US2087953A - Process and composition for rectification of curly hair - Google Patents
Process and composition for rectification of curly hair Download PDFInfo
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- US2087953A US2087953A US711988A US71198834A US2087953A US 2087953 A US2087953 A US 2087953A US 711988 A US711988 A US 711988A US 71198834 A US71198834 A US 71198834A US 2087953 A US2087953 A US 2087953A
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- 239000000203 mixture Substances 0.000 title description 31
- 238000000034 method Methods 0.000 title description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000003513 alkali Substances 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 description 10
- 239000011707 mineral Substances 0.000 description 10
- 235000010755 mineral Nutrition 0.000 description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 5
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 5
- 239000003974 emollient agent Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 5
- 239000001119 stannous chloride Substances 0.000 description 5
- 235000011150 stannous chloride Nutrition 0.000 description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- KYRUBSWVBPYWEF-UHFFFAOYSA-N copper;iron;sulfane;tin Chemical compound S.S.S.S.[Fe].[Cu].[Cu].[Sn] KYRUBSWVBPYWEF-UHFFFAOYSA-N 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 4
- 235000019345 sodium thiosulphate Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004902 Softening Agent Substances 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 231100000344 non-irritating Toxicity 0.000 description 3
- 229920001021 polysulfide Polymers 0.000 description 3
- 239000005077 polysulfide Substances 0.000 description 3
- 150000008117 polysulfides Polymers 0.000 description 3
- -1 sodium hydroxide Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000007514 bases Chemical class 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000003223 protective agent Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- HVTHJRMZXBWFNE-UHFFFAOYSA-J sodium zincate Chemical compound [OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Zn+2] HVTHJRMZXBWFNE-UHFFFAOYSA-J 0.000 description 2
- 239000011686 zinc sulphate Substances 0.000 description 2
- 235000009529 zinc sulphate Nutrition 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 210000002768 hair cell Anatomy 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N monoethanolamine hydrochloride Natural products NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- CVNKFOIOZXAFBO-UHFFFAOYSA-J tin(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Sn+4] CVNKFOIOZXAFBO-UHFFFAOYSA-J 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
Definitions
- This. invention deals with compositions and methods for removing objectionably obdurate kinkiness or curliness from human hair.
- the mineral binder present in proportion sufficient to render the composition pastelike, serves to preserve the hair in straightened order produced by brushing or combing until the softening ingredients of the composition effectively de-elasticizes the hair so that the kinkiness or curliness thereof is more or less completely removed and a practically straightened condition produced which, after removal of the composition, is preserved.
- emollients such as glycerine, or tri,- ethanolamine, or other substituted amines, which will tend to adhere to the hair after the remainder of the composition is removed and prevent the hair from becoming dry.
- composition of this invention is an improvement upon compositions heretofore employed for the purpose.
- Compositions known prior to this invention have been harsh and irritating and, in some cases, dangerously so.
- Previously known compositions of any merit which have actually produced what might be called a permanent straightening of hair have depended for their action upon very strong free alkalies. These alkalies, together with waxes and the like, when applied to the hair have exerted a softening action.
- the amount of free alkali necessary to obtain this efiect has invariably exceeded a non-irritating concentration and the tendency has been to reduce the concentration of alkali in order to avoid irritation, in which case the softening action necessary to obtain permanent straightening has been lost.
- the principal softening agents are negative radicals and free alkali is neither necessary nor desirable, although nonirritating amounts thereof may be employed.
- the mineral binder employed with this invention provides the necessary temporary retention of the hair, but at the same time, due to the ease of wetting thereof by the softening solution, the latter has at all times free and complete access to all parts of the hair surface.
- stannous chloride a soiution of stannous chloride is prepared to which solution suflicient alkali hydroxide, such as sodium hydroxide, is added to convert all of the stannous chloride to sodium stannite.
- suflicient alkali hydroxide such as sodium hydroxide
- sodium polysulfide solution prepared by digesting sulphur in alkali hydroxide solution.
- alkali sulfide composition is then added a small amount of zinc sulfate, suflicient to combine with all free alkali present forming alkali zincate, which substance, although of minor softening properties, itself substantially enhances the softening properties of the stannite and polysulfide.
- the softening property of tin is dependent upon the tin being present in a stannous condition
- suflicient protective reducing agent such as sodium hyposuliite to prevent atmospheric oxidation of the tin.
- This solution containing the softening and protective agents is then employed for the purpose of compounding a paste or cream in which the solution is the suspending fluid.
