US20190185969A1 - Aluminum alloy sheet that exhibits excellent surface quality after anodizing and method for producing the same - Google Patents
Aluminum alloy sheet that exhibits excellent surface quality after anodizing and method for producing the same Download PDFInfo
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- US20190185969A1 US20190185969A1 US16/283,031 US201916283031A US2019185969A1 US 20190185969 A1 US20190185969 A1 US 20190185969A1 US 201916283031 A US201916283031 A US 201916283031A US 2019185969 A1 US2019185969 A1 US 2019185969A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
- B21B1/26—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by hot-rolling, e.g. Steckel hot mill
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/02—Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
- B22D21/04—Casting aluminium or magnesium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/14—Alloys based on aluminium with copper as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/16—Alloys based on aluminium with copper as the next major constituent with magnesium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/057—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
Definitions
- JP-A-2000-273563 and JP-A-2006-52436 disclose related-art technology.
- An object of the invention is to provide an aluminum alloy sheet that exhibits an excellent surface quality after anodizing (i.e., does not show a band-like streak pattern after anodizing), and a method for producing the same.
- aspects of the invention may thus provide an aluminum alloy sheet that exhibits an excellent surface quality after anodizing (i.e., does not show a band-like streak pattern after anodizing), and a method for producing the same.
- the peritectic element in a solid-solution state is present in the surface area of the aluminum alloy sheet as a band that extends in the lengthwise direction (rolling direction) of the aluminum alloy sheet, and the concentration of the peritectic element in a solid-solution state differs depending on each band (i.e., varies in the widthwise direction of the aluminum alloy sheet).
- the peritectic element is incorporated in an anodic oxide coating in a solid-solution state due to anodizing.
- the resulting anodized aluminum alloy sheet also has a structure in which the concentration of the peritectic element in a solid-solution state that has been incorporated in the anodic oxide coating varies in the widthwise direction of the aluminum alloy sheet in the form of a band having a width of 0.05 to about 5 mm, and the difference in the concentration of the peritectic element between adjacent bands is 0.005% or less.
- the concentration of the peritectic element in a solid-solution state is determined by a linear analysis that measures the concentration of the peritectic element from fluorescent X-rays that are generated by applying electron beams at a pitch of 10 ⁇ m using an electron probe microanalyser (EPMA), and the difference in the concentration of the peritectic element between adjacent bands is calculated.
- EPMA electron probe microanalysis
- Examples of a preferable peritectic element include Ti and Cr.
- the Cr content is used as an element that improves the strength of the aluminum alloy sheet, and refines the crystal grains.
- the Cr content is 0.4% or less to obtain the above effect. However, if the Cr content is less than 0.0001%, the production cost is increased and it becomes difficult to produce the aluminum alloy sheet in a commercial base, because the use of a higher purity aluminum material is required.
- the Cr content is preferably 0.0001 to 0.4%, and the Cr content is more preferably 0.003 to 0.4%. If the Cr content exceeds 0.4%, coarse intermetallic compounds may be produced, and a streak pattern due to the intermetallic compounds may be observed after anodizing.
- Mg improves the strength of the aluminum alloy sheet.
- the Mg content is preferably 0.3 to 6.0%. If the Mg content is less than 0.3%, an improvement in strength may not be achieved. If the Mg content exceeds 6.0%, cracks may occur during hot rolling.
- Cu improves the strength of the aluminum alloy sheet, and ensures that the entire anodic oxide coating has a uniform color tone.
- the Cu content is preferably 0.5% or less. If the Cu content exceeds 0.5%, Al—Cu precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- Mn improves the strength of the aluminum alloy sheet, and refines the crystal grains.
- the Mn content is preferably 0.5% or less. If the Mn content exceeds 0.5%, Al—Mn—Si crystallized products or precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- Fe improves the strength of the aluminum alloy sheet, and refines the crystal grains.
- the Fe content is preferably 0.4% or less. If the Fe content exceeds 0.4%, Al—Fe—Si or Al—Fe crystallized products or precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- Si improves the strength of the aluminum alloy sheet, and refines the crystal grains.
- the Si content is preferably 0.3% or less. If the Si content exceeds 0.3%, Al—Fe—Si crystallized products or Si precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- an element such as Zn is inevitably included in the aluminum alloy.
