US2089883A - Wire finishing - Google Patents

Wire finishing Download PDF

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Publication number
US2089883A
US2089883A US27126A US2712635A US2089883A US 2089883 A US2089883 A US 2089883A US 27126 A US27126 A US 27126A US 2712635 A US2712635 A US 2712635A US 2089883 A US2089883 A US 2089883A
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United States
Prior art keywords
wire
coating
wet
sulphonated
alkyl
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Expired - Lifetime
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US27126A
Inventor
Frank H Ellsworth
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American Steel and Wire Company of New Jersey
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American Steel and Wire Company of New Jersey
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Priority to US27126A priority Critical patent/US2089883A/en
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Publication of US2089883A publication Critical patent/US2089883A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/286Esters of polymerised unsaturated acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles

Definitions

  • This invention relates to the production of shiny finish wire, one of the objects being to produce wire with a surface uncontaminated by the traces of lime resulting when conventional dry 5 drawing methods are followed and without involving the messy and malodorous conditions which prevail at the drawing frames in wet drawing operations.
  • Other objects may be inferred from the following disclosure.
  • rods or wire are properly prepared by cleaning and liming as in dry drawing.
  • a lime coating is applied to the rod or wire surfaces in the form of a thin continuous film. closed in an envelope of copper, tin, brass or any other metal prior to the application of the lime coating, and it may or may not be subsequently baked to remove brittleness, the customers demands or the reductions to be obtained determining these factors.
  • the wire is then contacted with a mixture or emulsion associated with a substance such as will accelerate thorough wetting of the wire surface in the drawing process.
  • a lubricant consisting of an emulsion containing a wetting agent, to apply conventional dry drawing equipment to the production of a wire previously drawn only by the wet wire drawing process.
  • the emulsion lubricant is not sufficient to effect a thorough moisture penetration of the rod or wire coating.
  • Some accelerating substance must be used for this purpose.
  • the emulsion lubricant may be the usual soap and water paste modified by the addition of the wetting agent.
  • the wire is drawn through a reducing die while its coating is wet; the result being a shiny finished wire which is aptly termed mirror finis wire. No coating contaminates its surface, and the operators are not subjected to the disagreeable conditions connected with the wet drawing method.
  • the wire may or may not be en-
  • suitable organic substances for accelerating the wetting of the lime coating are the following: sulphonated orthy butyl phenyl phenol; all sulphonated alkyl, aryl and aryl-alkyl derivatives of phenyl phenol; all higher fatty alcohols and acids, their ethers and esters, both alkyl and arakyl, all sulphonated higher fatty alcohols and acids, their ethers and esters, both alkyl and arakyl, sulphonated abietic acids and their substituted derivatives, sulphonated alkyl- -ated hydrocarbons, aromatic hydrocarbons and their derivatives, including the hydroxy, halogen alkyl, aryl and arakyl substances.
  • a method of producing shiny finished wire including applying a lime coating to said wire, contacting said wire with a wet lubricant associated with an organic substance such as will accelerate wetting of said coating and drawing said wire through a reducing die while said coating is wet.
  • a method of producing shiny finished wire including applying a coating to said wire of the character used in dry drawing, contacting said wire with a wet lubricant associated with an organic substance such as will accelerate wetting of said coating and drawing said wire through a reducing die while said coating is wet, said substance being selected from the group comprising sulphonated orthy butyl, phenyl phenol; all sulphonated alkyl, aryl, etc.
  • a method of producing shiny finished wire including applying a lime coating to said wire, contacting said wire with a wet lubricant associated with an organic substance such as will accelerate wetting of said coating and drawing said wire through a reducing die while said coating is wet, said substance being selected from the I group comprising sulphonated orthy butyl, phenyl phenol; all sulphonated alkyl, aryl, etc.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Metal Extraction Processes (AREA)

