US20180138255A1 - Electroluminscent display device and method of fabricating the same - Google Patents
Electroluminscent display device and method of fabricating the same Download PDFInfo
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- US20180138255A1 US20180138255A1 US15/808,435 US201715808435A US2018138255A1 US 20180138255 A1 US20180138255 A1 US 20180138255A1 US 201715808435 A US201715808435 A US 201715808435A US 2018138255 A1 US2018138255 A1 US 2018138255A1
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- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/121—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements
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- H01L27/15—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components having potential barriers, specially adapted for light emission
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- G09G3/20—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters
- G09G3/22—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources
- G09G3/30—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels
- G09G3/32—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED]
- G09G3/3208—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED] organic, e.g. using organic light-emitting diodes [OLED]
- G09G3/3225—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED] organic, e.g. using organic light-emitting diodes [OLED] using an active matrix
- G09G3/3233—Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix no fixed position being assigned to or needed to be assigned to the individual characters or partial characters using controlled light sources using electroluminescent panels semiconductive, e.g. using light-emitting diodes [LED] organic, e.g. using organic light-emitting diodes [OLED] using an active matrix with pixel circuitry controlling the current through the light-emitting element
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
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- H—ELECTRICITY
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- H—ELECTRICITY
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- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
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- H10K2102/351—Thickness
Definitions
- the present disclosure relates to a display device, and more particularly, to an electroluminescent display device being capable of providing a uniform brightness and a high display quality and a method of fabricating the same.
- an electroluminescent display device may be formed on a flexible substrate such as a plastic substrate.
- the electroluminescent display device since the electroluminescent display device is a self-emission type, the electroluminescent display device has excellent characteristics in contrast ratio, a viewing angle, a thin profile, a response time, a thermal stability, and so on.
- the electroluminescent display device may be referred to as a light emitting display device.
- the electroluminescent display device may include an anode as a hole injection electrode, a cathode as an electron injection electrode and an emitting layer between the anode and the cathode. The hole from the anode and the electron from the cathode are combined in the emitting layer to form an exciton, and the light is emitted from the emitting layer by a radiative recombination of the exciton.
- FIG. 1 is a schematic view showing an energy band diagram of the related art electroluminescent display device.
- the electroluminescent display device includes an anode 1 , a cathode 7 and an emitting material layer (EML) 4 between the anode 1 and the cathode 7 .
- EML emitting material layer
- the electroluminescent display device may further include a hole transporting layer (HTL) 3 between the anode 1 and the EML 4 and an electron transporting layer (ETL) 5 between the cathode 7 and the EML 4 .
- HTL hole transporting layer
- ETL electron transporting layer
- the electroluminescent display device may further include a hole injection layer (HIL) 2 between the anode 1 and the HTL 3 and an electron injection layer (EIL) 6 between the cathode and the ETL 5 .
- HIL hole injection layer
- EIL electron injection layer
- the hole “h+” provided from the anode 1 into the EML 4 through the HIL 2 and the HTL 3 and the electron “e-” provided from the cathode 7 into the EML 4 through the EIL 6 and the ETL 5 are combined to form an exciton, and the light having a color in correspondence to a band gap of the EML 4 is provided from the exciton.
- the EML 4 , the HIL 2 , the HTL 3 , the ETL 5 and the EIL 6 may be formed by a vacuum thermal evaporation process using a fine metal mask.
- the production cost of the electroluminescent display device is increased by the vacuum thermal evaporation process, and the application of the vacuum thermal evaporation process for the large size and high resolution electroluminescent display device is difficult because of a deviation problem of the mask, a deformation problem of the mask, a shadow effect in the mask, and so on.
- the solution process for the emitting layer is introduced.
- a nozzle of an injection apparatus is scanned along a direction to drop an emitting material in a pixel region surrounding by a bank.
- the emitting material is dried to form the emitting layer.
- the emitting layer formed by the solution process may have a non-uniform thickness. Namely, in a cross-section, the emitting layer may have a “U” shape or a “W” shape.
- the electroluminescent display device which includes the emitting layer having a non-uniform thickness, provides a non-uniform emission. Accordingly, in the electroluminescent display device, the brightness becomes non-uniform, and the display quality is degraded.
- the present invention is directed to an electroluminescent display device and a method of fabricating the same that substantially obviate one or more of the problems due to limitations and disadvantages of the related art.
- An object of the present invention is to provide an electroluminescent device that has a uniform brightness and a high display quality.
- an electroluminescent display device includes a substrate including first to third pixel regions, the second and third pixel regions being adjacent to the first pixel region along a first direction and a second direction, respectively; an insulating layer over the substrate and including a groove between the first and second pixel regions; a first electrode on the insulating layer and in each of the first to third pixel regions; a bank covering an edge of the first electrode and disposed between the first pixel region and the second pixel region and between the first pixel region and the third pixel region; an emitting layer on the first electrode; and a second electrode on the emitting layer, wherein the bank disposed between the first and second pixel regions has a first height from the first electrode and the bank disposed between the first and third pixel regions has a second height from the first electrode, and the first height is smaller than the second height.
- an electroluminescent display device in another aspect, includes a substrate including first to third pixel regions, the second and third pixel regions being adjacent to the first pixel region along a first direction and a second direction, respectively; a first electrode in each of the first to third pixel regions; a bank covering an edge of the first electrode and disposed between the first pixel region and the second pixel region and between the first pixel region and the third pixel region; an emitting layer on the first electrode; and a second electrode on the emitting layer, wherein a portion of a bottom surface of the bank between the first pixel region and the second pixel region is disposed lower than a portion of a bottom surface of the bank between the first pixel region and the third pixel region.
- FIG. 1 is a schematic view showing an energy band diagram of the related art electroluminescent display device.
- FIG. 2 is a schematic circuit diagram of an electroluminescent display device according to an embodiment of the present invention.
- FIG. 3 is a schematic cross-sectional view of an electroluminescent display device according to an embodiment of the present invention.
- FIG. 4 is a schematic plane view of an electroluminescent display device according to a first embodiment of the present invention.
- FIG. 5 is a schematic cross-sectional view taken along the line V-V of FIG. 4 .
- FIG. 6 is a schematic cross-sectional view taken along the line VI-VI of FIG. 4 .
- FIG. 7 is a schematic cross-sectional view taken along the line VII-VII of FIG. 4 .
- FIG. 8 is a schematic plane view of an electroluminescent display device according to a second embodiment of the present invention.
- FIG. 9 is a schematic cross-sectional view of an electroluminescent display device according to a third embodiment of the present invention.
- FIG. 10 is a schematic cross-sectional view of an electroluminescent display device according to a fourth embodiment of the present invention.
- FIG. 11 is a schematic cross-sectional view of an electroluminescent display device according to a fifth embodiment of the present invention.
- FIG. 12 is a schematic cross-sectional view of an electroluminescent display device according to a sixth embodiment of the present invention.
- FIGS. 13A to 13C are schematic cross-sectional view illustrating a fabricating process of a portion of an electroluminescent display device according to the sixth embodiment of the present invention.
- FIG. 14 is a schematic plane view of an electroluminescent display device according to a seventh embodiment of the present invention.
- FIG. 15 is a schematic cross-sectional view taken along the line XV-XV of FIG. 14 .
- FIG. 16 is a schematic cross-sectional view taken along the line XVI-XVI of FIG. 14 .
- FIG. 2 is a schematic circuit diagram of an electroluminescent display device according to the present invention. All components of the electroluminescent display device according to all embodiments of the present invention are operatively coupled and configured.
- a gate line GL and a data line DL are formed, and a pixel region P is defined by the gate and data lines GL and DL.
- a switching thin film transistor (TFT) Ts In the pixel region P, a switching thin film transistor (TFT) Ts, a driving TFT Td, a storage capacitor Cst and a light emitting diode D are formed.
- TFT switching thin film transistor
- a gate electrode of the switching TFT Ts is connected to the gate line GL, and a source electrode of the switching TFT Ts is connected to the data line DL.
- a gate electrode of the driving TFT Td is connected to a drain electrode of the switching TFT Ts, and a source electrode of the driving TFT Td is connected to a high voltage supply VDD.
- An anode of the light emitting diode D is connected to a drain electrode of the driving TFT Td, and a cathode of the light emitting diode D is connected to a low voltage supply VSS.
- the storage capacitor Cst is connected to a gate electrode and the drain electrode of the driving TFT Td.
- the switching TFT Ts when the switching TFT Ts is turned on by a gate signal applied through the gate line GL, a data signal from the data line DL is applied to a gate electrode of the driving TFT Td and an electrode of the storage capacitor Cst through the switching TFT Ts.
- the driving TFT Td When the driving TFT Td is turned on by the data signal, an electric current is supplied to the light emitting diode D from the high voltage supply VDD through the driving TFT Td. As a result, the light emitting diode D emits light. Since the current in the light emitting diode D is proportional to the data signal and the light intensity emitted from the light emitting diode D is proportional to the current in the light emitting diode D, the pixel region P provide a gray scale according to the data signal.
- the storage capacitor Cst serves to maintain the voltage of the gate electrode of the driving TFT Td for one frame. Accordingly, the electroluminescent display device displays images.
- FIG. 3 is a schematic cross-sectional view of an electroluminescent display device according to the present invention.
- a semiconductor layer 122 is formed on an insulating substrate 110 .
- the substrate 110 may be a glass substrate or a flexible substrate of a polymer.
- the substrate 110 may be a polyimide substrate.
- the semiconductor layer 122 may be formed of an oxide semiconductor material or a poly-silicon.
- a light-shielding pattern may be formed under the semiconductor layer 122 .
- the light radiated to the semiconductor layer 122 is shielded or blocked by the light-shielding pattern such that thermal degradation of the semiconductor layer 122 can be prevented.
- a buffer layer may be formed between the substrate 110 and the semiconductor layer 122 .
- impurities may be doped into both sides of the semiconductor layer 122 of polycrystalline silicon.
- a gate insulating layer 130 is formed on the semiconductor layer 122 .
- the gate insulating layer 130 may be formed of an inorganic insulating material such as silicon oxide or silicon nitride.
- a gate electrode 132 which is formed of a conductive material, e.g., metal, is formed on the gate insulating layer 130 to correspond to a center of the semiconductor layer 122 .
- the gate line and a first capacitor electrode may be formed on the gate insulating layer 130 .
- the gate line extends along a direction, and the first capacitor electrode is connected to the gate electrode 132 .
- the gate insulating layer 130 is formed on the entire surface of the substrate 110 .
- the gate insulating layer 130 may be patterned to have the same shape as the gate electrode 132 .
- An interlayer insulating layer 140 which is formed of an insulating material, is formed on an entire surface of the substrate 110 including the gate electrode 132 .
- the interlayer insulating layer 140 may be formed of an inorganic insulating material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl.
- the interlayer insulating layer 140 includes first and second contact holes 140 a and 140 b exposing both sides of the semiconductor layer 122 .
- the first and second contact holes 140 a and 140 b are positioned at both sides of the gate electrode 132 to be spaced apart from the gate electrode 132 .
- the first and second contact holes 140 a and 140 b are formed in the gate insulating layer 130 and the interlayer insulating layer 140 .
- the gate insulating layer 130 is patterned to have the same shape as the gate electrode 132
- the first and second contact holes 140 a and 140 b are formed in the interlayer insulating layer 140 .
