US2450887A - Semiconductor - Google Patents
Semiconductor Download PDFInfo
- Publication number
- US2450887A US2450887A US564409A US56440944A US2450887A US 2450887 A US2450887 A US 2450887A US 564409 A US564409 A US 564409A US 56440944 A US56440944 A US 56440944A US 2450887 A US2450887 A US 2450887A
- Authority
- US
- United States
- Prior art keywords
- selenium
- conductivity
- substances
- compounds
- mentioned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004065 semiconductor Substances 0.000 title description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 29
- 229910052711 selenium Inorganic materials 0.000 description 28
- 239000011669 selenium Substances 0.000 description 28
- 239000000126 substance Substances 0.000 description 13
- 150000002366 halogen compounds Chemical class 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- -1 halogen salts Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002497 iodine compounds Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- CXMYWOCYTPKBPP-UHFFFAOYSA-N 3-(3-hydroxypropylamino)propan-1-ol Chemical compound OCCCNCCCO CXMYWOCYTPKBPP-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- VIEXQFHKRAHTQS-UHFFFAOYSA-N chloroselanyl selenohypochlorite Chemical compound Cl[Se][Se]Cl VIEXQFHKRAHTQS-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D48/00—Individual devices not covered by groups H10D1/00 - H10D44/00
- H10D48/01—Manufacture or treatment
- H10D48/04—Manufacture or treatment of devices having bodies comprising selenium or tellurium in uncombined form
- H10D48/043—Preliminary treatment of the selenium or tellurium, its application to foundation plates or the subsequent treatment of the combination
Definitions
- the present invention relates to semi-conductors and particularly to high voltage selenium conducting surface to the supply electrode.
- This transition resistance must be as low as possible and must be independent of voltage if the operation of the rectifier is to be satisfactory.
- the characteristic resistance curve of the blocking layer itself is dependent upon its chemical and physical composition and the magnitude of the resistances in both direction of current flow is primarily determined by the conductivity of the selenium itself.
- the conductivity of selenium can be materially increased by a thorough conversion into a crystalline term by annealing it at a temperature close to the melting point and that the conductivity of selenium can be further increased by the addition of materials, such as pulverized halogen salts of heavy metals, alkalies, carbon powder, or organic compounds. After conversion the additional materials either appear as undecomposed matters having certain conductivity embodied in the selenium or they are mainly decomposed into oxides or selenides of good conductivity. These latter are conductive bodies and form dangerous shunting paths in the selenium and in the blocking layer itself.
- plum-bromide brought about an increase in the forward-conductivity of the blocking layer, but at the same time a proportionate increase in the back-conductivity had to be accepted.
- the admixture according to the present invention that means the addition of more than one halogen compound to the selenium, in contradiction to the above mentioned application in which only one halogen compound is added to the selenium, shows beneficial results where it is not only important to increase the forward-conductivity without increasing the reverse-conductivity but also to use a disc, designed for a certain voltage, at a still higher voltage than is allowed to use in the disc according to the above mentioned application.
- the novel construction of the present rectifier has the advantage of using less rectifying discs within the rectifier stack for a certain predetermined forward-conductivity where until now a greater number of rectifying discs had to be used.
- the improvement that comprises incorporating in the selenium layer a minor proportion of a plurality of substances selected from the class consisting of iodine compounds of chicrine and iodine compounds of bromine.
