US20180259251A1 - Method of removing co2 from a contaminated hydrocarbon stream - Google Patents
Method of removing co2 from a contaminated hydrocarbon stream Download PDFInfo
- Publication number
- US20180259251A1 US20180259251A1 US15/779,652 US201615779652A US2018259251A1 US 20180259251 A1 US20180259251 A1 US 20180259251A1 US 201615779652 A US201615779652 A US 201615779652A US 2018259251 A1 US2018259251 A1 US 2018259251A1
- Authority
- US
- United States
- Prior art keywords
- stream
- liquid
- hydrocarbon
- crystallization chamber
- enriched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 149
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 149
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 141
- 238000000034 method Methods 0.000 title claims abstract description 58
- 239000007788 liquid Substances 0.000 claims abstract description 111
- 239000002245 particle Substances 0.000 claims abstract description 90
- 238000002425 crystallisation Methods 0.000 claims abstract description 87
- 230000008025 crystallization Effects 0.000 claims abstract description 87
- 239000002002 slurry Substances 0.000 claims abstract description 77
- 239000007790 solid phase Substances 0.000 claims abstract description 25
- 239000007787 solid Substances 0.000 claims abstract description 23
- 239000007791 liquid phase Substances 0.000 claims abstract description 16
- 239000012071 phase Substances 0.000 claims abstract description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 62
- 239000007789 gas Substances 0.000 claims description 56
- 239000012530 fluid Substances 0.000 claims description 23
- 239000012265 solid product Substances 0.000 claims description 23
- 239000003949 liquefied natural gas Substances 0.000 claims description 15
- 238000007599 discharging Methods 0.000 claims description 11
- 238000004891 communication Methods 0.000 claims description 10
- 238000013022 venting Methods 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000000356 contaminant Substances 0.000 description 8
- 239000003345 natural gas Substances 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 230000005484 gravity Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011973 solid acid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006163 transport media Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
- F25J3/0635—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D43/00—Separating particles from liquids, or liquids from solids, otherwise than by sedimentation or filtration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
- F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/0605—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
- F25J3/061—Natural gas or substitute natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
- F25J3/067—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
- B01D2256/245—Methane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/10—Processes or apparatus using other separation and/or other processing means using combined expansion and separation, e.g. in a vortex tube, "Ranque tube" or a "cyclonic fluid separator", i.e. combination of an isentropic nozzle and a cyclonic separator; Centrifugal separation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/20—Processes or apparatus using other separation and/or other processing means using solidification of components
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/84—Processes or apparatus using other separation and/or other processing means using filter
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/04—Mixing or blending of fluids with the feed stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/04—Recovery of liquid products
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/66—Separating acid gases, e.g. CO2, SO2, H2S or RSH
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/30—Compression of the feed stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/60—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being hydrocarbons or a mixture of hydrocarbons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
- F25J2235/60—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being (a mixture of) hydrocarbons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/90—Processes or apparatus involving steps for recycling of process streams the recycled stream being boil-off gas from storage
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/04—Internal refrigeration with work-producing gas expansion loop
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/88—Quasi-closed internal refrigeration or heat pump cycle, if not otherwise provided
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Definitions
- the present invention relates to a method to separate CO2 from a contaminated hydrocarbon-containing stream.
- hydrocarbon-containing gas streams are well known in the art. It is desirable to liquefy a hydrocarbon-containing gas stream such as natural gas stream for a number of reasons.
- natural gas can be stored and transported over long distances more readily as a liquid than in gaseous form, because it occupies a smaller volume and does not need to be stored at high pressures.
- the contaminated hydrocarbon-containing gas stream is treated to remove one or more contaminants (such as H 2 O, CO 2 , H 2 S and the like) which may freeze out during the liquefaction process or are undesirable in the product.
- WO2014/166925 describes a method of liquefying a contaminated hydrocarbon-containing gas stream, the method comprising at least the steps of:
- step (4) expanding the liquid steam obtained in step (4) thereby obtaining a multiphase stream, the multiphase stream containing at least a vapour phase, a liquid phase and a solid phase;
- step (10) combining the compressed gas stream obtained in step (9) with the contaminated hydrocarbon-containing gas stream provided in step (1).
- the method as described in WO2014/166925 allows liquefying a contaminated hydrocarbon-containing gas stream with a relatively low equipment count, thereby providing a simple and cost-effective method of liquefying a contaminated hydrocarbon-containing gas stream, in particular a methane-containing contaminated gas stream such as natural gas.
- the contaminant may be CO2.
- the solubility of CO2 in liquefied natural gas is very low. So, the method according to WO2014/166925 doesn't remove the CO2 in the gaseous phase, but by expansion over a valve, leading to a rapid oversaturation of the liquids, leading to solid CO2 formation. The particles are allowed to reach equilibrium and may then be removed with the use of a cyclone, settler, filter or a combination thereof.
- waste stream may be a mix of CO2 and valuable hydrocarbons.
- the handling of the fine-grained slurry makes separation difficult and may lead to a significant loss of valuable hydrocarbons and thus a loss of value.
- U.S. Pat. No. 3,376,709 describes separation of acid gases from natural gas by solidification by a process which comprises providing the feed natural gas at conditions of pressure and temperature as to constitute a liquid solution, reducing the pressure on the solution to provide a mixture consisting of solid, liquid and vapor phases, immediately contacting the mixture with liquid natural gas containing solid acid gas particles and removing solid acid gas particles therefrom.
