US2091713A - Developer - Google Patents
Developer Download PDFInfo
- Publication number
- US2091713A US2091713A US8518A US851835A US2091713A US 2091713 A US2091713 A US 2091713A US 8518 A US8518 A US 8518A US 851835 A US851835 A US 851835A US 2091713 A US2091713 A US 2091713A
- Authority
- US
- United States
- Prior art keywords
- color
- developer
- para
- phenylenediamine
- image
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 22
- 150000001875 compounds Chemical class 0.000 description 22
- 238000009740 moulding (composite fabrication) Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 16
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 13
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 13
- 230000008569 process Effects 0.000 description 13
- 239000012670 alkaline solution Substances 0.000 description 11
- 230000003647 oxidation Effects 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 11
- 230000008878 coupling Effects 0.000 description 9
- 238000010168 coupling process Methods 0.000 description 9
- 238000005859 coupling reaction Methods 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- -1 silver halide Chemical class 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 150000004982 aromatic amines Chemical class 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 3
- 229940116357 potassium thiocyanate Drugs 0.000 description 3
- 150000003567 thiocyanates Chemical class 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/407—Development processes or agents therefor
- G03C7/413—Developers
Definitions
- This invention relates to photographic developers. and, more particularly, to developers having increased reduction potential.
- Certain developers such as the para-phenylenediamines
- developers are unsatisfactory for ordinary photographic use because of their low reduction potential.
- the color-forming compound may be mixed with the developer, or may be incorporated in the sensitized emulsion prior to exposure. Such a process is disclosed in Fischer U. S. Patent No.
- a film base coated with two or more silver halide emulsion layers, each of which is sensitized to a different region of the spectrum, is exposed to form a latent colorseparation image in each layer.
- the film is developed in a developer in which an aromatic amine, such as para-phenylenediamine hydrochloride, is the developing ingredient and which contains a color-forming compound.
- an aromatic amine such as para-phenylenediamine hydrochloride
- the silver halide present in the emulsion is reduced to metallic silver and where this occurs, the para-phenylenediamine is oxidized.
- the color-forming compound present in the developer is one which will combine with the oxidation product of the paraphenylenediamine to form a colored dye compound.
- Formula 1 produces on development a blue-green 10.
- Our invention is applicable to the formation of color pictures by any method in which a color is formed by coupling of the oxidation product of an aromatic amine developer with a color former.
- the sensitized emulsion may be in one or more layers and may be on one or both sides of a film.
- Our process may also be used with plates as well as films and with various types of color separation processes, for example, in which the 45 color separation negatives are exposed separately and later superposed to form a complete colored picture.
- 'Ihe 'colorforming compound may be present in the developer solution or it may be incorporated in the emulsion layer prior to exposure.
- Our invention is not limited to the use of thiccyanates with color developers. We have found that a small amount of thiocyanate will increase the reduction potential of an aromatic amino quarter to 2 grams per liter of developer solution, while with ordinary para-phenylenediamine developers, amounts as high as 7 grams per liter have been used.
- aromatic amino developers we intend to include the mono-, di-, and triamino aromatic compounds, of which the paraphenylenediamines are the compounds generally used.
- the salt form such as the hydrochloride or the sulfate, is most desirable, due to its stability in the dry state.
- These compounds may be substituted in the amino group or in the ring, forming the alkyl phenylenediamines, and the toluylenediamines.
- a particular advantage of our process is the fact that it enables the direct development of color films to form a colored image. It is frequently necessary with such films to develop the film in an ordinary meto'l-hydroquinone developer to a black and white image and later convert this image by color development to a colored image.
- the colored image may be obtained by direct development.
- a process of producing a colored photographic image which comprises developing a latent image in an alkaline solution containing a primary aryl amine developing agent, said aryl being of the benzene series, and a thiocyanate, and simultaneously coupling the oxidation product of the primary aryl amine developer with a color-forming compound.
- a process of producing a colored photographic image which comprises developing a latent image in an alkaline solution containing a para-phenylenediamine and a thiocyanate, and simultaneously coupling the oxidation product of the para-phenylenediamine with a color-form ing compound.
- a process of producing a coloredphotographic image which comprises developing a latent image in an alkaline solution containing a para-phenylenediamine and a thiocyanate, and simultaneously coupling the oxidation product of the para-phenylenediamine with a color-foaming compound originally present in the developer solution.
- a process of producing a colored photographic image which comprises developing a latent ima'ge in an alkaline solutionto which has been added a p'ara-phenylenediamine' hydrochloride and a thiocyanate, and simultaneously coupling the oxidation product of the para-phenylenediamine with a color-forming compound.
- a process of producing a, colored photographic image which comprises developing a latent image in an alkaline solution to which has been added a para-phenylenediamine hydrochloride and a thiocyanate, and simultaneously coupling the oxidation product of the para-phenylenediamine with a color-forming compound originally present in the developer solution.
- Aprocess of producing a colored photo'- graphic image which comprises developing a. latent image in an alkaline solution containing a para-phenylenediamine and an alkali thiocyanate, and simultaneously coupling the oxidation product of the, para-phenylenediamine with a color-forming compound.
- a process of producing a colored photographic image which comprises developing a latent image in an alkaline solution containing a para-phenylenediamine and potassium thiocyanate and simultaneously coupling the oxidation product of the para-phenylenediamine with a color-forming compound.
- a process of producing a colored photographic image which comprises incorporating a color-forming compound in a sensitive emulsion, exposing said emulsion to form a latent image, and developing said latent image in a developer containing a para-phenylenediamine and a thiocyanate.
- a process of producing a. colored photographic image which comprises incorporating a color-forming compound in a sensitive emulsion, exposing said emulsion to form a latent image, and developing said latent image in a developer containing a para-phenylenediamine salt and potassium thiocyanate.
- a photographic developer comprising a para-phenylenediamine in alkaline solution, a color-forming compound and a thiocyanate.
- a -photographic developer comprising a para-phenylenediamine in alkaline solution, a color-forming compound and an alkali thiocyanate.
- a photographic developer comprising a para-phenylenediamine inorganic acid salt in alkaline solution, a color-forming compound, and
- a photographic developer comprising a para-phenylenediamine hydrochloride in alkaline solution, a color-forming compound and a thiocyanate.
- a photographic developer comprising a para-phenylenediamine salt in alkaline solution, a color-forming compound and potassium thiocyanate.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8518A US2091713A (en) | 1935-02-27 | 1935-02-27 | Developer |
| FR804471D FR804471A (fr) | 1935-02-27 | 1936-02-27 | Révélateurs photographiques |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8518A US2091713A (en) | 1935-02-27 | 1935-02-27 | Developer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2091713A true US2091713A (en) | 1937-08-31 |
Family
ID=21732048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US8518A Expired - Lifetime US2091713A (en) | 1935-02-27 | 1935-02-27 | Developer |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2091713A (fr) |
| FR (1) | FR804471A (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2553498A (en) * | 1947-11-18 | 1951-05-15 | Gen Aniline & Film Corp | First developer for multilayer color film of the reversal type |
| US2665986A (en) * | 1939-11-02 | 1954-01-12 | Gevaert Photo Prod Nv | Process of producing colored reversal images |
| US5079133A (en) * | 1986-04-11 | 1992-01-07 | Fuji Photo Film Co., Ltd. | Silver halide color photographic material |
-
1935
- 1935-02-27 US US8518A patent/US2091713A/en not_active Expired - Lifetime
-
1936
- 1936-02-27 FR FR804471D patent/FR804471A/fr not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2665986A (en) * | 1939-11-02 | 1954-01-12 | Gevaert Photo Prod Nv | Process of producing colored reversal images |
| US2553498A (en) * | 1947-11-18 | 1951-05-15 | Gen Aniline & Film Corp | First developer for multilayer color film of the reversal type |
| DE968447C (de) * | 1947-11-18 | 1958-02-20 | Gen Aniline & Film Corp | Verfahren zur gleichmaessigen Entwicklung von belichteten, mehrschichtigen Farbumkehrfilmen |
| US5079133A (en) * | 1986-04-11 | 1992-01-07 | Fuji Photo Film Co., Ltd. | Silver halide color photographic material |
Also Published As
| Publication number | Publication date |
|---|---|
| FR804471A (fr) | 1936-10-24 |
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