US2280618A - Electric gaseous discharge device - Google Patents
Electric gaseous discharge device Download PDFInfo
- Publication number
- US2280618A US2280618A US263763A US26376339A US2280618A US 2280618 A US2280618 A US 2280618A US 263763 A US263763 A US 263763A US 26376339 A US26376339 A US 26376339A US 2280618 A US2280618 A US 2280618A
- Authority
- US
- United States
- Prior art keywords
- tube
- gas
- mercury
- amalgam
- vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007789 gas Substances 0.000 description 41
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 21
- 229910000497 Amalgam Inorganic materials 0.000 description 19
- 208000028659 discharge Diseases 0.000 description 15
- 229910052753 mercury Inorganic materials 0.000 description 14
- 229910052754 neon Inorganic materials 0.000 description 7
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 7
- 229910052724 xenon Inorganic materials 0.000 description 5
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000008246 gaseous mixture Substances 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 241001420622 Meris Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/24—Means for obtaining or maintaining the desired pressure within the vessel
- H01J61/28—Means for producing, introducing, or replenishing gas or vapour during operation of the lamp
Definitions
- the present invention relates to electric gas eous discharge devices and particularly to those devices in which a critical mixture of gases or vapors is utilized to permit starting of a dis charge at a low potential.
- a particular object of the invention is to provide means whereby such a critical mixture of gases may be maintained substantially constant throughout the life of the device.
- Another object of the invention is to provide means to feed gas to a tube at a substantially constant rate to compensate for gas lost to the tube through the from an inspection of the accompanying drawing.
- the invention consists in the new and novel combination of elements hereinafter set forth Discharge tubes with a gaseous atmosphere containing a rare main gas and a slight proportion of at' least one auxiliary rare gas or metal vapor, are well known.-
- Discharge tubes with a gaseous atmosphere containing a rare main gas and a slight proportion of at' least one auxiliary rare gas or metal vapor, are well known.
- auxiliary gas applies to the latter of-these two: gases; thus, in order to lower the starting potential of a discharge tube, there is added vto the main rare gas a trace of an auxiliary gas whose ionization potential is lower'than the excitation potential for the metastable state of the main gas.
- auxiliary gas in order to lower the starting potential of a discharge tube, there is added vto the main rare gas a trace of an auxiliary gas whose ionization potential is lower'than the excitation potential for the metastable state of the main gas.
- auxiliary gas in order to lower the starting potential of a discharge tube, there is added vto the main rare gas a trace of an auxiliary gas whose ionization potential is lower'than the excitation potential for the metastable state of the main gas.
- xenon, krypton, argon, ormercury vapor in the case of a neon tube, one adds xenon, krypton, argon, ormercury vapor.
- auxiliary gas it has been found that it is possible to overcome the disappearance of the auxiliary gas by placing the tube atmosphere in permanent contact with a body that retains auxiliary gas at the time of its introduction in thetube, and which, together with that auxiliary gas, brings about a system of. chemical divariant equilibrium, which admits as a gaseous phase, said gas or vapor.
- the nongaseous phase of that system preferably consists, in the case of an auxiliary rare gas, of a silica gel, active carbon, alumina, or the. like, which has adsorbed that gas.
- the nongaseous phase preferably'consistsof an alloy of suitable dissociation potential, especially zinc or tin amalgam, for instance with 10, per cent zinc or tin, if it is requiredto'lower the. starting-poten- .tial of .the. tube. it is preferably to prepare it by fusion, since the Wherea'n amalgam is used,
- contact-type amalgam may permit a relatively important amount of free mercury to subsist, whose excessive tension would make the lumi lawn emission of, mercury predominant;
- thepres'sure of equilibrium of the gas retaining body may .gb'e selected in such a way that the quantity of 'liberated'gas or vapor' v that iabsorbed in the will be slightly l ower ihan" 7 tube. durlng-operation.g
- this speed is the higherwthe lower the gaseous pressure which intervenes in adsorbed xenon and this tends to re-establish continuously the xenon pressure, which otherthat equilibrium, and the higher the relative-- pressure variation due to the absorption in the tube of the auxiliary gaseous atmosphere.
- Figs. 1, 2 and 3 show discharge devices con: taining amalgam, and represent various methods of arranging thatamalgam in the tube:
- Fig. 4 shows a device utilizing an auxiliary rare gas.
- the amalgam when used, the latter, which is represented at 3, may be placed in the sealing tube 2, of the discharge tube I, and outside (Fig. 1) or inside (Fig. 2) of this tube.
- the amalgam may be also placed in a perforated glass ball 4, arranged within the tube (Fig. 3), or directly in the tube (not shown).
- the only condition to be met is to avoid that the amalgam may lodge itself on the electrode, where, in view of the high temperature reigning there, it would be likely to become toorapidly dissociated. It is nevertheless possible to take even that case into consideration, when electrodes of large surface areas are used, provided the amalgam is placed at the far end of the electrode. In the case where the device is used for bringing about a reduction in the striking voltage, the following phenomena occur: At the start. the neon tube.