- the size of the solid acid gas particles is typically from about 0.001 to about 2 microns. As already mentioned above, the handling of fine-grained slurry makes separation difficult and may lead to a significant loss of value.
- One or more of the above or other objects are achieved according to the present invention by a method to separate CO2 from a contaminated hydrocarbon-containing stream ( 10 ); the method comprising
- a system for separating CO2 from a contaminated hydrocarbon-containing stream comprising
- extruder allows an efficient way of removing the concentrated slurry ( 140 ) from the crystallization chamber ( 91 ), while at the same time a relatively pure CO2 enriched solid product and a relatively pure methane enriched liquid hydrocarbon stream ( 147 ) are obtained separately from each other.
- the CO2 enriched solid product may also be referred to as a CO2 enriched compact product, and vice versa.
- the concentrated slurry comprises a liquid phase and a solid phase, formed by a plurality of CO2 particles.
- the extruder functions to remove the concentrated slurry out of the crystallization chamber, compact the solids in the concentrated slurry ( 140 ) and also functions as separator, at is separates the solid phase from the liquid phase (creating the CO2 enriched solid product and the methane enriched liquid hydrocarbon stream).
- An extruder removes the concentrated slurry by exerting a mechanical force (extrusion force) which pushes the solid phase particles present in the concentrated slurry together to form larger CO2 particles, CO2 chunks or a (semi) continuous solid CO2 product stream, which can be relatively easy separated from the liquid.
- the extrusion force squeezes out the liquid present in the concentrated slurry, e.g. via holes or filters in the housing of the extruder.
- any type of suitable extruder may be used, in particular a screw extruder.
- the extruder comprises an extruder outlet 155 and the extruder is orientated such that the extruder outlet 155 is at a gravitational lower level of the extruder.
- FIGS. 1 a -1 b schematically depict embodiments of a method and system to separate CO2 from a contaminated hydrocarbon-containing stream
- FIG. 2 schematically depicts an embodiment of a method and system for performing a method of liquefying a contaminated hydrocarbon-containing gas stream using the embodiment depicted in FIG. 1 b.
- FIGS. 1 a and 1 b depict a method and system to separate CO2 from a contaminated hydrocarbon-containing stream.
- a contaminated hydrocarbon-containing gas stream 10 is provided.
- the contaminated hydrocarbon-containing gas stream is not particularly limited, it preferably is a methane-rich gas stream such as natural gas.
- the contaminated hydrocarbon-containing gas stream 10 comprises at least 50 mol % methane, preferably at least 80 mol %.
- the hydrocarbon fraction of the contaminated hydrocarbon-containing gas stream 10 comprises especially at least 75 mol % of methane, preferably at least 90 mol %.
- the hydrocarbon fraction in the natural gas stream may suitably contain from between 0 and 25 mol % of C 2+ -hydrocarbons (i.e.
- hydrocarbons containing 2 or more carbon atoms per molecule preferably between 0 and 20 mol % of C 2 -C 6 hydrocarbons, more preferably between 0.3 and 18 mol % of C 2 -C 4 hydrocarbons, especially between 0.5 and 15 mol % of ethane.
- the contaminant comprises CO2 and possibly comprises further contaminants, such as H 2 S, H 2 O, C 6+ hydrocarbons, aromatic compounds.
- the amount of contaminant in the contaminated hydrocarbon-containing gas stream 10 is suitably between 0.5 and 50 mol %, typically above 1.0 mol % and below 20 mol %.
- the amount of CO2-contaminant in the contaminated hydrocarbon-containing gas stream is typically between 0.02 mol %-15 mol % of the contaminated hydrocarbon-containing gas stream, preferably in the range 0.02 mol %-5 mol %, more preferably in the range 0.1 mol %-5 mol %, and even more preferably in the range 0.2 mol %-3 mol %, e.g. 2 mol %.
- FIGS. 1 a and 1 b From the contaminated hydrocarbon-containing gas stream 10 a multiphase contaminated hydrocarbon-containing stream 100 is obtained. This is only schematically depicted in FIGS. 1 a and 1 b as this may be done in different ways as will be appreciated by the skilled person. A more detailed example will be described below with reference to FIG. 2 .
- the multiphase contaminated hydrocarbon-containing stream 100 contains at least a liquid phase and a solid phase, the solid phase comprising CO2 particles, the CO2 particles typically having an average size smaller than 50 micron, for instance smaller than 20 micron.
- the multiphase contaminated hydrocarbon-containing stream 100 may further comprise a vapour phase.
- the multiphase contaminated hydrocarbon-containing stream 100 Downstream of the valve, at lower pressure and temperature, the multiphase contaminated hydrocarbon-containing stream 100 is oversaturated with CO2.
- the CO2 in excess over the solubility will escape the liquid phase by crystallizing into a solid phase, forming a stable system at prevailing conditions.
- the formation of solid particles will start rapidly, but a certain amount of time is required before the system approaches steady state conditions, dependent on CO2 concentration, pressure and temperature, as can be appreciated by the person skilled in the art.