- Zn not more than 0.25% does not affect the effect of the invention.
- the method for producing an aluminum alloy sheet according to one embodiment of the invention includes subjecting an ingot to hot rolling and cold rolling to produce an aluminum alloy sheet, the rolling target side of the ingot having a structure in which the difference in the concentration of a peritectic element between an area having a diameter of 5 ⁇ m and positioned in a center area of a crystal grain and an area having a diameter of 5 ⁇ m and positioned away from the grain boundary of the crystal grain by 2.5 ⁇ m is 0.090% or less.
- An aluminum alloy sheet produced using such an ingot exhibits an excellent surface quality after anodizing (i.e., does not show a band-like streak pattern after anodizing).
- An ingot of an aluminum alloy having the composition shown in Table 1 was cast using a DC casting method.
- the resulting ingot (thickness: 500 mm, width: 1000 mm (transverse cross-sectional dimensions)) was homogenized under the conditions shown in Table 1, and cooled to room temperature.
- the upper side (rolling target side), the lower side (rolling target side), the right side, and the left side of the ingot were faced by 20 mm.
- the crystal grains of the rolling target side of the ingot were subjected to point analysis (five points) using an EPMA to determine the distribution state of Ti and Cr in a solid-solution state.
- the homogenized ingot was heated to 480° C., and hot-rolled to a thickness of 5.0 mm.
- the hot rolling finish temperature was set to 250° C.
- the ingot was then cold-rolled to a thickness of 1.0 mm, and softened at 400° C. for 1 hour.
- the resulting sheet material was subjected to linear analysis (in an arbitrary five areas having a length of 10 mm in the widthwise direction) using an EPMA to determine the distribution state of Ti and Cr in a solid-solution state to calculate the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands.
- a plurality of bands were measured by the linear analysis (length: 10 mm), and a plurality of concentration differential values were obtained. The maximum difference in concentration between adjacent bands was taken as a representative value. The average value of the five representative values was calculated.
- the sheet material was surface-roughened by shot blasting, chemically polished using phosphoric acid and sulfuric acid, and anodized using sulfuric acid to form an anodic oxide coating having a thickness of 10 ⁇ m.
- the presence or absence of a band-like streak pattern on the anodized sheet was determined with the naked eye.
- the anodized sheet was subjected to linear analysis (in five areas (streak pattern areas when a streak pattern was observed) having a length of 10 mm in the widthwise direction) using an EPMA to determine the distribution state of Ti and Cr in a solid-solution state.
- the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands was calculated.
- a plurality of bands were measured by the linear analysis (length: 10 mm), and a plurality of concentration differential values were obtained.
- the maximum difference in concentration between adjacent bands was taken as a representative value.
- the average value of the five representative values was calculated.
- the homogenized ingot had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between the area having a diameter of 5 ⁇ m and positioned in the center area of the crystal grain and the area having a diameter of 5 ⁇ m and positioned away from the grain boundary of the crystal grain by 2.5 ⁇ m was 0.040% or less, and the unanodized sheet material had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands was 0.008% or less.
- the samples 1 to 10 exhibited excellent surface quality after anodizing without showing a band-like streak pattern.
- the anodized sheet material had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands was 0.005% or less.
- the homogenized ingot had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between the area having a diameter of 5 ⁇ m and positioned in the center area of the crystal grain and the area having a diameter of 5 ⁇ m and positioned away from the grain boundary of the crystal grain by 2.5 ⁇ m exceeded 0.090%, and the unanodized sheet material had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands exceeded 0.008%.
- the anodized sheet material showed a band-like streak pattern after anodizing, and had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands exceeded 0.005%.
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Abstract
An aluminum alloy sheet that exhibits excellent surface quality after anodizing, includes a peritectic element that undergoes a peritectic reaction with at least aluminum, and requires an anodic oxide coating is characterized in that the concentration of the peritectic element in a solid-solution state that is present in the outermost surface area of the aluminum alloy sheet varies in the widthwise direction of the aluminum alloy sheet in the form of a band having a width of 0.05 mm or less, and the difference in the concentration of the peritectic element between adjacent bands is 0.008 mass % or less.
Description
- This application is a divisional of prior U.S. application Ser. No. 13/864,777, filed Apr. 17, 2013, which is hereby incorporated by reference in its entirety.
