US20150174799A1 - Molding method of resin molded product and resin molded product - Google Patents
Molding method of resin molded product and resin molded product Download PDFInfo
- Publication number
- US20150174799A1 US20150174799A1 US14/130,003 US201214130003A US2015174799A1 US 20150174799 A1 US20150174799 A1 US 20150174799A1 US 201214130003 A US201214130003 A US 201214130003A US 2015174799 A1 US2015174799 A1 US 2015174799A1
- Authority
- US
- United States
- Prior art keywords
- resin
- core member
- molded product
- resin sheets
- sheets
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 339
- 239000011347 resin Substances 0.000 title claims abstract description 339
- 238000000465 moulding Methods 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000012765 fibrous filler Substances 0.000 claims abstract description 24
- 238000005187 foaming Methods 0.000 claims abstract description 16
- 238000003466 welding Methods 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 12
- 230000008018 melting Effects 0.000 claims abstract description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 43
- 230000002349 favourable effect Effects 0.000 description 18
- 239000003063 flame retardant Substances 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 13
- 238000010586 diagram Methods 0.000 description 11
- 230000037303 wrinkles Effects 0.000 description 11
- 239000006260 foam Substances 0.000 description 10
- 239000000758 substrate Substances 0.000 description 9
- 239000012792 core layer Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
- 230000003014 reinforcing effect Effects 0.000 description 6
- 239000012508 resin bead Substances 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 239000002826 coolant Substances 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- BEZJLTXBBPGWIL-UHFFFAOYSA-N C1CCCCCCCCCCC1.[Br].[Br].[Br].[Br].[Br].[Br] Chemical compound C1CCCCCCCCCCC1.[Br].[Br].[Br].[Br].[Br].[Br] BEZJLTXBBPGWIL-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000000703 anti-shock Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- -1 for example Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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- 239000003381 stabilizer Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000013518 transcription Methods 0.000 description 1
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- 238000004804 winding Methods 0.000 description 1
Images
Classifications
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- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0017—Combinations of extrusion moulding with other shaping operations combined with blow-moulding or thermoforming
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
- B29C44/1228—Joining preformed parts by the expanding material
- B29C44/1233—Joining preformed parts by the expanding material the preformed parts being supported during expanding
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- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C48/25—Component parts, details or accessories; Auxiliary operations
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/20—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor of articles having inserts or reinforcements ; Handling of inserts or reinforcements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
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- B29C65/022—Particular heating or welding methods not otherwise provided for
- B29C65/028—Particular heating or welding methods not otherwise provided for making use of inherent heat, i.e. the heat for the joining comes from the moulding process of one of the parts to be joined
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- B29C65/74—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by welding and severing, or by joining and severing, the severing being performed in the area to be joined, next to the area to be joined, in the joint area or next to the joint area
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- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
- B29C66/43—Joining a relatively small portion of the surface of said articles
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- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/814—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
- B29C66/8141—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
- B29C66/81427—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined comprising a single ridge, e.g. for making a weakening line; comprising a single tooth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/814—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
- B29C66/8141—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
- B29C66/81431—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined comprising a single cavity, e.g. a groove
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
- B29K2025/04—Polymers of styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
- B32B2250/246—All polymers belonging to those covered by groups B32B27/32 and B32B27/30
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2451/00—Decorative or ornamental articles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
Definitions
- the present invention relates to a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets into a laminated product.
- patent document 1 WO2009/157197
- patent document 2 Japanese Patent Laid-Open Ser. No. 2011-51224
- patent document 3 Japanese Patent Laid-Open Ser. No. 2011-51227
- the reinforcing core member is welded onto the sheet-shaped parisons formed in a contour along cavities of the split molds; hence, the sheet-shaped parisons are cooled by the split molds and are easily hardened, and the welding strength between the reinforcing core member and the sheet-shaped parisons is lowered depending on cases.
- patent document 4 Japanese Patent Laid-Open Ser. No. 2008-222208 discloses a core board obtained by monoblock-pressing a laminated structure in which a first fibrous substrate, a thermoplastic foam core layer, and a second fibrous substrate are laminated in this order.
- the fibrous substrate includes entangled nonwoven fabric including a fibrous material and a resin binder, and the melting point of the resin element constituting the thermoplastic foam core layer is higher than that of the resin binder.
- PATENT DOCUMENT 2 Japanese Patent Laid-Open Ser. No. 2011-51224
- PATENT DOCUMENT 3 Japanese Patent Laid-Open Ser. No. 2011-51227
- PATENT DOCUMENT 4 Japanese Patent Laid-Open Ser. No. 2008-222208
- thermoplastic foam core layer on assumption that the contour of the thermoplastic foam core layer is stably retained even during the heating in the monoblock press, the surface of the thermoplastic foam core layer is not melted.
- the present invention has been made in consideration of the situation above and aims at providing a molding method of a resin molded product and a resin molded product in which it is possible to increase the welding strength between the core member and the resin sheets.
- the present invention has the following aspects.
- the molding method of a resin molded product in accordance with the present invention is
- a molding method of a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets in a melted state into a laminated product characterized in that:
- the resin sheets comprise fibrous filler, the method comprising:
- a molding step in which the core member and the resin sheets are clamped by a metallic mold, to mold the resin molded product.
- the resin molded product in accordance with the present invention is
- a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets into a laminated product, characterized in that:
- the resin sheets comprise fibrous filler
- the resin molded product comprises a laminated structure in which the core member with melted surfaces and the resin sheets in a melted state are welded onto each other into one block.
- the resin sheets in the melted state include the fibrous filler, it is possible to suppress the draw-down; hence, the molding can be conducted by extruding the resin sheets at a high temperature and it is possible to more securely melt the surfaces of the core member to weld the core member onto the resin sheets. As a result, the welding strength between the core member and the resin sheets can be improved. Also, by making the resin sheets in the melted state include the fibrous filler, it is possible to enhance rigidity of the molded product.
- FIG. 1 is a diagram showing a configuration example of a resin molded product 100 of the present embodying mode.
- FIG. 2 is a diagram showing a general configuration example of a molding device 60 to mold the resin molded product 100 of the present embodying mode.
- FIG. 3 is a diagram showing a state in which a flask member 128 is brought into contact with a resin sheet P.
- FIG. 4 is a diagram showing a state in which the resin sheet P is brought into contact with a split mold 32 .
- FIG. 5 is a diagram showing a state in which one of the resin sheets P is formed in a contour.
- FIG. 6 is a diagram showing a state in which a core member 102 is welded onto one of the resin sheets P.
- FIG. 7 is a diagram showing a state in which the other one of the resin sheets P is formed in a contour.
- FIG. 8 is a diagram showing a state in which the split mold 32 is clamped.
- FIG. 9 is a diagram showing a state in which the split mold 32 is unclamped.
- FIG. 10 is diagram showing a relationship example among thickness A of the resin sheets P, thickness B of the core member 102 , and depth C of the split mold 32 in a situation in which the resin sheets P and the core member 102 are compressed by the split mold 32 .
- FIG. 1 shows a configuration example of an embodying mode of the resin molded product 100 in accordance with the present invention
- FIGS. 2 , 6 , and 8 show a molding method example of the embodying mode of the resin molded product 100 in accordance with the present invention.
- the resin molded product 100 in accordance with the present invention is, as shown in FIG. 1 , a resin molded product 100 in which a core member 102 including a foaming element is interposed between at least two resin sheets 101 into a laminated product.
- the resin sheets 101 configuring the resin molded product 100 in accordance with the present invention contain fibrous filler.
- the molding is conducted by use of, for example, a molding device 60 shown in FIG. 2 ; as shown in FIGS. 6 and 8 , while melting the surfaces of the core member 102 by heat of the resin sheets P, the core member 102 and the resin sheets P are welded onto each other. Also, as shown in FIG. 8 , the core member 102 and the resin sheets P are clamped by the mold 32 , to mold the resin molded product 100 .
- the resin sheets P in the melted state contain fibrous filler, it is possible to suppress the draw-down.
- This makes it possible to conduct the molding by extruding the resin sheets P at a high temperature, and it is possible to more securely melt the surfaces of the core member 102 to weld the core member 102 and the resin sheets P onto each other.
- the welding strength between the core member 102 and the resin sheets P can be improved.
- FIG. 1 is a diagram showing a configuration example of the resin molded product 100 of the present embodying mode.
- the resin molded product 100 of the present embodying mode may be employed, for example, for a deck board of a car.
- the resin molded product 100 of the present embodying mode includes lamination in which a core member 102 including a foaming element is interposed between the resin sheets 101 .
- the core member 102 including a foaming element configures the inner side of the resin molded product 100 and includes styrene-based resin as its main component (at least 30 wt % or more). By configuring it using styrene-based resin as the main component, it is possible to enhance rigidity in a high-temperature environment (for example, 90° C. or more).
- styrene-based resins acrylonitrile-styrene copolymer (AS), acrylonitrile-butadiene-styrene copolymer (ABS), polystyrene (PS), and anti-shock polystyrene (HIPS) may be considered.
- an item obtained through the molding in which resin beads including a foaming agent are filled in a mold and are heated to foam and an item molded by foam extrusion may be employed.
- heat-resistive foaming polystyrene-based beads for example, Kanepearl (registered trademark) and Heatmax (registered trademark) made by Kaneka Inc.
- low-foaming molding heat-resistive foaming polystyrene-based beads for example, Kanepearl (registered trademark) and Heatmax (registered trademark) HM5 made by Kaneka Inc.
