US2431948A - Apparatus for electrodepositing metal on bearing shells and the like - Google Patents

Apparatus for electrodepositing metal on bearing shells and the like Download PDF

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US2431948A
US2431948A US508456A US50845643A US2431948A US 2431948 A US2431948 A US 2431948A US 508456 A US508456 A US 508456A US 50845643 A US50845643 A US 50845643A US 2431948 A US2431948 A US 2431948A
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plating
electrolyte
anode
bearing shells
bearing
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US508456A
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William M Martz
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Motors Liquidation Co
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Motors Liquidation Co
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/10Bearings
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/04Tubes; Rings; Hollow bodies

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  • This, invention relates genemn Vi any ⁇ of electrodepositing metals anddm'ore particularly to electrodepositinga "layer :or- 'coating 'of metalon the inside of bearing rshells: andathe like.
  • High'quality bearings such as employed in air-"- craft engines may be made by electrodepositing a" layer or layers-of relatively :soft" metal or alloy having goodxantifrictional properties onto a sup port of 'at'harder' and stronger metal which acts as the cathode'during the'plating operation;
  • Different forms of apparatuses havebeen proposedheretofore zfor: electrodeposting-metal on the inside oiiibearing shells andsthe like. While some of thecplatingapparatusessor devices" have given satisfactoryresults and many' high quality bear:
  • Che objectcitric-invention is the provisionof an improved apparatus for plating bearing shells' a and the :like thateliminates defects-in devices. heretofore employed.
  • Another object of the invention is theaprovi sion'of 'an'apparatus for plating bearings and the 'like that iseharacteriz'ed 'by its simplicity "andease of operationand control.
  • this invention to provide animproved apparatus for plating aplurality of stacks of hearing and the like at one time in which-- onlyasingle'pump is required-to circulate-the:
  • a further object of the invention isthe "pro-'--- vision of animproved device of the class'described in whichit is practical to filter the plating solutionso that only filtered solution flows past the "cathode.
  • 'Another object of the invention is to provide a device of the class described in which only a small amount of floor space is required per stack of bearings or other articles being plated.
  • Figure 1 is an elevational view with parts broken away and with parts in section illustrating an apparatus in accordance with the invention.
  • Figure 2 is an enlarged sectional view of one of the plating unit assemblies shown in Figure 1.
  • a lower tank having a supply I2 of plating solution or electrolyte.
  • another tank Is in which is an amount of plating solution indicated by It.
  • a pipe I8 leading from the lower tank to the inlet side of pump 20, a pump outlet 22, a filter 24 and a pipe 26 leading from the filter and discharging into the upper tank.
  • a pipe I8 leading from the lower tank to the inlet side of pump 20, a pump outlet 22, a filter 24 and a pipe 26 leading from the filter and discharging into the upper tank.
  • a plurality of similar outlet tubes or pipes 28 in this case three in number.
  • Each outlet tube has a valve 30 therein wherein flow of electrolyte therein can be stopped entirely or regulated in amount.
  • Each of the outlet tubes 28 leads downwardly to a corresponding plating unit assembly in the lower tank ind cated generally by 32.
  • the plating unit assemblies each comprise a hollow support 33 formed of hard rubber or equivalent material, a chamber 34 in each support, atubular connection 35 of rubber connecting the lower end of a pipe 28 and a chamber 34, an orifice plate or annular plug 35 of hard rubber or equivalent material having openings 3'!
  • the hollow support 33 is generally cup-shaped and has a base and upwardly extending walls of generally circular shape.
  • the upper portion of the hollow anode is spaced from the stack of bearing shells so as to form an annular passage between the same, while the intermediate portion of the hollow anode is spaced from the upwardly extending walls of the hollow support shape, the two annular passages being connected together.
  • the lower end of the tubular'anode passes through a centrally arranged opening in the base or bottom of the cup-shaped support and is in liquid-tight engagement therewith.
  • the electrolyte enters the hollow support by means of tubular connection 35 and flows upwardly in the annular passages until it reaches the upperend of the cathode and then flows downwardly through the tubular anode for return to the lower supply tank.
  • anode will 'be connected to the positive side of a source 33 to form a passage otannular- 4 of direct current and the metallic bearing shells 40 and 42 electrically connected to each other by metallic clamping ring 36 will be connected to the negative side of the source of current to form the cathode on which metal will be electrodeposited in the plating operation by means of electric current passing through the electrolyte from the anode to the cathode.
