US20220040054A1 - Long wear lip cosmetic sytem and topcoat - Google Patents
Long wear lip cosmetic sytem and topcoat Download PDFInfo
- Publication number
- US20220040054A1 US20220040054A1 US17/509,850 US202117509850A US2022040054A1 US 20220040054 A1 US20220040054 A1 US 20220040054A1 US 202117509850 A US202117509850 A US 202117509850A US 2022040054 A1 US2022040054 A1 US 2022040054A1
- Authority
- US
- United States
- Prior art keywords
- silicone
- volatile
- weight
- topcoat
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 145
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 48
- 239000003921 oil Substances 0.000 claims abstract description 45
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 39
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 27
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 27
- 239000000346 nonvolatile oil Substances 0.000 claims abstract description 23
- 239000003086 colorant Substances 0.000 claims abstract description 22
- 229920002545 silicone oil Polymers 0.000 claims description 48
- -1 polydimethylsiloxane Polymers 0.000 claims description 34
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 32
- 239000001993 wax Substances 0.000 claims description 30
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 12
- 239000000341 volatile oil Substances 0.000 claims description 9
- 239000000490 cosmetic additive Substances 0.000 claims description 7
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 19
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 30
- 229920005989 resin Polymers 0.000 description 24
- 239000011347 resin Substances 0.000 description 24
- 239000004615 ingredient Substances 0.000 description 19
- 229920002050 silicone resin Polymers 0.000 description 19
- 229920001577 copolymer Polymers 0.000 description 14
- 229940008099 dimethicone Drugs 0.000 description 13
- 229920002379 silicone rubber Polymers 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 239000000049 pigment Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000012530 fluid Substances 0.000 description 9
- 210000004209 hair Anatomy 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000004964 aerogel Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 7
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 239000000945 filler Substances 0.000 description 7
- 239000000499 gel Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 5
- 239000004965 Silica aerogel Substances 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- PHLASVAENYNAOW-UHFFFAOYSA-N methyl-bis[[methyl(diphenyl)silyl]oxy]-phenylsilane Chemical compound C=1C=CC=CC=1[Si](C)(C=1C=CC=CC=1)O[Si](C=1C=CC=CC=1)(C)O[Si](C)(C=1C=CC=CC=1)C1=CC=CC=C1 PHLASVAENYNAOW-UHFFFAOYSA-N 0.000 description 5
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 229920006037 cross link polymer Polymers 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 0 [1*][Si]([3*])(C)O[Si]([2*])([4*])CC(=O)N[Y]NC(=O)CC Chemical compound [1*][Si]([3*])(C)O[Si]([2*])([4*])CC(=O)N[Y]NC(=O)CC 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- YFCVAZGXPLMNDG-UHFFFAOYSA-N dimethyl-bis[[methyl(diphenyl)silyl]oxy]silane Chemical compound C=1C=CC=CC=1[Si](C)(C=1C=CC=CC=1)O[Si](C)(C)O[Si](C)(C=1C=CC=CC=1)C1=CC=CC=C1 YFCVAZGXPLMNDG-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000004005 microsphere Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000012860 organic pigment Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 229940117985 trimethyl pentaphenyl trisiloxane Drugs 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- 239000011782 vitamin Substances 0.000 description 3
- 229940088594 vitamin Drugs 0.000 description 3
- 235000013343 vitamin Nutrition 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 229940085262 cetyl dimethicone Drugs 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 235000013980 iron oxide Nutrition 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 150000003573 thiols Chemical group 0.000 description 2
- 239000007762 w/o emulsion Substances 0.000 description 2
- NDDLLTAIKYHPOD-ISLYRVAYSA-N (2e)-6-chloro-2-(6-chloro-4-methyl-3-oxo-1-benzothiophen-2-ylidene)-4-methyl-1-benzothiophen-3-one Chemical compound S/1C2=CC(Cl)=CC(C)=C2C(=O)C\1=C1/SC(C=C(Cl)C=C2C)=C2C1=O NDDLLTAIKYHPOD-ISLYRVAYSA-N 0.000 description 1
- XLTMWFMRJZDFFD-UHFFFAOYSA-N 1-[(2-chloro-4-nitrophenyl)diazenyl]naphthalen-2-ol Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1Cl XLTMWFMRJZDFFD-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- DSVUBXQDJGJGIC-UHFFFAOYSA-N 3',6'-dihydroxy-4',5'-diiodospiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C(I)=C1OC1=C(I)C(O)=CC=C21 DSVUBXQDJGJGIC-UHFFFAOYSA-N 0.000 description 1
- ZDTNHRWWURISAA-UHFFFAOYSA-N 4',5'-dibromo-3',6'-dihydroxyspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C(Br)=C1OC1=C(Br)C(O)=CC=C21 ZDTNHRWWURISAA-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- KGKQNDQDVZQTAG-UHFFFAOYSA-N 8-methylnonyl 2,2-dimethylpropanoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)(C)C KGKQNDQDVZQTAG-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- FJFFARKXMMPVSF-UHFFFAOYSA-N C.C.C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C Chemical compound C.C.C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C FJFFARKXMMPVSF-UHFFFAOYSA-N 0.000 description 1
- BQGDMISTAHNVCA-UHFFFAOYSA-N C[Si](C)(C)O[Si](C)(C)O[Si](C)(O[Si](C)(C)C)C1=CC=CC=C1 Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(O[Si](C)(C)C)C1=CC=CC=C1 BQGDMISTAHNVCA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 229910020487 SiO3/2 Inorganic materials 0.000 description 1
- 229910020485 SiO4/2 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000000909 amidinium group Chemical group 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- OHXVIZBSLGZEFS-UHFFFAOYSA-N benzhydrylsilyloxy-diphenyl-silyloxysilane Chemical class C1(=CC=CC=C1)C(C1=CC=CC=C1)[SiH2]O[Si](O[SiH3])(C1=CC=CC=C1)C1=CC=CC=C1 OHXVIZBSLGZEFS-UHFFFAOYSA-N 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- DBZJJPROPLPMSN-UHFFFAOYSA-N bromoeosin Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 DBZJJPROPLPMSN-UHFFFAOYSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- DGQLVPJVXFOQEV-JNVSTXMASA-N carminic acid Chemical compound OC1=C2C(=O)C=3C(C)=C(C(O)=O)C(O)=CC=3C(=O)C2=C(O)C(O)=C1[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O DGQLVPJVXFOQEV-JNVSTXMASA-N 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- OIQPTROHQCGFEF-UHFFFAOYSA-L chembl1371409 Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-UHFFFAOYSA-L 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- ZLWLTDZLUVBSRJ-UHFFFAOYSA-K chembl2360149 Chemical compound [Na+].[Na+].[Na+].O=C1C(N=NC=2C=CC(=CC=2)S([O-])(=O)=O)=C(C(=O)[O-])NN1C1=CC=C(S([O-])(=O)=O)C=C1 ZLWLTDZLUVBSRJ-UHFFFAOYSA-K 0.000 description 1
- XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 description 1
- QFSKIUZTIHBWFR-UHFFFAOYSA-N chromium;hydrate Chemical compound O.[Cr] QFSKIUZTIHBWFR-UHFFFAOYSA-N 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 229940075479 d & c red no. 27 Drugs 0.000 description 1
- 229940086624 d&c orange no. 10 Drugs 0.000 description 1
- 229940099449 d&c orange no. 4 Drugs 0.000 description 1
- 229940090962 d&c orange no. 5 Drugs 0.000 description 1
- 229940058010 d&c red no. 21 Drugs 0.000 description 1
- 229940075484 d&c red no. 30 Drugs 0.000 description 1
- 229940075493 d&c red no. 6 Drugs 0.000 description 1
- 229940057946 d&c red no. 7 Drugs 0.000 description 1
- VILAVOFMIJHSJA-UHFFFAOYSA-N dicarbon monoxide Chemical compound [C]=C=O VILAVOFMIJHSJA-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940090934 diphenylsiloxy phenyl trimethicone Drugs 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- RAGZEDHHTPQLAI-UHFFFAOYSA-L disodium;2',4',5',7'-tetraiodo-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C2=CC=CC=C2C21C1=CC(I)=C([O-])C(I)=C1OC1=C(I)C([O-])=C(I)C=C21 RAGZEDHHTPQLAI-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 235000004626 essential fatty acids Nutrition 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- BHXIWUJLHYHGSJ-UHFFFAOYSA-N ethyl 3-ethoxypropanoate Chemical compound CCOCCC(=O)OCC BHXIWUJLHYHGSJ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000012182 japan wax Substances 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 210000000088 lip Anatomy 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 210000000282 nail Anatomy 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical class C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- ZYIBVBKZZZDFOY-UHFFFAOYSA-N phloxine O Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 ZYIBVBKZZZDFOY-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229920006268 silicone film Polymers 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical group [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/03—Liquid compositions with two or more distinct layers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/884—Sequential application
Definitions
- the present invention relates to a topcoat composition for long-wear lip compositions comprising at least one silicone film-forming agent, as well as to cosmetic systems, kits and methods of treating, making-up and enhancing the appearance of lips, including a topcoat composition for application to a basecoat composition.
- compositions including pigmented cosmetics such as lipsticks or lip colors, have been formulated in an attempt to possess long-wearing properties upon application. Unfortunately, many of these compositions do not generally possess both good long-wear/transfer-resistance properties as well as high gloss.
- topcoat a second composition
- topcoat compositions tend to decrease the long-wear/transfer-resistance properties of the lip compositions, thereby rendering the long-wear/transfer resistant composition less acceptable to consumers and less acceptable for their intended purpose.
- one aspect of the present invention is a topcoat composition for long-wear lip compositions which provide or maintain good cosmetic properties such as, for example, good transfer-resistance, feel and shine properties upon application to a long-wear lip composition.
- the present invention relates to a cosmetic system comprising (1) a lip basecoat composition including at least one first silicone film-forming agent, colorant, and a volatile hydrocarbon oil, and (2) a topcoat composition including at least one second silicone film-forming agent in a non-volatile oil carrier.
- the present invention relates to a method of making up the lips.
- the method includes applying to the lips a first composition including at least one first silicone film-forming agent, colorant, and a volatile hydrocarbon oil to form a basecoat. After a waiting period, a second composition including at least one second silicone film-forming agent in a non-volatile oil carrier is applied to form a topcoat over the basecoat.
- the present invention relates to a topcoat composition for use on the lips, wherein the topcoat consists essentially of from about 15% by weight to about 30% by weight of at least one silicone film-forming agent; from about 60% to about 85% of a non-volatile silicone oil; and from about 0.001% to about 10% by weight of one or more cosmetic additives, wherein the at least one silicone film-forming agent and the one or more cosmetic additives are dispersed or dissolved in the non-volatile silicone oil.
- anhydrous refers to a composition not containing any water, that is to say a composition in which the water that may be present comes only from the water of crystallization or of adsorption of the starting materials. In any case contains less than about 2% by weight of water, such as less about 1% water, such as less than about 0.5% water such as less about 0.1% of water.
- the expression “at least one” means one or more and thus includes individual components as well as mixtures/combinations.
- Film former or “film forming agent” or “film forming polymer” or “film forming resin” as used herein mean a polymer or resin that leaves a film on the substrate to which it is applied, for example, after a solvent accompanying the film former has evaporated, absorbed into and/or dissipated on the substrate.
- Transfer resistance refers to the quality exhibited by compositions that are not readily removed by contact with another material, such as, for example, a glass, an item of clothing or the skin, for example, when eating or drinking. Transfer resistance may be evaluated by any method known in the art for evaluating such. For example, transfer resistance of a composition may be evaluated by a “kiss” test. The “kiss” test may involve application of the composition to human keratin material such as hair, skin or lips followed by rubbing a material, for example, a sheet of paper, against the hair, skin or lips after expiration of a certain amount of time following application, such as 2 minutes after application.
- transfer resistance of a composition may be evaluated by the amount of product transferred from a wearer to any other substrate, such as transfer from the hair, skin or lips of an individual to a collar when putting on clothing after the expiration of a certain amount of time following application of the composition to the hair, skin or lips.
- the amount of composition transferred to the substrate e.g., collar, or paper
- a composition may be transfer resistant if a majority of the product is left on the wearer's hair, skin or lips.
- the amount transferred may be compared with that transferred by other compositions, such as commercially available compositions. In a preferred embodiment of the present invention, little or no composition is transferred to the substrate from the hair, skin or lips.
- Long wear compositions refers to compositions where color remains the same or substantially the same as at the time of application, as viewed by the naked eye, after an extended period of time.
