US20200056837A1 - Lng production system equipped with recondenser - Google Patents

Lng production system equipped with recondenser Download PDF

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Publication number
US20200056837A1
US20200056837A1 US16/485,883 US201816485883A US2020056837A1 US 20200056837 A1 US20200056837 A1 US 20200056837A1 US 201816485883 A US201816485883 A US 201816485883A US 2020056837 A1 US2020056837 A1 US 2020056837A1
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United States
Prior art keywords
lng
recondenser
refrigerant
bog
gas
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Abandoned
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US16/485,883
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English (en)
Inventor
Kenji Hirose
Loic Joly
Daisuke Nagata
Shinji Tomita
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LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Application filed by LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority claimed from PCT/EP2018/053562 external-priority patent/WO2018096187A2/en
Publication of US20200056837A1 publication Critical patent/US20200056837A1/en
Abandoned legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F25J1/0025—Boil-off gases "BOG" from storages
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    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
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    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/34—Details about subcooling of liquids

Definitions

  • the present invention relates to an LNG production system equipped with a recondenser (Recondenser) that recondenses (reliquefies) boil off gas (BOG, Boil off Gas).
  • Recondenser recondenses (reliquefies) boil off gas (BOG, Boil off Gas).
  • FIG. 6 illustrates a general LNG production system.
  • Natural gas Natural Gas
  • NG Natural Gas
  • CO 2 is removed from the natural gas by using a predetermined solvent.
  • the NG after removal from which CO 2 is removed is fed to a dry process 63 .
  • predetermined drying treatment is applied to the NG after removal.
  • the dried NG is fed to a liquefaction process 64 .
  • the dried NG is liquefied by using a liquid refrigerant that is fed from a refrigeration system 65 .
  • the liquid natural gas (LNG) obtained by liquefaction is fed to an LNG storage tank 66 .
  • LNG is fed from the LNG storage tank 66 at a predetermined timing (for example, at the timing at which the LNG is transferred to a transport ship tank, or the like).
  • LNG in the LNG storage tank 66 sometimes evaporates by natural heat input and generates BOG.
  • BOG is sometimes generated.
  • piping is cooled when LNG is transferred to the transport ship tank, so that BOG is sometimes generated.
  • BOG is conventionally returned to the dry process 63 by a compressor 67 , and is supplied to the liquefaction process 64 with the dried NG. Thereby, it is possible to reliquefy BOG.
  • BOG is sometimes used as the heat source for regeneration of a drying material or the like in the dry process 63 .
  • a total amount of NG that is fed to the liquefaction process 64 from the dry process 63 includes the recycled BOG.
  • use as the fuel gas means that the total amount of LNG which is produced cannot be transferred to the transport ship tank.
  • BOG when BOG is returned to the dry process 63 as described above, BOG can be reliquefied only at the lime of LNG production, so that when BOG has to be discharged from the LNG storage tank at the time of producing no LNG, BOG has to be discharged into the air. That is, the timing for reliquefaction is limited, and there is no flexibility in reliquefaction process.
  • Patent Literature 1 U. S. Patent No. 2011/0094261
  • An object of the present invention is to provide an LNG production system including a recondenser that can recondense BOG (boil off gas) without using a BOG compressor and without depending on an LNG liquefaction process.
  • BOG blow off gas
  • a first LNG production system of the present invention includes
  • a liquefier that cools and liquefies natural gas by a refrigerant that is fed from a refrigerator
  • a recondenser that recondenses (reliquefies) boil off gas that is generated by heat being given to the liquid natural gas, by the refrigerant fed from the refrigerator, and
  • a second LNG production system of the present invention includes
  • a liquefier that cools and liquefies natural gas by a refrigerant that is fed from a first refrigerator
  • a recondenser that recondenses boil off gas (BOG) that is generated by heat being given to the liquid natural gas, by a refrigerant fed from the second refrigerator, and
  • BOG boil off gas
  • the refrigerant that is fed from the first refrigerator, and the refrigerant that is fed from the second refrigerator may be the same refrigerants, or may be different refrigerants.
  • the refrigerant from the first refrigerator a mixture such as hydrocarbon is cited, and as the refrigerant from the second refrigerator, nitrogen or the like is cited.
  • a third LNG production system of the present invention includes
  • a liquefier that cools and liquefies natural gas by a refrigerant that is fed from a refrigerator
  • a recondenser that switches to perform, alternately, a first recondensation processing of liquefying boil off gas that is generated by heat being given to the liquid natural gas, by the refrigerant fed from the refrigerator, and a second recondensation processing of liquefying boil off gas by the refrigerant fed from the refrigerator and a refrigerant fed from a refrigerant buffer to process more boil off gas than the boil off gas at a time of the first recondensation processing, and
  • the refrigerant that is fed from the refrigerator, and the refrigerant that is fed from the refrigerant buffer may be the same refrigerants, or may be different refrigerants.
