US2062427A - Copper-tin-phosphorus-zinc alloy - Google Patents

Copper-tin-phosphorus-zinc alloy Download PDF

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Publication number
US2062427A
US2062427A US98064A US9806436A US2062427A US 2062427 A US2062427 A US 2062427A US 98064 A US98064 A US 98064A US 9806436 A US9806436 A US 9806436A US 2062427 A US2062427 A US 2062427A
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United States
Prior art keywords
phosphorus
copper
tin
alloy
zinc
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Expired - Lifetime
Application number
US98064A
Inventor
Harold L Pierson
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American Brass Co
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American Brass Co
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Filing date
Publication date
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Priority to US98064A priority Critical patent/US2062427A/en
Application granted granted Critical
Publication of US2062427A publication Critical patent/US2062427A/en
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Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent

Definitions

  • the preferred specific alloy has about the following composition, 81% copper, 1% tin, 0.15% to 0.5% phosphorus and the remainder zinc.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Prevention Of Electric Corrosion (AREA)

Description

Patented Dec. 1, 1936 UNITED STATES- COPPER-TIN-PHOS PHOBUS-ZINC ALLOY Harold L. Pierson; Torrington, Conn., assignor to The American Brass Company, Conn., a corporation of Connecticut Waterbury,
No Drawing. Application August 26, 1936,
Serial No. 98,064
5 Claims. 75-157) This invention relates. to a copper base alloy, and more particularly to a copper base alloy containing tin, zinc and phosphorus. covered that by adding a relatively large amount of phosphorus to a copper-zinc-tin alloy containing about 70 to 90 percent copper the phosphorus imparts improved spring prperties to the alloy which are ordinarily obtained by large amounts of tin. That is a smaller amount of phosphorus has a similar effect to a larger amount of tin so that the tin content may be greatly reduced.
The alloy has a copper content of from about 70% to 90%, a tin content of from about 0.25%
to 1%, a phosphorus content of about 0.15% to 0.5% and balance zinc. With additions of small amounts of phosphorus up to about 0.15% there is a gradual and only small improvement, but at about 0.15% phosphorus there is a very marked improvement. The range of phosphorus may be from about 0.15% to about 0.5% with the greatest improvement at about 0.25% phosphorus. At about 0.15% phosphorus and up to about 0.5% there is also a material increase in the tensile strength of the alloy.
The preferred specific alloy has about the following composition, 81% copper, 1% tin, 0.15% to 0.5% phosphorus and the remainder zinc.
Another specific alloy which has been found to be very useful is of about the following composition, 89% copper, 1% tin, 0.15% to 0.5% phosphorus, and balance zinc.
Still another very useful alloy is of about the following composition, 88.25% copper, 0.75% tin,
0.15% to 0.5% phosphorus and balance zinc.
The alloy may be hot or cold rolled into plate,
sheet, strip, rodin fact, all rolled shapes. It
may be forged hot or cold as in die pressing or I have dis-- into shapes such as bars and rods.
The alloy, because of its hot and cold working properties, can be used to advantage in the manufacture of bolts,'nuts, U-bolts and similar articles. 5
The alloy may be soldered, welded or brazed and is thus suitable for use in the production of all types of fabricated articles either by gas, electric or other welding methods. The alloy may also be used as a filler material for welding 10 or brazing.
The alloy has good corrosion resistance being equal to or better than copper (depending upon the corrosive agent and the method of its use) and may obviously be used to advantage wherever 15 corrosion resistant properties are desired with the added advantages of strength, hardness and wear resistance superior to copper.
Having thus set forth the nature of my invention, what I claim is: 20 l. A copper base alloy composed of about to copper, 0.25% to 1%tin, 0.15% to 0.5%
phosphorus and balance zinc.
2. A copper base alloy composed of about 01% copper, 1% tin, 0.15% to 0.5% phosphorus and 25 balance zinc.
3. A copper base base alloy composed of about 89% copper, 1% tin, 0.15% to 0.5% phosphorus and balance zinc. T
'4. A copper base alloy composed of about 30 88.25% copper, 0.75% tin, 0.15% to 0.5% phosphorus and balance zinc.
5. A copper base alloy composed of about 70% to 90% copper, 0.25% to 1% tin, 0.15% to 0.5% phosphorus, and balance substantially zinc, said 35 alloy having improved strength and spring properties over the same alloy without the phosphorus.
' HAROLD L. PIERSON.
US98064A 1936-08-26 1936-08-26 Copper-tin-phosphorus-zinc alloy Expired - Lifetime US2062427A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US98064A US2062427A (en) 1936-08-26 1936-08-26 Copper-tin-phosphorus-zinc alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US98064A US2062427A (en) 1936-08-26 1936-08-26 Copper-tin-phosphorus-zinc alloy

Publications (1)

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US2062427A true US2062427A (en) 1936-12-01

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5820701A (en) * 1996-11-07 1998-10-13 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
US5865910A (en) * 1996-11-07 1999-02-02 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
US5893953A (en) * 1997-09-16 1999-04-13 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
US6436206B1 (en) 1999-04-01 2002-08-20 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
US6471792B1 (en) 1998-11-16 2002-10-29 Olin Corporation Stress relaxation resistant brass
CN100389218C (en) * 2006-01-13 2008-05-21 菏泽广源铜带股份有限公司 Method for manufacturing anti-corrosion alloy brass H65 and copper belt thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5820701A (en) * 1996-11-07 1998-10-13 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
US5865910A (en) * 1996-11-07 1999-02-02 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
US5893953A (en) * 1997-09-16 1999-04-13 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
US6471792B1 (en) 1998-11-16 2002-10-29 Olin Corporation Stress relaxation resistant brass
US6436206B1 (en) 1999-04-01 2002-08-20 Waterbury Rolling Mills, Inc. Copper alloy and process for obtaining same
CN100389218C (en) * 2006-01-13 2008-05-21 菏泽广源铜带股份有限公司 Method for manufacturing anti-corrosion alloy brass H65 and copper belt thereof

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