US20150050569A1 - Air cell - Google Patents

Air cell Download PDF

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Publication number
US20150050569A1
US20150050569A1 US14/390,325 US201314390325A US2015050569A1 US 20150050569 A1 US20150050569 A1 US 20150050569A1 US 201314390325 A US201314390325 A US 201314390325A US 2015050569 A1 US2015050569 A1 US 2015050569A1
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United States
Prior art keywords
liquid
air cell
plural
liquid injection
cell according
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Abandoned
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US14/390,325
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English (en)
Inventor
Yoshiko Tsukada
Mori Nagayama
Atsushi Miyazawa
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Nissan Motor Co Ltd
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Nissan Motor Co Ltd
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Publication date
Priority claimed from JP2012085301A external-priority patent/JP5999316B2/ja
Priority claimed from JP2012085303A external-priority patent/JP5999317B2/ja
Application filed by Nissan Motor Co Ltd filed Critical Nissan Motor Co Ltd
Assigned to NISSAN MOTOR CO., LTD. reassignment NISSAN MOTOR CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MIYAZAWA, ATSUSHI, NAGAYAMA, MORI, TSUKADA, YOSHIKO
Publication of US20150050569A1 publication Critical patent/US20150050569A1/en
Abandoned legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04276—Arrangements for managing the electrolyte stream, e.g. heat exchange
    • H01M8/04283—Supply means of electrolyte to or in matrix-fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/02—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60—Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • H01M50/609—Arrangements or processes for filling with liquid, e.g. electrolytes
    • H01M50/627—Filling ports
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/30—Deferred-action cells
    • H01M6/32—Deferred-action cells activated through external addition of electrolyte or of electrolyte components
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H01M12/065—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to an air cell using oxygen as a positive electrode active material, and particularly, relates to an injection-type air cell into which an electrolyte liquid can be injected at the time of use.
  • the air cell described in Japanese Unexamined Patent Application Publication No. S62-177873 includes a frame including electrodes and a tank housing the frame and an electrolysis solution.
  • the frame includes a pair of cathodes arranged at a predetermined interval and anodes each being placed to be opposed to the outer side of each cathode.
  • the air cell has a configuration in which the frame and the tank are provided with fin-shaped portions and grooves respectively.
  • the fin-shaped portions engage with the grooves when the frame and the tank are assembled together so that two electrolyte holding regions electrically separated from each other are formed in the tank. Accordingly, generation of a current path (liquid junction) via the electrolysis solution between the anodes can be avoided.
  • the air cell is provided with a non-conductive baffle between the paired cathodes. Therefore, a current flow can be prevented from being generated between the cathodes even if a liquid enters the space between the cathodes.
  • the above-described air cell uses, for example, seawater as the electrolysis solution. The air cell is dropped into the sea so as to introduce seawater into the tank and thereby start power generation.
  • An air cell mounted in a vehicle is required to ensure output performance and capacity necessary for the vehicle and therefore required to have a configuration in which a plurality of electrode structures are arranged in series and use a strong alkaline electrolysis solution.
  • the air cell using seawater as the electrolysis solution has no practical problem with regard to a slight liquid junction, since the electrolysis solution has low resistance and the output power is small in such an air cell.
  • any liquid junction should be prevented in an air cell using a strong alkaline electrolysis solution because the resistance of the electrolysis solution is high.
  • An object of the present invention is to provide an injection-type air cell including a plurality of electrode structures arranged in series, and particularly, an air cell capable of reliably preventing a liquid junction between the electrode structures via an electrolyte liquid.
  • An air cell includes: a plurality of electrode structures each including a filling chamber for an electrolyte liquid interposed between an air electrode and a metal negative electrode; an electrode housing portion individually housing the plural electrode structures; and a liquid supply unit which supplies the electrolyte liquid to the plural electrode structures, wherein the plural electrode structures are arranged in series in the electrode housing portion, the electrode housing portion includes a plurality of liquid injection holes to inject the electrolyte liquid into the filling chambers of the respective electrode structures and a plurality of liquid junction prevention portions each dividing a space between the liquid injection holes adjacent to each other, and the liquid supply unit includes a storage tank for the electrolyte liquid and a liquid injection device allowing the electrolyte liquid in the storage tank to flow into the plural liquid injection holes.
  • FIG. 1A is a cross-sectional view of an air cell according to a first embodiment of the present invention.
  • FIG. 1B is a side view of the air cell according to the first embodiment of the present invention.