  • Another pipe 56 leads from a point in the upper tank to a point of discharge in the lower tank and acts as an overflow return should the pump 20 circulate more solution or electrolyte to the upper tank than is returned to the lower tank by means of the pipes or tubes 28 leading to the several plating units.
  • the upper tank is supported above the lower tank at a suificient height to give sufficient volume of flow by means of gravity flow through each of the pipes 28 leading to the plating units. In most cases a head of 24 to 30 inches gives sufficient volume of flow upwardly through the plating units.
  • the valves 30 in the pipes 28 may be operated to control the flow. The flow through any pipe 28 may be cut oil entirely without affecting the head or amount of flow through the other pipes.
  • the jet or orifice plate 36 has the openings 31 arranged spirally at an angle of about 45 in order to impart a spiral flow to the electrolyte as it passes upward between the hollow anode and bearing shells. This most effectively brings fresh platin solution into contact with the surfaces to be plated.
  • the orifices may be so disposed as to cause the flow to be straight up between the anode and bearing shells.
  • the anodes and other materials may be whatever is necessary to conform with the type of electrolyte. If, for example, the solution or electrolyte is a silver plating solution, the anode may be of silver. In this case, of course, the anode will be used up as the silver passes into solution during electrolysis and eventually the anode must be replaced. If the anode is of iron or other insoluble material, it will be necessary to replace or replenish the silver that is electrodeposited out of the electrolyte. This can be accomplished by adding a silver salt to the electrolyte from time to time, or other means may be employed.
  • the soft rubber gaskets 38, 44 and 52 form liquid tight seals which prevent the electrolyte from escaping during upward flow of the electrolytebetween the hollow anode and bearin assembly.
  • the curved portions 49 and 50 of the caps are for the purpose of directing the electrolyte into the inside of the hollow anode with as little turbulence as possible.
  • Each cap 48 forms a tight press fit with the bearing shell. If desired, suitable clamping or hold down means (not shown) may be employed to hold the caps in position during the plating operation.
  • An apparatus for electrodepositing metal on the inside of a stack of bearing shells and the like which comprises, a generally cup-shaped support having a base and upwardly extending walls of generally circular shape, the upper portions of said walls adapted to engage in liquidtight relation and support a stack of bearing shells connected together to form a tubular cathode, said base having an opening centrally arranged therein, a tubular anode having an upper portion within the tubular cathode, an intermediate portion within the cup-shaped support and a lower portion extending through said opening, said upper portion being spaced from said tubu- 6 lar cathode to form an annular passage for electrolyte between said tubular cathode and said upper portion, said intermediate portion being spaced from said walls and forming therewith a passage of annular shape, said annular passages thus being connected together, said lower portion being in liquid-tight engagement with said opening, an annular plug in the annular passage between said intermediate portion and said walls at a point between said base and upper end of said walls, said

Description

Dec. 2, 1947. w. M. MARTZ ,948
APPARATUS FOR ELECTRODEPOSITING METAL ON BEARING SHELLS AND THE LIKE Filed Nov. 1, 1943- I ll 1 Snnentof ZZZ/$212772 7%152 Gltorncg Patented Dec. 2, 1947 OFF] APPARATUS FOR ELECTROD-EBO SITING- METAL ON BEARING SHELLS AND THE LIK-E .1
William"MFMartifIridianapolis, Ind., assignor to General Motors -Corporation;Detroit, Mich., a corporationpf"Delaware Application Novembenl, 1943, Serial N'o:2 508,456:
1,.C1aim... (01. 2045-272) This, invention: relates genemn Vi any} of electrodepositing metals anddm'ore particularly to electrodepositinga "layer :or- 'coating 'of metalon the inside of bearing rshells: andathe like.
High'quality bearings such as employed in air-"- craft engines may be made by electrodepositing a" layer or layers-of relatively :soft" metal or alloy having goodxantifrictional properties onto a sup port of 'at'harder' and stronger metal which acts as the cathode'during the'plating operation; Different forms of apparatuses havebeen proposedheretofore zfor: electrodeposting-metal on the inside oiiibearing shells andsthe like. While some of thecplatingapparatusessor devices" have given satisfactoryresults and many' high quality bear:
ings produced thereby;- all ithoseapparatuses of whichi am aware are -subject toone-or'more dis advantages.