- Long wear properties may be evaluated by any method known in the art for evaluating such properties. For example, long wear may be evaluated by a test involving the application of a composition to human hair, skin or lips and evaluating the color of the composition after an extended period of time. For example, the color of a composition may be evaluated immediately following application to hair, skin or lips and these characteristics may then be re-evaluated and compared after a certain amount of time. Further, these characteristics may be evaluated with respect to other compositions, such as commercially available compositions.
- “long wear” typically means the composition remains on the lips at least about 4 hours up to about 24 hours, and retains rich color even after eating.
- Liquid or “liquid cosmetic” or “liquid lipstick” or “liquid composition” means a composition having a fixed volume, flows to cover the bottom and assumes the shape of the portion of the container it fills and is slightly compressible.
- Tackiness refers to the adhesion between two substances. For example, the more tackiness there is between two substances, the more adhesion there is between the substances. To quantify “tackiness,” it is useful to determine the “work of adhesion” as defined by IUPAC associated with the two substances. Generally speaking, the work of adhesion measures the amount of work necessary to separate two substances. Thus, the greater the work of adhesion associated with two substances, the greater the adhesion there is between the substances, meaning the greater the tackiness is between the two substances.
- “Substituted” as used herein, means comprising at least one substituent.
- substituents include atoms, such as oxygen atoms and nitrogen atoms, as well as functional groups, such as amine groups, ether groups, alkoxy groups, acyloxyalky groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide groups, halogen containing groups, ester groups, thiol groups, sulphonate groups, thiosulphate groups, siloxane groups, and polysiloxane groups.
- the substituent(s) may be further substituted.
- substantially free means that while it is preferred that no amount of the specific component be present in the composition, it is possible to have very small amounts of it in the compositions of the invention provided that these amounts do not materially affect at least one, preferably most, of the advantageous properties of the conditioning compositions of the invention.
- substantially free means less than about 2% of the identified ingredient, such as less than about 1%, such as less than about 0.5% of the ingredient.
- Numerical ranges are inclusive of endpoints and meant to include all combinations and sub-combinations. For example, from about 5%, 10% or 15% to about 20%, 50% or 60% means about 5% to about 20%, about 5% to about 50%, about 5% to about 60%, about 10% to about 20%, about 10% to about 50%, about 10% to about 60%, about 15% to about 20%, about 15% to about 50%, or about 15% to about 60%.
- Keratinous materials includes materials containing keratin such as hair, skin, eyebrows, lips and nails.
- Volatile as used herein, means having a flash point of less than about 100° C.
- Non-volatile as used herein, means having a flash point of greater than about 100° C.
- Actives basis means considering only the particular component of ingredient (e.g., in a composition) and ignoring other chemically unrelated components that may be also be present in the same raw material source of that particular component.
- compositions and methods of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful.
- a long-wear lip composition including at least one silicone film-forming agent.
- the silicone film-forming agent is selected from the group consisting of silicone resins, polyorganosiloxane copolymers, and mixtures thereof.
- the basecoat compositions of the present invention may be in any form, either liquid or non-liquid (semi-solid, soft solid, solid, etc.). For example, it may be a paste, a solid, a gel, or a cream.
- composition of the invention may, for example, include an external or continuous fatty phase.
- the composition can also be a molded composition or cast as a stick or a dish.
- the basecoat is a liquid. In certain other notable embodiments, the basecoat is a solution or dispersion including at least one silicone film-forming agent and at least one colorant in a volatile hydrocarbon oil.
- the long-wear lip compositions of the present invention include at least one silicone resin.
- suitable silicone resins include those described, for example, in U.S. Pat. Nos. 5,505,937, 5,911,974, 5,965,112, 5,985,298, 6,074,654, 6,780,422, 6,908,621, the disclosures of which are hereby incorporated by reference in their entirety.
- the long-wear lip compositions contain siloxysilicate resins.
- siloxysilicate resins One non-limiting example of a siloxysilicate in accordance with the present invention is trimethylsiloxysilicate, which may be represented by the following formula:
- x and y may, for example, range from 50 to 80.
- siloxysilicates are commercially available from General Electric, Dow Corning, Wacker, Milliken, Siltech, Grant Industries, Momentive and Shin-Etsu Silicones under the tradename Resin MQ®.
- the long-wear lip compositions contain silsesquioxane resins such as, for example, polypropyl silsesquioxane resin.
- Silsesquioxane resins are a specific form of silicone resin. Silicone resin nomenclature is known in the art as “MDTQ” nomenclature, whereby a silicone resin is described according to the various monomeric siloxane units which make up the polymer. Each letter of “MDTQ” denotes a different type of unit. When the film-forming resin is made up predominantly of tri-functional units (or T units), it is generally called a silsesquioxane resin, which is described, for example in US 2006/0292096, herein incorporated by reference in its entirety.
- silsesquioxane resins that may be used in the present invention are alkyl silsesquioxane resins that are silsesquioxane homopolymers and/or copolymers having an average siloxane unit of the general formula R 1 n SiO (4-n)/2 , wherein each R1 is a propyl group, wherein more than 80 mole % of R1 represent a C3-C10 alkyl group, n is a value of from 1.0 to 1.4, and more than 60 mole % of the copolymer includes R 1 SiO 3/2 units.
- each R1 is a propyl group
- these polymers are called polypropylsilsesquioxane resins or “t-propyl” silsesquioxane resins. These resins and methods of making them are described, for example in U.S. Pat. No. 8,586,013, 2012/0301415, 2007/0093619, and 2006/0292096, all of which are herein incorporated by reference in their entirety.
- a non-limiting example of a polypropylsilsesquioxane resin suitable for use in the present invention is commercially available from Dow Corning as Dow Corning 670 Fluid or Dow Corning 680 Fluid.
- Dow Corning resins have a general formula of R n SiO (4-n)/2 wherein R is independently chosen from a hydrogen atom and a monovalent hydrocarbon group comprising 3 carbon atoms, wherein more than 80 mole % of R are propyl groups, n is a value from 1.0 to 1.4, more than 60 mole % of the copolymer includes RSiO 3/2 units, and having a hydroxyl or alkoxy content from 0.2 to 10% by weight, for example between 1 and 4% by weight, preferably between 5 and 10% by weight, and more preferably between 6 and 8% by weight.
- the polypropylsilsesquioxane resin has a molecular weight from about 5000 to about 30,000 and a Tg from about ⁇ 5° C. to about 5° C
- the long-wear lip composition contains at least one silicone resin selected from the group consisting of siloxy silicate resins, silsesquioxane resins, and mixtures thereof.
- the at least one silicone resin is preferably present in the long-wear lip compositions of the present invention in an amount ranging from about 5% to about 30% by weight, preferably from about 10% to about 25% by weight, and preferably from about 15% to about 20% by weight, including all ranges and subranges therebetween, all weights being based on the weight of the composition as a whole.
- the basecoat composition includes at least one volatile hydrocarbon oil.
- oil as used herein, means nonaqueous compounds having a melting point of less than about 25° C. and at atmospheric pressure (1.013 ⁇ . 1O 5 Pa). Oils are generally immiscible with water wherein “immiscible” is intended to mean that the mixing of the same amount of water and oil, after mixing (for example Rayneri 550 rpm; 10 minutes), does not result in a stable solution including just one phase, under normal temperature and pressure conditions
- Oils generally include a hydrophobic moiety, such as one meeting one or more of the following three criteria: (a) has a carbon chain of at least six carbons in which none of the six carbons is a carbonyl carbon or has a hydrophilic moiety (defined below) bonded directly to it; (b) has two or more alkyl siloxy groups; or (c) has two or more oxypropylene groups in sequence.
- the hydrophobic moiety may include linear, cyclic, aromatic, saturated or unsaturated groups.
- the hydrophobic compound is in certain embodiments not amphiphilic and, as such, in this embodiment does not include hydrophilic moieties, such as anionic, cationic, zwitterionic, or nonionic groups, that are polar, including sulfate, sulfonate, carboxylate, phosphate, phosphonate, ammonium, including mono-, di-, and trialkylammonium species, pyridinium, imidazolinium, amidinium, poly(ethyleneiminium), ammonioalkylsulfonate, ammonioalkylcarboxylate, amphoacetate, and poly(ethyleneoxy)sulfonyl moieties.
- the oil does not include hydroxyl moieties.
- the oil is not surface active—i.e., when added in a weight concentration of 1% to water does not reduce surface tension of the water to less than 50 dynes/cm.
- suitable volatile hydrocarbon oils include, for example, volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures and in particular branched C 8 to C 16 alkanes such as C 8 to C 16 isoalkanes (also known as isoparaffins), isododecane, isodecane, isohexadecane, and for example, the oils sold under the trade names of Isopar or Permethyl, the C 8 to C 16 branched esters such as isohexyl or isodecyl neopentanoate, alcohols, and their mixtures.
- the volatile hydrocarbon-based oils have a flash point of at least 40° C.
- volatile hydrocarbon-based oils examples include, but are not limited to those given in Table 1 below.
- the basecoat may optionally include one or more volatile silicone oils.
- the volatile silicone oil if present, may be chosen from linear or cyclic silicone oils, such as those having a viscosity, at room temperature, of less than or equal to 6 cSt, and having from 2 to 7 silicon atoms, optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms.
- suitable volatile silicone oils include, but are not limited to, those listed in Table 2 below.
- the one or more volatile hydrocarbon oils are present in a concentration by weight greater that is greater than the concentration by weight of the one or more volatile silicone oils. According to certain other embodiments the one or more volatile hydrocarbon oils are present in a concentration by weight that is at least 2 to about 10 times that of the one or more volatile silicone oils.
- the at least one volatile hydrocarbon oil is generally present in the compositions of the present invention in an amount ranging from about 5% to about 50% by weight; such as from about 10% to about 45% by weight; such as from about 15% to about 40% by weight, all weights being based on the weight of the composition as a whole.
- the at least one volatile silicone oil if present is generally present in the compositions of the present invention in an amount ranging from about 1% to about 25% by weight; such as from about 2% to about 15% by weight; such as from about 3% to about 10% by weight, all weights being based on the weight of the composition as a whole.
- the basecoat compositions of the present invention may include at least one polyorganosiloxane copolymer.
- the polyorganosiloxane copolymer useful herein is preferably a polymer (homopolymer or copolymer) having at least one moiety which contains: at least one polyorganosiloxane group consisting of 1 to about 1000 organosiloxane units in the chain of the moiety or in the form of a graft, and at least two groups capable of establishing hydrogen interactions.
- Non-limiting examples of polyorganosiloxane copolymers are disclosed, for example in U.S. Pat. No. 8,945,525, the disclosure of which is hereby incorporated by reference in its entirety.
- Additional polyorganosiloxane copolymers which may be used in the long-wear lip compositions of the present invention include those described in documents U.S. Pat. Nos. 5,874,069, 5,919,441, 6,051,216, and 5,981,680 the entire contents of which are hereby incorporated by reference in their entirety.
- a preferred polyorganosiloxane copolymer for use in the present invention contain at least one moiety chosen from formula (III):
- R 1 , R 2 , R 3 and R 4 are the same or different and may be selected from the group consisting of methyl, ethyl, propyl, isopropyl, a siloxane chain, and phenyl;
- X is a linear or branched chain alkylene having 1-30 carbons
- Y is selected from the group consisting of linear or branched chain alkylenes having 1-40 carbons;
- (d) m is a number between 1 and 700;
- n is a number between 1 and 500.
- Particularly preferred polyorganosiloxane copolymers useful herein are commercially available from Dow Corning under the tradenames DC 8178® and DC 8179®, which are known under the INCI denomination of Nylon-611/Dimethicone Copolymer.
- the polyorganosiloxane copolymer is present in the long-wear lip compositions of the present invention in an amount ranging from about 2% to about 35% by weight, preferably from about 5% to about 30% by weight, and preferably from about 7% to about 20% by weight, including all ranges and subranges therebetween, all weights being based on the weight of the composition as a whole.
- the long-wear lip composition may further include as least one silicone elastomer.
- the silicone elastomer is a non-emulsifying silicon elastomer.
- “Non-emulsifying” defines organopolysiloxane elastomers that do not contain hydrophilic chains, in particular polyoxyalkylene (especially polyoxyethylene or polyoxypropylene) or polyglyceryl units.
- the composition includes a silicone elastomer that is free of polyoxyalkylene units and polyglyceryl units.
- non-emulsifying elastomers useful in this invention include but not limit those sold under the names KSG-6, KSG-15, KSG-16, KSG-18, KSG-41, KSG-42, KSG-43 and KSG-44 by the company Shin-Etsu, DC 9040, DC 9041, DC 9509, DC 9505 and DC 9506, by the company Dow Corning, and SFE 839 by the company Momentive Performance Materials.
- the silicone elastomers are preferably in the form of a gel or a powder.
