TW201138627A - Composition, antibacterial processing agent and antibacterial molded article - Google Patents

Abstract

Disclosed is a composition which contains two kinds of imidazole-based organic antibacterial agents and an antiallergic agent. The composition therefore suppresses the production of causes of allergy-causing substances, namely bacteria, fungi and mites and provides a practical allergy deactivation performance even in cases where the amount of a deactivation agent for allergy-causing substances is reduced. Consequently, the composition enables reduction of the amount of a deactivation agent for allergy-causing substances, and an antibacterial molded article that contains the composition or antibacterial processing agent of the present invention can have a good texture and does not easily suffer from discoloration due to light or heat.

Description

201138627 VI. Description of the Invention: [Technical Field] The present invention relates to a composition, an antibacterial treatment agent, and an antibacterial molded article. [Prior Art] Previously, it has antibacterial, antifungal, and anti-mite properties. The anti-allergic composition 'and the processed molded article processed from the composition. For example, there is an antibacterial and anti-mite resin composition obtained by kneading a composition containing boron into a resin (Document 1: Japanese Patent Laid-Open Publication No. 2005-29451). Further, there are also insecticides containing a benzopyrene compound having a snail-killing and bactericidal property (Document 2: Japanese Patent Laid-Open Publication No. SHO 59-65065, Document No. 3: Japanese Patent Laid-Open No. 59-- Bulletin No. 172477). Further, there is also an antiallergen product containing an anti-allergic agent containing an inorganic solid acid (Document 4: Japanese Laid-Open Patent Publication No. 2003-81727, and Document 5: International Publication No. 9/44648). However, the compositions and the like described in Documents 1 to 5 cannot all satisfy the antibacterial property, the antifungal property, the anti-mite property, and the anti-allergic property. Further, when the anti-allergic agent is contained in the composition, when the content of the anti-allergic agent is too large, when the composition is processed into a molded article, there is a problem that the texture of the molded article is lowered or light is likely to occur. Heat caused by discoloration. SUMMARY OF THE INVENTION An object of the present invention is to provide a composition having antibacterial property, antifungal property, anti-cogwheel resistance and anti-allergic property, an antibacterial treatment agent and an antibacterial molded product, even if the anti-allergic agent is contained in a small amount. Play a practically full resistance to 152257.doc 201138627 sensitive performance. (!) The composition of the present invention contains an antibacterial composition containing at least two selected from the group consisting of imidazole-based organic antibacterial agents, and a deactivating agent for an allergy-inducing substance. (2) Here, the above-mentioned imidazole-based organic antibacterial agent is preferably a compound having a stilbene ring and a thiazolyl group, and a compound having a benzimidazole ring and a urethane group. (3) Further, the composition of the present invention preferably contains an inorganic antibacterial agent. (4) Here, the inorganic antibacterial agent is preferably a silver-loaded phosphoric acid. (5) Further, the composition of the present invention preferably contains an insecticide. (6) Here, the above-mentioned aphid removing agent is preferably boron oxide or a cellulose containing the same. Further, the deactivating agent for the allergy-inducing substance is preferably at least one selected from the group consisting of natural polyphenols, synthetic polymeric phenols, and inorganic solid acids. (8) The antibacterial treatment agent of the present invention comprising the above composition and a dispersion medium (9) Here, the antibacterial treatment agent of the present invention preferably contains a binder resin. (10) Further, the antibacterial treatment agent of the present invention preferably contains a crosslinking agent. (11) Further, the antibacterial treatment agent is preferably any of a domestic spray, a coating, a coating agent, a surface treatment agent, and a fiber treatment agent. (12) The antibacterial molded article of the present invention is characterized in that the fiber, the cloth, the resin film, and the layered body in which the fiber or the cloth is laminated on the resin film is used by the antibacterial agent. The person who handles it. (13) The antibacterial molded article of the present invention, which comprises a mixture of the above composition and a resin comprising 152257.doc 201138627. According to the composition of the present invention and the antibacterial treatment agent, the antibacterial property, the antifungal property, the anti-mite property, and the anti-allergic property can be exhibited by combining the antibacterial composition and the deactivating agent of the allergy-inducing substance. Further, since bacteria, (4), and worms, which are causes of the allergen-inducing substance, can be suppressed, practical desensitization deactivation performance can be obtained even if the content of the deactivating agent of the allergy-inducing substance is small. Therefore, the content of the deactivating agent of the allergy-inducing substance of the composition of the present invention and the antibacterial treatment agent can be made small, and the antibacterial molded article containing the composition of the present invention or the antibacterial treatment agent can be made into a good texture. It is not easy to cause discoloration caused by light or heat. [Embodiment] Hereinafter, embodiments for carrying out the invention will be described in detail. (Composition of the composition) The composition of the present invention contains an antibacterial composition containing at least two kinds of organic antibacterial agents selected from the group consisting of miso-type, and deactivation of the allergic-inducing substance (hereinafter sometimes referred to simply as "anti- Allergic agent"). As an organic antibacterial agent, for example, jujube can be listed. Servant & 1 and W-carbamic acid®

Two: benzene of the cesium atom, stupid and smelly (four) I two: Ding biological 荨. As the organic antibacterial agent, a compound having a benzo compound is preferred. ..., has this ring and aminomethine

As a stupid compound, such as H = Mi. Sodium carbamic acid broth, butyl melamine carboxylic acid decyl methacrylate, 6 benzophenone + hydrazine 2 imidazolidine carboxylic acid 〗 152257.doc 201138627 ester, 6-(2-thiophenecarbonyl)- 1H-2-benzimidazolyl carbamate, etc. As a sulfur atom, benzopyrene. The compound can be exemplified by: 1 Η-] thiocyanothio thiobenzimidazole, 1-didecylaminosulfonyl-2-cyano-4-bromo-6-trifluoromethylbenzo Imidazole and the like. As a derivative of the present invention, for example, 2-(4-thiazolyl)-1Η-benzimidazole, 2-(2-phenylphenyl)_1Η·benzimidazole, 2·(1_ (3,5-Dimethylpyrazolyl)) Η Η • benzimidazole, 2 —( 2 —furanyl)ih benzoimidazole, and the like. Among these organic antibacterial agents, 2_(4-thiazolyl)·1Η·benzoimin and 1Η-2-benzo are particularly preferred. Take 2 kinds of carbamic acid. By using these two different kinds, the superior multiplication effect of the antibacterial action and the antifungal action can be obtained for the microorganism, and the anti-mite effect can also be obtained. The ratio of the acid ester is preferably 丨: 丨 to 5, and 2-(4-嗟-saltyl)-1Η-benzopyrene and 汨_2_benzoimylamamine Where, if 2-(4-thiazolyl)-1Η·stupid imidazole and m-2-benzene succinylamine

The amount of increase.

