US20160374518A1 - Laminated shower curtains - Google Patents

Laminated shower curtains Download PDF

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Publication number
US20160374518A1
US20160374518A1 US15/197,213 US201615197213A US2016374518A1 US 20160374518 A1 US20160374518 A1 US 20160374518A1 US 201615197213 A US201615197213 A US 201615197213A US 2016374518 A1 US2016374518 A1 US 2016374518A1
Authority
US
United States
Prior art keywords
antimicrobial
shower curtain
liquid impermeable
laminated
fabric layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US15/197,213
Inventor
David M. Baines
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Maytex Mills Inc
Original Assignee
Maytex Mills Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Maytex Mills Inc filed Critical Maytex Mills Inc
Priority to US15/197,213 priority Critical patent/US20160374518A1/en
Assigned to MAYTEX MILLS, INC. reassignment MAYTEX MILLS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BAINES, DAVID M.
Publication of US20160374518A1 publication Critical patent/US20160374518A1/en
Assigned to BNP PARIBAS, AS COLLATERAL AGENT reassignment BNP PARIBAS, AS COLLATERAL AGENT SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MAYTEX MILLS, INC.
Priority to US16/917,250 priority patent/US10799074B1/en
Abandoned legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K3/00—Baths; Douches; Appurtenances therefor
    • A47K3/28—Showers or bathing douches
    • A47K3/38—Curtain arrangements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
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    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
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Definitions

  • the present invention relates to shower curtains having water repellency and mildew resistance.
  • the present invention provides laminated shower curtains having an antimicrobial pre-treated fabric layer comprising a first antimicrobial agent, and an antimicrobial liquid impermeable film layer bonded to the antimicrobial pre-treated fabric layer comprising a polymeric material and a second antimicrobial agent.
  • the antimicrobial pre-treated fabric layer and the antimicrobial pre-treated fabric layer of the laminated shower curtains may be individually produced before being bonded together.
  • An aspect of the present invention is to provide a laminated shower curtain comprising an antimicrobial pre-treated fabric layer comprising a first antimicrobial agent, and an antimicrobial liquid impermeable film layer bonded to the antimicrobial pre-treated fabric layer comprising a polymeric material and a second antimicrobial agent.
  • Another aspect of the present invention is to provide a method of making a laminated shower curtain material comprising laminating a pre-treated fabric layer comprising a first antimicrobial agent with a liquid impermeable film layer comprising a polymeric material and a second antimicrobial agent to produce the laminated shower curtain material.
  • FIG. 1 is a partially schematic side sectional view of a portion of a laminated shower curtain in accordance with an embodiment of the present invention.
  • FIG. 2 is a flow chart of the processing steps to make laminated shower curtains in accordance with an embodiment of the present invention.
  • FIG. 3 is a partially schematic illustration of the processing steps to make laminated shower curtains in accordance with an embodiment of the present invention.
  • the present invention provides laminated shower curtains that combine water repellency and mildew resistance.
  • the laminated shower curtains of the present invention comprise a fabric layer laminated with a liquid impermeable film layer. Before lamination, the fabric layer of the laminated shower curtain is pre-treated with an antimicrobial agent.
  • the liquid impermeable film layer may include a co-extrusion of polymer material and a second antimicrobial agent.
  • the term “shower curtain” includes curtains for use with a shower, a bath, or the like.
  • the term “curtain” may refer to a single curtain that is used by itself in a shower or bath, or is used as a liner for an additional curtain.
  • antiviral means substances, such as bactericidal, fungicidal, antiviral and the like, that kill or inhibit the growth of microorganisms.
  • liquid impermeable means impermeable or substantially impermeable to liquids, such as water.
  • a liquid impermeable film layer of the present invention prevents liquid water from flowing through the thickness of the film.
  • liquid permeable means permeable or substantially permeable to liquids, such as water.
  • a liquid permeable fabric layer of the present invention prior to lamination with the film layer, allows at least some liquid water to flow through the thickness of the fabric.
  • gas impermeable means impermeable or substantially impermeable to gas or vapor, such as water vapor, air and the like.
  • a gas impermeable film layer of the present invention prevents water vapor and/or air from passing through the thickness of the film.
  • gas permeable means permeable or substantially permeable to gas or vapor, such as water vapor, air and the like.
  • a gas permeable fabric layer of the present invention prior to lamination with the film layer, allows at least some passage of water vapor and/or air through the thickness of the fabric.
  • FIG. 1 is a partially schematic side sectional view of a portion of a laminated shower curtain 10 in accordance with an embodiment of the present invention, including an antimicrobial pre-treated fabric layer 12 and an antimicrobial liquid impermeable film layer 14 .
  • the laminated shower curtain 10 may include an interface 16 between the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 .
  • the antimicrobial pre-treated fabric layer 12 may typically face away from the shower or bath, while the antimicrobial liquid impermeable film layer 14 may typically face towards the shower or bath.
  • the laminated shower curtain 10 may have any suitable dimensions and features, e.g., as found in conventional standard shower curtains.
  • the dimensions of the laminated shower curtain 10 may be varied depending on the size of the shower or bath.
  • the width of the laminated shower curtain 10 may typically range from 3 to 7 feet, or from 4 to 6.5 feet.
  • the height of the laminated shower curtain 10 may typically range from 5 to 9 feet, or from 6 to 8 feet.
  • the laminated shower curtain 10 may comprise a top edge including standard openings or attachment points for conventional shower curtain rings or hooks (not shown).
  • the top, bottom and/or side edges of the laminated shower curtain 10 may include standard edge treatments as found in conventional shower curtains, such as hemming and the like (not shown).
  • the fabric of the antimicrobial pre-treated fabric layer 12 may have a material weight ranging from 10 to 500 grams per square meter (gsm), for example, from 20 to 200 gsm, or from 50 to 100 gsm. In a particular embodiment, the fabric of the antimicrobial pre-treated fabric layer 12 may have a material weight of 70 gsm. As shown in FIG. 1 , the antimicrobial pre-treated fabric layer 12 may have a thickness T F , and the antimicrobial liquid impermeable film layer 14 may have a thickness T I .
