US2377106A - Lubricant and process for preparing and using same - Google Patents

Lubricant and process for preparing and using same Download PDF

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Publication number
US2377106A
US2377106A US463780A US46378042A US2377106A US 2377106 A US2377106 A US 2377106A US 463780 A US463780 A US 463780A US 46378042 A US46378042 A US 46378042A US 2377106 A US2377106 A US 2377106A
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oil
lubricant
melting point
viscosity
acid
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US463780A
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Reswick Maurice
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Standard Oil Development Co
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Standard Oil Development Co
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Priority to BE511978D priority Critical patent/BE511978A/xx
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Priority to US463780A priority patent/US2377106A/en
Priority to GB13136/43A priority patent/GB586839A/en
Application granted granted Critical
Publication of US2377106A publication Critical patent/US2377106A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14Synthetic waxes, e.g. polythene waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17Fisher Tropsch reaction products
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/286Esters of polymerised unsaturated acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Form in which the lubricant is applied to the material being lubricated semi-solid; greasy

Definitions

  • This invention relates to 'a novel lubricant and I to methods of preparing and using same. More particularly. it relates to a metal fabricating lubricant and especially toone which is adapted for lubrication of sheet steel, etc., as it is being processed in high speed cold rolling mills. product of this invention is intended to be used also as a replacement for palm oil which has largely been used heretofore by' the steel mills-for such purposes. p In the cold rolling of steel sheets and strip on when dies and presses are used.
  • palm oil is that it is a solid or a semi-solid at room. temperatures but when heated to over ,120
  • the primary object of the present invention is to provide a metalfabricating lubricant which so nearly resembles palm oil in physical and chemical properties that in actual commercial operations in the steelmills where it is vitally -'important to have a high speed sheet steel lubricant having exactly the right combination of viscosity,
  • The. heavy mineral oil may bederived from any available crude.
  • Foots oil which usually contains about 45%50% of wax having a melting point of from 100 to 120, usually'has a-pour point of about 90F.
  • the preferred fatty acid for the purposes of this invention is a hydrogenated fish oil acid such as marketed under the trade name of"Hydrofol Acid 51," although other high molecular weight organic acids, in addition to those mentioned above, may be used such as cottonseed "stearic acid, palmitic acid.
  • Foots oil 40 to 60% preferably 45 to 55% 'Petrolatum .5 to 30% preferably 15 to 25% Heavy mineral.
  • oil 5 to 25% preferably -to Fat 5 to preferably 10 to 15% Fatty acid 2 to 20% preferably 5 to 15% oil acids,
  • foots oil is that the low viscosity oil is ideal for high speed rolling operations, which now go up as high as 3000 ft. per minute.
  • the wax content of foots oil imparts to the compound a high cold test so that it acts in this respect in the same manner as palm oil.
  • Hydrofol Tinfat is a hydrogenated fish oil containing less than 20% of acids of 020 to C22, the balance being mostly C18 to Cm, and it is suitable for lubrication at high temperatures. It has a low iodine number and in this respect it is superior to common tallow.
  • Hydrofol Acid 51 is also a hydrogenated fish oil similar to the Hydrofol Tinfat with the glycerides removed.
  • the purpose of this fatty acid is to Foots oil- Pour point F 70 Wax content (110 M. Pt.) per cent 48 Oil content (80 secs. vis. at 100 F.) per cent 52 Hydrofol Tinfat Melting point f F 130 Saponification value 190 Iodine value Hydrofol Acid 51- Saponification No 194 Acid No 194 Iodine No 6 Titre C 52 Crude petrolatum, melting point F 130 Cylinder oil Vis., Saybolt 100 F seconds 3200 vis., Saybolt 210 F do 155
  • the finished compounded product identified above as Example 1 had the, following characteristics:
  • Foots oil as one of the principal components is to act as a vehicle for the other ingredients. Foots oil is a by-product in the manufacture of petroleum waxes and consists Y to actually shear it off.
  • the liquid lubricant loses its fluidity, becoming more viscous and the copious flow of cold water, also usually applied to the rolls, assistsin cooling the lubricant without washing it ofi, so long as the pressure of the water stream is not high enough
  • the sheet metal such as thin sheet steel actually goes through the work rolls, it becomes coated with the lubricant, but at the same time it is subjected to mechanical working during the reduction in thickness and at the contact area of the work rolls with the sheet strip, the temperature of the strip becomes sufilciently high to change the water into a cloud of steam and to liquefy the lubricant in a thin the thickness gauge at the start and finish of the rolling andhow much reduction is made in each individual pass; the surface finish desired, the
  • this metal-fabricating lubricant may be recovered for re-use by a relatively simple system of salvaging and reconditioning.
  • Thisinvolves merely collecting the oil, which is generally mixed with water and perhaps dust and fine iron scaleparticles, in a trench or ture from there, preferably through a %-incl 1 mesh screen, into a settling tank. heating it under slight superatmospheric pressure, if desired toa temperature at least as high as 150 F. and preferably somewhat higher such as 200 and 250 F. in order to settle out the water and coarse foreign particles, and then drawing off the clarified oil. If desired; this clarified oil may be further refined by centrifuging.
  • a normally solid metal-fabricating lubricant having a melting point between about 95 F. and about 110 F., a viscosity of about to second Saybolt at 210 F., comprising about 45-55% by weight of foots oil, about 15-25% of petrolatum, about 10-15% of heavy mineral oil having a viscosity of about 100 to 350 seconds Saybolt at 210 F., about 1015% of a fat and about 515% of a higher fatty acid.
  • Anormally'solid metal-fabricating lubricant having a melting point between about 95 F. and about 110 F.,' adapted for cold rolling of sheet steel at a speed .of at least 1500 feet per minute,
  • a viscosity of about 40 to 60 seconds Saybolt at 210 F. comprising about 40-60% a by weight of foots oil, said lubricant also containing about 10-30% of petrolatum, about 5-25% of heavy mineral oil having a viscosity of about 100 to 350 seconds Saybolt at 210 F., about 5-20% of a fat and about 2-20% of a higher fatty acid.
  • a normally solid metal-fabricating lubricant Saybolt at 210 F. about 1015% of hydrogenatedabout 515% of hydrogenated fish oil having a melting point between about 95 F. and' about 110 F., adapted for cold rolling of sheet steel at a speed of at least 1500 feet per minute, comprising about 50% by weight of foots oil having a pour point of about 70 F. to about 90 F. and-containing about 48% of wax having a melting point of from 100 F. to 120 F., in 52% of an oil having a viscosity of about 80 seconds Saybolt at 100 F., said lubricant also containing about 20% of petrolatum having a melting point of about 90 F. to 130 F., about 10% of a cylinvtier oil having a viscosity of about 3200 seconds Saybolt at 100 F. and about seconds Saybolt at 210 E, about 10% of a hydrogenated fish oil acid.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
US463780A 1942-10-29 1942-10-29 Lubricant and process for preparing and using same Expired - Lifetime US2377106A (en)