Brewed, and inorganic solid acid, etc., may also contain a plurality of

Sugar, curcumin, coumarin, etc. I52257.doc 201138627 Examples of the synthetic high molecular phenols include polyphenylphenol and polyvinylphenol. Examples of the inorganic solid acid include a metal phosphate compound such as aluminum phosphate, a zeolite substituted with Y or the like, a composite oxide such as citric acid or Si〇2_A12〇3, magnesium citrate, zirconium phosphate, zirconium oxide, and ammonium zirconium carbonate. Or a zirconium compound such as potassium zirconium carbonate or an inorganic ion exchange product. Further, the ratio of the antibacterial composition to the antiallergic agent of the composition of the present invention is preferably from 3: 丨 to 丨: 5, and particularly preferably 丨: 3. When the compounding ratio of the antiallergic agent is more than the above range, when the composition is processed into a molded article, the texture of the molded article is lowered, and discoloration due to light or heat is likely to occur. On the other hand, if the compounding ratio of the antiallergic agent is less than the above range, it becomes impossible to obtain practical allergy deactivation performance. By setting such a specific mass ratio, the antibacterial property, the antifungal property, and the anti-mite property can be more effectively exhibited. As a result, even if the anti-allergic agent content is small, it can be made into a practical anti-allergy. Sexual composition. It is particularly preferred that the composition of the present invention contains an inorganic antibacterial agent and an aphid removing agent in addition to the antibacterial composition and the anti-allergic agent. Examples of the inorganic antibacterial agent include a copper compound such as copper sulfate, a zinc compound such as zinc oxide, a nickel compound, an inorganic metal compound such as a copper-nickel alloy, a metal-supporting zeolite, or a zirconium phosphate as a salt thereof. It is excellent in antibacterial and anti-fungal properties of silver-loaded strontium phosphate (silver-loaded zirconium phosphate-loaded silver zirconium phosphate). In addition to the antibacterial composition and anti-allergic agent in the composition of the present invention In the case where the inorganic antibacterial agent is also contained, the ratio of the antibacterial composition to the non-bacterial agent is 152257.doc 201138627. The ratio of the antibacterial agent is preferably 1.1 to 5. 1 and especially 2: 1. By setting such a specific mass ratio, it is possible to obtain an antibacterial molded article which is excellent in texture and is less likely to cause discoloration due to light or heat by adding a smaller amount of the composition, and can be efficiently obtained. The synergistic effect of the synergistic antibacterial action of the organic antibacterial agent of the imidazole type and the inorganic antibacterial agent is used in combination. Examples of the anti-insect agent include boron oxide or a glassy substance containing the same. Since boron oxide or a glassy substance containing the same is an inorganic compound, an antibacterial molded article which is less likely to cause discoloration than an organic compound and which is less likely to cause discoloration due to light or heat is obtained, and is further preferred. In addition to the antibacterial composition and the anti-allergic agent, the composition also contains the anti-allergic agent, and the ratio of the antibacterial composition to the aphid-removing agent is preferably 1:1 to 1:5 by mass ratio. More preferably, it is 1:3 c. By setting such a specific mass ratio, an antibacterial molded article excellent in aphid resistance can be obtained by adding a small amount of the composition. The composition of the present invention is shown in Table 1 to The microorganisms shown in Table 5, ie, fungi (fungi, bacteria, etc.) have antibacterial and antifungal properties. [Table 1] Fungi 1 Alternaria altemata 2 Aspergillus awamori 3 Aspergillus niger 4 Aspergillus oryzae 5 Aspergillus flavus I52257.doc 201138627 6 Aspergillus versicolor 7 Aspergillus fumigatus 8 Aspergi Llus nidulans 9 Aspergillus glaucus 10 Aspergillus terreus 11 Aspergillus phoenjcus 12 Aspergillus tamari 13 Aspergillus species 14 Confined Aspergillus restrictus 15 Aspergillus ochraceus 16 Aspergillus clavatus 17 Aspergillus ustus 18 Aspergillus candidus 19 Parasiticus Aspergillus parasiticus 20 Absidia corymbifera 21 Aspergillus luchensis 22 Absidia glauca 23 Fine chain Altemaria tenuis 24 Altemaria pisi 25 Altemaria candidus 26 Altemaria brassicicola 27 Aureobasidium pullulans 28 Ascosphaera apis 29 Ascomycetes Aphanomyces cochlioides 30 Aphanomyces raphani 31 Botrytis cinerea 32 Mycelium Byssochlamys nivea 33 Candida albicans 34 Beet Cerespora beticola 35 Cerespora musao 36 Claviceps purpurea 37 Colletotrichum trifolii 38 C. cerevisiae Ceratocystis cora 39 Chaetomium globosum 40 Cladosporium cladosporioides 41 Curvularia geniculata 42 Chrysosporium thermophilum 43 Candida guilliermondii 44 Candida lipolytica 45 Candida pelliculose 152257.doc -9- 201138627 46 Candida tropicalis 47 Candida glabrata 48 Candida acutus 49 Candida utilis 50 Cladosporium sphaerospermum 51 Cladosporium herbarum 52 Corticium rolfsii 53 Colletotrichum phomoides 54 Grass per charcoal Colletotrichum fragariae 55 Maltese anthracnose Colletotrichum atramentarium 56 Bean anthracnose Colletotrichum lindemuthianum 5 7 Fusarium oxysporum Ceratocystis ulmi 58 Clostridium acetobutylicum 59 Clostridium sporogenes 60 Cladosporium carpophilum 61 Curvularia lunata 62 Chrysosporium keratinophilum 63 Cryptococcus lutealus 64 New Cryptococcus neoformans 65 Cladosporium resinae 66 Cryptococcus albidas 67 Chaetomium clivaceum 68 Dactylium derdroides 69 Diplodia natalensis 70 Drechslera australiensis [Table 2] True 71 Eutopium tonophilum 72 Epicoccum purpurascens class 73 Euthium repens 74 E. sylvestris Eurotium rubrum 75 E. sylvestris Eurotium chevalieri 76 Amsterdam genus Eurotium amstelodami 77 Cellular Emericella nidulans 78 Exophiale jeanselmei 79 Fusarium semitectum 80 tip Fusarium oxysporum 81 Fusarium voseum 82 Fusarium moniliforme 152257.doc -10- 201138627 83 Fusarium solani 84 Fusarium roseum 85 Fusarium nivale 86 Fusarium avenaceum 87 Sharp top sickle Fusarium acuminatum 88 Fusarium proliferatum 89 Fusarium graminearum 90 Cotton root rot fungus Fhymatotricum omnivorum 91 White coat: Geotricham candidum 92 Geotricham lactus 93 Gliocladium virens 94 Glomerella cingulata 95 Long creep Helminthosporium sp. 96 Pedroca chromophyte Hormoderdrum pedrosoi 97 Helminthosporium gramineum 98 Lenzites trabea 99 Lenzites trabae 100 Lentinus lepideus 101 Medurella mycetomii 102 Microsporum canis 103 Microsporum gypseum 104 Microsporum audouini 105 Mucor racemosus 106 Myrothecixim verrucaria 107 Mucor mucedo 108 Mucor pusillus 109 Mucor spinescens 100 Mucor rouxii 111 Monascus ruber 112 Monilia Candida 113 Monilia fructigena 114 Monilia nigral 115 Rhizopus sinensis Monilia laxa 116 Menoniella echinita 117 Rhododendron fungus Neurospora crassa 118 Rhizoctonia solani Nigrospora oryzae 119 Neurospora sitophila 120 Neurospora sphaerica 121 Ocuremonium charticola 122 Penicillium frequentance 152257.doc -11 - 201138627 123 Penicillium citrinum 124 Penicillium variabile 125 Penicillium purpurogenum 126 Blue Penicillium glaucum 127 Amylopectin Pulluliana pullulans 128 Penicillium roquerforiti 129 Penicillium luteum 130 Penicillium expansum 131 Penicillium piscarium 132 Penicillium piscarium 132 Penicillium rugulosum 133 Penicillium cyclopium 134 Penicillium chrysium 134 Penicillium chrysium viride 136 Penicillium notatum 137 Penicillium rubrum 138 Penicillium oxalicum 139 Penicillium funiculosum 140 Penicillium digitatum [Table 3] 141 Penicillium islandicum 142 Penicillium nigricans 143 Penicillium lilacinum 144 Penicillium spinulosum 145 Smoke P. cerevisiae Pestalotia adusta 146 Infective P. sylvestris Pestalotia neglecta 147 Citrus Phomopsis Phomosis citri 148 Penicillium steckii 149 Citrus citricarpa 150 Pomegranate Phoma terrestius 151 Pomegranate Phoma Glomerata 152 P. sylvestris Phoma pigmentivora 153 Membrane Biqi Protozoa Pichia membranaefaciens 154 Peptococcus sp. 155 Proteus mirabilis 156 Phacidipycnus funfuracea 157 Phomopsis fukushii 158 Pythium debaryanum 159 Pythium irregulare 152257.doc -12- 201138627 160 Pythium aphanidermatam 161 Phomopsis vexan 162 Phytophthora megasperma 163 Phytophthora nicotianae 164 Phytophthora infestans 165 Phytophthora capsici 166 Phytophthora capsici 166 Plasmodiophora brassicae 167 Pyrenochaeta licopersici 168 Rhodotorula mimuta 169 Rhodotorula mucilaginosa 170 Rhodotorula texensis 171 Rhodotorula glutinis 172 Rhodotorula gulinis 