Groll | Gas-heated water-heater. |
US1482258A (en) * | 1922-04-01 | 1924-01-29 | Semet Solvay Co | Gas burner |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2592899A (en) * | 1949-06-11 | 1952-04-15 | Robert C Hopkins | Burner equipment for rotary driers for aggregates |
US2686560A (en) * | 1950-11-27 | 1954-08-17 | United Carbon Company Inc | Gas injector |
DE1036221B (en) * | 1951-06-04 | 1958-08-14 | Thann Fab Prod Chem | Process for the production of finely divided metal oxides or silicon dioxide |
US2705190A (en) * | 1951-07-31 | 1955-03-29 | Columbian Carbon | Apparatus for carbon black manufacture |
US2851337A (en) * | 1951-08-22 | 1958-09-09 | Columbian Carbon | Carbon black process |
US2781250A (en) * | 1952-02-18 | 1957-02-12 | Phillips Petroleum Co | Carbon black reactor |
US2825632A (en) * | 1952-04-08 | 1958-03-04 | Cabot Godfrey L Inc | Process of making furnace carbon black and burner therefor |
US2897062A (en) * | 1954-02-05 | 1959-07-28 | Phillips Petroleum Co | Gas reactor |
US3023083A (en) * | 1957-05-27 | 1962-02-27 | Knapsack Ag | Process for producing an alkali phosphate from an aqueous ortho-phosphate |
US2985232A (en) * | 1958-10-01 | 1961-05-23 | Lennox Ind Inc | Furnace gas manifold and clamping structure |
DE2261129A1 (en) * | 1972-11-10 | 1974-05-16 | Frossblacks Int Process Ets | PROCESS AND PLANT FOR PRODUCING SOOT FROM LIQUID AND / OR GASY HYDROCARBONS |
US4585644A (en) * | 1984-06-04 | 1986-04-29 | Phillips Petroleum Company | Changing oil tubes in a carbon black reactor |
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