  • the antimicrobial pre-treated fabric layer 12 may have a thickness T F ranging from 0.02 to 3 mm, for example, from 0.05 to 1.5 mm, or from 0.1 to 1 mm, or from 0.2 to 0.75 mm.
  • the antimicrobial pre-treated fabric layer 12 may be made from a liquid permeable and gas permeable fabric material, e.g., the fabric may be permeable to liquid water and to water vapor and/or air.
  • the antimicrobial pre-treated fabric layer 12 may be made from knitted or woven fabric material.
  • the antimicrobial pre-treated fabric layer 12 may comprise any suitable synthetic or natural material, such as polyester, nylon, cotton, or the like.
  • the fabric material of the antimicrobial pre-treated fabric layer 12 may comprise polyester.
  • the first antimicrobial agent of the antimicrobial pre-treated fabric layer 12 may comprise agents that kill microorganisms or inhibit their growth.
  • the first antimicrobial agent may contain at least one metal such as silver, gold, platinum, palladium, iridium, zinc, copper, nickel, tin, titanium, zirconium, molybdenum, iron, antimony, bismuth and the like, or mixtures of these metals with the same or other metals.
  • the first antimicrobial agent can comprise at least one such metal in combination with at least one of oxygen, nitrogen, carbon, boron, sulfur, a halogen (e.g., fluorine, chlorine, bromine, iodine) and/or hydrogen.
  • the first antimicrobial agent may comprise one or more metal oxide, carbide, hydroxide, nitride, nitrate, chloride, boride, sulfide, sulfate, halide, hydride, or metal salts containing metals as described above.
  • the first antimicrobial agent may comprise metal-containing compounds, such as coordination complexes or metal complexes, metal pyrithiones, metal trialkyls, organometallics, microcomposites and the like. The metal(s) components of such compounds may be selected from those listed above.
  • Suitable coordination complexes or metal complexes may include dehydroabietyl amine, 8-hydroxyquinolinium 2-ethylhexoate, copper naphthenate, copper oleate, silver pyrithione, gold pyrithione, zinc pyrithione, copper pyrithione, palladium (II) complexes, silver acetate, silver (I) carbene, zinc ammonium carbonate, copper ammonium carbonate, zinc borate, and the like.
  • suitable metal trialkyls may include tributyl tin oxide, tributyl tin acetate, and the like.
  • suitable organometallics may include copper 8-quinolinolate, and the like.
  • suitable microcomposites may include silver chloride nanoparticles attached to titanium dioxide as a carrier material and the like.
  • the first antimicrobial agent may comprise organic compounds such as phenolics, polybiguanides, quarternary ammonium compounds, isothiazolinones, and N-halamine compounds.
  • suitable phenolics may include triclosan, dalbergin (I) and the like.
  • suitable polybiguanides may include polyhexamethylene biguanides and the like.
  • suitable quarternary ammonium compounds may include domiphen bromid, 3-(trihydroxysilyl) propyldimethyl-octadecyl ammonium chloride, benzalkonium chloride, methylbenzethonium chloride, cetalkonium chloride, cetylpyridinium chloride, cetrimide, dofanium chloride, cetrimonium, benzethonium chloride, tetraethylammonium bromide, didecyldimethylammonium chloride, and the like.
  • Suitable isothiazolinones may include methylisothiazolinone, methylchloroisothiazolinone, benzisothiazolinone, octylisothiazolinone, dichlorooctylisothiazolinone, butylbenzisothiazolinone, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-Butyl-1,2-benzisothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, and the like.
  • N-halamine compounds may include hydantoins, isocyanurates, 1,3-Dichloro-2,2,5,5-tetramethyl-4-imidazolidinone, 1,3-Dibromo-2,2,5,5-tetramet hyl-4-imidazolidinone, 1-Bromo-3-chloro-2,2,5,5-tetramethyl-4-imidazolidinone, and the like.
  • the amount of the first antimicrobial agent contained in or on the antimicrobial pre-treated fabric layer 12 may typically be from 0.1 to 30 weight percent based on the total weight of the fabric of the antimicrobial pre-treated fabric layer 12 and the dry weight of the first antimicrobial agent.
  • the first antimicrobial agent may comprise from 1 to 20 weight percent, or from 2 to 10 weight percent.
  • the antimicrobial liquid impermeable film layer 14 may be both a liquid impermeable and a gas impermeable polymeric material, e.g., the film layer 14 is substantially impermeable to liquid water and to water vapor.
  • the antimicrobial liquid impermeable film layer 14 may comprise a continuous film of any suitable polymeric material, such as polyethylene, polypropylene, polyvinyl chloride, polystyrene, nylon, polycarbonate, polytetrafluoroethylene, polyurethane, and the like.
  • the polymeric material of the antimicrobial liquid impermeable film layer 14 may be a polyethylene material.
  • the antimicrobial liquid impermeable film layer 14 may have a thickness T I ranging from 0.02 to 2 mm, for example, from 0.05 to 1 mm, or from 0.1 to 0.5 mm. In a particular embodiment, the antimicrobial liquid impermeable film layer 14 may have a thickness T I of about 0.2 mm. In an embodiment of the present invention, the thickness T F of the antimicrobial pre-treated fabric layer 12 may be greater than the thickness T I of the impermeable antimicrobial liquid impermeable film layer 14 . In another embodiment, the thicknesses may be the same.
  • the antimicrobial liquid impermeable film layer 14 may comprise the second antimicrobial agent dispersed throughout a polymeric matrix of the antimicrobial liquid impermeable film layer 14 .
  • the antimicrobial liquid impermeable film layer 14 may be coextruded to form a coextrusion.
  • coextrusion when referring to the antimicrobial liquid impermeable film layer, means that the polymer and the second antimicrobial agent are extruded together into a film comprising a polymeric matrix and the second antimicrobial agent dispersed therein.