173 Rhodotorula lactosa 174 Black Rhizopus nigricans 175 Rhizopus oryzae 176 Rhizopus rhizopus sto Ronifer 177 Rhizopus delemar 178 Rhizopus solani 179 Rhizopus javanicus 180 Sporotrichum shenki 181 Stichococcus bacillavis 182 Sclerotina fructincola 183 Saccharomyces cerevisiae ~~' Saccharomycodes pasteurianus 184 Streptomyces Stachybotrys sp. 185 Amorpha sclerotiorum Spicaria vlolacea 186 Scorecobasidium constrictum 187 Spiderosporium ～ ~ Scedosporium apiospermum 188 Synaptophyta " Syncephalastrum racemosum 189 Spirulina - 'Stachybotrys chartarum 190 S. schenkeii' Sporothrix schenckii 191 Onion white rot Sclerotium cepivorum 192 Sphaerotheca humuli 193 Sclerotinia sclerotiorum 194 Scutellaria " ~ Scopulariopsis brevicaulis 195 Bacteria " - Trichophyton mentagrophytes 196 Trichophyton gypseum 197 Trichophyton rubrum 198 Trichothecium ros Eum 199 Trichoderma viride 152257.doc •13- 201138627 200 Trichophyton ajelloi 201 Trichoderma koningii 202 Trichoderma T-1 203 Trichoderma harzianum 204 White globular yeast Tolulopsis Candida 205 Trichosporum cutaneum 206 Trichoderuma lignorum 207 Black-striped Ulocladium atrum 208 Ustilago zeae 209 Verticillium albo-atrum 210 Verticillium Dahliae 211 Wallemia sebi 212 Tyroyces palustris 213 Trametes versicolor 214 dried rot fungi Serpula lacrymans [Table 4] Fine 1 Alcaligenes faecalis 2 Alcaligenes viscolactis 3 Ascophyta pisi 4 Autotrophic bacteria 5 Aster yellows pathogen Astertobacter calcoaceticus 7 Achrcmobacter gulyatus 8 Aerobacter aer Ogenes 9 Aerobacter cloacae 10 Italian buds Blastomyces italicum 11 Cactus Bacillus cereus 12 Bacillus mycoides 13 Bacillus subtillis 14 Bacillus megaterrium 15 Bacillus anthracis 16 Bacillus punctatum 17 Bacterium vulgar. 18 Pseudomonas pyocyaneum 19 dermatitis Blastomyces dermatidis 20 Bacteridae fragilis 21 Campylobacter fetus 22 Clostridium perfringens Clostridium perfringens -14- 152257.doc 201138627 23 Clostridium difficile 24 lichens Corticium fuciforme 25 Clostridium botulinum 26 Clonecker apiculata 27 Cellulomonas iugis 28 Campylobacter jejuni/coli 29 Dactylium dendroides 30 Grapes Spore Diplodia viticol 31 Debaryamyces hansenii 32 Desulfovibrio desulfuricans 33 Endothia paracitica 34 Escherichia coli 35 Enterobacter aerogenes 36 Enterobacter clocae 37 Carrot soft rot fungus Erwinia carotovora 38 Clostridium faecalis Fusobacterium nucleatum 39 Flavobacterium aminogenes 40 Flammulina Fla Vobacterium meningosepticum 41 Gluconobacter suboxydans 42 Hansenula anomala 43 Klebsiella oxytoca 44 Klebsiella pneumoniae 45 Lactbacillus acidophilus 46 Lactobacillus planntarum 47 Listeria monocytogens 48 Legionella pneamophila 49 Leptospira interrogans 50 Coronal mushroom Lepiota criststa 51 Lepiota castanae 52 Lactobacillus bulgericus 53 Micrococcus glatamicus 54 Tuberculosis Mycobacterrium tuberculosis 55 Micrococcus albus 56 Micrococcus aquilis 57 Micrococcus conglomerates 58 Micrococcus varians 59 Paecilomyces lilacinus 60 Pudiococcus soyae 61 Pudiococcus acidilactici Pseudomonas Pseudomonas Aeruginosa 15225 7.doc -15- 201138627 63 Pseudomonas fluresceus 64 Paecilomyces variotii 65 Phaffia rhodozyma 66 Pichia anomala 67 Pichia membranaefaciens 68 Proteus Vulgaris 69 Pythium vanterpoolii 70 Phyrass cinereum 71 Propionibacterium aces 72 Propioniabacterium shermanii 73 Podospira leucotricha 74 Pseudomonos syringae 75 Pseudomonos solanacearum [Table 5] Fine 76 gas-producing Escherichia coli Paracolabactrum aerogenoides 77 Rhizoctonia violacea 78 Rhizoctonia solani 79 Rickettsia rickettsii 80 Ruminococcus 81 Scleotina scleotiorum 82 S. scleotolomyces roseus 83 Streptococcus lactis 84 Schizosacchar Omyces pombe 85 Ruthenium Saccharomycodes ludwigii 86 Serratia marcesens 87 Staphylococcus aureus 88 Salmonella typhimurium 89 Streptoverticum reticulum 90 Staphylococcus faecalis 91 Salmonella enterophylla Salmonella Enteritidis 92 Salmonella enterrica 93 Salmonella arizonae 94 Salmonella paratyphi 95 Salmonella choleraesuis 96 Streptococcus agalactiae 97 Serratia marcesceus Serratia liguefaciens 99 Saccharomyces cerevisiae 152257.doc -16- 201138627 100 Sugeran mosaic 101 Staphylococcus epidermidis 102 Staphylococcus hominis 103 Staphylococcus agalactiae 104 Staphylococcus pneumoniae 105 Staphylococcus pyogenes 106 Staphylococcus pyogenes 106 Serratia salinaria 107 Salmonella typhosa 108 Salmonella typhosa 109 Sarcina flava 109 Sarcina latea 100 Sporocytohaga myxococcoides 111 Black round yeast Torula nigra 112 Thermoactinomyces vulgaris 113 Thiobacillus asidophilus 114 Thiobacillus delicatus 115 Thiobacillus denitrificans 116 Thiobacillus ferrooxidans 117 Thiobacillus intermedius 118 Thiobacillus kabolis 119 Thiobacillus neapolitans 120 Thiobacillus neapolitans 120 Metabolism of Thiobacillus novellus 121 Thiobacillus perometabolis 122 Thiobacillus rubellus 123 Thiobacillus thiooxidans 124 Thiobacillus thioparus 125 Thiobacillus thermophilica imschenetskii 126 Thiobacillus versutus 127 Vibrio u Lnificus 128 Venturia inaequalis 129 Yersinia enterocolitica 130 Corynebacterium diphtheriae 131 Corynebacterium glutamicum A composition of the invention is derived, for example, from plant-derived allergens, from molds Allergens such as allergens, aphids, mites, or excrement, such as animal and plant proteins, exert anti-allergic properties. Further, the composition of the present invention is, for example, a dust mites such as the American house dust mites, the European house dust mites, the river glutinous rice glutinous rice, the long-haired whitefly, the elliptic powder, and the like, 152257.doc -17· 201138627 , Malacca meat worms, strong meat glutinous rice, common meat butterfly, scallops, and other meat worms such as 'Bai's poultry _, forest birds, chicken skin thorns, skin thorns and other poultry, ball belly (four), (four), etc. Out of the anti-wormworm, Next, the antibacterial treatment agent and the antibacterial molded article of the present invention (antibacterial treatment agent and antibacterial molded article) The antibacterial treatment agent of the present invention contains the composition of the present invention and a dispersion medium. Sprays, coatings, coating agents, surface treatment agents, and fiber treatment agents. Examples of the dispersion medium include lower alcohols such as water and methanol, polyethylene glycol, and polyethylene glycol. Further, in order to easily fix the composition of the invention to an adherend such as a fiber product, the adhesive is mixed with a binder. Acrylic resin, polyaminoethylene-vinyl acetate copolymer tree As the binder resin, for example, an acid ester, a polyoxyalkylene gas, a polyethylene gas, or a gas ester can be mentioned. It is preferable to use the antibacterial treatment agent of the present invention as a crosslinking agent. The crosslinking agent may, for example, be a nitrogen-containing blocked inert gas, a water-dispersed isocyanate, a melamine, an aqueous epoxy compound or a carbodiimide. The antibacterial treatment agent can be adhered, for example, by using the composition of the present invention, a dispersion medium, and the like. The agent is obtained by mashing and mixing. χ, the composition of the present invention may also be dispersed to a monomer of a propylene fluorene resin or a styrene monomer, or a mixture thereof; 5 when the shape is clear, after coating the antibacterial treatment agent, irradiating ultraviolet rays I52257 .doc 201138627 or heating to polymerize the monomer to harden the molded article. The bacteriostatic molded article of the present invention is a fiber product such as a fiber or a fabric which is treated by the one-line treatment of the antibacterial property of the present invention, and the enamel film is formed by laminating a fiber or a cloth on a resin film. (4) A factory for treating such a fiber product or the like with the anti-H treatment agent of the present invention, for example, a material which is to be adhered or used as a raw material of the raw material In the liquid fiber treatment agent of the composition of the invention, etc., the impregnation method includes so-called groove impregnation, etc. Further, the surface of the adherend is sprayed by a spray or the like. The method of coating, coating, and surface treatment agent which is one example of the antibacterial treatment agent of the present invention may be, for example, brushing or roll coating, printing by inkjet or letterpress, scattering, scraping or Various coating means such as spray coating, gravure coating, shower coating, and knife coating; or various printing means such as screen printing, pad printing, plate printing, inkjet printing, etc. Using the antibacterial property of the present invention Treatment agent Examples of the product include natural fibers such as cotton, |month, wool, and short fibers or long fibers such as polyester, nylon, acryl, synthetic fiber, semi-synthetic fiber, and regenerated fiber, and two types of fibers can be used. The above composite fiber 'may also be a fabric such as a woven fabric, a woven fabric, or a non-woven fabric. Examples of the resin film include PVC (polyethylene) or TP0 (lean tobacco elastomer) or PU (polyurethane). In addition, as the antibacterial molded article of the present invention, a resin film laminate such as synthetic leather, artificial leather, or tarpaulin provided with a fabric on the film may be mentioned. 