- The invention relates to an aluminum alloy sheet that exhibits an excellent surface quality after anodizing (i.e., does not show a band-like streak pattern after anodizing), and a method for producing the same.
- In recent years, an aluminum alloy sheet has been increasingly applied to automotive interior parts and outer panels for consumer electronics. These products are required to exhibit an excellent surface quality, and are often used in an anodized state. However, an outer panel for consumer electronics may show a band-like streak pattern after anodizing, for example. Therefore, an aluminum alloy sheet that does not show a band-like streak pattern after anodizing has been desired.
- Various attempts have been made to prevent such a band-like streak pattern, and methods that control the chemical components, the crystal grain size of the final sheet, the dimensions and the distribution density of precipitates, or the like have been proposed. However, a band-like streak pattern may not be prevented by these methods.
- JP-A-2000-273563 and JP-A-2006-52436 disclose related-art technology.
- The invention was conceived as a result of finding that the occurrence of a band-like streak pattern after anodizing is affected by an element that undergoes a peritectic reaction with aluminum and is present in a solid-solution state, and conducting tests and studies based on the above finding. An object of the invention is to provide an aluminum alloy sheet that exhibits an excellent surface quality after anodizing (i.e., does not show a band-like streak pattern after anodizing), and a method for producing the same.
- A first aspect of the invention provides an aluminum alloy sheet that exhibits an excellent surface quality after anodizing, the aluminum alloy sheet including a peritectic element that undergoes a peritectic reaction with at least aluminum, and requiring an anodic oxide coating, a concentration of the peritectic element in a solid-solution state that is present in an outermost surface area of the aluminum alloy sheet varying in a widthwise direction of the aluminum alloy sheet in a form of a band having a width of 0.05 mm or more, and a difference in the concentration of the peritectic element between adjacent bands being 0.008 mass % or less. Note that the unit “mass %” may be hereinafter referred to as “%”.
- The aluminum alloy sheet may include either or both of 0.001 to 0.1 mass % of Ti and 0.0001 to 0.4 mass % of Cr as the peritectic element.
- The aluminum alloy sheet may include either or both of 0.001 to 0.1 mass % of Ti and 0.0001 to 0.4 mass % of Cr as the peritectic element, and one or more elements among 0.3 to 6.0 mass % of Mg, 0.5 mass % or less of Cu, 0.5 mass % or less of Mn, 0.4 mass % or less of Fe, and 0.3 mass % or less of Si, with the balance being Al and unavoidable impurities.
- A second aspect of the invention provides a method for producing the aluminum alloy sheet according to the first aspect of the invention, the method including subjecting an ingot to hot rolling and cold rolling to produce an aluminum alloy sheet, a rolling target side of the ingot having a structure in which a difference in concentration of a peritectic element between an area having a diameter of 5 μm and positioned in a center area of a crystal grain and an area having a diameter of 5 μm and positioned away from a grain boundary of the crystal grain by 2.5 μm is 0.040% or less.
- Several aspects of the invention may thus provide an aluminum alloy sheet that exhibits an excellent surface quality after anodizing (i.e., does not show a band-like streak pattern after anodizing), and a method for producing the same.
- When an aluminum alloy sheet that includes a peritectic element that undergoes a peritectic reaction with aluminum is produced by hot rolling and cold rolling using a normal method, the peritectic element in a solid-solution state is present in the surface area of the aluminum alloy sheet as a band that extends in the lengthwise direction (rolling direction) of the aluminum alloy sheet, and the concentration of the peritectic element in a solid-solution state differs depending on each band (i.e., varies in the widthwise direction of the aluminum alloy sheet).
- An aluminum alloy sheet according to one embodiment of the invention is characterized in that the concentration of the peritectic element in a solid-solution state that is present in the outermost surface area of the aluminum alloy sheet varies in the widthwise direction of the aluminum alloy sheet in the form of a band having a width of 0.05 to about 5 mm, and the difference in the concentration of the peritectic element between adjacent bands is 0.008% or less. It is possible to obtain an anodized aluminum alloy sheet that exhibits excellent surface quality and is free from a band-like streak pattern by anodizing an aluminum alloy sheet having the above features. If the difference in the concentration of the peritectic element between adjacent bands exceeds 0.008%, a streak pattern may be observed with the naked eye (i.e., excellent surface quality may not be obtained) after anodizing.
