US20210071008A1 - Coating composition for tube of heat exchanger and coating method for tube of heat exchanger using the same - Google Patents

Coating composition for tube of heat exchanger and coating method for tube of heat exchanger using the same Download PDF

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Publication number
US20210071008A1
US20210071008A1 US16/600,731 US201916600731A US2021071008A1 US 20210071008 A1 US20210071008 A1 US 20210071008A1 US 201916600731 A US201916600731 A US 201916600731A US 2021071008 A1 US2021071008 A1 US 2021071008A1
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United States
Prior art keywords
heat exchanger
base material
coating
exchanger tube
metallic base
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Application number
US16/600,731
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US11603471B2 (en
Inventor
Chang Yeol Yoo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hyundai Motor Co
Kia Corp
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Hyundai Motor Co
Kia Motors Corp
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Assigned to KIA MOTORS CORPORATION, HYUNDAI MOTOR COMPANY reassignment KIA MOTORS CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: YOO, CHANG YEOL
Publication of US20210071008A1 publication Critical patent/US20210071008A1/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00—Soldering, e.g. brazing, or unsoldering
    • B23K1/0008—Soldering, e.g. brazing, or unsoldering specially adapted for particular articles or work
    • B23K1/0012—Brazing heat exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00—Soldering, e.g. brazing, or unsoldering
    • B23K1/20—Preliminary treatment of work or areas to be soldered, e.g. in respect of a galvanic coating
    • B23K1/203—Fluxing, i.e. applying flux onto surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/226—Non-corrosive coatings; Primers applied before welding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3603—Halide salts
    • B23K35/3605—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3612—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with organic compounds as principal constituents
    • B23K35/3613—Polymers, e.g. resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/362—Selection of compositions of fluxes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
    • C23C10/30—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes using a layer of powder or paste on the surface
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/60—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
    • C23C26/02—Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04—Coatings characterised by the materials used
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00—Tubular elements; Assemblies of tubular elements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • F28F19/06—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of metal
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/089—Coatings, claddings or bonding layers made from metals or metal alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00—Articles made by soldering, welding or cutting
    • B23K2101/04—Tubular or hollow articles
    • B23K2101/14—Heat exchangers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0881—Titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/16—Halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2245/00—Coatings; Surface treatments

Definitions

  • the present disclosure relates to a coating composition for a heat exchanger tube which is capable of forming a coating layer excellent in corrosion resistance and a coating method of a tube for a heat exchanger using the same.
  • a condenser and an evaporator core of a heat exchanger of a vehicle are typically composed of a tube and a pin.
  • the heat exchanger tube is mainly made of aluminum, is a device for transferring heat from a high temperature fluid to a low temperature fluid through a heat transfer wall, and serves as a passage of a refrigerant or a heat medium.
  • the pin for the heat exchanger serves to maximize cooling or heating efficiency and is mainly made of aluminum.
  • the heat exchanger tube is generally manufactured by extruding aluminum wire into a tube shape.
  • a coating composition including a metal, a binder, and a flux (mixed salt) is coated on a surface of the heat exchanger tube and is brazed to form a coating layer, which increases corrosion resistance.
  • a coating layer which increases corrosion resistance.
  • the coating layer when corrosion occurs, only the coating layer may be corroded to inhibit the base aluminum tube from corroding.
  • Patent Document 1 discloses an apparatus for coating a paint mixed in a mechanical binder on a surface of a member for aluminum alloy heat exchanger assembled by a brazing processing using a top feed roll transfer method including at least three rolls.
  • the coating apparatus of Patent Document 1 may form the coating layer having a uniform thickness, there is a limit in improving the corrosion resistance of a member.
  • Patent Document 1 Japanese Patent Laid-Open No. 2005-118857 (Published Date: May 12, 2005)
  • the present disclosure provides a coating composition for a heat exchanger tube capable of forming a coating layer excellent in corrosion resistance and chipping resistance.