  • the refrigerant from the refrigerator a mixture such as hydrocarbon is cited, and as the refrigerant from the refrigerant buffer, nitrogen or the like is cited.
  • the refrigerant may be fed to the recondenser from the refrigerator, and in the second recondensation processing, the refrigerant from the refrigerant buffer may be fed to the recondenser in addition to that the refrigerant is fed to the recondenser from the refrigerator.
  • the operation of the refrigerator may be stopped, or the refrigerator may be continuously operated without stopping.
  • the recondenser may have a switch control section that switches the first recondensation processing and the second recondensation processing to each other.
  • the switch control section may switch from the first recondensation processing to the second recondensation processing, in the case of transferring BOG to the LNG carrier.
  • the switch control section may switch from the first recondensation processing to the second recondensation processing when a pressure value measured by a pressure gauge disposed in the LNG tank or the feed line that feeds the BOG to the recondenser becomes a predetermined value or more.
  • the first recondensation processing processing of liquefying BOG with the refrigerant from the refrigerator
  • the second recondensation processing processing of liquefaction also by the refrigerant fed from the refrigerant buffer while keeping liquefaction by the refrigerant fed from the refrigerator
  • each of the LNG production systems may include a removing device that removes predetermined impurities from natural gas, and a dryer that dries the natural gas that is treated by the removing device.
  • the transfer line may be provided with piping and a sluice valve.
  • the return line may be provided with piping, a pump for feeding LNG and an automatic on-off valve.
  • a feed line that feeds the BOG to the recondenser from the LNG tank may be included.
  • the feed line may be provided with any one or more of piping, an automatic on-off valve, a flow rate control valve and a pressure regulating valve.
  • a pressure gauge that measures the pressure of the LNG tank may be provided. When a pressure value of the pressure gauge reaches a predetermined value or more, valves of the feed line and the return line may open, and BOG may be fed to the recondenser through the feed line.
  • the recondenser may be controlled so as to increase a cooling capability of the recondenser when the pressure value of the pressure gauge installed in the feed line reaches the predetermined value or more. For example, control may be performed so as to increase the feeding amount of the refrigerant that is fed from the refrigerator (the first or the second refrigerator), for example.
  • the LNG carrier may be, for example, a loading station container, a loading pier, a loading station truck, and the like.
  • a recovery line for returning BOG that is present in the LNG carrier to the LNG tank may be provided.
  • the refrigerant stored in the refrigerant buffer may be supplied from the refrigerator or an external refrigerator.
  • the recondenser may have a piping through which the refrigerant fed from the refrigerator passes, and a piping through which the refrigerant fed from the refrigerant buffer passes as separate components, and the returning refrigerants may be returned together to the refrigerator.
  • the recondenser may have a first heat exchanger to which the refrigerant fed from the refrigerator is introduced, and a second heat exchanger to which the refrigerant fed from the refrigerant buffer is introduced.
  • the recondenser preferably has the following configuration.
  • the recondenser is designed to recondense (liquefy) the boil off gas by a refrigerant under a pressure lower than an operating pressure of the LNG tank.
  • BOG can be recondensed under the pressure lower than the operating pressure of the LNG tank without using the conventional BOG compressor.
  • the recondenser may be internally provided with a heat exchanger into which the refrigerant is introduced, and the BOG may be introduced into the heat exchanger, and is cooled by the refrigerant. Thereby, BOG can be effectively liquefied in a mode of the heat exchanger.
  • a volume (an external capacity) of the heat exchanger may be smaller than an internal volume (an internal space capacity) of the recondenser, and the heat exchanger may be disposed in the internal space of the recondenser.
  • BOG can be effectively liquefied in the mode of the heat exchanger.
  • the liquefied LNG accumulates on the bottom of the recondenser.
  • the accumulating LNG can be fed to the LNG tank by a liquid feed pump.
  • the pressure in the recondenser or in the heat exchanger may be regulated as follows.
  • a fourth LNG production system of the present invention includes
  • a liquefier that cools and liquefies natural gas by a refrigerant that is fed from a refrigerator
  • a sub-cooler that is provided in the LNG lead-out line and cools the liquid natural gas with a refrigerant (for example, liquid nitrogen or the like),
  • the recondenser may recondense (liquefy) boil off gas with LNG that is cooled by the sub-cooler under a pressure lower than an operating pressure of the LNG tank.
  • the liquid natural gas is firstly cooled by using the refrigerant such as LN 2 , and boil off gas is liquefied with the cooled liquid natural gas.
  • the refrigerant such as LN 2
  • boil off gas is liquefied with the cooled liquid natural gas.
  • the sub-cooler may be controlled so that liquid natural gas has a higher temperature than a solidifying point of the liquid natural gas by the pressure regulating valve or the flow rate regulating valve that is installed in the refrigerant line in which the refrigerant flows.
  • the fourth invention two or more of the sub-coolers may be adopted.