  • the antimicrobial liquid impermeable film layer 14 may be a composite layer comprising a polymeric matrix with molecules or particles of the second antimicrobial agent dispersed therein.
  • the second antimicrobial agent may be uniformly dispersed throughout the thickness of the antimicrobial liquid impermeable film layer 14 .
  • the second antimicrobial agent may be non-uniformly dispersed, for example, there may be a greater concentration of the second antimicrobial agent on one or both of the exterior surfaces than in the center of the antimicrobial liquid impermeable film layer 14 .
  • the second antimicrobial agent may comprise agents that kill microorganisms or inhibit their growth.
  • the second antimicrobial agent may contain at least one metal such as silver, gold, platinum, palladium, iridium, zinc, copper, nickel, tin, titanium, zirconium, molybdenum, iron, antimony, bismuth and the like, or mixtures of these metals with the same or other metals.
  • the second antimicrobial agent can comprise at least one such metal in combination with at least one of oxygen, nitrogen, carbon, boron, sulfur, a halogen (e.g., fluorine, chlorine, bromine, iodine) and/or hydrogen.
  • the second antimicrobial agent may comprise one or more metal oxide, carbide, hydroxide, nitride, nitrate, chloride, boride, sulfide, sulfate, halide, hydride, or metal salts containing metals as described above.
  • the second antimicrobial agent may comprise metal-containing compounds, such as coordination complexes or metal complexes, metal pyrithiones, metal trialkyls, organometallics, microcomposites and the like. The metal(s) components of such compounds may be selected from those listed above.
  • Suitable coordination complexes or metal complexes may include dehydroabietyl amine, 8-hydroxyquinolinium 2-ethylhexoate, copper naphthenate, copper oleate, silver pyrithione, gold pyrithione, zinc pyrithione, copper pyrithione, palladium (II) complexes, silver acetate, silver (I) carbene, zinc ammonium carbonate, copper ammonium carbonate, zinc borate, and the like.
  • suitable metal trialkyls may include tributyl tin oxide, tributyl tin acetate, and the like.
  • suitable organometallics may include copper 8-quinolinolate, and the like.
  • suitable microcomposites may include silver chloride nanoparticles attached to titanium dioxide as a carrier material and the like.
  • the second antimicrobial agent may comprise organic compounds such as phenolics, polybiguanides, quarternary ammonium compounds, isothiazolinones, and N-halamine compounds.
  • suitable phenolics may include triclosan, dalbergin (I) and the like.
  • suitable polybiguanides include polyhexamethylene biguanides and the like.
  • suitable quarternary ammonium compounds may include domiphen bromid, 3-(trihydroxysilyl) propyldimethyl-octadecyl ammonium chloride, benzalkonium chloride, methylbenzethonium chloride, cetalkonium chloride, cetylpyridinium chloride, cetrimide, dofanium chloride, cetrimonium, benzethonium chloride, tetraethylammonium bromide, didecyldimethylammonium chloride, and the like.
  • Suitable isothiazolinones may include methylisothiazolinone, methylchloroisothiazolinone, benzisothiazolinone, octylisothiazolinone, dichlorooctylisothiazolinone, butylbenzisothiazolinone, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-Butyl-1,2-benzisothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, and the like.
  • N-halamine compounds may include hydantoins, isocyanurates, 1,3-Dichloro-2,2,5,5-tetramethyl-4-imidazolidinone, 1,3-Dibromo-2,2,5,5-tetramethyl-4-imidazolidinone, 1-Bromo-3-chloro-2,2,5,5-tetramethyl-4-imidazolidinone, and the like.
  • the amount of the second antimicrobial agent contained in or on the antimicrobial liquid impermeable film layer 14 coextrusion may be from 0.1 to 30 weight percent based on the total weight of the polymeric material of the antimicrobial liquid impermeable film layer 14 and the weight of the second antimicrobial agent.
  • the second antimicrobial agent may comprise from 1 to 20 weight percent, or from 2 to 10 weight percent.
  • the second antimicrobial agent may be provided in the form of particles having an average particle size ranging from 5 nanometers up to the thickness T I of the antimicrobial liquid impermeable film layer 14 , for example, from 10 nanometers to 1,000 microns, or from 0.1 to 10 microns, or from 0.5 to 5 microns.
  • FIGS. 2 and 3 schematically illustrate processing steps for producing a laminated shower curtain material that may be used to fabricate a laminated shower curtain 10 in accordance with an embodiment of the present invention.
  • the fabric material of the antimicrobial pre-treated fabric layer 12 may begin on a roll 31 .
  • the fabric may then be subjected to an antimicrobial agent treatment 32 .
  • an antimicrobial agent solution 61 may be contained in a wet bath 60 .
  • the fabric may be continuously fed through the wet bath 60 of antimicrobial agent solution 61 .
  • the solution 61 may be a water-based aqueous solution or an organic solvent-based solution.
  • the antimicrobial agent treatment 32 may be applied in any other manner, such as spraying, brushing, rolling and the like.
  • the treated fabric layer is allowed to dry 33 to remove the water or organic solvent, and to thereby produce the antimicrobial pre-treated fabric layer 12 .
  • the drying 33 of the antimicrobial pre-treated fabric layer 12 may include air drying or drying at elevated temperatures.
  • the antimicrobial pre-treated fabric layer 12 may be rolled.
  • the antimicrobial liquid impermeable film layer 14 may be formed by combining a polymer material 41 and a second antimicrobial agent 42 in an extrusion feeding system.
  • the mixture of the polymer material 41 and the second antimicrobial agent 42 may then be heated to form a molten mixture 43 .
  • the molten mixture 43 may then be extruded 44 to form the antimicrobial liquid impermeable film layer 14 .
  • the antimicrobial liquid impermeable film layer 14 thus comprises a coextrusion of the polymer material 41 and the second antimicrobial agent 42 .
  • the antimicrobial liquid impermeable film layer 14 coextrusion may be rolled 45 to form a roll of liquid impermeable film layer 14 .
