US20150166748A1 - Mould for moulding a wind turbine blade - Google Patents
Mould for moulding a wind turbine blade Download PDFInfo
- Publication number
- US20150166748A1 US20150166748A1 US14/626,125 US201514626125A US2015166748A1 US 20150166748 A1 US20150166748 A1 US 20150166748A1 US 201514626125 A US201514626125 A US 201514626125A US 2015166748 A1 US2015166748 A1 US 2015166748A1
- Authority
- US
- United States
- Prior art keywords
- mould
- film
- wind turbine
- turbine blade
- inside surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000465 moulding Methods 0.000 title claims abstract description 22
- 238000000605 extraction Methods 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 11
- -1 polyethylene Polymers 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims 1
- 239000010408 film Substances 0.000 description 88
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 10
- 239000000835 fiber Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000011152 fibreglass Substances 0.000 description 6
- 239000003365 glass fiber Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 230000037303 wrinkles Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
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- 238000010438 heat treatment Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/68—Release sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C39/10—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles incorporating preformed parts or layers, e.g. casting around inserts or for coating articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/22—Component parts, details or accessories; Auxiliary operations
- B29C39/42—Casting under special conditions, e.g. vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
- B29C70/342—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using isostatic pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/10—Moulds or cores; Details thereof or accessories therefor with incorporated venting means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/08—Blades for rotors, stators, fans, turbines or the like, e.g. screw propellers
- B29L2031/082—Blades, e.g. for helicopters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/08—Blades for rotors, stators, fans, turbines or the like, e.g. screw propellers
- B29L2031/082—Blades, e.g. for helicopters
- B29L2031/085—Wind turbine blades
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/70—Wind energy
- Y02E10/72—Wind turbines with rotation axis in wind direction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/2457—Parallel ribs and/or grooves
Definitions
- the present invention relates to a mould for moulding a wind turbine blade.
- Embodiments of the present invention also provide a film for use in a wind turbine blade moulding process, and the use of such a film in the moulding of a wind turbine blade.
- Wind turbine rotor blades may be manufactured using a technique such as the closed-mould casting technique in which the entire blade can be moulded.
- Glass fibre matting can be used to build up component layers in a suitably shaped mould, and the layers of matting are bonded with a resin and cured in the mould to give a fibre-reinforced polymer or glass-reinforced plastic, generally referred to simply as ‘fibreglass’.
- fibreglass a fibre-reinforced polymer or glass-reinforced plastic
- the mould is usually coated with a release agent such as a suitable wax so that the resin does not bond with the mould.
- the release agent is applied to the mould before building up the fibreglass layers.
- Known release agents are polyvinyl alcohol, silicone wax, slip wax, etc.
- the release agent must be applied in a uniform layer, and this layer must be absolutely smooth if the outer surface of the cured blade is also to be smooth.
- the types of release agent generally used contain volatile solvents, which pose a health risk to anyone exposed to them.
- a method of moulding a wind turbine blade in a mould comprises the steps of applying a film to an inside surface of the mould, assembling component layers for the wind turbine blade on the film, performing curing steps to harden the component layers, and subsequently detaching the cured wind turbine blade from the mould.
- An obvious advantage of the method is that the film obviates the need for a release agent, so that it is no longer necessary to coat the inside surface (or ‘interior surface’) of the mould with a release agent, and it is no longer necessary to remove remnants of a release agent from the cured wind turbine blade. In this way, considerable savings can be made in the manufacturing process, without having to use an expensively prepared mould. Instead, a single sheet of film can simply be laid out to line the mould. After curing, the film can easily be detached from the wind turbine blade, as will be explained below.
- a film suitable for use in a wind turbine blade moulding process comprises an outside surface for lining the interior surface of a mould, and an inside surface for receiving a component layers of the wind turbine blade prior to curing, and wherein the inside and outside surfaces of the film are realised to allow a complete detachment of the cured wind turbine blade from the mould after curing.
- the mould for moulding a wind turbine blade comprises an inside or interior surface suitable for receiving such a film, and a vacuum extraction outlet for applying a vacuum to extract air from between the film and the inside surface of the mould.
- such a film may be used in the moulding of a wind turbine blade using the inventive moulding method.