- the silicone elastomer particles are conveyed in the form of a gel formed from an elastomeric organopolysiloxane included in at least one hydrocarbon-based oil and/or one silicone oil.
- the organopolysiloxane particles are often non-spherical particles.
- silicone elastomers useful in this invention are dimethicone crosspolymer gels (blends of dimethicone crosspolymers in solvents) having viscosity values from about 150 and to about 700 mm 2 /s, from about 200 to about 650 mm 2 /s and from about 300 to about 600 mm 2 /s, including all ranges and subranges therebetween.
- Particularly useful for this invention may be blends of high molecular weight silicone elastomers in volatile solvents, such as silicone oils, hydrocarbon oils and mixtures thereof.
- Suitable silicone elastomeric gels include DC EL-8040 ID (INCI name: Isododecane (and) Dimethicone Crosspolymer) and DC EL-9140 DM (INCI name: Dimethicone (and) Dimethicone Crosspolymer), supplied by Dow Corning.
- Non-limiting examples of silicone elastomers and their synthesis are disclosed, for example in U.S. Pat. No. 8,637,057 and US/20150174048, both of which are herein incorporated by reference in their entirety.
- the silicone elastomer thickens the composition, adds the cushiony (spongy) effect and/or improves the application properties of the long-wear lip composition. Also, it provides a very soft feel and/or mattifying effect after application.
- the silicone elastomer is present in a content ranging from 1 percent to 30 percent by weight of active material (dry matter), preferably from about 1.5 percent to about 20 percent, and preferably from 2 percent to 10 percent by weight relative to the total weight of the long-wear lip composition, including all ranges and subranges therebetween.
- basecoat compositions of the present invention may optionally further include at least one cosmetically acceptable colorant such as a pigment or dyestuff.
- suitable pigments include, but are not limited to, inorganic pigments, organic pigments, lakes, pearlescent pigments, iridescent or optically variable pigments, and mixtures thereof.
- a pigment should be understood to mean inorganic or organic, white or colored particles.
- Said pigments may optionally be surface-treated within the scope of the present invention but are not limited to treatments such as silicones, perfluorinated compounds, lecithin, and amino acids.
- inorganic pigments useful in the present invention include those selected from the group consisting of rutile or anatase titanium dioxide, coded in the Color Index under the reference CI 77,891; black, yellow, red and brown iron oxides, coded under references CI 77,499, 77, 492 and, 77,491; manganese violet (CI 77,742); ultramarine blue (CI 77,007); chromium oxide (CI 77,288); chromium hydrate (CI 77,289); and ferric blue (CI 77,510) and mixtures thereof.
- organic pigments and lakes useful in the present invention include, but are not limited to, D&C Red No. 19 (CI 45,170), D&C Red No. 9 (CI 15,585), D&C Red No. 21 (CI 45,380), D&C Orange No. 4 (CI 15,510), D&C Orange No. 5 (CI 45,370), D&C Red No. 27 (CI 45,410), D&C Red No. 13 (CI 15,630), D&C Red No. 7 (CI 15,850), D&C Red No. 6 (CI 15,850), D&C Yellow No. 5 (CI 19,140), D&C Red No. 36 (CI 12,085), D&C Orange No. 10 (CI 45,425), D&C Yellow No. 6 (CI 15,985), D&C Red No. 30 (CI 73,360), D&C Red No. 3 (CI 45,430) and the dye or lakes based on cochineal carmine (CI 75,570) and mixtures thereof.
- D&C Red No. 19 CI 45,170
- pearlescent pigments useful in the present invention include those selected from the group consisting of the white pearlescent pigments such as mica coated with titanium oxide, mica coated with titanium dioxide, bismuth oxychloride, titanium oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with ferric blue, chromium oxide and the like, titanium mica with an organic pigment of the above-mentioned type as well as those based on bismuth oxychloride and mixtures thereof.
- white pearlescent pigments such as mica coated with titanium oxide, mica coated with titanium dioxide, bismuth oxychloride, titanium oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with ferric blue, chromium oxide and the like, titanium mica with an organic pigment of the above-mentioned type as well as those based on bismuth oxychloride and mixtures thereof.
- colorant employed in the compositions of the present invention will depend on the color, intensity and use of the cosmetic composition and, as a result, will be determined by those skilled in the art of cosmetic formulation. However, one preferred amount of colorant for use in the present invention is from about 0.5% to about 15%, from about 1.5% to about 12%, and from about 2% to about 10%, based on the weight of the composition.
- the basecoat compositions of the present invention may optionally further include at least one filler.
- Fillers that may be used in the compositions of the invention include, for example, silica powder; talc; polyamide particles and especially those sold under the name Orgasol by the company Atochem; polyethylene powders; microspheres based on acrylic copolymers, such as those based on ethylene glycol dimethacrylate/lauryl methacrylate copolymer sold by the company Dow Corning under the name Polytrap; expanded powders such as hollow microspheres and especially the microspheres sold under the name Expancel by the company Kemanord Plast or under the name Micropearl F 80 ED by the company Matsumoto; powders of natural organic materials such as crosslinked or noncrosslinked corn starch, wheat starch or rice starch, such as the powders of starch crosslinked with octenyl succinate anhydride, sold under the name Dry-Flo by the company National Starch; silicone resin microbeads such as those sold under the
- the fillers may be present in the composition of the invention in an amount ranging from about 0.1% to about 50% by weight, such as from 0.5% to about 30% by weight, and such as from about 1% to about 20% by weight, all weights based on the weight of the composition as a whole.
- the basecoat compositions of the present invention may optionally further include at least one silica aerogel.
- Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air. They are generally synthesized via a sol-gel process in liquid medium and then dried, usually by extraction of a supercritical fluid, the one most commonly used being supercritical CO 2 . This type of drying makes it possible to avoid shrinkage of the pores and of the material. Silica aerogels, in general, have been disclosed in U.S. Pat. No. 9,320,689, the entire content of which is hereby incorporated by reference.
- hydrophobic silica aerogels that may be used in the invention, examples that may be mentioned include the aerogel sold under the name VM-2260 (INCI name: Silica silylate), by the company Dow Corning, the particles of which have a mean size of about 1000 microns and a specific surface area per unit of mass ranging from 600 to 800 m 2 /g.
- the aerogel sold under the name VM-2270 (INCI name: Silica silylate), by the company Dow Corning, the particles of which have a mean size ranging from 5-15 microns and a specific surface area per unit of mass ranging from 600 to 800 m 2 /g can be used.
- the silica aerogel particles can be used in the inventive compositions from 0.1% to about 8% by weight, preferably from 0.25% to 6% by weight, and preferably from 0.5% to 4% by weight, including all ranges and subranges therebetween, all weights based on the weight of the composition as a whole.
- the basecoat composition of the present invention may include at least one wax.
- a wax is a lipophilic fatty compound (similar to those described above for “oil”) except that it is solid at room temperature (25° C.), has a reversible solid/liquid change of state (that is, the state of the material may change based on temperature), has a melting point greater than 45° C., preferably greater than 55° C., more preferably between about 65° C. to about 120° C., and has anisotropic crystal organization in the solid state.
- the melting point of the wax may be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name DSC 30 by Mettler.
- DSC differential scanning calorimeter
- the melting point may be measured according to the drop ASTM method, D-127.
- the waxes can generally be those used in cosmetics.
- the waxes may be of natural origin, for instance beeswax, carnauba wax, candelilla wax, ouricoury wax, Japan wax, cork fiber wax, sugar cane wax, paraffin wax, lignite wax, microcrystalline waxes, lanolin wax, montan wax, ozokerites and hydrogenated oils, for instance hydrogenated jojoba oil.
- the waxes also may be of synthetic origin, for instance polyethylene waxes derived from the polymerization of ethylene, waxes obtained by Fischer-Tropsch synthesis, esters of fatty acids and of glycerides that are solid at 40° C.
- waxes include, for example, polyethylene waxes, for example the product sold under the name Performalene 500-L Polyethylene (New Phase Technology), and polymethylene waxes, for instance the product sold under the name Cirebelle 303 (Sasol).
- Particular waxes include, for example, silicone waxes such as polypropylsilsesquioxane wax substituted with alkyl units having at least 30 carbons.
- silicone waxes such as polypropylsilsesquioxane wax substituted with alkyl units having at least 30 carbons.
- Polypropylsilsesquioxane waxes in general, have been disclosed in patent publication WO2005/100444 and U.S. Pat. No. 8,586,013, the entire contents of which are hereby incorporated by reference in their entirety.
- a particularly preferred polypropylsilsesquioxane wax for use in the present invention is a C30-45 ALKYLDIMETHYLSILYL POLYPROPYLSILSESQUIOXANE commercially available from DOW CORNING under the tradename SW-8005 C30 Resin Wax.
- the basecoat compositions of the present invention may optionally further include at least one cosmetically or dermatologically acceptable additional additive such as thickener, a plasticizer, an antioxidant, an essential oil, a botanical extract, a fragrance, a preserving agent, a fragrance, a pasty fatty substance, a neutralizing agent, and a polymer, and cosmetically active agents and/or dermatological active agents such as, for example, emollients, moisturizers, vitamins, essential fatty acids and medicaments.
- additional additive such as thickener, a plasticizer, an antioxidant, an essential oil, a botanical extract, a fragrance, a preserving agent, a fragrance, a pasty fatty substance, a neutralizing agent, and a polymer
- cosmetically active agents and/or dermatological active agents such as, for example, emollients, moisturizers, vitamins, essential fatty acids and medicaments.
- basecoat compositions of the present invention may include from about volatile hydrocarbon oil in a concentration by weight from about 20%, 30% or 40% to about 65%, 75%, or 85%; at least one silicone resin in a concentration by weight from about 5%, 10% or 15% to about 25%, 35%, or 45%; colorant in a concentration by weight from about 1%, 2% or 5% to about 5%, 10% or 20%; and optionally a filler in a concentration by weight from about 2%, 3% or 5% to about 6%, 10%, or 20%.
- the basecoat is substantially free of one or more of: silicone oils, water, waxes, and non-volatile hydrocarbon oils.
- topcoat compositions including at least one film-forming agent and non-volatile oil carrier are provided.
- the topcoat composition consists essentially of at least one silicone resin and at least one non-volatile oil, such as a non-volatile silicone oil.
- the topcoat composition when the topcoat composition is applied to a long-wear lip composition such as the basecoats described herein, the topcoat composition does not inhibit the transfer-resistance of the long-wear lip composition.
- Silicone resins useful in the topcoat are those described above with reference to the basecoat. However, the basecoat and topcoat need not include any or all of the same silicone resins. According to certain embodiments, the silicone resin is selected from the group consisting of siloxysilicate resins, silsesquioxane resins, and mixtures thereof. In certain embodiments, the silicone resin includes or consists of siloxysilicate resins such as trimethylsiloxysilicate.
- the concentration by weight of the one or more silicone resins in the topcoat may be from at least about 10%, such as at least above 15% According to certain embodiments, the concentration by weight of the one or more silicone resins ranges from about 15% or 20% to about 25% or 30% by weight.
- the non-volatile oil carrier includes, consists essentially of or consists of one or more non-volatile oils.
- the terms “oil” and “non-volatile” are as described above.
- the non-volatile oil has a vapor pressure at 25° C. and atmospheric pressure that is non-zero and is less than 0.02 mmHg (2.66 Pa) and better still less than 10′′ 3 mmHg (0.13 Pa).
- the non-volatile oil carrier may include relatively small concentrations of volatile oils, such as volatile silicone oils.
- the concentration of volatile oils in the topcoat is less than the concentration of the non-volatile oils.
- the nonvolatile oil carrier may have up to 40%, such as up to 30%, such as up to 20%, such as up to 10%, such as up to 5%, such as up to 1% of volatile oils, measured on a concentration by weight basis versus the total oil in the non-volatile oil carrier.
- the non-volatile oil is a high viscosity oil which is a silicone oil and/or a hydrocarbon oil.
- “High viscosity” means an oil having a viscosity greater than 100 cSt, particularly greater than 250 cSt at 25° C.
- the non-volatile oil is selected from a silicone oil.
- Such oils are described, for example in US 2011/0293550 and US 2004/0126350, both of which are herein incorporated by reference.
- non-volatile silicone oils that may be used in the invention preferably have a viscosity at 25° C. between 9 cSt and 800 000 cSt, preferably less than or equal to 600 000 cSt and preferably less than or equal to 500 000 cSt.
- the viscosity of these silicone oils may be measured according to standard ASTM D-445.
- the non-volatile silicone oil is a non-phenylated silicone oil.
- non phenylated silicone oil or “non phenylated silicone oil” means a silicon oil having no phenyl substituent.
- a composition according to the invention contains at least one non-phenylated linear silicone oil.