  • the antimicrobial liquid impermeable film layer 14 may be directly extruded onto the antimicrobial pre-treated fabric layer 12 .
  • the antimicrobial treatments may be individually applied to the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 before they are laminated together.
  • Such individual treatments allow for different antimicrobial agents to be applied to the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 .
  • the use of different antimicrobial agents allows for the selection of first and second antimicrobial agents that work more effectively with the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 .
  • the use of such individual treatments avoids the necessity of treating a single fabric material with both water repellency chemicals and mildew resistant chemicals.
  • the antimicrobial liquid impermeable film layer 14 can be deposited on the surface of the antimicrobial pre-treated fabric layer 12 through a lamination process 51 .
  • the lamination process 51 may use heat and/or pressure to combine the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 into a laminated structure.
  • the antimicrobial liquid impermeable film layer 14 may be heated and passed through a upper nip-roller 71 and a lower nip-roller 72 to thereby bond the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 together.
  • other types of pressure-applying machines may be used.
  • the antimicrobial liquid impermeable film layer 14 may not significantly infiltrate the antimicrobial pre-treated fabric layer 12 , but is sufficiently bonded thereto to prevent delamination during use.
  • no other adhesive is used to combine the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 .
  • an adhesive may be used in other embodiments.
  • the antimicrobial liquid impermeable film layer 14 is laminated 51 to the antimicrobial pre-treated fabric layer 12 , the antimicrobial liquid impermeable film layer 14 provides a continuous film that allows the laminated shower curtains 10 to be both liquid impermeable and gas impermeable. After lamination, the laminated material of the shower curtain 10 may then be rolled 52 .
  • the roll 52 of the laminated material may be formed into a laminated shower curtain 10 by conventional techniques known to those skilled in the art.
  • the laminated material may be cut to the desired dimensions and conventional edge treatment such as hemming may be applied to the top, bottom and side edges.
  • the top edge of the laminated shower curtain 10 may be provided with standard holes or attachment points for shower curtain rings or hooks by conventional techniques.
  • Samples of laminated shower curtain materials of the present invention were tested for mildew resistance against sterilized control samples comprising sterilized filter paper. The tests were conducted in accordance with AATCC Test Method 30-2013 Antifungal activity, Assessment on Textile Materials: Mildew and Rot Resistance of Textile Materials—Test III: Agar Plate: Aspergillus Niger ATCC 6275. Three laminated shower curtain materials of the present invention were cut into multiple disc-shaped samples. For each type of laminated shower curtain material tested, one of the test discs was tested on its “Face” side and one of the test discs was tested on its “Back” side. The combined test results are listed in Table 1 below.
  • All of the laminated shower curtain test disc samples corresponding to the present invention exhibited no growth (no test organisms visible by the naked eye or under a microscope; 0% of the surface area of the test disc covered with the test organism), while all of the sterilized control samples exhibited macroscopic growth (visible to the naked eye; 100% of the surface area of the test disc covered with the test organism).

Abstract

Laminated shower curtains are disclosed having an antimicrobial pre-treated fabric layer comprising a first antimicrobial agent, and an antimicrobial liquid impermeable film layer bonded to the antimicrobial pre-treated fabric layer comprising a polymeric material and a second antimicrobial agent. The antimicrobial pre-treated fabric layer and the antimicrobial pre-treated fabric layer of the laminated shower curtains may be individually produced before being bonded together.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • This application claims the benefit of U.S. Provisional Patent Application Ser. No. 62/185,996, filed on Jun. 29, 2015, which is incorporated herein by reference.
    • FIELD OF THE INVENTION
  • The present invention relates to shower curtains having water repellency and mildew resistance.
    • BACKGROUND INFORMATION
  • The shower curtain industry has struggled and failed to produce a fabric liner that combines the needed water repellency and passes standard testing for mildew resistance. Conventionally, the problem faced by the industry was that two different chemical treatments previously used to accomplish a water impermeable and mildew resistant fabric fought each other. Accordingly, a need exists for shower curtains having an improved combination of water repellency and mildew resistance.
    • SUMMARY OF THE INVENTION
  • The present invention provides laminated shower curtains having an antimicrobial pre-treated fabric layer comprising a first antimicrobial agent, and an antimicrobial liquid impermeable film layer bonded to the antimicrobial pre-treated fabric layer comprising a polymeric material and a second antimicrobial agent. The antimicrobial pre-treated fabric layer and the antimicrobial pre-treated fabric layer of the laminated shower curtains may be individually produced before being bonded together.
  • An aspect of the present invention is to provide a laminated shower curtain comprising an antimicrobial pre-treated fabric layer comprising a first antimicrobial agent, and an antimicrobial liquid impermeable film layer bonded to the antimicrobial pre-treated fabric layer comprising a polymeric material and a second antimicrobial agent.
  • Another aspect of the present invention is to provide a method of making a laminated shower curtain material comprising laminating a pre-treated fabric layer comprising a first antimicrobial agent with a liquid impermeable film layer comprising a polymeric material and a second antimicrobial agent to produce the laminated shower curtain material.
  • These and other aspects of the present invention will be more apparent from the following description.
    • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a partially schematic side sectional view of a portion of a laminated shower curtain in accordance with an embodiment of the present invention.
  • FIG. 2 is a flow chart of the processing steps to make laminated shower curtains in accordance with an embodiment of the present invention.
  • FIG. 3 is a partially schematic illustration of the processing steps to make laminated shower curtains in accordance with an embodiment of the present invention.
    •  DETAILED DESCRIPTION
  • The present invention provides laminated shower curtains that combine water repellency and mildew resistance. Instead of obtaining water repellency of a fabric layer with chemicals, the laminated shower curtains of the present invention comprise a fabric layer laminated with a liquid impermeable film layer. Before lamination, the fabric layer of the laminated shower curtain is pre-treated with an antimicrobial agent. The liquid impermeable film layer may include a co-extrusion of polymer material and a second antimicrobial agent.