Infplatiilg bearings' and the like it is desirable to electrodeposit the relatively soft metal at a rapid-- rate requiring relatively high current dnsities; Thisfactor alongwith" others makes it necessary onadvantageous to provide a considerable amount of'agi'tation of the =plating solution, In some ap:
ingi solution td the inside surface *of the bear changingithe flow through'all of the other stacks-.3; inthe system; In accordance With'the'present in-:- ventioniby' making'iuse of :a* system including; gravity flow; a constant head is provided for each:
3: stack and the now throughzany stack-of a' lural ity of stacks may :be -changed"atxwillwithut; 51H?" fiuencing thes'rateof flow or :pressure in :any ofig. the. other 'stacks in the system.
Another)" disadvantage of some apparatuseslflxfheretgfore=empyed is that masking oithe hear ing backo-r shell formin'gthe cathode isnecessayr The procedure of applying'the masks. and removing: the 1 same after :plating is not 'only time con-t. sumingbut'the masks are a cause=ofplatingsreellitjectidns -due=toplating solution being trapped in";
means may be employed either by itself or with-- meansto agitate or rotate the anode and/or cathode. .S'uch'movable'means are not required in thepreferred embodiment of my invention and the platingtsolutionis agitated and a'supply of fresh platingzsolution is brought continuously into con tact iwith th'elinside surfaceoi the bearing shells by'simple means and without the meet rotary d-- vices inthe electrolyte;-
Inrgeneral: there are advantages in flo'wingth'eelectrolyte upwardly through a stack 0f bearings orotherzanticles tribe plated. It is desirable also to :have positive pressure such" as provided by a correct' type of pump. It' is desirable from pr m ticalz considerationsto employ a plurality of plat-= ingiunits :forieach'tank of plating "solution in or- 0"th'e outside of the bearing shells; plated-:atione time. However; unless a separateder. thatfa plurality of stacks of bearings canbe pumpsis used for each-plating unit, it is diflieult to :control the rate of flow through the individual stacksY-andithe rate of fiowithrough OIIG OIclIlOIE stacks cannot .ibe-salterediwithwt simultaneously #1 55 Y the'various types of masks-employed; In the pre-; ferred 'embodiment of my invention no external; masking devices are :necessary;
Che objectcitric-invention is the provisionof an improved apparatus for plating bearing shells' a and the :like thateliminates defects-in devices. heretofore employed.
Another object of the invention'is theaprovi sion'of 'an'apparatus for plating bearings and the 'like that iseharacteriz'ed 'by its simplicity "andease of operationand control.
It is also anobject of this invention to provide an apparatus" of simple construction adapted te-- plate a plurality of stacks ofbearings and the-'- like atone time and wherein theflow through any one stack may be changed'without influencing the rate of new through any of the other stacks":
IEisalsoanobjector this invention to provide animproved apparatus for plating aplurality of stacks of hearing and the like at one time in which-- onlyasingle'pump is required-to circulate-the:
platingsolution and in which the 'flow characteristics through any-one stack maybe changed without afiecting the flow characteristicsthrough -any of the other stacks.-
A further object of the invention isthe "pro-'--- vision of animproved device of the class'described in whichit is practical to filter the plating solutionso that only filtered solution flows past the "cathode.
It is-a further object of the invention to pro vide' an improved apparatus for plating'thein side of bearing shells and the like that eliminates the necessity of employing-masking devices for Afurther object of the inventionis to'provide an improvedmeans-for maintaining a fresh and undepleted' supply of plating solution at "the sur facesto be plated.
It is' 'also an object of' the invention to provide a device of the class described in which no rotary devices are required in the electrolyte.
'Another object of the invention is to provide a device of the class described in which only a small amount of floor space is required per stack of bearings or other articles being plated.
Other objects and advantages of the invention will become more apparent from the detailed description which follows.
Reference is herewith made to the accompanying drawing illustrating an apparatus in accord ance with one embodiment of the invention.
In the drawing:
Figure 1 is an elevational view with parts broken away and with parts in section illustrating an apparatus in accordance with the invention.
Figure 2 is an enlarged sectional view of one of the plating unit assemblies shown in Figure 1.