- the preferred manner of preparing such paste is to add alkali earth oxides directly to the solution.
- the alkali earth oxide added to the solution becomes hydrated therein and after the elapse of sufli'pient time an extremely fine, smooth, colloidal, mineral binder is formed.
- Theresult is a paste or cream which is smooth and plastic to a high degree.
- the proper amount of alkali earth oxide be added to produce a cream just stiff enough to stand alone. This may be varied widely, of course, depending upon the preference of the operator, but it should be borne in mind that the paste should have sufficient mobility so that it can be worked well into a head of hair and at the same time suflicient stiffness to maintain the hair in straightened condition.
- the paste is worked thoroughly into the hair and the hair is then combed until it lies in straightenedorder.
- the composition is then permitted to dry or'partially dry upon the hair. This occurs within an interval of about fifteen minutes to half an hour and may be hastened somewhat by the use of a hot air dryer. During this interval of drying, the hair is held in straightened order by the mineral binder and while so held the softening solution acts upon the hair substance itself. Large amounts of fluid are taken up by the hair, causing it to swell. Under the action of the softening agent the cement substance between hair cells is softened and this allows the cells to shift their relative position so that when the hair again hardens the new position is assumed.
- the elasticity of the hair returns as shown by its assuming the straight position after being bent, just as the hair prior to any treatment assumes the kinky position after being held straight.
- the dried material is preferably rinsed out with clear water.
- the hair is then combed to proper configuration and dried.
- the hair so straightened can also be shampooed with soap to remove the composition, if desired, without danger of recurrence of the kinky state, but the rinsing with clear water is more effective.
- the new configuration of the hair will remain without reversion until replaced by new growth.
- a useful addition to the paste as prepared above is a small amount of water-soluble emollient, such as glycerine or triethanolamine, or other substituted amines.
- emollient such as glycerine or triethanolamine, or other substituted amines.
- the emollient is also beneficial in its effect upon the paste, imparting a certain lubricity thereto which makes the paste easier to comb into the hair.
- the following directions for compounding may sometimes be employed:
- this mixture sets into a thick paste.
- This thick paste is then thoroughly stirred while adding to about eighty-five parts by weight thereof approximately five parts of triethanolamine and four parts of glycerine.
- the paste is now in completed condition, but if through slight departures from the exact proportions or for other reasons the composition is not of exactly the desired consistency, this may be adjusted to either thicken it or thin it, as necessary, by the addition, respectively, of small amounts of MgO or small amounts of additional solution as first prepared.
- the quantity of stannous chloride may be varied between relatively wide limits without producing an entirely inoperative composition. Some degree of operativeness will be found in the range between one-half to ten parts by weight of stannous chloride. In the case of zinc sulphate, this is also true in approximately the same range.
- the quantity of sodium hydroxide employed is related to the quantity of zinc and tin present. This can range between two to fifteen parts by weight..
- the quantity of hyposulfite may range between three parts by weight and thirty parts by weight.
- the quantity of polysulfide solution employed may also be varied widely from two parts to twenty parts by weight.
- the quantity of magnesium oxide employed is entirely dependent upon the consistency of cream desired.
- the quantity or presence of the emollient is optional, the quantity shown being representative of only one functioning proportion within a wide range. Any quantity of triethanolamine from one-half to fifteen per cent is useful and the quantity of glycerine can vary within one-half to ten per cent.
- compositions which Will contain from three-tenths to eight per cent of stannous tin compounds, three-tenths to eight per cent of sodium zincate, two to fifteen per cent of sodium hypo-sulfite, and one-half to eighteen per cent of sodium polysulfide in addition to twenty-five to fifty per cent of magnesium hydrate and two to fifteen per cent of triethanolamine and one-half to ten per cent of glycerine, together with some neutral salts, such as sodium chloride and sulfate, and possibly some free alkali.
- the recognized equivalents of sodium such as potassium
- the sodium hypo-sulfite can be replaced with any other nonpoisonous, non-irritating, mild, reducing agent of sufiicient reducing activity to preferentially accept oxidation in the presence of stannous tin.
- reducing agents will hereinafter be referred to as protective agents. Examples of these are hydroquinone and Na2S.
- the hydrated alkaline earth oxide which forms the mineral binder in the composition may be replaced in whole or in part by any well-known equivalent, such as calcium hydrate, and also, at times, as well by complex silicates with or without alumina such as kaolin, bentonite, or other colloidal mineral.