- foaming heat-resistive AS-based resin for example, Heatpole (registered trademark) made by JSP Inc.
- the core member 102 employed as the car deck board preferably has, from a point of view of decrease in weight, a foaming rate of 15 times or more. Also, it favorably has a heat resistive property, specifically, a dimensional change ratio of ⁇ 0.5% in 168 hours at 80° C.
- the monomer composition configuring the resin beads favorably includes ⁇ -methyl styrene at 10 wt % or more and 80 wt % or less, acrylonitrile at 5 wt % or more and 50 wt % or less, and styrene-based monomer at 85 wt % or less; more favorably, ⁇ -methyl styrene at 10 wt % or more and 50 wt % or less, acrylonitrile at 5 wt % or more and 35 wt % or less, and styrene-based monomer at 80 wt % or less.
- the core member 102 is highly heat resistive and is suitably used for the car deck board.
- the styrene-based monomers there may be considered styrene, and various substituted styrene such as chlorstyrene, para-methyl styrene, and t-butyl styrene.
- the resin beads used for the core member 102 may contain a fire retardant agent.
- a fire retardant agent which develops the fire retardant property and which does not deteriorate the heat resistive property and the foaming property, it is favorable that the fire retardant agent has a decomposition temperature of 210° C. or more, and more favorably, the melting point of the fire retardant agent is 80° C. or more.
- halogen-based fire retardant agent can be considered; specifically, hexabrom cyclododecan, tetrabrom bisphenol A, diallyl ether, and monochlor penthabrom cyclohexane can be considered; among these, hexabrom cyclododecan is favorable.
- the dose of the fire retardant agent favorably ranges from 1 wt % to 15 wt % in the resin beads, more favorably, 3 wt % to 10 wt % therein.
- the fire retardant assistant agent employed for such purpose a radical generating agent such as peroxide is used in general; however, as a favorable fire retardant assistant agent to develop the fire retardant property in the present embodying mode, a fire retardant assistant agent having a half-life temperature per hour of 150° C. or more and 250° C. or less is favorable.
- the resin sheet 101 configures the outer side of the resin molded product 100 and, in the resin sheet 101 , like in the core member 102 , styrene-based resin is contained at least 30 wt % or more.
- the core member 102 and the resin sheet 101 contain styrene-based resin at least 30 wt % or more; hence, it is possible to enhance rigidity in a high-temperature environment (for example, 90° C. or more).
- the resin sheet 101 of the present embodying mode includes fibrous filler. Since the resin sheet 101 of the present embodying mode includes fibrous filler, it is possible to enhance rigidity.
- the fibrous filler there can be considered Warastonite, potassium titanate whiskers, glass fiber, carbon fiber, and the like; particularly, glass fiber and carbon fiber are favorable.
- the value (aspect ratio) obtained by dividing the length of fiber by the diameter of fiber favorably ranges from 250 to 2000; in particular, from 500 to 1200 from the viewpoint of appropriate molding and improvement of rigidity.
- the length of fiber ranges from 8 mm to 20 mm and the diameter of fiber is equal to or less than 30 ⁇ m. This is because when the fiber length is less than 8 mm, the improvement due to filler mixing is small for the heat resistive property and for the rigidity at a high temperature; and when the fiber length is more than 20 mm, the filler is not easily mixed with the substrate resin.
- fibrous filler with the fiber length from 10 mm to 20 mm and the fiber diameter from about 14 ⁇ m to about 17 ⁇ m is contained in a range from 20 wt % to 40 wt % (more favorably, about 30 wt %) in the resin sheet 101 .
- the melting point of the styrene-based resin used for the resin sheet 101 is favorably higher than that of the styrene-based resin used for the core member 102 . This makes it possible that while melting the surfaces of the core member 102 by the heat of the resin sheet 101 in the melted state, the core member 102 and the resin sheet 101 are welded onto each other.
- FIG. 2 shows a configuration example of a molding device 60 to mold the resin molded product 100 of the present embodying mode
- FIGS. 2 to 9 show a molding process example to mold the resin molded product 100 of the present embodying mode.
- the molding device 60 of the present embodying mode includes an extruding machine 12 , a clamping machine 14 , and a core member inserting machine (not shown).
- the molding device 60 of the present embodying mode two resin sheets P in a melted state are extruded from the extruding machine 12 to arrange the two resin sheets P between the split molds 32 configuring the clamping machine 14 .
- one of the resin sheets P is formed in a contour along a cavity 116 of the split mold 32 , and onto the one resin sheet P thus formed, a core member 102 beforehand molded is welded by the core member inserting machine (not shown).
- the other one resin sheet P is formed in a contour along a cavity 116 of the split mold 32 , and the split mold 32 is clamped to weld the core member 102 onto the other one resin sheet P, and the resin sheets P are welded onto each other, to mold a resin molded product 100 in which the core member 102 and the other one resin sheet P are configured in one block.
- the extruding machine 12 includes a cylinder 18 equipped with a hopper 16 , a screw (not shown) disposed in the cylinder 18 , an electric motor 20 coupled with the screw, an accumulator 22 communicatively connected to the cylinder 18 , a plunger 24 communicatively connected to the accumulator 22 , and a T die 28 .
- the resin sheet P extruded from the extruding slit of the T die 28 is clamped by a pair of rollers 30 disposed with a gap therebetween and is delivered downward to be suspended between the split molds 32 .
- the resin sheet P is arranged between the split molds 32 in a state in which the sheet P has uniform thickness in the perpendicular direction (extruding direction).
- Extruding performance of the extruding machine 12 is appropriately selected in consideration of the size of the resin molded product to be molded and the prevention of occurrence of the draw-down or the neck-in of the resin sheet P.
- the extruding quantity of one shot in the intermittent extrusion favorably ranges from 1 kg to 10 kg
- the extruding speed of the resin sheet P from the extruding slit is several hundreds of kg/h or more; or, more preferably, 700 kg/h or more.
- the extrusion of the resin sheet P is favorably as short as possible; although depending on the kind of resin, the MFR value, and the melt tension value, it is favorable in general that the extrusion is completed within 40 seconds; or, more preferably, in a range from 10 seconds to 20 seconds.
- the extruding quantity per unitary area (1 cm 2 ) and unitary time (h) of the thermoplastic resin from the extruding slit is 50 kg/h cm 2 or more; or, more preferably, 150 kg/h cm 2 or more.
- thermoplastic resin having a density of 0.9 g/cm 3 it is regarded that the thermoplastic resin having a weight of 1.8 kg is extruded per one shot in 15 seconds, to obtain through calculation that the extruding speed is 432 kg/h and the extruding speed per unitary area is about 86 kg/h cm 2 .
- the extruding slit disposed in the T die 28 is arranged downward in a perpendicular direction, and the resin sheet P extruded from the extruding slit is perpendicularly transported downward in a state in which it suspends directly from the extruding slit.
- the extruding slit by changing the slit gap, it is possible to change thickness of the resin sheet P.
- the resin sheet P extruded from the T die 28 is favorably adjusted such that in a state in which it is suspended between the split molds 32 , that is, when it is clamped, thickness thereof in the extruding direction is uniform. In this situation, it is also possible to change the slit gap such that the slit gap is gradually enlarged beginning at the extrusion start point to be maximum at the extrusion end point.
- the thickness of the resin sheet P extruded from the T die 28 is gradually enlarged beginning at the extrusion start point; however, the resin sheet P extruded in the melted state is extended by its own weight to be gradually thinner from the lower end to the upper end of the sheet; hence, the thick portion extruded by enlarging the slit gap cancels the thin portion due to extension by the draw-down phenomenon, to thereby conduct the adjustment for the uniform thickness from the upper end to the lower end of the sheet.
- a resin sheet P pinched between a pair of rollers 30 is downward fed by the rotations of the pair of rollers 30 , to extend and to thin down the resin sheet P; by adjusting the relationship between the extruding speed of the resin sheet P extruded from the T die 28 and the feeding speed of the resin sheet P fed by the pair of rollers 30 , it is possible to prevent occurrence of the draw-down or the neck-in of the resin sheet P. Hence, it is possible to mitigate restrictions on the kind of resin to be adopted, in particular, on the MFR value, the MT value, and the extruding quantity per unitary time.
- the pair of rollers 30 are arranged to have axial symmetry with respect to the resin sheet P extruded in a state in which it downward suspends from the extruding slit.
- the diameter of the rollers 30 and the length in the axial direction of the rollers 30 are appropriately set according to the extruding speed of the resin sheet P to be molded, the length in the extruding direction of the resin sheet P, the width thereof, the kind of resin, and the like. Further, in respective outer surfaces of the pair of rollers 30 , there are disposed wrinkles in the contour of depressions and projections.
- the wrinkles in the contour of depressions and projections are favorably disposed in the outer surfaces of the rollers 30 , to be uniformly distributed throughout the surfaces to be brought into contact with the resin sheet P, and the depth and the density thereof are only to be appropriately determined so that the resin sheet P is smoothly fed downward by the pair of rollers 30 , in consideration of prevention of occurrence of slippage between the respective outer surfaces of the pair of rollers 30 and the corresponding surfaces of the resin sheet P.
- it is possible to form the wrinkles in the contour of depressions and projections for example, by the sand-blast process, it is favorable to form them by a blast machine by adopting a coarse level of about coarse 60 .