In the drawing, in indicates a lower tank having a supply I2 of plating solution or electrolyte. Directly above the lower tank is another tank Is, in which is an amount of plating solution indicated by It. For the purpose of pumping the plating solution from the lower tank to the upper tank there are provided; a pipe I8 leading from the lower tank to the inlet side of pump 20, a pump outlet 22, a filter 24 and a pipe 26 leading from the filter and discharging into the upper tank. In the bottom of the upper tank are a plurality of similar outlet tubes or pipes 28, in this case three in number. Each outlet tube has a valve 30 therein wherein flow of electrolyte therein can be stopped entirely or regulated in amount. Each of the outlet tubes 28 leads downwardly to a corresponding plating unit assembly in the lower tank ind cated generally by 32. The plating unit assemblies each comprise a hollow support 33 formed of hard rubber or equivalent material, a chamber 34 in each support, atubular connection 35 of rubber connecting the lower end of a pipe 28 and a chamber 34, an orifice plate or annular plug 35 of hard rubber or equivalent material having openings 3'! through which electrolyte flows from each chamber, a soft rubber gasket 38, a bearing shell assembly including two bearing shells ll] and G2, a soft rubber gasket 44 and a metallic clamping ring 46, a cap 48 of hard rubber above the bearing shell assembly having inner curved portions 49 and 50, a soft rubber gasket 52 between the upper bearing shell and cap forming a tight seal therebetween, and a hollow anode 54 within the bearing assembly, said anode passing downwardly through the orifice plate 36 and hard rubber support 33 and discharging into the lower tank It). The hollow support 33 is generally cup-shaped and has a base and upwardly extending walls of generally circular shape. The upper portion of the hollow anode is spaced from the stack of bearing shells so as to form an annular passage between the same, while the intermediate portion of the hollow anode is spaced from the upwardly extending walls of the hollow support shape, the two annular passages being connected together. The lower end of the tubular'anode passes through a centrally arranged opening in the base or bottom of the cup-shaped support and is in liquid-tight engagement therewith. The electrolyte enters the hollow support by means of tubular connection 35 and flows upwardly in the annular passages until it reaches the upperend of the cathode and then flows downwardly through the tubular anode for return to the lower supply tank. It will be understood that the anode will 'be connected to the positive side of a source 33 to form a passage otannular- 4 of direct current and the metallic bearing shells 40 and 42 electrically connected to each other by metallic clamping ring 36 will be connected to the negative side of the source of current to form the cathode on which metal will be electrodeposited in the plating operation by means of electric current passing through the electrolyte from the anode to the cathode.
Another pipe 56 leads from a point in the upper tank to a point of discharge in the lower tank and acts as an overflow return should the pump 20 circulate more solution or electrolyte to the upper tank than is returned to the lower tank by means of the pipes or tubes 28 leading to the several plating units.
As shown the solution in the lower tank is below the lowermost bearing shell and surrounding the hollow supports 33. When the solution level is thus maintained no external masking is required for the bearing shells.
The upper tank is supported above the lower tank at a suificient height to give sufficient volume of flow by means of gravity flow through each of the pipes 28 leading to the plating units. In most cases a head of 24 to 30 inches gives sufficient volume of flow upwardly through the plating units. For fine adjustment the valves 30 in the pipes 28 may be operated to control the flow. The flow through any pipe 28 may be cut oil entirely without affecting the head or amount of flow through the other pipes.
As shown the jet or orifice plate 36 has the openings 31 arranged spirally at an angle of about 45 in order to impart a spiral flow to the electrolyte as it passes upward between the hollow anode and bearing shells. This most effectively brings fresh platin solution into contact with the surfaces to be plated. In some cases the orifices may be so disposed as to cause the flow to be straight up between the anode and bearing shells.
The anodes and other materials may be whatever is necessary to conform with the type of electrolyte. If, for example, the solution or electrolyte is a silver plating solution, the anode may be of silver. In this case, of course, the anode will be used up as the silver passes into solution during electrolysis and eventually the anode must be replaced. If the anode is of iron or other insoluble material, it will be necessary to replace or replenish the silver that is electrodeposited out of the electrolyte. This can be accomplished by adding a silver salt to the electrolyte from time to time, or other means may be employed.
The number of units which may be used in the tank are, of course, limited only by the size of the tank desired.
While the construction illustrated in the drawings shows only two bearing shells in each assembly, it will be understood that a greater number can be plated at one time at each plating unit, or, of course, only one, if desired. After the desired thickness of metal is electrodeposited'onto each bearing shell assembly, the rubber cap 48 and gasket 52 are'removed from the upper bearing shell and the bearing shell assembly removed from its seat on the soft rubber gasket 38, whereupon an unplated bearing shell assembly can then be placed in position for plating. The operation of removing a plated bearing assembly and inserting an unplated bearing assembly is a simple one. The clamping rin 46 has adjustable screws 10 which, when tightened, secure the two bearing shells together as an assembly. When the screws are loosened the bearings can be separated from each other. The electrical connection leading to the negative side of the source of plating current may be attached to the clamping ring.