- the component to be moulded comprises layers of a suitable material such as glass fibre or carbon fibre, which layers are bonded with a fibre reinforcement such as resin, glue, thermosetting plastic, etc.
- Bonding can be carried out in a number of ways.
- dry fibreglass matting can be coated in resin during a manual laying step.
- previously impregnated fibre materials known as ‘prepreg’
- prepreg previously impregnated fibre materials
- the method can be used for any moulding technique in which layers are laid up on a mould prior to curing, and subsequently removed from the mould.
- an essentially hollow wind turbine blade can be made by moulding two half-shells which are then joined at leading and trailing edges by gluing these together.
- the structure can be given additional support by one or more beams bonded to the inside faces of the half-shells.
- it can be difficult to ensure a satisfactory quality of the glue joints, due to the different material proerties—such as elastic modulus—of the half-shells and the glue used to bond them along their entire lengths.
- these glue joints present a potential weakness and may eventually crack or open as a result of the extreme forces that can act on the blade.
- the mould comprises a closed mould for manufacturing a wind turbine blade in one piece.
- the fibreglass matting can be arranged around a core and this structure can then be enclosed in the mould.
- a fibre reinforcement such as resin or glue can be previously applied or introduced into the mould after it has been closed. After curing, the mould is opened and the wind turbine blade can be removed.
- this approach it is possible to manufacture a large, hollow component such as a wind turbine blade in one piece and without any potentially critical glue joints.
- the film used to line the mould can comprise any suitable material that does not adhere to the cured component layers, whether these comprise resin-filled fibre layers, thermosetting plastic layers, prepreg layers, etc.
- the film comprises polyethylene, polypropylene, or any other suitable plastic, such as the type of film used to manufacture ‘cling-film’ or ‘cling-wrap’.
- One or both surfaces of the film can have non-stick properties so that the film can easily be removed from the cured wind turbine blade and/or the mould.
- the term ‘non-stick’ in the context of a film surface is to be understood that the surface has properties that prevent other materials from sticking to it.
- the film can comprise a polyvinyl chloride component to reduce the ability of other materials to stick to it.
- the film used to line the mould can be manufactured easily in the required width, and can be supplied on a roll for convenient dispensing.
- the thickness of the film may determine the smoothness of the film layer laid out on the mould.
- the film should be flexible enough so that it can line the mould without any wrinkles or folds forming.
- the film should be strong enough to allow it to be pulled off the cured component. Therefore, in a preferred embodiment of the invention, the thickness of the film is at least 20 ⁇ m and at most 200 ⁇ m, more preferably at most 100 ⁇ m.
- the method comprises the step of applying a vacuum between the film and the interior surface of the mould.
- the vacuum can be applied by drawing air out through a nozzle positioned between the film and the inside surface of the mould. Extraction of air from between the film and the mould can ensure that the film lines the mould smoothly.
- the vacuum need only be applied until the film is sufficiently ‘pressed’ into the mould. Thereafter, the vacuum extraction can be stopped and the component layers can be built up in the mould.
- the vacuum can be applied also during laying up the layers, for example to prevent slippage of the film.
- the material and structure of the film used to line the mould can be chosen according to process requirements. For example, as mentioned above, it is desirable to obtain as flat a surface as possible when extracting air by vacuum from between the film and the mould. However, during vacuum extraction, it may be that the film is sucked onto the inside surface of the mould such that small air pockets are trapped. Therefore, in a particularly preferred embodiment of the invention, the film comprises a relief structure on a surface of the film applied to the inside surface of the mould. This relief structure can comprise depressions such as dimples, or raised areas, and can serve to improve the adherence of the film to the inside surface the mould during the step of laying up the component layers prior to curing.
- the relief structure can comprise a plurality of channels or grooves in the film, so that a vacuum, applied between the film and the inside surface of the mould, can optimally draw out any air without allowing any significant air pockets to remain.
- Such channels or grooves can easily be formed during manufacture of the film, for example in an extrusion process, and are preferably arranged such that they lie in essentially the same direction as the direction taken by the extracted air, i.e. in the direction of a vacuum nozzle.
- the film comprises parallel grooves or channels along its length, and the film is laid lengthwise into the mould, so that vacuum nozzles positioned at each end of the mould can optimally extract any air from between the film and the mould.
- the mould itself can be realised to assist the vacuum extraction step.
