US20230041423A1 - Process and Device for Producing a Coated Structural Component - Google Patents

Process and Device for Producing a Coated Structural Component Download PDF

Info

Publication number
US20230041423A1
US20230041423A1 US17/879,999 US202217879999A US2023041423A1 US 20230041423 A1 US20230041423 A1 US 20230041423A1 US 202217879999 A US202217879999 A US 202217879999A US 2023041423 A1 US2023041423 A1 US 2023041423A1
Authority
US
United States
Prior art keywords
component
molded component
deburring
molded
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US17/879,999
Inventor
Markus Pfestorf
Christian Rauber
Nora Unger
Jian An
Hanjie Chen
Zhen Yu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Pressler Advanced Forming Technologies Co Ltd
Bayerische Motoren Werke AG
Original Assignee
Suzhou Pressler Advanced Forming Technologies Co Ltd
Bayerische Motoren Werke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Pressler Advanced Forming Technologies Co Ltd, Bayerische Motoren Werke AG filed Critical Suzhou Pressler Advanced Forming Technologies Co Ltd
Assigned to Suzhou Pressler Advanced Forming Technologies Co. Ltd. reassignment Suzhou Pressler Advanced Forming Technologies Co. Ltd. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: AN, Jian, CHEN, HANJIE, YU, ZHEN
Assigned to BAYERISCHE MOTOREN WERKE AKTIENGESELLSCHAFT reassignment BAYERISCHE MOTOREN WERKE AKTIENGESELLSCHAFT ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PFESTORF, MARKUS, RAUBER, CHRISTIAN, Unger, Nora
Publication of US20230041423A1 publication Critical patent/US20230041423A1/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F3/00Electrolytic etching or polishing
    • C25F3/16Polishing
    • C25F3/22Polishing of heavy metals
    • C25F3/24Polishing of heavy metals of iron or steel
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/22Electroplating: Baths therefor from solutions of zinc
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F3/00Electrolytic etching or polishing
    • C25F3/16Polishing
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F7/00Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/22Servicing or operating apparatus or multistep processes

