US2190848A - Dyeings - Google Patents
Dyeings Download PDFInfo
- Publication number
- US2190848A US2190848A US143726A US14372637A US2190848A US 2190848 A US2190848 A US 2190848A US 143726 A US143726 A US 143726A US 14372637 A US14372637 A US 14372637A US 2190848 A US2190848 A US 2190848A
- Authority
- US
- United States
- Prior art keywords
- dyeings
- complex
- compound
- fibers
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K11/00—Resistance welding; Severing by resistance heating
- B23K11/08—Seam welding not restricted to one of the preceding subgroups
- B23K11/087—Seam welding not restricted to one of the preceding subgroups for rectilinear seams
- B23K11/0873—Seam welding not restricted to one of the preceding subgroups for rectilinear seams of the longitudinal seam of tubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- the present invention relates to a process oiimproving dyeings on textile fibers and similar material.
- dyeings' of organic dyestuffs can be improved by causing the said dyestuffs to interact on the dyed material with organic bases like amines, quaternary ammonium compounds or 10 soluble salts thereof.
- organic bases like amines, quaternary ammonium compounds or 10 soluble salts thereof.
- the metal complex compounds to be used according to our invention are derived from or- 40 ganic bases which may belong to the aliphatic or cyclic series.
- the metal complex compounds of guanidino guanidine, oi thiourea, of c-phenanthroline, of phenylene diamines, or -2.2'-dipyridyl, of 8- amino-quinoline, oi 8-amino-quinaldine and the like.
- the metals suitable for preparing the compounds to be used according to our invention are of the type which easily forms complex compounds with organic bases, for instance, chromium, iron and especially copper.
- the process oi our invention may be carried out by ai'tertreating the dyed fibers withan aqueous solution oi one of the said complex metal compounds; if desired, the solution may '55 be weakly acid or alkaline.
- the dyeing is per- The aqueous solution 01 the copper vcomplex oi the compound of the following constitution:
- the above mentioned compound is obtainable by reacting upon 1 mol of cyanuric chloride with 1 mol of m-amino-phenyl-trimethyl am- 'moniumchloride and 1 mol of 5-amino-8-hydroxy-quinoline.
- Example 2 A 2% dyeing on cotton with the dyestufi which is obtained by coupling in an alkaline medium diazobenzene and diazotized 2-naphthylamine-6- sulionic acid with the urea of I-acid, is treated, after washing, for half an hour at 30 C. with an aqueous solution of the complex compound pre.. pared from cupric sulfate and. B-amino-quinaldine (obtainable by stirring an alcoholic solution or B-amino-quinaldine into an aqueous cupric sulfate solution). By this treatment the scarlet red dyeing becomes dark brown and acquires a good fastness to washing.
- Example 3 A 2% dyeing oi Diamine Pure Blue FF is dull and faster to washing.
- Example 4 Cotton which has been dyed with 7% of Sirius Black L (comp. Schultz, Farbstofltabellen, Erganzungsband, 1934, page 132) is treated in an aqueous. solution at 30 C.- prepared from o-phenanthroline-cupric-chloride (obtainable from ophenanthroline and cupric chloride). The dyeing becomes more greenish and is improved as regards its iastness to washing.
- Example 5 The fastness to water and washing of cotton dyeings prepared with Diamine Green B are improved on aftertreating the same with solutions of the complex salts prepared from cupric chloride with 1 or 2 mols of a.u-dipyridyl.
- the fastness to washing of the dyeings is also improved by using the corresponding complex iron salts.
- Example 6 Cotton dyed with Direct Deep Black EW extra is aftertreated with the solution of the cupric complex salt of NN-tetramethyl-o-phenylene-diamine.
- Such solutions may, for instance, be obtained by adding'l mol of base and 1 mol of copper acetate in alcohol and dilution with water of this alcoholic solution which, if desired, may have been filtered.
- the Iastness to water of the aftertreated dyeings is improved.
- the modification which comprises causing the dyed fibers to interact with a complex metal compoundof a cyclic base containingv at least two basic nitrogen atoms which metal compound is capable 01' forming salts with acids.
- the modification which comprises treating the dyed fibers with an aqueous solution of a complex copper compound of a N-heterocyclic base containing at least two basic nitrogen atoms which'copper compound is capable of forming salts with acids.
- the modification which comprises treating the dyed fibers with an aqueous solution of a complex-copper compound of 8-amino-quinoline which copper compound is capable of forming salts with acids.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Coloring (AREA)
- Butt Welding And Welding Of Specific Article (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US254010A US2218924A (en) | 1937-05-20 | 1939-02-01 | Aftertreatment of dyed textile fibers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI55142D DE657117C (de) | 1936-05-31 | 1936-05-31 | Verfahren zur Verbesserung der Eigenschaften von Faerbungen mit substantiven, Sulfonsaeure- oder Carbonsaeuregruppen enthaltenden Farbstoffen auf Cellulosefasern |
GB17579/36A GB478953A (en) | 1936-05-31 | 1936-06-24 | Process for the manufacture on the fibre of transformation products of dyestuffs containing sulphonic acid or carboxylic acid groups |
Publications (1)
Publication Number | Publication Date |
---|---|
US2190848A true US2190848A (en) | 1940-02-20 |
Family
ID=25981937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US143726A Expired - Lifetime US2190848A (en) | 1936-05-31 | 1937-05-20 | Dyeings |
Country Status (6)
Country | Link |
---|---|
US (1) | US2190848A (fr) |
BE (1) | BE478953A (fr) |
DE (3) | DE300536C (fr) |
FR (2) | FR822252A (fr) |
GB (1) | GB478953A (fr) |
NL (1) | NL46452C (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3074814A (en) * | 1958-01-15 | 1963-01-22 | Ici Ltd | Treatment of cellulosic materials |
US3116103A (en) * | 1959-09-24 | 1963-12-31 | Ici Ltd | Textile colouration process |
US3211513A (en) * | 1961-08-17 | 1965-10-12 | Ciba Geigy Corp | Process for dyeing and printing reactive dyestuffs |
US3325242A (en) * | 1967-06-13 | Process for dyeing and printing with reactive dyestuffs |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2649354A (en) * | 1947-12-01 | 1953-08-18 | Sandoz Ltd | Process for improving fastiness properties of direct dyestuffs |
US2576241A (en) * | 1950-04-03 | 1951-11-27 | Dan River Mills Inc | Dye fixing product and process and treating of textiles therewith |
DE968041C (de) * | 1951-05-10 | 1958-01-09 | Bayer Ag | Verfahren zur Herstellung kupferhaltiger, hoehermolekularer, basischer Kondensationsprodukte |
DE954686C (de) * | 1953-08-17 | 1956-12-20 | Bayer Ag | Mittel zur Verbesserung der Echtheitseigenschaften von Faerbungen substantiver Farbstoffe auf Cellulosefasern |
-
0
- DE DENDAT304780D patent/DE304780C/de not_active Expired
-
1916
- 1916-11-22 DE DE1916300536D patent/DE300536C/de not_active Expired
-
1936
- 1936-05-31 DE DEI55142D patent/DE657117C/de not_active Expired
- 1936-06-24 GB GB17579/36A patent/GB478953A/en not_active Expired
-
1937
- 1937-05-14 NL NL82496A patent/NL46452C/xx active
- 1937-05-20 US US143726A patent/US2190848A/en not_active Expired - Lifetime
- 1937-05-26 FR FR822252D patent/FR822252A/fr not_active Expired
- 1937-05-27 FR FR822282D patent/FR822282A/fr not_active Expired
-
1947
- 1947-12-30 BE BE478953D patent/BE478953A/xx unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3325242A (en) * | 1967-06-13 | Process for dyeing and printing with reactive dyestuffs | ||
US3074814A (en) * | 1958-01-15 | 1963-01-22 | Ici Ltd | Treatment of cellulosic materials |
US3116103A (en) * | 1959-09-24 | 1963-12-31 | Ici Ltd | Textile colouration process |
US3211513A (en) * | 1961-08-17 | 1965-10-12 | Ciba Geigy Corp | Process for dyeing and printing reactive dyestuffs |
Also Published As
Publication number | Publication date |
---|---|
NL46452C (fr) | 1939-08-15 |
DE300536C (fr) | 1917-09-26 |
FR822282A (fr) | 1937-12-24 |
FR822252A (fr) | 1937-12-24 |
DE657117C (de) | 1938-02-28 |
GB478953A (en) | 1938-01-24 |
BE478953A (fr) | 1948-01-31 |
DE304780C (fr) | 1918-04-10 |
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