  • the first recondensation processing of liquefying BOG by the refrigerant fed from the first sub-cooler, and the second recondensation processing of liquefying BOG by the refrigerant fed from the first sub-cooler and the refrigerant fed from the second sub-cooler in order to process more boil off gas than the boil off gas at a time of the first recondensation processing may be performed by switching the first recondensation processing and the second recondensation processing to each other.
  • the operation of the refrigerator may be stopped, or the refrigerator may be continuously operated without stopping.
  • the recondenser may have a switch control section that switches the first recondensation processing and the second recondensation processing to each other.
  • the switch control section may switch from the first recondensation processing to the second recondensation processing in the case of transferring boil off gas to the LNG carrier.
  • the switch control section may switch from the first recondensation processing to the second recondensation processing when a pressure value measured by a pressure gauge disposed in the LNG tank or the feed line that feeds the BOG to the recondenser becomes a predetermined value or more.
  • the refrigerant in the second sub-cooler may be supplied from the refrigerant buffer in which the refrigerant is stored in advance.
  • the pump for feeding liquid natural gas (LNG) to the transfer line from the LNG tank may be an in-tank type pump that is installed inside the LNG tank, or may be a pump that is disposed on the transfer line.
  • LNG liquid natural gas
  • FIG. 1 is a diagram illustrating a configuration example of an LNG production system of embodiment 1.
  • FIG. 2 is a diagram illustrating a configuration example of an LNG production system of embodiment 2.
  • FIG. 3 is a diagram illustrating a configuration example of an LNG production system of embodiment 3.
  • FIG. 4A is a diagram illustrating a configuration example of a recondenser.
  • FIG. 4B is a diagram illustrating a configuration example of the recondenser.
  • FIG. 4C is a diagram illustrating a configuration example of the recondenser.
  • FIG. 5A is a diagram illustrating a configuration example of an LNG production system in embodiment 4.
  • FIG. 5B is a diagram illustrating a configuration example of the recondenser.
  • FIG. 5C is a diagram illustrating a configuration example of the recondenser.
  • FIG. 6 is a diagram illustrating a configuration example of a conventional LNG production system.
  • the LNG production system 1 has a first line L 1 for transferring natural gas to a process in a subsequent stage, a compressor 11 and a second line L 2 (a pipe, for example).
  • a removing unit 12 is disposed, and a predetermined substance (CO2, for example) is removed from NG here.
  • CO2 a predetermined substance
  • the NG after removal is fed to a dryer 13 through a third line L 3 , and is subjected to drying treatment.
  • the dried NG is fed to a liquefier 14 through a fourth line L 4 and is liquefied.
  • a refrigerant (a liquid refrigerant) is fed to the liquefier 14 from a refrigerator 15 to cool NG, and LNG is obtained. Further, the refrigerant which is subjected to heat exchange returns to the refrigerator 15 in an evaporated state. LNG is fed to the LNG tank 16 through a fifth line L 5 and stored.
  • the first line L 1 to the fifth line L 5 are configured by pipes and on-off valves, for example.
  • a predetermined control device controls operation of the respective devices, opening and closing of the valves, a production amount of LNG, and the like of the LNG production system 1 .
  • an in-tank type first pump P 1 is disposed, and LNG in the tank is fed into an LNG carrier 18 through a transfer line L 6 by the first pump P 1 .
  • the LNG carrier 18 for example, a loading station container, a loading pier, a loading station track, and the like are cited.
  • BOG that is present in the LNG carrier 18 is fed to the LNG tank 16 through a recovery line A 2 .
  • a second feed line for feeding BOG present in the LNG carrier 18 to a recondenser 17 may be provided.
  • BOG is generated by heat input. Further, when LNG is fed from the liquefier 14 , BOG is also generated. Further, when LNG is fed to the LNG carrier 18 , BOG is also generated. In this way, BOG in the LNG tank 16 is fed to the recondenser 17 through a first feed line A 1 . Further, BOG in the transfer line L 6 is fed to the recondenser 17 through a third feed line A 3 .
  • a refrigerant (liquid refrigerant) is introduced into the recondenser 17 through a refrigerant line B 1 from the refrigerator 15 .
  • BOG fed by each of the feed lines is recondensed (liquefied).
  • a configuration of the recondenser 17 is described later.
  • the LNG that is obtained by being recondensed (liquefied) is returned to the LNG tank 16 through a return line A 4 .
  • a second pump P 2 is disposed, and LNG is fed to the LNG tank 16 by operating the second pump P 2 .
  • a series of processes is not required, which feeds BOG to the dryer and feeds BOG to the liquefier with NG to liquefy BOG as in the conventional art. Consequently, it is not necessary to operate the entire LNG production system, and only the refrigerator 15 can be operated.
  • the recondenser 17 can recondense BOG to LNG, so that all of the liquefaction capability of the liquefier 14 can be used in liquefaction of NG that is fed from the dryer.