- any well-known equivalent such as calcium hydrate
- complex silicates with or without alumina such as kaolin, bentonite, or other colloidal mineral.
- mineral binder will be employed to mean any of the above substances in a highly divided, suspended state.
- a composition of matter for the straightening of hair comprising three-tenths to eight per cent of basic compounds of stannous tin, threetenths to eight per cent of sodium zincate, two to fifteen per cent of sodium hyposulfite, one-half to eighteen per cent of sodium polysulfide, and twenty-five to fifty per cent of mineral binder.
- a composition of matter for the straightening of hair comprising a suspension consisting of solid suspended matter and liquid, said liquid containing in the presence of hydroxyl ions and magnesium ions a non-depilating concentration of tin in stannous form as stannite and as stannous hydroxide, alkali polysulfide and alkali zincate, and the suspended matter consists of highly divided mineral binder.
- the method of straightening obdurately curly hair which consists in applying to the hair a paste consisting in a mineral binder suspended in a softening solution containing from .3 to 8% of basic compound of stannous tin, to 18% of sodium polysulfide, and free hydroxyl mechanically extending the hair for retention in the extended state by the binder while permitting softening solution to remove the elastic tendency of the hair which would return the hair to curly condition, allowing the hair and applied composition to dry, and then removing the dried composition from the hair.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
Patented July 27, 1937 UNITED STATES PROCESS AND COMPOSITION FOR RECTIFI- OATION OF CURLY HAIR Julian Y. Malone, Joseph H. Carroll, and Charles R. McKee, Milwaukee, Wis., assignors to The Perwav Company, Milwaukee, Wis, a
tion of Wisconsin No Drawing.
3 Claims. This. invention deals with compositions and methods for removing objectionably obdurate kinkiness or curliness from human hair.
duce it to an easily moidable state. The mineral binder, present in proportion sufficient to render the composition pastelike, serves to preserve the hair in straightened order produced by brushing or combing until the softening ingredients of the composition effectively de-elasticizes the hair so that the kinkiness or curliness thereof is more or less completely removed and a practically straightened condition produced which, after removal of the composition, is preserved. Sometimes it is also desirable to include in the composition emollients such as glycerine, or tri,- ethanolamine, or other substituted amines, which will tend to adhere to the hair after the remainder of the composition is removed and prevent the hair from becoming dry.
The composition of this invention is an improvement upon compositions heretofore employed for the purpose. Compositions known prior to this invention have been harsh and irritating and, in some cases, dangerously so. Previously known compositions of any merit which have actually produced what might be called a permanent straightening of hair have depended for their action upon very strong free alkalies. These alkalies, together with waxes and the like, when applied to the hair have exerted a softening action. The amount of free alkali necessary to obtain this efiect has invariably exceeded a non-irritating concentration and the tendency has been to reduce the concentration of alkali in order to avoid irritation, in which case the softening action necessary to obtain permanent straightening has been lost. In the composition of this invention, on the other hand, the principal softening agents are negative radicals and free alkali is neither necessary nor desirable, although nonirritating amounts thereof may be employed. The mineral binder employed with this invention provides the necessary temporary retention of the hair, but at the same time, due to the ease of wetting thereof by the softening solution, the latter has at all times free and complete access to all parts of the hair surface.
In preparing the composition of this invention corpora- Application February 19, 1934, Serial No. 711,988
a soiution of stannous chloride is prepared to which solution suflicient alkali hydroxide, such as sodium hydroxide, is added to convert all of the stannous chloride to sodium stannite. To this is then added sodium polysulfide solution prepared by digesting sulphur in alkali hydroxide solution. To this alkali stannite, alkali sulfide composition is then added a small amount of zinc sulfate, suflicient to combine with all free alkali present forming alkali zincate, which substance, although of minor softening properties, itself substantially enhances the softening properties of the stannite and polysulfide. Inasmuch as the softening property of tin is dependent upon the tin being present in a stannous condition, there is added to the composition suflicient protective reducing agent, such as sodium hyposuliite to prevent atmospheric oxidation of the tin. This solution containing the softening and protective agents is then employed for the purpose of compounding a paste or cream in which the solution is the suspending fluid. The preferred manner of preparing such paste is to add alkali earth oxides directly to the solution. The alkali earth oxide added to the solution becomes hydrated therein and after the elapse of sufli'pient time an extremely fine, smooth, colloidal, mineral binder is formed. Theresult is a paste or cream which is smooth and plastic to a high degree. It is preferred that the proper amount of alkali earth oxide be added to produce a cream just stiff enough to stand alone. This may be varied widely, of course, depending upon the preference of the operator, but it should be borne in mind that the paste should have sufficient mobility so that it can be worked well into a head of hair and at the same time suflicient stiffness to maintain the hair in straightened condition.