- the inside surface of the mould comprises at least one channel to facilitate the removal of air by vacuum extraction from between the film and the inside surface of the mould.
- a channel can be arranged to run the length of the mould, across the width of the mould, or in any appropriate way that would facilitate the extraction of air.
- the mould comprise a plurality of channels, and these can be arranged to originate or terminate in the vicinity of a vacuum nozzle through which the air is drawn out from between the film and the inside surface of the mould.
- the film may attach to the component. Depending on the properties of the film, this could simply be left on the component to act as an outer layer. However, for some finishing steps such as painting or varnishing, it may be preferably to carry these out on the actual component surface. Therefore, in a further embodiment of the invention, the method comprises the step of detaching the film from the component after the component has been removed from the mould so that the film may be peeled off the component. The film may simply be peeled off and discarded, but a robust film may lend itself to re-use in the moulding of a further wind turbine blade.
- the film may remain in the mould when the cured component is removed. Then, the film can simply be peeled from the mould. However, it may be preferred to have the film detach entirely from the mould when the blade is removed after curing. Therefore, in a further preferred embodiment of the invention, the inside surface of the mould comprises a non-stick surface or lining.
- the inside surface of the mould can be coated with a material such as Teflon®, which has favourable non-stick properties.
- FIG. 1 shows a cross-section through a mould with laid-up component layers in a prior art component moulding process
- FIG. 2 shows a cross-section through a mould with laid-up component layers in a component moulding process according to the invention
- FIG. 3 shows a film according to an embodiment of the invention.
- FIG. 4 shows a film being detached from a wind turbine blade moulded using the method according to the invention.
- FIG. 1 shows a cross-section through a mould 2 with laid-up component layers 10 in a prior art component moulding process such as that described in EP 1 310 351 A1, in which a wind turbine blade is formed of fibre layers 10 and cured in a closed mould 2 into which resin is injected under pressure.
- the mould 2 comprises nozzles 21 through which air can be extracted during a vacuum extraction step, thus causing the component layers 10 to expand, and by means of which glue or resin is drawn into the component layers 10 .
- a layer of release agent 4 such as silicone wax is applied to the inside surfaces 20 of the mould 2 , as shown in the enlarged part of the diagram.
- the release agent layer 4 When removing the cured blade from the mould 2 , remnants of the wax 4 can remain stuck to the outer surface of the blade 1 , and must be removed in an additional step such as scrubbing or sandblasting. Also, before the mould 2 can be used again, the release agent layer 4 must either be removed by scraping it off the inside surface 20 of the mould, or it must be smoothed again to give the required level of uniformity.
- FIG. 2 shows a cross-section through a part of a mould 2 with laid-up component layers 10 in a component moulding process according to the invention.
- the mould of FIG. 1 can be used.
- a film 3 is used to line the mould 2 , as shown in part A of the diagram.
- the film 3 can be optimally drawn onto the inside surface 20 of the mould 2 by extracting air from between the film 3 and the mould 2 .
- a vacuum is applied between the film 3 and the mould 2 , and air is extracted through a vacuum nozzle 21 .
- layers 10 of fibre material e.g. carbon-fibre, glass fibre, prepreg, etc.
- the remainder of the moulding process can be carried out in the usual manner, with a vacuum extraction step for drawing out air through a vacuum nozzle as shown in FIG. 1 to allow the component layers to expand, and a curing process to harden the layers.
- Part D of the diagram shows the section X-X′ taken through the mould 2 and film 3 shown in Part B.
- additional channels 22 in the inside surface 20 of the mould allow a more optimal extraction of air from the space between the film 3 and the mould 2 .
- the channels 22 are arranged in the direction of the vacuum extraction nozzle 21 .
- FIG. 3 shows a cross-section through a film 3 according to an embodiment of the invention.
- the film 3 is a thin film 3 of propylene or polyethylene, with a thickness in the range 20 ⁇ m to 100 ⁇ m.
- the ‘inside surface’ 31 of the film 3 which will be in contact with the component layers, is preferably flat and smooth.
- the film 3 exhibits channels 32 or grooves 32 .
- the film 3 is preferably laid into the mould so that these grooves 32 lie in the direction of a vacuum extraction nozzle. In this way, air can be optimally drawn out from the space between the film 3 and the inside surface of the mould during the vacuum extraction step.