- a source electrode 152 and a drain electrode 154 which are formed of a conductive material, e.g., metal, are formed on the interlayer insulating layer 140 .
- the data line, a power line and a second capacitor electrode may be formed on the interlayer insulating layer 140 .
- the data line extends along a direction, which may be perpendicular to the direction of the gate line.
- the gate and data lines cross each other to define a pixel region.
- the power line providing the high voltage may be parallel to and spaced apart from the data line.
- the second capacitor electrode is connected to the drain electrode 154 and overlaps the first capacitor electrode to form the storage capacitor with the interlayer insulating layer 140 as a dielectric layer.
- the source electrode 152 and the drain electrode 154 are spaced apart from each other with respect to the gate electrode 132 and respectively contact both sides of the semiconductor layer 122 through the first and second contact holes 140 a and 140 b.
- the semiconductor layer 122 , the gate electrode 132 , the source electrode 152 and the drain electrode 154 constitute a TFT.
- the gate electrode 132 , the source electrode 152 and the drain electrode 154 are positioned over the semiconductor layer 122 .
- the TFT has a coplanar structure.
- the gate electrode may be positioned under the semiconductor layer, and the source and drain electrodes may be positioned over the semiconductor layer such that the TFT may have an inverted staggered structure.
- the semiconductor layer may include amorphous silicon.
- the TFT serves as the driving TFT, and the switching TFT, which may have substantially same structure as the driving TFT, is further formed on the substrate 110 .
- the gate electrode 132 of the driving TFT is connected to the drain electrode of the switching TFT, and the source electrode 152 of the driving TFT is connected to the power line.
- the gate electrode and the source electrode of the switching TFT are connected to the gate line and the data line, respectively.
- a passivation layer 160 of an insulating material is formed over an entire surface of the substrate 110 to cover the source and drain electrodes 152 and 154 .
- the passivation layer 160 may be formed of an organic insulating material, e.g., benzocyclobutene or photo-acryl.
- An inorganic insulating layer, which is formed of an inorganic material such as silicon oxide or silicon nitride, may be formed under the passivation layer 160 .
- the passivation layer 160 includes a drain contact hole 160 a exposing the drain electrode 154 .
- the drain contact hole 160 a is positioned directly over the second contact hole 140 b .
- the drain contact hole 160 a may be spaced apart from the second contact hole 140 b.
- a first electrode 162 which is connected to the drain electrode 154 through the drain contact hole 160 a , is separately formed on the passivation layer 160 in each pixel region.
- the first electrode 162 may be an anode and may be formed of a conductive material having a relatively high work function.
- the first electrode 162 may be formed of a transparent conductive material such as indium-tin-oxide (ITO) or indium-zinc-oxide (IZO).
- a bank 170 which covers edges of the first electrode 162 , is formed on the passivation layer 160 .
- the bank 170 is formed of an insulating material.
- the bank 170 is positioned between adjacent pixel regions and includes a transmitting hole 170 a exposing a center of the first electrode 162 in the pixel region.
- the bank 170 includes a first bank 172 and a second bank 174 on the first bank 172 .
- a width of the first bank 172 is greater than that of the second bank 174 .
- the first bank 172 includes a material having a relatively high surface energy such that a contact angle of an emitting material to the first bank 172 is reduced.
- the second bank 174 includes a material having a relatively low surface energy such that a contact angle of an emitting material to the second bank 174 is increased such that an overflow of the emitting material into adjacent pixel region is prevented.
- the first bank 172 may be formed of an inorganic material or an organic material each having a hydrophilic property
- the second bank 174 may be formed of an organic material having a hydrophobic property.
- first bank 172 and the second bank 174 may be formed of the same material.
- each of the first and second banks 172 and 174 may be formed of an organic material having a hydrophobic property.
- the bank 170 may have a single-layered structure of an organic material having a hydrophobic property.
- An emitting layer 180 is formed on the first electrode 162 . Namely, the emitting layer 180 contacts the first electrode 162 in the transmitting hole 170 a .
- the emitting layer 180 may be formed by a solution process.
- the emitting layer 180 may be formed by a printing process or a coating process using an injection apparatus having a plurality of nozzles, but it is not limited thereto. An inkjet printing process may be used.
- the emitting layer 180 may include a hole auxiliary layer, an EML and an electron auxiliary layer sequentially stacked on the first electrode 162 .
- the hole auxiliary layer may include at least one of the HIL and the HTL
- the electron auxiliary layer may include at least one of the ETL and the EIL.
- the hole auxiliary layer and the EML may be formed in the transmitting hole 170 a , and the electron auxiliary layer may be formed over an entire surface of the substrate 110 .
- the hole auxiliary layer and the EML may be formed by a solution process, and the electron auxiliary layer may be formed by a deposition process.
- a second electrode 192 is formed over the substrate 110 including the emitting layer 180 .
- the second electrode 192 is positioned at an entire surface of the display area.
- the second electrode 192 may be a cathode and may be formed of a conductive material having a relatively low work function.
- the second electrode 192 may be formed of aluminum (Al), magnesium (Mg), silver (Ag) or their alloy.
- the first electrode 162 , the emitting layer 180 and the second electrode 192 constitute the light emitting diode D.
- An encapsulation film may be formed on the light emitting diode D to prevent penetration of moisture into the light emitting diode D.
- the encapsulation film may include a first inorganic layer, an organic layer and a second inorganic layer substantially stacked, but it is not limited thereto.
- the light from the emitting layer 180 is provided at a surface of the substrate 110 through the first electrode 162 .
- the electroluminescent display device may be a bottom emission type.
- the first electrode 162 may further include a reflection electrode or a reflection layer.
- the reflection electrode or the reflection layer may be formed of aluminum-palladium-copper (APC) alloy, and the first electrode 162 may have a triple-layered structure of ITO/APC alloy/ITO.
- the second electrode 192 may have a relatively small thickness for light-transmitting.
- the second electrode 192 may have the light transmittance of about 45 to 50%.
- the bank 170 may have different heights from the first electrode 162 or the substrate 110 in a major axis and a minor axis of the pixel region to overcome the thickness non-uniformity problem in the emitting layer.
- FIG. 4 is a schematic plane view of an electroluminescent display device according to a first embodiment of the present invention
- FIG. 5 is a schematic cross-sectional view taken along the line V-V of FIG. 4
- FIG. 6 is a schematic cross-sectional view taken along the line VI-VI of FIG. 4
- FIG. 7 is a schematic cross-sectional view taken along the line VII-VII of FIG. 4 .
- some elements are omitted.
- a plurality of pixel regions P are defined on the substrate 110 .
- the pixel region P is an effective light-emitting area for transmitting the light, and a distance between adjacent pixel regions is different in a first direction and a second direction. Namely, the adjacent pixel regions P along the first direction has a first interval distance d 1 , and the adjacent pixel regions P along the second direction has a second interval distance d 2 being greater than the first interval distance d 1 .
- the pixel region P may have a shape having a major axis and a minor axis, e.g., a rectangular shape. The minor axis is parallel to the first direction, and the major axis is parallel to the second direction.
- first and second pixel regions P 1 and P 2 are spaced apart from each other by the first interval distance d 1
- the first and third pixel regions P 1 and P 3 are spaced apart from each other by the second interval distance d 2 .
- the gate insulating layer 130 , the interlayer insulating layer 140 and the passivation layer 160 are sequentially formed on or over the substrate 110 .
- the gate insulating layer 130 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride
- the interlayer insulating layer 140 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl.
- the passivation layer 160 may be formed of an organic insulating material, e.g., benzocyclobutene or photo-acryl.
- An inorganic insulating layer formed of silicon oxide or silicon nitride may be further formed between the interlayer insulating layer 140 and the passivation layer 160 .
- the passivation layer 160 includes a groove 160 b in a space between the pixel regions P adjacent to each other along the first direction.
- the groove 160 b may have a rectangular shape.
- the groove 160 b may be formed in the passivation layer 160 between the first and second pixel regions P 1 and P 2 , and the groove 160 b may not be formed in the passivation layer 160 between the first and third pixel regions P 1 and P 3 .
- the switching TFT, the driving TFT, the storage capacitor, gate line, data line and power line are formed under the passivation layer 160 .
- the first electrode 162 is formed on the passivation layer 160 .
- the first electrode 162 in each pixel region P 1 is separated from each other and contacts the drain electrode of the driving TFT through the drain contact hole of the passivation layer 160 .
- the bank 170 is formed on an edge of the first electrode 162 .
- the bank 170 is positioned between adjacent pixel regions P.
- the bank 170 has the transmitting hole 170 a exposing the first electrode 162 in each pixel region P and covers the edge of the first electrode 162 .
- the transmitting hole 170 a may have a rectangular shape.
- the bank 170 includes a first bank 172 and a second bank 174 on the first bank 172 .
- a width of the first bank 172 is greater than that of the second bank 174 .
- the first bank 172 includes a material having a relatively high surface energy such that a contact angle of an emitting material to the first bank 172 is reduced.
- the second bank 174 includes a material having a relatively low surface energy such that a contact angle of an emitting material to the second bank 174 is increased such that an overflow of the emitting material into adjacent pixel region is prevented.
- the first bank 172 may be formed of an inorganic material or an organic material each having a hydrophilic property
- the second bank 174 may be formed of an organic material having a hydrophobic property.
- the first bank 172 includes a first transmitting hole 172 a
- the second bank 174 includes a second transmitting hole 174 a
- the second transmitting hole 174 a has a size being larger than the first transmitting hole 172 a and overlaps the first transmitting hole 172 a such that the transmitting hole 170 a is defined by the first and second transmitting holes 172 a and 174 a .
- a width of the second bank 174 is smaller than that of the first bank 172 such that a portion of the first bank 172 does not covered by the second bank 174 . Namely, the portion of the first bank 172 exposes and protrudes beyond the second bank 174 .
- Each of the first and second banks 172 and 174 may be formed by a photolithography process using a mask. Alternatively, the first and second banks 172 and 174 of the same material may be formed by a single photolithography process. In this instance, each of the first and second banks 172 and 174 may be formed of an organic material having a hydrophobic property. In addition, the bank 170 may have a single-layered structure of an organic material having a hydrophobic property.
- the emitting layer is formed on the first electrode 162 . Namely, the emitting layer contacts the first electrode 162 in the transmitting hole 170 a .
- the second electrode is formed over an entire surface of the substrate 110 .
- the emitting layer may include the hole auxiliary layer, the EML and the electron auxiliary layer sequentially stacked on the first electrode 162 .
- the hole auxiliary layer may include at least one of the HIL and the HTL
- the electron auxiliary layer may include at least one of the ETL and the EIL.
- a part or a total of the emitting layer may be formed by a solution process.
- the hole auxiliary layer and the EML may be formed by the solution process.
- the passivation layer 160 includes the groove 160 b in a space between adjacent pixel regions P along the first direction, and the bank 170 has a height difference in the first and second directions due to the groove 160 b.
- the bank 170 is formed according to a step difference in the groove 160 b of the passivation layer 160 such that the bank 170 between adjacent pixel regions P, e.g., the first and second pixel regions P 1 and P 2 , along the first direction has a first height h 1 from the first electrode 162 , and the bank 170 between adjacent pixel regions P, e.g., the first and third pixel regions P 1 and P 3 , along the second direction has a second height h 2 from the first electrode 162 .