In employing the composition described above, the paste is worked thoroughly into the hair and the hair is then combed until it lies in straightenedorder. The composition is then permitted to dry or'partially dry upon the hair. This occurs within an interval of about fifteen minutes to half an hour and may be hastened somewhat by the use of a hot air dryer. During this interval of drying, the hair is held in straightened order by the mineral binder and while so held the softening solution acts upon the hair substance itself. Large amounts of fluid are taken up by the hair, causing it to swell. Under the action of the softening agent the cement substance between hair cells is softened and this allows the cells to shift their relative position so that when the hair again hardens the new position is assumed. The elasticity of the hair returns as shown by its assuming the straight position after being bent, just as the hair prior to any treatment assumes the kinky position after being held straight. At the completion of the drying interval the dried material is preferably rinsed out with clear water. The hair is then combed to proper configuration and dried. The hair so straightened can also be shampooed with soap to remove the composition, if desired, without danger of recurrence of the kinky state, but the rinsing with clear water is more effective. After the hair has been so treated the new configuration of the hair will remain without reversion until replaced by new growth.
A useful addition to the paste as prepared above is a small amount of water-soluble emollient, such as glycerine or triethanolamine, or other substituted amines. When an emollient is employed the hair may be dressed and handled with greater facility after treatment; there is less tendency on the part of the hair to become excessively dry; and the straightening effect is somewhat improved. The emollient is also beneficial in its effect upon the paste, imparting a certain lubricity thereto which makes the paste easier to comb into the hair. The following directions for compounding may sometimes be employed:
Eight parts by weight of sodium hydroxide are dissolved in twelve parts by weight of water. To this is added six parts by weight of sodium polysulfide solution, formed by digesting sulphur in a forty percent solution of sodium hydroxide. To this is then added two parts by weight of stannous chloride contained in twenty-five parts by weight of water. There is then added two parts by weight of zinc sulphate dissolved in twentyfive parts by weight of water, and finally four parts by weight of sodium hyposulfite dissolved in sixteen parts by weight of water is added. A small amount of undissolved solids may remain and the solution as above prepared may be filtered to remove the solids. To about two parts by weight of the above solution is then added approximately one part by weight of MgO. After the elapse of a period of time this mixture sets into a thick paste. This thick paste is then thoroughly stirred while adding to about eighty-five parts by weight thereof approximately five parts of triethanolamine and four parts of glycerine. The paste is now in completed condition, but if through slight departures from the exact proportions or for other reasons the composition is not of exactly the desired consistency, this may be adjusted to either thicken it or thin it, as necessary, by the addition, respectively, of small amounts of MgO or small amounts of additional solution as first prepared.
In compounding the above composition the quantity of stannous chloride may be varied between relatively wide limits without producing an entirely inoperative composition. Some degree of operativeness will be found in the range between one-half to ten parts by weight of stannous chloride. In the case of zinc sulphate, this is also true in approximately the same range. The quantity of sodium hydroxide employed is related to the quantity of zinc and tin present. This can range between two to fifteen parts by weight.. The quantity of hyposulfite may range between three parts by weight and thirty parts by weight. The quantity of polysulfide solution employed may also be varied widely from two parts to twenty parts by weight. The quantity of magnesium oxide employed is entirely dependent upon the consistency of cream desired. This will be found to lie within the approximate neighborhood of three-fourths to two parts by weight of magnesium oxide to two parts by weight of solution, but variation therefrom may be resorted to if a different consistency is desired. The quantity or presence of the emollient is optional, the quantity shown being representative of only one functioning proportion within a wide range. Any quantity of triethanolamine from one-half to fifteen per cent is useful and the quantity of glycerine can vary within one-half to ten per cent.
Due to the chemical reactions which take place in compounding the composition under the above directions, a composition is formed which Will contain from three-tenths to eight per cent of stannous tin compounds, three-tenths to eight per cent of sodium zincate, two to fifteen per cent of sodium hypo-sulfite, and one-half to eighteen per cent of sodium polysulfide in addition to twenty-five to fifty per cent of magnesium hydrate and two to fifteen per cent of triethanolamine and one-half to ten per cent of glycerine, together with some neutral salts, such as sodium chloride and sulfate, and possibly some free alkali.