- FIGS. 1 a -1 b further show an optional separator 7 (shown with dashed lines), a solid-liquid separator 9 comprising a crystallization chamber 91 , an extruder 140 and a feedback conduit 141 .
- the multiphase contaminated hydrocarbon-containing stream 100 may be passed directly to the solid-liquid separator 9 as slurry stream 120 .
- a slurry comprises a liquid and a solid phase.
- the method may comprise
- the slurry stream may then be passed on to the solid-liquid separator 9 .
- the separator 7 may comprise an inlet being in fluid communication with the conduit ( 100 ) to receive multiphase contaminated hydrocarbon-containing stream, the separator ( 7 ) further comprising a first outlet for a gaseous stream ( 110 ) and a second outlet for a slurry stream ( 120 ).
- separator 7 and solid-liquid separator 9 are shown and described as separate vessels connected by a down-comer 123 , it will be understood that the separator 7 and solid-liquid separator 9 may also be embodied as a single vessel comprising separator 7 and solid-liquid separator 9 .
- the separator ( 7 ) as used in step (a′) may be a cyclone separator or a horizontal gravity based separator vessel.
- a cyclone separator the stream is brought in rotation such that the heavier components are forced outwardly and can be separated from the lighter components to form the gaseous stream ( 110 ) and a slurry stream ( 120 ).
- cyclone separator Any suitable type of cyclone separator may be used aimed for gas/liquid separation, including a (Gasunie) cyclone or an open vertical vessel with a tangential inlet.
- a (Gasunie) cyclone or an open vertical vessel with a tangential inlet.
- the crystallization chamber ( 91 ) is a gravity based separator vessel.
- the gravity based separator vessel may be an open vessel.
- the gravity based separator vessel is positioned vertically, but a horizontal gravity based separator vessel may be used as well.
- the terms vertical and horizontal are used here to refer to the orientation of the longitudinal body axis, such as the cylindrical body axis of the vessel.
- the slurry stream 120 obtained from the multiphase contaminated hydrocarbon-containing stream 100 is fed into the crystallization vessel 91 at the top via a slurry inlet 120 .
- the crystallization chamber 91 may comprise a stirring device to prevent the slurry from solidifying completely and/or to favour conditions to optimize crystal growth.
- the slurry inlet 120 is formed by a down-comer 123 having a discharge opening 124 , which, in use, is submerged into the slurry contained in the crystallization vessel 91 .
- the down-comer 123 has its discharge opening 123 positioned below or above the slurry contained in the crystallization vessel.
- Liquid is separated from the crystallization vessel 91 over a weir 92 and is discharged as liquid hydrocarbon stream 170 .
- the discharge opening 124 of the down-comer 123 may be positioned at a gravitational level above or below a top edge of the weir 92 .
- the slurry inlet ( 120 ) is formed by a downcomer 123 with a discharge opening ( 124 ), the solid-liquid separator ( 9 ) comprises a weir ( 92 ) having an upper edge positioned at a level gravitational above or below the discharge opening ( 124 ), wherein the fluid outlet ( 174 ) for discharging the liquid hydrocarbon stream ( 170 ) from the crystallization chamber ( 91 ) is positioned at an opposite side of the weir ( 92 ) than the discharge opening ( 124 ) of the downcomer ( 124 ).
- the weir separates liquid hydrocarbon from the slurry and the solid CO2 particles.
- the feedback conduit 141 may debouche in the crystallization chamber 91 at a level below the upper edge of the weir 92 .
- step (b2) comprises passing the liquid hydrocarbon stream ( 170 ) to a LNG storage tank. Passing the liquid hydrocarbon stream 170 to the LNG storage tank may be done by a pump 171 .
- the liquid hydrocarbon stream 170 obtained from the crystallization chamber 91 in step (b2) may comprise small CO2-particles, e.g. having an average size smaller than 10 micron. Optionally, these particles may be removed in a polishing step, as described in more detail below.
- the extruder ( 142 ) exerts a mechanical force (extrusion force) on the concentrated slurry ( 140 ) to move concentrated slurry ( 140 ) out of the crystallization chamber ( 91 ) thereby obtaining the CO2 enriched solid product.
- the CO2 enriched solid product may in fact be a stream of compacted CO2 particles, compacted CO2 chunks or a (semi) continuous solid CO2 product stream.
- the CO2 enriched solid product may further comprise a remainder of other process substances such as hydrocarbons.
- the extrusion force drives the concentrated slurry through an opening or die to compact or densify the concentrated slurry, thereby obtaining the CO2 enriched solid product. Due to the extrusion force exerted by the extruder ( 142 ) the CO2 particles group together to form the solid product, which may obtained as a continuous CO2 enriched solid product stream.
- the liquid present in the concentrated slurry is squeezed out of the concentrated slurry 140 thereby obtaining a methane enriched liquid hydrocarbon stream 147 .
- extruder Any suitable extruder may be used, including axial end plate extruders, radial screen extruders, rotary cylinder extruders, ram and piston type extruders and screw extruders.
- the extruder 142 is preferably a screw extruder. Screw extruders employ a screw (actuator) to exert the extrusion force on the concentrated slurry 140 to move concentrated slurry 140 out of the crystallization chamber 91 .
- a screw extruder 142 comprises a screw positioned in a drum (housing).
- the screw comprises a helical ridge wrapped around a shaft.