- the first height h 1 is smaller than the second height h 2 .
- the bank 170 has substantially the same thickness in a space between the first and second pixel regions P 1 and P 2 and in a space between the first and third pixel regions P 1 and P 3 , while the bank 170 has a height difference. As shown in FIG. 5 , a portion of a bottom surface of the bank 170 between the first and second pixel regions P 1 and P 2 is disposed lower than a bottom surface of the first electrode 162 .
- the influence in one pixel region P, i.e., the first pixel region P 1 , from adjacent pixel regions P, i.e., the second and third pixel regions P 2 and P 3 , along the first and second directions is different in the solution process of the emitting layer such that the emitting layer has the non-uniform thickness.
- the influence of the solution in the adjacent pixel regions P along the first direction is relatively high, while the influence of the solution in the adjacent pixel regions P along the second direction is relatively low. Accordingly, there is a difference in an evaporation rate of the solvent in the solution at the first and second directions. Since the evaporation rate of the solvent in the second direction is faster than that in the first direction, the emitting layer having the uniform thickness is difficult to be provided.
- the groove 160 b is formed in the passivation layer 160 such that an upper surface of the bank 170 between adjacent pixel regions P along the first direction has a height being smaller than an upper surface of the bank 170 between adjacent pixel regions P along the second direction.
- the bank 170 has the first height h 1 in a space between adjacent pixel regions P along the first direction and the second height h 2 , which is greater than the first height h 1 , in a space between adjacent pixel regions P along the second direction.
- a height of a bottom surface of the bank 170 i.e., a height of the upper surface of the passivation layer 160
- a height of a bottom surface of the bank 170 i.e., a height of the upper surface of the passivation layer 160
- the first height h 1 of the bank 170 in a space between adjacent pixel regions P along the first direction is smaller than the second height h 2 of the bank 170 in a space between adjacent pixel regions P along the second direction.
- the bank 170 may have a height difference in the first and second direction and has a thickness difference without the groove 160 b .
- a hydrophobic property of the bank is important fact to the thickness non-uniformity and/or the profile non-uniformity.
- the bank when making the bank, which has the thickness difference, the bank has a difference of the hydrophobicity in a space between adjacent pixel regions along the first direction and along the second direction. For example, a thicker portion of the bank may have the hydrophobicity being smaller than a thinner portion of the bank.
- the organic layer formed in the pixel region may have a thickness non-uniformity and/or a profile non-uniformity.
- the bank 170 since the bank 170 has a height difference in the first and second direction and has substantially the same thickness with the groove 160 b , the above problem is prevented.
- a contact position of the bank 170 and the passivation layer 160 is positioned at a first height from the substrate 110 .
- a contact position of the bank 170 and the passivation layer 160 is positioned at a second height, which is greater than the first height, from the substrate 110 .
- the first height h 1 may be substantially equal to the height of the bank in the related art electroluminescent display device
- the second height h 2 may be greater than the height of the bank in the related art electroluminescent display device.
- the first height h 1 may be smaller than the height of the bank in the related art electroluminescent display device, and the second height h 2 may be substantially equal to the height of the bank in the related art electroluminescent display device.
- the solvent in the pixel region is less trapped at the first direction and the evaporation rate of the solvent at the first direction is increased such that the pixel region has substantially the same evaporation rates in the first and second directions. As a result, the emitting layer having improved thickness uniformity is provided.
- a maximum thickness difference (e.g., deviation) in the HIL at the first direction is about 5.3 mm, and an average thickness difference in the HIL at the first direction is about 2.45 mm.
- a maximum thickness difference (e.g., deviation) in the HIL at the second direction is about 12.2 mm, and an average thickness difference in the HIL at the second direction is about 5.77 mm.
- a maximum thickness difference in the HIL at the first direction is about 8.4 mm, and an average thickness difference in the HIL at the first direction is about 3.40 mm.
- a maximum thickness difference (e.g., deviation) in the HIL at the second direction is about 15.7 mm, and an average thickness difference in the HIL at the second direction is about 12.7 mm.
- the thickness uniformity of the emitting layer is improved.
- a depth of the groove 160 b is smaller than a thickness of the passivation layer 160 , but it is not limited thereto.
- the depth of the groove 160 b may be equal to the thickness of the passivation layer 160 such that a surface of the interlayer insulating layer 140 may be exposed through the groove 160 b .
- the first bank 172 may contact the interlayer insulating layer 140 .
- the electroluminescent display device of the present invention since at least a part of the emitting layer is formed by the solution process, the production cost is reduced and the electroluminescent display device of large size and/or high resolution is provided.
- the evaporation rate of the solvent at the first and second direction is uniformed such that the thickness uniformity of the emitting layer and the display quality are improved.
- the emitting efficiency, the lifetime, the driving voltage and the color property of the electroluminescent display device are improved.
- the shape of the groove 160 b in the passivation layer 160 may be changed according to a shape of the pixel region P, i.e., an effective emitting area.
- FIG. 8 is a schematic plane view of an electroluminescent display device according to a second embodiment of the present invention.
- each pixel region P may have a narrow circle shape in a plane view.
- the pixel region P includes a minor axis along the first direction and a major axis along the second direction. Namely, the pixel region P includes semicircle-shaped ends and a linear center portion connecting the semicircle-shaped ends.
- the bank 170 includes a transmitting hole 170 a corresponding to the shape of the pixel region P. Namely, the transmitting hole 170 a also has a narrow circle shape in a plane view.
- the bank 170 includes a first bank 172 and a second bank 174 on the first bank 172 .
- the first bank 172 includes a first transmitting hole 172 a
- the second bank 174 includes a second transmitting hole 174 a .
- the second transmitting hole 174 a has a size being larger than the first transmitting hole 172 a and overlaps the first transmitting hole 172 a such that the transmitting hole 170 a is defined by the first and second transmitting holes 172 a and 174 a .
- a width of the second bank 174 is less than that of the first bank 172 such that a portion of the first bank 172 does not covered by the second bank 174 .
- the portion of the first bank 172 exposes and protrudes beyond the second bank 174 .
- the groove 160 b is formed in the passivation layer 160 between adjacent pixel regions P along the first direction.
- a side surface of the groove 160 b facing the transmitting hole 170 a has substantially the same shape as a side surface of the transmitting hole 170 a .
- the side surfaces of the groove 160 b and the transmitting hole 170 a have a constant distance.
- the groove 160 b includes a protrusion at a corner (four corners) toward a corner of the transmitting hole 170 a . Accordingly, the groove 160 b and the transmitting hole 170 a have a constant distance at the corner as well as the side surface.
- a shape of the groove 160 b is changed according to a shape of the pixel region P, i.e., a shape of the transmitting hole 170 a , to have a constant distance between the pixel region P and the groove 160 b .
- the emitting layer having the thickness uniformity is provided.
- FIG. 9 is a cross-sectional view of an electroluminescent display device according to a third embodiment of the present invention.
- FIG. 9 shows a cross-sectional view taken along the line VII-VII of FIG. 4 .
- the gate insulating layer 230 , the interlayer insulating layer 240 and the passivation layer 260 are sequentially formed on or over the substrate 210 , and the bank 270 including the first and second banks 272 and 274 is formed on the passivation layer 260 .
- the passivation layer 260 includes a groove 260 b in a space between the pixel regions P (of FIG. 4 ) adjacent to each other along the first direction. A height in a portion of the bank 270 in the groove 260 b is reduced.
- a center depth is greater than an edge depth in the second direction.
- the depth of the groove 260 b may be gradually decreased from the center to the edge along the second direction.
- an upper surface of the passivation layer 260 corresponding to the groove 260 b may have a convex shape toward the substrate 210 .
- the groove 260 b may be formed by a photolithography process using a mask having a light transmitting gradual difference from a center to an edge.
- FIG. 10 is a schematic cross-sectional view of an electroluminescent display device according to a fourth embodiment of the present invention.
- FIG. 10 shows a cross-sectional view taken along the line VII-VII of FIG. 4 .
- the gate insulating layer 330 , the interlayer insulating layer 340 and the passivation layer 360 are sequentially formed on or over the substrate 310 , and the bank 370 including the first and second banks 372 and 374 is formed on the passivation layer 360 .
- the passivation layer 360 includes a groove 360 b in a space between the pixel regions P (of FIG. 4 ) adjacent to each other along the first direction. A height in a portion of the bank 370 in the groove 360 b is reduced.
- a center depth is greater than an edge depth in the second direction.
- the groove 360 b may have a first depth in the center and a second depth, which is smaller than the first depth, in both edges along the second direction.
- the groove 360 b may have a dual step difference structure, e.g., a stair shape.
- the groove 360 b may be formed by a photolithography process using two masks having a light transmitting difference or a half-ton mask.
- the thickness difference of a W-shaped emitting layer may be efficiently uniformed.
- FIG. 11 is a schematic cross-sectional view of an electroluminescent display device according to a fifth embodiment of the present invention.
- FIG. 11 shows a cross-sectional view taken along the line VII-VII of FIG. 4 .
- the gate insulating layer 430 , the interlayer insulating layer 440 and the passivation layer 460 are sequentially formed on or over the substrate 410 , and the bank 470 including the first and second banks 472 and 474 is formed on the passivation layer 460 .
- the passivation layer 460 includes a groove 460 b in a space between the pixel regions P (of FIG. 4 ) adjacent to each other along the first direction. A height in a portion of the bank 470 in the groove 460 b is reduced.
- a center depth is smaller than an edge depth in the second direction.
- the depth of the groove 460 b may be gradually decreased from the edge to the center along the second direction.
- an upper surface of the passivation layer 460 corresponding to the groove 460 b may have a convex shape toward the bank 470 .
- a height of the bank 470 in an edge of the groove 460 b , which faces the transmitting hole 470 a is efficiently reduced such that an evaporation rate of the solvent in the emitting material solution is efficiently increased.
- the thickness uniformity of the emitting layer is improved.
- the groove 460 b may be formed by a photolithography process using a mask having a light transmitting gradual difference from a center to an edge.
- FIG. 12 is a schematic cross-sectional view of an electroluminescent display device according to a sixth embodiment of the present invention.
- FIG. 12 shows a cross-sectional view taken along the line V-V of FIG. 4 .
- the gate insulating layer 530 , the interlayer insulating layer 540 and the passivation layer 560 are sequentially formed on or over the substrate 510 , and the bank 570 including the first and second banks 572 and 574 is formed on the passivation layer 560 .
- the passivation layer 560 includes a groove 560 b in a space between the pixel regions P (of FIG. 4 ) adjacent to each other along the first direction.
- a width of the groove 560 b is substantially equal to a distance between adjacent first electrodes 562 .
- a height in a portion of the bank 570 in the groove 560 b is reduced.
- the groove 560 b has a rectangular cross-section.
- the groove 560 b may have a round cross-section similar to a shape of the groove 260 b (of FIG. 9 ) or a shape of the groove 460 b (of FIG. 11 ).
- a height of the bank 570 between adjacent pixel regions along the first direction is smaller than that of the bank 570 between adjacent pixel regions along the second direction. Accordingly, even though a distance between adjacent pixel regions is different along the first and second directions, an evaporation rate of the solvent in the emitting material solution is uniformed such that the emitting layer having the thickness uniformity is provided.