  • a coating composition for a heat exchanger tube includes vanadium (V), a flux, and a binder,
  • vanadium is included in an amount of 28 to 38 parts by weight with respect to 100 parts by weight of the composition.
  • a heat exchanger tube includes a metallic base material
  • an anti-corrosive reinforcement layer that is formed on the metallic base material and is derived from the coating composition for the heat exchanger tuber.
  • a coating method of a heat exchanger tube includes coating the coating composition for the heat exchanger tube on a surface of a metallic base material to form a coating layer;
  • the coating composition for the heat exchanger tube according to the present disclosure includes vanadium (V), a flux, and a binder.
  • Vanadium (V) serves to improve corrosion resistance by forming a coating layer containing vanadium dioxide (VO 2 ) on a surface of the heat exchanger tube.
  • the vanadium may be included in an amount of 28 to 38 parts by weight, or 30 to 40 parts by weight with respect to 100 parts by weight of the composition. When the content of the vanadium is within the above range, there is an effect of improving the corrosion resistance.
  • a flux serves to improve formability of the coating layer containing vanadium dioxide by removing an oxide layer on the surface of the heat exchanger tube.
  • the flux is not particularly limited as long as the flux is generally applicable to the coating composition for the heat exchanger tube, for example, includes a fluoride-based flux, a chloride-based flux, a borate-based flux, and the like.
  • the fluoride-based flux may include at least one selected from the group consisting of KF, AIF 3 , KAIF 4 , KAIF 5 , K 2 AIF 5 , K 3 AIF 6 , CsF, RbF, LiF, NaF, Ca 2 F, and KZnF 3 .
  • the flux may be included in the composition in an amount of 45 to 70 parts by weight, or 50 to 60 parts by weight with respect to 30 to 40 parts by weight of vanadium (V).
  • V vanadium
  • a binder serves to increase bonding strength of the components in the composition to improve the coating layer formability.
  • the binder may include at least one selected from the group consisting of a polyvinyl-based resin, an acrylic-based resin, and a urethane-based resin.
  • the binder may be included in the composition in an amount of 1 to 20 parts by weight, 5 to 15 parts by weight, or 5 to 10 parts by weight with respect to 30 to 40 parts by weight of vanadium.
  • the content of the binder is within the above range, there is an effect of maximizing the bonding strength of the composition.
  • a heat exchanger tube according to the present disclosure include a metallic base material; and an anti-corrosive reinforcement layer, which is formed on the metallic base material and is derived from the coating composition for the heat exchanger tube.
  • the metallic base material is a base material constituting the heat exchanger tube.
  • the metallic base material may be not particularly limited as long as it is commonly used in the heat exchanger tube, for example, may include at least one selected from the group consisting of aluminum, copper and stainless steel.
  • the metallic base material may be made of aluminum.
  • the metallic base material may be in the form of a tube.
  • the anti-corrosive reinforcement layer is formed on the metallic base material, and is corroded instead of the metallic base material when corrosion occurs, thereby effectively preventing or inhibiting the corrosion of the metallic base material.
  • the anti-corrosive reinforcement layer may include vanadium dioxide (VO 2 ).
  • VO 2 vanadium dioxide
  • the anti-corrosive reinforcement layer is corroded instead of the metallic base material when the corrosion occurs, thereby effectively preventing or inhibiting the corrosion of the metallic base material.
  • the anti-corrosive reinforcement layer may have an average thickness of 1 to 1,000 ⁇ m, 5 to 500 ⁇ m, or 10 to 100 ⁇ m.
  • the average thickness of the anti-corrosive reinforcement layer is within the above range, there is an effect that the corrosion resistance of the manufactured heat exchanger tube is improved.
  • the heat exchanger tube as described above is excellent in the corrosion resistance and chipping resistance because the anti-corrosive reinforcement layer is corroded instead of the metallic base material when the corrosion occurs.
  • the coating method of the heat exchanger tube according to the present disclosure includes coating the coating composition for the heat exchanger tube on the surface of the metallic base material to form the coating layer; joining the metallic base material, on which the coating layer is formed, by brazing; and heat-treating the brazed metallic base material to form the anti-corrosive reinforcement layer.