  • FIG. 2 is a block diagram schematically showing an air cell system including an air cell in which a liquid supply unit shown in FIG. 1A is further equipped with a controller and a pipe.
  • FIG. 3A is a cross-sectional view of an air cell according to a first modified example of the first embodiment of the present invention.
  • FIG. 3B is a side view of the air cell according to the first modified example of the first embodiment of the present invention.
  • FIG. 4A is a cross-sectional view of an air cell according to a second modified example of the first embodiment of the present invention.
  • FIG. 4B is a perspective view of a liquid junction prevention portion according to the second modified example of the first embodiment of the present invention.
  • FIG. 5A is a cross-sectional view of an air cell according to a third modified example of the first embodiment of the present invention.
  • FIG. 5B is a perspective view of a liquid junction prevention portion according to the third modified example of the first embodiment of the present invention.
  • FIG. 6A is a perspective view for explaining another form of the liquid junction prevention portion according to the third modified example of the first embodiment of the present invention.
  • FIG. 6B is a perspective view for explaining yet another form of the liquid junction prevention portion according to the third modified example of the first embodiment of the present invention.
  • FIG. 6C is a perspective view for explaining yet another form of the liquid junction prevention portion according to the third modified example of the first embodiment of the present invention.
  • FIG. 7A is a cross-sectional view of an air cell according to a fourth modified example of the first embodiment of the present invention.
  • FIG. 7B is a cross-sectional view for explaining another form of a liquid junction prevention portion according to the fourth modified example of the first embodiment of the present invention.
  • FIG. 8A is a cross-sectional view of an air cell according to a fifth modified example of the first embodiment of the present invention while showing a state during injection of an electrolyte liquid.
  • FIG. 8B is a cross-sectional view of the air cell according to the fifth modified example of the first embodiment of the present invention while showing a state after injection of the electrolyte liquid.
  • FIG. 9A is a cross-sectional view of an air cell according to a sixth modified example of the first embodiment of the present invention.
  • FIG. 9B is a partly enlarged view of a liquid injection device according to the sixth modified example of the first embodiment of the present invention.
  • FIG. 10A is a cross-sectional view of an air cell according to a seventh modified example of the first embodiment of the present invention.
  • FIG. 10B is a side view of the air cell according to the seventh modified example of the first embodiment of the present invention.
  • FIG. 10C is a partly enlarged view of a liquid junction prevention portion according to the seventh modified example of the first embodiment of the present invention.
  • FIG. 11A is a cross-sectional view of an air cell according to an eighth modified example of the first embodiment of the present invention.
  • FIG. 11B is a partly enlarged view of a liquid injection hole according to the eighth modified example of the first embodiment of the present invention.
  • FIG. 11C is a partly enlarged view of the liquid injection hole according to the eighth modified example of the first embodiment of the present invention.
  • FIG. 12A is a cross-sectional view of an air cell according to a second embodiment of the present invention.
  • FIG. 12B is an enlarged cross-sectional view of an upper portion of an electrode housing portion according to the second embodiment of the present invention.
  • FIG. 13A is a cross-sectional view of an air cell according to a first modified example of the second embodiment of the present invention.
  • FIG. 13B is an enlarged cross-sectional view of an upper portion of an electrode housing portion according to the first modified example of the second embodiment of the present invention.
  • FIG. 14A is a cross-sectional view of an air cell according to a second modified example of the second embodiment of the present invention while showing a state during injection of an electrolyte liquid.
  • FIG. 14B is a cross-sectional view of the air cell according to the second modified example of the second embodiment of the present invention while showing a state after injection of the electrolyte liquid.
  • FIG. 15A is a cross-sectional view of an air cell according to a third modified example of the second embodiment of the present invention.
  • FIG. 15B is an enlarged cross-sectional view of a liquid injection device and an upper portion of an electrode housing portion according to the third modified example of the second embodiment of the present invention.
  • An air cell C 1 shown in FIG. 1A includes a plurality of electrode structures 1 , an electrode housing portion 2 having a plurality of housing compartments individually housing the plural electrode structures 1 , and a liquid supply unit 3 for supplying an electrolyte liquid to the plural electrode structures 1 , each electrode structure 1 including an air electrode 11 , a metal negative electrode 12 and a filling chamber 13 for the electrolyte liquid interposed between the respective electrodes.
  • each of the electrode structures 1 serves as a single cell (an air cell) once the electrolyte liquid is supplied thereto.
  • the air cell C 1 according to the present embodiment is an assembly of single cells and is also referred to as an assembled battery.