- The peritectic element is incorporated in an anodic oxide coating in a solid-solution state due to anodizing. When anodizing an aluminum alloy sheet having the above features, the resulting anodized aluminum alloy sheet also has a structure in which the concentration of the peritectic element in a solid-solution state that has been incorporated in the anodic oxide coating varies in the widthwise direction of the aluminum alloy sheet in the form of a band having a width of 0.05 to about 5 mm, and the difference in the concentration of the peritectic element between adjacent bands is 0.005% or less.
- The concentration of the peritectic element in a solid-solution state is determined by a linear analysis that measures the concentration of the peritectic element from fluorescent X-rays that are generated by applying electron beams at a pitch of 10 μm using an electron probe microanalyser (EPMA), and the difference in the concentration of the peritectic element between adjacent bands is calculated.
- Examples of a preferable peritectic element include Ti and Cr.
- Ti is used as an element that suppresses coarsening of the cast structure. The Ti content is preferably 0.001 to 0.1%. If the Ti content is less than 0.001%, coarsening of the cast structure may not be suppressed. If the Ti content exceeds 0.1%, coarse intermetallic compounds may be produced, and a streak pattern due to the intermetallic compounds may be observed after anodizing.
- Cr is used as an element that improves the strength of the aluminum alloy sheet, and refines the crystal grains. The Cr content is 0.4% or less to obtain the above effect. However, if the Cr content is less than 0.0001%, the production cost is increased and it becomes difficult to produce the aluminum alloy sheet in a commercial base, because the use of a higher purity aluminum material is required. The Cr content is preferably 0.0001 to 0.4%, and the Cr content is more preferably 0.003 to 0.4%. If the Cr content exceeds 0.4%, coarse intermetallic compounds may be produced, and a streak pattern due to the intermetallic compounds may be observed after anodizing.
- The aluminum alloy sheet according to one embodiment of the invention may include one or more elements among the following alloy elements in addition to the peritectic element.
- Mg improves the strength of the aluminum alloy sheet. The Mg content is preferably 0.3 to 6.0%. If the Mg content is less than 0.3%, an improvement in strength may not be achieved. If the Mg content exceeds 6.0%, cracks may occur during hot rolling.
- Cu improves the strength of the aluminum alloy sheet, and ensures that the entire anodic oxide coating has a uniform color tone. The Cu content is preferably 0.5% or less. If the Cu content exceeds 0.5%, Al—Cu precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- Mn improves the strength of the aluminum alloy sheet, and refines the crystal grains. The Mn content is preferably 0.5% or less. If the Mn content exceeds 0.5%, Al—Mn—Si crystallized products or precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- Fe improves the strength of the aluminum alloy sheet, and refines the crystal grains. The Fe content is preferably 0.4% or less. If the Fe content exceeds 0.4%, Al—Fe—Si or Al—Fe crystallized products or precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- Si improves the strength of the aluminum alloy sheet, and refines the crystal grains. The Si content is preferably 0.3% or less. If the Si content exceeds 0.3%, Al—Fe—Si crystallized products or Si precipitates (intermetallic compounds) may be formed, and a streak pattern may occur, or the anodic oxide coating may become turbid due to the intermetallic compounds.
- As unavoidable impurities, an element such as Zn is inevitably included in the aluminum alloy. For example, Zn not more than 0.25% does not affect the effect of the invention.
- Specifically, the embodiments of the invention may be applied to a pure aluminum (1000 series) aluminum alloy, an Al—Mn (3000 series) aluminum alloy, an Al—Mg (5000 series) aluminum alloy, and an Al—Mg—Si (6000 series) aluminum alloy that include a peritectic element such as Ti and Cr.
- A method for producing an aluminum alloy sheet according to one embodiment of the invention is described below. The method for producing an aluminum alloy sheet according to one embodiment of the invention includes subjecting an ingot to hot rolling and cold rolling to produce an aluminum alloy sheet, the rolling target side of the ingot having a structure in which the difference in the concentration of a peritectic element between an area having a diameter of 5 μm and positioned in a center area of a crystal grain and an area having a diameter of 5 μm and positioned away from the grain boundary of the crystal grain by 2.5 μm is 0.090% or less. An aluminum alloy sheet produced using such an ingot exhibits an excellent surface quality after anodizing (i.e., does not show a band-like streak pattern after anodizing).