  • FIGS. 4A and 4B illustrate an embodiment of the recondenser 17 .
  • the recondenser 17 has an outer wall 171 , and a heat exchanger 172 covered with the outer wall 171 .
  • a refrigerant (a liquid refrigerant) is introduced into the heat exchanger 172 from the refrigerator 15 through a refrigerant line B 1 , and BOG is cooled by cold energy of the refrigerant.
  • the refrigerant evaporates and returns to the refrigerator 15 through a refrigerant return line B 2 .
  • LNG is fed to the LNG tank 16 from the recondenser 17 by the second pump P 2 .
  • the recondenser 17 is designed to recondense (liquefy) BOG with the refrigerant under a pressure lower than an operating pressure of the LNG tank 16 .
  • the first feed line A 1 may be provided with a safety valve for a time when the pressure in the LNG tank 16 becomes abnormally high. Further, in the first feed line A 1 , an automatic on-off valve 42 for performing feeding control of BOG to the recondenser 17 is provided. Further, in the first feed line A 1 , a pressure gauge, and a pressure regulating valve 41 controlled in accordance with a value of the pressure gauge are provided.
  • the operating pressure in the LNG tank 16 is an average of 1.2 barA (120 KPaA) in absolute pressure, and is controlled within ⁇ 15% as upper and lower limit values.
  • a tank internal pressure becomes high.
  • the tank internal pressure is measured with a pressure gauge, and based on a measurement result (a conversion result), a valve control section (not illustrated) controls opening and closing of the automatic on-off valve 42 .
  • a valve control section controls opening and closing of the automatic on-off valve 42 .
  • the pressure regulating valve 41 in-pipe pressure of the first feed line A 1 is measured, and a valve opening degree is controlled based on the measurement result.
  • the refrigerant which is supplied from the refrigerator 15 may be any medium having a lower temperature than a boiling point of LNG, and LN 2 may be used, for example.
  • Internal pressure of the heat exchanger 172 is controlled to be a pressure lower than the operating pressure (average of 1.2 barA (120 KPaA) in absolute pressure) of the LNG tank 16 , in a BOG recondensation processing.
  • the internal pressure of the heat exchanger 172 is measured with a pressure gauge, and is regulated to be lower than the operating pressure of the LNG tank 16 .
  • the refrigerant contacts BOG in the heat exchanger 172 , whereby a volume of BOG decreases by liquefaction and the pressure in the heat exchanger 172 is reduced.
  • the low pressure state is kept by the refrigerant being continuously supplied.
  • the internal pressure of the heat exchanger 172 is regulated by controlling a flow rate of the refrigerant.
  • a flow rate regulating valve (not illustrated) is provided in the refrigerant feed line B 1 , and the flow rate of the refrigerant may be controlled with the flow rate regulating valve in accordance with a measurement result of the pressure gauge that measures the internal pressure of the above described heat exchanger 172 .
  • the recondenser 17 is not limited to a mode of the heat exchanger 172 , but may be a mode in which BOG and the refrigerant are brought into direct contact with each other.
  • a method for contacting both BOG and the refrigerant to each other means of spraying the refrigerant by a shower, means of contacting both of them by using a filler and the like are cited.
  • a lower portion of the heat exchanger 172 and the return line A 4 are connected.
  • An automatic on-off valve (not illustrated) provided in the return line A 4 is controlled to open and close, and the second pump P 2 is controlled, whereby LNG can be fed back to the LNG tank 16 from the recondenser 17 .
  • a processing procedure of recondensation processing of boil off gas (BOG) will be described hereunder.
  • a temperature of the refrigerant is preferably set at a temperature higher than an LNG solidifying point, and lower than a temperature of LNG in the LNG tank 16 , for example.
  • the temperature of LNG which is cooled may be set based on an amount of BOG and an amount of LNG which is cooled.
  • first threshold value is a pressure that is 1.26 times as high as 1.2 barA (120 KPaA), for example.
  • second threshold value is a pressure that is 1.3 times as high as 1.2 barA (120 KPaA), for example.
  • a pressure regulating valve (not illustrated) or a flow rate regulating valve (not illustrated) may be installed in the refrigerant line B 1 , and a refrigerant feed amount (VN) and a BOG feed amount (VB) may be controlled to VN>VB.
  • a recondenser in FIG. 4B will be described.
  • a volume (an external capacity) of the heat exchanger 172 is smaller than an internal volume (an internal space capacity) of the recondenser 17 , and the heat exchanger 172 is disposed in an internal space 173 of the recondenser.
  • BOG can be effectively liquefied.
  • the liquefied LNG accumulates on a bottom of the internal space 173 of the recondenser 17 .
  • the accumulating LNG can be fed to the LNG tank 16 by the second pump P 2 .
  • An upper portion (preferably an upper side of the heat exchanger 172 ) of the internal space 173 of the recondenser 17 and the first feed line A 1 are directly connected. Further, a lower portion of the internal space 173 of the recondenser 17 and the return line A 4 are directly connected.