Definitions

  • the present invention relates to a method of manufacturing a coated structural component for a vehicle.
  • the invention further relates to an apparatus, in particular an industrial plant, for producing such a structural component.
  • hot formed components are used for the production of body-in-white.
  • Various process variants are known for the production of formed components.
  • uncoated sheet metal components are used which are hot formed and hardened in a so-called direct process from a flat uncoated sheet metal.
  • sheet metal components are coated with an alloy, for example an aluminum-silicon alloy, in a steel mill and then also hot-formed and hardened in a direct process.
  • This variant is by far the most commonly used in practice.
  • coated, for example galvanized sheet metal components are used, which are cold formed and trimmed to the desired dimensions. Only then is the component heated and hardened in a tool. This process is called the indirect process.
  • the build-up of oxides in the tool leads to grooves in the component as well as to the throw-up of material in the edge region of the grooves.
  • the throw-up can be sharp-edged and/or form peaks. If the peaks and/or throw-ups are too high, they can no longer be adequately covered by a subsequent and/or additional coating. In the event of subsequent stress during the use phase of the vehicle due to moisture and/or salt for example, there is a risk that the structural component will begin to corrode starting from these peaks. The peaks should therefore be prevented or at least reduced as far as possible.
  • a method of manufacturing a coated structural component for a vehicle comprises the following steps/stages:
  • the process of electrochemical deburring may advantageously be implemented in a direct process for manufacturing a structural component for a vehicle. That is, the method is particularly to be understood as a method for manufacturing a coated structural component for a vehicle according to a direct process.
  • structural components with an improved surface quality in particular without peaks and/or throw-ups which can subsequently lead to damages to the structural component, can thus be created in a simple and reliable manner.
  • a correspondingly advantageous corrosion resistance can be achieved by a corrosion protection layer covering the entire surface. Due to the electrochemical deburring, a relatively thin corrosion protection layer is already sufficient to achieve the desired surface coverage.
  • a further advantage in the procedure according to the invention is that no special precautions need to be taken with respect to the base component during hot forming. That is, no special temperature and/or heating curves need to be observed and/or restrictions in this respect need to be taken into account.
  • the heating process can thus be carried out in a accordingly simple manner.
  • an uncoated base component preferably in the form of a sheet metal component
  • a simple sheet metal component in particular a simple sheet steel component, such as a sheet metal component made of 22MnB5 steel or of manganese-boron steel having a tensile strength of about 2000 MPa, may be used.
  • the sheet metal component may be understood as a circuit board.
  • the base component may have a thickness in a range between 0.5 mm and 6 mm, in particular in a range between 0.7 mm and 3 mm.
  • the base component may have different sheet thicknesses at different locations and/or different materials at different locations within the specified range.
  • the base component may have different strengths at different locations, which may be achieved, for example, by different cooling curves.
  • the electrochemical deburring and the electrolytic application of the corrosion protection layer are preferably carried out directly one after the other. That is, right after the molded component has been electrochemically deburred, it can be directly moved for the electrolytic application of the corrosion protection layer, for example into an immersion bath and/or at least partially into a suitable electrolyte.
  • Hot forming is preferably performed in a direct process.
  • the base component is first heated to a pre-definable temperature, for example to a temperature in a range between 800° C. and 1000° C., and then formed or shaped into the desired shape.
  • a pre-definable temperature for example to a temperature in a range between 800° C. and 1000° C.
  • scaling of the base component can be reduced by using an inert gas in the furnace or by using a vacuum furnace.
  • the structural component can be understood in particular as a body component for a vehicle. Within the scope of the process, several structural components can also be produced simultaneously. In particular, several molded components can be electro-chemically deburred at the same time.
  • the molded component to be deburred is preferably suspended in a rack.
  • the cathode or a plurality of cathode parts can be selectively positioned in the rack for smoothing or deburring the desired area on the molded component.
  • the cathode or cathode portions may follow the geometry of the molded component.
  • the cathode comprises an electrically conductive material, in particular stainless steel or titanium.
  • the cathode is preferably provided as a flat or wire-shaped component.
  • the molded component forms the anode.
  • the electrochemical deburring is preferably performed selectively on area sections of the molded component, that is in particular not or at least not selectively on end edges, end portions and/or projections of the molded component.
  • the molded component has at least one forming edge with a forming radius produced by the hot forming, wherein the electrochemical deburring is carried out for deburring at least one area section adjacent to the at least one forming edge, that is, for selectively removing, for example, grooves in the area sections adjacent to the at least one forming edge.
  • the electrochemical deburring is selectively carried out on area sections of the molded component which are configured adjacent to the at least one forming edge, and in particular not, or at least not selectively, on the at least one forming edge, end edges and/or end portions of the molded component.
  • the electrolyte, the temperature of the electrolyte, the treatment time for the deburring and in particular the positioning of the at least one cathode on the molded component are designed or determined with reference to the at least one area section to be deburred.
  • electrolytically deburr complex components and/or in particular their cut and/or manufacturing edges or end edges it is generally known to electrolytically deburr complex components and/or in particular their cut and/or manufacturing edges or end edges.
  • electrochemical deburring is now used specifically for deburring segments and/or surfaces of the component which are subjected to relative movement between the workpiece and the tool during forming and are thus subject to the potential risk of grooving. According to the invention, this can be easily and effectively integrated into the previously known manufacturing process comprising electrochemical coating of a molded component.
  • At least two forming edges can be produced by the hot forming, wherein the electrochemical deburring is carried out for deburring at least one area section between the at least two forming edges.
  • the area section may be understood in particular as a straight and/or planar area section or, apart from any grooves, a straight, planar and/or relatively smooth area section.
  • the forming radius may be understood as a bending radius, an inner radius and/or an outer radius of the at least one forming edge and/or at the at least one forming edge.
  • a zinc coating is applied as a corrosion protection layer.
  • the zinc coating may be understood as a zinc-containing coating and/or alloy.
  • the application of a corrosion protection layer can thus be understood as galvanizing.
  • the zinc coating is applied as part of an electrolytic coating process.
  • the latter may remain in the rack described above.
  • the molded component with the rack is immersed in a suitable electrolyte and is connected as the cathode.
  • the purest possible zinc is used for the anode. Additional anodes can be positioned close to the component to specifically influence the zinc layer.
  • the molded component represents the anode and is at least partially immersed in an electrically conductive liquid, i.e. an electrolyte, during the process.
  • the temperature of the electrolyte may be or may be set in a range between 30° C. and 50° C. during the deburring process.
