US2063907A - Method of delustering fabric - Google Patents
Method of delustering fabric Download PDFInfo
- Publication number
- US2063907A US2063907A US303602A US30360228A US2063907A US 2063907 A US2063907 A US 2063907A US 303602 A US303602 A US 303602A US 30360228 A US30360228 A US 30360228A US 2063907 A US2063907 A US 2063907A
- Authority
- US
- United States
- Prior art keywords
- cellulose
- fabric
- treated
- barium
- treating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title description 26
- 238000000034 method Methods 0.000 title description 9
- 239000000463 material Substances 0.000 description 21
- 229920002678 cellulose Polymers 0.000 description 20
- 239000001913 cellulose Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 15
- 239000004753 textile Substances 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
- 230000008961 swelling Effects 0.000 description 10
- 229920002301 cellulose acetate Polymers 0.000 description 8
- 239000002932 luster Substances 0.000 description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 6
- 238000011282 treatment Methods 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 150000001342 alkaline earth metals Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- -1 sulphate ions Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 150000001553 barium compounds Chemical class 0.000 description 3
- 238000010409 ironing Methods 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- KGINNICDOZCYOA-UHFFFAOYSA-N barium;sulfurocyanidic acid Chemical compound [Ba].OS(=O)(=O)C#N KGINNICDOZCYOA-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- LKZCRGABYQYUFX-UHFFFAOYSA-L barium(2+);dithiocyanate Chemical compound [Ba+2].[S-]C#N.[S-]C#N LKZCRGABYQYUFX-UHFFFAOYSA-L 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000001761 ethyl methyl cellulose Substances 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BZWKPZBXAMTXNQ-UHFFFAOYSA-N sulfurocyanidic acid Chemical class OS(=O)(=O)C#N BZWKPZBXAMTXNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
Definitions
- This invention relates to the treatment of textile materials containing organic derivatives of cellulose so as to subdue the luster of the same.
- An object of our invention is to reduce the luster of textile materials containing organic derivatives of cellulose in such a manner that the deluster effect is comparatively permanent.
- Another object ofour invention is to deluster textile materials containing organic derivatives of cellulose by precipitating an opaque and insoluble salt in the textile material.
- a textile material containing organic derivatives of cellulose with a solution of a salt of a metal that produces a white and opaque salt, which is itself a swelling agent for the organic derivatives of cellulose, or in the presence of a foreign swelling agent, and then treat the same with a solution that is adapted to precipitate the metal in the form of an opaque and white salt.
- the textfle material to be treated in accordance with our invention may be in the form of yarns in a suitable package such as in hanks, on bobbins, etc.
- a fabric containing yarns of such organic derivatives of cellulose may contain any organic derivatives of cellulose such as cellulose esters and cellulose ethers.
- cellulose esters are cellulose acetate, cellulose formate, cellulose propionate and cellulose butyrate
- examples of cellulose ethers are ethyl cellulose, methyl cellulose and benzy cellulose.
- the fabric need not consist wholly of yarns of such organic derivatives but may also contain yarns of other material such as cotton, silk, wool, etc.
- solutions of salts of the alkaline earth metals such as barium, calcium or strontium produce satisfactory results.
- the solutions of such salts may be of themselves swelling agents. Examples of such salts are the sulfocyanides of barium or other alkaline earth metal.
- salts of such metals such as the chloride or chlorate of barium may be employed, which of themselves are not swelling agents.
- the treat- 10 ing bath may also contain a swelling agent such as formic acid, acetic acid, acetone, etc.
- the textile material may be first treated with a bath containing these swelling agents and then with a bath containing the salts of the 15 alkaline earth metals.
- the textile material is then treated with a solution that is adapted to precipitate the metal in the form of an 20 opaque and white salt.
- Suitable reagents for this purpose are aqueous solutions of sulphuric acid, phosphoric acid or the soluble salts of these acids such as the sulphates or phosphates of sodium, potassium, or ammonium.
- the textile materials produced by our invention have a subdued luster varying from complete deluster to partial deluster depending on the concentration and time of treatment, and this deluster effect is permanent. Fabrics when treated by our invention may be ironed while damp or subjected to dry'steam or other relustering agent without becoming relustered.
- the textile material to be treated by our invention may be partially saponified and particularly intensely surface saponified.
- This partial saponification step may be carried out on the textile material either prior to the delustering treatment or subsequent thereto.
- the fabrics when treated in accordance with our invention have an afiinity for organic derivatives of cellulose dyestuffs and basic dyestuffs, and also have an increased aifinity for direct cotton colors and for acid colors.