  • the coating composition for the heat exchanger tube is coated on the surface of the metallic base material to form the coating layer.
  • the coating may be a roll coating.
  • the roll coating may transfer the metallic base material at a rate of 1 to 10 m/min or 1 to 5 m/min and may provide the coating composition at a rate of 0.1 to 5 g/min or 0.1 to 1 g/min.
  • the coating layer having a uniform and appropriate thickness is formed on the surface of the metallic base material to improve the corrosion resistance and chipping resistance of the metallic base material.
  • the metallic base material on which the coating layer is formed is brazed.
  • vanadium in the coating composition for the heat exchanger tube may be diffused into the metallic base material by brazing.
  • the brazing may be performed for 1 to 15 minutes or 4 to 12 minutes at 350 to 650° C. or 400 to 600° C.
  • the brazing is carried out for 1 to 7 minutes or 3 to 7 minutes at 350 to 430° C. or 380 to 420° C., or is carried out for 8 to 15 minutes or 8 to 12 minutes at 500 to 650° C. or 550 to 620° C.
  • the temperature and time during the brazing are within the above range, there is an effect of improving a brazing property.
  • the brazed metallic base material is heat-treated to form the anti-corrosive reinforcement layer.
  • the heat-treating may be a high frequency heat treatment of a frequency 150 to 350 kHz.
  • the high frequency heat treatment may process a high frequency of 200 to 300 kHz for 3 to 15 minutes or 5 to 10 minutes.
  • vanadium dioxide (VO 2 ) is generated in the anti-corrosive reinforcement layer, thereby improving the corrosion resistance and chipping resistance of the metallic base material.
  • a coating composition was prepared by mixing 35 parts by weight of vanadium (V), 55 parts by weight of KAIF 4 , and 10 parts by weight of a binder (Manufacturer: Ternary Chemical, Product name: HF-66B, acrylic resin).
  • Coating compositions were prepared in the same manner as Example 1, except that the components were mixed in the amounts shown in Table 1 below.
  • Example 1 Example 2
  • Example 3 Example 4
  • An aluminum base material (Manufacturer: Ilsimalmax, Product name: A3003, Thickness: 200 ⁇ m) was roll coated with the coating compositions of Example and Comparative Examples.
  • the metallic base material was provided at a rate of 3 m/min and the coating composition was provided in an amount of 5 g/m2 to be coated on the metallic base material.
  • coated aluminum base material was brazed at 400° C. for 5 minutes to diffuse vanadium into the aluminum base material.
  • the brazed aluminum base material was treated with a high frequency of 250 KHz for 8 minutes to form the anti-corrosive reinforcement layer having an average thickness of 100 ⁇ m containing vanadium dioxide and thus, a specimen was manufactured.
  • salt water was treated on the specimen in an amount of 100 mL/m 2 , and a corrosion depth was measured after 1,000 hours, and results were shown in Table 2.
  • the salt water was used an aqueous solution containing 5% by weight of salt.
  • Example 1 including vanadium had a significantly lower corrosion depth in comparison with Comparative Examples 1 and 2, which contain the same amount of metal as Example 1.
  • Example 1 had a significantly shallower corrosion depth in comparison with Comparative Examples 3 to 5 containing less or more amounts of vanadium than the amount of vanadium of Example 1. Therefore, it was possible to confirm the remarkably excellent corrosion resistance of the specimen of Example 1 in comparison to the specimens of Comparative Examples 1 to 5.
  • the specimen of Example 1 has the damage depth, which is significantly shallow in comparison to the specimens of Comparative Examples 1 to 5 to be significantly excellent in the chipping resistance.
  • the coating composition for the heat exchanger tube according to the present disclosure is capable of forming the coating layer excellent in corrosion resistance and chipping resistance.

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Abstract

A coating composition for a heat exchanger tube including vanadium (V), a flux, and a binder, wherein the vanadium is included in an amount of 28 to 38 parts by weight with respect to 100 parts by weight of the composition, and a coating method of a heat exchanger tube using the same are provided.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • This application claims priority to and the benefit of Korean Patent Application No. 10-2019-0110981, filed on Sep. 6, 2019, the entire contents of which are incorporated herein by reference.
