US2409825A - Process for purifying exhaust gases - Google Patents

Process for purifying exhaust gases Download PDF

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US2409825A
US2409825A US468243A US46824342A US2409825A US 2409825 A US2409825 A US 2409825A US 468243 A US468243 A US 468243A US 46824342 A US46824342 A US 46824342A US 2409825 A US2409825 A US 2409825A
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gases
bell
tube
exhaust gases
box
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US468243A
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Baringoltz Bernardo
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2846Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for granular supports, e.g. pellets
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2882Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/06Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being an inertial, e.g. centrifugal, device
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/18Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being an adsorber or absorber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2250/00Combinations of different methods of purification
    • F01N2250/12Combinations of different methods of purification absorption or adsorption, and catalytic conversion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2370/00Selection of materials for exhaust purification
    • F01N2370/22Selection of materials for exhaust purification used in non-catalytic purification apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/24Methods or apparatus for fitting, inserting or repairing different elements by bolts, screws, rivets or the like
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2510/00Surface coverings
    • F01N2510/06Surface coverings for exhaust purification, e.g. catalytic reaction
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00Gas separation
    • Y10S55/30Exhaust treatment

Definitions

  • the invention relates to a device which serves as a silencer and disintoxicator of the escape gases of internal combustion engines, which may be added advantageously at the escape tube of the engine, as it will not only enable to silence the noise produced by the combustion, but also to disintoxicate completely the escape gases, causing thus the disappearance of a highly felt, present inconvenience.
  • Figure 2 a vertical view of the device seen from the left end of Figure 1, and
  • Figure 3 a similar vertical view of the device seen from the right end of Figure 1.
  • the novel device to which the invention relates is preferably cylindrical in shape, although this is not indispensable, and it is composed of a principal chamber 5, wherein is inserted a box 2 of much smaller dimensions, provided with a perforated bottom 3' and reposing within principal chamber I upon frame or pedestal 4.
  • Said chamber 2 will contain a filling 5 which consists of a granulated chemical compound which transforms the carbon oxide of the escape gases into carbon dioxide by catalytic oxidation; for example, it can be made up by a mixture which contains Per cent Potassium chlorate 20 Manganese oxide 20 Iron oxide 201 Copper oxide 20 Calcium carbide 201
  • box 2 is provided with a tube 8 which is doubled so as to fit hermetically with another tube of horizontal position l which passes through the lateral wall 8 of principal chamber I, so as to extend to the escape tube 9 of the motor (not shown), wherewith it forms, for example by means of fianges Ill, an hermetic connection.
  • Principal chamber I at the side opposed to lateral wall 8, is closed by a division II. Also said principal chamber I contains more or less up to two thirds of its height and surrounding box 2 and tubes 6 and i, a granulated filling of another chemical compound 32, the purpose of which is to absorb the carbon dioxide which is formed in box 2, as well as the other combustion gases.
  • Said compound may consist for example of a mixture of Per cent Calcium oxide 50 Iron sulphate 20 Caustic soda 30 Division II may be fixed to cylindrical wall I2 or" principal chamber I, for example, by means of a ring I3 combined with a groove I l, wherein equally will be retained a bell 55, in communication with principal chamber I by means of an opening I6 arranged at the upper part of division I I and protected by a metal web IT, preferably somewhat bulging towards principal chamber i. From said opening I6 there parts, descending obliquely, a tube I8 which ends at the center of bell 15 which is left open at its narrow hind-end I9, so that bell I5 forms a chamber 20 wherein a first retention of solid organic particles or corpuscles is produced.
  • the general body of the device formed in its first part by principal chamber I continues to extend to the other side, containing within its cylindrical walls I2 behind the first bell I5 a second hell 2! wherein first bell I5 encases, occupying the central part thereof with its open end I9.
  • contrary to first bell I5, is closed in the shape of a truncated cone by wall 22.
  • This second bell 2! is seated upon a horizontal division 22 which extends to the second body 24, and said second bell 2! furthermore is retained by clamps 25 fixed at 26 to the vertical Wall of said second body 2d.
  • the second body 24, which just has been mentioned, is fixed hermetically to the general body of the device, for example, by means of a ring 21 which within a groove 21 embraces the doubled ends of both walls of the two bodies, viz. of the general body and of second body 24.
  • Said connecting ring 21 will be divided into halves, being thus unmountable, and it can be adjusted hermetically by means of screwpins so as to form an absolutely hermetic union between both bodies.
  • This second body 24 contains a retention box for solid particles 29, and so as to retain said box 29 within the interior of body 24, said body, for example, may be provided with soldered legs 28.
  • Said box 29 will have as a wall metal webs 30, and to said walls 3! ⁇ preferably an oblique inclination will be given, such as shown in Figure 1.
  • second body 24 terminates in the outlet tube 3
  • Said gases pass from escape tube 9 of the engine through tube I continued by tube 6 to box 2 wherein they cross the layer of the granulated chemical compound 5, so as to pass through the perforated bottom 3 of said box 2 and get scattered, raising from pedestal 4 through the second layer of the other granulated chemical compound 32, so as to pass through opening I6 of division I I to tube I8, wherefrom, issuing at I9, they will 3 hit against back wall 22 of second bell 2
  • These runs and hits will provoke the precipitation of the solid particles which accumulate at bottom 20 of first bell l5, as well' as beneath second bell 2
  • a process for purifying the exhaust gases from internal combustion engines which comprises first treating said gases with an agent consisting of the following components in approximately the stated proportions: 20% potassium chlorate, 20% managanese oxide, 20% iron oxide, 20% copper oxide, and 20% calcium carbide, so as to transform the carbon monoxide present in the exhaust gases into carbon dioxide, and immediately thereafter treating said gases with an absorbing agent consisting of the following components in approximately the stated proportions: 50% calcium oxide, 20% iron sulphate, and 30% caustic soda.