- FIGS. 13A to 13C are schematic cross-sectional view illustrating a fabricating process of a portion of an electroluminescent display device according to the sixth embodiment of the present invention.
- the gate insulating layer 530 , the interlayer insulating layer 540 and the passivation layer 560 are formed on the substrate 510 .
- a conductive material layer is formed on the passivation layer 560 .
- the conductive material layer may include a transparent conductive material such as indium-tin-oxide (ITO) or indium-zinc-oxide (IZO).
- ITO indium-tin-oxide
- IZO indium-zinc-oxide
- the semiconductor layer 122 is formed on the substrate 510 before forming the gate insulating layer 530
- the gate electrode 132 is formed on the gate insulating layer 530 before forming the interlayer insulating layer 540 .
- the source electrode 152 and the drain electrode 154 are formed on the interlayer insulating layer 540 before forming the passivation layer 560 .
- a portion of the passivation layer 560 is patterned by an etching process using the first electrode 562 as an etching mask to form the groove 560 b .
- the etching process may be an anisotropic dry etching process.
- an end of the groove 560 b may exactly match with or correspond to an end of the first electrode 562 .
- a width of the groove 560 b is substantially equal to a distance between adjacent first electrodes 562 .
- the passivation layer 560 may be patterned to form the groove 560 b before forming the first electrode 562 .
- the groove 560 b and the drain contact hole 160 a may be formed by a single mask process.
- an end of the first electrode 562 may be positioned in the groove 560 b such that a height of the bank 570 in the groove 560 b may be increased.
- the first electrode 562 is not positioned in the groove 560 b . Accordingly, the above problem is prevented.
- an insulating material layer is formed on the first electrode 562 and the passivation layer 560 .
- the insulating material layer is patterned to form the bank 570 .
- the emitting layer 180 (of FIG. 3 ) and the second electrode 192 are formed on the first electrode 562 and optionally on the bank 570 .
- FIG. 14 is a schematic plane view of an electroluminescent display device according to a seventh embodiment of the present invention.
- FIG. 15 is a schematic cross-sectional view taken along the line XV-XV of FIG. 14
- FIG. 16 is a schematic cross-sectional view taken along the line XVI-XVI of FIG. 14 .
- a plurality of pixel regions P are defined on the substrate 610 .
- the pixel region P is an effective light-emitting area for transmitting the light, and a distance between adjacent pixel regions is different in a first direction and a second direction. Namely, the adjacent pixel regions P along the first direction has a first interval distance d 1 , and the adjacent pixel regions P along the second direction has a second interval distance d 2 being greater than the first interval distance d 1 .
- the pixel region P may have a shape having a major axis and a minor axis, e.g., a rectangular shape. The minor axis is parallel to the first direction, and the major axis is parallel to the second direction.
- first and second pixel regions P 1 and P 2 are spaced apart from each other by the first interval distance d 1
- the first and third pixel regions P 1 and P 3 are spaced apart from each other by the second interval distance d 2 .
- the gate insulating layer 630 , the interlayer insulating layer 640 and the passivation layer 660 are sequentially formed on or over the substrate 610 .
- the gate insulating layer 630 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride
- the interlayer insulating layer 640 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl.
- the passivation layer 660 may be formed of an organic insulating material, e.g., benzocyclobutene or photo-acryl.
- An inorganic insulating layer formed of silicon oxide or silicon nitride may be further formed between the interlayer insulating layer 140 and the passivation layer 660 .
- the passivation layer 660 includes a protruding portion 661 in a space between the pixel regions P adjacent to each other along the second direction. Namely, the protruding portion 661 of the passivation layer 660 is positioned between the first and third pixel regions P 1 and P 3 .
- an upper surface of the passivation layer 660 between the first and second pixel regions P 1 and P 2 adjacent along the first direction has a third height h 3 from the substrate 610
- an upper surface of the passivation layer 660 , i.e., the protruding portion 661 , between the first and third pixel regions P 1 and P 3 adjacent along the second direction has a fourth height h 4 , which is greater than the third height h 3 , from the substrate 610 .
- the protruding portion 661 is formed on the passivation layer 660 between the first and third pixel regions P 1 and P 3 , while there is no protruding portion 661 on the passivation layer 660 between the first and second pixel regions P 1 and P 2 such that the passivation layer 660 between the first and second pixel regions P 1 and P 2 provides a flat top surface.
- the switching TFT, the driving TFT, the storage capacitor, gate line, data line and power line are formed under the passivation layer 660 .
- the first electrode 662 is formed on the passivation layer 660 .
- the first electrode 662 in each pixel region P 1 is separated from each other and contacts the drain electrode of the driving TFT through the drain contact hole of the passivation layer 660 .
- the bank 670 is formed on an edge of the first electrode 662 .
- the bank 670 is positioned between adjacent pixel regions P.
- the bank 670 has the transmitting hole 670 a exposing the first electrode 662 in each pixel region P and covers the edge of the first electrode 662 .
- the transmitting hole 670 a may have a rectangular shape.
- the bank 670 includes a first bank 672 and a second bank 674 on the first bank 672 .
- a width of the first bank 672 is greater than that of the second bank 674 .
- the first bank 672 includes a material having a relatively high surface energy such that a contact angle of an emitting material to the first bank 672 is reduced.
- the second bank 674 includes a material having a relatively low surface energy such that a contact angle of an emitting material to the second bank 674 is increased such that an overflow of the emitting material into adjacent pixel region is prevented.
- the first bank 672 may be formed of an inorganic material or an organic material each having a hydrophilic property
- the second bank 674 may be formed of an organic material having a hydrophobic property.
- the first bank 672 includes a first transmitting hole 672 a
- the second bank 674 includes a second transmitting hole 674 a
- the second transmitting hole 674 a has a size being larger than the first transmitting hole 672 a and overlaps the first transmitting hole 672 a such that the transmitting hole 670 a is defined by the first and second transmitting holes 672 a and 674 a .
- a width of the second bank 674 is smaller than that of the first bank 672 such that a portion of the first bank 672 does not covered by the second bank 674 . Namely, the portion of the first bank 672 exposes and protrudes beyond the second bank 674 .
- Each of the first and second banks 672 and 674 may be formed by a photolithography process using a mask. Alternatively, the first and second banks 672 and 674 of the same material may be formed by a single photolithography process. In this instance, each of the first and second banks 672 and 674 may be formed of an organic material having a hydrophobic property. In addition, the bank 670 may have a single-layered structure of an organic material having a hydrophobic property.
- the emitting layer is formed on the first electrode 662 . Namely, the emitting layer contacts the first electrode 662 in the transmitting hole 670 a .
- the second electrode is formed over an entire surface of the substrate 610 .
- the emitting layer may include the hole auxiliary layer, the EML and the electron auxiliary layer sequentially stacked on the first electrode 662 .
- the hole auxiliary layer may include at least one of the HIL and the HTL
- the electron auxiliary layer may include at least one of the ETL and the EIL.
- a part or a total of the emitting layer may be formed by a solution process.
- the hole auxiliary layer and the EML may be formed by the solution process.
- the passivation layer 660 includes the protruding portion 661 in a space between adjacent pixel regions P along the second direction, and the bank 670 has a height difference in the first and second directions due to the protruding portion 661 .
- the bank 670 is formed according to a step difference in the protruding portion 661 of the passivation layer 660 such that the bank 670 between adjacent pixel regions P, e.g., the first and second pixel regions P 1 and P 2 , along the first direction has a fifth height h 5 from the substrate 610 , and the bank 670 between adjacent pixel regions P, e.g., the first and third pixel regions P 1 and P 3 , along the second direction has a sixth height h 6 from the substrate 610 .
- the fifth height h 5 is smaller than the sixth height h 6 .
- the bank 670 has substantially the same thickness in a space between the first and second pixel regions P 1 and P 2 and in a space between the first and third pixel regions P 1 and P 3 , while the bank 670 has a height difference.
- the influence in one pixel region P, i.e., the first pixel region P 1 , from adjacent pixel regions P, i.e., the second and third pixel regions P 2 and P 3 , along the first and second directions is different in the solution process of the emitting layer such that the emitting layer has the non-uniform thickness.
- the influence of the solution in the adjacent pixel regions P along the first direction is relatively high, while the influence of the solution in the adjacent pixel regions P along the second direction is relatively low. Accordingly, there is a difference in an evaporation rate of the solvent in the solution at the first and second directions. Since the evaporation rate of the solvent in the second direction is faster than that in the first direction, the emitting layer having the uniform thickness is difficult to be provided.
- the protruding portion 661 is formed in the passivation layer 660 such that an upper surface of the bank 670 between adjacent pixel regions P along the first direction has a height being smaller than an upper surface of the bank 670 between adjacent pixel regions P along the second direction.
- the bank 670 has the fifth height h 5 in a space between adjacent pixel regions P along the first direction and the sixth height h 6 , which is greater than the fifth height h 5 , in a space between adjacent pixel regions P along the second direction.
- a third height h 3 of a bottom surface of the bank 670 i.e., a height of the upper surface of the passivation layer 660
- a fourth height h 4 of a bottom surface of the bank 670 i.e., a height of the upper surface of the passivation layer 660
- the fifth height h 5 of the bank 670 in a space between adjacent pixel regions P along the first direction is smaller than the sixth height h 6 of the bank 670 in a space between adjacent pixel regions P along the second direction.
- the electroluminescent display device of the present invention since at least a part of the emitting layer is formed by the solution process, the production cost is reduced and the electroluminescent display device of large size and/or high resolution is provided.
- the evaporation rate of the solvent at the first and second direction is uniformed such that the thickness uniformity of the emitting layer and the display quality are improved.
- the emitting efficiency, the lifetime, the driving voltage and the color property of the electroluminescent display device are improved.
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Abstract
Description
- The present application claims the priority benefit of Korean Patent Application No. 10-2016-0150543 filed in the Republic of Korea on Nov. 11, 2016 and Korean Patent Application No. 10-2017-0125401 filed in the Republic of Korea on Sep. 27, 2017, all these applications are hereby incorporated by reference into the present application.
- The present disclosure relates to a display device, and more particularly, to an electroluminescent display device being capable of providing a uniform brightness and a high display quality and a method of fabricating the same.
- Recently, a flat panel display device having excellent characteristics of a thin profile, a light weight and low power consumption has been developed and used.
- Among the flat panel display device, an electroluminescent display device may be formed on a flexible substrate such as a plastic substrate. In addition, since the electroluminescent display device is a self-emission type, the electroluminescent display device has excellent characteristics in contrast ratio, a viewing angle, a thin profile, a response time, a thermal stability, and so on. The electroluminescent display device may be referred to as a light emitting display device. The electroluminescent display device may include an anode as a hole injection electrode, a cathode as an electron injection electrode and an emitting layer between the anode and the cathode. The hole from the anode and the electron from the cathode are combined in the emitting layer to form an exciton, and the light is emitted from the emitting layer by a radiative recombination of the exciton.