- the film could also be manually pressed into the mould by smoothing along the direction of the channels.
- the component layers can be laid up to form the wind turbine blade, as already described, on the inside surface 31 of the film 3 .
- FIG. 4 shows a film 3 being detached from a cured wind turbine blade 1 moulded using the method according to the invention.
- the film 3 can easily be detached from the cured blade 1 by simply peeling off the film 3 .
- the surface of the cured blade 1 is smooth, clean, free of any residue, and ready for any finishing steps such as priming or painting.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Wind Motors (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
Abstract
Description
- This application is a divisional application of U.S. patent application Ser. No. 13/092,193 filed Apr. 22, 2011, and claims the benefit thereof. The U.S. patent application Ser. No. 13/092,193 claims priority of European Patent Office application No. 10163393.1 EP filed May 20, 2010. All of the applications are incorporated by reference herein in their entirety.
- The present invention relates to a mould for moulding a wind turbine blade. Embodiments of the present invention also provide a film for use in a wind turbine blade moulding process, and the use of such a film in the moulding of a wind turbine blade.
- Wind turbine rotor blades may be manufactured using a technique such as the closed-mould casting technique in which the entire blade can be moulded. Glass fibre matting can be used to build up component layers in a suitably shaped mould, and the layers of matting are bonded with a resin and cured in the mould to give a fibre-reinforced polymer or glass-reinforced plastic, generally referred to simply as ‘fibreglass’. Such a method is described in
EP 1 310 351 A1. - To facilitate releasing the finished fibreglass component after curing, the mould is usually coated with a release agent such as a suitable wax so that the resin does not bond with the mould. The release agent is applied to the mould before building up the fibreglass layers. Known release agents are polyvinyl alcohol, silicone wax, slip wax, etc. The release agent must be applied in a uniform layer, and this layer must be absolutely smooth if the outer surface of the cured blade is also to be smooth. However, it is not easy to apply the release agent so that these requirements are met, and the result can be an uneven or dimpled component surface. Furthermore, the types of release agent generally used contain volatile solvents, which pose a health risk to anyone exposed to them. However, the main disadvantage of having to use such a release agent is that, after curing, remnants of the release agent can adhere to the blade in places. These remnants of release agent must be removed in a time-intensive procedure such as scrubbing or sandblasting, adding to the overall cost of manufacture.
- It is an object of the invention to provide an improved way of manufacturing a wind turbine blade by moulding, overcoming the problems mentioned above.
- The object is achieved by the features of the independent claims.
- A method of moulding a wind turbine blade in a mould comprises the steps of applying a film to an inside surface of the mould, assembling component layers for the wind turbine blade on the film, performing curing steps to harden the component layers, and subsequently detaching the cured wind turbine blade from the mould.
- An obvious advantage of the method is that the film obviates the need for a release agent, so that it is no longer necessary to coat the inside surface (or ‘interior surface’) of the mould with a release agent, and it is no longer necessary to remove remnants of a release agent from the cured wind turbine blade. In this way, considerable savings can be made in the manufacturing process, without having to use an expensively prepared mould. Instead, a single sheet of film can simply be laid out to line the mould. After curing, the film can easily be detached from the wind turbine blade, as will be explained below.
- According to one embodiment of the invention, a film suitable for use in a wind turbine blade moulding process comprises an outside surface for lining the interior surface of a mould, and an inside surface for receiving a component layers of the wind turbine blade prior to curing, and wherein the inside and outside surfaces of the film are realised to allow a complete detachment of the cured wind turbine blade from the mould after curing.
- According to one aspect of the invention, the mould for moulding a wind turbine blade comprises an inside or interior surface suitable for receiving such a film, and a vacuum extraction outlet for applying a vacuum to extract air from between the film and the inside surface of the mould.
- According to one embodiment of the invention, such a film may be used in the moulding of a wind turbine blade using the inventive moulding method.
- Particularly advantageous embodiments and features of the invention are given by the dependent claims, as revealed in the following description. Features of the embodiments may be combined as desired to arrive at further embodiments.