- the wrinkles in the contour of depressions and projections disposed respectively in the pair of rollers 30 are not disposed to transcribe the wrinkle pattern onto the surfaces of the resin sheet P, but, intrinsically, are disposed to prevent occurrence of slippage between the respective outer surfaces of the pair of rollers 30 and the corresponding surfaces of the resin sheet P.
- one of the pair of rollers is a wrinkle roll and the other one thereof is a lubber roll; however, in the pair of rollers 30 of the present embodying mode, by disposing wrinkles in the outer surfaces respectively of the pair of rollers 30 , the pair of rollers 30 respectively and securely hold the corresponding surfaces of the resin sheet P; on the other hand, by restricting the pushing force onto the resin sheet P due to the pair of rollers 30 , it is possible to prevent, immediately after feeding the resin sheet P by the pair of rollers 30 , the transcription of the wrinkle pattern onto the surfaces of the resin sheet P.
- the pair of rollers 30 are made of metal, for example, aluminum; each of the paired rollers 30 is equipped with surface temperature adjusting means to adjust, depending on the temperature of the resin sheet P in the melted state, the surface temperature of the roller 30 ; in the configuration thereof, by flowing coolant through the inside of the roller 30 and by circulating the coolant, heat exchange is performed such that the surface of the roller 30 is not excessively heated by the resin sheet P in the melted state clamped by the pair of rollers 30 .
- the outer surfaces of the pair of rollers 30 are heated through heat conduction when the pair of rollers 30 are brought into contact with the resin sheet P in the melted state; by cooling the outer surfaces of the pair of rollers 30 from the inside, an event is prevented in which the resin sheet P in the melted state clamped by the pair of rollers 30 adheres onto the outer surface of the roller 30 and is wound around the roller 30 by the rotations of the roller 30 , and the resin sheet P is not fed downward.
- the surface temperature of the rollers 30 it is favorable to lower the surface temperature of the rollers 30 ; however, from the viewpoint of the molding of the resin sheet P later, when the surface temperature of the rollers 30 is too low, the resin sheet P in the melted state is contrarily cooled too much by the surfaces of the rollers 30 , to cause hindrances in the molding.
- the predetermined range of temperature is determined according to the kind of the resin sheet P in the melted state.
- the clamping machine 14 of the present embodying mode includes the split molds 32 and a mold driving machine (not shown) to move the split molds 32 in a direction substantially vertical to the supply direction of the resin sheets P between an open position and a closed position.
- the split molds 32 are arranged in a state in which the cavities 116 oppose each other, and the respective cavities 116 face substantially the perpendicular direction.
- depressions and projections are disposed according to the outer contour and the surface contour of the molded product to be molded based on the resin sheets P in the melted state.
- pinch-off sections 118 are formed in the peripheries of the cavities 116 of the split molds 32 .
- the pinch-off sections 118 are formed in a circular contour in peripheries of the cavities 116 and project toward the opposing split molds 32 .
- flask members 33 are arranged between the split molds 32 .
- the flask members 33 include openings 130 ; by use of flask member driving machines, not shown, the flask members 33 are moved toward the resin sheets P, and the flask members 33 are brought into contact with the resin sheets P, to hold the resin sheets P. Also, in the state in which the resin sheets P are kept held, the flask members 33 moves in the reverse direction, to bring the resin sheets P into contact with the tip ends of the pinch-off sections 118 of the split molds 32 ; and a sealed space is formed by the sheets of resin P, the pinch-off sections 118 , and the cavities 116 .
- the split molds 32 are driven by the mold driving machine (not shown) so that the resin sheets P in the melted state are arranged between the split molds 32 at the open position. Further, at the closed position, the pinch-off sections 118 of the split molds 32 make contact with each other, to form a sealed space in the split molds 32 . Incidentally, for the movement of each split mold 32 from the open position to the closed position, the closed position is the position of the central line of the resin sheets P in the melted state; each split mold 32 is driven by the mold driving machine and moves toward the position.
- the resin sheets P includes styrene-based resin as the main component.
- styrene-based resin as the main component.
- styrene-based resin employed for the resin sheets P a styrene-based resin which has MFR (measured at a test temperature of 230° C. and with a test load of 2.16 kg according to JIS K-7210) equal to or less than 3.5 g/10 min at 230° C. is applicable.
- MFR measured at a test temperature of 230° C. and with a test load of 2.16 kg according to JIS K-7210
- the resin sheets P of the present embodying mode include fibrous filler in order to possess the heat resistive property and rigidity.
- fibrous filler in order to possess the heat resistive property and rigidity.
- the draw-down is conspicuous and the molding is difficult; however, when the fibrous filler is contained in the resin sheets P, it is possible to suppress the influence of the draw-down.
- the surfaces of the core member 102 are melted by the heat of the resin sheets P; hence, it is favorable that when the resin sheets P are extruded from the T dies 28 , the temperature of the resin sheets P is 210° C. or more, and more preferably, 250° C. or more.
- the resin sheets P of the present embodying mode include fibrous filler.
- the resin sheets P of the present embodying mode from the viewpoint of the reduction in thickness and the improvement in rigidity, it is also possible to further add powder inorganic filler such as silica, mica, talc, calcium carbonate, and the like.
- powder inorganic filler such as silica, mica, talc, calcium carbonate, and the like.
- the quantity of added inorganic filler is increased, roughness appears on the surface of the molded product, and pinholes easily take place.
- plasticizers such as plasticizers, stabilizers, coloring agents, antistatic agents, fire retardants, foaming agents, and the like.
- the resin sheets P are extruded from the T dies 28 , and the extruded resin sheets P are fed through a pair of rollers 30 to adjust thickness of the resin sheets P and then are suspended between the pair of split molds 32 .
- the relative speed difference between the extruding speed of the resin sheets P and the feed speed at which the resin sheets P are fed downward by the pair of rollers 30 is adjusted by the rotation speed of the pair of rollers 30 such that when the resin sheets P pass between the pair of rollers 30 , they are drawn downward by the pair of rollers 30 and are extended to be reduced in thickness; as a result, occurrence of the draw-down or the neck-in is prevented.
- each of the pair of rollers 30 coolant is circulated through the roller 30 to cool the roller 30 , to set the temperature of the outer surface of each roller 30 to be lower in a predetermined temperature range than the temperature of the resin sheet P in a melted state, to prevent the event in which when the resin sheet P in a melted state is clamped by the pair of rollers 30 , the resin sheet P in a melted state adheres onto the surface the roller 30 and is wound around the roller 30 by the rotations of the roller 30 ; on the other hand, the resin sheet P is kept in a melted state suitable for the molding.
- the extruding slit gap adjustment may also be carried out.
- flask members 128 are moved by a flask member driving machine (not shown) toward the corresponding sheets of resin P, and as shown in FIG. 3 , the flask members 128 are brought into contact with the sheets of resin P, to hold the sheets of resin P by the flask members 128 .
- the flask members 128 are moved toward the split molds 32 , and as shown in FIG. 4 , the sheets of resin P are brought into contact with the pinch-off sections 118 of the split molds 32 , to form a sealed space 117 by the sheets of resin P, the pinch-off sections 118 , and the cavities 116 . Further, the core member 102 held by adsorbing plates 119 of a manipulator (not shown) is inserted between the split molds 32 as shown in FIG. 4 .
- the air in the sealed space 117 is sucked via the split molds 32 to push one of the sheets of resin P onto the cavity 116 , to form, as shown in FIG. 5 , the one sheet of resin P in a contour according to the cavity 116 .
- the manipulator is moved toward the split mold 32 on the right side, to push, as shown in FIG. 6 , the core member 102 onto the one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the right side, to weld the core member 102 onto the one resin sheet P.
- the resin sheet P of the present embodying mode includes styrene-based resin and fibrous filler; hence, even after the resin sheet P is formed in the contour of the cavity 116 , it is possible to retain the state of temperature to melt the surfaces of the core member 102 . Hence, when the core member 102 is pushed onto the resin sheet P, the surfaces of the core member 102 can be melted by the heat of the resin sheet P. As a result, in the present embodying mode, while melting the surfaces of the core member 102 by the heat of the resin sheet P, the core member 102 can be welded onto the resin sheet P.
- the adsorbing plates 119 are removed from the core member 102 and the manipulator is pulled to be removed from the space between the two split molds 32 , and the other one resin sheet P is pushed onto the cavity 116 , to form, as shown in FIG. 7 , the other one resin sheet P in the contour along the cavity 116 .
- the two split molds 32 are clamped by the mold driving machine, and as shown in FIG. 8 , the core member 102 is pushed onto the other one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the left side, to weld the core member 102 onto the other one resin sheet P. Moreover, peripheries respectively of the two resin sheets P are welded onto each other to form parting lines PL.
- the surfaces of the core member 102 of the present embodying mode are melted by the heat of the resin sheets P; hence, when the split molds 32 are clamped to mold a resin molded product 100 in which the core member 102 and the resin sheets P are formed in one block, it is favorable to compress the core member 102 and the resin sheets P by the split molds 32 . As a result, the welding strength between the core member 102 and the resin sheets P is further enhanced.
- the fibrous filler contained in the resin sheets P is easily pushed into the core member 102 ; hence, it is possible that the welding between the resin sheets P and the core member 102 is stronger and it is possible to mold the resin molded product 100 with high rigidity.
- it is favorable that the compression is performed in a range from about 0.5 mm to about 1.0 mm by each of the split molds 32 .
- the two split molds 32 are unclamped and the cavities 116 are removed from the completed resin molded product 100 , and then burrs formed in peripheries of the parting lines PL are removed. This completes the molding of the resin molded product 100 .