  • Each of the electrode structures 1 is formed into a rectangular plate as a whole.
  • the air electrode 11 includes a positive electrode member and a water-repellent layer placed as an outermost layer of the air electrode 11 (not shown in the figure).
  • the positive electrode member contains, for example, a catalyst component and an electric conductive catalyst carrier on which the catalyst component is supported.
  • the catalyst component is metal selected as appropriate from platinum (Pt), ruthenium (Ru), iridium (Ir), silver (Ag), rhodium (Rh), palladium (Pd), osmium (Os), tungsten (W), lead (Pb), iron (Fe), chromium (Cr), cobalt (Co), nickel (Ni), manganese (Mn), vanadium (V), molybdenum (Mo), gallium (Ga), and aluminum (Al), or an alloy of these metals arbitrarily combined together.
  • the shape and size of the catalyst component are not particularly limited, and any shape and size similar to those used in conventionally-known catalyst components may be used. However, the catalyst component is preferably in a particle state.
  • the average particle diameter of catalyst particles is preferably in a range from 1 nm to 30 nm.
  • the average particle diameter of the catalyst particles is within the range from 1 nm to 30 nm, a balance of ease of support of the catalyst component and a catalyst utilization rate with regard to an effective electrode area in which an electrochemical reaction progresses, can be controlled as appropriate.
  • the catalyst carrier functions as a carrier for supporting the catalyst component as described above and as an electron conducting path involved in electron communication between the catalyst component and other substances.
  • the catalyst carrier is not particularly limited as long as it has a specific surface area sufficient to support the catalyst component in a desired dispersed state and has sufficient electron conductivity, and preferably contains carbon as a main component.
  • a specific example of the catalyst carrier may be carbon particles containing carbon black, activated carbon, coke, natural graphite or artificial graphite.
  • the size of the catalyst carrier is not particularly limited; however, an average particle diameter of the catalyst carrier may be approximately in a range from 5 nm to 200 nm, preferably approximately in a range from 10 nm to 100 nm, in view of ease of support, the catalyst utilization rate, the thickness of the catalyst layer adjusted within an appropriate range, and the like.
  • the supported amount of the catalyst component in the positive electrode member is preferably in a range from 10% to 80% by mass, more preferably in a range from 30% to 70% by mass, with respect to the total amount of the positive electrode member.
  • the positive electrode member is not limited thereto, and conventionally-known materials applied to air cells may be used.
  • the water-repellent layer has a liquid-tight (watertight) property with respect to the electrolyte liquid and has air permeability with respect to oxygen.
  • the water-repellent layer includes a water-repellent film such as polyolefin or fluorine resin in order to prevent leakage of the electrolyte liquid, and also has a large number of fine pores in order to supply oxygen to the positive electrode member.
  • the metal negative electrode 12 includes a negative electrode active material containing a single substance of metal or an alloy having a standard electrode potential which is less noble than that of hydrogen.
  • a single substance of metal having a standard electrode potential less noble than that of hydrogen include zinc (Zn), iron (Fe), aluminum (Al), magnesium (Mg), manganese (Mn), silicon (Si), titanium (Ti), chromium (Cr), and vanadium (V).
  • the alloy may be obtained in such a manner as to add, to the metal element as listed above, one or more kinds of metal elements or non-metal elements.
  • the material is not limited thereto, and conventionally-known materials applied to air cells may be used.
  • the electrode housing portion 2 has a configuration in which the plural electrode structures 1 are each formed into a rectangular plate and kept in a standing state, and are arranged in series in the horizontal direction and individually housed in each of the plural housing compartments. Each of the housing compartments of the electrode housing portion 2 is provided with an air chamber 21 located towards the air electrode 11 of each electrode structure 1 .
  • the electrode housing portion 2 further includes a plurality of liquid injection holes 22 formed at the upper portion of the electrode housing portion 2 through which the electrolyte liquid is injected into the plural filling chambers 13 of the electrode structures 1 , and a plurality of liquid junction prevention portions 51 having a protruding structure so that a space between the liquid injection holes 22 adjacent to each other is divided by each liquid junction prevention portion 51 .
  • the plural liquid junction prevention portions 51 of the present embodiment are each formed into a rib as shown in FIG. 1 .
  • the electrode housing portion 2 is further provided with liquid junction prevention portions 51 located towards the end portions in the arrangement direction with respect to the liquid injection holes 22 for injecting the electrolyte liquid into the filling chambers 13 of the electrode structures 1 located at the end portions in the arrangement direction.