In the above composition the recognized equivalents of sodium, such as potassium, may be substituted. The sodium hypo-sulfite can be replaced with any other nonpoisonous, non-irritating, mild, reducing agent of sufiicient reducing activity to preferentially accept oxidation in the presence of stannous tin. Such reducing agents will hereinafter be referred to as protective agents. Examples of these are hydroquinone and Na2S.
The hydrated alkaline earth oxide which forms the mineral binder in the composition may be replaced in whole or in part by any well-known equivalent, such as calcium hydrate, and also, at times, as well by complex silicates with or without alumina such as kaolin, bentonite, or other colloidal mineral. Herein the term mineral binder will be employed to mean any of the above substances in a highly divided, suspended state.
What we claim as our invention is:
1. A composition of matter for the straightening of hair comprising three-tenths to eight per cent of basic compounds of stannous tin, threetenths to eight per cent of sodium zincate, two to fifteen per cent of sodium hyposulfite, one-half to eighteen per cent of sodium polysulfide, and twenty-five to fifty per cent of mineral binder.
2. A composition of matter for the straightening of hair comprising a suspension consisting of solid suspended matter and liquid, said liquid containing in the presence of hydroxyl ions and magnesium ions a non-depilating concentration of tin in stannous form as stannite and as stannous hydroxide, alkali polysulfide and alkali zincate, and the suspended matter consists of highly divided mineral binder.
3. The method of straightening obdurately curly hair which consists in applying to the hair a paste consisting in a mineral binder suspended in a softening solution containing from .3 to 8% of basic compound of stannous tin, to 18% of sodium polysulfide, and free hydroxyl mechanically extending the hair for retention in the extended state by the binder while permitting softening solution to remove the elastic tendency of the hair which would return the hair to curly condition, allowing the hair and applied composition to dry, and then removing the dried composition from the hair.
JULIAN Y. MALONE. JOSEPH H. CARROLL. CHARLES R. McKEE.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US711988A US2087953A (en) | 1934-02-19 | 1934-02-19 | Process and composition for rectification of curly hair |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US711988A US2087953A (en) | 1934-02-19 | 1934-02-19 | Process and composition for rectification of curly hair |
Publications (1)
Publication Number | Publication Date |
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US2087953A true US2087953A (en) | 1937-07-27 |
Family
ID=24860330
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US711988A Expired - Lifetime US2087953A (en) | 1934-02-19 | 1934-02-19 | Process and composition for rectification of curly hair |
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US (1) | US2087953A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE970665C (en) * | 1952-08-08 | 1958-10-16 | Kurt Lindner Dr | Process for achieving permanent changes in the shape of human or animal hair |
US2865811A (en) * | 1952-05-02 | 1958-12-23 | Irval Cosmetics Inc | Hair straightener containing a kerating reducing agent, anionic wetting agent and water-soluble soap and method of using same |
US4237910A (en) * | 1979-09-24 | 1980-12-09 | Johnson Products Co., Inc. | Stable hair relaxer |
US5061483A (en) * | 1990-05-01 | 1991-10-29 | Chesebrough-Pond's Inc. | Permanent wave hair compositions containing transition metal oxide compounds |
US5415856A (en) * | 1990-05-08 | 1995-05-16 | Preemptive Advertising Inc. | Hair treatment compositions containing disaccharides |
-
1934
- 1934-02-19 US US711988A patent/US2087953A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2865811A (en) * | 1952-05-02 | 1958-12-23 | Irval Cosmetics Inc | Hair straightener containing a kerating reducing agent, anionic wetting agent and water-soluble soap and method of using same |
DE970665C (en) * | 1952-08-08 | 1958-10-16 | Kurt Lindner Dr | Process for achieving permanent changes in the shape of human or animal hair |
US4237910A (en) * | 1979-09-24 | 1980-12-09 | Johnson Products Co., Inc. | Stable hair relaxer |
US5061483A (en) * | 1990-05-01 | 1991-10-29 | Chesebrough-Pond's Inc. | Permanent wave hair compositions containing transition metal oxide compounds |
US5415856A (en) * | 1990-05-08 | 1995-05-16 | Preemptive Advertising Inc. | Hair treatment compositions containing disaccharides |
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