- the resin sheets 101 configuring the resin molded product 100 of the present embodying mode contain fibrous filler. And when molding the resin molded product 100 , while melting, as shown in FIGS. 6 and 8 , the surfaces of the core member 102 by the heat of the resin sheets P in the melted state, the core member 102 and the resin sheets P are welded onto each other. And as shown in FIG. 8 , the core member 102 and the resin sheets P are clamped by the split molds 32 , to mold the resin molded product 100 .
- the resin sheets P in the melted state contain fibrous filler, it is possible to suppress draw-down. This makes it possible that the molding is conducted by extruding the resin sheets P at high temperature and the surfaces of the core member 102 are more securely melted, to weld the core member 102 and the resin sheets P onto each other. As a result, the welding strength between the core member 102 and the resin sheets P can be improved. Also, by making the resin sheets P contain fibrous filler, it is possible to enhance rigidity of the resin molded product 100 .
- the core member 102 and the resin sheets P configuring the resin molded product 100 of the present embodying mode include styrene-based resin as the primary component, it is possible to further enhance the welding strength between the core member 102 and the resin sheets P and the rigidity of the resin molded product 100 .
- the embodying modes described above are favorable embodying modes of the present invention, and the scope of the present invention is not limited only to these embodying modes, but various changes may be made therein without departing from the gist of the present invention.
- the sheets of resin P are brought into contact with the pinch-off sections 118 of the split molds 32 , to form a sealed space 117 by the sheets of resin P, the pinch-off sections 118 , and the cavities 116 , and then the core member 102 is inserted between the split molds 32 .
- the core member 102 is beforehand inserted between the split molds 32 . This makes it possible to warm up the surfaces of the core member 102 by the heat of the sheets of resin P extruded from the T dies 28 .
- the core member 102 is sequentially welded onto the two resin sheets P.
- the core member 102 is sequentially welded onto the two resin sheets P. Specifically, first, one of the resin sheets P is arranged in the split molds 32 , to form the resin sheet P in a contour along the cavity of the split mold 32 , and then the core member 102 is welded onto the resin sheet P.
- the other one of the resin sheets P is arranged in the split molds 32 , to form the resin sheet P in a contour along the cavity of the split mold 32 , and then the core member 102 is welded onto the resin sheet P.
- the core member 102 is welded onto the resin sheets P extruded from the T dies 28 ; hence, the surfaces of the core member 102 can be easily melted by the heat of the resin sheets P.
- the core member 102 is welded onto the resin sheets P while melting the surfaces of the core member 102 by the heat of the resin sheets P.
- the surfaces of the core member 102 are warmed up in advance by warming means before the core member 102 is pushed onto the one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the right side and the core member 102 is welded onto the one resin sheet P.
- the surfaces of the core member 102 are warmed up by warming means before the core member 102 is pushed onto the other one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the left side and the core member 102 is welded onto the other one resin sheet P.
- timing to warm up the surfaces of the core member 102 by warming means is not particularly restricted; only if the timing is before the resin sheets P and the core member 102 are welded onto each other, it is possible to warm up the surfaces of the core member 102 at any timing.
- a decorative sheet is arranged between the split molds 32 such that the decorative sheet is welded onto the resin sheets P by clamping the split molds 32 .
- a decorative sheet is supplied together with the resin sheets P to a space between a pair of rollers 30 such that by adjusting the rotation speed of the pair of rollers 30 , thickness of the resin sheets P is adjusted and the decorative sheet is pushed to be tightly fixed onto the resin sheets P.
- the resin molded product 100 of the embodying mode described above is molded by interposing the core member 102 between two resin sheets P.
- the resin molded product 100 of the embodying mode is molded by interposing the core member 102 between at least two resin sheets P; for example, it is also possible to mold the product by interposing the core member 102 by four resin sheets P.
- the layer configuration of the resin molded product 100 in this situation is as resin sheet/resin sheet/core member/resin sheet/resin sheet.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
A molding method of a resin molded product in which it is possible to increase the welding strength between the core member and the resin sheets is provided. In a molding method of a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets in a melted state into a laminated product, wherein the resin sheets include fibrous filler, and while melting surfaces of the core member by heat of the resin sheets, the core member and the resin sheets are welded onto each other, and the core member and the resin sheets are clamped by a metallic mold, to mold the resin molded product.
Description
- The present invention relates to a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets into a laminated product.
- As technical literature filed prior to the present invention, there are literature (reference is to be made to, for example, patent document 1: WO2009/157197, patent document 2: Japanese Patent Laid-Open Ser. No. 2011-51224, and patent document 3: Japanese Patent Laid-Open Ser. No. 2011-51227) disclosing a molding method of a resin molded product in which a core member is interposed between two resin sheets into a laminated product.
- In patent document 1 to 3, two sheet-shaped parisons (corresponding to resin sheets) are supplied between split molds to form the sheet-shaped parisons in a contour along cavities of the split molds. Next, a beforehand molded reinforcing core member (corresponding to the core member) is inserted between the split molds and the reinforcing core member is welded onto one of the sheet-shaped parisons. Next, the split molds are clamped such that the reinforcing core member is welded onto the other one of the sheet-shaped parisons and the sheet-shaped parisons are welded onto each other, to mold a resin molded product in which the reinforcing core member and the sheet-shaped parisons are configured in one block. As a result, there is molded a resin molded product in which a core member is interposed between two resin sheets into a laminated product.
- Incidentally, in patent document 1 to 3, the reinforcing core member is welded onto the sheet-shaped parisons formed in a contour along cavities of the split molds; hence, the sheet-shaped parisons are cooled by the split molds and are easily hardened, and the welding strength between the reinforcing core member and the sheet-shaped parisons is lowered depending on cases.
- Under this circumstance, the development of a molding method capable of increasing the welding strength between the core member and the resin sheets has been regarded as necessary.
- Incidentally, as technical literature filed prior to the present invention, patent document 4 (Japanese Patent Laid-Open Ser. No. 2008-222208) discloses a core board obtained by monoblock-pressing a laminated structure in which a first fibrous substrate, a thermoplastic foam core layer, and a second fibrous substrate are laminated in this order.
- In patent document 4, the fibrous substrate includes entangled nonwoven fabric including a fibrous material and a resin binder, and the melting point of the resin element constituting the thermoplastic foam core layer is higher than that of the resin binder. As a result, while stably keeping the contour of the thermoplastic foam core layer even during the heating in the monoblock press, only the resin binder of the fibrous substrate is partly melted and the fibrous substrate is tightly fixed onto the surface of the thermoplastic foam core layer.
- PATENT DOCUMENT 1: WO2009/157197
- PATENT DOCUMENT 2: Japanese Patent Laid-Open Ser. No. 2011-51224
- PATENT DOCUMENT 3: Japanese Patent Laid-Open Ser. No. 2011-51227
- PATENT DOCUMENT 4: Japanese Patent Laid-Open Ser. No. 2008-222208
- In patent document 4, on assumption that the contour of the thermoplastic foam core layer is stably retained even during the heating in the monoblock press, the surface of the thermoplastic foam core layer is not melted.
- Hence, in the invention of literature 4 above, even when only the resin binder of the fibrous substrate is partly melted and the fibrous substrate is tightly fixed onto the surface of the thermoplastic foam core layer, there may appear a situation in which the welding strength between the fibrous substrate and the thermoplastic foam core layer is insufficient.
- The present invention has been made in consideration of the situation above and aims at providing a molding method of a resin molded product and a resin molded product in which it is possible to increase the welding strength between the core member and the resin sheets.
- To achieve the object, the present invention has the following aspects.
- The molding method of a resin molded product in accordance with the present invention is
- a molding method of a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets in a melted state into a laminated product, characterized in that:
- the resin sheets comprise fibrous filler, the method comprising:
- a welding step in which while melting surfaces of the core member by heat of the resin sheets, the core member and the resin sheets are welded onto each other; and
- a molding step in which the core member and the resin sheets are clamped by a metallic mold, to mold the resin molded product.
- The resin molded product in accordance with the present invention is
- a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets into a laminated product, characterized in that:
- the resin sheets comprise fibrous filler; and
- the resin molded product comprises a laminated structure in which the core member with melted surfaces and the resin sheets in a melted state are welded onto each other into one block.
- In accordance with the present invention, by making the resin sheets in the melted state include the fibrous filler, it is possible to suppress the draw-down; hence, the molding can be conducted by extruding the resin sheets at a high temperature and it is possible to more securely melt the surfaces of the core member to weld the core member onto the resin sheets. As a result, the welding strength between the core member and the resin sheets can be improved. Also, by making the resin sheets in the melted state include the fibrous filler, it is possible to enhance rigidity of the molded product.