  • the liquid junction prevention portions 51 are also located on both sides of each liquid injection hole 22 .
  • the liquid supply unit 3 includes a storage tank 31 for the electrolyte liquid, and a plurality of liquid injection devices 32 located above the respective liquid injection holes 22 to allow the electrolyte liquid in the storage tank 31 to flow into the liquid injection holes 22 .
  • each liquid injection device 32 includes a switching body 41 which controls the flow of the electrolyte liquid.
  • the plural liquid injection devices 32 are located to face the corresponding liquid injection holes 22 .
  • the switching body 41 is a switching valve.
  • the plural liquid injection devices 32 are each located at a position vertically separate from the liquid junction prevention portions 51 .
  • the electrolyte liquid stored in the liquid supply unit 3 is an electrolysis solution or, for example, a liquid (water) for dissolving a solid electrolyte placed or mixed in the electrode structures 1 or in a pipe 35 (shown in FIG. 2 ) installed from the storage tank 31 to the respective liquid injection devices 32 .
  • an aqueous solution of potassium chloride, sodium chloride, or potassium hydroxide may be applicable.
  • the electrolyte liquid is not limited thereto, and conventionally-known electrolysis solutions applied to air cells may be used.
  • the amount of the electrolyte liquid is determined in view of a discharge time of the air cell C 1 , a precipitation amount of metal salt produced at the time of discharge, or the like.
  • FIG. 2 is a block diagram schematically showing an air cell system including an air cell C 1 ′ in which the liquid supply unit 3 shown in FIG. 1 is further equipped with a controller 33 and the pipe 35 .
  • Each of the electrode structures 1 includes a case housing the air electrode 11 and the metal negative electrode 12 so as to serve as a cartridge, and is housed in each of the housing compartments of the electrode housing portion 2 as indicated by the arrow in the figure.
  • the electrode housing portion 2 is provided with a cover (not shown in the figure) placed on the respective housing compartments. The cover may also be provided with the liquid injection holes 22 and the liquid junction prevention portions 51 .
  • the electrode housing portion 2 further includes a busbar 23 inside thereof on which the plural electrode structures 1 housed in the electrode housing portion 2 are connected in series.
  • the air cell C 1 ′ supplies electric power to a driven body 5 such as a motor via a controller 4 .
  • the electrode housing portion 2 is further connected with an air supply unit 6 .
  • the air supply unit 6 supplies air to the air chambers 21 adjacent to the electrode structures 1 in the respective housing compartments.
  • the air supply unit 6 includes an air compressor, a flow amount control valve, pipes, and the like.
  • the liquid supply unit 3 includes the storage tank 31 , the liquid injection devices 32 , the pipe 35 and the controller 33 that controls the flow of the electrolyte liquid.
  • the controller 33 includes a pump, a flow amount control valve, and the like.
  • the air cell C 1 ′ may have a configuration in which the storage tank 31 and the liquid injection devices 32 are provided separately from each other, as shown in FIG. 2 .
  • the liquid supply unit 3 opens the switching bodies (the switching valves) 41 of the respective liquid injection devices 32 so that the electrolyte liquid flows down through the liquid injection holes 22 to be injected into the filling chambers 13 of the respective electrode structures 1 . Accordingly, each of the electrode structures 1 serves as a single cell (an air cell) to start power generation.
  • the air cell C 1 includes the plural liquid junction prevention portions 51 each having a protruding structure and dividing the space between the liquid injection holes 22 adjacent to each other.
  • the remaining electrolyte liquid does not flow into the adjacent liquid injection hole 22 . Accordingly, the air cell C 1 can reliably prevent a liquid junction between the electrode structures (the single cells) 1 adjacent to each other, namely, a short circuit via the electrolyte liquid.
  • the air cell C 1 can be applied appropriately to an air cell with high output power and high capacity using an electrolysis solution having high resistance, such as a strong alkaline electrolysis solution, in which any liquid junction should be prevented.
  • the air cell C 1 is thus remarkably suitable for an onboard power supply for a vehicle or the like which is required to have high output power and high capacity.
  • the air cell C 1 has a configuration in which the electrode housing portion 2 is provided with the liquid junction prevention portions 51 also at the end portions in the arrangement direction of the electrode structures 1 .
  • This configuration can prevent the electrolyte liquid from flowing out of the air cell C 1 at the time of injecting the electrolyte liquid.