- non-volatile non phenylated silicone oils include polydimethylsiloxanes; alkyl dimethicones; vinyl methyl methicones; and also silicones modified with optionally fluorinated aliphatic groups, or with functional groups such as hydroxyl, thiol and/or amine groups.
- Non-limiting examples of suitable non-volatile silicone oils include polymethylsiloxanes (PDMS) with a linear or cyclic silicone chain, which are liquid or pasty at room temperature, especially cyclopolydimethylsiloxanes (cyclomethicones) such as cyclohexasiloxane; polydimethylsiloxanes (CTFA designation “dimethicones”) including alkyl or alkoxy groups, which are pendent or at the end of a silicone chain, these groups containing from 2 to 24 carbon atoms; polydiethyl siloxanes; and dimethicone fluids having viscosity from about 300 cPs at 25° C. to about 1500 cPs at 25° C. Particularly useful dimethicone fluids have viscosity from about 350 cPs at 25° C. to about 1000 cPs at 25° C.
- high viscosity silicone oils include, but are not limited to, Xiameter® silicone fluids from Dow Corning.
- the at least one non-volatile silicone oil is preferably present in the compositions of the present invention in an amount ranging from about 2% to about 30% by weight, including from about 4% to about 25% by weight, typically about 6% to about 20% by weight, based on the total weight of the composition, including all ranges and subranges within these ranges.
- the non-volatile non phenylated silicon oil is preferably chosen from dimethicone oils, preferably chosen from polydimethylsiloxanes (PDMS); alkyl dimethicones.
- PDMS polydimethylsiloxanes
- the PDMSs may include alkyl or alkoxy groups, which are pendent and/or at the end of the silicone chain, these groups each containing from 2 to 24 carbon atoms, such as cetyldimethicone sold under the commercial reference ABIL WAX 9801 from Evonik Goldschmidt,
- the PDMS may include aliphatic and/or aromatic groups, or functional groups such as hydroxyl, thiol and/or amine groups,
- the non-phenylated linear silicone oil may be chosen especially from the silicones of formula (I):
- R groups are together or separately, an alkyl radical containing 1 to 6 carbon atoms, vinyl radical, an amine radical or a hydroxyl radical,
- X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or an amine radical, n and p are integers chosen so as to have a fluid compound, in particular whose viscosity at 25° C. is between 9 centistokes (cSt) (9 ⁇ 1 OW/s) and 800 000 cSt.
- the non-volatile silicone oil includes, consists essentially of or consists of polydimethylsiloxanes having a viscosity from about 100 cSt to about 5000 cSt.
- the non-volatile silicone oil includes at least one non-volatile phenylated silicone oil.
- phenylated silicone oil or “phenyl silicone oil” means a silicone oil having at least one phenyl substituent.
- Such a phenyl silicone oil is preferably trimethyl pentaphenyl trisiloxane, or Tetramethyl Tetraphenyl Trisiloxane.
- oils are especially manufactured by Dow Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl-1,1,3,5,5-pentaphenyl trisiloxane; INCI name: trimethyl pentaphenyl trisiloxane), or Tetramethyl Tetraphenyl Trisiloxane sold under the reference Dow Corning 554 Cosmetic Fluid by Dow Corning may also be used.
- the phenyl silicone oils corresponding to the following formula (TV):
- non-volatile silicone oils examples that may be mentioned include phenyl trimethicones, Tetramethyl Tetraphenyl Trisiloxane, diphenyl siloxyphenyltrimethicone, diphenyl siloxyphenyldimethicone, trimethylpentaphenyl trisiloxane, phenyldimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes and 2-phenylethyl trimethylsiloxysilicates, and mixtures thereof.
- the topcoat includes from about 15% by weight to about 30% by weight of the second silicone film-forming agent and from about 60% to about 85% by weight of one or more non-volatile silicone oils.
- the topcoat composition may include additional ingredients such as preservatives, natural extracts, colorants, waxes, polymers vitamins, antioxidants, skin benefit agents, and the like.
- concentrations of these other ingredients may be, for examples, less than about 20%, such as less than about 10%, such as less than about 5% by weight.
- the topcoat composition includes from about 0.001%, 0.005% or 0.1% to about 0.5%, 1%, 2%, 5% or 10% of a cosmetic additive, such as an additive selected from a group consisting of vitamins, antioxidants, natural extracts, polymers, or colorants.
- the topcoat composition is substantially free of one or more or even all of: non-volatile hydrocarbon oils, volatile oils, waxes, colorants, C2-C4 monoalcohols, glycols, and water. According to certain other embodiments the topcoat composition is substantially free of diglyceryl polyacyladipate and/or non-volatile phenylated silicone oils. According to certain other embodiments the topcoat composition is substantially free of colorants.
- the topcoat composition for use on the lips consists essentially of from about 15% by weight to about 30% by weight of at least one silicone film-forming agent; from about 65% to about 85% of a non-volatile silicone oil; and from about 0.001% to about 10% by weight of one or more cosmetic additives, wherein the at least one silicone film-forming agent and the one or more cosmetic additives are dispersed or dissolved in the non-volatile silicone oil.
- the topcoat may be substantially free of one or more of: colorants, hydrocarbon oils, water, waxes, and phenylated silicone oils, diglyceryl polyacyladipate, and/or volatile oils.
- the basecoat and topcoat are included in a cosmetic system or “kit.”
- the kit includes (1) a long-wear lip composition including at least one silicone film-forming agent, colorant, and a volatile hydrocarbon oil; and (2) a topcoat composition including at least one second silicone film-forming agent in a non-volatile oil carrier.
- methods for enhancing the appearance of lips including applying a long-wear lip composition including at least one silicone film-forming agent, colorant, and a volatile hydrocarbon oil to the lips to form a basecoat, and after some waiting period such as sufficient to dry the basecoat or to allow a sufficient amount of volatile oil to evaporate; (2) applying a (topcoat) composition including at least one second silicone film-forming agent in a non-volatile oil carrier to form a topcoat over the basecoat, are provided.
- the topcoat composition when the topcoat composition is applied to the long-wear lip composition, the topcoat composition does not inhibit the transfer-resistance of the long-wear lip composition.
- compositions and methods of the present invention can “comprise,” “consist of” or “consist essentially of” the identified ingredients and process steps.
- the sole “basic and novel property” of such compositions and/or methods is transfer-resistance.
- transfer-resistance enhancers or boosters for example, additional film-forming agents
- a “material effect” on the basic and novel property of the invention can only be an adverse effect.
- inventive cosmetic system is surprisingly able to provide long lasting wear and long lasting high gloss due to the selection of ingredients. It is believed that the volatile hydrocarbon oil of the basecoat evaporates quickly allowing the basecoat film-forming agent to set. The non-volatile silicone in the topcoat simultaneously plasticizes the silicone film formers in the basecoat and the topcoat and builds durable gloss without disrupting the basecoat layer underneath.
- Basecoat Topcoat Isododecane 50-60 Triethylsiloxy silicate 15-25 15-25 Dimethicone, 1000 cSt — 75-85 Nylon-611/Dimethicone 5-15 Polymer Colorants 3-8 Fillers 6-10 Additional Ingredients 0-5 0-0.1
- the basecoat composition is made by conventional techniques, for example, by: by charging the vessel with optional filler at room temperature and homogenizing, adding pigments (colorants), homogenizing, adding copolymer such as Nylon-611/Dimethicone Polymer, homogenizing and applying vacuum, adding silicone resin and isododecane at elevated temperature such as 80 C, homogenizing, adding additional fillers, homogenizing, and allowing to cool.
- the topcoat composition is made by charging a vessel with dimethicone, adding vitamin E (additional ingredient) under vortex shear; slowly adding triethylsiloxysilicate, increasing mixing speed and allow to mix while maintaining temperature below 35° C. until Triethylsiloxysilicate is well-dispersed.
- Example 1 A basecoat and topcoat consistent with Example 1 were tested together as a cosmetic system. One hundred and thirty-four women applied the basecoat and topcoat in a manner consistent with the invention described herein.
Abstract
Description
- The present application is based upon and claims the benefit of priority from U.S. application Ser. No. 16/910,729, filed Jun. 24, 2020, the entire contents of which are incorporated herein by reference.
- The present invention relates to a topcoat composition for long-wear lip compositions comprising at least one silicone film-forming agent, as well as to cosmetic systems, kits and methods of treating, making-up and enhancing the appearance of lips, including a topcoat composition for application to a basecoat composition.
- Many cosmetic compositions, including pigmented cosmetics such as lipsticks or lip colors, have been formulated in an attempt to possess long-wearing properties upon application. Unfortunately, many of these compositions do not generally possess both good long-wear/transfer-resistance properties as well as high gloss.
- For example, with respect to lip compositions, commercial products containing silicon resins such as MQ resins are known. Such products are known to provide good long wear properties/transfer-resistance.
- At times, a second composition (topcoat) is separately applied to such products to improve poor properties of the compositions to make the products acceptable to consumers. However, topcoat compositions tend to decrease the long-wear/transfer-resistance properties of the lip compositions, thereby rendering the long-wear/transfer resistant composition less acceptable to consumers and less acceptable for their intended purpose.
- Thus, there remains a need for improved lip compositions and systems having improved cosmetic properties, particularly good transfer-resistance, feel and shine characteristics upon application.
- Accordingly, one aspect of the present invention is a topcoat composition for long-wear lip compositions which provide or maintain good cosmetic properties such as, for example, good transfer-resistance, feel and shine properties upon application to a long-wear lip composition.
- In one aspect, the present invention relates to a cosmetic system comprising (1) a lip basecoat composition including at least one first silicone film-forming agent, colorant, and a volatile hydrocarbon oil, and (2) a topcoat composition including at least one second silicone film-forming agent in a non-volatile oil carrier.
- In another aspect, the present invention relates to a method of making up the lips. The method includes applying to the lips a first composition including at least one first silicone film-forming agent, colorant, and a volatile hydrocarbon oil to form a basecoat. After a waiting period, a second composition including at least one second silicone film-forming agent in a non-volatile oil carrier is applied to form a topcoat over the basecoat.
- In another aspect, the present invention relates to a topcoat composition for use on the lips, wherein the topcoat consists essentially of from about 15% by weight to about 30% by weight of at least one silicone film-forming agent; from about 60% to about 85% of a non-volatile silicone oil; and from about 0.001% to about 10% by weight of one or more cosmetic additives, wherein the at least one silicone film-forming agent and the one or more cosmetic additives are dispersed or dissolved in the non-volatile silicone oil.
- According to the invention, the term “anhydrous” refers to a composition not containing any water, that is to say a composition in which the water that may be present comes only from the water of crystallization or of adsorption of the starting materials. In any case contains less than about 2% by weight of water, such as less about 1% water, such as less than about 0.5% water such as less about 0.1% of water.
- All percentages of ingredients herein are listed on an actives basis unless specifically stated otherwise. Further, all percentages of ingredients are percent by weight unless specifically stated otherwise.
- As used herein, the expression “at least one” means one or more and thus includes individual components as well as mixtures/combinations.
- Other than in the operating examples, or where otherwise indicated, all numbers expressing quantities of ingredients and/or reaction conditions are to be understood as being modified in all instances by the term “about,” meaning within 15%, such as within 10%, of the indicated number. For example, about 10% means from 8.5% to 11.5%, such as between 9% and 11%.
- “Film former” or “film forming agent” or “film forming polymer” or “film forming resin” as used herein mean a polymer or resin that leaves a film on the substrate to which it is applied, for example, after a solvent accompanying the film former has evaporated, absorbed into and/or dissipated on the substrate.
- “Transfer resistance” as used herein refers to the quality exhibited by compositions that are not readily removed by contact with another material, such as, for example, a glass, an item of clothing or the skin, for example, when eating or drinking. Transfer resistance may be evaluated by any method known in the art for evaluating such. For example, transfer resistance of a composition may be evaluated by a “kiss” test. The “kiss” test may involve application of the composition to human keratin material such as hair, skin or lips followed by rubbing a material, for example, a sheet of paper, against the hair, skin or lips after expiration of a certain amount of time following application, such as 2 minutes after application. Similarly, transfer resistance of a composition may be evaluated by the amount of product transferred from a wearer to any other substrate, such as transfer from the hair, skin or lips of an individual to a collar when putting on clothing after the expiration of a certain amount of time following application of the composition to the hair, skin or lips. The amount of composition transferred to the substrate (e.g., collar, or paper) may then be evaluated and compared. For example, a composition may be transfer resistant if a majority of the product is left on the wearer's hair, skin or lips. Further, the amount transferred may be compared with that transferred by other compositions, such as commercially available compositions. In a preferred embodiment of the present invention, little or no composition is transferred to the substrate from the hair, skin or lips.