-
FIG. 1 is a diagram showing a configuration example of a resin moldedproduct 100 of the present embodying mode. -
FIG. 2 is a diagram showing a general configuration example of amolding device 60 to mold the resin moldedproduct 100 of the present embodying mode. -
FIG. 3 is a diagram showing a state in which a flask member 128 is brought into contact with a resin sheet P. -
FIG. 4 is a diagram showing a state in which the resin sheet P is brought into contact with a split mold 32. -
FIG. 5 is a diagram showing a state in which one of the resin sheets P is formed in a contour. -
FIG. 6 is a diagram showing a state in which acore member 102 is welded onto one of the resin sheets P. -
FIG. 7 is a diagram showing a state in which the other one of the resin sheets P is formed in a contour. -
FIG. 8 is a diagram showing a state in which the split mold 32 is clamped. -
FIG. 9 is a diagram showing a state in which the split mold 32 is unclamped. -
FIG. 10 is diagram showing a relationship example among thickness A of the resin sheets P, thickness B of thecore member 102, and depth C of the split mold 32 in a situation in which the resin sheets P and thecore member 102 are compressed by the split mold 32. - (Outline of Resin Molded
Product 100 in Accordance with Present Invention) - First, by referring to
FIGS. 1 , 2, 6, and 8, description will be given of an outline of the resin moldedproduct 100 in accordance with the present invention.FIG. 1 shows a configuration example of an embodying mode of the resin moldedproduct 100 in accordance with the present invention, andFIGS. 2 , 6, and 8 show a molding method example of the embodying mode of the resin moldedproduct 100 in accordance with the present invention. - The resin molded
product 100 in accordance with the present invention is, as shown inFIG. 1 , a resin moldedproduct 100 in which acore member 102 including a foaming element is interposed between at least tworesin sheets 101 into a laminated product. - The
resin sheets 101 configuring the resin moldedproduct 100 in accordance with the present invention contain fibrous filler. - In the molding of the resin molded
product 100 in accordance with the present invention, the molding is conducted by use of, for example, amolding device 60 shown inFIG. 2 ; as shown inFIGS. 6 and 8 , while melting the surfaces of thecore member 102 by heat of the resin sheets P, thecore member 102 and the resin sheets P are welded onto each other. Also, as shown inFIG. 8 , thecore member 102 and the resin sheets P are clamped by the mold 32, to mold the resin moldedproduct 100. - As a result, it is possible to mold the resin molded
product 100 wherein thecore member 102 the surfaces of which are melted and the resin sheets P in the melted state are welded onto each other into a monoblock laminated structure. - Incidentally, in the molding of the resin molded
product 100 in accordance with the present invention, since the resin sheets P in the melted state contain fibrous filler, it is possible to suppress the draw-down. This makes it possible to conduct the molding by extruding the resin sheets P at a high temperature, and it is possible to more securely melt the surfaces of thecore member 102 to weld thecore member 102 and the resin sheets P onto each other. As a result, the welding strength between thecore member 102 and the resin sheets P can be improved. - Also, by making the resin sheets P in the melted state contain fibrous filler, it is possible to enhance rigidity of the resin molded
product 100. Next, referring to the accompanying drawings, description will be given in detail of the embodying mode of the resin moldedproduct 100 in accordance with the present invention. - First, referring to
FIG. 1 , description will be given of a configuration example of the resin moldedproduct 100 of the present embodying mode.FIG. 1 is a diagram showing a configuration example of the resin moldedproduct 100 of the present embodying mode. The resin moldedproduct 100 of the present embodying mode may be employed, for example, for a deck board of a car. - The resin molded
product 100 of the present embodying mode includes lamination in which acore member 102 including a foaming element is interposed between theresin sheets 101. - The
core member 102 including a foaming element configures the inner side of the resin moldedproduct 100 and includes styrene-based resin as its main component (at least 30 wt % or more). By configuring it using styrene-based resin as the main component, it is possible to enhance rigidity in a high-temperature environment (for example, 90° C. or more). As the styrene-based resins, acrylonitrile-styrene copolymer (AS), acrylonitrile-butadiene-styrene copolymer (ABS), polystyrene (PS), and anti-shock polystyrene (HIPS) may be considered. - As the
core member 102, an item obtained through the molding in which resin beads including a foaming agent are filled in a mold and are heated to foam and an item molded by foam extrusion may be employed. - As the resin beads, heat-resistive foaming polystyrene-based beads (for example, Kanepearl (registered trademark) and Heatmax (registered trademark) made by Kaneka Inc.) and low-foaming molding heat-resistive foaming polystyrene-based beads (for example, Kanepearl (registered trademark) and Heatmax (registered trademark) HM5 made by Kaneka Inc.) may be employed. Also, foaming heat-resistive AS-based resin (for example, Heatpole (registered trademark) made by JSP Inc.) may be employed.
- The
core member 102 employed as the car deck board preferably has, from a point of view of decrease in weight, a foaming rate of 15 times or more. Also, it favorably has a heat resistive property, specifically, a dimensional change ratio of ±0.5% in 168 hours at 80° C. - Incidentally, for the resin beads configuring the
core member 102, for example, the monomer composition configuring the resin beads favorably includes α-methyl styrene at 10 wt % or more and 80 wt % or less, acrylonitrile at 5 wt % or more and 50 wt % or less, and styrene-based monomer at 85 wt % or less; more favorably, α-methyl styrene at 10 wt % or more and 50 wt % or less, acrylonitrile at 5 wt % or more and 35 wt % or less, and styrene-based monomer at 80 wt % or less. For the composition within the range described above, thecore member 102 is highly heat resistive and is suitably used for the car deck board. As the styrene-based monomers, there may be considered styrene, and various substituted styrene such as chlorstyrene, para-methyl styrene, and t-butyl styrene. - Further, to assign a fire retardant property to the resin molded
product 100, the resin beads used for thecore member 102 may contain a fire retardant agent. As the fire retardant agent which develops the fire retardant property and which does not deteriorate the heat resistive property and the foaming property, it is favorable that the fire retardant agent has a decomposition temperature of 210° C. or more, and more favorably, the melting point of the fire retardant agent is 80° C. or more. For such fire retardant agent, halogen-based fire retardant agent can be considered; specifically, hexabrom cyclododecan, tetrabrom bisphenol A, diallyl ether, and monochlor penthabrom cyclohexane can be considered; among these, hexabrom cyclododecan is favorable. The dose of the fire retardant agent favorably ranges from 1 wt % to 15 wt % in the resin beads, more favorably, 3 wt % to 10 wt % therein. When the dose is less than 1 wt %, it is difficult to assign the fire retardant property in some cases; and when the dose is more than 15 wt %, it is likely that the heat resistive property and the foaming property are lowered. Additionally, by using, in addition to the fire retardant agent described above, a small amount of fire retardant assistant agent, it is possible to improve the fire retardant property. As the fire retardant assistant agent employed for such purpose, a radical generating agent such as peroxide is used in general; however, as a favorable fire retardant assistant agent to develop the fire retardant property in the present embodying mode, a fire retardant assistant agent having a half-life temperature per hour of 150° C. or more and 250° C. or less is favorable. - The
resin sheet 101 configures the outer side of the resin moldedproduct 100 and, in theresin sheet 101, like in thecore member 102, styrene-based resin is contained at least 30 wt % or more. In the resin moldedproduct 100 of the present embodying mode, thecore member 102 and theresin sheet 101 contain styrene-based resin at least 30 wt % or more; hence, it is possible to enhance rigidity in a high-temperature environment (for example, 90° C. or more). - Moreover, the
resin sheet 101 of the present embodying mode includes fibrous filler. Since theresin sheet 101 of the present embodying mode includes fibrous filler, it is possible to enhance rigidity. As the fibrous filler, there can be considered Warastonite, potassium titanate whiskers, glass fiber, carbon fiber, and the like; particularly, glass fiber and carbon fiber are favorable. - For the fibrous filler of the present embodying mode, the value (aspect ratio) obtained by dividing the length of fiber by the diameter of fiber favorably ranges from 250 to 2000; in particular, from 500 to 1200 from the viewpoint of appropriate molding and improvement of rigidity. Incidentally, when fibrous filler of glass is employed, it is favorable that the length of fiber ranges from 8 mm to 20 mm and the diameter of fiber is equal to or less than 30 μm. This is because when the fiber length is less than 8 mm, the improvement due to filler mixing is small for the heat resistive property and for the rigidity at a high temperature; and when the fiber length is more than 20 mm, the filler is not easily mixed with the substrate resin. In this situation, particularly, it is favorable that fibrous filler with the fiber length from 10 mm to 20 mm and the fiber diameter from about 14 μm to about 17 μm is contained in a range from 20 wt % to 40 wt % (more favorably, about 30 wt %) in the
resin sheet 101. - Incidentally, for the styrene-based resins used for the
core member 102 and theresin sheet 101, the melting point of the styrene-based resin used for theresin sheet 101 is favorably higher than that of the styrene-based resin used for thecore member 102. This makes it possible that while melting the surfaces of thecore member 102 by the heat of theresin sheet 101 in the melted state, thecore member 102 and theresin sheet 101 are welded onto each other. - Next, referring to
FIGS. 2 to 9 , description will be given of a molding method example of the resin moldedproduct 100 of the present embodying mode.FIG. 2 shows a configuration example of amolding device 60 to mold the resin moldedproduct 100 of the present embodying mode, andFIGS. 2 to 9 show a molding process example to mold the resin moldedproduct 100 of the present embodying mode. - First, referring to
FIG. 2 , description will be given of a configuration example of themolding device 60 to mold the resin moldedproduct 100 of the present embodying mode. - The
molding device 60 of the present embodying mode includes an extrudingmachine 12, a clampingmachine 14, and a core member inserting machine (not shown). - In the
molding device 60 of the present embodying mode, two resin sheets P in a melted state are extruded from the extrudingmachine 12 to arrange the two resin sheets P between the split molds 32 configuring the clampingmachine 14. Next, one of the resin sheets P is formed in a contour along a cavity 116 of the split mold 32, and onto the one resin sheet P thus formed, acore member 102 beforehand molded is welded by the core member inserting machine (not shown). Also, the other one resin sheet P is formed in a contour along a cavity 116 of the split mold 32, and the split mold 32 is clamped to weld thecore member 102 onto the other one resin sheet P, and the resin sheets P are welded onto each other, to mold a resin moldedproduct 100 in which thecore member 102 and the other one resin sheet P are configured in one block. - The extruding
machine 12 includes a cylinder 18 equipped with a hopper 16, a screw (not shown) disposed in the cylinder 18, an electric motor 20 coupled with the screw, an accumulator 22 communicatively connected to the cylinder 18, a plunger 24 communicatively connected to the accumulator 22, and a T die 28. - In the extruding
machine 12 of the present embodying mode, resin pellets supplied from the hopper 16 are melted and are kneaded through the rotations of the screw by the electric motor 20 in the cylinder 18 into resin (molten resin) in the melted state. Next, the molten resin is transported to the accumulator 22 such that a fixed quantity thereof is accumulated, and then by the driving of the plunger 24, the molten resin is fed to the T die 28, to extrude, from an extruding slit (not shown) of the T die 28, a resin sheet P in the contour of a continuous sheet. - The resin sheet P extruded from the extruding slit of the T die 28 is clamped by a pair of rollers 30 disposed with a gap therebetween and is delivered downward to be suspended between the split molds 32. As a result, the resin sheet P is arranged between the split molds 32 in a state in which the sheet P has uniform thickness in the perpendicular direction (extruding direction).