  • An internal pressure of the recondenser 17 is controlled to be a pressure lower than the operating pressure (an average of 1.2 barA (120 KPaA) in absolute pressure) of the LNG tank 16 in the BOG recondensation processing.
  • the internal pressure of the recondenser 17 is measured by a pressure gauge, and is regulated to be lower than the operating pressure of the LNG tank 16 .
  • the refrigerant is fed to the heat exchanger 172 , and thereby the inside of the recondenser 17 is cooled.
  • the volume of BOG decreases by liquefaction and the pressure inside the recondenser 17 is reduced.
  • the refrigerant is continuously supplied to the heat exchanger 172 and thereby continues to cool the inside of the recondenser 17 to liquefy BOG to keep the inside of the recondenser 17 in a low-pressure state.
  • the internal pressure of the recondenser 17 is regulated by controlling the flow rate of the refrigerant.
  • a flow rate regulating valve is provided in the refrigerant line B 1 , and the flow rate of the refrigerant may be controlled by the flow rate regulating valve in accordance with the measurement result of the pressure gauge that measures the internal pressure of the above described recondenser 17 , the flow rate of the refrigerant may be controlled by controlling the opening degree of the automatic on-off valve provided in the refrigerant line B 1 , or both of them may be controlled.
  • a temperature of the refrigerant is preferably set at a temperature higher than the LNG solidifying point, and lower than a temperature of LNG in the LNG tank 16 , for example.
  • the temperature of LNG which is cooled may be set based on an amount of BOG and an amount of LNG which is cooled.
  • first threshold value is a pressure that is 1.26 times as high as 1.2 barA (120 KPaA), for example.
  • second threshold value is a pressure that is 1.3 times as high as 1.2 barA (120 KPaA), for example.
  • a pressure regulating valve (not illustrated) or a flow rate regulating valve (not illustrated) may be installed in the refrigerant line B 1 , and a refrigerant feed amount (VN) and a BOG feed amount (VB) may be controlled to VN>VB.
  • the LNG production system 2 of embodiment 2 has the first refrigerator 15 and a second refrigerator 20 .
  • the first refrigerator feeds a refrigerant to a cooling device 14 .
  • the second refrigerator 20 feeds the refrigerant (liquid refrigerant) to the recondenser 17 through a refrigerant line C 1 (corresponding to B 1 in FIG. 1 ), and returns the refrigerant used as a cold source in the recondenser 17 through a return line C 2 (corresponding to B 2 in FIG. 1 ).
  • the second refrigerator 20 is provided separately from the first refrigerator 15 , it is not necessary to supply the refrigerant to the operating cooling device 14 from the large refrigerator and supply the refrigerant to the recondenser 17 , it is not necessary to install the refrigerator that is larger than necessary, and only a medium or small refrigerator can be installed, so that the installation space can be small, and the initial cost and the running cost can be reduced.
  • the recondenser 17 of the LNG production system 3 of embodiment 3 can perform a first recondensation processing of liquefying BOG by the refrigerant fed from the refrigerator 15 , and a second recondensation processing that liquefies BOG by the refrigerant fed from the refrigerator 15 and a refrigerant fed from a refrigerant buffer 30 in order to process more BOG than BOG at the time of the first recondensation processing by switching the first and the second recondensation processings to each other.
  • the refrigerant buffer 30 the refrigerant is supplied from the refrigerator 15 through a first supply line E 1 and/or the refrigerant is supplied from an external refrigerant source through a second supply line E 2 and is stored in advance.
  • the refrigerant is introduced into the recondenser 17 through a buffer line D 1 from the refrigerant buffer 30 .
  • the recondenser 17 has a switch control section (not illustrated) that switches the first recondensation processing and the second recondensation processing to each other.
  • the switch control section can switch from the first recondensation processing to the second recondensation processing in response to a timing of start of transfer that is scheduled, or a timing at which a detecting section detects that LNG is transferred from the LNG tank 16 , for example.
  • the detecting section there are cited a detecting section that detects that the transportation ship enters a harbor, a detecting section that detects that the automatic on-off valve of the transfer line L 6 opens, a detecting section that uses a control signal for controlling the automatic on-off valve as a detection signal, a detecting section that detects that a measurement result of a flow meter disposed in the transfer line L 6 reaches a threshold value or more and the like.
  • the switch control section can switch from the first recondensation processing to the second recondensation processing when a pressure value of the inside of the LNG tank 16 measured by the pressure gauge, or a pressure value measured by a pressure gauge disposed in at least any one of the feed line A 1 , the recovery line A 2 and the feed line A 3 reaches a predetermined value or more.
  • the recondenser 17 has a first heat exchanger 172 and a second heat exchanger 174 in an internal space 173 thereof.
  • a refrigerant is introduced into the first heat exchanger 172 from the refrigerator 15 at a time of the first recondensation processing, and cools BOG.