    • FIELD
  • The present disclosure relates to a coating composition for a heat exchanger tube which is capable of forming a coating layer excellent in corrosion resistance and a coating method of a tube for a heat exchanger using the same.
    • BACKGROUND
  • The statements in this section merely provide background information related to the present disclosure and may not constitute prior art.
  • A condenser and an evaporator core of a heat exchanger of a vehicle are typically composed of a tube and a pin. The heat exchanger tube is mainly made of aluminum, is a device for transferring heat from a high temperature fluid to a low temperature fluid through a heat transfer wall, and serves as a passage of a refrigerant or a heat medium. In addition, the pin for the heat exchanger serves to maximize cooling or heating efficiency and is mainly made of aluminum. Here, the heat exchanger tube is generally manufactured by extruding aluminum wire into a tube shape.
  • Furthermore, in the heat exchanger tube, a coating composition including a metal, a binder, and a flux (mixed salt) is coated on a surface of the heat exchanger tube and is brazed to form a coating layer, which increases corrosion resistance. In the heat exchanger tube including the coating layer, when corrosion occurs, only the coating layer may be corroded to inhibit the base aluminum tube from corroding.
  • In detail, Japanese Patent Laid-Open No. 2005-118857 (Patent Document 1) discloses an apparatus for coating a paint mixed in a mechanical binder on a surface of a member for aluminum alloy heat exchanger assembled by a brazing processing using a top feed roll transfer method including at least three rolls. However, although the coating apparatus of Patent Document 1 may form the coating layer having a uniform thickness, there is a limit in improving the corrosion resistance of a member.
  • Therefore, there is a need for research and development of a coating composition for the heat exchanger tube capable of forming the coating layer having excellent corrosion resistance and chipping resistance.
  • (Patent Document 1) Japanese Patent Laid-Open No. 2005-118857 (Published Date: May 12, 2005)
  • The above information disclosed in this Background section is only for enhancement of understanding of the background of the present disclosure, and therefore it may contain information that does not form the prior art that is already known to a person of ordinary skill in the art.
    • SUMMARY
  • In one aspect, the present disclosure provides a coating composition for a heat exchanger tube capable of forming a coating layer excellent in corrosion resistance and chipping resistance.
  • According to an aspect of the present disclosure, a coating composition for a heat exchanger tube includes vanadium (V), a flux, and a binder,
  • wherein the vanadium is included in an amount of 28 to 38 parts by weight with respect to 100 parts by weight of the composition.
  • According to an aspect of the present disclosure, a heat exchanger tube includes a metallic base material; and
  • an anti-corrosive reinforcement layer that is formed on the metallic base material and is derived from the coating composition for the heat exchanger tuber.
  • According to an aspect of the present disclosure, a coating method of a heat exchanger tube includes coating the coating composition for the heat exchanger tube on a surface of a metallic base material to form a coating layer;
  • joining the metallic base material, on which the coating layer is formed, by brazing; and
  • heat-treating the brazed metallic base material to form an anti-corrosive reinforcement layer.
  • Further areas of applicability will become apparent from the description provided herein. It should be understood that the description and specific examples are intended for purposes of illustration only and are not intended to limit the scope of the present disclosure.
    • DETAILED DESCRIPTION
  • The following description is merely exemplary in nature and is not intended to limit the present disclosure, application, or uses.
  • Hereinafter, the present disclosure will be described in detail.
  • In the present specification, when a member is located “on” another member, this includes not only when one member is in contact with another member but also when another member exists between the two members.
  • In the present specification, when a part is said to “include” a certain component, it means that it may further include other components, without excluding the other components unless specifically stated otherwise.
  • Coating Composition for Heat Exchanger Tube
  • The coating composition for the heat exchanger tube according to the present disclosure includes vanadium (V), a flux, and a binder.