Landscapes
- Primary Cells (AREA)
- Photoreceptors In Electrophotography (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE463238D BE463238A (en(2012)) | 1944-11-20 | ||
BE461942D BE461942A (en(2012)) | 1944-11-20 | ||
US564408A US2450886A (en) | 1944-11-20 | 1944-11-20 | Semiconductor |
US564409A US2450887A (en) | 1944-11-20 | 1944-11-20 | Semiconductor |
GB30788/45A GB601430A (en) | 1944-11-20 | 1945-11-16 | Semi-conductor |
CH254387D CH254387A (de) | 1944-11-20 | 1945-11-16 | Selen-Halbleiter und Verfahren zu dessen Herstellung. |
CH258963D CH258963A (de) | 1944-11-20 | 1945-11-16 | Selenhalbleiter und Verfahren zu dessen Herstellung. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US564409A US2450887A (en) | 1944-11-20 | 1944-11-20 | Semiconductor |
Publications (1)
Publication Number | Publication Date |
---|---|
US2450887A true US2450887A (en) | 1948-10-12 |
Family
ID=24254358
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US564409A Expired - Lifetime US2450887A (en) | 1944-11-20 | 1944-11-20 | Semiconductor |
Country Status (4)
Country | Link |
---|---|
US (1) | US2450887A (en(2012)) |
BE (2) | BE463238A (en(2012)) |
CH (2) | CH254387A (en(2012)) |
GB (1) | GB601430A (en(2012)) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080135415A1 (en) * | 2006-12-07 | 2008-06-12 | Yongbong Han | Electrodeposition technique and apparatus to form selenium containing layers |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1106424B (de) * | 1953-02-10 | 1961-05-10 | Siemens Ag | Selengleichrichter, bei dem die Selen-schicht aus mindestens zwei Teilschichten mit unterschiedlichem Zusatzstoffgehalt aufgebaut ist |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB472951A (en) * | 1936-04-07 | 1937-10-04 | Marconi Wireless Telegraph Co | Improvements in or relating to electrical measuring instrument arrangements |
US2173249A (en) * | 1935-10-30 | 1939-09-19 | Philips Nv | Asymmetric electrode system |
US2226715A (en) * | 1939-03-08 | 1940-12-31 | Suddeutsche App Fabrik G M B H | Rectifier device |
US2227827A (en) * | 1938-09-21 | 1941-01-07 | Union Switch & Signal Co | Manufacture of devices presenting electrical asymmetric conductivity |
US2316905A (en) * | 1939-07-01 | 1943-04-20 | Westinghouse Electric & Mfg Co | Selenium rectifier |
-
0
- BE BE461942D patent/BE461942A/xx unknown
- BE BE463238D patent/BE463238A/xx unknown
-
1944
- 1944-11-20 US US564409A patent/US2450887A/en not_active Expired - Lifetime
-
1945
- 1945-11-16 CH CH254387D patent/CH254387A/de unknown
- 1945-11-16 CH CH258963D patent/CH258963A/de unknown
- 1945-11-16 GB GB30788/45A patent/GB601430A/en not_active Expired
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2173249A (en) * | 1935-10-30 | 1939-09-19 | Philips Nv | Asymmetric electrode system |
GB472951A (en) * | 1936-04-07 | 1937-10-04 | Marconi Wireless Telegraph Co | Improvements in or relating to electrical measuring instrument arrangements |
US2227827A (en) * | 1938-09-21 | 1941-01-07 | Union Switch & Signal Co | Manufacture of devices presenting electrical asymmetric conductivity |
US2226715A (en) * | 1939-03-08 | 1940-12-31 | Suddeutsche App Fabrik G M B H | Rectifier device |
US2316905A (en) * | 1939-07-01 | 1943-04-20 | Westinghouse Electric & Mfg Co | Selenium rectifier |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080135415A1 (en) * | 2006-12-07 | 2008-06-12 | Yongbong Han | Electrodeposition technique and apparatus to form selenium containing layers |
US8066863B2 (en) * | 2006-12-07 | 2011-11-29 | Solopower, Inc. | Electrodeposition technique and apparatus to form selenium containing layers |
Also Published As
Publication number | Publication date |
---|---|
CH258963A (de) | 1948-12-31 |
GB601430A (en) | 1948-05-05 |
BE463238A (en(2012)) | |
BE461942A (en(2012)) | |
CH254387A (de) | 1948-04-30 |
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