  • the cathode and/or cathode elements may be adapted to the geometry of the component for this purpose. Compared to conventional galvanizing processes of uncoated and preformed sheet metal components, significantly smoother surfaces can be coated evenly and closed with a relatively thin zinc layer.
  • a cathodic dip coating is applied to the coated molded component after the application of the zinc coating. It has been shown that a cathodic dip coating applied in addition to, for example, a zinc coating does regularly not sufficiently cover the surface of the structural component due to burrs in the molded component or in the originally formed base component. Thus, in particular, edges and/or tips which may still be pronounced in the first corrosion coating can no longer be sufficiently covered by the relatively thin cathodic dip coating. In other words, the tips of the grooves and/or ejections, which are usually still covered with zinc, are only insufficiently covered or not covered at all by the subsequent cathodic dip coating. These spots can relatively quickly be the starting point of corrosion. By deburring according to the invention before the first coating process, this problem can be satisfactorily taken into account.
  • a layer thickness of the cathodic dip coating in a range between 10 ⁇ m and 40 ⁇ m can already be sufficient to provide a cathodic dip coating covering the entire surface.
  • the cathodic dip coating can be applied with a layer thickness in a range between 10 ⁇ m and 40 ⁇ m, in particular in a range between 15 ⁇ m and 25 ⁇ m.
  • the electrochemical deburring of the molded component is carried out by means of a cathode and an anode, wherein the molded component is used as at least a part of the anode and the cathode for the electrochemical deburring is positioned at a distance of less than 30 mm from at least one forming edge and/or a surface of the molded component to be deburred at the forming edge.
  • the cathode may be positioned at a distance in a range between 5 mm and 30 mm, in particular between 10 mm and 20 mm, from the at least one forming edge and/or surface.
  • the cathode may comprise a plurality of cathode elements.
  • the cathode may be configured and/or fixed in a tool, for example in the form of a rack, in which the molded component is at least partially positioned in an electrolyte in a predefined position for electrochemical deburring.
  • the electrochemical deburring can be performed with an electrolytic current density in a range between 5 A/dm 2 and 15 A/dm 2 .
  • An operating time or time duration for the electrochemical deburring is preferably set to a value between 3 minutes and 12 minutes, in particular between 5 minutes and 10 minutes.
  • the electrochemical deburring may be carried out for a corresponding period of time.
  • the electrodes used, the currents used and/or the electrolyte may be adjusted and/or positioned accordingly. With the above-described operating time and/or current density, advantageous deburring can be performed.
  • an electrolyte comprising sodium sulfate and sodium chloride is used in a method according to the present invention for electrochemical deburring, wherein at least twice as much sodium sulfate is used as sodium chloride.
  • an apparatus for carrying out a method, as described in detail above, for producing a deburred and coated structural component in the form of a body component for a vehicle is provided.
  • the apparatus in particular in the form of an industrial plant, may comprise a provisioning tool for providing the basic structural component.
  • the apparatus further comprises a forming tool for forming the base component into the formed component, a deburring tool for performing the electrochemical deburring and/or a coating tool for performing the electrolytic application of the corrosion protection layer and/or the cathodic dip coating.
  • FIG. 1 a flow chart explaining a process according to one embodiment of the present invention
  • FIG. 2 a flow chart explaining further details of the process according to the invention
  • FIG. 3 a flow chart explaining an exemplary procedure for manufacturing a structural component according to the invention.
  • FIG. 4 a formed structural component known in the prior art.
  • FIG. 1 shows the various process steps for manufacturing a structural component 10 for a motor vehicle according to a preferred embodiment.
  • base components 11 having a thickness of about 1.4 mm are first cut from a coil 18 .
  • the sheet metal components are then heated to about 900° C. in a furnace 22 , and then formed into the desired shape by a forming tool 20 . That is, the heated and uncoated base components 11 in the form of blanks are formed into molded components 12 by the forming tool 20 . Even before the molded components are now coated, they are trimmed and then electrochemically deburred.
  • the molded component 12 which forms an anode 17 via the rack for suspending the molded component 12 in the electrolyte, is positioned on a cathode 16 or on plate-shaped cathode components. More specifically, the cathode 16 or plate-shaped cathode components are positioned at a distance of about 10 mm from the molded component 12 , respectively, at an area section 14 between two forming edges 15 on the surfaces to be deburred.
  • Electrochemical deburring is carried out with an electrolytic current density of approx. 10 A/dm 2 for approx. 8 minutes.
  • the electrolyte used is a liquid containing about 180g/I sodium sulfate and 50g/I sodium chloride at a temperature of about 40° C.
  • the electrochemically deburred molded component 12 is coated with a corrosion protection layer 13 shown in FIG. 2 to produce the structural component 10 .
  • a zinc coating is applied to the deburred molded component 12 by moving the deburred molded component 12 through an electrolyte 19 .
  • a cathodic dip coating 21 shown in FIG. 2 is also applied to the coated molded component 12 with a coating thickness of about 20 ⁇ m over the entire surface.
  • the molded component 12 or structural component 10 coated with the corrosion protection layer 13 is moved through a cathodic dip coating bath 23 .
  • the tools and aids for carrying out the process shown in FIG. 1 may be understood as components of an apparatus for carrying out the process and thus for producing the deburred and coated structural component 10 .
  • FIG. 2 shows the deburring and coating process in further detail.
  • the molded component 12 has edges and peaks that protrude more than average in the area of an area section 14 upon closer inspection. These are removed or reduced and/or smoothed by the electrochemical deburring process.
  • the corrosion protection layer 13 is applied in the form of the zinc coating.
  • the cathodic dip coating 21 is applied.
  • a first step 51 the coil 18 is provided, from which, in a second step S 2 , the base component 11 is then provided in the form of a circuit board.
  • the base component 11 is now heated to about 900° C. in step S 3 , and formed and press-hardened in step S 4 .
  • the base component 11 is first cold formed in step S 2 a , which is performed after step S 2 , and then trimmed to the desired shape in step S 2 b .
  • heating according to step S 3 follows only thereafter. Step S 2 b can initially be omitted in the indirect process.
  • step S 3 is followed by trimming the molded component 12 in step S 4 and cleaning the molded component 12 in step S 5 .
  • step S 6 the molded component 12 is now cleaned and, in this process, electrochemically deburred as described in detail above.
  • steps S 4 and S 5 may be skipped.
  • step S 7 galvanizing follows.
  • the molded component 12 can already be considered as the structural component 10 described above.
  • Step S 7 is followed by annealing in step S 8 .
  • the cleaned, galvanized and annealed structural component 10 is now oiled in step S 9 to produce a transport protection.
  • step S 10 an assembly of possible sub-components of the structural component 10 may take place.
  • step S 11 a further cleaning process takes place.
  • the structural component 10 is coated with a cathodic dip coating 21 in step S 12 , which up to this point may also in principle still be regarded as a molded component 12 .
  • FIG. 4 shows a prior art structural component 10 a in which the molded component 12 has not been deburred prior to galvanizing. In this case, the edges and tips are still covered by the first corrosion protection layer 13 . However, the cathodic dip coating 21 is penetrated by the anti-corrosion layer 13 , as a result of which the structural component 10 a has only a correspondingly lower corrosion resistance.