- the neon tube which I have shown is provided with an appendix I which is closed within the tube by a very fine point 0, and which terminates at the other extremity by a stem I.
- the carbon may be purged under vacuum, by suitable heating. After the carbon wise would decrease as time goes on. A few grams of carbon will insure a. sufficient pressure for several thousand operating hours.
- An electric gaseous discharge device com-- prising -a sealed envelope containing a rare gas intermixed with a critically small percentage of another gaseous element having a lower ionizing potential than the metastable potential of the rare gas to lower the starting potential of said device and an additional supply of said gaseous element located out of the path of the discharge within said envelope and .bonded to another element in such a manner that its gaseous pressure is "reduced prior to the initiation of a discharge in said device,'to a value substantially equal to the partial pressure of the critically small percentage thereof required for lowering the starting potential of the device, the quantity of said gaseous element evolved from said bonded supply being less than the quantity thereof lost by clean-up during operation of the device whereby said device has the low starting potential characteristic of the gaseous mixture and emits light characteristic of the rare gas during operation.
- An electric gaseous discharge device comprising a sealed envelope containing a principal gas intermixed with a critically small percentage of mercury vapor, the metastable potential of the principal gas being higher than the ionizing potential of the mercury vapor, said mercury vapor lowering the starting potential of said device, the partial pressure of said mercury vapor being less than that corresponding to mercury at room temperature, and an amalgam within said envelope at a point where it is not directly exposed to said discharge, the vapor pressure of the mercury in said amalgam being substantially equal to thepartial pressure of said mercury in the vapor-phase.
- the quantity of mercury evolved from said amalgam being less than the quantity of mercury lost by clean-up during the operation of the device.-wherebysaid device has the low starting potential character-. istic of the gaseous mixture and emits light characteristic of the principal gas duringoperation.
- xenon is introduced in 8 under a pressure of several mm. of mercury, after which the stem 1 is sealed.
- the discharge tube is now closed in the well known manner and, the electrodes and the tube being thoroughly freed of gas, a high vacuum is produced in the tube by means of the evacuating stem I.
- point I is broken in vacuum by any well known means (steel ball or high frequency), and one. adds the xenon, through pumping, into the tube, until the desired pressure is obtained (a few hundredths of a mm. if it is desired to' bring about a lowering of the starting potentiah a few tenths oi a mm. if.
- An electric gaseous discharge device comprising a sealed envelope containing neon intermixed with a critically small percentage of mercury vapor, the partial pressure of said mercury cury at room temperature and an amalgam within said'envelope at a point where it is not directly exposed to said discharge, the vaporpressure of the mercury in said amalgam being substantially equal to the partial pressure of said mercury in the vapor phase prior to the initiation of a discharge in said device, the quantity" of mercury evolved from said amalgam being less than the quantity of mercury lost by clean-up during operation of the device, whereby the device has the low starting potential characteristic of the gaseous mixture and emits light characteristic of the neon during operation.
Landscapes
- Discharge Lamp (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH588707X | 1938-03-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2280618A true US2280618A (en) | 1942-04-21 |
Family
ID=4521985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US263763A Expired - Lifetime US2280618A (en) | 1938-03-25 | 1939-03-23 | Electric gaseous discharge device |
Country Status (7)
Country | Link |
---|---|
US (1) | US2280618A (enrdf_load_stackoverflow) |
BE (1) | BE433316A (enrdf_load_stackoverflow) |
CH (1) | CH217337A (enrdf_load_stackoverflow) |
DE (1) | DE734790C (enrdf_load_stackoverflow) |
FR (1) | FR852066A (enrdf_load_stackoverflow) |
GB (1) | GB588707A (enrdf_load_stackoverflow) |
NL (1) | NL53407C (enrdf_load_stackoverflow) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3025745A (en) * | 1953-06-30 | 1962-03-20 | Beckman Instruments Inc | Method and apparatus for analyzing gases |
US3331977A (en) * | 1965-03-15 | 1967-07-18 | Westinghouse Electric Corp | High output discharge lamp with vapor pressure control means |
US3373303A (en) * | 1965-04-29 | 1968-03-12 | Westinghouse Electric Corp | Amalgam-containing fluorescent lamp with integral starting aid |
US3504215A (en) * | 1967-11-30 | 1970-03-31 | Westinghouse Electric Corp | Planar fluorescent lamp with integral amalgam type mercury-vapor pressure control component |
US3675067A (en) * | 1968-02-02 | 1972-07-04 | Csf | Optical resonance cell with means for regulating internal vapor pressure |
US3688148A (en) * | 1970-11-17 | 1972-08-29 | Anatoly Stepanovich Fedorenko | Amalgam housing means for a fluorescent lamp |
US3855543A (en) * | 1972-02-21 | 1974-12-17 | Philips Corp | Device for producing stimulated infrared emission |
US3898720A (en) * | 1972-09-28 | 1975-08-12 | Westinghouse Electric Corp | Method of providing a fluorescent lamp stem with an integral mercury-vapor pressure regulating means |
US4020378A (en) * | 1972-09-28 | 1977-04-26 | Westinghouse Electric Corporation | Integral mercury-vapor pressure regulating means for fluorescent lamp |
US4145634A (en) * | 1978-02-17 | 1979-03-20 | Westinghouse Electric Corp. | Fluorescent lamp having integral mercury-vapor pressure control means |
US4393325A (en) * | 1979-08-15 | 1983-07-12 | U.S. Philips Corporation | Low-pressure mercury vapor discharge lamp with mercury amalgam |
US20070216308A1 (en) * | 2006-03-16 | 2007-09-20 | Kiermaier Ludwig P | Lamp electrode and method for delivering mercury |
US20070216282A1 (en) * | 2006-03-16 | 2007-09-20 | Kiermaier Ludwig P | Lamp electrode and method for delivering mercury |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1086804B (de) * | 1958-04-29 | 1960-08-11 | Patra Patent Treuhand | Elektrische Quecksilberniederdruckentladungslampe, insbesondere Leuchtstofflampe |
NL7903285A (nl) * | 1979-04-26 | 1980-10-28 | Philips Nv | Ontladingslamp. |
NL7903286A (nl) * | 1979-04-26 | 1980-10-28 | Philips Nv | Ontladingsbuis. |
-
0
- BE BE433316D patent/BE433316A/xx unknown
- NL NL53407D patent/NL53407C/xx active
-
1938
- 1938-03-25 CH CH217337D patent/CH217337A/fr unknown
-
1939
- 1939-03-11 GB GB7938/39A patent/GB588707A/en not_active Expired
- 1939-03-16 DE DES136323D patent/DE734790C/de not_active Expired
- 1939-03-23 US US263763A patent/US2280618A/en not_active Expired - Lifetime
- 1939-03-24 FR FR852066D patent/FR852066A/fr not_active Expired
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3025745A (en) * | 1953-06-30 | 1962-03-20 | Beckman Instruments Inc | Method and apparatus for analyzing gases |
US3331977A (en) * | 1965-03-15 | 1967-07-18 | Westinghouse Electric Corp | High output discharge lamp with vapor pressure control means |
US3373303A (en) * | 1965-04-29 | 1968-03-12 | Westinghouse Electric Corp | Amalgam-containing fluorescent lamp with integral starting aid |
US3504215A (en) * | 1967-11-30 | 1970-03-31 | Westinghouse Electric Corp | Planar fluorescent lamp with integral amalgam type mercury-vapor pressure control component |
US3675067A (en) * | 1968-02-02 | 1972-07-04 | Csf | Optical resonance cell with means for regulating internal vapor pressure |
US3688148A (en) * | 1970-11-17 | 1972-08-29 | Anatoly Stepanovich Fedorenko | Amalgam housing means for a fluorescent lamp |
US3855543A (en) * | 1972-02-21 | 1974-12-17 | Philips Corp | Device for producing stimulated infrared emission |
US3898720A (en) * | 1972-09-28 | 1975-08-12 | Westinghouse Electric Corp | Method of providing a fluorescent lamp stem with an integral mercury-vapor pressure regulating means |
US4020378A (en) * | 1972-09-28 | 1977-04-26 | Westinghouse Electric Corporation | Integral mercury-vapor pressure regulating means for fluorescent lamp |
US4145634A (en) * | 1978-02-17 | 1979-03-20 | Westinghouse Electric Corp. | Fluorescent lamp having integral mercury-vapor pressure control means |
US4393325A (en) * | 1979-08-15 | 1983-07-12 | U.S. Philips Corporation | Low-pressure mercury vapor discharge lamp with mercury amalgam |
US20070216308A1 (en) * | 2006-03-16 | 2007-09-20 | Kiermaier Ludwig P | Lamp electrode and method for delivering mercury |
US20070216282A1 (en) * | 2006-03-16 | 2007-09-20 | Kiermaier Ludwig P | Lamp electrode and method for delivering mercury |
US7288882B1 (en) | 2006-03-16 | 2007-10-30 | E.G.L. Company Inc. | Lamp electrode and method for delivering mercury |
Also Published As
Publication number | Publication date |
---|---|
GB588707A (en) | 1947-06-02 |
FR852066A (fr) | 1940-01-23 |
DE734790C (de) | 1943-04-24 |
BE433316A (enrdf_load_stackoverflow) | |
NL53407C (enrdf_load_stackoverflow) | |
CH217337A (fr) | 1941-10-15 |
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