152257.doc -19·201138627 The antibacterial molded article of the present invention contains the composition of the present invention and a resin, and may be formed by molding the resin. Examples of the resin include a molding resin, a fiber resin, a rubber resin, and the like. The mixture of the composition of the present invention and the resin is melted into a fiber or a film by a known molding method of stretching into a fiber shape or extrusion molding, thereby obtaining an antibacterial molded article of the present invention. system An antibacterial molded article of the present invention is obtained by a fiber product such as a fiber-containing fabric or a resin film laminated body obtained by laminating a film. As an example of the antibacterial treatment agent of the present invention, for example, it can be used as a household or industrial product. Coatings for interior and exterior materials, sprays for household or vehicle interiors, carpet cleaners, coatings or surface treatments for films or sheets, adhesives for fiber laminates, sand t, cement, wall materials In addition, as the adherend to be treated by the antibacterial treatment agent of the present invention, artificial leather processed by an adhesive for a fiber laminate, at least one of vinyl, paper, and cloth can be used. Wallpapers, building materials, wood, flooring, furniture for building and construction materials, aluminum panels for aluminum panels, aluminum alloys, resin moldings, toiletries, feed containers, air conditioning, air conditioning, air conditioning, air conditioning Road components, steel products, blankets, roofing materials, insulation materials, kitchen supplies, bathroom supplies, bedding, filters, furniture, paper 〇^ cookware, Skin 〇 〇 〇 (Effect of the embodiment) The composition of the present invention contains two kinds of imidazole-based antibacterial agents 152257.doc -20- 201138627 and anti-allergic agents, thereby inhibiting the cause of allergic substances The production of bacteria, mold, and aphids can make the content of the anti-allergic agent small, and exert the deactivation performance of the practical allergy-inducing substance. In particular, 'the antibacterial property can be obtained by using two imidazole-based organic antibacterial agents as a compound having a benzimidazole ring and a thiazolyl group, and a compound having a benzimidazole ring and an urethane group. Composition 0 which is more excellent in antifungal properties. Further, since the composition of the present invention further contains an inorganic antibacterial agent, the antibacterial property and the antifungal property can be further improved. In particular, by using an inorganic antibacterial agent as a silver-plated dish, a synergistic effect of the antibacterial action can be obtained, and a composition exhibiting more remarkable antibacterial and antifungal properties can be obtained. Further, since the composition of the present invention further contains an insecticide, the insecticidal property is further improved. In particular, the antibacterial property of the present invention is such that the antibacterial molded article containing the composition is less likely to cause discoloration due to light or heat by using the antimony agent as boron oxide or a vitreous material containing the same. The treatment agent contains the composition of the present invention and a dispersion medium, particularly a domestic spray, a paint, a coating agent, a surface treatment agent, and a fiber treatment agent. Therefore, it is easy to apply the composition to the adherend, and it is possible to produce an antibacterial treatment agent which is excellent in convenience. Further, since the antibacterial treatment agent of the present invention contains a binder resin, the composition can be effectively fixed to the adherend. Further, by using a crosslinking agent in combination, the fixing durability can be improved. That is, even if 152257.doc 21 201138627 is repeatedly washed, it is possible to maintain antibacterial, antibacterial, anti-insect, and anti-allergic properties for a long time. Further, the antibacterial molded article of the present invention is obtained by treating the fiber, the cloth, the resin film, or the laminate obtained by laminating the fiber or the cloth on the resin film by the antibacterial treatment agent of the present invention. Therefore, the application range is wide and the convenience is excellent. Further, since the antibacterial treatment agent of the present invention has a relatively small content of the anti-allergic agent, the antibacterial molded article treated with the antibacterial treatment agent has a good texture and is less likely to cause discoloration due to light or heat. Therefore, in general, there is room for cleaning. Further, the antibacterial molded article of the present invention contains the composition of the present invention and a resin, and may be formed by molding the same. Since the composition of the present invention has a small content of the anti-allergic agent, it can be made into an antibacterial molded article which is excellent in texture and which is less likely to cause discoloration due to light or heat. [Examples] Hereinafter, the present invention will be described more specifically by way of examples and comparative examples, but the present invention is not limited to the examples and the like. [Examples 1-1 to 4-2 and Comparative Examples 1 to 1 to 5] (Production of Antibacterial Treatment Agent and Antibacterial Shaped Product) Examples 1-1 to 4-2 and Comparative Examples 1_1 to 5 were It is implemented as follows. (Example 1-1) In Example 1-1, an aqueous spray was prepared in the following Production Example U, and the filter paper was processed using the aqueous spray of Production Example 1_1 in the following Production Example 1-2. Processing filter paper. I52257.doc •22·201138627 (Production Example 1-1) The (1A) to (3 A) of Table 6 were stirred and mixed in a beaker, and diluted to a volume of 1 L with distilled water (4A). The mixture was mashed and mixed for 20 minutes using LabStar LMZ06 (manufactured by Ashizawa Finetech Co., Ltd.) and using an oxide bead having a diameter of 0.5 mm. At this time, Sanxian gum was added at a time when the liquid viscosity became 700 mPa*s to 800 mPa*s, and an aqueous spray was prepared as an antibacterial treatment agent. (1A) Antibacterial composition 2-(4-thiazolyl)-1Η-benzimidazole (35 mass%), 1H-2-benzimidazolyl carbamate (35 mass%), and Mixture of silver-loaded zirconium phosphate (30% by mass) 3 g (2A) Anti-allergic agent Polyethylene (average molecular weight: 3,000) 4.5 g (3A) Dispersant Noigen TDS-100 (First Industrial Pharmaceutical Co., Ltd.) 3g (4A) Distilled water - 936 g (Manufacturing Example 1-2) Using a household sprayer, the amount of coating is 50 g/m2 for the filter paper (8:8) 2. 2) Spraying the aqueous spray of Production Example 1-1 to prepare a processed filter paper. Using the processed filter paper, the following antibacterial test was performed. (Example 1-2) In Example 1-2, except A processed fabric was produced in the same manner as in Example 1-1 except that the filter paper was changed to a polyester woven fabric (Tricot fabric basis weight: 320 g/m 2 ). The following antibacterial test was carried out using the processed fabric $ (Example 2) -1) 152257.doc •23·201138627 In Example 2-1, the fiber treatment agent was prepared in the following Production Example 2-1, and the fiber treatment agent of Production Example 2-1 was used in the following Production Example 2-2. machining The fabric was produced, and the following antibacterial property test was carried out. (Production Example 2_1) After combining and mixing (1B) to (3B) of Table 7 in the beaker, the above-mentioned LabStar LMZ06 was used and the diameter was 〇. A 5 mm zirconia bead was ground and mixed for 30 minutes to prepare a fiber treating agent. [Table 7] (1B) Antibacterial composition 2-(4-thiazolyl)-iH-benzopyrene (50% by mass) ) a mixture with methyl 1H-2-benzimidazolylamine decanoate (50% by mass) 180 g (2B) Antiallergic agent Polyphenon 70A (Mitsui Nonglin Co., Ltd.) 20 g (3B) Adhesive resin Light Epoch AX- 30 (Hokko Chemical Co., Ltd.) 300 g (Production Example 2-2) The fiber treating agent of Production Example 2 - 1 was diluted to a capacity of 20 times with distilled water, and the cloth of size A4 was treated with fiber in a metal crucible. The solution was immersed for 5 seconds. Here, the cloth was made of a standard cotton woven cotton cloth No. 3. Then, it was extruded by a roller press having a pressure between rolls of 4.0 kg/cm 2 (extrusion rate: 100%). The fabric of Example 2-1 was produced by drying with a hot air dryer at a temperature of 120 ° C for 10 minutes. 