Abstract

The present invention relates to a method of manufacturing a coated structural component (10) for a vehicle, comprising the steps of: providing a base component (11), hot forming the base component (11) into a molded component (12), electrochemically deburring the molded component (12), and electrolytically applying a corrosion protection layer (13) to the deburred molded component (12) to produce the structural component (10). The invention further relates to an apparatus for carrying out a method according to the invention for producing a deburred and coated structural component.

Description

  • The present invention relates to a method of manufacturing a coated structural component for a vehicle. The invention further relates to an apparatus, in particular an industrial plant, for producing such a structural component.
  • In the automotive industry, hot formed components are used for the production of body-in-white. Various process variants are known for the production of formed components. On the one hand, uncoated sheet metal components are used which are hot formed and hardened in a so-called direct process from a flat uncoated sheet metal. According to another variant, sheet metal components are coated with an alloy, for example an aluminum-silicon alloy, in a steel mill and then also hot-formed and hardened in a direct process. This variant is by far the most commonly used in practice. As an alternative to this process, coated, for example galvanized sheet metal, components are used, which are cold formed and trimmed to the desired dimensions. Only then is the component heated and hardened in a tool. This process is called the indirect process.
  • In practice, direct process methods are preferred because they are generally faster and easier to carry out, and are more cost-effective due to lower tool investments. As an alternative to the processes described above, a process was developed in which the sheet metal components to be produced are first hot formed in the direct process and then electrolytically coated with a corrosion protection layer. In order to drive out any hydrogen from the material, the components are then annealed. The problem, however, is that an oxide layer of the sheet metal components, which is formed when heated to 900° C. for example, regularly flakes off during the forming process. This means that the formation of oxides on the circuit board before it is inserted into the tool cannot usually be completely avoided. The build-up of oxides in the tool leads to grooves in the component as well as to the throw-up of material in the edge region of the grooves. The throw-up can be sharp-edged and/or form peaks. If the peaks and/or throw-ups are too high, they can no longer be adequately covered by a subsequent and/or additional coating. In the event of subsequent stress during the use phase of the vehicle due to moisture and/or salt for example, there is a risk that the structural component will begin to corrode starting from these peaks. The peaks should therefore be prevented or at least reduced as far as possible.
  • It is an object of the present invention to at least partially address the foregoing problem. In particular, it is an object of the present invention to provide a method and an apparatus for producing a coated structural component made from a sheet metal component while avoiding or reducing peaks and/or throw-ups.
  • The preceding task is solved by the patent claims. In particular, the foregoing problem is solved by the method as described and claimed herein and the device as described and claimed herein. Further advantages of the invention result from the subclaims, the description and the figures. In this context, features described in connection with the method naturally also apply in connection with the apparatus according to the invention and vice versa in each case, so that reference is and/or can always be made mutually with regard to the disclosure concerning the individual aspects of the invention.
  • In accordance with a first aspect of the present invention, a method of manufacturing a coated structural component for a vehicle is provided. The method comprises the following steps/stages:
      • providing a base component,
      • hot forming of the base component into a molded component,
      • electrochemical deburring of the molded component, and
      • electrolytic application of a corrosion protection layer to the deburred molded component.
  • In the context of the present invention, it has been recognized that the process of electrochemical deburring may advantageously be implemented in a direct process for manufacturing a structural component for a vehicle. That is, the method is particularly to be understood as a method for manufacturing a coated structural component for a vehicle according to a direct process. Compared to conventional forming processes, structural components with an improved surface quality, in particular without peaks and/or throw-ups which can subsequently lead to damages to the structural component, can thus be created in a simple and reliable manner. A correspondingly advantageous corrosion resistance can be achieved by a corrosion protection layer covering the entire surface. Due to the electrochemical deburring, a relatively thin corrosion protection layer is already sufficient to achieve the desired surface coverage.
  • A further advantage in the procedure according to the invention is that no special precautions need to be taken with respect to the base component during hot forming. That is, no special temperature and/or heating curves need to be observed and/or restrictions in this respect need to be taken into account. The heating process can thus be carried out in a accordingly simple manner. In particular, an uncoated base component, preferably in the form of a sheet metal component, is used for the base component. For example, a simple sheet metal component, in particular a simple sheet steel component, such as a sheet metal component made of 22MnB5 steel or of manganese-boron steel having a tensile strength of about 2000 MPa, may be used. The sheet metal component may be understood as a circuit board. The base component may have a thickness in a range between 0.5 mm and 6 mm, in particular in a range between 0.7 mm and 3 mm. The base component may have different sheet thicknesses at different locations and/or different materials at different locations within the specified range. Furthermore, the base component may have different strengths at different locations, which may be achieved, for example, by different cooling curves.
  • The electrochemical deburring and the electrolytic application of the corrosion protection layer are preferably carried out directly one after the other. That is, right after the molded component has been electrochemically deburred, it can be directly moved for the electrolytic application of the corrosion protection layer, for example into an immersion bath and/or at least partially into a suitable electrolyte.
  • Hot forming is preferably performed in a direct process. In the hot forming process, the base component is first heated to a pre-definable temperature, for example to a temperature in a range between 800° C. and 1000° C., and then formed or shaped into the desired shape. When heating the base component, scaling of the base component can be reduced by using an inert gas in the furnace or by using a vacuum furnace.
  • The structural component can be understood in particular as a body component for a vehicle. Within the scope of the process, several structural components can also be produced simultaneously. In particular, several molded components can be electro-chemically deburred at the same time.