- The rolling target side of an ingot that has been cast using a normal semicontinuous casting method, and then homogenized has a cast structure in which the crystal grains formed during casting have an average grain size of 50 to 500 μm. For example, the crystal grains at several points of each (upper and lower) rolling target side of the ingot are subjected to point analysis that measures the concentration of the peritectic element from fluorescent X-rays that are generated by applying electron beams using an EPMA in an area having a diameter of 5 μm and positioned in the center area of a crystal grain and an area having a diameter of 5 μm and positioned away from the grain boundary of the crystal grain by 2.5 μm to determine the difference in the concentration of the peritectic element. When the difference in the concentration of the peritectic element is 0.040% or less, an aluminum alloy sheet that is to be anodized is produced using the ingot.
- In order to obtain an ingot which is obtained by casting and homogenizing aluminum alloy molten metal that includes the peritectic element, and of which the rolling target side has a structure in which the difference in the concentration of the peritectic element between an area having a diameter of 5 μm and positioned in the center area of a crystal grain and an area having a diameter of 5 μm and positioned away from the grain boundary of the crystal grain by 2.5 μm is 0.040% or less, it is preferable to homogenize the ingot at a temperature less than the solidus temperature of the aluminum alloy (more preferably at a temperature equal to or higher than “solidus temperature−50° C.”) for more than 3 hours.
- The invention is further described below by way of examples and comparative examples to demonstrate the advantageous effects of the invention. Note that the following examples merely illustrate several embodiments of the invention, and the invention is not limited to the following examples.
- An ingot of an aluminum alloy having the composition shown in Table 1 was cast using a DC casting method. The resulting ingot (thickness: 500 mm, width: 1000 mm (transverse cross-sectional dimensions)) was homogenized under the conditions shown in Table 1, and cooled to room temperature. The upper side (rolling target side), the lower side (rolling target side), the right side, and the left side of the ingot were faced by 20 mm. The crystal grains of the rolling target side of the ingot were subjected to point analysis (five points) using an EPMA to determine the distribution state of Ti and Cr in a solid-solution state. The difference in the average value of the total concentration of Ti and Cr in a solid-solution state between an area having a diameter of 5 μm and positioned in the center area of the crystal grain and an area having a diameter of 5 μm and positioned away from the grain boundary of the crystal grain by 2.5 μm was calculated.
- The homogenized ingot was heated to 480° C., and hot-rolled to a thickness of 5.0 mm. The hot rolling finish temperature was set to 250° C. The ingot was then cold-rolled to a thickness of 1.0 mm, and softened at 400° C. for 1 hour.
- The resulting sheet material was subjected to linear analysis (in an arbitrary five areas having a length of 10 mm in the widthwise direction) using an EPMA to determine the distribution state of Ti and Cr in a solid-solution state to calculate the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands. A plurality of bands were measured by the linear analysis (length: 10 mm), and a plurality of concentration differential values were obtained. The maximum difference in concentration between adjacent bands was taken as a representative value. The average value of the five representative values was calculated.
- The sheet material was surface-roughened by shot blasting, chemically polished using phosphoric acid and sulfuric acid, and anodized using sulfuric acid to form an anodic oxide coating having a thickness of 10 μm. The presence or absence of a band-like streak pattern on the anodized sheet was determined with the naked eye. The anodized sheet was subjected to linear analysis (in five areas (streak pattern areas when a streak pattern was observed) having a length of 10 mm in the widthwise direction) using an EPMA to determine the distribution state of Ti and Cr in a solid-solution state. The difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands was calculated. A plurality of bands were measured by the linear analysis (length: 10 mm), and a plurality of concentration differential values were obtained. The maximum difference in concentration between adjacent bands was taken as a representative value. The average value of the five representative values was calculated.
- The results are shown in Tables 2 and 3. As shown in Table 2, when using the inventive samples 1 to 10, the homogenized ingot had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between the area having a diameter of 5 μm and positioned in the center area of the crystal grain and the area having a diameter of 5 μm and positioned away from the grain boundary of the crystal grain by 2.5 μm was 0.040% or less, and the unanodized sheet material had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands was 0.008% or less.