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FIG. 1 is a schematic view showing an energy band diagram of the related art electroluminescent display device. - As shown in
FIG. 1 , the electroluminescent display device includes an anode 1, acathode 7 and an emitting material layer (EML) 4 between the anode 1 and thecathode 7. For the hole injection from the anode into theEML 4 and the electron injection from thecathode 7 into theEML 4, the electroluminescent display device may further include a hole transporting layer (HTL) 3 between the anode 1 and theEML 4 and an electron transporting layer (ETL) 5 between thecathode 7 and theEML 4. In addition, to further efficiently injecting the hole and the electron into theEML 4, the electroluminescent display device may further include a hole injection layer (HIL) 2 between the anode 1 and theHTL 3 and an electron injection layer (EIL) 6 between the cathode and theETL 5. - In the electroluminescent display device, the hole “h+” provided from the anode 1 into the
EML 4 through theHIL 2 and theHTL 3 and the electron “e-” provided from thecathode 7 into theEML 4 through theEIL 6 and theETL 5 are combined to form an exciton, and the light having a color in correspondence to a band gap of theEML 4 is provided from the exciton. - For example, the EML 4, the
HIL 2, theHTL 3, theETL 5 and theEIL 6 may be formed by a vacuum thermal evaporation process using a fine metal mask. - However, the production cost of the electroluminescent display device is increased by the vacuum thermal evaporation process, and the application of the vacuum thermal evaporation process for the large size and high resolution electroluminescent display device is difficult because of a deviation problem of the mask, a deformation problem of the mask, a shadow effect in the mask, and so on.
- To resolve the problems, the solution process for the emitting layer is introduced. In the solution process, a nozzle of an injection apparatus is scanned along a direction to drop an emitting material in a pixel region surrounding by a bank. The emitting material is dried to form the emitting layer.
- However, the emitting layer formed by the solution process may have a non-uniform thickness. Namely, in a cross-section, the emitting layer may have a “U” shape or a “W” shape.
- The electroluminescent display device, which includes the emitting layer having a non-uniform thickness, provides a non-uniform emission. Accordingly, in the electroluminescent display device, the brightness becomes non-uniform, and the display quality is degraded.
- Accordingly, the present invention is directed to an electroluminescent display device and a method of fabricating the same that substantially obviate one or more of the problems due to limitations and disadvantages of the related art.
- An object of the present invention is to provide an electroluminescent device that has a uniform brightness and a high display quality.
- Additional features and advantages of the invention will be set forth in the description which follows, and in part will be apparent from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention will be realized and attained by the structure particularly pointed out in the written description and claims hereof as well as the appended drawings.
- To achieve these and other advantages and in accordance with the purpose of the present invention, as embodied and broadly described herein, an electroluminescent display device includes a substrate including first to third pixel regions, the second and third pixel regions being adjacent to the first pixel region along a first direction and a second direction, respectively; an insulating layer over the substrate and including a groove between the first and second pixel regions; a first electrode on the insulating layer and in each of the first to third pixel regions; a bank covering an edge of the first electrode and disposed between the first pixel region and the second pixel region and between the first pixel region and the third pixel region; an emitting layer on the first electrode; and a second electrode on the emitting layer, wherein the bank disposed between the first and second pixel regions has a first height from the first electrode and the bank disposed between the first and third pixel regions has a second height from the first electrode, and the first height is smaller than the second height.
- In another aspect, an electroluminescent display device includes a substrate including first to third pixel regions, the second and third pixel regions being adjacent to the first pixel region along a first direction and a second direction, respectively; a first electrode in each of the first to third pixel regions; a bank covering an edge of the first electrode and disposed between the first pixel region and the second pixel region and between the first pixel region and the third pixel region; an emitting layer on the first electrode; and a second electrode on the emitting layer, wherein a portion of a bottom surface of the bank between the first pixel region and the second pixel region is disposed lower than a portion of a bottom surface of the bank between the first pixel region and the third pixel region.
- It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.
- The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention.
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FIG. 1 is a schematic view showing an energy band diagram of the related art electroluminescent display device. -
FIG. 2 is a schematic circuit diagram of an electroluminescent display device according to an embodiment of the present invention. -
FIG. 3 is a schematic cross-sectional view of an electroluminescent display device according to an embodiment of the present invention. -
FIG. 4 is a schematic plane view of an electroluminescent display device according to a first embodiment of the present invention. -
FIG. 5 is a schematic cross-sectional view taken along the line V-V ofFIG. 4 . -
FIG. 6 is a schematic cross-sectional view taken along the line VI-VI ofFIG. 4 . -
FIG. 7 is a schematic cross-sectional view taken along the line VII-VII ofFIG. 4 . -
FIG. 8 is a schematic plane view of an electroluminescent display device according to a second embodiment of the present invention. -
FIG. 9 is a schematic cross-sectional view of an electroluminescent display device according to a third embodiment of the present invention. -
FIG. 10 is a schematic cross-sectional view of an electroluminescent display device according to a fourth embodiment of the present invention. -
FIG. 11 is a schematic cross-sectional view of an electroluminescent display device according to a fifth embodiment of the present invention. -
FIG. 12 is a schematic cross-sectional view of an electroluminescent display device according to a sixth embodiment of the present invention. -
FIGS. 13A to 13C are schematic cross-sectional view illustrating a fabricating process of a portion of an electroluminescent display device according to the sixth embodiment of the present invention. -
FIG. 14 is a schematic plane view of an electroluminescent display device according to a seventh embodiment of the present invention. -
FIG. 15 is a schematic cross-sectional view taken along the line XV-XV ofFIG. 14 . -
FIG. 16 is a schematic cross-sectional view taken along the line XVI-XVI ofFIG. 14 . - Reference will now be made in detail to the preferred embodiments of the present invention, examples of which are illustrated in the accompanying drawings.
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FIG. 2 is a schematic circuit diagram of an electroluminescent display device according to the present invention. All components of the electroluminescent display device according to all embodiments of the present invention are operatively coupled and configured. - As shown in
FIG. 2 , in the electroluminescent display device, a gate line GL and a data line DL are formed, and a pixel region P is defined by the gate and data lines GL and DL. In the pixel region P, a switching thin film transistor (TFT) Ts, a driving TFT Td, a storage capacitor Cst and a light emitting diode D are formed. - A gate electrode of the switching TFT Ts is connected to the gate line GL, and a source electrode of the switching TFT Ts is connected to the data line DL. A gate electrode of the driving TFT Td is connected to a drain electrode of the switching TFT Ts, and a source electrode of the driving TFT Td is connected to a high voltage supply VDD. An anode of the light emitting diode D is connected to a drain electrode of the driving TFT Td, and a cathode of the light emitting diode D is connected to a low voltage supply VSS. The storage capacitor Cst is connected to a gate electrode and the drain electrode of the driving TFT Td.
- In the electroluminescent display device, when the switching TFT Ts is turned on by a gate signal applied through the gate line GL, a data signal from the data line DL is applied to a gate electrode of the driving TFT Td and an electrode of the storage capacitor Cst through the switching TFT Ts.
- When the driving TFT Td is turned on by the data signal, an electric current is supplied to the light emitting diode D from the high voltage supply VDD through the driving TFT Td. As a result, the light emitting diode D emits light. Since the current in the light emitting diode D is proportional to the data signal and the light intensity emitted from the light emitting diode D is proportional to the current in the light emitting diode D, the pixel region P provide a gray scale according to the data signal.
- The storage capacitor Cst serves to maintain the voltage of the gate electrode of the driving TFT Td for one frame. Accordingly, the electroluminescent display device displays images.
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FIG. 3 is a schematic cross-sectional view of an electroluminescent display device according to the present invention. - As shown in
FIG. 3 , a semiconductor layer 122 is formed on an insulatingsubstrate 110. Thesubstrate 110 may be a glass substrate or a flexible substrate of a polymer. For example, thesubstrate 110 may be a polyimide substrate. - The semiconductor layer 122 may be formed of an oxide semiconductor material or a poly-silicon. When the semiconductor layer 122 includes the oxide semiconductor material, a light-shielding pattern may be formed under the semiconductor layer 122. The light radiated to the semiconductor layer 122 is shielded or blocked by the light-shielding pattern such that thermal degradation of the semiconductor layer 122 can be prevented. On the other hand, when the semiconductor layer 122 includes polycrystalline silicon, a buffer layer may be formed between the
substrate 110 and the semiconductor layer 122. In addition, impurities may be doped into both sides of the semiconductor layer 122 of polycrystalline silicon. - A
gate insulating layer 130 is formed on the semiconductor layer 122. Thegate insulating layer 130 may be formed of an inorganic insulating material such as silicon oxide or silicon nitride. - A
gate electrode 132, which is formed of a conductive material, e.g., metal, is formed on thegate insulating layer 130 to correspond to a center of the semiconductor layer 122. In addition, the gate line and a first capacitor electrode may be formed on thegate insulating layer 130. The gate line extends along a direction, and the first capacitor electrode is connected to thegate electrode 132. - In
FIG. 3 , thegate insulating layer 130 is formed on the entire surface of thesubstrate 110. Alternatively, thegate insulating layer 130 may be patterned to have the same shape as thegate electrode 132. - An interlayer insulating
layer 140, which is formed of an insulating material, is formed on an entire surface of thesubstrate 110 including thegate electrode 132. The interlayer insulatinglayer 140 may be formed of an inorganic insulating material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl. - The interlayer insulating
layer 140 includes first and second contact holes 140 a and 140 b exposing both sides of the semiconductor layer 122. The first and second contact holes 140 a and 140 b are positioned at both sides of thegate electrode 132 to be spaced apart from thegate electrode 132. - In
FIG. 3 , the first and second contact holes 140 a and 140 b are formed in thegate insulating layer 130 and the interlayer insulatinglayer 140. Alternatively, when thegate insulating layer 130 is patterned to have the same shape as thegate electrode 132, the first and second contact holes 140 a and 140 b are formed in theinterlayer insulating layer 140. - A
source electrode 152 and adrain electrode 154, which are formed of a conductive material, e.g., metal, are formed on theinterlayer insulating layer 140. In addition, the data line, a power line and a second capacitor electrode may be formed on theinterlayer insulating layer 140. The data line extends along a direction, which may be perpendicular to the direction of the gate line. The gate and data lines cross each other to define a pixel region. The power line providing the high voltage may be parallel to and spaced apart from the data line. The second capacitor electrode is connected to thedrain electrode 154 and overlaps the first capacitor electrode to form the storage capacitor with the interlayer insulatinglayer 140 as a dielectric layer. - The
source electrode 152 and thedrain electrode 154 are spaced apart from each other with respect to thegate electrode 132 and respectively contact both sides of the semiconductor layer 122 through the first and second contact holes 140 a and 140 b. - The semiconductor layer 122, the
gate electrode 132, thesource electrode 152 and thedrain electrode 154 constitute a TFT. - The
gate electrode 132, thesource electrode 152 and thedrain electrode 154 are positioned over the semiconductor layer 122. Namely, the TFT has a coplanar structure. - Alternatively, in the TFT, the gate electrode may be positioned under the semiconductor layer, and the source and drain electrodes may be positioned over the semiconductor layer such that the TFT may have an inverted staggered structure. In this instance, the semiconductor layer may include amorphous silicon.