  • For electrochemical deburring of the molded component, the molded component to be deburred is preferably suspended in a rack. The cathode or a plurality of cathode parts can be selectively positioned in the rack for smoothing or deburring the desired area on the molded component. The cathode or cathode portions may follow the geometry of the molded component. Preferably, the cathode comprises an electrically conductive material, in particular stainless steel or titanium. The cathode is preferably provided as a flat or wire-shaped component. In the process of deburring, the molded component forms the anode. The electrochemical deburring is preferably performed selectively on area sections of the molded component, that is in particular not or at least not selectively on end edges, end portions and/or projections of the molded component.
  • According to a further embodiment of the present invention, it is possible that in a process the molded component has at least one forming edge with a forming radius produced by the hot forming, wherein the electrochemical deburring is carried out for deburring at least one area section adjacent to the at least one forming edge, that is, for selectively removing, for example, grooves in the area sections adjacent to the at least one forming edge. In other words, the electrochemical deburring is selectively carried out on area sections of the molded component which are configured adjacent to the at least one forming edge, and in particular not, or at least not selectively, on the at least one forming edge, end edges and/or end portions of the molded component. Accordingly, also the electrolyte, the temperature of the electrolyte, the treatment time for the deburring and in particular the positioning of the at least one cathode on the molded component are designed or determined with reference to the at least one area section to be deburred. In the prior art, it is generally known to electrolytically deburr complex components and/or in particular their cut and/or manufacturing edges or end edges. According to the invention, however, electrochemical deburring is now used specifically for deburring segments and/or surfaces of the component which are subjected to relative movement between the workpiece and the tool during forming and are thus subject to the potential risk of grooving. According to the invention, this can be easily and effectively integrated into the previously known manufacturing process comprising electrochemical coating of a molded component. In the process, at least two forming edges can be produced by the hot forming, wherein the electrochemical deburring is carried out for deburring at least one area section between the at least two forming edges. In this context, the area section may be understood in particular as a straight and/or planar area section or, apart from any grooves, a straight, planar and/or relatively smooth area section. The forming radius may be understood as a bending radius, an inner radius and/or an outer radius of the at least one forming edge and/or at the at least one forming edge.
  • In a process according to the invention, in particular a zinc coating is applied as a corrosion protection layer. The zinc coating may be understood as a zinc-containing coating and/or alloy. The application of a corrosion protection layer can thus be understood as galvanizing. Preferably, the zinc coating is applied as part of an electrolytic coating process. For electrolytic coating of the component, the latter may remain in the rack described above. In this case, the molded component with the rack is immersed in a suitable electrolyte and is connected as the cathode. The purest possible zinc is used for the anode. Additional anodes can be positioned close to the component to specifically influence the zinc layer. In the context of the invention, it is proposed, as it were, to electrochemically deburr the molded component in the process sequence of galvanizing prior to galvanizing. In this way, as already mentioned-above, build-up at the edge of the grooves as well as, at least in part, the grooves of the at least one molded component or in the region of an oxide layer of the molded component can be reduced to the desired minimum. Molded components have so far been produced either uncoated, i.e. without corrosion protection, without cathodic corrosion protection, or with, for example, a zinc-iron coating, in which cathodic corrosion protection is provided but there is an electrochemical potential to galvanized components, for the reasons stated in the introduction to the description. By the intermediate step of electrochemical deburring proposed in accordance with the invention and the subsequent electrolytic galvanizing, the desired corrosion resistance can now be achieved in a simple and reliable manner and without any loss of quality. In electrochemical deburring, the molded component represents the anode and is at least partially immersed in an electrically conductive liquid, i.e. an electrolyte, during the process. The temperature of the electrolyte may be or may be set in a range between 30° C. and 50° C. during the deburring process. The cathode and/or cathode elements may be adapted to the geometry of the component for this purpose. Compared to conventional galvanizing processes of uncoated and preformed sheet metal components, significantly smoother surfaces can be coated evenly and closed with a relatively thin zinc layer.
  • According to a further embodiment of the present invention, it is possible that in a process a cathodic dip coating is applied to the coated molded component after the application of the zinc coating. It has been shown that a cathodic dip coating applied in addition to, for example, a zinc coating does regularly not sufficiently cover the surface of the structural component due to burrs in the molded component or in the originally formed base component. Thus, in particular, edges and/or tips which may still be pronounced in the first corrosion coating can no longer be sufficiently covered by the relatively thin cathodic dip coating. In other words, the tips of the grooves and/or ejections, which are usually still covered with zinc, are only insufficiently covered or not covered at all by the subsequent cathodic dip coating. These spots can relatively quickly be the starting point of corrosion. By deburring according to the invention before the first coating process, this problem can be satisfactorily taken into account.
  • When carrying out the process according to the invention, it has been shown that a layer thickness of the cathodic dip coating in a range between 10 μm and 40 μm can already be sufficient to provide a cathodic dip coating covering the entire surface. In other words, the cathodic dip coating can be applied with a layer thickness in a range between 10 μm and 40 μm, in particular in a range between 15 μm and 25 μm.
  • Using a method according to the present invention, it is further possible that the electrochemical deburring of the molded component is carried out by means of a cathode and an anode, wherein the molded component is used as at least a part of the anode and the cathode for the electrochemical deburring is positioned at a distance of less than 30 mm from at least one forming edge and/or a surface of the molded component to be deburred at the forming edge. In particular, the cathode may be positioned at a distance in a range between 5 mm and 30 mm, in particular between 10 mm and 20 mm, from the at least one forming edge and/or surface. In experiments within the scope of the present invention, this distance has been found to be particularly advantageous for achieving the desired deburring reliably and yet with a relatively low effort for producing a tool for suitable positioning of the formed component. Selectively positioning the cathode in proximity to the at least one forming edge provides effective deburring. The cathode may comprise a plurality of cathode elements. The cathode may be configured and/or fixed in a tool, for example in the form of a rack, in which the molded component is at least partially positioned in an electrolyte in a predefined position for electrochemical deburring.