2-2) In Example 2-2, a fiber treating agent was prepared in Production Example 2-1, and a fabric was processed in the following Production Example 2-3 using the fiber treating agent of Production Example 2-1, thereby producing a processed fabric. And the following antibacterial test and the like were carried out. 152257.doc •24_ 201138627 (Manufacturing Example 2-3) The fiber treating agent of Production Example 2 - 1 was diluted to a capacity of 丨〇 times with distilled water, and the cloth of size Α4 was impregnated into the fiber containing in the metal drum. The solution of the treatment agent was for 5 seconds. Here, the fabric is Nylon (Nyl〇n, basis weight 110 g/m2). Then, extrusion was carried out using a roller compactor with a pressure between the rolls of 4 〇 kg/m2 (extrusion rate: 5〇%), using a hot air dryer at i2〇 The film of Example 2-2 was produced by drying at a temperature of <>c for 2 minutes and heat-treating at 150 °C for 丨min. (Example 2-3) In Example 2-3, a fiber treating agent was prepared in Production Example 2, and the fabric was processed in the following Production Example 2-4 using the fiber treating agent of Production Example 2_ The fabric is processed, and the following antibacterial test is performed. (Manufacturing Example 2-4) The fiber treating agent of Production Example 2-1 was diluted to a capacity of 15 times by using distilled water. The cloth of the size A4 was immersed in a solution containing the fiber treating agent in a metal drum for 5 seconds. bell. Here, the fabric is a polyester/cotton blend (65 〇/./35%) plain weave 2 structure (basis weight 120 g/m2). Then, 'the extrusion was carried out using a roller compactor having a pressure between the rolls of 4 〇kg/m 2 (extrusion ratio: 7〇%)', which was dried for 3 minutes at the temperature of the bribe, and heat-treated under the armpit. This production example 2-3 Processing cloth. (Example 3-1) In Example 3, a surface treating agent was prepared in the following Production Example 3_丨, and a fiber treating agent was prepared in the following Production Example 3-2. Further, in the production example μ, the synthetic surface leather was produced by using the surface treatment agent of Production Example 3 and the fiber treatment agent of Production Example 3_2, and 152257.doc • 25·201138627 synthetic leather. (Production Example 3-1) (1C) and (2C) of Table 8 were sufficiently mixed in a powder state, and the mixture was added to (3C), and stirred and mixed by AGI Homomixer (manufactured by Primix Co., Ltd., TK Robomix). A surface treatment agent for an antibacterial treatment agent for synthetic leather was prepared for 5 minutes. (1C) Antibacterial composition 2-(4-thiazolyl)-1Η-benzimidazole (35 mass%), 1H-2-benzimidazolylamine decanoate (35 mass%), And a mixture of silver-containing male acid (30% by mass) 0.025 g (2C) mixture of anti-allergic agent zirconium phosphate (70% by mass) and tannic acid (30% by mass) 1.0 g (3C) treating agent Leatheroid LU- 4305SP (Daily Seiki Co., Ltd.) 100 g (Production Example 3-2) Using the above-mentioned LabStar LMZ06 and using 0.5 mm diameter cerium oxide beads, the (3D) distilled water is used to dilute (1D) and (1) 2D) The mixture was mashed and mixed for 20 minutes to prepare a fiber treatment agent for synthetic leather. [Table 9] (ID) Anti-mite agent Glass powder containing boron oxide (10% by mass) 20 g (2D) Adhesive resin Evafanol AS-21 (曰华化工股份有限公司) 200 g (3D) Distilled water - 780 g ( Production Example 3-3) First, 2 g of the fiber treating agent of Production Example 3-2 was uniformly sprayed on the back surface (base fabric side) of a synthetic leather having a size of 20 x 20 cm, using a hot air dryer at 152257.doc -26 - Dry at 201138627 110 C for 5 minutes. Then, the surface treatment agent 4 g' of the production example 3_丨 was applied to the surface (silver side) by a bar coater again. Dry at <t for 5 minutes. As a result, a synthetic leather was produced as an antibacterial molded article of Example %. The synthetic leather was made of a silver-based surface made of polyacrylic acid S-ruthenium and the base fabric was PET (poly-p-butyl phthalate). 〇〇% 编 帛 。. (Example 3-2) A surface treating agent was prepared in Production Example 3-1 in Example 3-2, and a fiber treating agent was prepared in the following Production Example 3-2. In the production example 3_4, the synthetic leather was processed by using the surface treatment agent of Production Example 3-1 and the fiber treatment agent of Production Example 3-2. (Production Example 3-4) First, 2 g of the fiber treating agent of Production Example 3-2 was applied to the back surface (base fabric side) of a synthetic leather having a size of 20 x 20 cm by a gravure roll, and a hot air dryer was used at 110 ° C. Dry at the temperature for 5 minutes. Then, 4 g of the surface treatment agent of Production Example 3-1 was applied to the surface (silver side) by a bar coater, and dried again at a temperature of 110 ° C for 5 minutes. Thus, a processed synthetic leather which is an antibacterial molded article of Example 3-2 was produced. Synthetic leather is made of a silver surface made of polyamino phthalate and the base fabric is a nylon 100% woven fabric. (Example 4-1) In Example 4-1, a fiber treating agent was prepared in the following Production Example 4-1, and the fiber treating agent was used in the following Production Example 4-2. Thereby making a processing fabric. (Production Example 4-1) 152257.doc •27·201138627 The mixture of (1E) to (3E) of Table 10 was diluted with distilled water (4E) in a beaker and stirred, and the above-mentioned LabStar LMZ06 was used and the diameter was used. The 0.5 mm zirconia beads were mashed and mixed for 30 minutes to prepare a fiber treating agent as an antibacterial treating agent. (1E) Antibacterial composition 2-(4-thiazolyl)-1Η-benzimidazole (35 mass%), 1H-2-benzimidazolylamine decanoate (35 mass%), And a mixture of silver-loaded yttrium phosphate (30% by mass) 60 g (2E) Anti-allergic agent cerium oxide 75 g (3E) Dispersing agent Noigen TDS-100 (First Industrial Pharmaceutical Co., Ltd.) 60 g (4E) Distilled water - 855 g (Production Example 4-2) The fiber treatment agent (35 g) of Production Example 4-1, the Neostecker SI (10 g) manufactured by Shunhua Chemical Co., Ltd., and 455 g of distilled water were mixed, and the size was set in a metal drum. The fabric of A4 was immersed in a solution containing a fiber treatment agent for 10 seconds. Here, the fabric is a PET 100% Tricot fabric having a basis weight of 270 g/m2. Then, extrusion was carried out using a roller compactor having a pressure of 4.0 kg/cm 2 (extrusion ratio: 95%), and dried by a hot air dryer at a temperature of 120 ° C for 10 minutes. Thus, a processed fabric as an antimicrobial molded article of Example 4-1 was produced. (Example 4-2) In Example 4-2, a fiber treating agent was prepared in Production Example 4-1, and a fiber treating agent was used in the following Production Example 4-3 to process a fabric. Make and process fabrics. 