It will be understood that the soft rubber gaskets 38, 44 and 52 form liquid tight seals which prevent the electrolyte from escaping during upward flow of the electrolytebetween the hollow anode and bearin assembly. The curved portions 49 and 50 of the caps are for the purpose of directing the electrolyte into the inside of the hollow anode with as little turbulence as possible. Each cap 48 forms a tight press fit with the bearing shell. If desired, suitable clamping or hold down means (not shown) may be employed to hold the caps in position during the plating operation.
In place of causing the electrolyte to return to the lower tank through the anode it is possible to omit the cap member and otherwise modify the construction to permit the electrolyte to flow over the upper edge of the upper bearing shell of the bearing shell assembly and return to the lower tank. In such case, however, suitable external masking means must be provided for the backs of the bearing shells. Suitable masking means also will be required in the apparatus illustrated in the drawing if the solution level is permitted to rise above the portion of the bearing shell assembly above the hollow support 32.
Various changes and modifications may be made without departing from the spirit and principles of the invention.
1 claim:
An apparatus for electrodepositing metal on the inside of a stack of bearing shells and the like which comprises, a generally cup-shaped support having a base and upwardly extending walls of generally circular shape, the upper portions of said walls adapted to engage in liquidtight relation and support a stack of bearing shells connected together to form a tubular cathode, said base having an opening centrally arranged therein, a tubular anode having an upper portion within the tubular cathode, an intermediate portion within the cup-shaped support and a lower portion extending through said opening, said upper portion being spaced from said tubu- 6 lar cathode to form an annular passage for electrolyte between said tubular cathode and said upper portion, said intermediate portion being spaced from said walls and forming therewith a passage of annular shape, said annular passages thus being connected together, said lower portion being in liquid-tight engagement with said opening, an annular plug in the annular passage between said intermediate portion and said walls at a point between said base and upper end of said walls, said plug having angularly arranged jet openings adapted to impart a spiralling effect to electrolyte as it flows therethrough, a cap in liquid-tight engagement with the upper end of said tubular cathode and spaced from the upper end of said tubular anode, means for flowing electrolyte into said annular passage below said plug, then upwardly through the angularly arranged jet openings, then spirally upward through said annular passageway formed between the upper portion of said tubular anode and said tubular cathode to the upper end of the cathode and then downwardly through the tubular anode, and means for passing electric current from the tubular anode to the tubular cathode through the electrolyte flowing spirally upward in said annular passageway between the two.
WILLIAM M. MARTZ.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 1,259,683 Van Hasselt Mar. 19, 1918 686,395 Dessolle Nov. 12, 1901 2,297,252 Schmidt Sept. 29, 1942 1,886,218 Olin Nov. 1, 1932 1,594,509 Rosenqvist Aug. 3, 1926 588,740 Becker Aug. 24, 1897 1,872,290 Hitner Aug. 16, 1932 1,927,162 Fiedler et al Sept, 19, 1933 FOREIGN PATENTS Number Country Date 215,409 Switzerland Nov. 3, 1939 825,071 France Nov. 27, 1937
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2535966A (en) * 1947-02-07 1950-12-26 Teplitz Alfred Electrolytic apparatus for cleaning strip
US2706175A (en) * 1949-03-18 1955-04-12 Electro Metal Hardening Co S A Apparatus for electroplating the inner surface of a tubular article
US2990353A (en) * 1954-03-01 1961-06-27 Donald F Howard Nuclear reactor control system
US3003942A (en) * 1954-12-16 1961-10-10 Hispeed Equipment Inc Electrolytic cell for recovery of silver from spent photographic fixing baths
FR2159177A1 (en) * 1971-11-09 1973-06-22 Citroen Sa
FR2159178A1 (en) * 1971-11-09 1973-06-22 Citroen Sa
US3956096A (en) * 1973-03-23 1976-05-11 Electro-Coatings, Inc. Apparatus for plating aircraft cylinders
US4279706A (en) * 1980-03-27 1981-07-21 Alsthom-Atlantique Method and assembly for depositing a metal on a cylindrical bore which passes through a central portion of a large part
US4293400A (en) * 1980-02-01 1981-10-06 Liggett James J Electrolytic treatment of water
US4853099A (en) * 1988-03-28 1989-08-01 Sifco Industries, Inc. Selective electroplating apparatus
US4931150A (en) * 1988-03-28 1990-06-05 Sifco Industries, Inc. Selective electroplating apparatus and method of using same
US5002649A (en) * 1988-03-28 1991-03-26 Sifco Industries, Inc. Selective stripping apparatus

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US588740A (en) * 1897-08-24 becker
US686395A (en) * 1900-03-06 1901-11-12 Emile Louis Dessolle Apparatus for electrocoppering metals.