  • the switch control section switches from the first recondensation processing to the second recondensation processing.
  • the first heat exchanger 172 is operated, the second heat exchanger 174 is further operated.
  • the refrigerant is introduced into the second heat exchanger 174 through the buffer line D 1 from the refrigerant buffer 30 .
  • cooling by the two heat exchangers is executed, so that at a peak time (for example, in a case of processing a large amount of BOG that is generated when LNG is fed into the LNG transport ship, for example) at which the amount of BOG that is fed is larger than the amount of BOG at a normal time, BOG is also effectively cooled to be converted into LNG and the LNG can be returned to the LNG tank 16 .
  • the refrigerant that is used in the second heat exchanger 174 is configured to join the refrigerant return line B 2 of the first heat exchanger 172 through a refrigerant return line D 2 , but the present invention is not limited to this, and the refrigerant return line D 2 may be connected to the refrigerator 15 .
  • the switch control section can switch from the second recondensation processing to the first recondensation processing in response to a timing of end of transfer that is scheduled, or timing at which a detecting section detects that LNG transfer from the LNG tank 16 is completed, for example.
  • a detecting section there are cited a detecting section that detects that the automatic on-off valve in the transfer line L 6 is closed, a detecting section that detects the control signal that controls the automatic on-off valve as a detection signal, a detecting section that detects that the measurement result of the flow meter disposed in the transfer line L 6 becomes a threshold value or less and the like.
  • the switch control section can switch from the second recondensation processing to the first recondensation processing when a pressure value of the inside of the LNG tank 16 measured by the pressure gauge, or a pressure value measured by a pressure gauge disposed in at least one of the feed line A 1 , the recovery line A 2 and the feed line A 3 becomes less than a predetermined value.
  • two heat exchangers are disposed in the recondenser 17 , and cooling capabilities of the heat exchangers may be the same or different.
  • a combination of the refrigerant buffer and the heat exchanger is provided to be one, but the present invention is not limited to this, and two or more combinations may be provided.
  • FIGS. 5A to 5B An LNG production system 5 in embodiment 4 will be described with reference to FIGS. 5A to 5B .
  • Components with the same reference signs as those in the LNG production system 1 of embodiment 1 have the same functions, and therefore, explanation of the components will be omitted, or will be made briefly.
  • the refrigerator in the LNG production system is not used, but LNG in the LNG tank is used. That is, in embodiment 4, LNG is sub-cooled to a predetermined temperature by a refrigerant, and LNG is fed to the recondenser to be brought into contact with BOG to liquefy BOG.
  • Embodiment 4 has a first feed line A 1 that feeds BOG from the LNG tank 16 , an LNG lead-out line E 1 that leads out LNG from the LNG tank 16 , a sub-cooler 52 that cools LNG with the refrigerant, a recondenser 57 that liquefies BOG that is fed through the first feed line A 1 for BOG by LNG that is cooled in the sub-cooler 52 , under a pressure lower than the operating pressure of the LNG tank 16 , and a return line A 4 that returns LNG that is BOG liquefied in the recondenser 57 to the LNG tank 16 .
  • the respective components will be described in detail hereunder.
  • the first feed line A 1 may be provided with a safety valve (not illustrated) for a time when the pressure in the LNG tank 16 becomes abnormally high. Further, the first feed line A 1 is provided with an automatic on-off valve 42 and a pressure regulating valve 41 for performing feeding control of BOG to the condenser 10 .
  • the operating pressure in the LNG tank 16 is an average of 1.2 barA (120 KPaA) in absolute pressure, and is controlled within ⁇ 15% as an upper and lower limit values.
  • the tank internal pressure is measured by a pressure gauge, and a valve control section (not illustrated) controls opening and closing of the automatic on-off valve 42 based on a measurement result (conversion result) thereof.
  • a measurement result conversion result
  • the pressure regulating valve 41 measures a pipe internal pressure of the first feed line A 1 , and controls a valve opening degree based on a measurement result.
  • LNG is introduced into the sub-cooler 52 through the LNG lead-out line E 1 from the LNG tank 16 .
  • the valve control section (not illustrated) performs opening and closing control of the automatic on-off valve 51 provided in the LNG lead-out line E 1 , and controls a liquid feed pump P 5 , whereby LNG is fed to the sub-cooler 52 from the LNG tank 16 , and is fed to the recondenser 57 in a subsequent stage.
  • the in-tank liquid feed pump P 1 may be configured to feed LNG, instead of the liquid feed pump P 5 .
  • the refrigerant in the sub-cooler 52 can be a medium having a temperature lower than the boiling point of LNG, and LN 2 is used in the present embodiment.
  • LN 2 is introduced into the sub-cooler 52 through a refrigerant line F 1 from an LN 2 source (LN 2 tank, for example), and is used as a cold source for cooling LNG passing through an inside of the sub-cooler 52 .