- “Long wear” compositions as used herein, refers to compositions where color remains the same or substantially the same as at the time of application, as viewed by the naked eye, after an extended period of time. Long wear properties may be evaluated by any method known in the art for evaluating such properties. For example, long wear may be evaluated by a test involving the application of a composition to human hair, skin or lips and evaluating the color of the composition after an extended period of time. For example, the color of a composition may be evaluated immediately following application to hair, skin or lips and these characteristics may then be re-evaluated and compared after a certain amount of time. Further, these characteristics may be evaluated with respect to other compositions, such as commercially available compositions. For lip compositions, “long wear” typically means the composition remains on the lips at least about 4 hours up to about 24 hours, and retains rich color even after eating.
- “Liquid” or “liquid cosmetic” or “liquid lipstick” or “liquid composition” means a composition having a fixed volume, flows to cover the bottom and assumes the shape of the portion of the container it fills and is slightly compressible.
- “Tackiness” as used herein refers to the adhesion between two substances. For example, the more tackiness there is between two substances, the more adhesion there is between the substances. To quantify “tackiness,” it is useful to determine the “work of adhesion” as defined by IUPAC associated with the two substances. Generally speaking, the work of adhesion measures the amount of work necessary to separate two substances. Thus, the greater the work of adhesion associated with two substances, the greater the adhesion there is between the substances, meaning the greater the tackiness is between the two substances.
- Work of adhesion and, thus, tackiness, can be quantified using acceptable techniques and methods generally used to measure adhesion and the one far along described.
- “Substituted” as used herein, means comprising at least one substituent. Non-limiting examples of substituents include atoms, such as oxygen atoms and nitrogen atoms, as well as functional groups, such as amine groups, ether groups, alkoxy groups, acyloxyalky groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide groups, halogen containing groups, ester groups, thiol groups, sulphonate groups, thiosulphate groups, siloxane groups, and polysiloxane groups. The substituent(s) may be further substituted.
- “Substantially free” as it is used herein means that while it is preferred that no amount of the specific component be present in the composition, it is possible to have very small amounts of it in the compositions of the invention provided that these amounts do not materially affect at least one, preferably most, of the advantageous properties of the conditioning compositions of the invention. In certain embodiments, substantially free means less than about 2% of the identified ingredient, such as less than about 1%, such as less than about 0.5% of the ingredient.
- “About,” as referring to, for example, concentrations of ingredients, means within 10% to 15% of the indicated number.
- Numerical ranges are inclusive of endpoints and meant to include all combinations and sub-combinations. For example, from about 5%, 10% or 15% to about 20%, 50% or 60% means about 5% to about 20%, about 5% to about 50%, about 5% to about 60%, about 10% to about 20%, about 10% to about 50%, about 10% to about 60%, about 15% to about 20%, about 15% to about 50%, or about 15% to about 60%.
- All concentrations in this specification are by weight unless otherwise specifically stated differently.
- “Keratinous materials” includes materials containing keratin such as hair, skin, eyebrows, lips and nails.
- “Volatile”, as used herein, means having a flash point of less than about 100° C.
- “Non-volatile”, as used herein, means having a flash point of greater than about 100° C.
- “Actives basis” as used herein means considering only the particular component of ingredient (e.g., in a composition) and ignoring other chemically unrelated components that may be also be present in the same raw material source of that particular component.
- The compositions and methods of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful.
- Basecoat Composition
- According to embodiments of the present invention, a long-wear lip composition including at least one silicone film-forming agent is provided. Preferably, the silicone film-forming agent is selected from the group consisting of silicone resins, polyorganosiloxane copolymers, and mixtures thereof. The basecoat compositions of the present invention may be in any form, either liquid or non-liquid (semi-solid, soft solid, solid, etc.). For example, it may be a paste, a solid, a gel, or a cream. It may be an emulsion, such as an oil-in-water or water-in-oil emulsion, a multiple emulsion, such as an oil-in-water-in-oil emulsion or a water-in-oil-in-water emulsion, or a solid, rigid or supple gel. The composition of the invention may, for example, include an external or continuous fatty phase. The composition can also be a molded composition or cast as a stick or a dish.
- In certain notable embodiments, the basecoat is a liquid. In certain other notable embodiments, the basecoat is a solution or dispersion including at least one silicone film-forming agent and at least one colorant in a volatile hydrocarbon oil.
- Silicone Resins
- According to preferred embodiments, the long-wear lip compositions of the present invention include at least one silicone resin. Examples of suitable silicone resins include those described, for example, in U.S. Pat. Nos. 5,505,937, 5,911,974, 5,965,112, 5,985,298, 6,074,654, 6,780,422, 6,908,621, the disclosures of which are hereby incorporated by reference in their entirety.
- According to preferred embodiments, the long-wear lip compositions contain siloxysilicate resins. One non-limiting example of a siloxysilicate in accordance with the present invention is trimethylsiloxysilicate, which may be represented by the following formula:
-
[(CH3)3SiO]x(SiO4/2)y - wherein x and y may, for example, range from 50 to 80. Such siloxysilicates are commercially available from General Electric, Dow Corning, Wacker, Milliken, Siltech, Grant Industries, Momentive and Shin-Etsu Silicones under the tradename Resin MQ®.
- According to preferred embodiments, the long-wear lip compositions contain silsesquioxane resins such as, for example, polypropyl silsesquioxane resin.
- Silsesquioxane resins are a specific form of silicone resin. Silicone resin nomenclature is known in the art as “MDTQ” nomenclature, whereby a silicone resin is described according to the various monomeric siloxane units which make up the polymer. Each letter of “MDTQ” denotes a different type of unit. When the film-forming resin is made up predominantly of tri-functional units (or T units), it is generally called a silsesquioxane resin, which is described, for example in US 2006/0292096, herein incorporated by reference in its entirety.
- Examples of silsesquioxane resins that may be used in the present invention are alkyl silsesquioxane resins that are silsesquioxane homopolymers and/or copolymers having an average siloxane unit of the general formula R1 nSiO(4-n)/2, wherein each R1 is a propyl group, wherein more than 80 mole % of R1 represent a C3-C10 alkyl group, n is a value of from 1.0 to 1.4, and more than 60 mole % of the copolymer includes R1SiO3/2 units. As each R1 is a propyl group these polymers are called polypropylsilsesquioxane resins or “t-propyl” silsesquioxane resins. These resins and methods of making them are described, for example in U.S. Pat. No. 8,586,013, 2012/0301415, 2007/0093619, and 2006/0292096, all of which are herein incorporated by reference in their entirety.
- A non-limiting example of a polypropylsilsesquioxane resin suitable for use in the present invention is commercially available from Dow Corning as Dow Corning 670 Fluid or Dow Corning 680 Fluid. These Dow Corning resins have a general formula of RnSiO(4-n)/2 wherein R is independently chosen from a hydrogen atom and a monovalent hydrocarbon group comprising 3 carbon atoms, wherein more than 80 mole % of R are propyl groups, n is a value from 1.0 to 1.4, more than 60 mole % of the copolymer includes RSiO3/2 units, and having a hydroxyl or alkoxy content from 0.2 to 10% by weight, for example between 1 and 4% by weight, preferably between 5 and 10% by weight, and more preferably between 6 and 8% by weight. Preferably, the polypropylsilsesquioxane resin has a molecular weight from about 5000 to about 30,000 and a Tg from about −5° C. to about 5° C.
- According to preferred embodiments, the long-wear lip composition contains at least one silicone resin selected from the group consisting of siloxy silicate resins, silsesquioxane resins, and mixtures thereof.
- The at least one silicone resin is preferably present in the long-wear lip compositions of the present invention in an amount ranging from about 5% to about 30% by weight, preferably from about 10% to about 25% by weight, and preferably from about 15% to about 20% by weight, including all ranges and subranges therebetween, all weights being based on the weight of the composition as a whole.
- Volatile Hydrocarbon Oils
- The basecoat composition includes at least one volatile hydrocarbon oil. The term “oil,” as used herein, means nonaqueous compounds having a melting point of less than about 25° C. and at atmospheric pressure (1.013×. 1O5 Pa). Oils are generally immiscible with water wherein “immiscible” is intended to mean that the mixing of the same amount of water and oil, after mixing (for example Rayneri 550 rpm; 10 minutes), does not result in a stable solution including just one phase, under normal temperature and pressure conditions
- Oils generally include a hydrophobic moiety, such as one meeting one or more of the following three criteria: (a) has a carbon chain of at least six carbons in which none of the six carbons is a carbonyl carbon or has a hydrophilic moiety (defined below) bonded directly to it; (b) has two or more alkyl siloxy groups; or (c) has two or more oxypropylene groups in sequence. The hydrophobic moiety may include linear, cyclic, aromatic, saturated or unsaturated groups. The hydrophobic compound is in certain embodiments not amphiphilic and, as such, in this embodiment does not include hydrophilic moieties, such as anionic, cationic, zwitterionic, or nonionic groups, that are polar, including sulfate, sulfonate, carboxylate, phosphate, phosphonate, ammonium, including mono-, di-, and trialkylammonium species, pyridinium, imidazolinium, amidinium, poly(ethyleneiminium), ammonioalkylsulfonate, ammonioalkylcarboxylate, amphoacetate, and poly(ethyleneoxy)sulfonyl moieties. In certain embodiments, the oil does not include hydroxyl moieties. In certain embodiments, the oil is not surface active—i.e., when added in a weight concentration of 1% to water does not reduce surface tension of the water to less than 50 dynes/cm.
- Examples of suitable volatile hydrocarbon oils include, for example, volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures and in particular branched C8 to C16 alkanes such as C8 to C16 isoalkanes (also known as isoparaffins), isododecane, isodecane, isohexadecane, and for example, the oils sold under the trade names of Isopar or Permethyl, the C8 to C16 branched esters such as isohexyl or isodecyl neopentanoate, alcohols, and their mixtures. Preferably, the volatile hydrocarbon-based oils have a flash point of at least 40° C.
- Examples of volatile hydrocarbon-based oils include, but are not limited to those given in Table 1 below.
-
TABLE 1 Compound Flash Point (° C.) Isododecane 43 Isohexadecane 102 Propylene glycol n-butyl ether 60 Ethyl 3-ethoxypropionate 58 Propylene glycol methylether acetate 46 Isopar L (isoparaffin C11-C13) 62 lsopar H (isoparaffin C11-C12) 56 - In addition to the volatile hydrocarbon oil, the basecoat may optionally include one or more volatile silicone oils. The volatile silicone oil, if present, may be chosen from linear or cyclic silicone oils, such as those having a viscosity, at room temperature, of less than or equal to 6 cSt, and having from 2 to 7 silicon atoms, optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms.
- Examples of suitable volatile silicone oils include, but are not limited to, those listed in Table 2 below.
-
TABLE 2 Viscosity Compound Flash Point (° C.) (cSt) Octyltrimethicone 93 1.2 Hexyltrimethicone 79 1.2 Decamethylcyclopentasiloxane 72 4.2 (cyclopentasiloxane or D5) Octamethylcyclotetrasiloxane 55 2.5 (cyclotetradimethylsiloxane or D4) Dodecamethylcyclohexasiloxane 93 7 (D6) Decamethyltetrasiloxane(L4) 63 1.7 KF-96 A from Shin Etsu 94 6 PDMS (polydimethylsiloxane) 56 1.5 DC 200 (1.5 cSt) from Dow Corning PDMS DC 200 (2 cSt) from Dow 87 2 Corning PDMS DC 200 (3 St) from Dow 102 3 Corning - According to certain embodiments the one or more volatile hydrocarbon oils are present in a concentration by weight greater that is greater than the concentration by weight of the one or more volatile silicone oils. According to certain other embodiments the one or more volatile hydrocarbon oils are present in a concentration by weight that is at least 2 to about 10 times that of the one or more volatile silicone oils.
- The at least one volatile hydrocarbon oil is generally present in the compositions of the present invention in an amount ranging from about 5% to about 50% by weight; such as from about 10% to about 45% by weight; such as from about 15% to about 40% by weight, all weights being based on the weight of the composition as a whole.
- The at least one volatile silicone oil if present, is generally present in the compositions of the present invention in an amount ranging from about 1% to about 25% by weight; such as from about 2% to about 15% by weight; such as from about 3% to about 10% by weight, all weights being based on the weight of the composition as a whole.
- According to notable embodiments, the basecoat compositions of the present invention may include at least one polyorganosiloxane copolymer. The polyorganosiloxane copolymer useful herein is preferably a polymer (homopolymer or copolymer) having at least one moiety which contains: at least one polyorganosiloxane group consisting of 1 to about 1000 organosiloxane units in the chain of the moiety or in the form of a graft, and at least two groups capable of establishing hydrogen interactions. Non-limiting examples of polyorganosiloxane copolymers are disclosed, for example in U.S. Pat. No. 8,945,525, the disclosure of which is hereby incorporated by reference in its entirety.
