US2158050A - Motor fuel - Google Patents

Motor fuel Download PDF

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Publication number
US2158050A
US2158050A US128929A US12892937A US2158050A US 2158050 A US2158050 A US 2158050A US 128929 A US128929 A US 128929A US 12892937 A US12892937 A US 12892937A US 2158050 A US2158050 A US 2158050A
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US
United States
Prior art keywords
fuel
nitrates
amyl
ignition
carbinitrate
Prior art date
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Expired - Lifetime
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US128929A
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English (en)
Inventor
Euphime V Bereslavaky
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Individual
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Individual
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Publication date
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Priority to US128929A priority Critical patent/US2158050A/en
Priority to FR821211D priority patent/FR821211A/fr
Application granted granted Critical
Publication of US2158050A publication Critical patent/US2158050A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G59/00Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha
    • C10G59/02Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha plural serial stages only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/14Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/1811Organic compounds containing oxygen peroxides; ozonides

Definitions

  • This invention relates to motor fuels, and more particularly to motor fuels having a low temperature of ignition,' which are adapted for solid injection engines of theDiesel typ
  • This application constitutes a continuation in part of my application Serial Number 49,027 filed 7 advantages of Diesel type or compression igni- -tion engines are greater fuel economy and smaller 15 fire risk. They also have a high thermal ef- 20 great favor and the high speed engine operates" 25 low octane number and it is desirable to change flciency, simplicity of operation and construction and the elimination of carbureters and magnetos.
  • the high speed Diesel type engine is' finding more efficiently and effectively with a motor fuel .having' a high octane number.
  • most hydrocarbon products which aresuitable-for fuel with the-Diesel type engines have a the characteristics of the fuel in order to raise the octane number.
  • One of the important fuel characteristics attendant a high octane number is a prompt ignition accompanied by a high rate r so of flame propagation.
  • Another characteristic is a low temperature-of ignition. The lower are the temperatures at; which compression-ignitionfuels 'ignite, the lower may be the compression ratio of the engine burning the fuel and the more 36 easily may the. engine .be started.
  • One important object of the present invention is to provide an accelerator by which the buming characteristics of a compression-ignition fuel may be effectively changed to increase its cetane devalue.
  • Another object of the invention is to provlde.
  • Another object of the invention is to provide a chemical compo 1 treating 1117- drocarbon distillates, particularly petroleum dis tillates, which have a, slow rate of flame propagation and a comparatively, high temperature of ignition whereby the burning characteristics of such fuels may be changed to lowerthe ignition temperature and increase the rate of flame propagation and the cetane value of the fuel in order fuel in to improve combustion.
  • characteristics of a motonfuel is dependent upon the chemical structure of the hydrocarbons in the fuel. Paraf:
  • the nitrites cetanenumbcr ofa thermore these lower alkyl nitrates are explosive having low boiling point and flash point ranges and present a strong fire hazard. They also fail to improve startability sufiiciently. It has been found, furthermore, that the lower alkyl nitrates are not completely soluble in hydrocarbon motor fuels and therefore it is necessary to use a blending agent in order to get them into solution in the motor .fuels. Due to the low solubility of the compounds there is a tendency for the highly volatile low boiling alkyl nitrates to come out of solution and the presence of these vapors inthe fuel tanks is a dangerous fire hazard, as well as being very explosive.
  • One of the features of this invention is to provide an improved method of operating an internal combustion engine and particularly a compression ignition engine by burning the fuel therein in the presence 'of amyl nitrates-which act to herent in other accelerators and give a comparahaving a marked effect are the secondary butyl carbinitrate the primary iso-amyl nitrate and the tively large increase in the cetane value of hydrocarbon motor fuels.
  • Amyl nitrates are more effeetive as ignition accelerators than lower alkyl nitrates.
  • amyl nitrates Of the eight isomers of amyl nitrates the normal primary amyl nitrate appears to have the most marked effect'on the cetane value of hydrocarbon motor fuels; Other amyl nitrates normal and the symmetric secondary amyl nitrates. These compounds are plentiful and comparatively cheap to manufacture.
  • the approximate ranges of boiling points of amyl nitrates are as follows: primary normal amyl nitrate boiling points 152-156 (2., secondary butyl carbinitrate 'boiling points 148-152 0., primary iso-amyl mtrate boiling points 146-l48 0., mixed primary amyl nitrates boiling points 146156 CQ, mixed secondary amyl nitrates boiling points 136-145 C., tertiary amyl nitrate boiling points 23- -27 C. at 4/5 mm.
  • amyl nitrates which properly may be called pentyl nitrates are manufactured from corresponding alcohols derived from natural gas or petroleum products and have the followingmolecular formulae:
  • the first three nitrates mentioned above are primary nitrates, the .next three are secondary and the seventh isomer is a tertiary nitrate.
  • cetane value is substantially directly proportional to the percentage of amyl nitrates in the fuel. thermore the cetane value tends to increase along an almost straight line curve until more than percent by volume of the amyl nitrates has been used in modifying the fuel.
  • amyl nitrates are substantially completely directly soluble inmost hydrocarbon distiliates in all proportions, do not require the use of blending agents and are non-corrosive.
  • Pentyl nitrates comprised a mixture of about 10% primary (approximately 20% normal, 25% secondary butyl carbinitrate, 25% iso-am'yl): and of about 30% secondary amyl nitrates I (normal and diethyl carbinitrate)
  • Primary amyl nitrates comprised approximately 30% normal amyl nitrate, 55% secondary butyl carbinitrate and 15% iso-amyl nitrate.
  • a liquid fuel for compression ignition en- 4 erative property of amyl nitrates and therefore their removal is desirable, when amyl nitrates are used.
  • a process of enhancing the cetane susceptibility of high sulfur Diesel oils comprising hydrocarbon distillates of the gas 011 type comprising refining the distillate to reduce the sulfur content to less than .25 percent by weight of .the distillate and dissolving in the distillate a-pentyl nitrate selected from the group consisting of normal butyl carbinitrate, secondary butyl carbinitrate, methylpropyl carbinitrate anddiethyl carbinitrate.
  • a process of enhancing the cetane suscepticarbon distillates of the gas oil type comprising refining the distillate to reduce the sulfur content to' less. than .25- percent by weight of the distillate and dissolving a mixture of two or more pentyl mtrates in the distillate selected from the group consisting of normal butyl carbinitrate, secondary butyl carbinitrate, methylpropyl carbinitrate and diethyl carbinitrate'and wherein isobutyl carbinitrate may be mixed with one or more of the nitrates of .said group.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
US128929A 1937-03-04 1937-03-04 Motor fuel Expired - Lifetime US2158050A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US128929A US2158050A (en) 1937-03-04 1937-03-04 Motor fuel
FR821211D FR821211A (fr) 1937-03-04 1937-04-28 Perfectionnements aux combustibles pour moteurs

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US128929A US2158050A (en) 1937-03-04 1937-03-04 Motor fuel

Publications (1)

Publication Number Publication Date
US2158050A true US2158050A (en) 1939-05-16

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FR (1) FR821211A (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2472152A (en) * 1944-08-05 1949-06-07 Union Oil Co Diesel engine fuel
US2658340A (en) * 1945-02-01 1953-11-10 Power Jets Res & Dev Ltd Apparatus for igniting fuel in fast-moving hot gas streams
US2698513A (en) * 1947-12-29 1955-01-04 Phillips Petroleum Co Paraffin hydrocarbon fuel for and method of operating pulse-jet engines
US2785662A (en) * 1953-04-06 1957-03-19 Leonard D Boyce Compositions and methods for removing deposits
US2854819A (en) * 1946-01-23 1958-10-07 Power Jets Res & Dev Ltd Apparatus for igniting fuel in a fastmoving hot gas stream by means of a spontaneously ignitable pilot fuel
US2858200A (en) * 1954-06-28 1958-10-28 Union Oil Co Diesel engine fuel
US2934047A (en) * 1951-08-13 1960-04-26 Sinclair Refining Co Operation of internal combustion engines of the compression ignition type
US2934048A (en) * 1955-10-13 1960-04-26 Sinclair Refining Co Composition
US4240801A (en) * 1979-05-31 1980-12-23 Ethyl Corporation Diesel fuel composition
WO1987003295A1 (fr) * 1985-11-25 1987-06-04 The Lubrizol Corporation Accelerateur d'ignition
US5405417A (en) * 1990-07-16 1995-04-11 Ethyl Corporation Fuel compositions with enhanced combustion characteristics
EP1516909A2 (fr) * 2003-09-18 2005-03-23 Afton Chemical Corporation Procédé pour diminuer la quantité de péroxydes, pour diminuer les sédiments du combustible et pour augmenter la durabilité de l'élastomère du système de combustion, la stabilité du combustible et la durabilité de la couleur du combustible.
US11046903B2 (en) * 2019-08-22 2021-06-29 Exxonmobil Research And Engineering Company Fuel additives with low NOx emissions

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE748638C (de) * 1938-11-30 1944-11-09 Dieseloele
GB757086A (en) * 1952-07-16 1956-09-12 Socony Mobil Oil Co Fuel oil composition
CA2040818A1 (fr) * 1990-05-17 1991-11-18 Lawrence J. Cunningham Compositions de carburant a caracteristiques de combustion ameliorees
IL100669A0 (en) 1991-05-13 1992-09-06 Lubrizol Corp Low-sulfur diesel fuel containing organometallic complexes
US5376154A (en) 1991-05-13 1994-12-27 The Lubrizol Corporation Low-sulfur diesel fuels containing organometallic complexes
CA2078844A1 (fr) * 1991-10-08 1993-04-09 Lawrence J. Cunningham Compositions de combustibles

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2472152A (en) * 1944-08-05 1949-06-07 Union Oil Co Diesel engine fuel
US2658340A (en) * 1945-02-01 1953-11-10 Power Jets Res & Dev Ltd Apparatus for igniting fuel in fast-moving hot gas streams
US2854819A (en) * 1946-01-23 1958-10-07 Power Jets Res & Dev Ltd Apparatus for igniting fuel in a fastmoving hot gas stream by means of a spontaneously ignitable pilot fuel
US2698513A (en) * 1947-12-29 1955-01-04 Phillips Petroleum Co Paraffin hydrocarbon fuel for and method of operating pulse-jet engines
US2934047A (en) * 1951-08-13 1960-04-26 Sinclair Refining Co Operation of internal combustion engines of the compression ignition type
US2785662A (en) * 1953-04-06 1957-03-19 Leonard D Boyce Compositions and methods for removing deposits
US2858200A (en) * 1954-06-28 1958-10-28 Union Oil Co Diesel engine fuel
US2934048A (en) * 1955-10-13 1960-04-26 Sinclair Refining Co Composition
US4240801A (en) * 1979-05-31 1980-12-23 Ethyl Corporation Diesel fuel composition
WO1987003295A1 (fr) * 1985-11-25 1987-06-04 The Lubrizol Corporation Accelerateur d'ignition
US5405417A (en) * 1990-07-16 1995-04-11 Ethyl Corporation Fuel compositions with enhanced combustion characteristics
EP1516909A2 (fr) * 2003-09-18 2005-03-23 Afton Chemical Corporation Procédé pour diminuer la quantité de péroxydes, pour diminuer les sédiments du combustible et pour augmenter la durabilité de l'élastomère du système de combustion, la stabilité du combustible et la durabilité de la couleur du combustible.
US20050061749A1 (en) * 2003-09-18 2005-03-24 Bennett Joshua J. Method of reducing amount of peroxides, reducing fuel sediments and enhancing fuel system elastomer durability, fuel stability and fuel color durability
EP1516909A3 (fr) * 2003-09-18 2005-06-22 Afton Chemical Corporation Procédé pour diminuer la quantité de péroxydes, pour diminuer les sédiments du combustible et pour augmenter la durabilité de l'élastomère du système de combustion, la stabilité du combustible et la durabilité de la couleur du combustible.
US7396450B2 (en) 2003-09-18 2008-07-08 Afton Chemical Corporation Method of reducing amount of peroxides, reducing fuel sediments and enhancing fuel system elastomer durability, fuel stability and fuel color durability
US11046903B2 (en) * 2019-08-22 2021-06-29 Exxonmobil Research And Engineering Company Fuel additives with low NOx emissions

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Publication number Publication date
FR821211A (fr) 1937-11-30

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