  • LN 2 may be gasified, or may be discharged as a fluid in which a liquid and gas are mixed, when LN 2 is discharged from the sub-cooler 52 through a discharge line F 2 .
  • the fluid (LN 2 and/or GN 2 ) which is discharged may be subjected to discharge treatment to the atmosphere or may be subjected to recycle processing.
  • LNG may be controlled to have a temperature higher than the LNG solidifying point by a pressure regulating valve (not illustrated), or a flow rate regulating valve (not illustrated) that is installed in the refrigerant line F 1 in which the refrigerant (LN 2 ) flows.
  • An internal pressure of the recondenser 57 is controlled to be a pressure lower than the operating pressure (an average of 1.2 barA (120 KPaA) in the absolute pressure) of the LNG tank 16 in the BOG recondensation processing.
  • the internal pressure of the recondenser 57 is measured by the pressure gauge, and is regulated to be lower than the operating pressure of the LNG tank 16 .
  • LNG that is cooled in the sub-cooler 52 contacts BOG in the recondenser 57 , whereby the volume of BOG decreases by liquefaction, and the pressure in the recondenser 57 is reduced.
  • the low pressure state is kept by the cooled LNG being continuously supplied.
  • the internal pressure of the recondenser 57 is regulated by controlling the flow rate of the cooled LNG.
  • a flow rate regulating valve is provided in an LNG feed line E 2 between the sub-cooler 52 and the recondenser 57 , and the flow rate of LNG may be controlled by the flow rate regulating valve in accordance with a measurement result of the pressure gauge that measures the internal pressure of the above described recondenser 57 , the flow rate of LNG may be controlled by controlling the opening degree of an automatic on-off valve 51 , or both of them may be controlled.
  • the BOG that is introduced into the recondenser 57 is brought into contact with cooled LNG, whereby BOG is liquefied to be LNG, and LNG accumulates on a bottom of the recondenser 57 .
  • a method for bringing both BOG and LNG into contact with each other there are means of spraying LNG cooled in the sub-cooler 52 by shower, means of bringing both of them into contact with each other by using a filler, and the like.
  • a lower part of the recondenser 57 and the return line A 4 are connected.
  • the valve control section (not illustrated) performs on-off control of an automatic on-off valve 54 provided in the return line A 4 , and controls the liquid feed pump P 2 , whereby the valve control section can feed LNG back to the LNG tank 16 from the recondenser 57 .
  • a processing procedure of the recondensation processing of BOG will be described hereunder.
  • the respective valves 41 to 42 , 51 and 54 are in closed states except for the recondensation processing.
  • a temperature of the LNG which is cooled is preferably set at a temperature higher than the LNG solidifying point, and lower than the temperature of LNG in the LNG tank 16 .
  • the temperature of LNG which is cooled may be set based on the amount of BOG and the amount of LNG which is cooled.
  • the automatic on-off valve 54 of the return line A 4 is closed.
  • a second threshold value the second threshold value>the first threshold value
  • open the automatic on-off valve 42 and the pressure regulating valve 41 and introduce BOG to the recondenser 57 from the LNG tank 16 .
  • the recondenser 57 is pre-cooled, and the cooled LNG is introduced into the recondenser 57 with BOG, whereby BOG is cooled and changes state to LNG, and the LNG accumulates on the bottom of the recondenser 57 .
  • BOG may be configured to be discharged from the LNG tank 16 with a safety valve (not illustrated), or BOG may be discharged to external air by a vent not illustrated.
  • first threshold value is the pressure that is 1.26 times as high as 1.2 barA (120 KPaA), for example.
  • second threshold value is the pressure that is 1.3 times as high as 1.2 barA (120 KPaA), for example.
  • a first and second sub-coolers are disposed, and a first recondensation processing of liquefying BOG by a refrigerant fed from the first sub-cooler 52 , and a second recondensation processing of liquefying BOG by the refrigerant fed from the first sub-cooler 52 and a refrigerant fed from a second sub-cooler 521 in order to process more BOG than BOG at the time of the first recondensation processing are switched.
  • the first recondensation processing processing of liquefying BOG with LNG cooled in the first sub-cooler
  • the second recondensation processing can be executed.
  • the switch control section may switch from the first recondensation processing to the second recondensation processing in the case of transferring BOG to the LNG carrier, or may switch from the first recondensation processing to the second recondensation processing when the pressure value that is measured by the pressure gauge disposed in the LNG tank or in the feed line A 1 that feeds BOG to the recondenser 57 reaches a predetermined value or more.
  • the switch control section can perform switching from the first recondensation processing to the second recondensation processing in the timing of embodiment 3 described above.
  • the valve control section (not illustrated) performs opening and closing control of a sluice valve 53 , feeds LNG to the second sub-cooler 521 , and feeds LNG to the recondenser 57 in the subsequent stage.