- Additional polyorganosiloxane copolymers which may be used in the long-wear lip compositions of the present invention include those described in documents U.S. Pat. Nos. 5,874,069, 5,919,441, 6,051,216, and 5,981,680 the entire contents of which are hereby incorporated by reference in their entirety.
- A preferred polyorganosiloxane copolymer for use in the present invention contain at least one moiety chosen from formula (III):
- and formula (IV)
- in which:
- (a) R1, R2, R3 and R4 are the same or different and may be selected from the group consisting of methyl, ethyl, propyl, isopropyl, a siloxane chain, and phenyl;
- (b) X is a linear or branched chain alkylene having 1-30 carbons;
- (c) Y is selected from the group consisting of linear or branched chain alkylenes having 1-40 carbons;
- (d) m is a number between 1 and 700;
- (e) n is a number between 1 and 500.
- Particularly preferred polyorganosiloxane copolymers useful herein are commercially available from Dow Corning under the tradenames DC 8178® and DC 8179®, which are known under the INCI denomination of Nylon-611/Dimethicone Copolymer.
- Preferably, the polyorganosiloxane copolymer is present in the long-wear lip compositions of the present invention in an amount ranging from about 2% to about 35% by weight, preferably from about 5% to about 30% by weight, and preferably from about 7% to about 20% by weight, including all ranges and subranges therebetween, all weights being based on the weight of the composition as a whole.
- According to preferred embodiments, the long-wear lip composition may further include as least one silicone elastomer. Preferably, the silicone elastomer is a non-emulsifying silicon elastomer. “Non-emulsifying” defines organopolysiloxane elastomers that do not contain hydrophilic chains, in particular polyoxyalkylene (especially polyoxyethylene or polyoxypropylene) or polyglyceryl units. Thus, according to one particular embodiment of the invention, the composition includes a silicone elastomer that is free of polyoxyalkylene units and polyglyceryl units.
- Suitable examples of non-emulsifying elastomers are described in U.S. Pat. No. 8,637,057, the disclosure of which is hereby incorporated by reference in its entirety.
- Further suitable examples of non-emulsifying elastomers useful in this invention include but not limit those sold under the names KSG-6, KSG-15, KSG-16, KSG-18, KSG-41, KSG-42, KSG-43 and KSG-44 by the company Shin-Etsu, DC 9040, DC 9041, DC 9509, DC 9505 and DC 9506, by the company Dow Corning, and SFE 839 by the company Momentive Performance Materials.
- The silicone elastomers are preferably in the form of a gel or a powder.
- According to preferred embodiments, the silicone elastomer particles are conveyed in the form of a gel formed from an elastomeric organopolysiloxane included in at least one hydrocarbon-based oil and/or one silicone oil. In these gels, the organopolysiloxane particles are often non-spherical particles. Not limiting examples of silicone elastomers useful in this invention are dimethicone crosspolymer gels (blends of dimethicone crosspolymers in solvents) having viscosity values from about 150 and to about 700 mm2/s, from about 200 to about 650 mm2/s and from about 300 to about 600 mm2/s, including all ranges and subranges therebetween.
- Particularly useful for this invention may be blends of high molecular weight silicone elastomers in volatile solvents, such as silicone oils, hydrocarbon oils and mixtures thereof.
- Specific examples of suitable silicone elastomeric gels include DC EL-8040 ID (INCI name: Isododecane (and) Dimethicone Crosspolymer) and DC EL-9140 DM (INCI name: Dimethicone (and) Dimethicone Crosspolymer), supplied by Dow Corning.
- Non-limiting examples of silicone elastomers and their synthesis are disclosed, for example in U.S. Pat. No. 8,637,057 and US/20150174048, both of which are herein incorporated by reference in their entirety.
- Although not wishing to be bound by any particular theory, it is believed that the silicone elastomer thickens the composition, adds the cushiony (spongy) effect and/or improves the application properties of the long-wear lip composition. Also, it provides a very soft feel and/or mattifying effect after application.
- Preferably, the silicone elastomer is present in a content ranging from 1 percent to 30 percent by weight of active material (dry matter), preferably from about 1.5 percent to about 20 percent, and preferably from 2 percent to 10 percent by weight relative to the total weight of the long-wear lip composition, including all ranges and subranges therebetween.
- Further, basecoat compositions of the present invention may optionally further include at least one cosmetically acceptable colorant such as a pigment or dyestuff. Examples of suitable pigments include, but are not limited to, inorganic pigments, organic pigments, lakes, pearlescent pigments, iridescent or optically variable pigments, and mixtures thereof. A pigment should be understood to mean inorganic or organic, white or colored particles. Said pigments may optionally be surface-treated within the scope of the present invention but are not limited to treatments such as silicones, perfluorinated compounds, lecithin, and amino acids.
- Representative examples of inorganic pigments useful in the present invention include those selected from the group consisting of rutile or anatase titanium dioxide, coded in the Color Index under the reference CI 77,891; black, yellow, red and brown iron oxides, coded under references CI 77,499, 77, 492 and, 77,491; manganese violet (CI 77,742); ultramarine blue (CI 77,007); chromium oxide (CI 77,288); chromium hydrate (CI 77,289); and ferric blue (CI 77,510) and mixtures thereof.
- Representative examples of organic pigments and lakes useful in the present invention include, but are not limited to, D&C Red No. 19 (CI 45,170), D&C Red No. 9 (CI 15,585), D&C Red No. 21 (CI 45,380), D&C Orange No. 4 (CI 15,510), D&C Orange No. 5 (CI 45,370), D&C Red No. 27 (CI 45,410), D&C Red No. 13 (CI 15,630), D&C Red No. 7 (CI 15,850), D&C Red No. 6 (CI 15,850), D&C Yellow No. 5 (CI 19,140), D&C Red No. 36 (CI 12,085), D&C Orange No. 10 (CI 45,425), D&C Yellow No. 6 (CI 15,985), D&C Red No. 30 (CI 73,360), D&C Red No. 3 (CI 45,430) and the dye or lakes based on cochineal carmine (CI 75,570) and mixtures thereof.
- Representative examples of pearlescent pigments useful in the present invention include those selected from the group consisting of the white pearlescent pigments such as mica coated with titanium oxide, mica coated with titanium dioxide, bismuth oxychloride, titanium oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with ferric blue, chromium oxide and the like, titanium mica with an organic pigment of the above-mentioned type as well as those based on bismuth oxychloride and mixtures thereof.
- The precise amount and type of colorant employed in the compositions of the present invention will depend on the color, intensity and use of the cosmetic composition and, as a result, will be determined by those skilled in the art of cosmetic formulation. However, one preferred amount of colorant for use in the present invention is from about 0.5% to about 15%, from about 1.5% to about 12%, and from about 2% to about 10%, based on the weight of the composition.
- The basecoat compositions of the present invention may optionally further include at least one filler. Fillers that may be used in the compositions of the invention include, for example, silica powder; talc; polyamide particles and especially those sold under the name Orgasol by the company Atochem; polyethylene powders; microspheres based on acrylic copolymers, such as those based on ethylene glycol dimethacrylate/lauryl methacrylate copolymer sold by the company Dow Corning under the name Polytrap; expanded powders such as hollow microspheres and especially the microspheres sold under the name Expancel by the company Kemanord Plast or under the name Micropearl F 80 ED by the company Matsumoto; powders of natural organic materials such as crosslinked or noncrosslinked corn starch, wheat starch or rice starch, such as the powders of starch crosslinked with octenyl succinate anhydride, sold under the name Dry-Flo by the company National Starch; silicone resin microbeads such as those sold under the name Tospearl by the company Toshiba Silicone; clays (hectorite, bentone, laponite, saponite, etc.); and mixtures thereof.
- The fillers may be present in the composition of the invention in an amount ranging from about 0.1% to about 50% by weight, such as from 0.5% to about 30% by weight, and such as from about 1% to about 20% by weight, all weights based on the weight of the composition as a whole.
- The basecoat compositions of the present invention may optionally further include at least one silica aerogel. Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air. They are generally synthesized via a sol-gel process in liquid medium and then dried, usually by extraction of a supercritical fluid, the one most commonly used being supercritical CO2. This type of drying makes it possible to avoid shrinkage of the pores and of the material. Silica aerogels, in general, have been disclosed in U.S. Pat. No. 9,320,689, the entire content of which is hereby incorporated by reference.
- As hydrophobic silica aerogels that may be used in the invention, examples that may be mentioned include the aerogel sold under the name VM-2260 (INCI name: Silica silylate), by the company Dow Corning, the particles of which have a mean size of about 1000 microns and a specific surface area per unit of mass ranging from 600 to 800 m2/g.
- Mention may also be made of the aerogels sold by the company Cabot under the references AEROGEL TLD 201, AEROGEL OGD 201, AEROGEL TLD 203, ENOVA® AEROGEL MT 1100, ENOVA AEROGEL MT 1200.
- In particular, the aerogel sold under the name VM-2270 (INCI name: Silica silylate), by the company Dow Corning, the particles of which have a mean size ranging from 5-15 microns and a specific surface area per unit of mass ranging from 600 to 800 m2/g can be used.
- The silica aerogel particles can be used in the inventive compositions from 0.1% to about 8% by weight, preferably from 0.25% to 6% by weight, and preferably from 0.5% to 4% by weight, including all ranges and subranges therebetween, all weights based on the weight of the composition as a whole.
- According to preferred embodiments, the basecoat composition of the present invention may include at least one wax. For the purposes of the present invention, a wax is a lipophilic fatty compound (similar to those described above for “oil”) except that it is solid at room temperature (25° C.), has a reversible solid/liquid change of state (that is, the state of the material may change based on temperature), has a melting point greater than 45° C., preferably greater than 55° C., more preferably between about 65° C. to about 120° C., and has anisotropic crystal organization in the solid state. The melting point of the wax may be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name DSC 30 by Mettler. For waxes that are derived from petroleum, such as microcrystalline wax, the melting point may be measured according to the drop ASTM method, D-127.
- The waxes can generally be those used in cosmetics. The waxes may be of natural origin, for instance beeswax, carnauba wax, candelilla wax, ouricoury wax, Japan wax, cork fiber wax, sugar cane wax, paraffin wax, lignite wax, microcrystalline waxes, lanolin wax, montan wax, ozokerites and hydrogenated oils, for instance hydrogenated jojoba oil.
- The waxes also may be of synthetic origin, for instance polyethylene waxes derived from the polymerization of ethylene, waxes obtained by Fischer-Tropsch synthesis, esters of fatty acids and of glycerides that are solid at 40° C.
- Particular waxes include, for example, polyethylene waxes, for example the product sold under the name Performalene 500-L Polyethylene (New Phase Technology), and polymethylene waxes, for instance the product sold under the name Cirebelle 303 (Sasol).
- Particular waxes include, for example, silicone waxes such as polypropylsilsesquioxane wax substituted with alkyl units having at least 30 carbons. Polypropylsilsesquioxane waxes, in general, have been disclosed in patent publication WO2005/100444 and U.S. Pat. No. 8,586,013, the entire contents of which are hereby incorporated by reference in their entirety. A particularly preferred polypropylsilsesquioxane wax for use in the present invention is a C30-45 ALKYLDIMETHYLSILYL POLYPROPYLSILSESQUIOXANE commercially available from DOW CORNING under the tradename SW-8005 C30 Resin Wax.
- The basecoat compositions of the present invention may optionally further include at least one cosmetically or dermatologically acceptable additional additive such as thickener, a plasticizer, an antioxidant, an essential oil, a botanical extract, a fragrance, a preserving agent, a fragrance, a pasty fatty substance, a neutralizing agent, and a polymer, and cosmetically active agents and/or dermatological active agents such as, for example, emollients, moisturizers, vitamins, essential fatty acids and medicaments.
- According to certain embodiments, basecoat compositions of the present invention may include from about volatile hydrocarbon oil in a concentration by weight from about 20%, 30% or 40% to about 65%, 75%, or 85%; at least one silicone resin in a concentration by weight from about 5%, 10% or 15% to about 25%, 35%, or 45%; colorant in a concentration by weight from about 1%, 2% or 5% to about 5%, 10% or 20%; and optionally a filler in a concentration by weight from about 2%, 3% or 5% to about 6%, 10%, or 20%. In certain of these embodiments, the basecoat is substantially free of one or more of: silicone oils, water, waxes, and non-volatile hydrocarbon oils.