- the drum is formed by a cylindrical wall. The longitudinal axes of the screw and the drum are aligned.
- the cylindrical wall comprises one or more filters.
- Rotation of the screw employs a force to drive the concentrated slurry and densify the CO2 particles thereby obtaining the CO2 enriched solid product, while the liquid present in the concentrated slurry is squeezed out of the drum via the one or more filters or openings in the drum wall to obtain the methane enriched
- the method further comprises
- the seed particles may be provided to the crystallization chamber directly, or may be provided to the crystallization chamber ( 91 ) indirectly by feeding back the CO2 feedback stream ( 141 ) to a position upstream of the crystallization chamber 91 , in particular to separator 7 or to multiphase contaminated hydrocarbon-containing stream ( 100 ).
- the CO2 feedback stream may comprise the CO2 seed particles ( FIG. 1 a ) or may comprise liquid CO2 where the CO2 seed particles are created upon re-introduction of the feedback stream ( FIG. 1 b ), as will be explained in more detail below.
- a concentrated slurry 140 is formed by removing a liquid hydrocarbon stream 170 and allowing the CO2 to crystallize.
- the concentrated slurry comprises less liquid and larger CO2 particles than the slurry stream 120 obtained from the multiphase contaminated hydrocarbon-containing stream 100 .
- This process is facilitated by providing CO2 seed particles by means of the CO2 feedback stream 141 .
- the seed particles provided in (b5) have an average size greater than 20 micron.
- the seed particles provided in step (b5) may have an average size greater than 50, or even greater than 100 micron.
- the feedback stream that is used to feed seed particles to the crystallization vessel comprises seed particles having an average size greater than 20 micron.
- the average size of the seed particles in the feedback stream 141 is in the range 20 micron-20 mm, more preferably in the range 20 micron-1 mm and more preferably in the range 50 micron-200 micron.
- seed particles are preferably kept small to maximize the surface available for crystallization.
- seed particles having an average size as indicated provide a good balance between crystallization speed (kg/s) on the one hand and ease of separation on the other hand.
- micron is used in this text in line with common practice: 1 micron equals 1 ⁇ 10 ⁇ 6 metre.
- (b4) comprises obtaining a CO2 feedback stream comprising CO2 seed particles and (b5) comprises passing the CO2 feedback stream ( 141 ) into the crystallization chamber ( 91 ) to provide the seed particles to the crystallization chamber ( 91 ).
- This embodiment is shown in FIG. 1 a.
- the CO2 feedback stream comprises seed particles having an average size greater than 20 micron.
- the average size of the seed particles in the feedback stream 141 is in the range 20 micron-20 mm, more preferably in the range 20 micron-1 mm and more preferably in the range 50 micron-200 micron.
- (b4) comprises breaking the solid CO2 obtained in (b3) to form the seed particles.
- the system may comprise a seed particle forming device, such as a scraper, chopper, die or palleting device, arranged to obtain seed particles from the solid CO2 obtained from the extruder, the CO2 seed particles.
- the seed particle forming device may be operated in a vapour atmosphere.
- a scraper may be used in step (b3) arranged to scrape CO2 seed particles from the solid CO2 obtained from the extruder to create a CO2 feedback stream comprising seed particles having the above indicated size.
- the scraper or breaker 148 may be positioned directly downstream of an extruder outlet 155 .
- (b4) comprises adding a carrier fluid, such as a liquid natural gas stream, to the feedback stream ( 141 ).
- a carrier fluid such as a liquid natural gas stream
- the seed particles may be suspended in a carrier fluid.
- the carrier fluid may be a carrier liquid or a carrier gas.
- the carrier fluid is a liquid natural gas stream.
- the carrier fluid may comprise a portion of the liquefied natural gas as produced in the overall process.
- the liquefied natural gas stream added to the feedback stream may be obtained from the liquid hydrocarbon stream 170 obtained from the crystallization chamber 91 in step b2.
- the liquefied natural gas stream added to the feedback stream may also be obtained from the polished liquid hydrocarbon stream 170 ′, as will be discussed in more detail below.
- the volumetric fraction of the seed particles in the suspended feedback stream is in the range 30-70%, preferably in the range 40-60%.
- the CO2 feedback stream comprises liquid CO2 which is fed back by spray-cooling, thereby forming seed particles.
- step (b4) comprises heating at least part of the CO2 enriched solid product thereby creating a liquid CO2 enriched stream, and forming the feedback stream ( 141 ) from at least part of the liquid CO2 enriched stream.
- the extruder 142 compresses the concentrated slurry and increases the pressure to form the CO2 enriched solid product.
- the CO2 enriched solid product is heated to create a liquid CO2 enriched stream, of which a part is taken to form the CO2 feedback stream.
- the CO2 seed particles may be formed from the liquid CO2 enriched stream. According to this embodiment, no carrier fluid is needed.
- Heating may be done by one or more heaters 150 .
- the heater 150 ′ may be positioned downstream of the extruder to heat the part of the CO2 enriched solid product not being passed to the feedback stream 141 .
- the heater 150 may be integrated into the extruder 142 or being positioned adjacent to the extruder 142 .
- the heaters are preferably positioned close to or at the extruder outlet 155 .