US1259683A (en) * 1916-10-12 1918-03-19 Rolf Van Hasselt Process for the electrolysis of alkali chlorids.
US1594509A (en) * 1925-02-24 1926-08-03 Rosenqvist Gunnar Apparatus for producing articles by electrolytic deposition
US1872290A (en) * 1928-06-23 1932-08-16 Westinghouse Electric & Mfg Co Corrugated or threaded anode
US1886218A (en) * 1927-06-29 1932-11-01 Western Cartridge Co Gun barrel and process of finishing the same
US1927162A (en) * 1931-02-27 1933-09-19 Research Corp Electroplating
FR825071A (en) * 1937-04-27 1938-02-23 Device for doubling cylinders and machine bearings
CH215409A (en) * 1939-11-03 1941-06-30 Rausser Emil Method and device for the production of galvanic coatings.
US2297252A (en) * 1937-02-13 1942-09-29 Schmidt Heinrich Process for the purification of solutions that serve as generators for percompounds

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US588740A (en) * 1897-08-24 becker
US686395A (en) * 1900-03-06 1901-11-12 Emile Louis Dessolle Apparatus for electrocoppering metals.
US1259683A (en) * 1916-10-12 1918-03-19 Rolf Van Hasselt Process for the electrolysis of alkali chlorids.
US1594509A (en) * 1925-02-24 1926-08-03 Rosenqvist Gunnar Apparatus for producing articles by electrolytic deposition
US1886218A (en) * 1927-06-29 1932-11-01 Western Cartridge Co Gun barrel and process of finishing the same
US1872290A (en) * 1928-06-23 1932-08-16 Westinghouse Electric & Mfg Co Corrugated or threaded anode
US1927162A (en) * 1931-02-27 1933-09-19 Research Corp Electroplating
US2297252A (en) * 1937-02-13 1942-09-29 Schmidt Heinrich Process for the purification of solutions that serve as generators for percompounds
FR825071A (en) * 1937-04-27 1938-02-23 Device for doubling cylinders and machine bearings
CH215409A (en) * 1939-11-03 1941-06-30 Rausser Emil Method and device for the production of galvanic coatings.

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2535966A (en) * 1947-02-07 1950-12-26 Teplitz Alfred Electrolytic apparatus for cleaning strip
US2706175A (en) * 1949-03-18 1955-04-12 Electro Metal Hardening Co S A Apparatus for electroplating the inner surface of a tubular article
US2990353A (en) * 1954-03-01 1961-06-27 Donald F Howard Nuclear reactor control system
US3003942A (en) * 1954-12-16 1961-10-10 Hispeed Equipment Inc Electrolytic cell for recovery of silver from spent photographic fixing baths
FR2159177A1 (en) * 1971-11-09 1973-06-22 Citroen Sa
FR2159178A1 (en) * 1971-11-09 1973-06-22 Citroen Sa
US3956096A (en) * 1973-03-23 1976-05-11 Electro-Coatings, Inc. Apparatus for plating aircraft cylinders
US4293400A (en) * 1980-02-01 1981-10-06 Liggett James J Electrolytic treatment of water
US4279706A (en) * 1980-03-27 1981-07-21 Alsthom-Atlantique Method and assembly for depositing a metal on a cylindrical bore which passes through a central portion of a large part
US4345977A (en) * 1980-03-27 1982-08-24 Alsthom-Atlantique Method and apparatus for depositing metal in a large diameter cylindrical bore which passes through a large part
US4853099A (en) * 1988-03-28 1989-08-01 Sifco Industries, Inc. Selective electroplating apparatus
US4931150A (en) * 1988-03-28 1990-06-05 Sifco Industries, Inc. Selective electroplating apparatus and method of using same
US5002649A (en) * 1988-03-28 1991-03-26 Sifco Industries, Inc. Selective stripping apparatus

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