- The TFT serves as the driving TFT, and the switching TFT, which may have substantially same structure as the driving TFT, is further formed on the
substrate 110. Thegate electrode 132 of the driving TFT is connected to the drain electrode of the switching TFT, and thesource electrode 152 of the driving TFT is connected to the power line. The gate electrode and the source electrode of the switching TFT are connected to the gate line and the data line, respectively. - A
passivation layer 160 of an insulating material is formed over an entire surface of thesubstrate 110 to cover the source and drainelectrodes passivation layer 160 may be formed of an organic insulating material, e.g., benzocyclobutene or photo-acryl. An inorganic insulating layer, which is formed of an inorganic material such as silicon oxide or silicon nitride, may be formed under thepassivation layer 160. - The
passivation layer 160 includes adrain contact hole 160 a exposing thedrain electrode 154. Thedrain contact hole 160 a is positioned directly over the second contact hole 140 b. Alternatively, thedrain contact hole 160 a may be spaced apart from the second contact hole 140 b. - A
first electrode 162, which is connected to thedrain electrode 154 through thedrain contact hole 160 a, is separately formed on thepassivation layer 160 in each pixel region. Thefirst electrode 162 may be an anode and may be formed of a conductive material having a relatively high work function. For example, thefirst electrode 162 may be formed of a transparent conductive material such as indium-tin-oxide (ITO) or indium-zinc-oxide (IZO). - A
bank 170, which covers edges of thefirst electrode 162, is formed on thepassivation layer 160. Thebank 170 is formed of an insulating material. Thebank 170 is positioned between adjacent pixel regions and includes a transmittinghole 170 a exposing a center of thefirst electrode 162 in the pixel region. - The
bank 170 includes afirst bank 172 and asecond bank 174 on thefirst bank 172. A width of thefirst bank 172 is greater than that of thesecond bank 174. Thefirst bank 172 includes a material having a relatively high surface energy such that a contact angle of an emitting material to thefirst bank 172 is reduced. Thesecond bank 174 includes a material having a relatively low surface energy such that a contact angle of an emitting material to thesecond bank 174 is increased such that an overflow of the emitting material into adjacent pixel region is prevented. For example, thefirst bank 172 may be formed of an inorganic material or an organic material each having a hydrophilic property, and thesecond bank 174 may be formed of an organic material having a hydrophobic property. - Alternatively, the
first bank 172 and thesecond bank 174 may be formed of the same material. In this instance, each of the first andsecond banks bank 170 may have a single-layered structure of an organic material having a hydrophobic property. - An emitting
layer 180 is formed on thefirst electrode 162. Namely, the emittinglayer 180 contacts thefirst electrode 162 in the transmittinghole 170 a. The emittinglayer 180 may be formed by a solution process. For example, the emittinglayer 180 may be formed by a printing process or a coating process using an injection apparatus having a plurality of nozzles, but it is not limited thereto. An inkjet printing process may be used. - Further, the emitting
layer 180 may include a hole auxiliary layer, an EML and an electron auxiliary layer sequentially stacked on thefirst electrode 162. For example, the hole auxiliary layer may include at least one of the HIL and the HTL, and the electron auxiliary layer may include at least one of the ETL and the EIL. - In this instance, the hole auxiliary layer and the EML may be formed in the transmitting
hole 170 a, and the electron auxiliary layer may be formed over an entire surface of thesubstrate 110. The hole auxiliary layer and the EML may be formed by a solution process, and the electron auxiliary layer may be formed by a deposition process. - A
second electrode 192 is formed over thesubstrate 110 including the emittinglayer 180. Thesecond electrode 192 is positioned at an entire surface of the display area. Thesecond electrode 192 may be a cathode and may be formed of a conductive material having a relatively low work function. For example, thesecond electrode 192 may be formed of aluminum (Al), magnesium (Mg), silver (Ag) or their alloy. - The
first electrode 162, the emittinglayer 180 and thesecond electrode 192 constitute the light emitting diode D. - An encapsulation film may be formed on the light emitting diode D to prevent penetration of moisture into the light emitting diode D. For example, the encapsulation film may include a first inorganic layer, an organic layer and a second inorganic layer substantially stacked, but it is not limited thereto.
- The light from the emitting
layer 180 is provided at a surface of thesubstrate 110 through thefirst electrode 162. Namely, the electroluminescent display device may be a bottom emission type. - Alternatively, when the electroluminescent display device of the present invention is a top-emission type, the
first electrode 162 may further include a reflection electrode or a reflection layer. For example, the reflection electrode or the reflection layer may be formed of aluminum-palladium-copper (APC) alloy, and thefirst electrode 162 may have a triple-layered structure of ITO/APC alloy/ITO. Thesecond electrode 192 may have a relatively small thickness for light-transmitting. For example, thesecond electrode 192 may have the light transmittance of about 45 to 50%. - In the electroluminescent display device of the present invention, the
bank 170 may have different heights from thefirst electrode 162 or thesubstrate 110 in a major axis and a minor axis of the pixel region to overcome the thickness non-uniformity problem in the emitting layer. -
FIG. 4 is a schematic plane view of an electroluminescent display device according to a first embodiment of the present invention,FIG. 5 is a schematic cross-sectional view taken along the line V-V ofFIG. 4 .FIG. 6 is a schematic cross-sectional view taken along the line VI-VI ofFIG. 4 , andFIG. 7 is a schematic cross-sectional view taken along the line VII-VII ofFIG. 4 . For the sake of explanation, some elements are omitted. - Referring to
FIGS. 4 to 7 , a plurality of pixel regions P are defined on thesubstrate 110. - The pixel region P is an effective light-emitting area for transmitting the light, and a distance between adjacent pixel regions is different in a first direction and a second direction. Namely, the adjacent pixel regions P along the first direction has a first interval distance d1, and the adjacent pixel regions P along the second direction has a second interval distance d2 being greater than the first interval distance d1. The pixel region P may have a shape having a major axis and a minor axis, e.g., a rectangular shape. The minor axis is parallel to the first direction, and the major axis is parallel to the second direction.
- Among a first pixel region P1, a second pixel region P2, which is adjacent to the first pixel region P1 along the first direction, and a third pixel region P3, which is adjacent to the first pixel region P1 along the second direction, the first and second pixel regions P1 and P2 are spaced apart from each other by the first interval distance d1, and the first and third pixel regions P1 and P3 are spaced apart from each other by the second interval distance d2.
- The
gate insulating layer 130, theinterlayer insulating layer 140 and thepassivation layer 160 are sequentially formed on or over thesubstrate 110. - The
gate insulating layer 130 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride, and the interlayer insulatinglayer 140 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl. Thepassivation layer 160 may be formed of an organic insulating material, e.g., benzocyclobutene or photo-acryl. An inorganic insulating layer formed of silicon oxide or silicon nitride may be further formed between the interlayer insulatinglayer 140 and thepassivation layer 160. - The
passivation layer 160 includes agroove 160 b in a space between the pixel regions P adjacent to each other along the first direction. Thegroove 160 b may have a rectangular shape. For example, thegroove 160 b may be formed in thepassivation layer 160 between the first and second pixel regions P1 and P2, and thegroove 160 b may not be formed in thepassivation layer 160 between the first and third pixel regions P1 and P3. - As explained with
FIG. 3 , the switching TFT, the driving TFT, the storage capacitor, gate line, data line and power line are formed under thepassivation layer 160. - The
first electrode 162 is formed on thepassivation layer 160. Thefirst electrode 162 in each pixel region P1 is separated from each other and contacts the drain electrode of the driving TFT through the drain contact hole of thepassivation layer 160. - The
bank 170 is formed on an edge of thefirst electrode 162. Thebank 170 is positioned between adjacent pixel regions P. Thebank 170 has the transmittinghole 170 a exposing thefirst electrode 162 in each pixel region P and covers the edge of thefirst electrode 162. The transmittinghole 170 a may have a rectangular shape. - The
bank 170 includes afirst bank 172 and asecond bank 174 on thefirst bank 172. A width of thefirst bank 172 is greater than that of thesecond bank 174. Thefirst bank 172 includes a material having a relatively high surface energy such that a contact angle of an emitting material to thefirst bank 172 is reduced. Thesecond bank 174 includes a material having a relatively low surface energy such that a contact angle of an emitting material to thesecond bank 174 is increased such that an overflow of the emitting material into adjacent pixel region is prevented. For example, thefirst bank 172 may be formed of an inorganic material or an organic material each having a hydrophilic property, and thesecond bank 174 may be formed of an organic material having a hydrophobic property. - The
first bank 172 includes afirst transmitting hole 172 a, and thesecond bank 174 includes asecond transmitting hole 174 a. Thesecond transmitting hole 174 a has a size being larger than thefirst transmitting hole 172 a and overlaps thefirst transmitting hole 172 a such that the transmittinghole 170 a is defined by the first and second transmitting holes 172 a and 174 a. As a result, a width of thesecond bank 174 is smaller than that of thefirst bank 172 such that a portion of thefirst bank 172 does not covered by thesecond bank 174. Namely, the portion of thefirst bank 172 exposes and protrudes beyond thesecond bank 174. - Each of the first and
second banks second banks second banks bank 170 may have a single-layered structure of an organic material having a hydrophobic property. - The emitting layer is formed on the
first electrode 162. Namely, the emitting layer contacts thefirst electrode 162 in the transmittinghole 170 a. The second electrode is formed over an entire surface of thesubstrate 110. The emitting layer may include the hole auxiliary layer, the EML and the electron auxiliary layer sequentially stacked on thefirst electrode 162. For example, the hole auxiliary layer may include at least one of the HIL and the HTL, and the electron auxiliary layer may include at least one of the ETL and the EIL. A part or a total of the emitting layer may be formed by a solution process. For example, the hole auxiliary layer and the EML may be formed by the solution process. - As mentioned above, the
passivation layer 160 includes thegroove 160 b in a space between adjacent pixel regions P along the first direction, and thebank 170 has a height difference in the first and second directions due to thegroove 160 b. - In more detail, the
bank 170 is formed according to a step difference in thegroove 160 b of thepassivation layer 160 such that thebank 170 between adjacent pixel regions P, e.g., the first and second pixel regions P1 and P2, along the first direction has a first height h1 from thefirst electrode 162, and thebank 170 between adjacent pixel regions P, e.g., the first and third pixel regions P1 and P3, along the second direction has a second height h2 from thefirst electrode 162. The first height h1 is smaller than the second height h2. Namely, thebank 170 has substantially the same thickness in a space between the first and second pixel regions P1 and P2 and in a space between the first and third pixel regions P1 and P3, while thebank 170 has a height difference. As shown inFIG. 5 , a portion of a bottom surface of thebank 170 between the first and second pixel regions P1 and P2 is disposed lower than a bottom surface of thefirst electrode 162. - When the
bank 170 has the same height in the first and second directions with different interval distances d1 and d2 between adjacent pixel regions along the first and second directions, the influence in one pixel region P, i.e., the first pixel region P1, from adjacent pixel regions P, i.e., the second and third pixel regions P2 and P3, along the first and second directions is different in the solution process of the emitting layer such that the emitting layer has the non-uniform thickness. - Namely, with the
bank 170 having the same height in the first and second directions, in the drying process of the solution of the emitting layer, the influence of the solution in the adjacent pixel regions P along the first direction is relatively high, while the influence of the solution in the adjacent pixel regions P along the second direction is relatively low. Accordingly, there is a difference in an evaporation rate of the solvent in the solution at the first and second directions. Since the evaporation rate of the solvent in the second direction is faster than that in the first direction, the emitting layer having the uniform thickness is difficult to be provided. - In the present invention, the
groove 160 b is formed in thepassivation layer 160 such that an upper surface of thebank 170 between adjacent pixel regions P along the first direction has a height being smaller than an upper surface of thebank 170 between adjacent pixel regions P along the second direction. Namely, thebank 170 has the first height h1 in a space between adjacent pixel regions P along the first direction and the second height h2, which is greater than the first height h1, in a space between adjacent pixel regions P along the second direction. - Namely, although the
bank 170 between adjacent pixel regions P along the first direction and thebank 170 between adjacent pixel regions P along the second direction have the same thickness, a height of a bottom surface of thebank 170, i.e., a height of the upper surface of thepassivation layer 160, between adjacent pixel regions P along the first direction is smaller than a height of a bottom surface of thebank 170, i.e., a height of the upper surface of thepassivation layer 160, between adjacent pixel regions P along the second direction by thegroove 160 b. Accordingly, the first height h1 of thebank 170 in a space between adjacent pixel regions P along the first direction is smaller than the second height h2 of thebank 170 in a space between adjacent pixel regions P along the second direction. - On the other hand, the
bank 170 may have a height difference in the first and second direction and has a thickness difference without thegroove 160 b. In this instance, there may be a problem of a thickness non-uniformity and/or a profile non-uniformity in an organic layer. In a solution process of the organic layer, a hydrophobic property of the bank is important fact to the thickness non-uniformity and/or the profile non-uniformity. However, when making the bank, which has the thickness difference, the bank has a difference of the hydrophobicity in a space between adjacent pixel regions along the first direction and along the second direction. For example, a thicker portion of the bank may have the hydrophobicity being smaller than a thinner portion of the bank. As a result, the organic layer formed in the pixel region may have a thickness non-uniformity and/or a profile non-uniformity. - However, in the present invention, since the
bank 170 has a height difference in the first and second direction and has substantially the same thickness with thegroove 160 b, the above problem is prevented. - In a space between adjacent pixel regions P along the first direction, a contact position of the
bank 170 and thepassivation layer 160 is positioned at a first height from thesubstrate 110. In a space between adjacent pixel regions P along the second direction, a contact position of thebank 170 and thepassivation layer 160 is positioned at a second height, which is greater than the first height, from thesubstrate 110. - In this instance, the first height h1 may be substantially equal to the height of the bank in the related art electroluminescent display device, and the second height h2 may be greater than the height of the bank in the related art electroluminescent display device. The solvent in the pixel region is efficiently trapped at the second direction and the evaporation rate of the solvent at the second direction is decreased such that the pixel region has substantially the same evaporation rates in the first and second directions. As a result, the emitting layer having improved thickness uniformity is provided.