Description

' B. BARINGOLTZ PROCESS FOR PURIFYING EXHAUST GASES Filed Dec. 8, 1942 INVENTOR Bmmwea BARmaoL-r;
7&4: ATTORNEY.
Patented Oct. 22, 1946 1 Claim.
The invention relates to a device which serves as a silencer and disintoxicator of the escape gases of internal combustion engines, which may be added advantageously at the escape tube of the engine, as it will not only enable to silence the noise produced by the combustion, but also to disintoxicate completely the escape gases, causing thus the disappearance of a highly felt, present inconvenience.
At continuation one constructive way of said device will be specified by means of a preferred example of execution of the invention, wherein Figure 1 is a vertical, longitudinal cut through the device,
Figure 2 a vertical view of the device seen from the left end of Figure 1, and
Figure 3 a similar vertical view of the device seen from the right end of Figure 1.
The novel device to which the invention relates, is preferably cylindrical in shape, although this is not indispensable, and it is composed of a principal chamber 5, wherein is inserted a box 2 of much smaller dimensions, provided with a perforated bottom 3' and reposing within principal chamber I upon frame or pedestal 4. Said chamber 2 will contain a filling 5 which consists of a granulated chemical compound which transforms the carbon oxide of the escape gases into carbon dioxide by catalytic oxidation; for example, it can be made up by a mixture which contains Per cent Potassium chlorate 20 Manganese oxide 20 Iron oxide 201 Copper oxide 20 Calcium carbide 201 In the middle of its top, box 2 is provided with a tube 8 which is doubled so as to fit hermetically with another tube of horizontal position l which passes through the lateral wall 8 of principal chamber I, so as to extend to the escape tube 9 of the motor (not shown), wherewith it forms, for example by means of fianges Ill, an hermetic connection.
Principal chamber I, at the side opposed to lateral wall 8, is closed by a division II. Also said principal chamber I contains more or less up to two thirds of its height and surrounding box 2 and tubes 6 and i, a granulated filling of another chemical compound 32, the purpose of which is to absorb the carbon dioxide which is formed in box 2, as well as the other combustion gases. Said compound may consist for example of a mixture of Per cent Calcium oxide 50 Iron sulphate 20 Caustic soda 30 Division II may be fixed to cylindrical wall I2 or" principal chamber I, for example, by means of a ring I3 combined with a groove I l, wherein equally will be retained a bell 55, in communication with principal chamber I by means of an opening I6 arranged at the upper part of division I I and protected by a metal web IT, preferably somewhat bulging towards principal chamber i. From said opening I6 there parts, descending obliquely, a tube I8 which ends at the center of bell 15 which is left open at its narrow hind-end I9, so that bell I5 forms a chamber 20 wherein a first retention of solid organic particles or corpuscles is produced.
The general body of the device formed in its first part by principal chamber I continues to extend to the other side, containing within its cylindrical walls I2 behind the first bell I5 a second hell 2! wherein first bell I5 encases, occupying the central part thereof with its open end I9. This second bell 2|, contrary to first bell I5, is closed in the shape of a truncated cone by wall 22. This second bell 2! is seated upon a horizontal division 22 which extends to the second body 24, and said second bell 2! furthermore is retained by clamps 25 fixed at 26 to the vertical Wall of said second body 2d.
The second body 24, which just has been mentioned, is fixed hermetically to the general body of the device, for example, by means of a ring 21 which within a groove 21 embraces the doubled ends of both walls of the two bodies, viz. of the general body and of second body 24. Said connecting ring 21 will be divided into halves, being thus unmountable, and it can be adjusted hermetically by means of screwpins so as to form an absolutely hermetic union between both bodies.
This second body 24 contains a retention box for solid particles 29, and so as to retain said box 29 within the interior of body 24, said body, for example, may be provided with soldered legs 28. Said box 29 will have as a wall metal webs 30, and to said walls 3!} preferably an oblique inclination will be given, such as shown in Figure 1. Finally, second body 24 terminates in the outlet tube 3| Wherethrough issue to the atmosphere only completely disintoxicated gases, the run of which through the device from escape tube 9 to said outlet tube 3| it is worth While to describe briefly.
Said gases pass from escape tube 9 of the engine through tube I continued by tube 6 to box 2 wherein they cross the layer of the granulated chemical compound 5, so as to pass through the perforated bottom 3 of said box 2 and get scattered, raising from pedestal 4 through the second layer of the other granulated chemical compound 32, so as to pass through opening I6 of division I I to tube I8, wherefrom, issuing at I9, they will 3 hit against back wall 22 of second bell 2|. These runs and hits will provoke the precipitation of the solid particles which accumulate at bottom 20 of first bell l5, as well' as beneath second bell 2|, whereas the light parts, viz., the gases, will raise along the upper wall of second hell 2! so as to pass to second body 24, wherein again they will meet with metal web walls 30 which serve for retaining the last solid particles which may have reached until there. To said. walls 30 the oblicuous inclination shown in Figure 1 has been given so as to lessen the hit of the gases against said walls 30, and, finally, after having passed also through said two walls 30, the purified gases, made innocuous, will escape through outlet tube 31.
I claim:
A process for purifying the exhaust gases from internal combustion engines, which comprises first treating said gases with an agent consisting of the following components in approximately the stated proportions: 20% potassium chlorate, 20% managanese oxide, 20% iron oxide, 20% copper oxide, and 20% calcium carbide, so as to transform the carbon monoxide present in the exhaust gases into carbon dioxide, and immediately thereafter treating said gases with an absorbing agent consisting of the following components in approximately the stated proportions: 50% calcium oxide, 20% iron sulphate, and 30% caustic soda.
BERNARDO BARINGOLTZ.
US468243A 1942-12-08 1942-12-08 Process for purifying exhaust gases Expired - Lifetime US2409825A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2831762A (en) * 1954-04-06 1958-04-22 Waagner Biro Ag Treating converter waste gases
US2877098A (en) * 1955-02-14 1959-03-10 Joseph P Ruth Apparatus for conditioning exhaust gases from internal combustion engines
US3054664A (en) * 1959-11-23 1962-09-18 Universal Oil Prod Co Apparatus for the catalytic conversion of vehicular exhaust gases
US3061416A (en) * 1957-11-22 1962-10-30 George P Kazokas Catalytic muffler
US3083083A (en) * 1959-07-31 1963-03-26 Boysen Friedrich Device for catalytically combusting ingredients of exhaust gases
US3802191A (en) * 1971-09-20 1974-04-09 R Fox Air pollution control unit for internal combustion engines
US3979906A (en) * 1974-08-02 1976-09-14 Staggs George W Anti-pollution exhaust system for vehicles
US20070113547A1 (en) * 2005-11-21 2007-05-24 Thaler David M Exhaust treatment device with condensate gate
US20120020854A1 (en) * 2010-02-24 2012-01-26 International Engine Intellectual Property Company Llc Method, system and apparatus for liquid injection into a gas system

