US2317965A - Process of coloring fibrous materials and the materials obtained thereby - Google Patents

Process of coloring fibrous materials and the materials obtained thereby Download PDF

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Publication number
US2317965A
US2317965A US332015A US33201540A US2317965A US 2317965 A US2317965 A US 2317965A US 332015 A US332015 A US 332015A US 33201540 A US33201540 A US 33201540A US 2317965 A US2317965 A US 2317965A
Authority
US
United States
Prior art keywords
dyeing
dyed
materials
acid
washing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US332015A
Other languages
English (en)
Inventor
Bestian Herbert
Nusslein Joseph
Monheim Josef
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
General Aniline and Film Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Aniline and Film Corp filed Critical General Aniline and Film Corp
Application granted granted Critical
Publication of US2317965A publication Critical patent/US2317965A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D203/00—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D203/04—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D203/06—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D203/16—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with acylated ring nitrogen atoms
    • C07D203/20—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with acylated ring nitrogen atoms by carbonic acid, or by sulfur or nitrogen analogues thereof, e.g. carbamates
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/487—Aziridinylphosphines; Aziridinylphosphine-oxides or sulfides; Carbonylaziridinyl or carbonylbisaziridinyl compounds; Sulfonylaziridinyl or sulfonylbisaziridinyl compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/10—Polyvinyl halide esters or alcohol fiber modification
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/21—Nylon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y10T442/2197—Nitrogen containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2352—Coating or impregnation functions to soften the feel of or improve the "hand" of the fabric

Definitions

  • the said products are partly water-soluble and may be applied to the fibrous material in an aqueous solution.
  • the compounds are insoluble or diificultly soluble in water they may be used in the form of their aqueous suspensions or their solutions in organic solvents; also products which'have already been partially polymerized may, if desired, be applied to the material.
  • the compounds are polymerized, suitably by a heat treatment, for instance at 100 C. -l60 C. or a higher temperature, and in this way are incorporated with the fibrous material in a water- Cotton or regenerated cellulose may thus be treated with the compounds according to the above-named formula which are to be considered as urea derivatives, and the compounds may be polymerized on the fiber. In this manner a material is obtained which possesses an increased absorption capacity for acid wool dyestuffs.
  • the cellulose fibers thus pre-treated also show an improved afiinity for the ordinary cotton dyestuffs, the so-called substantive dyestuffs, and the fastness to water and to washing of the dyeings thus obtained is considerably-improved.
  • fibrous materials there are suitable fibers of vegetable or animal origin, furthermore fibers from regenerated cellulose or cellulose derivatives, also mineral or synthetic fibers, for instance glass or asbestos fibers, polyamide and polyvinyl chloride fibers and likewise leathers and hides.
  • the above-named products may likewise be applied on textile materials simultaneously with dyeing bodies and then firmly be fixed on the material by a thermal after-treatment.
  • there may be'obtained vivid dyeings and prints for instance by padding, spraying and printing fabrics from cotton or regenerated cellulose with solutions or suspensions of acid wool V dyestufl's and of urea derivatives which, when dyestuifs capable of being discharged are used, may be discharged-in known manner so as to obtain white or colored effects.
  • aqueous solutions of the products named are mixed with pigments such as titanium dioxide, soot, ultramarine, iron oxide or organic pigments such as azo-dyestufis insoluble in waymerization of the urea compounds the pigments are firmly fixed on the material;
  • the dyeings or prints so obtained are very stable against the usual ashing processes. It is not always necessary apply to the fibrous material a mixture of the pigment dyestufl! and the urea derivative, but the pigment dyestuif may also be prepadded, dried and cross-padded with the solution of the urea derivative.
  • This process of fixing pigments on fibrous materials is especially suitable for uniformly coloring mixed fabrics or mixed structures, for instance union or halfsilk or mixtures from regenerated cellulose and other fibrous materials which do not possess uniform aflinity for dyestuffs.
  • the hydrogen atoms of the ethylene groups may partly or entirely be substituted by methyl, ethyl, propyl, isopropyl, butyl, isobutyl, amyl, isoamyl, decyl, furthermore by phenyl, the methylphenyl radicals, benzyl and orth0, meta and -para-to1yl.
  • Two, three or all of the four hydrogen atoms may likewise be substituted by two, three or four different substituents asnamed above.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US332015A 1939-05-27 1940-04-27 Process of coloring fibrous materials and the materials obtained thereby Expired - Lifetime US2317965A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2314968X 1939-05-27