- The method is particularly suited to moulding of large wind turbine blades that must be light and require a smooth outer surface suitable for the application of paint. Therefore, in a preferred embodiment of the invention, the component to be moulded comprises layers of a suitable material such as glass fibre or carbon fibre, which layers are bonded with a fibre reinforcement such as resin, glue, thermosetting plastic, etc.
- Bonding can be carried out in a number of ways. For example, dry fibreglass matting can be coated in resin during a manual laying step. Alternatively, previously impregnated fibre materials (known as ‘prepreg’) can be used, which are cured by heating, applying UV-irradiation, etc.
- The method can be used for any moulding technique in which layers are laid up on a mould prior to curing, and subsequently removed from the mould. For example, an essentially hollow wind turbine blade can be made by moulding two half-shells which are then joined at leading and trailing edges by gluing these together. The structure can be given additional support by one or more beams bonded to the inside faces of the half-shells. However, it can be difficult to ensure a satisfactory quality of the glue joints, due to the different material proerties—such as elastic modulus—of the half-shells and the glue used to bond them along their entire lengths. In the case of a wind turbine blade, these glue joints present a potential weakness and may eventually crack or open as a result of the extreme forces that can act on the blade. Therefore, in a particularly preferred embodiment of the invention, the mould comprises a closed mould for manufacturing a wind turbine blade in one piece. In the closed-mould approach, the fibreglass matting can be arranged around a core and this structure can then be enclosed in the mould. A fibre reinforcement such as resin or glue can be previously applied or introduced into the mould after it has been closed. After curing, the mould is opened and the wind turbine blade can be removed. Using this approach, it is possible to manufacture a large, hollow component such as a wind turbine blade in one piece and without any potentially critical glue joints.
- The film used to line the mould can comprise any suitable material that does not adhere to the cured component layers, whether these comprise resin-filled fibre layers, thermosetting plastic layers, prepreg layers, etc. In a particularly preferred embodiment of the invention, therefore, the film comprises polyethylene, polypropylene, or any other suitable plastic, such as the type of film used to manufacture ‘cling-film’ or ‘cling-wrap’. One or both surfaces of the film can have non-stick properties so that the film can easily be removed from the cured wind turbine blade and/or the mould. The term ‘non-stick’ in the context of a film surface is to be understood that the surface has properties that prevent other materials from sticking to it. For example, the film can comprise a polyvinyl chloride component to reduce the ability of other materials to stick to it. The film used to line the mould can be manufactured easily in the required width, and can be supplied on a roll for convenient dispensing.
- The thickness of the film may determine the smoothness of the film layer laid out on the mould. Evidently, the film should be flexible enough so that it can line the mould without any wrinkles or folds forming. On the other hand, the film should be strong enough to allow it to be pulled off the cured component. Therefore, in a preferred embodiment of the invention, the thickness of the film is at least 20 μm and at most 200 μm, more preferably at most 100 μm.
- As mentioned above, it is desirable for the film to have as smooth a surface as possible, without wrinkles or folds, so that the surface of the moulded component will be correspondingly smooth also. Therefore, in a further preferred embodiment of the invention, the method comprises the step of applying a vacuum between the film and the interior surface of the mould. The vacuum can be applied by drawing air out through a nozzle positioned between the film and the inside surface of the mould. Extraction of air from between the film and the mould can ensure that the film lines the mould smoothly. The vacuum need only be applied until the film is sufficiently ‘pressed’ into the mould. Thereafter, the vacuum extraction can be stopped and the component layers can be built up in the mould. Of course, if required, the vacuum can be applied also during laying up the layers, for example to prevent slippage of the film.
- The material and structure of the film used to line the mould can be chosen according to process requirements. For example, as mentioned above, it is desirable to obtain as flat a surface as possible when extracting air by vacuum from between the film and the mould. However, during vacuum extraction, it may be that the film is sucked onto the inside surface of the mould such that small air pockets are trapped. Therefore, in a particularly preferred embodiment of the invention, the film comprises a relief structure on a surface of the film applied to the inside surface of the mould. This relief structure can comprise depressions such as dimples, or raised areas, and can serve to improve the adherence of the film to the inside surface the mould during the step of laying up the component layers prior to curing. A film that lies in close contact with the inside surface of the mould is preferable in order to avoid any slippage when the component layers are laid up in the mould. Alternatively, the relief structure can comprise a plurality of channels or grooves in the film, so that a vacuum, applied between the film and the inside surface of the mould, can optimally draw out any air without allowing any significant air pockets to remain. Such channels or grooves can easily be formed during manufacture of the film, for example in an extrusion process, and are preferably arranged such that they lie in essentially the same direction as the direction taken by the extracted air, i.e. in the direction of a vacuum nozzle. In a particularly simple realisation, the film comprises parallel grooves or channels along its length, and the film is laid lengthwise into the mould, so that vacuum nozzles positioned at each end of the mould can optimally extract any air from between the film and the mould.