Description

Patented Aug. 10, 1937 UNITED STATES PATENT OFFICE WIRE FINISHING No Drawing. Application June 17, 1935, Serial No. 27,126
3 Claims.
This invention relates to the production of shiny finish wire, one of the objects being to produce wire with a surface uncontaminated by the traces of lime resulting when conventional dry 5 drawing methods are followed and without involving the messy and malodorous conditions which prevail at the drawing frames in wet drawing operations. Other objects may be inferred from the following disclosure.
According to the invention, rods or wire are properly prepared by cleaning and liming as in dry drawing. A lime coating is applied to the rod or wire surfaces in the form of a thin continuous film. closed in an envelope of copper, tin, brass or any other metal prior to the application of the lime coating, and it may or may not be subsequently baked to remove brittleness, the customers demands or the reductions to be obtained determining these factors.
The wire is then contacted with a mixture or emulsion associated with a substance such as will accelerate thorough wetting of the wire surface in the drawing process. Hence, it is possible with the use of a lubricant, consisting of an emulsion containing a wetting agent, to apply conventional dry drawing equipment to the production of a wire previously drawn only by the wet wire drawing process. The emulsion lubricant is not sufficient to effect a thorough moisture penetration of the rod or wire coating. Some accelerating substance must be used for this purpose. The emulsion lubricant may be the usual soap and water paste modified by the addition of the wetting agent.
Subsequently, the wire is drawn through a reducing die while its coating is wet; the result being a shiny finished wire which is aptly termed mirror finis wire. No coating contaminates its surface, and the operators are not subjected to the disagreeable conditions connected with the wet drawing method.
The wire may or may not be en- Among suitable organic substances for accelerating the wetting of the lime coating are the following: sulphonated orthy butyl phenyl phenol; all sulphonated alkyl, aryl and aryl-alkyl derivatives of phenyl phenol; all higher fatty alcohols and acids, their ethers and esters, both alkyl and arakyl, all sulphonated higher fatty alcohols and acids, their ethers and esters, both alkyl and arakyl, sulphonated abietic acids and their substituted derivatives, sulphonated alkyl- -ated hydrocarbons, aromatic hydrocarbons and their derivatives, including the hydroxy, halogen alkyl, aryl and arakyl substances.
I claim:
1. A method of producing shiny finished wire, including applying a lime coating to said wire, contacting said wire with a wet lubricant associated with an organic substance such as will accelerate wetting of said coating and drawing said wire through a reducing die while said coating is wet.
2. A method of producing shiny finished wire, including applying a coating to said wire of the character used in dry drawing, contacting said wire with a wet lubricant associated with an organic substance such as will accelerate wetting of said coating and drawing said wire through a reducing die while said coating is wet, said substance being selected from the group comprising sulphonated orthy butyl, phenyl phenol; all sulphonated alkyl, aryl, etc.
3. A method of producing shiny finished wire, including applying a lime coating to said wire, contacting said wire with a wet lubricant associated with an organic substance such as will accelerate wetting of said coating and drawing said wire through a reducing die while said coating is wet, said substance being selected from the I group comprising sulphonated orthy butyl, phenyl phenol; all sulphonated alkyl, aryl, etc.
FRANK H. ELLSWORTH.
US27126A 1935-06-17 1935-06-17 Wire finishing Expired - Lifetime US2089883A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2576362A (en) * 1947-10-08 1951-11-27 Westinghouse Electric Corp Electrophoretic method of coating wire with graphite
US3111218A (en) * 1958-05-26 1963-11-19 United States Steel Corp Method of drawing wire and a lubricant therefor
US4404828A (en) * 1980-08-01 1983-09-20 H. L. Blachford Ltd/Ltee Method of drawing a metal wire and lubricant composition therefor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2576362A (en) * 1947-10-08 1951-11-27 Westinghouse Electric Corp Electrophoretic method of coating wire with graphite
US3111218A (en) * 1958-05-26 1963-11-19 United States Steel Corp Method of drawing wire and a lubricant therefor
US4404828A (en) * 1980-08-01 1983-09-20 H. L. Blachford Ltd/Ltee Method of drawing a metal wire and lubricant composition therefor

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