- As shown in Table 3, the samples 1 to 10 exhibited excellent surface quality after anodizing without showing a band-like streak pattern. The anodized sheet material had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands was 0.005% or less.
- As shown in Table 2, when using the samples 11 to 15 that were homogenized at a low temperature, the homogenized ingot had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between the area having a diameter of 5 μm and positioned in the center area of the crystal grain and the area having a diameter of 5 μm and positioned away from the grain boundary of the crystal grain by 2.5 μm exceeded 0.090%, and the unanodized sheet material had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands exceeded 0.008%. As shown in Table 3, the anodized sheet material showed a band-like streak pattern after anodizing, and had a structure in which the difference in the average value of the total concentration of Ti and Cr in a solid-solution state between adjacent bands exceeded 0.005%.
-
TABLE 1 Component (mass %) Alloy Si Fe Cu Mn Mg Cr Zn Ti Al A 0.031 0.396 0.008 0.007 2.412 0.161 0.006 0.022 Bal. B 0.051 0.256 0.011 0.005 5.975 0.003 0.011 0.096 Bal. C 0.295 0.04 0.497 0.488 0.312 0.396 0.007 0.003 Bal. D 0.092 0.225 0.042 0.037 1.324 0.113 0.01 0.001 Bal. E 0.113 0.292 0.083 0.281 2.107 0.0001 0.005 0.042 Bal. -
TABLE 2 Total concentration of Total concentration of Ti and Cr in solid-solution state Ti and Cr in solid-solution state (ingot) (average value of five points) Difference in total (unanodized sheet) Difference in total Area having concentration of (average value of five points) concentration of diameter of 5 μm Ti and Cr in Total Total Ti and Cr in Homogenization and positioned Area positioned solid-solution concentration concentration solid-solution conditions in center area away from grain state of Ti and Cr of Ti and Cr in state (Temp (° C.) - of crystal grain boundary by 2.5 μm (ingot) in one band adjacent band (unanodized sheet) Sample Alloy time (h)) (A) (B) (|A − B|) (C) (D) (|C − D|) 1 A 590-5 0.199 0.164 0.035 0.188 0.180 0.008 2 B 540-12 0.112 0.091 0.021 0.103 0.096 0.007 3 C 540-24 0.416 0.391 0.025 0.403 0.396 0.007 4 D 540-12 0.128 0.099 0.029 0.118 0.111 0.007 5 E 540-12 0.052 0.027 0.025 0.046 0.038 0.008 6 A 590-240 0.196 0.174 0.022 0.187 0.181 0.006 7 B 540-480 0.108 0.093 0.015 0.102 0.097 0.005 8 C 540-480 0.410 0.393 0.017 0.402 0.397 0.005 9 D 540-240 0.123 0.104 0.019 0.117 0.112 0.005 10 E 540-240 0.047 0.031 0.016 0.044 0.039 0.005 11 A 500-3 0.212 0.167 0.045 0.197 0.175 0.022 12 B 450-3 0.129 0.078 0.051 0.121 0.085 0.036 13 C 480-3 0.461 0.372 0.089 0.441 0.374 0.067 14 D 450-3 0.148 0.084 0.064 0.136 0.095 0.041 15 E 480-3 0.065 0.021 0.044 0.056 0.026 0.030 -
TABLE 3 Total concentration of Ti and Cr in solid-solution state (anodized sheet) (average value of five areas) Difference in total concentration Total concentration of Total concentration of of Ti and Cr in solid-solution state Ti and Cr in one band Ti and Cr in adjacent band (anodized sheet) Streak pattern Sample (E) (F) (|E − F|) after anodizing 1 0.187 0.182 0.005 No 2 0.101 0.097 0.004 No 3 0.401 0.397 0.004 No 4 0.116 0.112 0.004 No 5 0.044 0.040 0.004 No 6 0.186 0.182 0.004 No 7 0.101 0.098 0.003 No 8 0.401 0.398 0.003 No 9 0.116 0.113 0.003 No 10 0.043 0.040 0.003 No 11 0.191 0.178 0.013 Yes 12 0.110 0.092 0.018 Yes 13 0.418 0.388 0.030 Yes 14 0.128 0.106 0.022 Yes 15 0.046 0.032 0.014 Yes - Although only some exemplary embodiments and/or examples of the invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments and/or examples without materially departing from the novel teachings and advantages of the invention. Accordingly, all such modifications are intended to be included within the scope of the invention.