  • Furthermore, in a process according to the invention, the electrochemical deburring can be performed with an electrolytic current density in a range between 5 A/dm2 and 15 A/dm2. An operating time or time duration for the electrochemical deburring is preferably set to a value between 3 minutes and 12 minutes, in particular between 5 minutes and 10 minutes. In other words, the electrochemical deburring may be carried out for a corresponding period of time. For this purpose, the electrodes used, the currents used and/or the electrolyte may be adjusted and/or positioned accordingly. With the above-described operating time and/or current density, advantageous deburring can be performed. Furthermore, it has been found advantageous if an electrolyte comprising sodium sulfate and sodium chloride is used in a method according to the present invention for electrochemical deburring, wherein at least twice as much sodium sulfate is used as sodium chloride. An electrolyte containing three times as much sodium sulfate as sodium chloride, for example in a ratio of 180g/I sodium sulfate to 50g/I sodium chloride, has been found to be particularly advantageous.
  • According to another aspect of the present invention, an apparatus for carrying out a method, as described in detail above, for producing a deburred and coated structural component in the form of a body component for a vehicle is provided. For carrying out the method, the apparatus, in particular in the form of an industrial plant, may comprise a provisioning tool for providing the basic structural component. The apparatus further comprises a forming tool for forming the base component into the formed component, a deburring tool for performing the electrochemical deburring and/or a coating tool for performing the electrolytic application of the corrosion protection layer and/or the cathodic dip coating. Thus, the apparatus according to the invention brings the same advantages as have been described in detail with reference to the process according to the invention.
  • Further measures improving the invention will be apparent from the following description of various embodiments of the invention, which are shown schematically in the figures. All features and/or advantages, including constructional details and spatial arrangements, arising from the claims, the description or the figures may be essential to the invention both individually and in the various combinations.
  • It is schematically shown in each case:
  • FIG. 1 a flow chart explaining a process according to one embodiment of the present invention,
  • FIG. 2 a flow chart explaining further details of the process according to the invention,
  • FIG. 3 a flow chart explaining an exemplary procedure for manufacturing a structural component according to the invention, and
  • FIG. 4 a formed structural component known in the prior art.
  • Elements with the same function and mode of operation are each given the same reference signs in the figures.
  • FIG. 1 shows the various process steps for manufacturing a structural component 10 for a motor vehicle according to a preferred embodiment. As shown in FIG. 1 , base components 11 having a thickness of about 1.4 mm are first cut from a coil 18. The sheet metal components are then heated to about 900° C. in a furnace 22, and then formed into the desired shape by a forming tool 20. That is, the heated and uncoated base components 11 in the form of blanks are formed into molded components 12 by the forming tool 20. Even before the molded components are now coated, they are trimmed and then electrochemically deburred. For this purpose, the molded component 12, which forms an anode 17 via the rack for suspending the molded component 12 in the electrolyte, is positioned on a cathode 16 or on plate-shaped cathode components. More specifically, the cathode 16 or plate-shaped cathode components are positioned at a distance of about 10 mm from the molded component 12, respectively, at an area section 14 between two forming edges 15 on the surfaces to be deburred.
  • Electrochemical deburring is carried out with an electrolytic current density of approx. 10 A/dm2 for approx. 8 minutes. The electrolyte used is a liquid containing about 180g/I sodium sulfate and 50g/I sodium chloride at a temperature of about 40° C. Next, the electrochemically deburred molded component 12 is coated with a corrosion protection layer 13 shown in FIG. 2 to produce the structural component 10. More specifically, a zinc coating is applied to the deburred molded component 12 by moving the deburred molded component 12 through an electrolyte 19. After the application of the corrosion protection layer 13, a cathodic dip coating 21 shown in FIG. 2 is also applied to the coated molded component 12 with a coating thickness of about 20 μm over the entire surface. For this purpose, the molded component 12 or structural component 10 coated with the corrosion protection layer 13 is moved through a cathodic dip coating bath 23.
  • The tools and aids for carrying out the process shown in FIG. 1 may be understood as components of an apparatus for carrying out the process and thus for producing the deburred and coated structural component 10.
  • FIG. 2 shows the deburring and coating process in further detail. As can be seen in FIG. 2 , after forming, the molded component 12 has edges and peaks that protrude more than average in the area of an area section 14 upon closer inspection. These are removed or reduced and/or smoothed by the electrochemical deburring process. Thereupon, the corrosion protection layer 13 is applied in the form of the zinc coating. Subsequently, the cathodic dip coating 21 is applied.
  • With reference to FIG. 3 , further embodiments for manufacturing the structural component 10 are described. In a first step 51, the coil 18 is provided, from which, in a second step S2, the base component 11 is then provided in the form of a circuit board. In a direct process, the base component 11 is now heated to about 900° C. in step S3, and formed and press-hardened in step S4. In an indirect process, the base component 11 is first cold formed in step S2 a, which is performed after step S2, and then trimmed to the desired shape in step S2 b. In the indirect process, heating according to step S3 follows only thereafter. Step S2b can initially be omitted in the indirect process. In the direct process, press hardening or hot forming is usually carried out by means of intermediate cooling. In the direct process, step S3 is followed by trimming the molded component 12 in step S4 and cleaning the molded component 12 in step S5. In step S6, the molded component 12 is now cleaned and, in this process, electrochemically deburred as described in detail above. In the indirect process, steps S4 and S5 may be skipped. In step S7, galvanizing follows. The molded component 12 can already be considered as the structural component 10 described above. Step S7 is followed by annealing in step S8. The cleaned, galvanized and annealed structural component 10 is now oiled in step S9 to produce a transport protection. In the subsequent step S10, an assembly of possible sub-components of the structural component 10 may take place. In step S11, a further cleaning process takes place. Subsequently, the structural component 10 is coated with a cathodic dip coating 21 in step S12, which up to this point may also in principle still be regarded as a molded component 12.
  • FIG. 4 shows a prior art structural component 10 a in which the molded component 12 has not been deburred prior to galvanizing. In this case, the edges and tips are still covered by the first corrosion protection layer 13. However, the cathodic dip coating 21 is penetrated by the anti-corrosion layer 13, as a result of which the structural component 10 a has only a correspondingly lower corrosion resistance.
  • The invention admits of further design principles in addition to the embodiments illustrated. That is, the invention is not to be considered limited to the embodiments explained with reference to the figures.
  • LIST OF REFERENCE SIGNS
  • 10 Structural component
  • 10 a Structural component
  • 11 Base component
  • 12 Molded component
  • 13 Corrosion protection layer/ zinc coating
  • 14 Area section
  • 15 Forming edge
  • 16 Cathode
  • 17 Anode
  • 18 Coil
  • 19 Electrolyte/ Zinc bath
  • 20 Forming tool
  • 21 Cathodic dip coating
  • 22 Furnace
  • 23 Cathodic dip coating bath