152257.doc -28-201138627 (Production Example 4-3) The fiber treatment agent (35 g) of Production Example 4-1, Neosetker SI (10 g) manufactured by Rihua Chemical Co., Ltd., and Yuhua Chemical Co., Ltd. Manufactured * anti-imine-imine cross-linking agent NK Assist Cl 1 0 g (crosslinking agent) and steamed water 445 g mixed, the fabric of size A4 was immersed in the metal barrel to the solution containing the fiber treatment agent 1 second. Here, the cloth is made of PET 100% Tricot fabric having a basis weight of 270 g/m2. Then, extrusion was carried out by means of a press machine having an inter-roller pressure of 4.0 kg/cm (extrusion ratio: 95%), and dried by a hot air dryer at a temperature of 120 C for 1 minute. Thus, a processed fabric as an antibacterial molded article of Example 4-2 was produced. (Comparative Example 1-1) In Comparative Example 1-1, the same as the filter paper used in Example U was prepared and was not spray-processed. (Comparative Example 1-2) In Comparative Example 1-2, the same as the polyester woven fabric used in Example 1-2 was prepared and was not spray-processed. (Comparative Example 2-1) In Comparative Example 2-1, a fiber treating agent was prepared in the following Production Example 5-1, and the fabric was processed in the following Production Example 5-2 using the fiber treating agent of Production Example 5, This is used to make processing cold. (Production Example 5-1) After mixing and stirring (1F) to (3F) of Table 11 in a beaker, the above-mentioned LabStar LMZ06 was used and pulverized by a oxidized conical bead having a diameter of 5 Å, for 3 minutes. A fiber treatment agent is prepared. σ 152257.doc -29- 201138627 [表Η] (IF) Antibacterial composition zinc pyrithione 1 OA (2F) anti-allergic agent Polyphenon 70A -- 20 g (Mitsui Nonglin Co., Ltd., (3F) Adhesive Resin Light Epoch AX-30 300 g (Hokko Chemical Co., Ltd.) (Production Example 5-2) The fiber treating agent of Production Example 5-1 was diluted to a capacity of 2 times with distilled water, and the size was A4 in a metal drum. The fabric was immersed in a solution containing a fiber treatment agent for 5 seconds. Here, the cloth was made of a standard cotton woven cotton cloth No. 3. " Then, the squeezing was carried out using a roller press having a pressure between rolls of 4.0 kg/cm2. (Extrusion ratio: 1% by weight), and dried in a hot air dryer at 12 (minute at rc temperature to prepare a processed cloth of Comparative Example 2-1. (Comparative Example 2-2) In Comparative Example 2-2 In the production example, a fiber treatment agent was prepared, and the fabric was processed using the fiber treatment agent of the production example w in Production Example 5-3, thereby producing a processed fabric, and the following antibacterial property test was carried out. (Production Example 5-3) The steaming water will dilute the fiber treatment agent of the manufacturing example 5 _ 1 to the capacity of i 〇, and the size of the gold (four) is A4. The cloth was immersed in a solution containing a fiber treating agent for 5 seconds. Here, the cloth was spun nylon. Then, the press was performed using a press machine having a pressure between rolls of 〇kg/cm2 (extrusion ratio: 50%) 'Using a hot air dryer at 12 () t clock' under (10) heat treatment for 1 minute, thereby producing Comparative Example 2: 152257.doc -30- 201138627 Fabric. (Comparative Example 2-3) Comparative Example 2-3 In the production example 5_丨, a fiber treatment agent was prepared, and in the production example 5·4, the fabric was processed using the fiber treatment agent of the production example 5_丨, thereby producing a processed fabric. ' (Production Example 5-4) Using distilled water The fiber treating agent of Production Example 5-1 was diluted to a capacity of 15 times. The cloth of size A4 was dipped in a solution containing the fiber treating agent in a metal drum for 5 seconds. Here, the cloth was polyester/ Cotton mixed (65%/35%) plain weave (weight: 120 g/m2). Then, it is extruded by a pressure-sensitive machine with a pressure between rolls of 4 〇kg/m2 (extrusion rate: 7〇%). It was dried by a hot air dryer at a temperature of 120 ° C for 3 minutes, and heat-treated at ISO t for 丨 minutes to prepare a processed fabric of Comparative Example 2-3 (Comparative Example 3). In Comparative Example 3, in the production example 3-3 of Example 3-1, the fiber treatment agent was not sprayed on the back side of the synthetic leather, and 4 g of Leatheroid LU-4305SP (manufactured by Otsuka Seika Chemical Co., Ltd.) was applied instead of the production example. In the same manner as in Example 3-1, an unprocessed synthetic leather of Comparative Example 3 containing no antibacterial composition, anti-allergic agent, or anti-mite agent was prepared except that the surface treatment agent of the crucible was used. (Comparative Example 4) In Comparative Example 4, in the production example 4-1 of Example 4-1, the (4 £) laughter water of Table 1 was increased to 930 g without using (2E) cerium oxide of Table 10. (75) A fiber treatment agent J 0 152257.doc -31·201138627 was prepared under the same conditions as in Production Example 4-1, and the prepared fiber treatment agent (35 g), manufactured by Rihua Chemical Co., Ltd. A processing fabric was produced under the same conditions as in Production Example 4-2 except that Neostecker SI (10 g) was mixed and used as a solution containing a fiber treating agent. (Comparative Example 5) In Preparation Example 5, 'Preparation and Example 4_ 1 PET 100% Tricot fabric used is the same and unprocessed. Secondly, 'antibacterial test' of the molded articles of the examples and comparative examples' anti-fungal test, aphid inhibition test and anti-allergen test. (Antibacterial test) Antibacterial tests were carried out on the fabrics of Examples 2-1 to 2-3, 4-1, 4-2 and Comparative Examples 2-1 to 2-3, 5. The antibacterial test was based on JIS_L_ 1902 (2002) It is carried out by the absorption method. The strains use Staphylococcus aureus and Klebsiella pneumoniae, in Examples 2-1 to 2-3, 4-1, 4- 2 and Comparative Example. 2-1 to 2-3, 5 cloth and cotton standard white cloth were inoculated with the bacterial liquid, and the bactericidal activity value was calculated using the following formula (number); the results are shown in Table 12. Bactericidal activity value = Log(a/b)...(Number 1) a : Number of bacteria immediately after inoculation of cotton standard white cloth b: Number of bacteria after 18 hours of cloth culture. 152257.doc -32· 201138627 [Table 12] Sample sterilization activity * 1± Value S. aureus K. pneumoniae Example 2-1 L. Processed fabric (close-knit cotton No. 3) > 1.5 1.4 Example 2-2 Processed fabric (nylon) > 1.5 1.3 Example 2-3 Processed fabric (polyester /cotton) >1.5 1.4 Comparative Example 2-1 Processing fabric using other antibacterial agents (close-knit cotton cloth No. 3) > 1.5 1.2 Comparative Example 2-2 Processing fabric using other antibacterial agents (nylon) >1.5 1.2 Comparison Example 2-3 Processed fabric using other antibacterial agents (polyester/cotton) > 1.5 1.1 Example 4-1 Processed fabric (PET Tricot) 1.2 > 1.5 Example 4·2 Processed fabric (PET Tricot) 1.3 > 1.5 Comparative Example 5 Unprocessed fabric (PET Tricot) -1.0 -0.8 If Examples 2-1 to 2-3, 4-1, and 4-2 are compared with Comparative Examples 2-1 to 2-3 and 5, then Got : Examples 2-1 to 2-3,4-1,4-2 because it contains 2- (4- ° saliva plug-yl) lH-benzo sings and discharge 1H-2- benzimidazole. By sitting on the guanidinium decanoate, a processed cloth having excellent antibacterial properties is obtained. On the other hand, it was found that Comparative Example 5 does not have antibacterial properties because it does not contain the antibacterial composition of the present invention. Further, 'Comparative Examples 2-1 to 2-3 have a general antibacterial agent other than the present application, and therefore have been confirmed to have antibacterial properties. (Antifungal performance test) For Examples 1-1, 1-2, and 2-1 2-3, 3-1, 3-2, 4-1, 4-2 and Comparative Examples 1-1, 1-2, 2-1 to 2-3, 3 filter paper, synthetic leather, fabric anti-fungal performance test. The furnace and paper of Example 1-1 were sprayed at room temperature for one hour using a spray prepared by using the prepared aqueous spray. A 3 cm x 3 cm square was cut out from the center of the crepe paper, and the spray surface was used as the front side to carry out the following 20-method antifungal performance test. Further, the paper of Comparative Example 1-1, which was not sprayed with a water-based nozzle, was similarly cut into 3 cm><3 cm square' performed the following two methods of antifungal activity 152257.doc -33-201138627. For the synthetic leathers of Examples 3-1, 3-2 and Comparative Example 3, 3 cm x 3 cm square was cut out, and the silver surface was used as the front side, and the following 20-method mold-proof performance test was carried out. For the fabrics of Examples 1-2, 2-1 to 2-3, 4-1, 4-2 and Comparative Examples ι. 2, 2-1 to 2-3, 3 cm was also taken. <3 cm square, the following 20-method anti-fungal performance test was carried out. In the mold-proof performance test, the test bacteria shown in Table 14 were used, and the examples 1 _ 1, 1 _2, 2-1 to 2-3, 3-1, 3-2 were confirmed according to the following test methods and criteria. The antifungal properties of 4-1, 4-2 and Comparative Examples 1-1, 1-2, 2-1 to 2-3, 3. (Method for testing mold resistance) (Preparation of culture medium) (1) The medium used for the mold resistance test was used in JI; S-type medium was added with potato dextrose culture solution (Potato Dextrose Broth, manufactured by Difco Co., Ltd.) The plate medium was composed as shown in Table 13 below. This was heat-sterilized at 121 ° C for 2 Torr. (Composition of medium) [Table 13] 1.000 ml 3-0 g 10 g 0-5 g 0.25 g 0.002 g 7.0 g 25 g Purified water ammonium nitrate potassium dihydrogen phosphate magnesium nitrate heptahydrate potassium sulfate iron (II) Heptahydrate potato dextrose broth (manufactured by Difco Co., Ltd.) Agar 152257.doc -34 201138627 (Preparation of test bacterial solution) (2) The test bacteria of Table 14 were inoculated in the medium prepared in (1), and sufficiently cultured. 