US20160222496A1 - Metal powder for powder metallurgy, compound, granulated powder, and sintered body - Google Patents

Metal powder for powder metallurgy, compound, granulated powder, and sintered body Download PDF

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Publication number
US20160222496A1
US20160222496A1 US15/002,769 US201615002769A US2016222496A1 US 20160222496 A1 US20160222496 A1 US 20160222496A1 US 201615002769 A US201615002769 A US 201615002769A US 2016222496 A1 US2016222496 A1 US 2016222496A1
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United States
Prior art keywords
powder
sintered body
mass
less
metal powder
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Abandoned
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US15/002,769
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English (en)
Inventor
Hidefumi Nakamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
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Seiko Epson Corp
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Assigned to SEIKO EPSON CORPORATION reassignment SEIKO EPSON CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NAKAMURA, HIDEFUMI
Publication of US20160222496A1 publication Critical patent/US20160222496A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • B22F1/0059
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0257Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0285Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/09Mixtures of metallic powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • B22F2003/248Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/35Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/14Both compacting and sintering simultaneously
    • B22F3/15Hot isostatic pressing

Definitions

  • the present inventors have made intensive studies to find conditions for obtaining a sintered body having a high density without performing an additional treatment. As a result, they found that the density of a sintered body can be increased by optimizing the chemical composition and the crystal structure of each particle contained in a metal powder, and thus completed the invention.
  • the content of C in the particle 1 is set to 0.1% by mass or more and 2% by mass or less, but is set to preferably 0.35% by mass or more and 1.15% by mass or less, more preferably 0.4% by mass or more and 1.1% by mass or less. If the content of C is less than the above lower limit, crystal grains are liable to grow depending on the overall composition so that the mechanical properties of the sintered body are insufficient. On the other hand, if the content of C exceeds the above upper limit, the amount of C is too large depending on the overall composition so that the sinterability is deteriorated instead.
  • E1/E2 is preferably 0.58 or more and 5.76 or less, more preferably 0.96 or more and 3.84 or less.
  • E1/E2 is preferably 0.16 or more and 1.58 or less, more preferably 0.26 or more and 1.05 or less.
  • the presence of the high Si concentration region 4 can also be determined by, for example, a mapping analysis by energy dispersive X-ray spectrometry (EDX).
  • EDX energy dispersive X-ray spectrometry
  • the content E1 of the first element and the content E2 of the second element are as described above, respectively, however, the sum of the contents of these elements is preferably 0.05% by mass or more and 0.6% by mass or less, more preferably 0.10% by mass or more and 0.48% by mass or less, further more preferably 0.12% by mass or more and 0.24% by mass or less.
  • (E1+E2)/C is preferably 1 or more and 16 or less, more preferably 2 or more and 13 or less, further more preferably 3 or more and 10 or less.
  • JIS G 1221 Iron and steel—Methods for determination of vanadium content
  • the “major axis” is the maximum length in the projected image of the particle
  • the “minor axis” is the maximum length in the direction perpendicular to the major axis.
  • the average of the aspect ratio can be obtained as the average of the measured aspect ratios of 100 or more particles.
  • the molding conditions in the case of an extrusion molding method are preferably such that the material temperature is about 80° C. or higher and 210° C. or lower, and the extrusion pressure is about 50 MPa or more and 500 MPa or less (0.5 t/cm 2 or more and 5 t/cm 2 or less), which vary depending on the respective conditions.
  • the degreased body may be subjected to a machining process such as grinding, polishing, or cutting.
  • the degreased body has a relatively low hardness and relatively high plasticity, and therefore, the machining process can be easily performed while preventing the degreased body from losing its shape. According to such a machining process, a sintered body having high dimensional accuracy can be easily obtained in the end.
  • A2-A1 is preferably 0.1% or more and 3% or less, more preferably 0.2% or more and 2% or less.
  • the sintered body showing the value of A2-A1 within the above range not only has necessary and sufficient mechanical strength, but also can easily flatten the surface. That is, by polishing the surface of such a sintered body, a surface having high specularity can be obtained.
  • Cooling method water cooling
  • this granulated powder was subjected to powder compacting under the following molding conditions.
  • a press molding machine was used.
  • the shape of the molded body to be produced was determined to be a cube with a side length of 20 mm.
  • the circle equivalent diameter of the Fe-based alloy crystal was 1% or more and 100% or less the circle equivalent diameter of the particle. Specifically, the lowest ratio of the circle equivalent diameter of the Fe-based alloy crystal to the circle equivalent diameter of the particle was 2%, and the highest ratio thereof was 84%.
  • the tensile strength of the sintered body is slightly low (1200 MPa or more and less than 1400 MPa).
  • the fatigue strength of the sintered body is 555 MPa or more and less than 575 MPa.
  • the Vickers hardness was measured in accordance with the Vickers hardness test method specified in JIS Z 2244 (2009).
  • the average number of the Fe-based alloy crystals was 6 or more.
  • the average number of the Fe-based alloy crystals was 1 or more and 5 or less.
  • the circle equivalent diameter of the Fe-based alloy crystal was 1% or more and 100% or less the circle equivalent diameter of the particle.
  • the specularity of the surface is high (the specular gloss is 150 or more and less than 200).

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)
US15/002,769 2015-01-29 2016-01-21 Metal powder for powder metallurgy, compound, granulated powder, and sintered body Abandoned US20160222496A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015016091A JP6319121B2 (ja) 2015-01-29 2015-01-29 粉末冶金用金属粉末、コンパウンド、造粒粉末および焼結体の製造方法
JP2015-016091 2015-01-29

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US20160222496A1 true US20160222496A1 (en) 2016-08-04

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US (1) US20160222496A1 (enrdf_load_stackoverflow)
EP (1) EP3050985B1 (enrdf_load_stackoverflow)
JP (1) JP6319121B2 (enrdf_load_stackoverflow)
CN (1) CN105834413B (enrdf_load_stackoverflow)

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JPH0729776Y2 (ja) 1988-07-19 1995-07-12 三菱農機株式会社 ロータリにおけるセンサー取付構造
CN106777807B (zh) * 2017-01-13 2020-09-25 北京航空航天大学 一种粉末冶金随机粒度分布3d有限元建模与仿真方法
SE541309C2 (en) * 2017-10-09 2019-06-25 Uddeholms Ab Steel suitable for hot working tools
EP4190933B1 (en) * 2017-10-31 2025-07-16 Proterial, Ltd. Alloy powder
JP7110629B2 (ja) * 2018-03-08 2022-08-02 セイコーエプソン株式会社 粉末冶金用金属粉末、コンパウンド、造粒粉末および焼結体

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US20160136729A1 (en) * 2013-06-27 2016-05-19 Robert Bosch Gmbh Method for producing a steel shaped body
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US20160136729A1 (en) * 2013-06-27 2016-05-19 Robert Bosch Gmbh Method for producing a steel shaped body
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Also Published As

Publication number Publication date
CN105834413B (zh) 2020-03-17
EP3050985B1 (en) 2019-05-22
JP6319121B2 (ja) 2018-05-09
CN105834413A (zh) 2016-08-10
JP2016141820A (ja) 2016-08-08
EP3050985A1 (en) 2016-08-03

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