  • Vanadium (V)
  • Vanadium (V) serves to improve corrosion resistance by forming a coating layer containing vanadium dioxide (VO2) on a surface of the heat exchanger tube.
  • The vanadium may be included in an amount of 28 to 38 parts by weight, or 30 to 40 parts by weight with respect to 100 parts by weight of the composition. When the content of the vanadium is within the above range, there is an effect of improving the corrosion resistance.
  • Flux
  • A flux serves to improve formability of the coating layer containing vanadium dioxide by removing an oxide layer on the surface of the heat exchanger tube.
  • The flux is not particularly limited as long as the flux is generally applicable to the coating composition for the heat exchanger tube, for example, includes a fluoride-based flux, a chloride-based flux, a borate-based flux, and the like.
  • Here, the fluoride-based flux may include at least one selected from the group consisting of KF, AIF3, KAIF4, KAIF5, K2AIF5, K3AIF6, CsF, RbF, LiF, NaF, Ca2F, and KZnF3.
  • KAIF4
  • In addition, the flux may be included in the composition in an amount of 45 to 70 parts by weight, or 50 to 60 parts by weight with respect to 30 to 40 parts by weight of vanadium (V). When the flux content is within the above range, there is an effect of maximizing the oxide layer removal.
  • Binder
  • A binder serves to increase bonding strength of the components in the composition to improve the coating layer formability.
  • The binder may include at least one selected from the group consisting of a polyvinyl-based resin, an acrylic-based resin, and a urethane-based resin.
  • In addition, the binder may be included in the composition in an amount of 1 to 20 parts by weight, 5 to 15 parts by weight, or 5 to 10 parts by weight with respect to 30 to 40 parts by weight of vanadium. When the content of the binder is within the above range, there is an effect of maximizing the bonding strength of the composition.
  • Heat Exchanger Tube
  • A heat exchanger tube according to the present disclosure include a metallic base material; and an anti-corrosive reinforcement layer, which is formed on the metallic base material and is derived from the coating composition for the heat exchanger tube.
  • Metallic Base Material
  • The metallic base material is a base material constituting the heat exchanger tube. In addition, the metallic base material may be not particularly limited as long as it is commonly used in the heat exchanger tube, for example, may include at least one selected from the group consisting of aluminum, copper and stainless steel. In detail, the metallic base material may be made of aluminum.
  • The metallic base material may be in the form of a tube.
  • Anti-Corrosive Reinforcement Layer
  • The anti-corrosive reinforcement layer is formed on the metallic base material, and is corroded instead of the metallic base material when corrosion occurs, thereby effectively preventing or inhibiting the corrosion of the metallic base material.
  • Here, the anti-corrosive reinforcement layer may include vanadium dioxide (VO2). When anti-corrosive reinforcement layer includes vanadium dioxide, the anti-corrosive reinforcement layer is corroded instead of the metallic base material when the corrosion occurs, thereby effectively preventing or inhibiting the corrosion of the metallic base material.
  • In addition, the anti-corrosive reinforcement layer may have an average thickness of 1 to 1,000 μm, 5 to 500 μm, or 10 to 100 μm. When the average thickness of the anti-corrosive reinforcement layer is within the above range, there is an effect that the corrosion resistance of the manufactured heat exchanger tube is improved.
  • The heat exchanger tube as described above is excellent in the corrosion resistance and chipping resistance because the anti-corrosive reinforcement layer is corroded instead of the metallic base material when the corrosion occurs.
  • Coating Method of Heat Exchanger Tube
  • The coating method of the heat exchanger tube according to the present disclosure includes coating the coating composition for the heat exchanger tube on the surface of the metallic base material to form the coating layer; joining the metallic base material, on which the coating layer is formed, by brazing; and heat-treating the brazed metallic base material to form the anti-corrosive reinforcement layer.
  • Coating
  • The coating composition for the heat exchanger tube is coated on the surface of the metallic base material to form the coating layer.