  • As used herein, the term “shower curtain” includes curtains for use with a shower, a bath, or the like. The term “curtain” may refer to a single curtain that is used by itself in a shower or bath, or is used as a liner for an additional curtain.
  • As used herein, the term “antimicrobial” means substances, such as bactericidal, fungicidal, antiviral and the like, that kill or inhibit the growth of microorganisms.
  • As used herein, the term “liquid impermeable” means impermeable or substantially impermeable to liquids, such as water. For example, a liquid impermeable film layer of the present invention prevents liquid water from flowing through the thickness of the film.
  • As used herein, the term “liquid permeable” means permeable or substantially permeable to liquids, such as water. For example, a liquid permeable fabric layer of the present invention, prior to lamination with the film layer, allows at least some liquid water to flow through the thickness of the fabric.
  • As used herein, the term “gas impermeable” means impermeable or substantially impermeable to gas or vapor, such as water vapor, air and the like. For example, a gas impermeable film layer of the present invention prevents water vapor and/or air from passing through the thickness of the film.
  • As used herein, the term “gas permeable” means permeable or substantially permeable to gas or vapor, such as water vapor, air and the like. For example, a gas permeable fabric layer of the present invention, prior to lamination with the film layer, allows at least some passage of water vapor and/or air through the thickness of the fabric.
  • FIG. 1 is a partially schematic side sectional view of a portion of a laminated shower curtain 10 in accordance with an embodiment of the present invention, including an antimicrobial pre-treated fabric layer 12 and an antimicrobial liquid impermeable film layer 14. The laminated shower curtain 10 may include an interface 16 between the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14. When installed, the antimicrobial pre-treated fabric layer 12 may typically face away from the shower or bath, while the antimicrobial liquid impermeable film layer 14 may typically face towards the shower or bath.
  • The laminated shower curtain 10 may have any suitable dimensions and features, e.g., as found in conventional standard shower curtains. The dimensions of the laminated shower curtain 10 may be varied depending on the size of the shower or bath. For example, the width of the laminated shower curtain 10 may typically range from 3 to 7 feet, or from 4 to 6.5 feet. The height of the laminated shower curtain 10 may typically range from 5 to 9 feet, or from 6 to 8 feet. The laminated shower curtain 10 may comprise a top edge including standard openings or attachment points for conventional shower curtain rings or hooks (not shown). The top, bottom and/or side edges of the laminated shower curtain 10 may include standard edge treatments as found in conventional shower curtains, such as hemming and the like (not shown).
  • In an embodiment of the invention, the fabric of the antimicrobial pre-treated fabric layer 12 may have a material weight ranging from 10 to 500 grams per square meter (gsm), for example, from 20 to 200 gsm, or from 50 to 100 gsm. In a particular embodiment, the fabric of the antimicrobial pre-treated fabric layer 12 may have a material weight of 70 gsm. As shown in FIG. 1, the antimicrobial pre-treated fabric layer 12 may have a thickness TF, and the antimicrobial liquid impermeable film layer 14 may have a thickness TI. In an embodiment of the laminated shower curtain 10, the antimicrobial pre-treated fabric layer 12 may have a thickness TF ranging from 0.02 to 3 mm, for example, from 0.05 to 1.5 mm, or from 0.1 to 1 mm, or from 0.2 to 0.75 mm.
  • In accordance with an embodiment of the present invention, the antimicrobial pre-treated fabric layer 12 may be made from a liquid permeable and gas permeable fabric material, e.g., the fabric may be permeable to liquid water and to water vapor and/or air. The antimicrobial pre-treated fabric layer 12 may be made from knitted or woven fabric material. In accordance with an embodiment of the invention, the antimicrobial pre-treated fabric layer 12 may comprise any suitable synthetic or natural material, such as polyester, nylon, cotton, or the like. In a particular embodiment, the fabric material of the antimicrobial pre-treated fabric layer 12 may comprise polyester.
  • The first antimicrobial agent of the antimicrobial pre-treated fabric layer 12 may comprise agents that kill microorganisms or inhibit their growth. For example, the first antimicrobial agent may contain at least one metal such as silver, gold, platinum, palladium, iridium, zinc, copper, nickel, tin, titanium, zirconium, molybdenum, iron, antimony, bismuth and the like, or mixtures of these metals with the same or other metals. In certain embodiments, the first antimicrobial agent can comprise at least one such metal in combination with at least one of oxygen, nitrogen, carbon, boron, sulfur, a halogen (e.g., fluorine, chlorine, bromine, iodine) and/or hydrogen. In certain embodiments, the first antimicrobial agent may comprise one or more metal oxide, carbide, hydroxide, nitride, nitrate, chloride, boride, sulfide, sulfate, halide, hydride, or metal salts containing metals as described above. In certain embodiments, the first antimicrobial agent may comprise metal-containing compounds, such as coordination complexes or metal complexes, metal pyrithiones, metal trialkyls, organometallics, microcomposites and the like. The metal(s) components of such compounds may be selected from those listed above.
  • Examples of suitable coordination complexes or metal complexes may include dehydroabietyl amine, 8-hydroxyquinolinium 2-ethylhexoate, copper naphthenate, copper oleate, silver pyrithione, gold pyrithione, zinc pyrithione, copper pyrithione, palladium (II) complexes, silver acetate, silver (I) carbene, zinc ammonium carbonate, copper ammonium carbonate, zinc borate, and the like. Examples of suitable metal trialkyls may include tributyl tin oxide, tributyl tin acetate, and the like. Examples of suitable organometallics may include copper 8-quinolinolate, and the like. Examples of suitable microcomposites may include silver chloride nanoparticles attached to titanium dioxide as a carrier material and the like.