- the extruder 142 may be a screw extruder 142 comprising a screw 151 being positioned in a barrel 152 , the barrel comprising a cylindrical wall surrounding the screw.
- the heaters 150 may be integrated in the wall of the barrel at a position at or towards the discharge extruder outlet 155 .
- step (b5) comprises spraying the liquid CO2 enriched stream into a feedback position thereby creating seed particles.
- Spraying may be done by introducing the liquid CO2 enriched stream via one or more spraying nozzles 158 .
- the liquid CO2 droplets expand to a state where the liquid phase does not exist. Almost all CO2 will solidify. Due to the high local CO2 concentration, the resulting CO2 solid size will be closely correlating to the CO2 droplet size.
- the seed particle size can be adjusted to the preferred value.
- the spraying nozzles comprise a plurality of nozzle openings. By selecting the amount of nozzle openings and size of the nozzle openings the size of the CO2 droplets and thus of the CO2 seed particles provided may be controlled.
- step (b5) further comprises processing the liquid CO2 enriched stream to form the CO2 seed particles and feeding back the CO2 seed particles by passing the CO2 seed particles to the crystallization chamber ( 91 ) or to a position upstream of the crystallization chamber ( 91 ) to provide seed particles.
- the liquid CO2 stream may be converted into a stream comprising of solid CO2 parcels and a transport medium, such as liquid or gaseous hydrocarbons.
- a transport medium such as liquid or gaseous hydrocarbons.
- an expansion step into gas/solid is deployed, followed by compression into pellets of the desired size.
- liquid hydrocarbon stream 170 obtained from the crystallization chamber 91 in (b2) may comprise small CO2-particles.
- (b2) further comprises subjecting the liquid hydrocarbon stream ( 170 ) obtained from the crystallization chamber to a polishing treatment ( 172 ) to obtain a polished liquid hydrocarbon stream ( 170 ′) and a residue stream ( 175 ), wherein method further comprises
- the optional polishing treatment serves the purpose of removing any remaining small solids from the liquid hydrocarbon stream ( 170 ), in particular any residual CO2 particles that may have ended up in the liquid hydrocarbon stream.
- the polished liquid hydrocarbon stream comprises less CO2 particles than the liquid hydrocarbon stream as obtained from the crystallization chamber 91 .
- the residue stream 175 may be recycled, such as by combining the residue stream 175 with one of the multiphase contaminated hydrocarbon-containing stream 100 , the feedback stream, the concentrated slurry stream obtained from the crystallization chamber 91 .
- the residue stream may function as carrier fluid for the feedback stream.
- the residue stream 175 may also be recycled by introducing the residue stream 175 into one of the separator 7 , the crystallization vessel 91 or any other suitable vessel or stream upstream of separator 7 .
- the polishing treatment may be any kind of suitable polishing treatment, including passing the liquid hydrocarbon stream through a filter, such as a band filter or HEPA filter, or passing the liquid hydrocarbon stream through static separation equipment, such as (parallel) desanding cyclones or one or more (parallel) hydroclones 172 , from which the residue stream is obtained from the one or more bottom streams and the polished liquid hydrocarbon stream is obtained by combining the one or more top streams.
- a filter such as a band filter or HEPA filter
- static separation equipment such as (parallel) desanding cyclones or one or more (parallel) hydroclones 172 , from which the residue stream is obtained from the one or more bottom streams and the polished liquid hydrocarbon stream is obtained by combining the one or more top streams.
- Passing the liquid hydrocarbon stream 170 to the LNG storage tank may comprise passing the liquid hydrocarbon stream through a pressure reduction stage, e.g. formed by a throttle vale 173 and/or an end flash vessel.
- a pressure reduction stage e.g. formed by a throttle vale 173 and/or an end flash vessel.
- the method further comprises obtaining a venting stream ( 121 ) from the crystallization chamber ( 91 ).
- the separator 7 and the solid-liquid separator 9 may operate at substantial equal pressure.
- a vent line ( 121 ) may be provided to allow such a flow. This is in particular the case in embodiments wherein the downcomer debouches under the liquid or slush level in the solid-liquid separator 9 .
- the crystallization chamber ( 91 ) may comprise an overhead venting outlet ( 122 ).
- a venting conduit may be provided which is with one end in fluid communication with the venting outlet and with an other end in fluid communication with the separator 7 to feedback the venting stream to the separator.
- the venting outlet is preferably positioned in a top part of the crystallization chamber.
- Gas may escape from the slurry stream after having been fed to the crystallization chamber.
- the venting stream may be passed to the separator ( 7 ) of step (a′) via the venting conduit.
- the venting stream may be combined with the gaseous stream 110 obtained in (a′).
- connection is made to the extruder, in particular a screw extruder. Connection between the extruder and the crystallization vessel can be made by any method known in the art.
- a portion of the concentrated slurry ( 140 ) removed from the crystallization chamber ( 91 ) not being part of the feedback stream ( 141 ) is liquefied by heating (by means of a heater downstream of the extruder 142 or by means of an integrated heater (integrated into the extruder) thereby obtaining a liquefied concentrated stream ( 144 ) and the liquefied concentrated stream ( 144 ) is
- the gaseous hydrocarbon enriched top stream obtained from the flash vessel may be combined with a fuel gas stream.