- Alternatively or in addition to the relief structure on the outside surface of the film, the mould itself can be realised to assist the vacuum extraction step. Therefore, in a preferred embodiment of the invention, the inside surface of the mould comprises at least one channel to facilitate the removal of air by vacuum extraction from between the film and the inside surface of the mould. Such a channel can be arranged to run the length of the mould, across the width of the mould, or in any appropriate way that would facilitate the extraction of air. Preferably, the mould comprise a plurality of channels, and these can be arranged to originate or terminate in the vicinity of a vacuum nozzle through which the air is drawn out from between the film and the inside surface of the mould.
- After curing and removal of the component from the mould, the film may attach to the component. Depending on the properties of the film, this could simply be left on the component to act as an outer layer. However, for some finishing steps such as painting or varnishing, it may be preferably to carry these out on the actual component surface. Therefore, in a further embodiment of the invention, the method comprises the step of detaching the film from the component after the component has been removed from the mould so that the film may be peeled off the component. The film may simply be peeled off and discarded, but a robust film may lend itself to re-use in the moulding of a further wind turbine blade.
- Regardless of whether a vacuum extraction step is used in lining the mould with the film, the film may remain in the mould when the cured component is removed. Then, the film can simply be peeled from the mould. However, it may be preferred to have the film detach entirely from the mould when the blade is removed after curing. Therefore, in a further preferred embodiment of the invention, the inside surface of the mould comprises a non-stick surface or lining. For example, the inside surface of the mould can be coated with a material such as Teflon®, which has favourable non-stick properties.
- Other objects and features of the present invention will become apparent from the following detailed descriptions considered in conjunction with the accompanying drawings. It is to be understood, however, that the drawings are designed solely for the purposes of illustration and not as a definition of the limits of the invention.
-
FIG. 1 shows a cross-section through a mould with laid-up component layers in a prior art component moulding process; -
FIG. 2 shows a cross-section through a mould with laid-up component layers in a component moulding process according to the invention; -
FIG. 3 shows a film according to an embodiment of the invention; and -
FIG. 4 shows a film being detached from a wind turbine blade moulded using the method according to the invention. - In the drawings, like reference numbers refer to like objects throughout. Objects in the diagrams are not necessarily drawn to scale.
-
FIG. 1 shows a cross-section through amould 2 with laid-up component layers 10 in a prior art component moulding process such as that described inEP 1 310 351 A1, in which a wind turbine blade is formed of fibre layers 10 and cured in aclosed mould 2 into which resin is injected under pressure. - Here, the
mould 2 comprises nozzles 21 through which air can be extracted during a vacuum extraction step, thus causing the component layers 10 to expand, and by means of which glue or resin is drawn into the component layers 10. To allow the cured wind turbine blade to be removed from themould 2 without damage to its surface, a layer of release agent 4 such as silicone wax is applied to the inside surfaces 20 of themould 2, as shown in the enlarged part of the diagram. - When removing the cured blade from the
mould 2, remnants of the wax 4 can remain stuck to the outer surface of theblade 1, and must be removed in an additional step such as scrubbing or sandblasting. Also, before themould 2 can be used again, the release agent layer 4 must either be removed by scraping it off theinside surface 20 of the mould, or it must be smoothed again to give the required level of uniformity. -