  • In accordance with certain embodiments, the first antimicrobial agent may comprise organic compounds such as phenolics, polybiguanides, quarternary ammonium compounds, isothiazolinones, and N-halamine compounds. Examples of suitable phenolics may include triclosan, dalbergin (I) and the like. Examples of suitable polybiguanides may include polyhexamethylene biguanides and the like. Examples of suitable quarternary ammonium compounds may include domiphen bromid, 3-(trihydroxysilyl) propyldimethyl-octadecyl ammonium chloride, benzalkonium chloride, methylbenzethonium chloride, cetalkonium chloride, cetylpyridinium chloride, cetrimide, dofanium chloride, cetrimonium, benzethonium chloride, tetraethylammonium bromide, didecyldimethylammonium chloride, and the like. Examples of suitable isothiazolinones may include methylisothiazolinone, methylchloroisothiazolinone, benzisothiazolinone, octylisothiazolinone, dichlorooctylisothiazolinone, butylbenzisothiazolinone, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-Butyl-1,2-benzisothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, and the like. Examples of N-halamine compounds may include hydantoins, isocyanurates, 1,3-Dichloro-2,2,5,5-tetramethyl-4-imidazolidinone, 1,3-Dibromo-2,2,5,5-tetramet hyl-4-imidazolidinone, 1-Bromo-3-chloro-2,2,5,5-tetramethyl-4-imidazolidinone, and the like.
  • In accordance with certain embodiments, the amount of the first antimicrobial agent contained in or on the antimicrobial pre-treated fabric layer 12 may typically be from 0.1 to 30 weight percent based on the total weight of the fabric of the antimicrobial pre-treated fabric layer 12 and the dry weight of the first antimicrobial agent. For example, the first antimicrobial agent may comprise from 1 to 20 weight percent, or from 2 to 10 weight percent.
  • In accordance with an embodiment of the present invention, the antimicrobial liquid impermeable film layer 14 may be both a liquid impermeable and a gas impermeable polymeric material, e.g., the film layer 14 is substantially impermeable to liquid water and to water vapor. The antimicrobial liquid impermeable film layer 14 may comprise a continuous film of any suitable polymeric material, such as polyethylene, polypropylene, polyvinyl chloride, polystyrene, nylon, polycarbonate, polytetrafluoroethylene, polyurethane, and the like. In a particular embodiment, the polymeric material of the antimicrobial liquid impermeable film layer 14 may be a polyethylene material.
  • In an embodiment, the antimicrobial liquid impermeable film layer 14 may have a thickness TI ranging from 0.02 to 2 mm, for example, from 0.05 to 1 mm, or from 0.1 to 0.5 mm. In a particular embodiment, the antimicrobial liquid impermeable film layer 14 may have a thickness TI of about 0.2 mm. In an embodiment of the present invention, the thickness TF of the antimicrobial pre-treated fabric layer 12 may be greater than the thickness TI of the impermeable antimicrobial liquid impermeable film layer 14. In another embodiment, the thicknesses may be the same.
  • In accordance with an embodiment of the present invention, the antimicrobial liquid impermeable film layer 14 may comprise the second antimicrobial agent dispersed throughout a polymeric matrix of the antimicrobial liquid impermeable film layer 14. In accordance with an embodiment of the invention, the antimicrobial liquid impermeable film layer 14 may be coextruded to form a coextrusion. As used herein, the term “coextrusion”, when referring to the antimicrobial liquid impermeable film layer, means that the polymer and the second antimicrobial agent are extruded together into a film comprising a polymeric matrix and the second antimicrobial agent dispersed therein. The antimicrobial liquid impermeable film layer 14 may be a composite layer comprising a polymeric matrix with molecules or particles of the second antimicrobial agent dispersed therein. In accordance with certain embodiments, the second antimicrobial agent may be uniformly dispersed throughout the thickness of the antimicrobial liquid impermeable film layer 14. In other embodiments, the second antimicrobial agent may be non-uniformly dispersed, for example, there may be a greater concentration of the second antimicrobial agent on one or both of the exterior surfaces than in the center of the antimicrobial liquid impermeable film layer 14.
  • The second antimicrobial agent may comprise agents that kill microorganisms or inhibit their growth. For example, the second antimicrobial agent may contain at least one metal such as silver, gold, platinum, palladium, iridium, zinc, copper, nickel, tin, titanium, zirconium, molybdenum, iron, antimony, bismuth and the like, or mixtures of these metals with the same or other metals. In certain embodiments, the second antimicrobial agent can comprise at least one such metal in combination with at least one of oxygen, nitrogen, carbon, boron, sulfur, a halogen (e.g., fluorine, chlorine, bromine, iodine) and/or hydrogen. In certain embodiments, the second antimicrobial agent may comprise one or more metal oxide, carbide, hydroxide, nitride, nitrate, chloride, boride, sulfide, sulfate, halide, hydride, or metal salts containing metals as described above. In certain embodiments, the second antimicrobial agent may comprise metal-containing compounds, such as coordination complexes or metal complexes, metal pyrithiones, metal trialkyls, organometallics, microcomposites and the like. The metal(s) components of such compounds may be selected from those listed above.
  • Examples of suitable coordination complexes or metal complexes may include dehydroabietyl amine, 8-hydroxyquinolinium 2-ethylhexoate, copper naphthenate, copper oleate, silver pyrithione, gold pyrithione, zinc pyrithione, copper pyrithione, palladium (II) complexes, silver acetate, silver (I) carbene, zinc ammonium carbonate, copper ammonium carbonate, zinc borate, and the like. Examples of suitable metal trialkyls may include tributyl tin oxide, tributyl tin acetate, and the like. Examples of suitable organometallics may include copper 8-quinolinolate, and the like. Examples of suitable microcomposites may include silver chloride nanoparticles attached to titanium dioxide as a carrier material and the like.
