GB318467A - Improvements in the treatment of materials made of or containing organic derivatives of cellulose - Google Patents
Improvements in the treatment of materials made of or containing organic derivatives of celluloseInfo
- Publication number
- GB318467A GB318467A GB26640/29A GB2664029A GB318467A GB 318467 A GB318467 A GB 318467A GB 26640/29 A GB26640/29 A GB 26640/29A GB 2664029 A GB2664029 A GB 2664029A GB 318467 A GB318467 A GB 318467A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cellulose
- solution
- salts
- barium
- metallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002678 cellulose Polymers 0.000 title abstract 8
- 239000000463 material Substances 0.000 title abstract 7
- 239000001913 cellulose Substances 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 5
- 150000003839 salts Chemical class 0.000 abstract 5
- 239000000243 solution Substances 0.000 abstract 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 3
- 229920003086 cellulose ether Polymers 0.000 abstract 3
- 230000001376 precipitating effect Effects 0.000 abstract 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 2
- 229910052788 barium Inorganic materials 0.000 abstract 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 abstract 2
- 229910001626 barium chloride Inorganic materials 0.000 abstract 2
- 229920002301 cellulose acetate Polymers 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 235000019253 formic acid Nutrition 0.000 abstract 2
- 239000001117 sulphuric acid Substances 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- 230000008961 swelling Effects 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 229920013683 Celanese Polymers 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- 239000000980 acid dye Substances 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- KGINNICDOZCYOA-UHFFFAOYSA-N barium;sulfurocyanidic acid Chemical compound [Ba].OS(=O)(=O)C#N KGINNICDOZCYOA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000981 basic dye Substances 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000000982 direct dye Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 238000010409 ironing Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- 238000007127 saponification reaction Methods 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- BZWKPZBXAMTXNQ-UHFFFAOYSA-N sulfurocyanidic acid Chemical class OS(=O)(=O)C#N BZWKPZBXAMTXNQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
318,467. British Celanese, Ltd., (Assignees of Platt, H.; and Dreyfus, C.). Sept. 1, 1928, [Convention date]. Yarns, treating with liquids, gases, and vapours. -The lustre of yarns, fabrics, or other materials made of or containing organic derivatives of cellulose, for example cellulose acetate or other cellulose esters or ethers, is reduced by precipitating therein insoluble opaque salts, preferably white, by the interaction of reagents successively applied thereto. Insoluble salts, particularly sulphates or phosphates, of alkaline earth metals, such as barium, calcium or strontium, give particularly good results. The precipitation may be effected by first treating the material with a soluble metallic salt and thereafter with a precipitating agent, the metallic radicles being preferably introduced while the material is in a swollen condition. For this purpose metallic salts which are themselves swelling agents may be employed, for example sulphocyanides of barium or other alkaline earth metals, or swelling agents such as formic acid, acetic acid or acetone may be caused to act upon the material either prior to or simultaneously with the treatment with a metallic salt solution, for example a solution of barium chloride or chlorate. As precipitating agents, aqueous solutions of sulphuric or phosphoric acid or of their soluble salts, such as the sodium, potassium or ammonium salts, may be used. Cellulose ester materials may, in addition, be subjected to a saponification, preferably superficial, either before or after the application of the metallic radicle, whereby they acquire an affinity for direct and acid dyes, while retaining their affinity for the dyes normally applied to cellulose esters and for basic dyes. The delustring effects produced are permanent and are not appreciably affected by ironing or washing, or by treatment with dry steam or other relustring agents. The process may be applied to other cellulose esters besides the acetate, for example the formate, propionate or butyrate, or to cellulose ethers, such as methyl, ethyl and benzyl cellulose, as well as to mixed materials containing other fibres, such as cotton, silk or wool, in addition to cellulose esters or ethers. In examples, cellulose acetate fabrics are (1) treated first with a solution of barium sulphocyanide, then with a 1 per cent sulphuric acid, and (2) treated first with 20 per cent formic acid solution, then with barium chloride solution and finally with 1 per cent phosphoric acid solution. Specifications 258,874, 259,899, 279,502, 281,084, 284,798, 285,941, 303,128, 323,501 and 323,785 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US303602A US2063907A (en) | 1928-09-01 | 1928-09-01 | Method of delustering fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB318467A true GB318467A (en) | 1931-01-02 |
Family
ID=23172849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB26640/29A Expired GB318467A (en) | 1928-09-01 | 1929-09-02 | Improvements in the treatment of materials made of or containing organic derivatives of cellulose |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2063907A (en) |
| BE (1) | BE363365A (en) |
| FR (1) | FR681060A (en) |
| GB (1) | GB318467A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2966428A (en) * | 1956-04-05 | 1960-12-27 | Celanese Corp | Heat stable saponified cellulose ester filamentary material and process of making |
-
0
- BE BE363365D patent/BE363365A/xx unknown
-
1928
- 1928-09-01 US US303602A patent/US2063907A/en not_active Expired - Lifetime
-
1929
- 1929-08-31 FR FR681060D patent/FR681060A/en not_active Expired
- 1929-09-02 GB GB26640/29A patent/GB318467A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE363365A (en) | |
| US2063907A (en) | 1936-12-15 |
| FR681060A (en) | 1930-05-09 |
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