FIG. 2 shows a cross-section through a part of amould 2 with laid-up component layers 10 in a component moulding process according to the invention. Essentially, the mould ofFIG. 1 can be used. However, in contrast to the set-up shown inFIG. 1 , instead of treating theinside surface 20 of themould 2 with a release agent, afilm 3 is used to line themould 2, as shown in part A of the diagram. For the sake of clarity, because of the relative thicknesses of thefilm 3 and themould 2, only a small region of the entire set-up is shown. Thefilm 3 can be optimally drawn onto theinside surface 20 of themould 2 by extracting air from between thefilm 3 and themould 2. To this end, as shown in part B of the diagram, a vacuum is applied between thefilm 3 and themould 2, and air is extracted through a vacuum nozzle 21. Then, once themould 2 is satisfactorily lined with thefilm 3, layers 10 of fibre material (e.g. carbon-fibre, glass fibre, prepreg, etc.) can be laid up as desired, as shown in part C of the diagram. The remainder of the moulding process can be carried out in the usual manner, with a vacuum extraction step for drawing out air through a vacuum nozzle as shown inFIG. 1 to allow the component layers to expand, and a curing process to harden the layers. Evidently, a single vacuum nozzle could be used for both air extraction steps, and the vacuum nozzle could be realized to intrude between thefilm 3 and themould 2 for the first extraction step, and to intrude between thefilm 3 and the component layers 10 for the second extraction step. Part D of the diagram shows the section X-X′ taken through themould 2 andfilm 3 shown in Part B. Here,additional channels 22 in theinside surface 20 of the mould allow a more optimal extraction of air from the space between thefilm 3 and themould 2. Here, thechannels 22 are arranged in the direction of the vacuum extraction nozzle 21. -
FIG. 3 shows a cross-section through afilm 3 according to an embodiment of the invention. Here, thefilm 3 is athin film 3 of propylene or polyethylene, with a thickness in therange 20 μm to 100 μm. The ‘inside surface’ 31 of thefilm 3, which will be in contact with the component layers, is preferably flat and smooth. Along its length on the ‘outside surface’ 32 (i.e. the surface which will be in contact with the interior surface of the mould), thefilm 3exhibits channels 32 orgrooves 32. Thefilm 3 is preferably laid into the mould so that thesegrooves 32 lie in the direction of a vacuum extraction nozzle. In this way, air can be optimally drawn out from the space between thefilm 3 and the inside surface of the mould during the vacuum extraction step. However, a vacuum extraction step is not absolutely necessary, since the film could also be manually pressed into the mould by smoothing along the direction of the channels. Once the film is satisfactorily pressed or sucked into the mould to give a favourably smooth surface, the component layers can be laid up to form the wind turbine blade, as already described, on theinside surface 31 of thefilm 3. -
FIG. 4 shows afilm 3 being detached from a curedwind turbine blade 1 moulded using the method according to the invention. As the diagram shows, thefilm 3 can easily be detached from the curedblade 1 by simply peeling off thefilm 3. Assuming that thefilm 3 lined the mould to give a smooth lining without any wrinkles, the surface of the curedblade 1 is smooth, clean, free of any residue, and ready for any finishing steps such as priming or painting. - Although the present invention has been disclosed in the form of preferred embodiments and variations thereon, it will be understood that numerous additional modifications and variations could be made thereto without departing from the scope of the invention. For example, instead of removing the film, a specific film material may be used so that the film could be left on the cured wind turbine blade. For example, if the outside surface of the film has appropriate properties, it could be included in any subsequent finishing steps such as priming or painting, and may even serve a protective function.
- For the sake of clarity, it is to be understood that the use of “a” or “an” throughout this application does not exclude a plurality, and “comprising” does not exclude other steps or elements. A “unit” or “module” can comprise a number of units or modules, unless otherwise stated.