  • In accordance with certain embodiments, the second antimicrobial agent may comprise organic compounds such as phenolics, polybiguanides, quarternary ammonium compounds, isothiazolinones, and N-halamine compounds. Examples of suitable phenolics may include triclosan, dalbergin (I) and the like. Examples of suitable polybiguanides include polyhexamethylene biguanides and the like. Examples of suitable quarternary ammonium compounds may include domiphen bromid, 3-(trihydroxysilyl) propyldimethyl-octadecyl ammonium chloride, benzalkonium chloride, methylbenzethonium chloride, cetalkonium chloride, cetylpyridinium chloride, cetrimide, dofanium chloride, cetrimonium, benzethonium chloride, tetraethylammonium bromide, didecyldimethylammonium chloride, and the like. Examples of suitable isothiazolinones may include methylisothiazolinone, methylchloroisothiazolinone, benzisothiazolinone, octylisothiazolinone, dichlorooctylisothiazolinone, butylbenzisothiazolinone, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-Butyl-1,2-benzisothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, and the like. Examples of suitable N-halamine compounds may include hydantoins, isocyanurates, 1,3-Dichloro-2,2,5,5-tetramethyl-4-imidazolidinone, 1,3-Dibromo-2,2,5,5-tetramethyl-4-imidazolidinone, 1-Bromo-3-chloro-2,2,5,5-tetramethyl-4-imidazolidinone, and the like.
  • In certain embodiments, the amount of the second antimicrobial agent contained in or on the antimicrobial liquid impermeable film layer 14 coextrusion may be from 0.1 to 30 weight percent based on the total weight of the polymeric material of the antimicrobial liquid impermeable film layer 14 and the weight of the second antimicrobial agent. For example, the second antimicrobial agent may comprise from 1 to 20 weight percent, or from 2 to 10 weight percent.
  • In accordance with certain embodiments, the second antimicrobial agent may be provided in the form of particles having an average particle size ranging from 5 nanometers up to the thickness TI of the antimicrobial liquid impermeable film layer 14, for example, from 10 nanometers to 1,000 microns, or from 0.1 to 10 microns, or from 0.5 to 5 microns.
  • FIGS. 2 and 3 schematically illustrate processing steps for producing a laminated shower curtain material that may be used to fabricate a laminated shower curtain 10 in accordance with an embodiment of the present invention. The fabric material of the antimicrobial pre-treated fabric layer 12 may begin on a roll 31. The fabric may then be subjected to an antimicrobial agent treatment 32. As shown in FIG. 3, an antimicrobial agent solution 61 may be contained in a wet bath 60. The fabric may be continuously fed through the wet bath 60 of antimicrobial agent solution 61. The solution 61 may be a water-based aqueous solution or an organic solvent-based solution. The antimicrobial agent treatment 32 may be applied in any other manner, such as spraying, brushing, rolling and the like. After the antimicrobial agent solution 61 is applied to the fabric, the treated fabric layer is allowed to dry 33 to remove the water or organic solvent, and to thereby produce the antimicrobial pre-treated fabric layer 12. In certain embodiments, the drying 33 of the antimicrobial pre-treated fabric layer 12 may include air drying or drying at elevated temperatures. In certain embodiments, after drying 33 of the antimicrobial pre-treated fabric layer 12, the antimicrobial pre-treated fabric layer 12 may be rolled.
  • As schematically shown in FIGS. 2 and 3, the antimicrobial liquid impermeable film layer 14 may be formed by combining a polymer material 41 and a second antimicrobial agent 42 in an extrusion feeding system. The mixture of the polymer material 41 and the second antimicrobial agent 42 may then be heated to form a molten mixture 43. The molten mixture 43 may then be extruded 44 to form the antimicrobial liquid impermeable film layer 14. The antimicrobial liquid impermeable film layer 14 thus comprises a coextrusion of the polymer material 41 and the second antimicrobial agent 42. In certain embodiments, after the antimicrobial liquid impermeable film layer 14 coextrusion is formed, it may be rolled 45 to form a roll of liquid impermeable film layer 14. In another embodiment, the antimicrobial liquid impermeable film layer 14 may be directly extruded onto the antimicrobial pre-treated fabric layer 12.
  • As schematically shown in FIGS. 2 and 3, the antimicrobial treatments may be individually applied to the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 before they are laminated together. Such individual treatments allow for different antimicrobial agents to be applied to the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14. The use of different antimicrobial agents allows for the selection of first and second antimicrobial agents that work more effectively with the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14. In addition, the use of such individual treatments avoids the necessity of treating a single fabric material with both water repellency chemicals and mildew resistant chemicals.
  • In accordance with certain embodiments, after the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 are produced, the antimicrobial liquid impermeable film layer 14 can be deposited on the surface of the antimicrobial pre-treated fabric layer 12 through a lamination process 51. The lamination process 51 may use heat and/or pressure to combine the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 into a laminated structure. For example, the antimicrobial liquid impermeable film layer 14, or both the antimicrobial liquid impermeable film layer 14 and antimicrobial pre-treated fabric layer 12, may be heated and passed through a upper nip-roller 71 and a lower nip-roller 72 to thereby bond the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14 together. In other embodiments, other types of pressure-applying machines may be used. During the lamination process, the antimicrobial liquid impermeable film layer 14 may not significantly infiltrate the antimicrobial pre-treated fabric layer 12, but is sufficiently bonded thereto to prevent delamination during use. In an embodiment of the present invention, no other adhesive is used to combine the antimicrobial pre-treated fabric layer 12 and the antimicrobial liquid impermeable film layer 14. However, an adhesive may be used in other embodiments. When the antimicrobial liquid impermeable film layer 14 is laminated 51 to the antimicrobial pre-treated fabric layer 12, the antimicrobial liquid impermeable film layer 14 provides a continuous film that allows the laminated shower curtains 10 to be both liquid impermeable and gas impermeable. After lamination, the laminated material of the shower curtain 10 may then be rolled 52.
  • In accordance with the certain embodiments, the roll 52 of the laminated material may be formed into a laminated shower curtain 10 by conventional techniques known to those skilled in the art. For example, the laminated material may be cut to the desired dimensions and conventional edge treatment such as hemming may be applied to the top, bottom and side edges. In addition, the top edge of the laminated shower curtain 10 may be provided with standard holes or attachment points for shower curtain rings or hooks by conventional techniques.