Claims (10)

1. A method of manufacturing a coated structural component for a vehicle, comprising:
providing a base component,
hot forming of the base component into a molded component,
electrochemical deburring of the molded component, and
electrolytic application of a corrosion protection layer to the deburred molded component to produce the structural component.
2. The method according to claim 1, wherein
the molded component has at least one forming edge produced by the hot forming and having a forming radius, wherein the electrochemical deburring for deburring at least one area section is carried out adjacent to the at least one forming edge.
3. The method according to claim 1, wherein
a zinc coating is applied as corrosion protection layer.
4. The method according to claim 3, wherein
after the zinc coating has been applied, a cathodic dip coating is applied to the coated molded component.
5. The method according to claim 1, wherein
the cathodic dip coating is applied with a layer thickness in a range between 10 μm and 40 μm.
6. The method according to claim 2, wherein
the electrochemical deburring of the molded component is performed by means of a cathode and an anode, the molded component being used as at least part of the anode and the cathode for the electrochemical deburring being positioned at a distance of less than 30 mm from the at least one forming edge.
7. The method according to claim 1, wherein
the electrochemical deburring is performed with an electrolytic current density in a range between 5 A/dm2 and 15 A/dm2.
8. The method according to claim 1, wherein
the electrochemical deburring is performed over a period of time in a range between 3 minutes and 12 minutes.
9. The method according to claim 1, wherein
an electrolyte comprising sodium sulfate and sodium chloride is used for electrochemical deburring, wherein at least twice as much sodium sulfate as sodium chloride is used.
10. An apparatus for carrying out a method according to claim 1 for producing a deburred and coated structural component in the form of a body component for a vehicle.
US17/879,999 2021-08-04 2022-08-03 Process and Device for Producing a Coated Structural Component Pending US20230041423A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102021120263.9A DE102021120263A1 (en) 2021-08-04 2021-08-04 Process and device for producing a coated structural component
DE102021120263.9 2021-08-04

Publications (1)

Publication Number Publication Date
US20230041423A1 true US20230041423A1 (en) 2023-02-09

Family

ID=84975190

Family Applications (1)

Application Number Title Priority Date Filing Date
US17/879,999 Pending US20230041423A1 (en) 2021-08-04 2022-08-03 Process and Device for Producing a Coated Structural Component

Country Status (3)

Country Link
US (1) US20230041423A1 (en)
CN (1) CN115889909A (en)
DE (1) DE102021120263A1 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3401103A (en) * 1965-10-23 1968-09-10 Gen Motors Corp Electrochemical machining process and electrolyte composition of chloride and sulfates
CS202165B1 (en) * 1977-06-16 1980-12-31 Ivo Rousar Device for electrochemical removing of burrs
EP0550831A1 (en) * 1992-01-09 1993-07-14 International Business Machines Corporation Electrochemical micromachining tool and process for through-mask patterning of thin metallic films supported by non-conducting or poorly conducting surfaces
US20080217186A1 (en) * 2007-03-09 2008-09-11 Poligrat Gmbh Electropolishing process for titanium
DE102012009379A1 (en) * 2012-05-11 2012-12-06 Daimler Ag Method for determining risk of corrosion of components of prototype vehicle, involves calculating risk factors associated with general basic condition, constructional corrosion protection and corrosion protection measure features
CN109570312A (en) * 2018-11-29 2019-04-05 合肥常青机械股份有限公司 A kind of super-high strength steel auto parts thermoforming process
CN111434403A (en) * 2019-04-30 2020-07-21 苏州普热斯勒先进成型技术有限公司 Method and device for manufacturing corrosion-resistant hot stamping part

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012208494A1 (en) 2012-05-22 2013-11-28 Bayerische Motoren Werke Aktiengesellschaft Method for producing a component composite

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3401103A (en) * 1965-10-23 1968-09-10 Gen Motors Corp Electrochemical machining process and electrolyte composition of chloride and sulfates
CS202165B1 (en) * 1977-06-16 1980-12-31 Ivo Rousar Device for electrochemical removing of burrs
EP0550831A1 (en) * 1992-01-09 1993-07-14 International Business Machines Corporation Electrochemical micromachining tool and process for through-mask patterning of thin metallic films supported by non-conducting or poorly conducting surfaces
US20080217186A1 (en) * 2007-03-09 2008-09-11 Poligrat Gmbh Electropolishing process for titanium
DE102012009379A1 (en) * 2012-05-11 2012-12-06 Daimler Ag Method for determining risk of corrosion of components of prototype vehicle, involves calculating risk factors associated with general basic condition, constructional corrosion protection and corrosion protection measure features
CN109570312A (en) * 2018-11-29 2019-04-05 合肥常青机械股份有限公司 A kind of super-high strength steel auto parts thermoforming process
CN111434403A (en) * 2019-04-30 2020-07-21 苏州普热斯勒先进成型技术有限公司 Method and device for manufacturing corrosion-resistant hot stamping part