Publications (1)

Publication Number Publication Date
US2317965A true US2317965A (en) 1943-04-27

Family

ID=7994539

Family Applications (2)

Application Number Title Priority Date Filing Date
US332014A Expired - Lifetime US2314968A (en) 1939-05-27 1940-04-27 Process of impregnating textile materials and the material thus obtained
US332015A Expired - Lifetime US2317965A (en) 1939-05-27 1940-04-27 Process of coloring fibrous materials and the materials obtained thereby

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US332014A Expired - Lifetime US2314968A (en) 1939-05-27 1940-04-27 Process of impregnating textile materials and the material thus obtained

Country Status (4)

Country Link
US (2) US2314968A (fr)
BE (2) BE439195A (fr)
FR (2) FR865869A (fr)
NL (1) NL54564C (fr)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2458397A (en) * 1943-11-18 1949-01-04 Courtaulds Ltd Dyeing of nylon fibers by treating with nitrogenous condensation products
US2462428A (en) * 1943-10-29 1949-02-22 Ciba Ltd Process of dyeing glass fibers
US2893892A (en) * 1953-12-10 1959-07-07 Ct Tech Ind Dit I Textile De F Method for the coating of glass threads and tissues with artificial resin
US2908543A (en) * 1956-06-29 1959-10-13 Gen Aniline & Film Corp Aftertreatment of leather dyeings
US2922723A (en) * 1957-01-31 1960-01-26 Johnson & Johnson Product and method of manufacture
US2925313A (en) * 1957-04-29 1960-02-16 Union Carbide Corp Siloxane azo dyestuffs
US2925314A (en) * 1954-02-05 1960-02-16 Basf Ag Process of dyeing and printing cellulose derivatives
US2927839A (en) * 1957-04-29 1960-03-08 Union Carbide Corp Siloxane azo dyestuffs
US2931693A (en) * 1957-04-29 1960-04-05 Union Carbide Corp Silicon azo dyestuff and fibers dyed therewith
US2933416A (en) * 1960-04-19 Process for fixing figments on
US2955053A (en) * 1958-08-20 1960-10-04 Hess Goldsmith & Company Process for selectively coloring glass fabric and resultant article
US2955898A (en) * 1957-04-29 1960-10-11 Union Carbide Corp Thiazine dyestuffs and process of dyeing fibrous material
US2957744A (en) * 1957-04-29 1960-10-25 Union Carbide Corp Silicon-containing ice colors
US2961349A (en) * 1956-08-21 1960-11-22 Hoechst Ag Process for fixing pigments on fibrous materials
US3038776A (en) * 1960-05-17 1962-06-12 Leon H Chance Wrinkle resistant cellulose textiles and processes for producing same
US3079209A (en) * 1960-05-24 1963-02-26 Marble Products Company Of Geo Dyeing natural stones and shells with oil soluble dyes
US3295916A (en) * 1965-09-27 1967-01-03 Allied Chem Production of wash fast colorations with water-soluble metallized azo dyes
US3388964A (en) * 1965-08-19 1968-06-18 Agriculture Usa Shrinkproofing wool with dhsocyanates and ethylenimine