- step (b3) the concentrated slurry 140 is removed from the crystallization chamber 91 by means of an extruder 142 , thereby obtaining solid CO2.
- concentrated slurry is used to indicate that the density and viscosity of the concentrated slurry is higher than the density and viscosity of the slurry as comprised by the slurry stream received from separator 7 .
- the extruder is in fluid communication with a lower part of the crystallization chamber 91 , preferably with a lowest part of the crystallization chamber 91 such that under the influence of gravity, the extruder receives a relatively dense portion of the concentrated slurry 140 .
- the extruder mechanically forces the concentrated slurry 140 out of the crystallization chamber 91 , pushing the CO2 particles together and pushing liquids out of the concentrated slurry creating solid CO2, preferably in the form of a continuous solid CO2 stream and a methane enriched liquid hydrocarbon stream 147 .
- the extruder comprises a housing, the housing comprising at least one opening for discharging the methane enriched liquid hydrocarbon stream ( 147 ).
- the housing comprises an extruder outlet 155 for discharging the CO2 enriched solid product and at least one opening for discharging the methane enriched liquid hydrocarbon stream ( 147 ).
- the one or more openings may comprise filters allowing the methane enriched liquid hydrocarbon through but not allowing the CO2 enriched solid product through.
- Step (b3) then comprises obtaining the methane enriched liquid hydrocarbon stream ( 147 ) from the extruder ( 142 ) via the at least one opening for discharging the methane enriched liquid hydrocarbon stream ( 147 ).
- the housing forms a flow path from an extruder inlet being in fluid communication with a concentrated slurry outlet ( 145 ) of the crystallization chamber ( 91 ) to the extruder outlet ( 155 ), the extruder comprising an actuator being at least partially positioned in the housing to mechanically push the concentrated slurry ( 140 ) from the crystallization chamber ( 91 ) towards the extruder outlet, wherein the housing comprises one openings for discharging the methane enriched liquid hydrocarbon stream ( 147 ).
- the at least one opening for discharging the methane enriched liquid hydrocarbon stream ( 147 ) is preferably in fluid communication with a conduit carrying the liquid hydrocarbon stream ( 170 ) obtained in step (b2) from the crystallization chamber 91 , the method thus comprising combining the methane enriched liquid hydrocarbon stream ( 147 ) and the liquid hydrocarbon stream ( 170 ) obtained in step (b2) from the crystallization chamber 91 .
- FIG. 2 shows an embodiment of how the method and system as described above with reference to FIG. 1 b may be embedded in a process/liquefaction scheme generally referred to with reference number 1 .
- the process scheme 1 comprises a compressor 2 , a heat exchanger 3 (“the first heat exchanger”), an expander 4 , a first separator 5 , a JT-valve 6 , a second separator 7 , an LNG storage tank 11 , further compressors 13 and 14 , a second heat exchanger 15 , an expander 16 and an optional methanol separator 17 .
- the process scheme may comprise further heat exchangers in addition to the first heat exchanger 3 and second heat exchanger 15 .
- the first heat exchanger 3 and second heat exchanger 15 are separate heat exchangers.
- a contaminated hydrocarbon-containing gas stream 10 is provided which is compressed in compressor 2 .
- the compressed contaminated hydrocarbon-containing gas stream 20 is cooled (as stream 30 ) in the first heat exchanger 3 thereby obtaining a cooled contaminated hydrocarbon-containing gas stream 40 .
- the first heat exchanger 3 is (like the second heat exchanger 15 ) an indirect heat exchanger; hence no direct contact between the streams takes place, but only heat exchanging contact.
- the cooled contaminated hydrocarbon-containing stream 40 is passed to the methanol separator 17 to separate methanol (as stream 50 ) that has been previously injected (e.g. into stream 20 ) to prevent hydrate formation.
- the (methanol-depleted) cooled contaminated hydrocarbon-containing gas stream is further cooled as stream 60 in the expander 4 thereby obtaining a partially liquefied stream 70 .
- This partially liquefied stream 70 is separated in separator 5 thereby obtaining a gaseous stream 80 and a liquid stream 90 .
- the liquid steam 90 is expanded in JT-valve 6 thereby obtaining the multiphase contaminated hydrocarbon-containing stream 100 as described above which is passed to the separator 7 .
- the gaseous stream 80 is passed through the first heat exchanger 3 thereby obtaining a heated gaseous stream 270 ; if desired some inerts (such as N 2 ) may be removed from the heated gaseous stream 270 as (minor) stream 280 . As stream 80 is used to cool the stream 30 , this is an “auto-refrigeration” step.
- the heated gaseous stream 270 is compressed in compressor 13 thereby obtaining a compressed gas stream 220 .
- Part 230 of the compressed gas stream 220 is combined with the contaminated hydrocarbon-containing gas stream 20 .
- a part 240 of the compressed gas stream 220 is passed through the second heat exchanger 15 (and cooled therein) thereby obtaining a cooled compressed gas stream 250 .
- the cooled compressed gas stream 250 is expanded in expander 16 thereby obtaining an expanded an expanded gas stream 260 .
- the expanded gas stream 260 is combined with the gaseous stream 80 to form stream 265 .
- the gaseous stream 110 is passed as stream 190 through the second heat exchanger 15 thereby obtaining a second heated gaseous stream 200 .