  • cooled LNG is fed to the recondenser 57 through the LNG feed line E 2 from the first sub-cooler 52 , but the processing is switched to the second recondensation processing, and cooled LNG is fed to the recondenser 57 through an LNG feed line E 21 from the second sub-cooler 521 , in addition to the cooled LNG being fed to the recondenser 57 from the first sub-cooler 52 .
  • the refrigerant of the second sub-cooler 521 can be any medium with a temperature lower than the boiling point of LNG, and LN 2 is used in the present embodiment.
  • LN 2 is introduced into the second sub-cooler 521 through a refrigerant line F 11 from an LN 2 source (an LN 2 tank, for example), and is used as a cold source for cooling LNG that passes through an inside of the second sub-cooler 521 .
  • LN 2 may be gasified, or may be discharged as a fluid in which a liquid and gas are mixed, when the LN 2 is discharged through a discharge line F 21 from the second sub-cooler 521 .
  • the fluid (LN 2 and/or GN 2 ) which is discharged may be subjected to discharge treatment into the atmosphere, or may be subjected to recycling processing. Further, in the second sub-cooler 521 , LNG may be controlled to have a temperature higher than the LNG solidifying point, by a pressure regulating valve (not illustrated) or a flow rate regulating valve (not illustrated) that is installed in a refrigerant line F 11 in which the refrigerant (LN 2 ) flows.
  • the respective automatic on-off valves, pressure regulating valves and liquid feed pumps are provided in the respective lines, but some or all of them may be omitted in accordance with the use purpose without being limited to the above described dispositions.
  • LNG that is cooled is fed to pre-cool the recondenser 57 before BOG is fed into the recondenser 57
  • cooled LNG and BOG may be fed together.
  • a feeding amount (VL) of the cooled LNG and a feeding amount (VB) of BOG may be controlled to VL>VB.
  • the flow rate regulating valves may be provided in the respective LNG introduction line E 1 , line E 2 and first feed line A 1 for BOG to perform flow rate control of the respective feeding amounts.
  • the liquid feed pump P 2 is provided in the return line A 4 , but a configuration in which the liquid feed pump is not provided in the return line A 4 may be adopted.
  • LNG changed in state from BOG in the recondenser 57 may be fed into the LNG tank 16 by the gravity.
  • the refrigerant in the aforementioned second sub-cooler 521 may be supplied from a refrigerant buffer in which the refrigerant is stored in advance.
  • the pump P 1 is of an in-tank type, but the pump P 1 is not limited to this, and the pump P 1 may be a pump disposed on the transfer line L 6 .

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
US16/485,883 2017-02-14 2018-02-13 Lng production system equipped with recondenser Abandoned US20200056837A1 (en)

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JP2017-024938 2017-02-14
JP2017024938 2017-02-14
JP2017-036432 2017-02-28
JP2017036432A JP6812272B2 (ja) 2017-02-14 2017-02-28 リコンデンサーを備えるｌｎｇ製造システム
PCT/EP2018/053562 WO2018096187A2 (en) 2017-02-14 2018-02-13 Lng production system equipped with recondenser

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US11067335B1 (en) * 2020-08-26 2021-07-20 Next Carbon Soiittions, Llc Devices, systems, facilities, and processes for liquefied natural gas production
US20220065160A1 (en) * 2020-08-26 2022-03-03 ND Global Solutions, LLC Liquid natural gas processing with hydrogen production
CN114135423A (zh) * 2021-10-21 2022-03-04 中科楷亚动力科技(浙江)有限公司 一种lng发动机碳捕集装置
CN114321700A (zh) * 2021-12-30 2022-04-12 陕西融科低温设备有限公司 一种清洁燃料的储存系统及其储存方法
US11953157B2 (en) 2018-10-09 2024-04-09 L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Claude Georges Claude Method and facility for storing and distributing liquefied hydrogen

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CN111569693B (zh) * 2020-04-01 2022-09-02 海洋石油工程股份有限公司 用于氮气和液氮气液混合的装置

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11953157B2 (en) 2018-10-09 2024-04-09 L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Claude Georges Claude Method and facility for storing and distributing liquefied hydrogen
US11067335B1 (en) * 2020-08-26 2021-07-20 Next Carbon Soiittions, Llc Devices, systems, facilities, and processes for liquefied natural gas production
WO2022046536A1 (en) * 2020-08-26 2022-03-03 Next Carbon Solutions, Llc Devices, systems, facilities, and processes for liquefied natural gas production
US20220065160A1 (en) * 2020-08-26 2022-03-03 ND Global Solutions, LLC Liquid natural gas processing with hydrogen production
CN114135423A (zh) * 2021-10-21 2022-03-04 中科楷亚动力科技(浙江)有限公司 一种lng发动机碳捕集装置
CN114321700A (zh) * 2021-12-30 2022-04-12 陕西融科低温设备有限公司 一种清洁燃料的储存系统及其储存方法

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JP2018132182A (ja) 2018-08-23

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