- Extruding performance of the extruding
machine 12 is appropriately selected in consideration of the size of the resin molded product to be molded and the prevention of occurrence of the draw-down or the neck-in of the resin sheet P. Specifically, from the viewpoint of practice, the extruding quantity of one shot in the intermittent extrusion favorably ranges from 1 kg to 10 kg, and the extruding speed of the resin sheet P from the extruding slit is several hundreds of kg/h or more; or, more preferably, 700 kg/h or more. Further, from the viewpoint of the prevention of occurrence of the draw-down or the neck-in of the resin sheet P, the extrusion of the resin sheet P is favorably as short as possible; although depending on the kind of resin, the MFR value, and the melt tension value, it is favorable in general that the extrusion is completed within 40 seconds; or, more preferably, in a range from 10 seconds to 20 seconds. - Hence, the extruding quantity per unitary area (1 cm2) and unitary time (h) of the thermoplastic resin from the extruding slit is 50 kg/h cm2 or more; or, more preferably, 150 kg/h cm2 or more. For example, in a situation wherein from an extruding slit of the T die 28 in which the slit gap is 0.5 mm and the length in the width direction of the slit is 1000 mm, a resin sheet P having a thickness of 1.0 mm, a width of 1000 mm, and a length in extruding direction of 2000 mm is extruded in 15 seconds by use of thermoplastic resin having a density of 0.9 g/cm3, it is regarded that the thermoplastic resin having a weight of 1.8 kg is extruded per one shot in 15 seconds, to obtain through calculation that the extruding speed is 432 kg/h and the extruding speed per unitary area is about 86 kg/h cm2.
- Incidentally, the extruding slit disposed in the T die 28 is arranged downward in a perpendicular direction, and the resin sheet P extruded from the extruding slit is perpendicularly transported downward in a state in which it suspends directly from the extruding slit. In the extruding slit, by changing the slit gap, it is possible to change thickness of the resin sheet P.
- However, the resin sheet P extruded from the T die 28 is favorably adjusted such that in a state in which it is suspended between the split molds 32, that is, when it is clamped, thickness thereof in the extruding direction is uniform. In this situation, it is also possible to change the slit gap such that the slit gap is gradually enlarged beginning at the extrusion start point to be maximum at the extrusion end point. As a result, the thickness of the resin sheet P extruded from the T die 28 is gradually enlarged beginning at the extrusion start point; however, the resin sheet P extruded in the melted state is extended by its own weight to be gradually thinner from the lower end to the upper end of the sheet; hence, the thick portion extruded by enlarging the slit gap cancels the thin portion due to extension by the draw-down phenomenon, to thereby conduct the adjustment for the uniform thickness from the upper end to the lower end of the sheet.
- In the
molding device 60 of the present embodying mode, a resin sheet P pinched between a pair of rollers 30 is downward fed by the rotations of the pair of rollers 30, to extend and to thin down the resin sheet P; by adjusting the relationship between the extruding speed of the resin sheet P extruded from the T die 28 and the feeding speed of the resin sheet P fed by the pair of rollers 30, it is possible to prevent occurrence of the draw-down or the neck-in of the resin sheet P. Hence, it is possible to mitigate restrictions on the kind of resin to be adopted, in particular, on the MFR value, the MT value, and the extruding quantity per unitary time. - The pair of rollers 30 are arranged to have axial symmetry with respect to the resin sheet P extruded in a state in which it downward suspends from the extruding slit. The diameter of the rollers 30 and the length in the axial direction of the rollers 30 are appropriately set according to the extruding speed of the resin sheet P to be molded, the length in the extruding direction of the resin sheet P, the width thereof, the kind of resin, and the like. Further, in respective outer surfaces of the pair of rollers 30, there are disposed wrinkles in the contour of depressions and projections. The wrinkles in the contour of depressions and projections are favorably disposed in the outer surfaces of the rollers 30, to be uniformly distributed throughout the surfaces to be brought into contact with the resin sheet P, and the depth and the density thereof are only to be appropriately determined so that the resin sheet P is smoothly fed downward by the pair of rollers 30, in consideration of prevention of occurrence of slippage between the respective outer surfaces of the pair of rollers 30 and the corresponding surfaces of the resin sheet P. Incidentally, although it is possible to form the wrinkles in the contour of depressions and projections, for example, by the sand-blast process, it is favorable to form them by a blast machine by adopting a coarse level of about coarse 60.
- Incidentally, the wrinkles in the contour of depressions and projections disposed respectively in the pair of rollers 30 are not disposed to transcribe the wrinkle pattern onto the surfaces of the resin sheet P, but, intrinsically, are disposed to prevent occurrence of slippage between the respective outer surfaces of the pair of rollers 30 and the corresponding surfaces of the resin sheet P.
- When transcribing the wrinkle pattern onto the surfaces of the resin sheet P, it is an ordinary practice that one of the pair of rollers is a wrinkle roll and the other one thereof is a lubber roll; however, in the pair of rollers 30 of the present embodying mode, by disposing wrinkles in the outer surfaces respectively of the pair of rollers 30, the pair of rollers 30 respectively and securely hold the corresponding surfaces of the resin sheet P; on the other hand, by restricting the pushing force onto the resin sheet P due to the pair of rollers 30, it is possible to prevent, immediately after feeding the resin sheet P by the pair of rollers 30, the transcription of the wrinkle pattern onto the surfaces of the resin sheet P.
- The pair of rollers 30 are made of metal, for example, aluminum; each of the paired rollers 30 is equipped with surface temperature adjusting means to adjust, depending on the temperature of the resin sheet P in the melted state, the surface temperature of the roller 30; in the configuration thereof, by flowing coolant through the inside of the roller 30 and by circulating the coolant, heat exchange is performed such that the surface of the roller 30 is not excessively heated by the resin sheet P in the melted state clamped by the pair of rollers 30.
- The outer surfaces of the pair of rollers 30 are heated through heat conduction when the pair of rollers 30 are brought into contact with the resin sheet P in the melted state; by cooling the outer surfaces of the pair of rollers 30 from the inside, an event is prevented in which the resin sheet P in the melted state clamped by the pair of rollers 30 adheres onto the outer surface of the roller 30 and is wound around the roller 30 by the rotations of the roller 30, and the resin sheet P is not fed downward. In this situation, from the viewpoint of prevention of the winding, it is favorable to lower the surface temperature of the rollers 30; however, from the viewpoint of the molding of the resin sheet P later, when the surface temperature of the rollers 30 is too low, the resin sheet P in the melted state is contrarily cooled too much by the surfaces of the rollers 30, to cause hindrances in the molding. Hence, it is required to set the surface temperatures respectively of the pair of rollers 30 to be lower, in a predetermined range of temperature, than the temperature of the resin sheet P in the melted state extruded toward the pair of rollers 30. The predetermined range of temperature is determined according to the kind of the resin sheet P in the melted state. In this situation, to conduct temperature adjustment of the surface temperatures of the pair of rollers 30, when the insides respectively of the pair of rollers 30 are water-cooled, it is desirable to set the temperature of the coolant according to the kind of the resin sheet P; and the temperature of the coolant is to be kept constant during the molding of the resin sheet P.
- The clamping
machine 14 of the present embodying mode includes the split molds 32 and a mold driving machine (not shown) to move the split molds 32 in a direction substantially vertical to the supply direction of the resin sheets P between an open position and a closed position. - The split molds 32 are arranged in a state in which the cavities 116 oppose each other, and the respective cavities 116 face substantially the perpendicular direction. In the surfaces of the cavities 116, depressions and projections are disposed according to the outer contour and the surface contour of the molded product to be molded based on the resin sheets P in the melted state. Also, in the peripheries of the cavities 116 of the split molds 32, pinch-off sections 118 are formed. The pinch-off sections 118 are formed in a circular contour in peripheries of the cavities 116 and project toward the opposing split molds 32. Hence, it is possible that when the split molds 32 are clamped, the tip end sections of the respective pinch-off sections 118 make contact with each other, to form the parting lines in the circumferential edges of the molded product.
- Further, between the split molds 32, flask members 33 are arranged. The flask members 33 include openings 130; by use of flask member driving machines, not shown, the flask members 33 are moved toward the resin sheets P, and the flask members 33 are brought into contact with the resin sheets P, to hold the resin sheets P. Also, in the state in which the resin sheets P are kept held, the flask members 33 moves in the reverse direction, to bring the resin sheets P into contact with the tip ends of the pinch-off sections 118 of the split molds 32; and a sealed space is formed by the sheets of resin P, the pinch-off sections 118, and the cavities 116.
- The split molds 32 are driven by the mold driving machine (not shown) so that the resin sheets P in the melted state are arranged between the split molds 32 at the open position. Further, at the closed position, the pinch-off sections 118 of the split molds 32 make contact with each other, to form a sealed space in the split molds 32. Incidentally, for the movement of each split mold 32 from the open position to the closed position, the closed position is the position of the central line of the resin sheets P in the melted state; each split mold 32 is driven by the mold driving machine and moves toward the position.
- The resin sheets P includes styrene-based resin as the main component. For the resin sheets P of the present embodying mode, from the viewpoint of prevention of occurrence of dispersion in thickness due to the draw-down and the neck-in, it is favorable to employ styrene-based resin having high melting tension; on the other hand, to improve transcribing performance and tracing performance with respect to the split molds 32, it is favorable to employ styrene-based resin having high fluidity.
- As the styrene-based resin employed for the resin sheets P, a styrene-based resin which has MFR (measured at a test temperature of 230° C. and with a test load of 2.16 kg according to JIS K-7210) equal to or less than 3.5 g/10 min at 230° C. is applicable. When MFR is more than 3.5 g/10 min, the draw-down becomes excessive and it is difficult to mold a thin molded product.
- Further, the resin sheets P of the present embodying mode include fibrous filler in order to possess the heat resistive property and rigidity. As a result, even after the resin sheets P are extruded from the T dies 28, it is possible to suppress the lowering of temperature of the resin sheets P. Also, even when the resin sheets P are extruded at a high temperature (for example, 210° C. or more) from the T dies 28, it is possible to suppress influence of the draw-down. Ordinarily, when the resin sheets P are extruded at a high temperature (for example, 210° C. or more), the draw-down is conspicuous and the molding is difficult; however, when the fibrous filler is contained in the resin sheets P, it is possible to suppress the influence of the draw-down. Incidentally, in the present embodying mode, the surfaces of the
core member 102 are melted by the heat of the resin sheets P; hence, it is favorable that when the resin sheets P are extruded from the T dies 28, the temperature of the resin sheets P is 210° C. or more, and more preferably, 250° C. or more. Hence, to suppress the influence of the draw-down, the resin sheets P of the present embodying mode include fibrous filler. - Further, to the resin sheets P of the present embodying mode, from the viewpoint of the reduction in thickness and the improvement in rigidity, it is also possible to further add powder inorganic filler such as silica, mica, talc, calcium carbonate, and the like. However, when the quantity of added inorganic filler is increased, roughness appears on the surface of the molded product, and pinholes easily take place. Hence, to suppress the roughness on the surface of the molded product and to prevent pinholes from easily taking place, it is favorable to add the inorganic filler at less than 30 wt %.
- Further, to the resin sheets P, it is also possible to add plasticizers, stabilizers, coloring agents, antistatic agents, fire retardants, foaming agents, and the like.
- Next, referring to
FIGS. 2 to 9 , description will be given of a molding process example of the resin moldedproduct 100 of the present embodying mode. - First, as shown in
FIG. 2 , the resin sheets P are extruded from the T dies 28, and the extruded resin sheets P are fed through a pair of rollers 30 to adjust thickness of the resin sheets P and then are suspended between the pair of split molds 32. - In the
molding device 60 of the present embodying mode, the relative speed difference between the extruding speed of the resin sheets P and the feed speed at which the resin sheets P are fed downward by the pair of rollers 30 is adjusted by the rotation speed of the pair of rollers 30 such that when the resin sheets P pass between the pair of rollers 30, they are drawn downward by the pair of rollers 30 and are extended to be reduced in thickness; as a result, occurrence of the draw-down or the neck-in is prevented. - In this situation, in each of the pair of rollers 30, wrinkles are dispose in the contour of depressions and projections on the surfaces of the rollers 30 and a gear mechanism is disposed at one end of the rollers 30, to respectively transmit rotation driving force of a rotation driving roller 30BA to a rotation driven roller 30BB and rotation driving force of a rotation driving roller 30AA to a rotation driven roller 30AB such that no rotation speed difference appears between the rotation driving roller 30A and the rotation driven roller 30B, which prevents occurrence of wrinkles or shear marks on the surfaces of the resin sheets P.
- Further, in each of the pair of rollers 30, coolant is circulated through the roller 30 to cool the roller 30, to set the temperature of the outer surface of each roller 30 to be lower in a predetermined temperature range than the temperature of the resin sheet P in a melted state, to prevent the event in which when the resin sheet P in a melted state is clamped by the pair of rollers 30, the resin sheet P in a melted state adheres onto the surface the roller 30 and is wound around the roller 30 by the rotations of the roller 30; on the other hand, the resin sheet P is kept in a melted state suitable for the molding.
- Incidentally, in association with the adjustment of the number of rotations of the pair of rollers 30, the extruding slit gap adjustment may also be carried out.
- When the sheets of resin P are arranged between the split molds 32, flask members 128 are moved by a flask member driving machine (not shown) toward the corresponding sheets of resin P, and as shown in
FIG. 3 , the flask members 128 are brought into contact with the sheets of resin P, to hold the sheets of resin P by the flask members 128. - Next, the flask members 128 are moved toward the split molds 32, and as shown in
FIG. 4 , the sheets of resin P are brought into contact with the pinch-off sections 118 of the split molds 32, to form a sealed space 117 by the sheets of resin P, the pinch-off sections 118, and the cavities 116. Further, thecore member 102 held by adsorbingplates 119 of a manipulator (not shown) is inserted between the split molds 32 as shown inFIG. 4 . - Next, the air in the sealed space 117 is sucked via the split molds 32 to push one of the sheets of resin P onto the cavity 116, to form, as shown in
FIG. 5 , the one sheet of resin P in a contour according to the cavity 116. - Also, the manipulator is moved toward the split mold 32 on the right side, to push, as shown in
FIG. 6 , thecore member 102 onto the one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the right side, to weld thecore member 102 onto the one resin sheet P. - The resin sheet P of the present embodying mode includes styrene-based resin and fibrous filler; hence, even after the resin sheet P is formed in the contour of the cavity 116, it is possible to retain the state of temperature to melt the surfaces of the
core member 102. Hence, when thecore member 102 is pushed onto the resin sheet P, the surfaces of thecore member 102 can be melted by the heat of the resin sheet P. As a result, in the present embodying mode, while melting the surfaces of thecore member 102 by the heat of the resin sheet P, thecore member 102 can be welded onto the resin sheet P. - Next, the adsorbing
plates 119 are removed from thecore member 102 and the manipulator is pulled to be removed from the space between the two split molds 32, and the other one resin sheet P is pushed onto the cavity 116, to form, as shown inFIG. 7 , the other one resin sheet P in the contour along the cavity 116. - Next, the two split molds 32 are clamped by the mold driving machine, and as shown in
FIG. 8 , thecore member 102 is pushed onto the other one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the left side, to weld thecore member 102 onto the other one resin sheet P. Moreover, peripheries respectively of the two resin sheets P are welded onto each other to form parting lines PL. - Incidentally, the surfaces of the
core member 102 of the present embodying mode are melted by the heat of the resin sheets P; hence, when the split molds 32 are clamped to mold a resin moldedproduct 100 in which thecore member 102 and the resin sheets P are formed in one block, it is favorable to compress thecore member 102 and the resin sheets P by the split molds 32. As a result, the welding strength between thecore member 102 and the resin sheets P is further enhanced. - For example, as shown in
FIG. 10 , when two resin sheets S configuring the resin moldedproduct 100 have thickness A as A=1 mm and thecore member 102 has thickness B as B=15 mm, it is favorable that the cavities 116 of the split molds 32 have depth C as C=8 mm and thecore member 102 and the resin sheets S are compressed by about 1 mm. In this situation, the sealed space formed when the split molds 32 are clamped has width 2C as 2C=16 mm, and the total thickness of the two resin sheets P and thecore member 102 is 2A+B=17 mm; hence, the resin moldedproduct 100 clamped by the split molds 32 is compressed by 0.5 mm by each of the split molds 32. As a result, the fibrous filler contained in the resin sheets P is easily pushed into thecore member 102; hence, it is possible that the welding between the resin sheets P and thecore member 102 is stronger and it is possible to mold the resin moldedproduct 100 with high rigidity. Incidentally, when compressing by the split molds 32, it is favorable that the compression is performed in a range from about 0.5 mm to about 1.0 mm by each of the split molds 32. - Through the processes described above, a resin molded product in which the
core member 102 and the resin sheets P are laminated is completely produced. - Next, as shown in
FIG. 9 , the two split molds 32 are unclamped and the cavities 116 are removed from the completed resin moldedproduct 100, and then burrs formed in peripheries of the parting lines PL are removed. This completes the molding of the resin moldedproduct 100. - As above, the
resin sheets 101 configuring the resin moldedproduct 100 of the present embodying mode contain fibrous filler. And when molding the resin moldedproduct 100, while melting, as shown inFIGS. 6 and 8 , the surfaces of thecore member 102 by the heat of the resin sheets P in the melted state, thecore member 102 and the resin sheets P are welded onto each other. And as shown inFIG. 8 , thecore member 102 and the resin sheets P are clamped by the split molds 32, to mold the resin moldedproduct 100. - In the molding of the resin molded
product 100 of the present embodying mode, since the resin sheets P in the melted state contain fibrous filler, it is possible to suppress draw-down. This makes it possible that the molding is conducted by extruding the resin sheets P at high temperature and the surfaces of thecore member 102 are more securely melted, to weld thecore member 102 and the resin sheets P onto each other. As a result, the welding strength between thecore member 102 and the resin sheets P can be improved. Also, by making the resin sheets P contain fibrous filler, it is possible to enhance rigidity of the resin moldedproduct 100. - In addition, since the
core member 102 and the resin sheets P configuring the resin moldedproduct 100 of the present embodying mode include styrene-based resin as the primary component, it is possible to further enhance the welding strength between thecore member 102 and the resin sheets P and the rigidity of the resin moldedproduct 100. - Incidentally, the embodying modes described above are favorable embodying modes of the present invention, and the scope of the present invention is not limited only to these embodying modes, but various changes may be made therein without departing from the gist of the present invention.