- Topcoat Composition
- According to the present invention, topcoat compositions including at least one film-forming agent and non-volatile oil carrier are provided. According to certain embodiments, the topcoat composition consists essentially of at least one silicone resin and at least one non-volatile oil, such as a non-volatile silicone oil. Preferably, when the topcoat composition is applied to a long-wear lip composition such as the basecoats described herein, the topcoat composition does not inhibit the transfer-resistance of the long-wear lip composition.
- Silicone resins useful in the topcoat are those described above with reference to the basecoat. However, the basecoat and topcoat need not include any or all of the same silicone resins. According to certain embodiments, the silicone resin is selected from the group consisting of siloxysilicate resins, silsesquioxane resins, and mixtures thereof. In certain embodiments, the silicone resin includes or consists of siloxysilicate resins such as trimethylsiloxysilicate.
- The concentration by weight of the one or more silicone resins in the topcoat may be from at least about 10%, such as at least above 15% According to certain embodiments, the concentration by weight of the one or more silicone resins ranges from about 15% or 20% to about 25% or 30% by weight.
- Non-Volatile Carrier
- The non-volatile oil carrier includes, consists essentially of or consists of one or more non-volatile oils. The terms “oil” and “non-volatile” are as described above. According to certain embodiments, the non-volatile oil has a vapor pressure at 25° C. and atmospheric pressure that is non-zero and is less than 0.02 mmHg (2.66 Pa) and better still less than 10″3 mmHg (0.13 Pa).
- The non-volatile oil carrier may include relatively small concentrations of volatile oils, such as volatile silicone oils. In certain embodiments, the concentration of volatile oils in the topcoat is less than the concentration of the non-volatile oils. For example, the nonvolatile oil carrier may have up to 40%, such as up to 30%, such as up to 20%, such as up to 10%, such as up to 5%, such as up to 1% of volatile oils, measured on a concentration by weight basis versus the total oil in the non-volatile oil carrier.
- According to a particular embodiment of the present invention, the non-volatile oil is a high viscosity oil which is a silicone oil and/or a hydrocarbon oil. “High viscosity” means an oil having a viscosity greater than 100 cSt, particularly greater than 250 cSt at 25° C. Most particularly, the non-volatile oil is selected from a silicone oil. Such oils are described, for example in US 2011/0293550 and US 2004/0126350, both of which are herein incorporated by reference.
- In particular, the non-volatile silicone oils that may be used in the invention preferably have a viscosity at 25° C. between 9 cSt and 800 000 cSt, preferably less than or equal to 600 000 cSt and preferably less than or equal to 500 000 cSt. The viscosity of these silicone oils may be measured according to standard ASTM D-445.
- According to certain embodiments, the non-volatile silicone oil is a non-phenylated silicone oil. The expression “non phenylated silicone oil” or “non phenylated silicone oil” means a silicon oil having no phenyl substituent.
- According to one embodiment, a composition according to the invention contains at least one non-phenylated linear silicone oil. Representative examples of these non-volatile non phenylated silicone oils that may be mentioned include polydimethylsiloxanes; alkyl dimethicones; vinyl methyl methicones; and also silicones modified with optionally fluorinated aliphatic groups, or with functional groups such as hydroxyl, thiol and/or amine groups.
- Non-limiting examples of suitable non-volatile silicone oils include polymethylsiloxanes (PDMS) with a linear or cyclic silicone chain, which are liquid or pasty at room temperature, especially cyclopolydimethylsiloxanes (cyclomethicones) such as cyclohexasiloxane; polydimethylsiloxanes (CTFA designation “dimethicones”) including alkyl or alkoxy groups, which are pendent or at the end of a silicone chain, these groups containing from 2 to 24 carbon atoms; polydiethyl siloxanes; and dimethicone fluids having viscosity from about 300 cPs at 25° C. to about 1500 cPs at 25° C. Particularly useful dimethicone fluids have viscosity from about 350 cPs at 25° C. to about 1000 cPs at 25° C.
- Specific examples of suitable for this invention high viscosity silicone oils include, but are not limited to, Xiameter® silicone fluids from Dow Corning.
- The at least one non-volatile silicone oil, if present, is preferably present in the compositions of the present invention in an amount ranging from about 2% to about 30% by weight, including from about 4% to about 25% by weight, typically about 6% to about 20% by weight, based on the total weight of the composition, including all ranges and subranges within these ranges.
- The non-volatile non phenylated silicon oil is preferably chosen from dimethicone oils, preferably chosen from polydimethylsiloxanes (PDMS); alkyl dimethicones.
- “Dimethicone” (INCI Name) corresponds to polydimethylsiloxane (chemical name).
- The PDMSs may include alkyl or alkoxy groups, which are pendent and/or at the end of the silicone chain, these groups each containing from 2 to 24 carbon atoms, such as cetyldimethicone sold under the commercial reference ABIL WAX 9801 from Evonik Goldschmidt,
- The PDMS may include aliphatic and/or aromatic groups, or functional groups such as hydroxyl, thiol and/or amine groups,
-
- polyalkylmethylsiloxanes such as cetyldimethicone sold under the commercial reference ABIL WAX 9801 from Evonik Goldschmidt, or polyalkylmethylsiloxane optionally substituted with a fluorinated group, such as polymemyltrifluoropropyldimethylsiloxanes,
- The non-phenylated linear silicone oil may be chosen especially from the silicones of formula (I):
- in which: R groups are together or separately, an alkyl radical containing 1 to 6 carbon atoms, vinyl radical, an amine radical or a hydroxyl radical,
- X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or an amine radical, n and p are integers chosen so as to have a fluid compound, in particular whose viscosity at 25° C. is between 9 centistokes (cSt) (9×1 OW/s) and 800 000 cSt.
- According to a particular embodiment, the non-volatile silicone oil includes, consists essentially of or consists of polydimethylsiloxanes having a viscosity from about 100 cSt to about 5000 cSt.
- According to other embodiments, the non-volatile silicone oil includes at least one non-volatile phenylated silicone oil.
- The expression “phenylated silicone oil” or “phenyl silicone oil” means a silicone oil having at least one phenyl substituent.
- Such a phenyl silicone oil is preferably trimethyl pentaphenyl trisiloxane, or Tetramethyl Tetraphenyl Trisiloxane. Such oils are especially manufactured by Dow Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl-1,1,3,5,5-pentaphenyl trisiloxane; INCI name: trimethyl pentaphenyl trisiloxane), or Tetramethyl Tetraphenyl Trisiloxane sold under the reference Dow Corning 554 Cosmetic Fluid by Dow Corning may also be used. d) the phenyl silicone oils corresponding to the following formula (TV):
- in which Me represents methyl, y is between 1 and 1,000 and X represents —CH2-CH(CH3)(Ph). e) the phenyl silicone oils corresponding to formula (V) below:
- in which Me is methyl and Ph is phenyl, OR′ represents a group —OSiMe3 and y is 0 or ranges between 1 and 1000, and z ranges between 1 and 1000. In particular, y and z are such that compound (V) is a non-volatile oil.
- As preferred non-volatile silicone oils, examples that may be mentioned include phenyl trimethicones, Tetramethyl Tetraphenyl Trisiloxane, diphenyl siloxyphenyltrimethicone, diphenyl siloxyphenyldimethicone, trimethylpentaphenyl trisiloxane, phenyldimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes and 2-phenylethyl trimethylsiloxysilicates, and mixtures thereof.
- In certain embodiments, the topcoat includes from about 15% by weight to about 30% by weight of the second silicone film-forming agent and from about 60% to about 85% by weight of one or more non-volatile silicone oils.
- Additional Ingredients
- According to certain embodiments, the topcoat composition may include additional ingredients such as preservatives, natural extracts, colorants, waxes, polymers vitamins, antioxidants, skin benefit agents, and the like. The concentrations of these other ingredients may be, for examples, less than about 20%, such as less than about 10%, such as less than about 5% by weight. According to certain embodiments the topcoat composition includes from about 0.001%, 0.005% or 0.1% to about 0.5%, 1%, 2%, 5% or 10% of a cosmetic additive, such as an additive selected from a group consisting of vitamins, antioxidants, natural extracts, polymers, or colorants.
- According to certain other embodiments, the topcoat composition is substantially free of one or more or even all of: non-volatile hydrocarbon oils, volatile oils, waxes, colorants, C2-C4 monoalcohols, glycols, and water. According to certain other embodiments the topcoat composition is substantially free of diglyceryl polyacyladipate and/or non-volatile phenylated silicone oils. According to certain other embodiments the topcoat composition is substantially free of colorants.
- According to certain other embodiments, the topcoat composition for use on the lips consists essentially of from about 15% by weight to about 30% by weight of at least one silicone film-forming agent; from about 65% to about 85% of a non-volatile silicone oil; and from about 0.001% to about 10% by weight of one or more cosmetic additives, wherein the at least one silicone film-forming agent and the one or more cosmetic additives are dispersed or dissolved in the non-volatile silicone oil. The topcoat may be substantially free of one or more of: colorants, hydrocarbon oils, water, waxes, and phenylated silicone oils, diglyceryl polyacyladipate, and/or volatile oils.
- According to preferred embodiments, the basecoat and topcoat are included in a cosmetic system or “kit.” Accordingly, in certain embodiments, the kit includes (1) a long-wear lip composition including at least one silicone film-forming agent, colorant, and a volatile hydrocarbon oil; and (2) a topcoat composition including at least one second silicone film-forming agent in a non-volatile oil carrier.
- According to preferred embodiments, methods for enhancing the appearance of lips including applying a long-wear lip composition including at least one silicone film-forming agent, colorant, and a volatile hydrocarbon oil to the lips to form a basecoat, and after some waiting period such as sufficient to dry the basecoat or to allow a sufficient amount of volatile oil to evaporate; (2) applying a (topcoat) composition including at least one second silicone film-forming agent in a non-volatile oil carrier to form a topcoat over the basecoat, are provided.
- Preferably, when the topcoat composition is applied to the long-wear lip composition, the topcoat composition does not inhibit the transfer-resistance of the long-wear lip composition.
- The compositions and methods of the present invention can “comprise,” “consist of” or “consist essentially of” the identified ingredients and process steps. For purposes of the compositions and methods of the present invention where the invention “consists essentially of” the identified ingredients and/or process steps, the sole “basic and novel property” of such compositions and/or methods is transfer-resistance. Further, given that it is contemplated that other transfer-resistance enhancers or boosters (for example, additional film-forming agents) can be added to the invention methods and compositions in the context of the present invention, a “material effect” on the basic and novel property of the invention can only be an adverse effect. That is, because positive effects on transfer-resistance properties (such as those effected by additional film-forming agents) are within the scope of the present invention, only ingredients which have a material adverse effect on transfer-resistance properties would be relevant to determining whether or not compositions or methods “consist essentially of” the required elements.
- Without wishing to be held by theory, Applicants believe that the inventive cosmetic system is surprisingly able to provide long lasting wear and long lasting high gloss due to the selection of ingredients. It is believed that the volatile hydrocarbon oil of the basecoat evaporates quickly allowing the basecoat film-forming agent to set. The non-volatile silicone in the topcoat simultaneously plasticizes the silicone film formers in the basecoat and the topcoat and builds durable gloss without disrupting the basecoat layer underneath.
- Unless otherwise indicated, all numbers expressing quantities of ingredients, reaction conditions, and so forth used in the specification and claims are to be understood as being modified in all instances by the term “about.” Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties sought to be obtained by the present invention.
- Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contain certain errors necessarily resulting from the standard deviation found in their respective measurements. The following examples are intended to illustrate the invention without limiting the scope as a result. The percentages are given on a weight basis.
- The present invention will be better understood from the examples which follow. The examples are intended to be nonrestrictive and explanatory only, with the scope of the invention defined by the claims.
- The following tables set forth a basecoat and topcoat that are consistent with embodiments of the present invention.
-
Ingredient (% by Weight) Basecoat Topcoat Isododecane 50-60 Triethylsiloxy silicate 15-25 15-25 Dimethicone, 1000 cSt — 75-85 Nylon-611/Dimethicone 5-15 Polymer Colorants 3-8 Fillers 6-10 Additional Ingredients 0-5 0-0.1 - The basecoat composition is made by conventional techniques, for example, by: by charging the vessel with optional filler at room temperature and homogenizing, adding pigments (colorants), homogenizing, adding copolymer such as Nylon-611/Dimethicone Polymer, homogenizing and applying vacuum, adding silicone resin and isododecane at elevated temperature such as 80 C, homogenizing, adding additional fillers, homogenizing, and allowing to cool.
- The topcoat composition is made by charging a vessel with dimethicone, adding vitamin E (additional ingredient) under vortex shear; slowly adding triethylsiloxysilicate, increasing mixing speed and allow to mix while maintaining temperature below 35° C. until Triethylsiloxysilicate is well-dispersed.