- Alternatively, the first height h1 may be smaller than the height of the bank in the related art electroluminescent display device, and the second height h2 may be substantially equal to the height of the bank in the related art electroluminescent display device. The solvent in the pixel region is less trapped at the first direction and the evaporation rate of the solvent at the first direction is increased such that the pixel region has substantially the same evaporation rates in the first and second directions. As a result, the emitting layer having improved thickness uniformity is provided.
- When the HIL is formed by the solution process on the bank structure of the present invention, in one pixel region P, a maximum thickness difference (e.g., deviation) in the HIL at the first direction is about 5.3 mm, and an average thickness difference in the HIL at the first direction is about 2.45 mm. A maximum thickness difference (e.g., deviation) in the HIL at the second direction is about 12.2 mm, and an average thickness difference in the HIL at the second direction is about 5.77 mm.
- On the other hand, when the HIL is formed by the solution process on the bank structure of the related art electroluminescent display device, in one pixel region P, a maximum thickness difference in the HIL at the first direction is about 8.4 mm, and an average thickness difference in the HIL at the first direction is about 3.40 mm. A maximum thickness difference (e.g., deviation) in the HIL at the second direction is about 15.7 mm, and an average thickness difference in the HIL at the second direction is about 12.7 mm.
- Namely, in the electroluminescent display device according to the present invention, the thickness uniformity of the emitting layer is improved.
- In
FIGS. 5 and 7 , a depth of thegroove 160 b is smaller than a thickness of thepassivation layer 160, but it is not limited thereto. The depth of thegroove 160 b may be equal to the thickness of thepassivation layer 160 such that a surface of the interlayer insulatinglayer 140 may be exposed through thegroove 160 b. In this instance, thefirst bank 172 may contact theinterlayer insulating layer 140. - In the electroluminescent display device of the present invention, since at least a part of the emitting layer is formed by the solution process, the production cost is reduced and the electroluminescent display device of large size and/or high resolution is provided.
- In addition, with the bank having a difference in the height, the evaporation rate of the solvent at the first and second direction is uniformed such that the thickness uniformity of the emitting layer and the display quality are improved.
- Moreover, the emitting efficiency, the lifetime, the driving voltage and the color property of the electroluminescent display device are improved.
- The shape of the
groove 160 b in thepassivation layer 160 may be changed according to a shape of the pixel region P, i.e., an effective emitting area. -
FIG. 8 is a schematic plane view of an electroluminescent display device according to a second embodiment of the present invention. - As shown in
FIG. 8 , a plurality of pixel regions P are defined on a substrate 110 (ofFIG. 5 ), and each pixel region P may have a narrow circle shape in a plane view. The pixel region P includes a minor axis along the first direction and a major axis along the second direction. Namely, the pixel region P includes semicircle-shaped ends and a linear center portion connecting the semicircle-shaped ends. - The
bank 170 includes a transmittinghole 170 a corresponding to the shape of the pixel region P. Namely, the transmittinghole 170 a also has a narrow circle shape in a plane view. - The
bank 170 includes afirst bank 172 and asecond bank 174 on thefirst bank 172. Thefirst bank 172 includes afirst transmitting hole 172 a, and thesecond bank 174 includes asecond transmitting hole 174 a. Thesecond transmitting hole 174 a has a size being larger than thefirst transmitting hole 172 a and overlaps thefirst transmitting hole 172 a such that the transmittinghole 170 a is defined by the first and second transmitting holes 172 a and 174 a. As a result, a width of thesecond bank 174 is less than that of thefirst bank 172 such that a portion of thefirst bank 172 does not covered by thesecond bank 174. Namely, the portion of thefirst bank 172 exposes and protrudes beyond thesecond bank 174. - The
groove 160 b is formed in thepassivation layer 160 between adjacent pixel regions P along the first direction. A side surface of thegroove 160 b facing the transmittinghole 170 a has substantially the same shape as a side surface of the transmittinghole 170 a. As a result, the side surfaces of thegroove 160 b and the transmittinghole 170 a have a constant distance. On the other hand, thegroove 160 b includes a protrusion at a corner (four corners) toward a corner of the transmittinghole 170 a. Accordingly, thegroove 160 b and the transmittinghole 170 a have a constant distance at the corner as well as the side surface. - In the embodiment(s) of the present invention, a shape of the
groove 160 b is changed according to a shape of the pixel region P, i.e., a shape of the transmittinghole 170 a, to have a constant distance between the pixel region P and thegroove 160 b. As a result, the emitting layer having the thickness uniformity is provided. -
FIG. 9 is a cross-sectional view of an electroluminescent display device according to a third embodiment of the present invention.FIG. 9 shows a cross-sectional view taken along the line VII-VII ofFIG. 4 . - As shown in
FIG. 9 , thegate insulating layer 230, theinterlayer insulating layer 240 and thepassivation layer 260 are sequentially formed on or over thesubstrate 210, and thebank 270 including the first andsecond banks passivation layer 260. - The
passivation layer 260 includes agroove 260 b in a space between the pixel regions P (ofFIG. 4 ) adjacent to each other along the first direction. A height in a portion of thebank 270 in thegroove 260 b is reduced. - In the
groove 260 b, a center depth is greater than an edge depth in the second direction. The depth of thegroove 260 b may be gradually decreased from the center to the edge along the second direction. Namely, an upper surface of thepassivation layer 260 corresponding to thegroove 260 b may have a convex shape toward thesubstrate 210. - For example, the
groove 260 b may be formed by a photolithography process using a mask having a light transmitting gradual difference from a center to an edge. -
FIG. 10 is a schematic cross-sectional view of an electroluminescent display device according to a fourth embodiment of the present invention.FIG. 10 shows a cross-sectional view taken along the line VII-VII ofFIG. 4 . - As shown in
FIG. 10 , thegate insulating layer 330, theinterlayer insulating layer 340 and thepassivation layer 360 are sequentially formed on or over thesubstrate 310, and the bank 370 including the first andsecond banks passivation layer 360. - The
passivation layer 360 includes agroove 360 b in a space between the pixel regions P (ofFIG. 4 ) adjacent to each other along the first direction. A height in a portion of the bank 370 in thegroove 360 b is reduced. - In the
groove 360 b, a center depth is greater than an edge depth in the second direction. Thegroove 360 b may have a first depth in the center and a second depth, which is smaller than the first depth, in both edges along the second direction. Namely, thegroove 360 b may have a dual step difference structure, e.g., a stair shape. - For example, the
groove 360 b may be formed by a photolithography process using two masks having a light transmitting difference or a half-ton mask. - Due to the shape of the
groove 360 b, the thickness difference of a W-shaped emitting layer may be efficiently uniformed. -
FIG. 11 is a schematic cross-sectional view of an electroluminescent display device according to a fifth embodiment of the present invention.FIG. 11 shows a cross-sectional view taken along the line VII-VII ofFIG. 4 . - As shown in
FIG. 11 , thegate insulating layer 430, the interlayer insulating layer 440 and thepassivation layer 460 are sequentially formed on or over thesubstrate 410, and thebank 470 including the first andsecond banks passivation layer 460. - The
passivation layer 460 includes agroove 460 b in a space between the pixel regions P (ofFIG. 4 ) adjacent to each other along the first direction. A height in a portion of thebank 470 in thegroove 460 b is reduced. - In the
groove 460 b, a center depth is smaller than an edge depth in the second direction. The depth of thegroove 460 b may be gradually decreased from the edge to the center along the second direction. Namely, an upper surface of thepassivation layer 460 corresponding to thegroove 460 b may have a convex shape toward thebank 470. - In this instance, a height of the
bank 470 in an edge of thegroove 460 b, which faces the transmitting hole 470 a, is efficiently reduced such that an evaporation rate of the solvent in the emitting material solution is efficiently increased. As a result, the thickness uniformity of the emitting layer is improved. - For example, the
groove 460 b may be formed by a photolithography process using a mask having a light transmitting gradual difference from a center to an edge. -
FIG. 12 is a schematic cross-sectional view of an electroluminescent display device according to a sixth embodiment of the present invention.FIG. 12 shows a cross-sectional view taken along the line V-V ofFIG. 4 . - As shown in
FIG. 12 , thegate insulating layer 530, theinterlayer insulating layer 540 and thepassivation layer 560 are sequentially formed on or over thesubstrate 510, and thebank 570 including the first andsecond banks passivation layer 560. - The
passivation layer 560 includes agroove 560 b in a space between the pixel regions P (ofFIG. 4 ) adjacent to each other along the first direction. A width of thegroove 560 b is substantially equal to a distance between adjacentfirst electrodes 562. A height in a portion of thebank 570 in thegroove 560 b is reduced. - The
groove 560 b has a rectangular cross-section. Alternatively, thegroove 560 b may have a round cross-section similar to a shape of thegroove 260 b (ofFIG. 9 ) or a shape of thegroove 460 b (ofFIG. 11 ). - In the present invention, a height of the
bank 570 between adjacent pixel regions along the first direction is smaller than that of thebank 570 between adjacent pixel regions along the second direction. Accordingly, even though a distance between adjacent pixel regions is different along the first and second directions, an evaporation rate of the solvent in the emitting material solution is uniformed such that the emitting layer having the thickness uniformity is provided. -
FIGS. 13A to 13C are schematic cross-sectional view illustrating a fabricating process of a portion of an electroluminescent display device according to the sixth embodiment of the present invention. - As shown in
FIG. 13A , thegate insulating layer 530, theinterlayer insulating layer 540 and thepassivation layer 560 are formed on thesubstrate 510. A conductive material layer is formed on thepassivation layer 560. The conductive material layer may include a transparent conductive material such as indium-tin-oxide (ITO) or indium-zinc-oxide (IZO). The conductive material layer is patterned to form thefirst electrode 562 in each pixel region. - Referring to
FIG. 3 , the semiconductor layer 122 is formed on thesubstrate 510 before forming thegate insulating layer 530, and thegate electrode 132 is formed on thegate insulating layer 530 before forming the interlayer insulatinglayer 540. In addition, thesource electrode 152 and thedrain electrode 154 are formed on theinterlayer insulating layer 540 before forming thepassivation layer 560. - Next, as shown in
