US20160222496A1 - Metal powder for powder metallurgy, compound, granulated powder, and sintered body - Google Patents
Metal powder for powder metallurgy, compound, granulated powder, and sintered body Download PDFInfo
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- US20160222496A1 US20160222496A1 US15/002,769 US201615002769A US2016222496A1 US 20160222496 A1 US20160222496 A1 US 20160222496A1 US 201615002769 A US201615002769 A US 201615002769A US 2016222496 A1 US2016222496 A1 US 2016222496A1
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- United States
- Prior art keywords
- powder
- sintered body
- mass
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- metal powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- B22F1/0059—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
- C22C33/0285—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/09—Mixtures of metallic powders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
- B22F2003/248—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2301/00—Metallic composition of the powder or its coating
- B22F2301/35—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
- B22F3/15—Hot isostatic pressing
Definitions
- the present inventors have made intensive studies to find conditions for obtaining a sintered body having a high density without performing an additional treatment. As a result, they found that the density of a sintered body can be increased by optimizing the chemical composition and the crystal structure of each particle contained in a metal powder, and thus completed the invention.
- the content of C in the particle 1 is set to 0.1% by mass or more and 2% by mass or less, but is set to preferably 0.35% by mass or more and 1.15% by mass or less, more preferably 0.4% by mass or more and 1.1% by mass or less. If the content of C is less than the above lower limit, crystal grains are liable to grow depending on the overall composition so that the mechanical properties of the sintered body are insufficient. On the other hand, if the content of C exceeds the above upper limit, the amount of C is too large depending on the overall composition so that the sinterability is deteriorated instead.
- E1/E2 is preferably 0.58 or more and 5.76 or less, more preferably 0.96 or more and 3.84 or less.
- E1/E2 is preferably 0.16 or more and 1.58 or less, more preferably 0.26 or more and 1.05 or less.
- the presence of the high Si concentration region 4 can also be determined by, for example, a mapping analysis by energy dispersive X-ray spectrometry (EDX).
- EDX energy dispersive X-ray spectrometry
- the content E1 of the first element and the content E2 of the second element are as described above, respectively, however, the sum of the contents of these elements is preferably 0.05% by mass or more and 0.6% by mass or less, more preferably 0.10% by mass or more and 0.48% by mass or less, further more preferably 0.12% by mass or more and 0.24% by mass or less.
- (E1+E2)/C is preferably 1 or more and 16 or less, more preferably 2 or more and 13 or less, further more preferably 3 or more and 10 or less.
- JIS G 1221 Iron and steel—Methods for determination of vanadium content
- the “major axis” is the maximum length in the projected image of the particle
- the “minor axis” is the maximum length in the direction perpendicular to the major axis.
- the average of the aspect ratio can be obtained as the average of the measured aspect ratios of 100 or more particles.
- the molding conditions in the case of an extrusion molding method are preferably such that the material temperature is about 80° C. or higher and 210° C. or lower, and the extrusion pressure is about 50 MPa or more and 500 MPa or less (0.5 t/cm 2 or more and 5 t/cm 2 or less), which vary depending on the respective conditions.
- the degreased body may be subjected to a machining process such as grinding, polishing, or cutting.
- the degreased body has a relatively low hardness and relatively high plasticity, and therefore, the machining process can be easily performed while preventing the degreased body from losing its shape. According to such a machining process, a sintered body having high dimensional accuracy can be easily obtained in the end.
- A2-A1 is preferably 0.1% or more and 3% or less, more preferably 0.2% or more and 2% or less.
- the sintered body showing the value of A2-A1 within the above range not only has necessary and sufficient mechanical strength, but also can easily flatten the surface. That is, by polishing the surface of such a sintered body, a surface having high specularity can be obtained.
- Cooling method water cooling
- this granulated powder was subjected to powder compacting under the following molding conditions.
- a press molding machine was used.
- the shape of the molded body to be produced was determined to be a cube with a side length of 20 mm.
- the circle equivalent diameter of the Fe-based alloy crystal was 1% or more and 100% or less the circle equivalent diameter of the particle. Specifically, the lowest ratio of the circle equivalent diameter of the Fe-based alloy crystal to the circle equivalent diameter of the particle was 2%, and the highest ratio thereof was 84%.
- the tensile strength of the sintered body is slightly low (1200 MPa or more and less than 1400 MPa).
- the fatigue strength of the sintered body is 555 MPa or more and less than 575 MPa.
- the Vickers hardness was measured in accordance with the Vickers hardness test method specified in JIS Z 2244 (2009).
- the average number of the Fe-based alloy crystals was 6 or more.
- the average number of the Fe-based alloy crystals was 1 or more and 5 or less.
- the circle equivalent diameter of the Fe-based alloy crystal was 1% or more and 100% or less the circle equivalent diameter of the particle.