20 ml of the wetting solution of the composition of the following Table 15 was added to the culture dish to recover the spores. After the spore solution was filtered, the number of spores was prepared to be lxl06±1 / 'mL. When the spore concentration is high, the composition liquid obtained by removing agar from the above JIS standard medium is diluted. (Types of test bacteria) [Table 14] 1 Alternaria 2, black fungus 3, variegated fungus 4, soil fungus 5, rot fungus, Aureobasidium pullulans, 7 globosa, 8 genus Cladosporium 9 Fusarium sporogenes 10 Vibrio genus 11 Fusarium oxysporum 12 Myxosporium fungus 13 Scleroderma sinensis 14 Rhizoctonia solani 15 Paecilomyces variabilis 16 Penicillium citrinum 17 Penicillium funiculosum 18 Purple cocci 28 small Mycelium 20 Trichoderma viride (composition of moisturizing liquid) [Table 15] Purified water 1,000 ml Sodium dioctyl sulfosuccinate 0.05 g 152257.doc -35· 201138627 (culture) · Prepared in (1) After the spore liquid prepared in (2) was inoculated on the medium, the synthetic paper of the filter papers of Examples 1-1 and 1-1, and the synthetic leathers of Examples 3-1, 3-2 and Comparative Example 3 were respectively carried thereon and carried out. After processing fabrics of Examples 1-2, 2-1 to 2-3, 4-1, 4-2 and Comparative Examples 1-2 and 2-1 to 2-3, using a circulator with a humidity temperature controller, The temperature was maintained at 29 ± 1 ° C, and the humidity was maintained at 85% R · Η or higher for 28 days. Further, the growth status of the mold was visually confirmed weekly (confirmed on the first week, the second week, the third week, and the fourth week after the start of the culture), and evaluated according to the five evaluation levels shown in Table 16 below. The results are shown in Table 17. [Table 16] Evaluation of bacterial growth on the surface of the sample 0 Bacteria did not grow at all 1 10% or less Growth 2 10 to 30% or less Growth 3 30 to 60% or less Growth 4 60% or more completely grown [Table 17] Samples 1 week later 2 weeks After 4 weeks after 3 weeks, Example 1-1 Processing filter paper 0 0 0 0~1 Example 1-2 Processing cloth 0 0 0 0 Comparative example 1-1 Processing paper 2 3 4 4 Comparative example 1-2 Processing cloth 2 3 4 4 Example 2-1 Processed fabric 0 0 0 0 Example 2-2 0 0 0 0 Example 2-3 0 0 0 0 Comparative Example 2-1 Other antibacterial agent processing cloth 0 1 3 3 Comparative Example 2 -2 0 1 3 3 Comparative Example 2-3 0 1 3 3 -36- 152257.doc 201138627 After 1 week, 2 weeks, 2 weeks later, 2 4, Deutsche, Example 3-1, processed synthetic leather 0 〇 1 Λ Example 3-2 Processed synthetic leather (gravure) 0 0 〇U π Comparative example 3 Unprocessed synthetic leather 1 2 3 U 实施 Example 4-1 Processed fabric—0 0 0 J Λ Example 4-2 0 0 0 U 0 Right Comparing the examples 1 -1 1-2, 2-1 to 2-3, 3-1 3_2, 4-1, 4-2 with the comparative examples M, i-2, W to 2_3, 3, It is understood that each embodiment can obtain filter paper having excellent mold resistance, synthetic leather, Silk. On the other hand, it was found that each of the comparative examples did not have antifungal properties because it did not contain the antibacterial composition of the present invention. (Spiral Inhibition Test) 1-2, 3-1, 3-2, 4-1, 4_2 and Comparative Examples Aphid inhibition was carried out on the filter paper, synthetic leather, and cloth of Examples 1-1, i-2, 3, and 5. test. According to the JIS_L_1920 proliferation inhibition test a method, the aphid test examples 丨 to 3 were carried out as a tapeworm inhibition test. Specifically, the worm is a European house dust worm (the Tokyo Women's University). The paper, synthetic leather, and cloth (4) of the examples and comparative examples cut into a diameter of 4 (10) were placed on a petri dish, and a mites medium containing 7 〇 ± 1 。 was seeded thereon. Thereafter, the cells were cultured at 25 ± 2 and 75 ± 5% RH2 j , and the number of aphids in the fourth and sixth weeks was counted, and the total number of survivals was determined three times. The growth inhibition rate was calculated from the average survival number obtained and the following formula (number 2). Proliferation inhibition rate (%) = 10 〇 x (cd) / c (number 2) C: Average survival number on unprocessed molded articles (filter paper, synthetic leather, fabric) d. Processed molded articles (filter paper, synthetic leather, Average survival number on the cloth (Vibrio sinensis test example 1) 152257.doc • 37- 201138627 In the aphid test example 1, the processing filter paper of Example 1-1 having a diameter of 4 cm and the comparative example 1-1 were used. The sprayed unprocessed filter paper was used as a sample and tested by the above method. Further, the processed synthetic leather of Example 1-2 and Comparative Example 1-2 was used as a sample, which was cut into a circular shape having a diameter of 4 cm and the base fabric was faced upward, and the test was carried out in the above manner. The results after 6 weeks are shown in Table 18. [Table 18] Survival cochlear number proliferation inhibition rate (%) after 6 weeks of initial survival of locusts Example 1-1 225 2 > 99.9 Example 1-2 3 > 99.9 Comparative Example 1-1 6,977 • Comparative Example 1 -2 7,023 - (Aphid test example 2) In the aphid test example 2, the processed fabric of Examples 3-1 and 3-2 and the unprocessed synthetic leather of Comparative Example 3 were used as a sample, and cut into a diameter of 4 cm. The test was carried out by rounding the base fabric face up. The results after 4 weeks and 6 weeks are shown in Table 19. [Table 19] Inhibition rate of survival of aphids after 4 weeks of initial survival of aphids (%) Proliferation inhibition rate of survival of aphids after 6 weeks (%) Example 3-1 223 9 (99.8) 28 (99.7) Example 3 2 8 (99.8) 27 (99.7) Comparative Example 3 3,894 10,920 (Aphid Test Example 3) 152257.doc -38 - 201138627 In the aphid test example 3 'Working fabrics and comparative examples using Examples 4_1, 4-2 The unprocessed fabric of 5 was used as a sample 'cut it into a circle having a diameter of * cm and tested by the above method. The results after 4 weeks and 6 weeks are shown in Table 20. [Table 20] Inhibition rate of survival of aphids after 4 weeks of initial survival of aphids (%) Proliferation inhibition rate of survival of aphids after 6 weeks (%) Example 4-1 174 0 (97.5) f>99.9) Example 4- 2 206 168 0 (97.6) (>99.9) Comparative Example 5 6,939 16,275 (Evaluation) If Examples 1-1, 1-2, 3-1, 3-2, 4-1, 4-2 and Comparative Examples When 1-1, 1 - 2, 3, and 5 were compared, it was found that each of the examples can obtain processed filter paper having excellent anti-mite properties, processed synthetic leather, and processed fabric. Further, the fabrics of Examples 4-1 and 4-2 obtained the following results: the reproduction of about 5, 4 ticks which can be propagated on a circular cloth having a diameter of 4 cm (12_5 cm2) was suppressed. Since it is said that each corpse of dust mites (European house dust mites, American house dust mites) will produce 100 ng of Df allergen (refer to Mighty Checker (Sumika Enviro-Science Co., Ltd.) operating instructions), it is suppressed Corresponding to 430 mg/m2 of allergen, it is known to be related to the reduction of anti-allergic agents. In addition, the aphid inhibition test is suitable for the growth of dust mite (25±2. (:, 75 ± 5% RH, The bait) was propagated, and the result was not the number of proliferation under normal conditions. 152257.doc -39- 201138627 (anti-allergen test) For Examples 1-1, 1-2, 3-1, 3-2, 4-1 The anti-allergen test was carried out on the filter paper, the cloth, and the synthetic leather of Comparative Example 1-1, 1-2' 3, and 4. In the anti-allergen test for the processing filter paper of Example 1-1,

The concentration of Mite Extract-Df (American House Dust Mites: manufactured by COSMO BIO Co., Ltd.) was diluted to 8 pg/ml using a dish acid buffer. Further, 20 ml of the processed filter paper of Example 1-1 was cut out and placed in a test tube, followed by the addition of 3.5 ml of the above-mentioned diluted allergen solution, and the filter paper was impregnated. Mix in a water bath with a water temperature of 3 7 C for more than 24 hours. Thereafter, 0.1 ml of the /colum solution in the test tube was taken and added to the Mighty Checker (Sumika Enviro.