  • Samples of laminated shower curtain materials of the present invention were tested for mildew resistance against sterilized control samples comprising sterilized filter paper. The tests were conducted in accordance with AATCC Test Method 30-2013 Antifungal activity, Assessment on Textile Materials: Mildew and Rot Resistance of Textile Materials—Test III: Agar Plate: Aspergillus Niger ATCC 6275. Three laminated shower curtain materials of the present invention were cut into multiple disc-shaped samples. For each type of laminated shower curtain material tested, one of the test discs was tested on its “Face” side and one of the test discs was tested on its “Back” side. The combined test results are listed in Table 1 below. All of the laminated shower curtain test disc samples corresponding to the present invention exhibited no growth (no test organisms visible by the naked eye or under a microscope; 0% of the surface area of the test disc covered with the test organism), while all of the sterilized control samples exhibited macroscopic growth (visible to the naked eye; 100% of the surface area of the test disc covered with the test organism).
  • TABLE 1
    Concentration
    of Spores Fungal growth level on the test discs
    Test Sample (Spores/mL) (7 days)
    Face Treated sample 1.0 × 106 Percentage of surface area of the discs covered
    with the growth of Aspergillus Niger: 0%
    Control sample Percentage of surface area of the discs covered
    with the growth of Aspergillus Niger: 100%
    Back Treated sample 1.0 × 106 Percentage of surface area of the discs covered
    with the growth of Aspergillus Niger: 0%
    Control Percentage of surface area of the discs covered
    Sample with the growth of Aspergillus Niger: 100%
  • Whereas particular embodiments of this invention have been described above for purposes of illustration, it will be evident to those skilled in the art that numerous variations of the details of the present invention may be made without departing from the invention as defined in the appended claims.

Claims (22)

What is claimed is:
1. A laminated shower curtain comprising:
an antimicrobial pre-treated fabric layer comprising a first antimicrobial agent; and
an antimicrobial liquid impermeable film layer bonded to the antimicrobial pre-treated fabric layer comprising a polymeric material and a second antimicrobial agent.
2. The laminated shower curtain of claim 1, wherein the antimicrobial pre-treated fabric layer comprises a liquid permeable and gas permeable fabric material.
3. The laminated shower curtain of claim 1, wherein the antimicrobial pre-treated fabric layer comprises woven or knitted fabric material.
4. The laminated shower curtain of claim 1, wherein the antimicrobial pre-treated fabric layer comprises polyester, nylon, cotton, or a combination thereof.
5. The laminated shower curtain of claim 1, wherein the antimicrobial pre-treated fabric layer has a material weight of from 20 to 200 gsm.
6. The laminated shower curtain of claim 1, wherein the antimicrobial pre-treated fabric layer has a thickness of from 0.01 to 1 millimeter.
7. The laminated shower curtain of claim 1, wherein the amount of the first antimicrobial agent comprises from 1 to 20 weight percent based on the total weight of the fabric of the antimicrobial pre-treated fabric layer and the dry weight of the first antimicrobial agent.
8. The laminated shower curtain of claim 1, wherein the first antimicrobial agent comprises at least one metal, at least one metal compound, at least one organic compound, or a combination thereof.
9. The laminated shower curtain of claim 1, wherein the antimicrobial liquid impermeable film layer comprises a liquid impermeable and gas impermeable material.
10. The laminated shower curtain of claim 1, wherein the antimicrobial liquid impermeable film layer comprises a coextrusion of the polymeric material and the second antimicrobial agent.
11. The laminated shower curtain of claim 1, wherein the polymeric material of the antimicrobial liquid impermeable film layer comprises extruded polyethylene, polypropylene, polyvinyl chloride, polystyrene, nylon, polycarbonate, polytetrafluoroethylene, polyurethane, or a combination thereof.
12. The laminated shower curtain of claim 1, wherein the antimicrobial liquid impermeable film layer has a thickness from 0.05 to 1 millimeter.
13. The laminated shower curtain of claim 1, wherein the second antimicrobial agent may comprise at least one metal, at least one metal compound, at least one organic compound, or a combination thereof.
14. The laminated shower curtain of claim 1, wherein the amount of the second antimicrobial agent comprises from 1 to 20 weight percent based on the total weight of the polymeric material of the antimicrobial liquid impermeable film layer and the weight of the second antimicrobial agent.
15. The laminated shower curtain of claim 1, wherein the first antimicrobial agent and the second antimicrobial agent comprise different antimicrobial materials.
16. The laminated shower curtain of claim 1, wherein the antimicrobial pre-treated fabric layer has a thickness that is greater than a thickness of the antimicrobial liquid impermeable film layer.
17. The laminated shower curtain of claim 1, wherein the laminated shower curtain has a width of from 3 to 7 feet, and a height of from 5 to 9 feet.
18. A method of making a laminated shower curtain material comprising laminating a pre-treated fabric layer comprising a first antimicrobial agent with a liquid impermeable film layer comprising a polymeric material and a second antimicrobial agent to produce the laminated shower curtain material.
19. The method of claim 18, wherein the antimicrobial pre-treated fabric layer is produced by contacting the fabric layer with the first antimicrobial agent in a wet bath.
20. The method of claim 18, wherein the antimicrobial liquid impermeable film layer is produced by co-extruding a molten mixture of the polymer material and the second antimicrobial agent.
21. The method of claim 18, wherein the antimicrobial pre-treated fabric layer and the antimicrobial liquid impermeable film layer are laminated by heating at least one of the antimicrobial pre-treated fabric layer and the antimicrobial liquid impermeable film layer, and applying pressure to the antimicrobial pre-treated fabric layer and the antimicrobial liquid impermeable film layer to thereby bond the antimicrobial pre-treated fabric layer and the antimicrobial liquid impermeable film layer together.
22. The method of claim 18, further comprising forming the laminated shower curtain material into a shower curtain having top, bottom and side edges, having a width of from 3 to 7 feet, and having a height of from 5 to 9 feet.
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