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BE511978D BE511978A (en, 2012) 1942-10-29
US463780A US2377106A (en) 1942-10-29 1942-10-29 Lubricant and process for preparing and using same
GB13136/43A GB586839A (en) 1942-10-29 1943-08-13 Improvements in or relating to normally solid metal-fabricating lubricants

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2565938A (en) * 1949-05-11 1951-08-28 Ironsides Company Lubricant metal-rolling composition
US3223635A (en) * 1964-04-06 1965-12-14 Far Best Corp Coolant and lubricant composition and method for cold working metal
US3429815A (en) * 1965-10-08 1969-02-25 Bethlehem Steel Corp Rolling oils
US6284007B1 (en) * 1998-08-12 2001-09-04 Indiana Soybean Board, Inc. Vegetable lipid-based composition and candle
US20030046860A1 (en) * 2001-08-02 2003-03-13 Archer Daniels Midland Co. Vegetable fat-based candles
US20030061760A1 (en) * 2001-03-08 2003-04-03 Bernard Tao Vegetable lipid-based composition and candle
US6730137B2 (en) * 2001-11-14 2004-05-04 Bath & Body Works, Inc. Vegetable oil candle

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4191801A (en) 1977-02-08 1980-03-04 The Lubrizol Corporation Hot melt metal working lubricants

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2565938A (en) * 1949-05-11 1951-08-28 Ironsides Company Lubricant metal-rolling composition
US3223635A (en) * 1964-04-06 1965-12-14 Far Best Corp Coolant and lubricant composition and method for cold working metal
US3429815A (en) * 1965-10-08 1969-02-25 Bethlehem Steel Corp Rolling oils
US20080138753A1 (en) * 1998-08-12 2008-06-12 Bernard Tao Vegetable lipid-based composition and candle
US6497735B2 (en) 1998-08-12 2002-12-24 Indiana Soybean Board Vegetable lipid-based composition and candle
US20040200136A1 (en) * 1998-08-12 2004-10-14 Indiana Soybean Board, Inc. Vegetable lipid-based composition and candle
US6284007B1 (en) * 1998-08-12 2001-09-04 Indiana Soybean Board, Inc. Vegetable lipid-based composition and candle
US7387649B2 (en) 1998-08-12 2008-06-17 Tao Bernard Y Vegetable lipid-based composition and candle
US7569084B2 (en) 1998-08-12 2009-08-04 Bernard Tao Vegetable lipid-based composition and candle
US7731767B2 (en) 1998-08-12 2010-06-08 Indiana Soybean Board, Inc. Vegetable lipid-based composition and candle
US8137418B2 (en) 1998-08-12 2012-03-20 Indiana Soybean Alliance Vegetable lipid-based composition and candle
US8404003B2 (en) 1998-08-12 2013-03-26 Indiana Soybean Board, Inc. Vegetable lipid-based composition and candle
US20030061760A1 (en) * 2001-03-08 2003-04-03 Bernard Tao Vegetable lipid-based composition and candle
US20030046860A1 (en) * 2001-08-02 2003-03-13 Archer Daniels Midland Co. Vegetable fat-based candles
US6730137B2 (en) * 2001-11-14 2004-05-04 Bath & Body Works, Inc. Vegetable oil candle

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