- The documents described in the specification are incorporated herein by reference in their entirety.
Claims (1)
1. A method for producing the aluminum alloy sheet comprising subjecting an ingot to hot rolling and cold rolling to produce an aluminum alloy sheet, a rolling target side of the ingot having a structure in which a difference in concentration of a peritectic element between an area having a diameter of 5 μm and positioned in a center area of a crystal grain and an area having a diameter of 5 μm and positioned away from a grain boundary of the crystal grain by 2.5 μm is 0.040% or less.
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JP5944862B2 (en) * | 2012-08-08 | 2016-07-05 | 株式会社Uacj | Aluminum alloy plate excellent in surface quality after anodizing treatment and manufacturing method thereof |
JP6433380B2 (en) * | 2014-06-27 | 2018-12-05 | 株式会社神戸製鋼所 | Aluminum alloy rolled material |
CN106011562B (en) * | 2015-03-27 | 2018-04-06 | 株式会社神户制钢所 | Aluminium alloy plate |
CN106929781B (en) * | 2015-12-29 | 2019-01-08 | 徐工集团工程机械股份有限公司 | A kind of preparation method of high-strength aluminum alloy pin shaft |
RU2710475C1 (en) * | 2016-06-28 | 2019-12-26 | Новелис Инк. | Anodised aluminum alloys and related products and methods |
CN106694547B (en) * | 2016-12-22 | 2019-03-26 | 新疆众和股份有限公司 | A kind of hot rolling technology of the hard state aluminium alloy of anodic oxidation |
CN106694548B (en) * | 2016-12-22 | 2019-03-26 | 新疆众和股份有限公司 | A kind of hot rolling technology of anodic oxidation aluminium alloy |
CN106521373B (en) * | 2016-12-22 | 2018-08-03 | 新疆众和股份有限公司 | A kind of granule surface contral technique of anodic oxidation aluminium alloy |
CN109207814A (en) * | 2018-10-26 | 2019-01-15 | 中铝瑞闽股份有限公司 | With the 5 line aluminium alloy Strips and its manufacturing method of good gloss degree after anodic oxidation |
CN114252466B (en) * | 2021-12-16 | 2024-01-12 | 昆山晶微新材料研究院有限公司 | Quantitative analysis method and comparison method for intra-crystal solid solubility of alloy |
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US3164494A (en) | 1960-10-19 | 1965-01-05 | Reynolds Metals Co | Bright finished aluminum alloy system |
JPS5811769B2 (en) | 1978-06-30 | 1983-03-04 | 富士通株式会社 | Periodic pulse check method |
JPS5918469B2 (en) * | 1980-08-21 | 1984-04-27 | 株式会社神戸製鋼所 | Method for producing aluminum alloy plate with excellent bright alumite properties and strength |
JPS5811769A (en) * | 1981-07-15 | 1983-01-22 | Mitsubishi Alum Co Ltd | Production of bright al alloy plate material having superior anodized surface |
JP3308305B2 (en) * | 1992-07-06 | 2002-07-29 | 住友軽金属工業株式会社 | Manufacturing method of aluminum alloy plate for anodizing treatment |
JPH09143602A (en) * | 1995-11-15 | 1997-06-03 | Nippon Light Metal Co Ltd | Aluminum alloy sheet in which anodically oxidized film develops into achromatic light gray |
JP4040787B2 (en) | 1999-03-18 | 2008-01-30 | 古河スカイ株式会社 | Aluminum alloy rolled plate with stable gray color after anodization and method for producing the same |
JP2006052436A (en) | 2004-08-11 | 2006-02-23 | Furukawa Sky Kk | Shot finished aluminum-alloy plate for alumite treatment, and method for manufacturing aluminum-alloy part using it |
US20080289731A1 (en) * | 2007-05-24 | 2008-11-27 | Akio Uesugi | Method of producing aluminum alloy sheet for lithographic printing plate |
JP5354954B2 (en) * | 2007-06-11 | 2013-11-27 | 住友軽金属工業株式会社 | Aluminum alloy plate for press forming |
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JP5640399B2 (en) * | 2010-03-03 | 2014-12-17 | 日本軽金属株式会社 | Aluminum alloy plate with anodized film and method for producing the same |
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