- Example I A fabric consisting solely of yarns of cellulose acetate is treated for one hour at 70 C. in a 25 'Ifw. solution of barium thiocyanate. It is then treated for 20 minutes in the cold in a 1% solution of sulphuric acid, after which it is rinsed and dried. The fabric so treated is quite well delustered, which luster is not appreciably affected by ironing or washing.
- Example II A fabric consisting wholly of cellulose acetate is first treated for one hour at 50 C. in an aqueous solution containing 20% of formic acid, which acts as a swelling agent. It is then treated for one hour at 70 C. in a solution of barium chloride and is then treated for 20 minutes in the cold in a 1% aqueous solution of phosphoric acid and is then rinsed and dried.
- the fabric is satisfactory delustered and is not appreciably relustered by ironing, either wet or dry or by washing.
- the fabric resulting from the treatments of the foregoing examples contains filaments wherein the barium compound, which is a pigment-like inorganic material, occurs as small particles subnierged in and widely distributed throughout the mass of the filaments and the quantity and distribution of the particles is such as not to materially impair the continuity of the mass of the filaments. Moreover the amount of barium compound that becomes incorporated in the filaments is a small percentage of the mass of the filaments.
- Such barium compounds are inert to the action of chemicals used in the manufacture, dyeing and bleaching of the filaments or fabrics.
- Method of treating fabric containing yarns of organic derivatives of cellulose comprising treating such fabric with a solution of barium sulphocyanide and then treating the fabric with a solution containing sulphate ions, whereby barium sulphate is precipitated within the fibres of such yarn.
- Method of treating fabric containing yarns of cellulose acetate comprising treating such fabric with a solution of barium sulphocyanide and then treating the fabric with a solution containing sulphate ions, whereby barium sulphate is precipitated within the fibres of such yarn.
- Method of treating fabric containing yarns of organic derivatives of cellulose comprising treating such fabric with a solution of an alkaline earth metal sulphocyanide which is a swelling agent for the derivative of cellulose and then treating the fabric with a solution containing ions selected from the group consisting of sulphate and phosphate ions, whereby an insoluble alkaline earth metal compound is precipitated within the fibres of such yarn.
- Method of treating fabric containing yarns of cellulose acetate comprising treating such fabric with a solution of an alkaline earth metal sulphocyanide which is a swelling agent for the cellulose acetate and then treating the fabric with a solution containing ions selected from the group consisting of sulphate and phosphate ions, where-
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE366315D BE366315A (ko) | 1928-09-01 | ||
BE363365D BE363365A (ko) | 1928-09-01 | ||
US303602A US2063907A (en) | 1928-09-01 | 1928-09-01 | Method of delustering fabric |
FR681060D FR681060A (fr) | 1928-09-01 | 1929-08-31 | Perfectionnements au traitement de matières artificielles |
GB26640/29A GB318467A (en) | 1928-09-01 | 1929-09-02 | Improvements in the treatment of materials made of or containing organic derivatives of cellulose |
GB3812129A GB344093A (en) | 1928-09-01 | 1929-12-12 | Improvements in the manufacture of materials made of or containing organic derivatives of cellulose |
FR37813D FR37813E (fr) | 1928-09-01 | 1929-12-17 | Perfectionnements au traitement de matières artificielles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US303602A US2063907A (en) | 1928-09-01 | 1928-09-01 | Method of delustering fabric |
Publications (1)
Publication Number | Publication Date |
---|---|
US2063907A true US2063907A (en) | 1936-12-15 |
Family
ID=23172849
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US303602A Expired - Lifetime US2063907A (en) | 1928-09-01 | 1928-09-01 | Method of delustering fabric |
Country Status (4)
Country | Link |
---|---|
US (1) | US2063907A (ko) |
BE (1) | BE363365A (ko) |
FR (1) | FR681060A (ko) |
GB (1) | GB318467A (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2966428A (en) * | 1956-04-05 | 1960-12-27 | Celanese Corp | Heat stable saponified cellulose ester filamentary material and process of making |
-
0
- BE BE363365D patent/BE363365A/xx unknown
-
1928
- 1928-09-01 US US303602A patent/US2063907A/en not_active Expired - Lifetime
-
1929
- 1929-08-31 FR FR681060D patent/FR681060A/fr not_active Expired
- 1929-09-02 GB GB26640/29A patent/GB318467A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2966428A (en) * | 1956-04-05 | 1960-12-27 | Celanese Corp | Heat stable saponified cellulose ester filamentary material and process of making |
Also Published As
Publication number | Publication date |
---|---|
FR681060A (fr) | 1930-05-09 |
BE363365A (ko) | |
GB318467A (en) | 1931-01-02 |
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