- the specularity of the surface is high (the specular gloss is 150 or more and less than 200).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
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JP2015016091A JP6319121B2 (ja) | 2015-01-29 | 2015-01-29 | 粉末冶金用金属粉末、コンパウンド、造粒粉末および焼結体の製造方法 |
JP2015-016091 | 2015-01-29 |
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US20160222496A1 true US20160222496A1 (en) | 2016-08-04 |
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US15/002,769 Abandoned US20160222496A1 (en) | 2015-01-29 | 2016-01-21 | Metal powder for powder metallurgy, compound, granulated powder, and sintered body |
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US (1) | US20160222496A1 (enrdf_load_stackoverflow) |
EP (1) | EP3050985B1 (enrdf_load_stackoverflow) |
JP (1) | JP6319121B2 (enrdf_load_stackoverflow) |
CN (1) | CN105834413B (enrdf_load_stackoverflow) |
Families Citing this family (5)
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JPH0729776Y2 (ja) | 1988-07-19 | 1995-07-12 | 三菱農機株式会社 | ロータリにおけるセンサー取付構造 |
CN106777807B (zh) * | 2017-01-13 | 2020-09-25 | 北京航空航天大学 | 一种粉末冶金随机粒度分布3d有限元建模与仿真方法 |
SE541309C2 (en) * | 2017-10-09 | 2019-06-25 | Uddeholms Ab | Steel suitable for hot working tools |
EP4190933B1 (en) * | 2017-10-31 | 2025-07-16 | Proterial, Ltd. | Alloy powder |
JP7110629B2 (ja) * | 2018-03-08 | 2022-08-02 | セイコーエプソン株式会社 | 粉末冶金用金属粉末、コンパウンド、造粒粉末および焼結体 |
Citations (6)
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US4299623A (en) * | 1979-11-05 | 1981-11-10 | Azbukin Vladimir G | Corrosion-resistant weldable martensitic stainless steel, process for the manufacture thereof and articles |
US4434006A (en) * | 1979-05-17 | 1984-02-28 | Daido Tokushuko Kabushiki Kaisha | Free cutting steel containing controlled inclusions and the method of making the same |
US6827755B2 (en) * | 2001-09-21 | 2004-12-07 | Hitachi, Ltd. | High-toughness and high-strength ferritic steel and method of producing the same |
US20100258217A1 (en) * | 2001-02-09 | 2010-10-14 | Questek Innovatioans Llc | Nanocarbide Precipitation Strengthened Ultrahigh-Strength, Corrosion Resistant, Structural Steels |
US20160136729A1 (en) * | 2013-06-27 | 2016-05-19 | Robert Bosch Gmbh | Method for producing a steel shaped body |
US10094007B2 (en) * | 2013-10-24 | 2018-10-09 | Crs Holdings Inc. | Method of manufacturing a ferrous alloy article using powder metallurgy processing |
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FR2158687A5 (enrdf_load_stackoverflow) * | 1971-10-28 | 1973-06-15 | Poudres Grenailles Metal | |
JPS53125207A (en) * | 1977-04-09 | 1978-11-01 | Daido Steel Co Ltd | Stainless steel sintered body |
JP2817587B2 (ja) * | 1993-09-17 | 1998-10-30 | 住友金属工業株式会社 | ボイラ用耐摩耗複層鋼管およびその製造方法 |
SE0000002L (sv) * | 2000-01-01 | 2000-12-11 | Sandvik Ab | Förfarande för tillverkning av ett FeCrAl-material och ett sådant marerial |
SE526249C2 (sv) * | 2003-12-05 | 2005-08-02 | Erasteel Kloster Ab | Stålmaterial samt användning av detta material |
SE0401707D0 (sv) * | 2004-07-02 | 2004-07-02 | Hoeganaes Ab | Stainless steel powder |
CN101284308A (zh) * | 2007-04-12 | 2008-10-15 | 吴旭升 | 低镍奥氏体不锈钢粉末及其应用 |
JP5311941B2 (ja) * | 2007-11-13 | 2013-10-09 | セイコーエプソン株式会社 | 粉末冶金用金属粉末、焼結体および焼結体の製造方法 |
JP5270926B2 (ja) * | 2008-02-20 | 2013-08-21 | 三菱製鋼株式会社 | 鉄基焼結合金粉末 |
CN101797640A (zh) * | 2009-02-05 | 2010-08-11 | 台耀科技股份有限公司 | 烧结硬化原料粉末及其烧结坯体 |
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- 2015-01-29 JP JP2015016091A patent/JP6319121B2/ja active Active
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2016
- 2016-01-20 CN CN201610037413.6A patent/CN105834413B/zh active Active
- 2016-01-21 US US15/002,769 patent/US20160222496A1/en not_active Abandoned
- 2016-01-27 EP EP16152921.9A patent/EP3050985B1/en active Active
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US20100258217A1 (en) * | 2001-02-09 | 2010-10-14 | Questek Innovatioans Llc | Nanocarbide Precipitation Strengthened Ultrahigh-Strength, Corrosion Resistant, Structural Steels |
US6827755B2 (en) * | 2001-09-21 | 2004-12-07 | Hitachi, Ltd. | High-toughness and high-strength ferritic steel and method of producing the same |
US20160136729A1 (en) * | 2013-06-27 | 2016-05-19 | Robert Bosch Gmbh | Method for producing a steel shaped body |
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CN105834413B (zh) | 2020-03-17 |
EP3050985B1 (en) | 2019-05-22 |
JP6319121B2 (ja) | 2018-05-09 |
CN105834413A (zh) | 2016-08-10 |
JP2016141820A (ja) | 2016-08-08 |
EP3050985A1 (en) | 2016-08-03 |
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