- For example, in the molding method of the embodying mode; as shown in
FIG. 4 , the sheets of resin P are brought into contact with the pinch-off sections 118 of the split molds 32, to form a sealed space 117 by the sheets of resin P, the pinch-off sections 118, and the cavities 116, and then thecore member 102 is inserted between the split molds 32. However, it is also possible that before the sheets of resin P are extruded from the T dies 28 to a space between the split molds 32, thecore member 102 is beforehand inserted between the split molds 32. This makes it possible to warm up the surfaces of thecore member 102 by the heat of the sheets of resin P extruded from the T dies 28. - Further, in the molding method of the embodying mode, after two resin sheets P are arranged between the split molds 32, the
core member 102 is sequentially welded onto the two resin sheets P. However, it is also possible that while separately arranging two resin sheets P in the split molds 32, thecore member 102 is sequentially welded onto the two resin sheets P. Specifically, first, one of the resin sheets P is arranged in the split molds 32, to form the resin sheet P in a contour along the cavity of the split mold 32, and then thecore member 102 is welded onto the resin sheet P. Further, the other one of the resin sheets P is arranged in the split molds 32, to form the resin sheet P in a contour along the cavity of the split mold 32, and then thecore member 102 is welded onto the resin sheet P. As a result, it is possible to shorten the time lapsed by when thecore member 102 is welded onto the resin sheets P extruded from the T dies 28; hence, the surfaces of thecore member 102 can be easily melted by the heat of the resin sheets P. - Additionally, in the molding method described above, without conducting any warming process for the
core member 102, thecore member 102 is welded onto the resin sheets P while melting the surfaces of thecore member 102 by the heat of the resin sheets P. However, in the molding method described above, it is also possible to warm up, before thecore member 102 is inserted between the split molds 32, the surfaces of thecore member 102 in advance by warming means such as an infrared heater. - Further, it is also possible, as shown in
FIG. 6 , that the surfaces of thecore member 102 are warmed up in advance by warming means before thecore member 102 is pushed onto the one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the right side and thecore member 102 is welded onto the one resin sheet P. - Moreover, it is also possible, as shown in
FIG. 8 , that the surfaces of thecore member 102 are warmed up by warming means before thecore member 102 is pushed onto the other one resin sheet P adsorbed onto the cavity 116 of the split mold 32 on the left side and thecore member 102 is welded onto the other one resin sheet P. - That is, it is possible, before the
core member 102 and the resin sheets P are welded onto each other, to warm up the surfaces of thecore member 102 by warming means to beforehand melt the surfaces of thecore member 102. - Incidentally, timing to warm up the surfaces of the
core member 102 by warming means is not particularly restricted; only if the timing is before the resin sheets P and thecore member 102 are welded onto each other, it is possible to warm up the surfaces of thecore member 102 at any timing. - Further, in the embodying mode described above, it is also possible that a decorative sheet is arranged between the split molds 32 such that the decorative sheet is welded onto the resin sheets P by clamping the split molds 32. Moreover, it is also possible that a decorative sheet is supplied together with the resin sheets P to a space between a pair of rollers 30 such that by adjusting the rotation speed of the pair of rollers 30, thickness of the resin sheets P is adjusted and the decorative sheet is pushed to be tightly fixed onto the resin sheets P.
- In addition, the resin molded
product 100 of the embodying mode described above is molded by interposing thecore member 102 between two resin sheets P. However, it is only required that the resin moldedproduct 100 of the embodying mode is molded by interposing thecore member 102 between at least two resin sheets P; for example, it is also possible to mold the product by interposing thecore member 102 by four resin sheets P. The layer configuration of the resin moldedproduct 100 in this situation is as resin sheet/resin sheet/core member/resin sheet/resin sheet. -
- 100 Resin molded product
- 102 Core member
- 101, P Resin sheet
- 60 Molding machine
- 12 Extruding machine
- 14 Clamping machine
- 16 Hopper
- 18 Cylinder
- 20 Electric motor
- 22 Accumulator
- 24 Plunger
- 28 T die
- 30 Roller
- 32 Split mold
- 128 Flask member
- 130 Opening
- 116 Cavity
- 118 Pinch-off section
Claims (6)
1. A molding method of a resin molded product in which a core member including a foaming element is interposed between at least two resin sheets in a melted state into a laminated product, characterized in that:
the resin sheets comprise fibrous filler, the method comprising:
a welding step in which while melting surfaces of the core member by heat of the resin sheets, the core member and the resin sheets are welded onto each other; and
a molding step in which the core member and the resin sheets are clamped by a metallic mold, to mold the resin molded product.
2. A molding method of a resin molded product in accordance with claim 1 , characterized in that the core member and the resin sheets comprise styrene-based resin.
3. A molding method of a resin molded product in accordance with claim 1 , characterized in that the core member and the resin sheets are compressed by clamping the metallic mold.
4. A resin molded product in which a core member including a foaming element is interposed between at least two resin sheets into a laminated product, characterized in that:
the resin sheets comprise fibrous filler; and
the resin molded product comprises a laminated structure in which the core member with melted surfaces and the resin sheets in a melted state are welded onto each other into one block.
5. A resin molded product in accordance with claim 4 ,
characterized in that the core member and the resin sheets comprise styrene-based resin.
6. A molding method of a resin molded product in accordance with claim 2 , characterized in that the core member and the resin sheets are compressed by clamping the metallic mold.
Applications Claiming Priority (3)
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JP2011-156086 | 2011-07-14 | ||
JP2011156086A JP6173657B2 (en) | 2011-07-14 | 2011-07-14 | Molding method of resin molded products |
PCT/JP2012/066489 WO2013008633A1 (en) | 2011-07-14 | 2012-06-28 | Method for forming resin molded product, and resin molded product |
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PCT/JP2012/066489 A-371-Of-International WO2013008633A1 (en) | 2011-07-14 | 2012-06-28 | Method for forming resin molded product, and resin molded product |
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US15/221,667 Division US10668652B2 (en) | 2011-07-14 | 2016-07-28 | Molding method of resin molded product and resin molded product |
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US20150174799A1 true US20150174799A1 (en) | 2015-06-25 |
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US15/221,667 Active 2033-02-07 US10668652B2 (en) | 2011-07-14 | 2016-07-28 | Molding method of resin molded product and resin molded product |
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US15/221,667 Active 2033-02-07 US10668652B2 (en) | 2011-07-14 | 2016-07-28 | Molding method of resin molded product and resin molded product |
Country Status (6)
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US (2) | US20150174799A1 (en) |
EP (1) | EP2732953B1 (en) |
JP (1) | JP6173657B2 (en) |
KR (1) | KR101578593B1 (en) |
CN (1) | CN103635302B (en) |
WO (1) | WO2013008633A1 (en) |
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US10611065B2 (en) * | 2013-03-29 | 2020-04-07 | Toyota Boshoku Kabushiki Kaisha | Manufacturing method for conveyance seat |
US20160243751A1 (en) * | 2013-11-01 | 2016-08-25 | Toyota Jidosha Kabushiki Kaisha | Method of manufacturing resin molded product and manufacturing device thereof |
US20180147754A1 (en) * | 2016-11-28 | 2018-05-31 | Tzu-Chi LIN | Uniform temperature roll-extrusion forming system and uniform temperature roller structure thereof |
US11110500B2 (en) | 2016-11-28 | 2021-09-07 | Tzu-Chi LIN | Uniform temperature roller system having uniform heat exchange by supercritical fluid |
US11529754B2 (en) | 2017-03-31 | 2022-12-20 | Jsp Corporation | Skin material-coated foamed particle molded body |
WO2023006536A1 (en) * | 2021-07-30 | 2023-02-02 | Safran Seats | Method for manufacturing an aircraft seat part |
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Also Published As
Publication number | Publication date |
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JP6173657B2 (en) | 2017-08-02 |
JP2013022734A (en) | 2013-02-04 |
EP2732953A4 (en) | 2015-06-17 |
KR101578593B1 (en) | 2015-12-17 |
US10668652B2 (en) | 2020-06-02 |
CN103635302A (en) | 2014-03-12 |
EP2732953A1 (en) | 2014-05-21 |
US20160332343A1 (en) | 2016-11-17 |
KR20140015569A (en) | 2014-02-06 |
EP2732953B1 (en) | 2017-04-05 |
WO2013008633A1 (en) | 2013-01-17 |
CN103635302B (en) | 2016-08-17 |
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