- A basecoat and topcoat consistent with Example 1 were tested together as a cosmetic system. One hundred and thirty-four women applied the basecoat and topcoat in a manner consistent with the invention described herein.
- After wearing the cosmetic system, the women were asked whether the product lasted sixteen hours (yes or no). One hundred seven (80%) of the women answered yes. This is surprisingly high, especially for a glossy product.
Claims (14)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17/509,850 US20220040054A1 (en) | 2020-06-24 | 2021-10-25 | Long wear lip cosmetic sytem and topcoat |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/910,729 US11160735B1 (en) | 2020-06-24 | 2020-06-24 | Long wear lip cosmetic system and topcoat |
US17/509,850 US20220040054A1 (en) | 2020-06-24 | 2021-10-25 | Long wear lip cosmetic sytem and topcoat |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/910,729 Division US11160735B1 (en) | 2020-06-24 | 2020-06-24 | Long wear lip cosmetic system and topcoat |
Publications (1)
Publication Number | Publication Date |
---|---|
US20220040054A1 true US20220040054A1 (en) | 2022-02-10 |
Family
ID=78331324
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/910,729 Active US11160735B1 (en) | 2020-06-24 | 2020-06-24 | Long wear lip cosmetic system and topcoat |
US17/509,850 Pending US20220040054A1 (en) | 2020-06-24 | 2021-10-25 | Long wear lip cosmetic sytem and topcoat |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/910,729 Active US11160735B1 (en) | 2020-06-24 | 2020-06-24 | Long wear lip cosmetic system and topcoat |
Country Status (1)
Country | Link |
---|---|
US (2) | US11160735B1 (en) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004182667A (en) * | 2002-12-05 | 2004-07-02 | Mikimoto Pharmaceut Co Ltd | Lip cosmetic |
DE10316305A1 (en) * | 2003-04-08 | 2004-12-02 | Kryolan Gmbh Chemische Fabrik | Cosmetic skin marking compositions, e.g. for body painting or simulated tattoos, comprising trimethylsiloxy silicate, dimethicone, pigment and optionally polymethyl silsesquioxane and/or filler |
FR2918273A1 (en) * | 2007-07-03 | 2009-01-09 | Oreal | Cosmetic product, useful for make-up of skin, lips and/or integument, comprises a first composition comprising a silicone polyamide and a resin, and a second composition comprising phenylated silicone oil and at least a fatty paste |
US7842285B2 (en) * | 2004-11-04 | 2010-11-30 | L'oreal | Cosmetic compositions and methods of use |
US20110117043A1 (en) * | 2009-10-27 | 2011-05-19 | James Herman Dempsey | Methods of coating eyelashes and eyelids with a long-wearing mascara composition |
US20170281478A1 (en) * | 2016-03-31 | 2017-10-05 | L'oréal | Liquid lipstick compositions capable of forming a multilayer structure after application to lips |
JP2019065010A (en) * | 2017-10-04 | 2019-04-25 | 株式会社コーセー | Oily lip cosmetic |
US20190262257A1 (en) * | 2018-02-28 | 2019-08-29 | L'oreal | Matte lip compositions |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2107253C (en) | 1992-12-15 | 1998-04-21 | Anthony Castrogiovanni | Cosmetic compositions with improved transfer resistance |
IL115693A (en) | 1994-10-25 | 2000-08-13 | Revlon Consumer Prod Corp | Cosmetic compositions with improved transfer resistance |
US6139823A (en) | 1995-11-07 | 2000-10-31 | The Procter & Gamble Company | Transfer resistant cosmetic compositions |
US6071503A (en) | 1995-11-07 | 2000-06-06 | The Procter & Gamble Company | Transfer resistant cosmetic compositions |
US5919441A (en) | 1996-04-01 | 1999-07-06 | Colgate-Palmolive Company | Cosmetic composition containing thickening agent of siloxane polymer with hydrogen-bonding groups |
US5874069A (en) | 1997-01-24 | 1999-02-23 | Colgate-Palmolive Company | Cosmetic composition containing silicon-modified amides as thickening agents and method of forming same |
US6051216A (en) | 1997-08-01 | 2000-04-18 | Colgate-Palmolive Company | Cosmetic composition containing siloxane based polyamides as thickening agents |
US5981680A (en) | 1998-07-13 | 1999-11-09 | Dow Corning Corporation | Method of making siloxane-based polyamides |
US6620417B1 (en) | 1999-04-26 | 2003-09-16 | Revlon Consumer Products Corporation | Color cosmetic compositions containing organic oil and silicone mixture |
US8110206B2 (en) | 2002-09-06 | 2012-02-07 | L'oreal S.A. | Cosmetic composition comprising a hydrocarbon oil and a silicone oil |
KR100762154B1 (en) | 2003-04-14 | 2007-10-04 | 더 프록터 앤드 갬블 캄파니 | Anhydrous, transfer-resistant cosmetic lip compositions |
US7482419B2 (en) | 2004-04-12 | 2009-01-27 | Dow Corning Corporation | Silsesquioxane resin wax |
US20060115439A1 (en) | 2004-11-04 | 2006-06-01 | L'oreal | Compositions containing at least one silicone resin and glass beads |
US8025869B2 (en) | 2005-06-28 | 2011-09-27 | L'oréal | Cosmetic compositions having enhanced wear properties |
US20070093619A1 (en) | 2005-10-24 | 2007-04-26 | L'oreal | Compositions having enhanced cosmetic properties |
US20070248550A1 (en) | 2006-04-25 | 2007-10-25 | L'oreal | Cosmetic emulsions containing uncoated silicone elastomers and non silicone treated pigments |
US7601179B2 (en) | 2007-09-14 | 2009-10-13 | L'oreal S.A. | Methods of preserving artificial coloring on keratin materials |
FR2931673B1 (en) | 2008-06-02 | 2013-01-04 | Oreal | POLYESTER AND VOLATILE OIL COMPOSITIONS AND USES THEREOF. |
JP2012512180A (en) | 2008-12-16 | 2012-05-31 | ロレアル | Mascara composition with long lasting, water resistance and detergency |
FR2967910B1 (en) | 2010-11-26 | 2012-12-21 | Oreal | COSMETIC PRODUCT COMPRISING A SILICONE POLYAMIDE, A SILICONE RESIN AND AT LEAST ONE ETHYLENE COPOLYMER SEQUENCE |
FR2968984B1 (en) | 2010-12-21 | 2012-12-14 | Oreal | COSMETIC COMPOSITION COMPRISING SILICA AEROGEL PARTICLES |
US8586013B2 (en) | 2010-12-30 | 2013-11-19 | L'oreal | Comfortable, long-wearing, transfer-resistant colored cosmetic compositions having a non-tacky feel |
JP6321554B2 (en) | 2012-06-21 | 2018-05-09 | ロレアル | Cosmetic composition having pore concealment and long lasting effect |
US9586332B2 (en) | 2015-07-21 | 2017-03-07 | Chin-Fa Lin | Curtain cutting machine |
US11185490B2 (en) | 2016-03-31 | 2021-11-30 | L'oreal | Cosmetic compositions comprising silicone capable of forming a multilayer structure after application to a keratinous material |
US20180243202A1 (en) | 2017-02-28 | 2018-08-30 | L'oréal | Cosmetic compositions capable of forming a multilayer structure after application to a keratinous material |
US10369387B2 (en) | 2017-02-28 | 2019-08-06 | L'oreal | Cosmetic compositions capable of forming a multilayer structure after application to a keratinous material |
US11179313B2 (en) | 2016-03-31 | 2021-11-23 | L'oreal | Cosmetic compositions comprising silicone and hydrocarbon capable of forming a multilayer structure after application to a keratinous material |
US10894010B2 (en) | 2016-12-28 | 2021-01-19 | L'oreal | Cosmetic compositions which are homogenous in the bulk and capable of forming a multilayer structure after application to a keratinous material |
US20180214370A1 (en) * | 2017-01-31 | 2018-08-02 | L'oreal | Topcoat for long-wear lip compositions |
-
2020
- 2020-06-24 US US16/910,729 patent/US11160735B1/en active Active
-
2021
- 2021-10-25 US US17/509,850 patent/US20220040054A1/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004182667A (en) * | 2002-12-05 | 2004-07-02 | Mikimoto Pharmaceut Co Ltd | Lip cosmetic |
DE10316305A1 (en) * | 2003-04-08 | 2004-12-02 | Kryolan Gmbh Chemische Fabrik | Cosmetic skin marking compositions, e.g. for body painting or simulated tattoos, comprising trimethylsiloxy silicate, dimethicone, pigment and optionally polymethyl silsesquioxane and/or filler |
US7842285B2 (en) * | 2004-11-04 | 2010-11-30 | L'oreal | Cosmetic compositions and methods of use |
FR2918273A1 (en) * | 2007-07-03 | 2009-01-09 | Oreal | Cosmetic product, useful for make-up of skin, lips and/or integument, comprises a first composition comprising a silicone polyamide and a resin, and a second composition comprising phenylated silicone oil and at least a fatty paste |
US20110117043A1 (en) * | 2009-10-27 | 2011-05-19 | James Herman Dempsey | Methods of coating eyelashes and eyelids with a long-wearing mascara composition |
US20170281478A1 (en) * | 2016-03-31 | 2017-10-05 | L'oréal | Liquid lipstick compositions capable of forming a multilayer structure after application to lips |
JP2019065010A (en) * | 2017-10-04 | 2019-04-25 | 株式会社コーセー | Oily lip cosmetic |
US20190262257A1 (en) * | 2018-02-28 | 2019-08-29 | L'oreal | Matte lip compositions |
Non-Patent Citations (6)
Title |
---|
Dow "Dowsil 593 Fluid" Product Information Overview, accessed 2023; https://www.dow.com/en-us/pdp.dowsil-593-fluid.01225707z.html#overview (Year: 2023) * |
Gelest "Silicone Fluids," accessed 2023; https://www.gelest.com/wp-content/uploads/Goods-PDF-brochures-inert_silicones_2013.pdf (Year: 2023) * |
Google translation DE 10316305 A1, printed 2023 (Year: 2023) * |
Google translation FR 2918273 A1, printed 2023 (Year: 2023) * |
Google translation JP 2004-182667 A, printed 2023 (Year: 2023) * |
Google translation JP 2019-065010 A, printed 2023 (Year: 2023) * |
Also Published As
Publication number | Publication date |
---|---|
US11160735B1 (en) | 2021-11-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8945525B2 (en) | Comfortable, long-wearing, transfer-resistant colored cosmetic compositions having high gloss and a non-tacky feel | |
EP3576845B1 (en) | Topcoat for permanent lip make up | |
US10076487B2 (en) | Comfortable, long-wearing, transfer-resistant colored cosmetic compositions | |
US10688034B2 (en) | Long-wearing, transfer-resistant cosmetic composition having improved tackiness | |
US20110038820A1 (en) | Cosmetic makeup and/or care method using a siloxane resin and a phenyl silicone oil | |
JP2017518329A (en) | Solid lipstick composition having improved hardness | |
WO2009085888A1 (en) | Composition containing a polyorganosiloxane polymer and a polar modified wax | |
US20090092567A1 (en) | Oil-containing compositions exhibiting reduced feathering | |
JP5461429B2 (en) | Composition containing polar modified wax | |
JP2011507961A5 (en) | ||
US20180214369A1 (en) | Long-wear compositions containing silicone resin and silicone elastomer resin | |
US11364191B2 (en) | Topcoat for basecoat compositions | |
US11160735B1 (en) | Long wear lip cosmetic system and topcoat | |
WO2021262430A1 (en) | Long wear lip cosmetic system and topcoat | |
US11058626B2 (en) | Long-wear compositions containing silicone acrylate copolymer, silicone elastomer resin and surface-treated pigment | |
US20190262257A1 (en) | Matte lip compositions | |
US10786439B2 (en) | Satin lip compositions | |
US20230067902A1 (en) | Dilute long-wearing cosmetic composition comprising mixed sensory modifiers | |
US20230046620A1 (en) | Long-wearing cosmetic composition comprising expanded perlite | |
FR3113239A1 (en) | COSMETIC SYSTEM AND LONG-LASTING LIP TOPCOAT | |
US11058625B2 (en) | Long-wear compositions containing silicone acrylate copolymer and silicone elastomer resin | |
FR3127404A1 (en) | Diluted, long-wearing cosmetic composition comprising mixed sensory modifiers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STPP | Information on status: patent application and granting procedure in general |
Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
AS | Assignment |
Owner name: L'OREAL, FRANCE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MARTINEZ, SANTANA NICOLE;GOMEZ, NADIN AHMED;PATEL, PURVESH;SIGNING DATES FROM 20200622 TO 20200623;REEL/FRAME:065719/0668 |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: FINAL REJECTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: ADVISORY ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION |