US210690A - Improvement in preparing paper to take copies - Google Patents
Improvement in preparing paper to take copies Download PDFInfo
- Publication number
- US210690A US210690A US210690DA US210690A US 210690 A US210690 A US 210690A US 210690D A US210690D A US 210690DA US 210690 A US210690 A US 210690A
- Authority
- US
- United States
- Prior art keywords
- paper
- improvement
- copying
- preparing paper
- perchloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000000976 ink Substances 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 8
- 235000006408 oxalic acid Nutrition 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L Iron(II) sulfate Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- -1 citric Chemical class 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000001105 regulatory Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/70—Inorganic compounds forming new compounds in situ, e.g. within the pulp or paper, by chemical reaction with other substances added separately
Definitions
- This invention has for its object, in chief, to provide paper which, by the usual practice of damping before use, as with ordinary copying-papers, will readily take impressions from written or printed matter which has been produced with ink free from the impurities inseparable from specially-prepared copying-ink. I thereby render it possible and advantageous to use apurer, better, and cheaper ink for copying than can be used with ordinary copying-paper, which inlc is also suitable for all other purposes for which ink is used. I avoid the cost, trouble, and annoyance which result from the necessity of using two separate inks-that is to say, one kind for copying, and the other for ordinary purposes.
- the paper prepared according to this invention also produces better impressions from prepared copyingink than any other paper at present in use, and will copy documents which have been previously copied.
- the essential feature of my invention con sists in the preparation of special copyingpapers, by mixing oxalic or citric acid and the perchloride of iron with the pulp during the process of manufacture, (or sulphate of iron may be used in lieu of the perchloride.)
- Copying-papers thus made can be used in the same manner as ordinary copying-papersthat is, by moistcning them with water, in the usual way, before taking impressions of documents.
- the proportions in which the acids and the perchloride of iron are to be employed are regulated according to the thickness of the paper required to be manufactured, as hereinafter described, to avoid any deterioration in the substance of the paper.
- the proportions I prefer to employ are as followsthat is to say, for paper weighing twelve to fifteen pounds to the ream of four hundred and eighty sheets, each measuring nineteen by twenty-two inches, to the wa. ter used in manufacturing three hundred pounds weight of pulp from the rag-engine I add about one and a half gallon of perchloride of iron, calculated at Fe Gl and in which is dissolved about sixteen ounces of pure crystals of oxalic acid.
- I claim as my invention- The preparation of special copying-papers by mixing oxalic or citric acid, in combination with the perchloride or sulphate or iron, with the pulp during the process of manufacture, as hereinbefore described.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Description
UNITED STATES PATENT OEEIOE.
FnEDEmoK HAWKE, OF LONDON, ENGLAND.
IMPROVEMENT IN PREPARING PAPER TO TAKE COPIES.
Specification forming part of Letters Patent No. 210,690, dated December 10, 1878; application filed October 18, 1877; patented in England, May 17, 1877.
of 10 St. J ohns Wood Park, London, in the county of Middlesex, England, have invented improvements in the preparation of paper for taking impressions of matter, written or printed, in inks which are prepared or unprepared, for copying purposes, as fully set forth herein.
This invention has for its object, in chief, to provide paper which, by the usual practice of damping before use, as with ordinary copying-papers, will readily take impressions from written or printed matter which has been produced with ink free from the impurities inseparable from specially-prepared copying-ink. I thereby render it possible and advantageous to use apurer, better, and cheaper ink for copying than can be used with ordinary copying-paper, which inlc is also suitable for all other purposes for which ink is used. I avoid the cost, trouble, and annoyance which result from the necessity of using two separate inks-that is to say, one kind for copying, and the other for ordinary purposes.
The paper prepared according to this invention also produces better impressions from prepared copyingink than any other paper at present in use, and will copy documents which have been previously copied.
The essential feature of my invention con sists in the preparation of special copyingpapers, by mixing oxalic or citric acid and the perchloride of iron with the pulp during the process of manufacture, (or sulphate of iron may be used in lieu of the perchloride.) Copying-papers thus made can be used in the same manner as ordinary copying-papersthat is, by moistcning them with water, in the usual way, before taking impressions of documents.
The proportions in which the acids and the perchloride of iron are to be employed are regulated according to the thickness of the paper required to be manufactured, as hereinafter described, to avoid any deterioration in the substance of the paper.
The proportions I prefer to employ are as followsthat is to say, for paper weighing twelve to fifteen pounds to the ream of four hundred and eighty sheets, each measuring nineteen by twenty-two inches, to the wa. ter used in manufacturing three hundred pounds weight of pulp from the rag-engine I add about one and a half gallon of perchloride of iron, calculated at Fe Gl and in which is dissolved about sixteen ounces of pure crystals of oxalic acid. For a paper weighing six to seven and a half pounds to the ream of four hundred and eighty sheets, each measuring nineteen by twen ty-two inches, to the water used in manufacturing three hundred pounds weight of pulp from the rag-engine I add about one and a quarter gallon of perchloride of iron, calculated at I e- 01 and in which is dissolved about twelve ounces ofpure crystals of oxalic acid. For other thicknesses of paper I use a corresponding strength of solution to those indicated above, according to the weight per ream.
I use the above-named combination as the cheapest and best; but other acids, such as citric, may be employed, and I may use either the perchloride or sulphate of iron. From the latter salt, however, I have not obtained such good results.
I claim as my invention- The preparation of special copying-papers by mixing oxalic or citric acid, in combination with the perchloride or sulphate or iron, with the pulp during the process of manufacture, as hereinbefore described.
FREDERICK HAVVKE.
IVitnesses:
JOHN HAWKE,
7 St. Mt'ldrcds Court, London. WILLIAM GnANvILLE HAWKE,
7 St. Mildrcds Court, London.
Publications (1)
Publication Number | Publication Date |
---|---|
US210690A true US210690A (en) | 1878-12-10 |
Family
ID=2280097
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US210690D Expired - Lifetime US210690A (en) | Improvement in preparing paper to take copies |
Country Status (1)
Country | Link |
---|---|
US (1) | US210690A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3000298A (en) * | 1956-01-03 | 1961-09-19 | Sherman | Printing by diazotization |
US4715931A (en) * | 1987-03-24 | 1987-12-29 | Betz Laboratories, Inc. | Process for inhibiting aluminum hydroxide deposition in papermaking felts |
-
0
- US US210690D patent/US210690A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3000298A (en) * | 1956-01-03 | 1961-09-19 | Sherman | Printing by diazotization |
US4715931A (en) * | 1987-03-24 | 1987-12-29 | Betz Laboratories, Inc. | Process for inhibiting aluminum hydroxide deposition in papermaking felts |
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