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1068657A (fr) * 1951-06-28 1954-06-30 Bayer Ag Procédé pour rendre hydrofuges des textiles, etc.
US2764504A (en) * 1952-08-28 1956-09-25 Du Pont Coating process and products therefrom
US2764503A (en) * 1952-08-28 1956-09-25 Du Pont Coating fabrics
BE575304A (fr) * 1958-02-10 1900-01-01
US3148164A (en) * 1961-04-21 1964-09-08 Pfersee Chem Fab Means for making textiles water resistant
DE1213373B (de) * 1961-04-22 1966-03-31 Pfersee Chem Fab Hydrophobiermittel fuer Textilien aller Art
US3150000A (en) * 1961-06-24 1964-09-22 Pfersee Chem Fab Method and means for treating textiles
US3232790A (en) * 1961-06-24 1966-02-01 Pfersee Chem Fab Method for treating textile with perfluoroalkyl compounds and the treated textile
US3274174A (en) * 1962-02-14 1966-09-20 Pfersee Chem Fab N-1, 1-dihydrofluoroalkyl-n'-alkylene urea
US3535141A (en) * 1967-04-17 1970-10-20 Deering Milliken Res Corp Process for making sail release synthetic textile
US4011613A (en) * 1975-11-18 1977-03-15 The United States Of America As Represented By The Secretary Of Agriculture Durable-press properties in cotton containing fabrics via polymeric N-methylol reagents
JPS595703B2 (ja) 1981-12-02 1984-02-06 大和化学工業株式会社 繊維製品類の耐洗濯性衛生加工方法
US4696760A (en) * 1983-12-08 1987-09-29 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for production of aqueous dispersion of N-substituted N',N'-alkylene urea

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2933416A (en) * 1960-04-19 Process for fixing figments on
US2462428A (en) * 1943-10-29 1949-02-22 Ciba Ltd Process of dyeing glass fibers
US2458397A (en) * 1943-11-18 1949-01-04 Courtaulds Ltd Dyeing of nylon fibers by treating with nitrogenous condensation products
US2893892A (en) * 1953-12-10 1959-07-07 Ct Tech Ind Dit I Textile De F Method for the coating of glass threads and tissues with artificial resin
US2925314A (en) * 1954-02-05 1960-02-16 Basf Ag Process of dyeing and printing cellulose derivatives
US2908543A (en) * 1956-06-29 1959-10-13 Gen Aniline & Film Corp Aftertreatment of leather dyeings
US2961349A (en) * 1956-08-21 1960-11-22 Hoechst Ag Process for fixing pigments on fibrous materials
US2922723A (en) * 1957-01-31 1960-01-26 Johnson & Johnson Product and method of manufacture
US2931693A (en) * 1957-04-29 1960-04-05 Union Carbide Corp Silicon azo dyestuff and fibers dyed therewith
US2927839A (en) * 1957-04-29 1960-03-08 Union Carbide Corp Siloxane azo dyestuffs
US2955898A (en) * 1957-04-29 1960-10-11 Union Carbide Corp Thiazine dyestuffs and process of dyeing fibrous material
US2957744A (en) * 1957-04-29 1960-10-25 Union Carbide Corp Silicon-containing ice colors
US2925313A (en) * 1957-04-29 1960-02-16 Union Carbide Corp Siloxane azo dyestuffs
US2955053A (en) * 1958-08-20 1960-10-04 Hess Goldsmith & Company Process for selectively coloring glass fabric and resultant article
US3038776A (en) * 1960-05-17 1962-06-12 Leon H Chance Wrinkle resistant cellulose textiles and processes for producing same
US3079209A (en) * 1960-05-24 1963-02-26 Marble Products Company Of Geo Dyeing natural stones and shells with oil soluble dyes
US3388964A (en) * 1965-08-19 1968-06-18 Agriculture Usa Shrinkproofing wool with dhsocyanates and ethylenimine
US3295916A (en) * 1965-09-27 1967-01-03 Allied Chem Production of wash fast colorations with water-soluble metallized azo dyes

Also Published As

Publication number Publication date
NL54564C (fr) 1943-05-15
BE439195A (fr) 1940-08-31
FR879159A (fr) 1943-02-16
US2314968A (en) 1943-03-30
BE441247A (fr) 1941-04-30
FR865869A (fr) 1941-06-06

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