  • The coating may be a roll coating. The roll coating may transfer the metallic base material at a rate of 1 to 10 m/min or 1 to 5 m/min and may provide the coating composition at a rate of 0.1 to 5 g/min or 0.1 to 1 g/min. Here, when the transfer rate of the metallic base material and the feed rate of the coating composition during the roll coating is within the above range, the coating layer having a uniform and appropriate thickness is formed on the surface of the metallic base material to improve the corrosion resistance and chipping resistance of the metallic base material.
  • Joining
  • The metallic base material on which the coating layer is formed is brazed. Here, vanadium in the coating composition for the heat exchanger tube may be diffused into the metallic base material by brazing.
  • The brazing may be performed for 1 to 15 minutes or 4 to 12 minutes at 350 to 650° C. or 400 to 600° C. In detail, the brazing is carried out for 1 to 7 minutes or 3 to 7 minutes at 350 to 430° C. or 380 to 420° C., or is carried out for 8 to 15 minutes or 8 to 12 minutes at 500 to 650° C. or 550 to 620° C. When the temperature and time during the brazing are within the above range, there is an effect of improving a brazing property.
  • Heat-Treating
  • The brazed metallic base material is heat-treated to form the anti-corrosive reinforcement layer.
  • The heat-treating may be a high frequency heat treatment of a frequency 150 to 350 kHz. In detail, the high frequency heat treatment may process a high frequency of 200 to 300 kHz for 3 to 15 minutes or 5 to 10 minutes. When the frequency and the treatment time of the high frequency are within the above range, vanadium dioxide (VO2) is generated in the anti-corrosive reinforcement layer, thereby improving the corrosion resistance and chipping resistance of the metallic base material.
  • Hereinafter, the present disclosure will be described in more detail with reference to Examples. However, Examples are only for the understanding of the present disclosure, and the scope of the present disclosure in any sense is not limited to Examples.
    • EXAMPLES Example 1. Manufacturing Coating Composition for Heat Exchanger Tube
  • A coating composition was prepared by mixing 35 parts by weight of vanadium (V), 55 parts by weight of KAIF4, and 10 parts by weight of a binder (Manufacturer: Ternary Chemical, Product name: HF-66B, acrylic resin).
    • Comparative Examples 1 to 5
  • Coating compositions were prepared in the same manner as Example 1, except that the components were mixed in the amounts shown in Table 1 below.
  • TABLE 1
    Component Comparative Comparative Comparative Comparative Comparative
    (parts by weight) Example 1 Example 1 Example 2 Example 3 Example 4 Example 5
    Vanadium (V) 35 — — 15 25 45
    Zirconium (Zr) — 35 — — — —
    Titanium (Ti) — — 35 — — —
    KAIF4 55 55 55 55 55 55
    Binder 10 10 10 10 10 10
    Total 100  100  100 80 90 110 
    • Test Example 1: Evaluation of Corrosion Resistance
  • An aluminum base material (Manufacturer: Ilsimalmax, Product name: A3003, Thickness: 200 μm) was roll coated with the coating compositions of Example and Comparative Examples. Here, the metallic base material was provided at a rate of 3 m/min and the coating composition was provided in an amount of 5 g/m2 to be coated on the metallic base material.
  • Hereafter, the coated aluminum base material was brazed at 400° C. for 5 minutes to diffuse vanadium into the aluminum base material.
  • Then, the brazed aluminum base material was treated with a high frequency of 250 KHz for 8 minutes to form the anti-corrosive reinforcement layer having an average thickness of 100 μm containing vanadium dioxide and thus, a specimen was manufactured.
  • Subsequently, salt water was treated on the specimen in an amount of 100 mL/m2, and a corrosion depth was measured after 1,000 hours, and results were shown in Table 2. Here, the salt water was used an aqueous solution containing 5% by weight of salt.