- the second heated gaseous stream 200 is compressed in compressor 14 thereby obtaining a second compressed gas stream 210 ; this second compressed gas stream 210 is combined with the heated gaseous stream 270 (to form stream 215 ).
- a boil-off gas stream 180 is obtained from the LNG storage tank 11 which may be combined with the gaseous stream 110 obtained from separator 7 (in step (a′)).
- step (a) comprises
- step (a5) expanding the liquid steam ( 90 ) obtained in step (a4) thereby obtaining the multiphase contaminated hydrocarbon-containing stream ( 100 ), the multiphase contaminated hydrocarbon-containing stream ( 100 ) containing at least a liquid phase and a solid phase, wherein the solid phase comprises CO2 particles.
- the multiphase contaminated hydrocarbon-containing stream ( 100 ) may comprise a vapour phase.
- the liquid hydrocarbon product stream obtained in step (a4) may contain more CO 2 than the partially liquefied stream, such as at least 250 ppm-mol, and may comprise more C 5+ , such as at least 0.1 mol %.
- the method further comprises
- step (d) passing the gaseous stream ( 80 ) obtained in step (a4) through the first heat exchanger ( 3 ) thereby obtaining a heated gaseous stream ( 270 );
- step (f) combining the compressed gas stream ( 220 ) obtained in step (e) with the contaminated hydrocarbon-containing gas stream ( 20 ) provided in step (a1).
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15197896.2 | 2015-12-03 | ||
EP15197896 | 2015-12-03 | ||
PCT/EP2016/079403 WO2017093387A1 (en) | 2015-12-03 | 2016-12-01 | Method of removing co2 from a contaminated hydrocarbon stream |
Publications (1)
Publication Number | Publication Date |
---|---|
US20180259251A1 true US20180259251A1 (en) | 2018-09-13 |
Family
ID=55077330
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/779,652 Abandoned US20180259251A1 (en) | 2015-12-03 | 2016-12-01 | Method of removing co2 from a contaminated hydrocarbon stream |
Country Status (8)
Country | Link |
---|---|
US (1) | US20180259251A1 (ru) |
EP (1) | EP3384217A1 (ru) |
CN (1) | CN108291769B (ru) |
AU (1) | AU2016363739B2 (ru) |
BR (1) | BR112018010975A2 (ru) |
CA (1) | CA3006784A1 (ru) |
RU (1) | RU2731426C2 (ru) |
WO (1) | WO2017093387A1 (ru) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10329182B2 (en) * | 2016-12-20 | 2019-06-25 | Sustainable Energy Solutions, Llc | Method for separating solids suspended or entrained in a liquid |
US10704830B2 (en) * | 2018-01-24 | 2020-07-07 | Gas Technology Development Pte Ltd | Process and system for reliquefying boil-off gas (BOG) |
US11697114B2 (en) | 2015-12-11 | 2023-07-11 | Babson Diagnostics, Inc. | Centrifugation method separating serum or plasma from whole blood using a specimen container having a cap to retain blood cells |
US12025629B2 (en) | 2023-04-14 | 2024-07-02 | Babson Diagnostics, Inc. | Automated centrifuge loader |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113082983B (zh) * | 2021-04-19 | 2022-02-15 | 大连理工大学 | 一种基于气体节流技术的连续式水合物法分离二氧化碳和氢气的系统 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6581409B2 (en) * | 2001-05-04 | 2003-06-24 | Bechtel Bwxt Idaho, Llc | Apparatus for the liquefaction of natural gas and methods related to same |
JP2005515298A (ja) * | 2002-01-18 | 2005-05-26 | カーティン ユニバーシティ オブ テクノロジー | 凝固性固形物を除去することによりlngを製造する方法および装置 |
WO2007030888A1 (en) * | 2005-09-15 | 2007-03-22 | Cool Energy Limited | Process and apparatus for removal of sour species from a natural gas stream |
FR2899320B1 (fr) * | 2006-04-03 | 2008-05-16 | Air Liquide | Dispositif et procede d'emballage de neige carbonique dans un film plastique |
WO2010023238A1 (en) * | 2008-08-29 | 2010-03-04 | Shell Internationale Research Maatschappij B.V. | Process and apparatus for removing gaseous contaminants from gas stream comprising gaseous contaminants |
CA2748128C (en) * | 2008-12-22 | 2018-06-05 | Twister B.V. | Method of removing carbon dioxide from a fluid stream and fluid separation assembly |
AU2010204309A1 (en) * | 2009-01-08 | 2011-07-14 | Shell Internationale Research Maatschappij B.V. | Process and apparatus for separating a gaseous product from a feed stream comprising contaminants |
CN103237585A (zh) * | 2010-10-26 | 2013-08-07 | 国际壳牌研究有限公司 | 从含ch4的气态进料物流中分离污染物或污染物混合物的方法 |
CN102620523B (zh) * | 2012-04-16 | 2014-10-15 | 上海交通大学 | 带凝华脱除co2的混合制冷剂循环天然气带压液化工艺 |
CN102628635B (zh) * | 2012-04-16 | 2014-10-15 | 上海交通大学 | 带凝华脱除co2的气体膨胀天然气带压液化工艺 |
WO2014026712A1 (en) * | 2012-08-15 | 2014-02-20 | Statoil Petroleum As | System and method for removing carbon dioxide from a natural gas stream and the use thereof |
US9683777B2 (en) * | 2012-10-08 | 2017-06-20 | Exxonmobil Upstream Research Company | Separating carbon dioxide from natural gas liquids |
EP2789957A1 (en) * | 2013-04-11 | 2014-10-15 | Shell Internationale Research Maatschappij B.V. | Method of liquefying a contaminated hydrocarbon-containing gas stream |
-
2016
- 2016-12-01 US US15/779,652 patent/US20180259251A1/en not_active Abandoned
- 2016-12-01 WO PCT/EP2016/079403 patent/WO2017093387A1/en active Application Filing
- 2016-12-01 RU RU2018123854A patent/RU2731426C2/ru active
- 2016-12-01 AU AU2016363739A patent/AU2016363739B2/en not_active Ceased
- 2016-12-01 EP EP16805787.5A patent/EP3384217A1/en not_active Withdrawn
- 2016-12-01 BR BR112018010975A patent/BR112018010975A2/pt not_active Application Discontinuation
- 2016-12-01 CA CA3006784A patent/CA3006784A1/en not_active Abandoned
- 2016-12-01 CN CN201680070472.1A patent/CN108291769B/zh not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11697114B2 (en) | 2015-12-11 | 2023-07-11 | Babson Diagnostics, Inc. | Centrifugation method separating serum or plasma from whole blood using a specimen container having a cap to retain blood cells |
US10329182B2 (en) * | 2016-12-20 | 2019-06-25 | Sustainable Energy Solutions, Llc | Method for separating solids suspended or entrained in a liquid |
US10704830B2 (en) * | 2018-01-24 | 2020-07-07 | Gas Technology Development Pte Ltd | Process and system for reliquefying boil-off gas (BOG) |
US12025629B2 (en) | 2023-04-14 | 2024-07-02 | Babson Diagnostics, Inc. | Automated centrifuge loader |
Also Published As
Publication number | Publication date |
---|---|
AU2016363739A1 (en) | 2018-06-07 |
BR112018010975A2 (pt) | 2018-12-04 |
EP3384217A1 (en) | 2018-10-10 |
CA3006784A1 (en) | 2017-06-08 |
CN108291769B (zh) | 2020-09-15 |
CN108291769A (zh) | 2018-07-17 |
WO2017093387A1 (en) | 2017-06-08 |
RU2731426C2 (ru) | 2020-09-02 |
AU2016363739B2 (en) | 2019-09-19 |
RU2018123854A3 (ru) | 2020-04-14 |
RU2018123854A (ru) | 2020-01-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2016363739B2 (en) | Method of removing CO2 from a contaminated hydrocarbon stream | |
AU2009286701B2 (en) | Process and apparatus for removing gaseous contaminants from gas stream comprising gaseous contaminants | |
USRE39826E1 (en) | Comprehensive natural gas processing | |
CA2239758C (fr) | Procede de degazolinage d'un gaz contenant des hydrocarbures condensables | |
US20110123432A1 (en) | Hydrate formation for gas separation or transport | |
JP2005515298A (ja) | 凝固性固形物を除去することによりlngを製造する方法および装置 | |
EP2486224B1 (en) | System and method for hydrocarbon removal and recovery from drill cuttings | |
EP3672710B1 (en) | Integration of cold solvent and acid gas removal | |
US11000797B2 (en) | Integration of cold solvent and acid gas removal | |
JP2002540223A (ja) | 水和物の生成、処理、輸送及び貯蔵 | |
TW201531456A (zh) | 藉由分離技術處理二甲醚反應器之產物流的方法 | |
CN108291766B (zh) | 液化co2污染的含烃气流的方法 | |
CN210048683U (zh) | 一种从混合气中回收乙烷的系统 | |
RU2003118273A (ru) | Способ очистки от углеводородов парогазовой среды, образующей при хранении нефтепродукта и при заполнении им емкости (варианты) и установка для его осуществления | |
AU2016363566B2 (en) | Method of liquefying a contaminated hydrocarbon-containing gas stream | |
AU2015202653B2 (en) | Method for hydrocarbon removal and recovery from drill cuttings | |
EP3976224A1 (en) | A system and method for handling a multiple phase hydrocarbon feed | |
RU2182266C1 (ru) | Способ сжатия и разделения газообразной углеводородосодержащей среды и насосно-эжекторная установка для осуществления способа | |
FR2512013A1 (fr) | Procede perfectionne de fabrication d'ethylene purifie par distillation thermocouplee et installation de production d'ethylene comportant application de ce procede |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STPP | Information on status: patent application and granting procedure in general |
Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION |
|
AS | Assignment |
Owner name: SHELL OIL COMPANY, TEXAS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:VAN AKEN, MICHIEL GIJSBERT;VAN CAMPEN, LAURENS JOSEPH ARNOLD MARIE;VAN SANTEN, HELMAR;SIGNING DATES FROM 20180107 TO 20180706;REEL/FRAME:046472/0684 |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NOTICE OF ALLOWANCE MAILED -- APPLICATION RECEIVED IN OFFICE OF PUBLICATIONS |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NOTICE OF ALLOWANCE MAILED -- APPLICATION RECEIVED IN OFFICE OF PUBLICATIONS |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO PAY ISSUE FEE |