FIG. 13B , a portion of thepassivation layer 560 is patterned by an etching process using thefirst electrode 562 as an etching mask to form thegroove 560 b. The etching process may be an anisotropic dry etching process. As a result, an end of thegroove 560 b may exactly match with or correspond to an end of thefirst electrode 562. Namely, a width of thegroove 560 b is substantially equal to a distance between adjacentfirst electrodes 562. - Alternatively, the
passivation layer 560 may be patterned to form thegroove 560 b before forming thefirst electrode 562. In this instance, thegroove 560 b and thedrain contact hole 160 a (ofFIG. 3 ) may be formed by a single mask process. - In this instance, by a mis-alignment of the
first electrode 562 and thegroove 560 b, an end of thefirst electrode 562 may be positioned in thegroove 560 b such that a height of thebank 570 in thegroove 560 b may be increased. - However, when the
groove 560 b is patterned using thefirst electrode 562 as an etching mask, thefirst electrode 562 is not positioned in thegroove 560 b. Accordingly, the above problem is prevented. - Next, as shown in
FIG. 13C , an insulating material layer is formed on thefirst electrode 562 and thepassivation layer 560. The insulating material layer is patterned to form thebank 570. The emitting layer 180 (ofFIG. 3 ) and thesecond electrode 192 are formed on thefirst electrode 562 and optionally on thebank 570. -
FIG. 14 is a schematic plane view of an electroluminescent display device according to a seventh embodiment of the present invention.FIG. 15 is a schematic cross-sectional view taken along the line XV-XV ofFIG. 14 , andFIG. 16 is a schematic cross-sectional view taken along the line XVI-XVI ofFIG. 14 . - Referring to
FIGS. 14 to 16 , a plurality of pixel regions P are defined on thesubstrate 610. - The pixel region P is an effective light-emitting area for transmitting the light, and a distance between adjacent pixel regions is different in a first direction and a second direction. Namely, the adjacent pixel regions P along the first direction has a first interval distance d1, and the adjacent pixel regions P along the second direction has a second interval distance d2 being greater than the first interval distance d1. The pixel region P may have a shape having a major axis and a minor axis, e.g., a rectangular shape. The minor axis is parallel to the first direction, and the major axis is parallel to the second direction.
- Among a first pixel region P1, a second pixel region P2, which is adjacent to the first pixel region P1 along the first direction, and a third pixel region P3, which is adjacent to the first pixel region P1 along the second direction, the first and second pixel regions P1 and P2 are spaced apart from each other by the first interval distance d1, and the first and third pixel regions P1 and P3 are spaced apart from each other by the second interval distance d2.
- The
gate insulating layer 630, theinterlayer insulating layer 640 and thepassivation layer 660 are sequentially formed on or over thesubstrate 610. - The
gate insulating layer 630 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride, and the interlayer insulatinglayer 640 may be formed of an inorganic material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl. Thepassivation layer 660 may be formed of an organic insulating material, e.g., benzocyclobutene or photo-acryl. An inorganic insulating layer formed of silicon oxide or silicon nitride may be further formed between the interlayer insulatinglayer 140 and thepassivation layer 660. - The
passivation layer 660 includes a protrudingportion 661 in a space between the pixel regions P adjacent to each other along the second direction. Namely, the protrudingportion 661 of thepassivation layer 660 is positioned between the first and third pixel regions P1 and P3. As a result, an upper surface of thepassivation layer 660 between the first and second pixel regions P1 and P2 adjacent along the first direction has a third height h3 from thesubstrate 610, and an upper surface of thepassivation layer 660, i.e., the protrudingportion 661, between the first and third pixel regions P1 and P3 adjacent along the second direction has a fourth height h4, which is greater than the third height h3, from thesubstrate 610. The protrudingportion 661 is formed on thepassivation layer 660 between the first and third pixel regions P1 and P3, while there is no protrudingportion 661 on thepassivation layer 660 between the first and second pixel regions P1 and P2 such that thepassivation layer 660 between the first and second pixel regions P1 and P2 provides a flat top surface. - As explained with
FIG. 3 , the switching TFT, the driving TFT, the storage capacitor, gate line, data line and power line are formed under thepassivation layer 660. - The
first electrode 662 is formed on thepassivation layer 660. Thefirst electrode 662 in each pixel region P1 is separated from each other and contacts the drain electrode of the driving TFT through the drain contact hole of thepassivation layer 660. - The
bank 670 is formed on an edge of thefirst electrode 662. Thebank 670 is positioned between adjacent pixel regions P. Thebank 670 has the transmitting hole 670 a exposing thefirst electrode 662 in each pixel region P and covers the edge of thefirst electrode 662. The transmitting hole 670 a may have a rectangular shape. - The
bank 670 includes afirst bank 672 and asecond bank 674 on thefirst bank 672. A width of thefirst bank 672 is greater than that of thesecond bank 674. Thefirst bank 672 includes a material having a relatively high surface energy such that a contact angle of an emitting material to thefirst bank 672 is reduced. Thesecond bank 674 includes a material having a relatively low surface energy such that a contact angle of an emitting material to thesecond bank 674 is increased such that an overflow of the emitting material into adjacent pixel region is prevented. For example, thefirst bank 672 may be formed of an inorganic material or an organic material each having a hydrophilic property, and thesecond bank 674 may be formed of an organic material having a hydrophobic property. - The
first bank 672 includes afirst transmitting hole 672 a, and thesecond bank 674 includes a second transmitting hole 674 a. The second transmitting hole 674 a has a size being larger than thefirst transmitting hole 672 a and overlaps thefirst transmitting hole 672 a such that the transmitting hole 670 a is defined by the first and second transmitting holes 672 a and 674 a. As a result, a width of thesecond bank 674 is smaller than that of thefirst bank 672 such that a portion of thefirst bank 672 does not covered by thesecond bank 674. Namely, the portion of thefirst bank 672 exposes and protrudes beyond thesecond bank 674. - Each of the first and
second banks second banks second banks bank 670 may have a single-layered structure of an organic material having a hydrophobic property. - The emitting layer is formed on the
first electrode 662. Namely, the emitting layer contacts thefirst electrode 662 in the transmitting hole 670 a. The second electrode is formed over an entire surface of thesubstrate 610. The emitting layer may include the hole auxiliary layer, the EML and the electron auxiliary layer sequentially stacked on thefirst electrode 662. For example, the hole auxiliary layer may include at least one of the HIL and the HTL, and the electron auxiliary layer may include at least one of the ETL and the EIL. A part or a total of the emitting layer may be formed by a solution process. For example, the hole auxiliary layer and the EML may be formed by the solution process. - As mentioned above, the
passivation layer 660 includes the protrudingportion 661 in a space between adjacent pixel regions P along the second direction, and thebank 670 has a height difference in the first and second directions due to the protrudingportion 661. - In more detail, the
bank 670 is formed according to a step difference in the protrudingportion 661 of thepassivation layer 660 such that thebank 670 between adjacent pixel regions P, e.g., the first and second pixel regions P1 and P2, along the first direction has a fifth height h5 from thesubstrate 610, and thebank 670 between adjacent pixel regions P, e.g., the first and third pixel regions P1 and P3, along the second direction has a sixth height h6 from thesubstrate 610. The fifth height h5 is smaller than the sixth height h6. Namely, thebank 670 has substantially the same thickness in a space between the first and second pixel regions P1 and P2 and in a space between the first and third pixel regions P1 and P3, while thebank 670 has a height difference. - When the
bank 670 has the same height in the first and second directions with different interval distances d1 and d2 between adjacent pixel regions along the first and second directions, the influence in one pixel region P, i.e., the first pixel region P1, from adjacent pixel regions P, i.e., the second and third pixel regions P2 and P3, along the first and second directions is different in the solution process of the emitting layer such that the emitting layer has the non-uniform thickness. - Namely, with the
bank 670 having the same height in the first and second directions, in the drying process of the solution of the emitting layer, the influence of the solution in the adjacent pixel regions P along the first direction is relatively high, while the influence of the solution in the adjacent pixel regions P along the second direction is relatively low. Accordingly, there is a difference in an evaporation rate of the solvent in the solution at the first and second directions. Since the evaporation rate of the solvent in the second direction is faster than that in the first direction, the emitting layer having the uniform thickness is difficult to be provided. - In the present invention, the protruding
portion 661 is formed in thepassivation layer 660 such that an upper surface of thebank 670 between adjacent pixel regions P along the first direction has a height being smaller than an upper surface of thebank 670 between adjacent pixel regions P along the second direction. Namely, thebank 670 has the fifth height h5 in a space between adjacent pixel regions P along the first direction and the sixth height h6, which is greater than the fifth height h5, in a space between adjacent pixel regions P along the second direction. - Namely, although the
bank 670 between adjacent pixel regions P along the first direction and thebank 670 between adjacent pixel regions P along the second direction have the same thickness, a third height h3 of a bottom surface of thebank 670, i.e., a height of the upper surface of thepassivation layer 660, between adjacent pixel regions P along the first direction is smaller than a fourth height h4 of a bottom surface of thebank 670, i.e., a height of the upper surface of thepassivation layer 660, between adjacent pixel regions P along the second direction by the protrudingportion 661. Accordingly, the fifth height h5 of thebank 670 in a space between adjacent pixel regions P along the first direction is smaller than the sixth height h6 of thebank 670 in a space between adjacent pixel regions P along the second direction. - In the electroluminescent display device of the present invention, since at least a part of the emitting layer is formed by the solution process, the production cost is reduced and the electroluminescent display device of large size and/or high resolution is provided.
- In addition, with the bank having a difference in the height, the evaporation rate of the solvent at the first and second direction is uniformed such that the thickness uniformity of the emitting layer and the display quality are improved.
- Moreover, the emitting efficiency, the lifetime, the driving voltage and the color property of the electroluminescent display device are improved.
- It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the invention. Thus, it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.
Claims (25)
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EP3321985B1 (en) | 2020-12-30 |
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