  • TABLE 2
    Categories Depth Of Corrosion (μm)
    Example 1 50
    Comparative Example 1 100
    Comparative Example 2 200
    Comparative Example 3 200
    Comparative Example 4 100
    Comparative Example 5 100
  • As shown in Table 2, Example 1 including vanadium had a significantly lower corrosion depth in comparison with Comparative Examples 1 and 2, which contain the same amount of metal as Example 1. In addition, Example 1 had a significantly shallower corrosion depth in comparison with Comparative Examples 3 to 5 containing less or more amounts of vanadium than the amount of vanadium of Example 1. Therefore, it was possible to confirm the remarkably excellent corrosion resistance of the specimen of Example 1 in comparison to the specimens of Comparative Examples 1 to 5.
    • Test Example 2: Evaluation of Chipping Resistance
  • Pebbles of 3 mm in diameter and 100 g in weight were sprayed onto the specimens prepared in the same manner as in Test Example 1 at a pressure of 5 kgf/cm2 for 10 seconds at 90° angle, and then a damage depth of each specimen surface was measured. Measurement results were shown in Table 3.
  • TABLE 3
    Damage Depth (μm)
    Example 1 50
    Comparative Example 1 100
    Comparative Example 2 200
    Comparative Example 3 200
    Comparative Example 4 100
    Comparative Example 5 100
  • As shown in Table 3, the specimen of Example 1 has the damage depth, which is significantly shallow in comparison to the specimens of Comparative Examples 1 to 5 to be significantly excellent in the chipping resistance.
  • The coating composition for the heat exchanger tube according to the present disclosure is capable of forming the coating layer excellent in corrosion resistance and chipping resistance.
  • While this present disclosure has been described in connection with what is presently considered to be practical exemplary forms, it is to be understood that the present disclosure is not limited to the disclosed forms, but, on the contrary, it is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the present disclosure.

Claims (14)

What is claimed is:
1. A coating composition for a heat exchanger tube comprising vanadium (V), a flux, and a binder,
wherein the vanadium is included in an amount of 28 to 38 parts by weight with respect to 100 parts by weight of the coating composition.
2. The coating composition for the heat exchanger tube of claim 1, wherein the flux includes a fluoride-based flux including at least one selected from the group consisting of KF, AIF3, KAIF4, KAIF5, K2AIF5, K3AIF6, CsF, RbF, LiF, NaF, Ca2F, and KZnF3.
3. The coating composition for the heat exchanger tube of claim 1, wherein the binder includes at least one selected from the group consisting of a polyvinyl-based resin, an acrylic-based resin, and a urethane-based resin.
4. The coating composition for the heat exchanger tube of claim 1, wherein the composition includes 30 to 40 parts by weight of vanadium (V), 45 to 70 parts by weight of the flux, and 1 to 20 parts by weight of the binder.
5. A heat exchanger tube comprising:
a metallic base material; and
an anti-corrosive reinforcement layer famed on the metallic base material derived from a coating composition comprising vanadium (V), a flux, and a binder.
6. The heat exchanger tube of claim 5, wherein the metallic base material includes at least one selected from the group consisting of aluminum, copper and stainless steel.
7. The heat exchanger tube of claim 5, wherein the anti-corrosive reinforcement layer includes vanadium dioxide (VO2).
8. The heat exchanger tube of claim 5, wherein the anti-corrosive reinforcement layer has an average thickness of 1 to 1,000 μm.
9. A coating method comprising:
coating a surface of a metallic base material with a coating composition comprising vanadium (V), a flux, and a binder to form a coating layer;
joining the metallic base material to the coating layer by brazing to form a brazed metallic base material; and
heat-treating the brazed metallic base material to form an anti-corrosive reinforcement layer.
10. The method of claim 9, wherein coating the surface includes roll coating.
11. The method of claim 10, wherein the roll coating transfers the metallic base material at a rate of 1 to 10 m/min and provides the coating composition at a rate of 0.1 to 5 g/min.
12. The method of claim 9, wherein joining is performed for 1 to 15 minutes at 350 to 650° C. by the brazing.
13. The method of claim 9, wherein heat-treating includes a high frequency heat treatment of a frequency 150 to 350 kHz.
14. The method of claim 13, wherein the high frequency heat treatment processes a high frequency of 200 to 300 kHz for 3 to 15 minutes.
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