Non-Patent Citations (9)

* Cited by examiner, † Cited by third party
Title
Davidson, "Surface Condition Impacts Part Performance: Burrs, Edges Can Negatively Influence Function of Components," Metal Finishing (2007 Feb 1), Vol. 105, No. 2, pp. 22-31. (Year: 2007) *
Denkena et al., "Development of a Concept to Optimize the Energy Efficiency in Forging Process Chains," International Journal of Precision Engineering and Manufacturing (2013 Jul), Vol. 14, pp. 1229-1236. (Year: 2013) *
James et al., "The Influence of Steel Coating Type and Galvanneal Coating Structure on Electrocoat Primer Paintability," SAE Transactions (1999 Jan 1), pp. 40-46. (Year: 1999) *
James et al., "The Influence of Steel Coating Type and Galvanneal Coating Structure on Electrocoat Primer Paintability," SAF Transactions (1999 Jan 1), pp. 40-46. (Year: 1999) *
Kadam et al., "Electrochemical Deburring - A Comprehensive Review," Materials Today: Proceedings (2021 Jan 1), Vol. 46, pp. 141-1488. (Year: 2021) *
Kapfer et al., "Investigation and Modelling of Edge Corrosion of E-Coated Galvanized Steel with Respect to the Spatial Edge Orientation," Materials and Corrosion (Jan 2002) [First published: 03 August 2021], Vol. 73, Issue 1, pp. 55-67. (Year: 2002) *
Kapfer et al., "Investigation and Modelling of Edge Corrosion of E-Coated Galvanized Steel with Respect to the Spatial Edge Orientation," Materials and Corrosion (Jan 2022) [First published: 03 August 2021], Vol. 73, Issue 1, pp. 55-67. (Year: 2021) *
Kapfer et al., "Investigation and Modelling of Edge Corrosion of E-Coated Galvanized Steel with Respect to the Spatial Edge Orientation," Materials and Corrosion (Jan 2022) [First published: 03 August 2021], Vol. 73, Issue 1, pp. 55-67. (Year: 2022) *
Schemme, "Magnesium Motorcycle Wheels for Racing Applications," Magnesium Alloys and their Applications (2000 Sep 20), pp. 391-396. (Year: 2000) *

Also Published As

Publication number Publication date
CN115889909A (en) 2023-04-04
DE102021120263A1 (en) 2023-02-09

Similar Documents

Publication Publication Date Title
JP6640090B2 (en) Steel part provided with anticorrosion coating and method of manufacturing the same
KR101760224B1 (en) Method for producing a product from rolled strip material
KR101108312B1 (en) Plated steel sheet for can and process for producing the same
JP6483709B2 (en) Method for producing steel part with metal anticorrosion coating
US9938600B2 (en) Manufacturing a hardened formed part
JP2003129209A (en) Surface-treated steel for hot press forming and production method therefor
CN110709537B (en) Steel sheet for can and method for producing same
RU2001117509A (en) METHOD OF ZINC AND Galvanic Annealing WHEN USING A BATH WITH ZINC AND ALUMINUM
WO2022097738A1 (en) Fe-BASED ELECTROPLATED STEEL SHEET, ALLOYED HOT-DIPPED GALVANIZED STEEL SHEET, AND METHODS FOR MANUFACTURING SAME
EP0744475A1 (en) Process for improving the formability and weldability properties of zinc coated sheet steel
US20160237585A1 (en) Producing a product from a rolled strip material
CN111434403B (en) Method and device for manufacturing corrosion-resistant hot stamping part
US20230041423A1 (en) Process and Device for Producing a Coated Structural Component
CN115485415A (en) Method for producing a hardened steel component having an anti-corrosion zinc treatment
KR102285532B1 (en) Method for coating steel sheets or strips of steel and for producing press-hardened parts therefrom
JP7368712B2 (en) Plated steel plate for hot press forming
JP7445113B2 (en) Plated steel plate for hot press forming
JP7050739B2 (en) Methods, Corresponding Parts and Vehicles for Manufacturing Parts with Less Waviness from Electro-Galvanized Metal Sheets
JPS6330998B2 (en)
JP2000080499A (en) Chemical treating method for nickel plated steel sheet
JP2000080498A (en) Chemical treatment of tin group plated steel plate
JP2000008194A (en) Chemical treatment of tinned steel sheet
JPH0797697A (en) Production of highly corrosion resistant suspension spring
JPH07166398A (en) Production of steel sheet for welded can excellent in high speed seam weldability, corrosion resistance and coating adhesion
JPH0617287A (en) Surface treated aluminum sheet excellent in spot weldability

Legal Events

Date Code Title Description
AS Assignment

Owner name: SUZHOU PRESSLER ADVANCED FORMING TECHNOLOGIES CO. LTD., CHINA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:AN, JIAN;CHEN, HANJIE;YU, ZHEN;REEL/FRAME:060741/0471

Effective date: 20220725

Owner name: BAYERISCHE MOTOREN WERKE AKTIENGESELLSCHAFT, GERMANY

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:PFESTORF, MARKUS;RAUBER, CHRISTIAN;UNGER, NORA;REEL/FRAME:060741/0466

Effective date: 20220801

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE AFTER FINAL ACTION FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: ADVISORY ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION