US226447A - Jambs polet - Google Patents
Jambs polet Download PDFInfo
- Publication number
- US226447A US226447A US226447DA US226447A US 226447 A US226447 A US 226447A US 226447D A US226447D A US 226447DA US 226447 A US226447 A US 226447A
- Authority
- US
- United States
- Prior art keywords
- hides
- skins
- hair
- sulphide
- barium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 210000003491 Skin Anatomy 0.000 description 32
- 210000004209 Hair Anatomy 0.000 description 22
- UCKMPCXJQFINFW-UHFFFAOYSA-N sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 20
- 229910052788 barium Inorganic materials 0.000 description 16
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium(0) Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 16
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 14
- 235000015450 Tilia cordata Nutrition 0.000 description 14
- 235000011941 Tilia x europaea Nutrition 0.000 description 14
- 239000004571 lime Substances 0.000 description 14
- 210000002615 Epidermis Anatomy 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 210000002268 Wool Anatomy 0.000 description 6
- 239000010985 leather Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920001864 tannin Polymers 0.000 description 4
- 235000018553 tannin Nutrition 0.000 description 4
- 239000001648 tannin Substances 0.000 description 4
- 210000001519 tissues Anatomy 0.000 description 4
- QVQLCTNNEUAWMS-UHFFFAOYSA-N Barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 210000004369 Blood Anatomy 0.000 description 2
- 239000001828 Gelatine Substances 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 229920002253 Tannate Polymers 0.000 description 2
- 229910001864 baryta Inorganic materials 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000000266 injurious Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003307 slaughter Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/06—Facilitating unhairing, e.g. by painting, by liming
Definitions
- This invention relates to removing the hair and epidermis from hides and skins of every description and however cured, softening dried and cured hides and skins, and separating the wool and hair from skinsin their natural state.
- solutions of sulphide of barium of varying strengths prepared by dissolving in water solid sulphide of barium, produced by heating finely-ground sulphate of baryta mixed with carbonaceous substances to about a white heat in a 'reverberatory furnace or other suitable appliance.
- My invention has a great many advantages over the present liming process and all processes now in use for removinghair from hides and skins and softening them, and among others the following: No part of the gelatinous tissue, grain, or substance of the hide is removed or disturbed. Hides and skins are left in their natural state and suppleness. At least twenty-five per cent. greater weight of leather can be obtained from hides treated by my invention than by any other process. The hair is removed in one-twentieth part of the time usually employed, thus effecting a great saving in time,labor, and expense. Hides and skins treated by my invention and intended for upper-leather do not require to go through the operation of hating or puring, which effects another saving in time and expense.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
ilNiTEn STATES ATENT Grrrcn.
JAMES FOLEY, OF MONTREAL, QUEBEC, CANADA.
SOFTENING, PLUMPING, AND DEPILATING HIDES AND SKINS.
SPECIFIGATION'fQrming part of Letters Patent No. 226,447, dated April 13,1880,
' Application filed October 30, 1879.
To all whom it may concern:
Be it known that I, JAMES FOLEY, of Montreal, Province of Quebec, Dominion of Canada, have invented certain new and useful Improvements in Treating Hides and Skins Previous to Tanning; and I do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to which it appertains to make and use the same.
This invention relates to removing the hair and epidermis from hides and skins of every description and however cured, softening dried and cured hides and skins, and separating the wool and hair from skinsin their natural state.
There are many methods of removing hair from hides and skins, the oldest of which, and that most extensively followed, consists in the application of a solution of lime but this method is not free from important objections. Owing to the energetic action which free lime exerts on animal tissues, a considerable portion of the gelatinoustissue of the hide is disintegrated and decomposed during the liming process, being removed from the hide in the form of soluble gelatine, or else so altered as to be rendered incapable of combining with tannin, thereby incurring a serious loss in the weight of leather that should be produced and in its quality.
For unhairing or removing the hair and epidermis from hides and skins I use, instead of lime, but in a somewhat similar manner, solutions of sulphide of barium of varying strengths, prepared by dissolving in water solid sulphide of barium, produced by heating finely-ground sulphate of baryta mixed with carbonaceous substances to about a white heat in a 'reverberatory furnace or other suitable appliance.
In treating green slaughter hides and skins to remove the hair and epidermis, I first wash them to remove the blood and dirt, and then immerse them in a strong solution of sulphide of barium, about 15 Baum, for about three to six hours. They are then withdrawn, again washed, and taken to the beam-house, to be treated in the usual manner.
In the treatment of salted or cured hides and skins for the removal of the hair and epidermis, I first immerse them about .ten to twelve hours in an old or partially-spent solution of sulphide of barium, for the purpose of cleansing them and destroying the effect of the salt or substance with which they were cured, and afterward immerse them in a solution of sulphide of barium of about 6 to S Baum for about ten hours, when they are ready for the usual treatment in the beam-house.
In the treatment of dried or flint hides and skins, it is necessary, before the hair and epidermis can be removed, to soften them, and this I do by soaking them about twenty-four hours in a solution of sulphide of barium that has already been used for unhairing, or in a weak fresh solution of about 3 Baum.
After the dried hides and skins are thoroughly softened in all their parts, in the manner above set forth, I immerse them, for the purpose of removing the hair and epidermis, in a solution of sulphide of barium of about 5 Baum for about six hours, and then pass them on to the beam-house.
In the treatment of skins for the removal of wool and hair, I apply on the flesh side of the skins, by any suitable means, a concentrated solution of sulphide of barium mixed with any inert substance to the consistency of a thin paste. The solution applied in this manner penetrates the skin, loosens the roots of the wool or hair, and allows it to be removed uninjured and in its natural condition.
My invention has a great many advantages over the present liming process and all processes now in use for removinghair from hides and skins and softening them, and among others the following: No part of the gelatinous tissue, grain, or substance of the hide is removed or disturbed. Hides and skins are left in their natural state and suppleness. At least twenty-five per cent. greater weight of leather can be obtained from hides treated by my invention than by any other process. The hair is removed in one-twentieth part of the time usually employed, thus effecting a great saving in time,labor, and expense. Hides and skins treated by my invention and intended for upper-leather do not require to go through the operation of hating or puring, which effects another saving in time and expense.
I am aware that a number of patents have been obtained for sulphide or sulphuret of calcium for the purpose of depilating hides and skins.
Sulphide of calcium has been tried by tanners both in Europe and America, and abandoned, owing to its cost theincreased expenditure for labor attending its application, and its injurious action upon the hides. It dissolves and removes a portion of the fibrous tissue-a very formidable objection to its use.
In my experience I have found that sulphur combined with lime simply renders the lime more soluble, allowing it (the lime) to act quicker; but in this state the lime also penetrates the hide, and, notwithstanding repeated washings, remains in the hide and forms, with the tannin, an almost insoluble tannate which deprives the hides of their suppleness and renders them dry and brittle.
JAMES FOLEY.
Witnesses:
E. A. LEDGARD, WM. F. LIGHTHALL.
Publications (1)
Publication Number | Publication Date |
---|---|
US226447A true US226447A (en) | 1880-04-13 |
Family
ID=2295833
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US226447D Expired - Lifetime US226447A (en) | Jambs polet |
Country Status (1)
Country | Link |
---|---|
US (1) | US226447A (en) |
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0
- US US226447D patent/US226447A/en not_active Expired - Lifetime
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