Claims (11)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/626,125 US20150166748A1 (en) | 2010-05-20 | 2015-02-19 | Mould for moulding a wind turbine blade |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10163393.1A EP2388131B1 (en) | 2010-05-20 | 2010-05-20 | Method of moulding a wind turbine blade using a release film, and said film |
| EP10163393.1 | 2010-05-20 | ||
| US13/092,193 US9005381B2 (en) | 2010-05-20 | 2011-04-22 | Method of moulding a wind turbine blade |
| US14/626,125 US20150166748A1 (en) | 2010-05-20 | 2015-02-19 | Mould for moulding a wind turbine blade |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/092,193 Division US9005381B2 (en) | 2010-05-20 | 2011-04-22 | Method of moulding a wind turbine blade |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20150166748A1 true US20150166748A1 (en) | 2015-06-18 |
Family
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|---|---|---|---|
| US13/092,193 Expired - Fee Related US9005381B2 (en) | 2010-05-20 | 2011-04-22 | Method of moulding a wind turbine blade |
| US14/626,125 Abandoned US20150166748A1 (en) | 2010-05-20 | 2015-02-19 | Mould for moulding a wind turbine blade |
Family Applications Before (1)
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|---|---|---|---|
| US13/092,193 Expired - Fee Related US9005381B2 (en) | 2010-05-20 | 2011-04-22 | Method of moulding a wind turbine blade |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US9005381B2 (en) |
| EP (1) | EP2388131B1 (en) |
| KR (1) | KR20110128159A (en) |
| CN (1) | CN102248687B (en) |
| BR (1) | BRPI1102261A2 (en) |
| CA (1) | CA2740478A1 (en) |
| DK (1) | DK2388131T3 (en) |
| NZ (1) | NZ592931A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9914859B2 (en) | 2014-07-31 | 2018-03-13 | Tesa Se | Method for molding a body in a mold |
| WO2018114123A1 (en) * | 2016-12-21 | 2018-06-28 | Siemens Wind Power A/S | Method of applying a protective layer to a wind turbine rotor blade |
| US10343373B2 (en) * | 2015-12-16 | 2019-07-09 | Airbus Defence and Space GmbH | Coated composite component |
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| US7988421B2 (en) * | 2009-03-31 | 2011-08-02 | General Electric Company | Retrofit sleeve for wind turbine blade |
| US20120138223A1 (en) * | 2011-09-29 | 2012-06-07 | General Electric Company | Uv-ir combination curing system and method of use for wind blade manufacture and repair |
| CN102529108A (en) * | 2011-11-24 | 2012-07-04 | 成都飞机工业(集团)有限责任公司 | Overlaying manufacture method for composite material part |
| DE102013221847A1 (en) | 2013-08-01 | 2015-02-05 | Tesa Se | Method for molding a body in a mold |
| EP2918405A1 (en) * | 2014-03-11 | 2015-09-16 | Siemens Aktiengesellschaft | A method for manufacturing a component for a wind turbine |
| EP2942174B1 (en) | 2014-05-07 | 2016-09-21 | Siemens Aktiengesellschaft | Method of preparing a mould for vacuum resin transfer moulding |
| DE102015213507A1 (en) | 2015-07-17 | 2017-01-19 | Tesa Se | Adhesive tape, which can be used in particular in a method for molding a body in a mold |
| CN107482800B (en) * | 2017-08-16 | 2019-02-01 | 北京金风科创风电设备有限公司 | Magnetic conductive parts of motors, winding structures of motors, motors and wind turbines |
| CN108843486B (en) * | 2018-07-30 | 2023-10-13 | 中科国风检测(天津)有限公司 | Wind power blade leading edge protection system and construction process |
| CN111173675A (en) * | 2020-02-18 | 2020-05-19 | 中材科技风电叶片股份有限公司 | Paint prefabricated film, protective structure and preparation method thereof |
| ES2965466T3 (en) * | 2021-02-15 | 2024-04-15 | Klingspor Windpower Aps | Device for treating a mold surface and use of the device |
| CN114856927A (en) * | 2022-04-07 | 2022-08-05 | 中广核全椒风力发电有限公司 | Device for transporting blades for wind turbine generator |
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| US9914859B2 (en) | 2014-07-31 | 2018-03-13 | Tesa Se | Method for molding a body in a mold |
| US10343373B2 (en) * | 2015-12-16 | 2019-07-09 | Airbus Defence and Space GmbH | Coated composite component |
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Also Published As
| Publication number | Publication date |
|---|---|
| NZ592931A (en) | 2012-08-31 |
| US20110284150A1 (en) | 2011-11-24 |
| KR20110128159A (en) | 2011-11-28 |
| DK2388131T3 (en) | 2016-12-19 |
| EP2388131A1 (en) | 2011-11-23 |
| BRPI1102261A2 (en) | 2012-12-25 |
| CN102248687B (en) | 2016-08-31 |
| CA2740478A1 (en) | 2011-11-20 |
| EP2388131B1 (en) | 2016-08-31 |
| US9005381B2 (en) | 2015-04-14 |
| CN102248687A (en) | 2011-11-23 |
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