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2831762A (en) * 1954-04-06 1958-04-22 Waagner Biro Ag Treating converter waste gases
US2877098A (en) * 1955-02-14 1959-03-10 Joseph P Ruth Apparatus for conditioning exhaust gases from internal combustion engines
US3061416A (en) * 1957-11-22 1962-10-30 George P Kazokas Catalytic muffler
US3083083A (en) * 1959-07-31 1963-03-26 Boysen Friedrich Device for catalytically combusting ingredients of exhaust gases
US3054664A (en) * 1959-11-23 1962-09-18 Universal Oil Prod Co Apparatus for the catalytic conversion of vehicular exhaust gases
US3068079A (en) * 1959-11-23 1962-12-11 Universal Oil Prod Co Apparatus for the conversion of exhaust gases
US3802191A (en) * 1971-09-20 1974-04-09 R Fox Air pollution control unit for internal combustion engines
US3979906A (en) * 1974-08-02 1976-09-14 Staggs George W Anti-pollution exhaust system for vehicles
US20070113547A1 (en) * 2005-11-21 2007-05-24 Thaler David M Exhaust treatment device with condensate gate
US20120020854A1 (en) * 2010-02-24 2012-01-26 International Engine Intellectual Property Company Llc Method, system and apparatus for liquid injection into a gas system
US8173088B2 (en) * 2010-02-24 2012-05-08 International Engine Intellectual Property Company, Llc Method, system and apparatus for liquid injection into a gas system

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