Extracted by the Science Co., Ltd.). After 〇 水平 horizontally, the allergen is deactivated according to the color status of the detection line window. Furthermore, the determination by the AND and the detection line window is performed in the same manner as in the following embodiment, and the embodiment is as follows.

Synthesis of 2, 4-1, 4-2 and Comparative Examples ", n 3, 4 filter paper, cloth leather anti-allergen test. The results are shown in Table 2 (determination of the detection line window) in the usual situation ++ : Clear and thicker clear lines «Minami needs to be removed» + : It is clear that the lines are clear (usually the average level of the family). It is known that the faint color (good level) _·· completely uncolored (very satisfactory) Level) I52257.doc 201138627 [Table 21] Sample Determination Example 1-1 Processing Filter Paper Comparative Example 1-1 Unprocessed Paper ++ Example 1-2 Processed Fabric Comparative Example 1-2 Unprocessed Fabric Example 3 1 Processed synthetic leather Example 3-2 Comparative Example 3 Unprocessed synthetic leather ++ Example 4·1 Processed fabric (PET Tricot) Example 4-2 - Comparative Example 4 Processed fabric (no anti-allergic agent, PET Tricot) • H- (Evaluation) It is understood that Examples 1-1, 1_2, 3-1, 3-2, 4-1, and 4-2 contain the composition of the present invention, so that processing paper and processing excellent in anti-allergic properties are obtained. Cloth, processed synthetic leather. On the other hand, Comparative Example 3 does not contain as an anti-allergic agent. The results of the anti-allergic test were inferior to those of Examples 3-1 and 3-2. Further, it was found that Comparative Example 4 contained 2-(4-β-Sermyl)_iH-benzimidazole, 1H-2- Benzimidazolamide-based methyl decanoate and Thiabendazole, but not containing zirconia as an anti-allergic agent, are therefore less resistant to allergies than Examples 4-1 and 4-2. In order to confirm the durability improvement effect of the crosslinking agent, the PET 100% Tricot fabric of Examples 4-1, 4-2 and Comparative Example 4 was subjected to a predetermined number of household washing treatments in accordance with JIS 0217-103. (JIS [ 0217_ 103 : Household washing conditions). Adding a temperature of 4 〇χ: water to a household washing machine suitable for the above JIS standard, adding a synthetic lotion for clothing to a ratio of 2 g with respect to 1 L of water, 152257 .doc • 41 - 201138627 Dissolve it into a washing liquid. Put the sample and the required load cloth into the washing liquid at a bath ratio of 1:30, and start the operation. After 5 minutes of treatment, stop the operation and use the dehydrator. Dewatering the sample and the load cloth, and then changing the washing liquid to a new water at room temperature, in the same bath ratio After washing for 2 minutes, the mixture was washed for 2 minutes, dehydrated, and dried without being exposed to direct sunlight. Thereafter, the PET 100% Tricot fabric of Example 4-1, Example 4-2, and Comparative Example 4 was subjected to antibacterial treatment. Test, mold resistance test, aphid inhibition test, anti-allergen test. The results are shown in Tables 22 and 23. Further, in Tables 22 and 23, 10HL indicates the case where the home washing was performed 10 times, and 30HL indicates the case where the home washing was performed 30 times. [Table 22] Antibacterial test Antifungal performance test Sterilization activity 'ft value (Staphylococcus aureus) Evaluation of 5 grades after 4 encounters 10HL 30HL Initial 10HL 30HL Example 4-1 > 1.5 0.7 -0.1 0 0~ 1 2 Example 4-2 > 1.5 > 1.5 > 1.5 0 0 0 Comparative Example 4 - 1.0 - 1.2 - 1.2 4 4 4 [Table 23] Aphid inhibition test Anti-allergic test Proliferation inhibition rate (%) Mighty Checker Initial 10HL 30HL Initial 10HL 30HL Example 4-1 >99.9 90.0 70 - 士 + Example 4-2 >99.9 >99.9 97.3 _ - Comparative Example 4 - - - ++ ++ -H- (Evaluation) 152257.doc -42- 201138627 It is known that Example 4-2 contains a crosslinking agent in addition to the composition of the present invention, so that even if it is washed 30 times or more, it maintains antibacterial, antifungal, anti-mite, anti-allergy. Sex. On the other hand, it was found that Example 4·1 which does not contain a crosslinking agent has no antibacterial property, mold resistance, cochlear resistance, and antiallergic property as compared with Example 4-2. Further, in Comparative Example 4, although it contains 2·(4·thiazolyl)_1Η_benzimidazole, 1Η-2-benzoimidazolium carboxylic acid decyl ester, and rot, but does not contain an oxidizing port, it is known that for comparison Example 4, antibacterial, anti-mite, anti-mite, anti-allergic when washing more than twice, less than Example 1, 4-2 ° 152257.doc • 43-

Claims (1)

201138627 VII. Patent Application Range: 1 . A composition comprising: an antibacterial composition having at least two antibacterial agents selected from the group consisting of imidazole-based organic antibacterial agents, and a deactivating agent for an allergy-inducing substance. 2. The composition of the present invention, wherein the organic antimicrobial agent of the above-mentioned (4) has a compound having a benzo-salt ring and an anthracene group, and a compound having a benzo-oxime ring and a urethane group. 3. The composition of the claim , contains an inorganic antibacterial agent. 4. The composition of claim 3, wherein the inorganic antibacterial agent of the blister & bing 1P is silver-loaded. 5. The composition of claim 1 which comprises an insecticide. 6_ such as the composition of the smudge item 5, the beans in the a, A, the above-mentioned worms are oxidized and have their vitreous. 7. The composition of claim 1, wherein the above-mentioned decommissioning of the allergic-inducing substance is carried out by the "Mr. 矾M#", which is derived from natural polyphenols, 忐 忐 (4) cheeks, phenolic phenols, and inorganic solids At least one of the following: 8. An antibacterial treatment agent which contains the composition of claim R and a dispersion medium. 〃 9. The antibacterial treatment agent of claim 8 which contains a binder resin. The antibacterial treatment agent according to claim 8, which comprises a crosslinking agent. 11. The antibacterial treatment agent according to claim 8, wherein the six antibacterial treatment agent of the above-mentioned antibacterial treatment agent g, a paint, a coating agent, a physiotherapy agent任任任+ 纟面处理剂, and ed. 152257.doc 201138627 12. An antibacterial treatment agent for an antibacterial molded article, which is formed by depositing a layer on a resin film. The item is treated with any one of a fiber, a cloth, a resin film, and a laminate of fibers or cloth. 13. 152257.doc 201138627 IV. Designated representative drawings: (1) The representative representative of the case is: (none) (2) A brief description of the symbol of the representative figure: When the case if the formula, please reveal the best features of the invention show a chemical formula: (None) 152257.doc