  • the air cell C 1 uses the storage tank 31 as a common tank for the plural electrode structures 1 so as to simplify the structure thereof and reduce costs.
  • the liquid injection devices 32 each include the switching body (the switching valve) 41 , the amount of the electrolyte liquid used can be adjusted. Since the switching bodies 41 are closed after the electrolyte liquid is injected, a liquid junction via the electrolyte liquid in the storage tank 31 can be prevented.
  • the air cell C 1 is provided with the plural liquid injection devices 32 in such a manner as to face the corresponding liquid injection holes 22 . Therefore, the electrolyte liquid can be injected rapidly into the respective electrode structures 1 , which can contribute to shortening the startup time. Further, since the air cell C 1 can inject the electrolyte liquid only into the selected electrode structures 1 , the air cell C 1 can selectively start a particular number of the electrode structures (the single cells) 1 depending on the required amount of electricity. The air cell C 1 can also easily deal with automatic control of liquid injection.
  • the air cell C 1 includes the plural liquid injection devices 32 each being located at a position vertically separate from the liquid junction prevention portions 51 , a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid on the liquid supply unit 3 side can be prevented at the time of and after injecting the electrolyte liquid.
  • FIG. 3A to FIG. 11C are views for explaining air cells C 2 to C 9 according to the first to eighth modified examples of the first embodiment of the present invention. It should be noted that the same elements as those of the air cell C 1 are indicated by the same reference numerals in the respective modified examples, and specific explanations thereof are omitted as appropriate.
  • An air cell C 2 according to the first modified example shown in FIG. 3A and FIG. 3B includes, on the upper surface of the electrode housing portion 2 , the liquid injection holes 22 corresponding to the respective electrode structures 1 , and liquid junction prevention portions 52 each having a protruding structure formed into a step and being located on one side of each liquid injection hole 22 .
  • the liquid supply unit 3 includes the storage tank 31 and a supply head 34 provided with the plural liquid injection devices 32 .
  • the supply head 34 is connected to the storage tank 31 via the pipe 35 and can be lifted up and down with respect to the electrode housing portion 2 .
  • the electrolyte liquid is injected into the respective electrode structures 1 by the liquid supply unit 3 .
  • the electrolyte liquid may be injected while the supply head 34 is in contact with the liquid junction prevention portions 52 .
  • the air cell C 2 can reliably prevent a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid in the same manner as the air cell C 1 .
  • An air cell C 3 according to the second modified example shown in FIG. 4A includes a plurality of liquid junction prevention portions 53 each having surfaces inclined downward to the liquid injection holes 22 or having a step.
  • each of the liquid junction prevention portions 53 has a triangular cross-section and has surfaces inclined downward to the liquid injection holes 22 .
  • the air cell C 3 can ensure smooth and rapid injection of the electrolyte liquid into the liquid injection holes 22 and shorten the startup time in a manner such that the inclined surfaces of the liquid junction prevention portions 53 serve as a guide at the time of injecting the electrolyte liquid, so as to achieve the same functions and effects as the air cell C 1 .
  • the inclined surfaces of the liquid junction prevention portions 53 contribute to avoiding the remains of the electrolyte liquid and thereby reliably preventing a liquid junction.
  • An air cell C 4 according to the third modified example shown in FIG. 5A includes a plurality of liquid junction prevention portions 54 each having surfaces inclined downward to the liquid injection holes 22 or having a step.
  • each of the liquid junction prevention portions 54 has a trapezoidal cross-section and has surfaces inclined downward to the liquid injection holes 22 .
  • the air cell C 4 can ensure smooth and rapid injection of the electrolyte liquid into the liquid injection holes 22 and shorten the startup time in a manner such that the inclined surfaces of the liquid junction prevention portions 53 serve as a guide at the time of injecting the electrolyte liquid, so as to achieve the same functions and effects as the air cell C 1 .
  • the liquid supply unit 3 comes into contact with the liquid junction prevention portions 54 when the electrolyte liquid is injected so that the liquid supply unit 3 can be positioned appropriately.
  • FIGS. 6A , 6 B and 6 C show liquid junction prevention portions 55 , 56 and 57 , respectively, each having surfaces inclined downward to the liquid injection holes 22 or having steps.
  • the liquid junction prevention portion 55 shown in FIG. 6A has a cross-sectional shape having downward steps towards the liquid injection hole 22 .
  • the liquid junction prevention portion 56 shown in FIG. 6B has a cross-sectional shape having a concave curved surface inclined downward to the liquid injection hole 22 .
  • the liquid junction prevention portion 57 shown in FIG. 6C has a cross-sectional shape having a convex curved surface inclined downward to the liquid injection hole 22 .
  • the respective liquid junction prevention portions 55 , 56 and 57 can achieve the same effects as the liquid junction prevention portion 51 of the air cell C 1 .
  • An air cell C 5 according to the fourth modified example shown in FIG. 7A includes a plurality of liquid junction prevention portions 58 each including a plurality of projections 58 A located at predetermined intervals in the arrangement direction of the electrode structures 1 .
  • the respective liquid junction prevention portions 58 include the plural projections 58 A having the same height.
  • the air cell C 5 can achieve the same functions and effects as the air cell C 1 .
  • the air cell C 5 can secure the state of preventing a liquid junction immediately after the electrolyte liquid is injected, so as to achieve an improved liquid junction preventing function.
  • the liquid junction prevention portions 58 each include the plural projections 58 A having different heights.
  • the air cell C 5 may further include sensors S between the respective projections 58 A, as shown in FIG. 7B . According to this configuration, even when the electrolyte liquid flowing from the liquid injection devices 32 flows over the projections 58 A closest to the liquid injection holes 22 , the sensors S can detect the flowing electrolyte liquid so as to close the switching body 41 .
  • the liquid injection device 32 of the liquid supply unit 3 includes a switching body 42 instead of the switching body 41 (the switching valve) of the air cell C 1 .
  • the switching body 42 is placed to allow the electrolyte liquid to flow into the plural liquid injection holes 22 .
  • the switching body 42 of this modified example is a partitioning plate.
  • the air cell C 6 opens the switching body 42 so as to allow the electrolyte liquid to immediately flow onto the upper surface of the electrode housing portion 2 and thereby inject the electrolyte liquid into the plural electrode structures 1 .
  • the electrolyte liquid may fall on and cover the middle liquid junction prevention portion 51 .
  • the air cell C 6 can greatly shorten the time interval between the injection of the electrolyte liquid and the startup.
  • the liquid junction prevention portions 51 can reliably prevent a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid after the injection of the electrolyte liquid.
  • An air cell C 7 according to the sixth modified example shown in FIG. 9A and FIG. 9B includes water-repellent portions 61 a having water repellency provided at least on peripheral surfaces of the respective liquid injection devices 32 .
  • the water-repellent portions 61 a are formed, for example, in a manner such that an arbitrary water-repellent agent is applied to the peripheral surfaces of the respective liquid injection devices 32 .
  • the contact angle of each water-repellent portion 61 a with respect to the electrolyte liquid is at least 50 degrees or greater, preferably 80 degrees or greater.
  • the air cell C 7 can achieve the same functions and effects as the air cell C 1 and also prevent the electrolyte liquid from adhering to the peripheries of the respective liquid injection devices 32 due to the water-repellent portions 61 a. Accordingly, even in a state where the storage tank 31 is in contact with the liquid junction prevention portions 51 as shown in FIG. 9A , a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid on the storage tank 31 side can be prevented.
  • An air cell C 8 according to the seventh modified example shown in FIGS. 10A , 10 B and 10 C includes water-repellent portions 61 b having water repellency provided at least on surfaces of top portions of the respective liquid junction prevention portions 52 .
  • the air cell C 8 can achieve the same functions and effects as the air cell C 1 and also prevent the electrolyte liquid from remaining on the top portions of the respective liquid junction prevention portions 52 due to the water-repellent portions 61 b. Accordingly, the air cell C 8 can further improve the liquid junction preventing function due to the liquid junction prevention portions 52 .
  • An air cell C 9 according to the eighth modified example shown in FIG. 11A and FIG. 11B includes hydrophilic portions 62 a having hydrophilicity provided on peripheries of the openings of the respective liquid injection holes 22 .
  • the hydrophilic portions 62 a are formed, for example, in a manner such that an arbitrary hydrophilic agent is applied to the peripheries of the openings of the respective liquid injection holes 22 .
  • the contact angle of each hydrophilic portion 62 a with respect to the electrolyte liquid is at least less than 80 degrees, preferably less than 50 degrees.
  • the air cell C 9 can achieve the same functions and effects as the air cell C 1 and also allow the electrolyte liquid to easily flow into the respective liquid injection holes 22 due to the hydrophilic portions 62 a so as to further shorten the startup time in association with an increase of the liquid injection rate.
  • the air cell C 9 may further include water-repellent portions 61 c serving as water-repellent regions on the outer sides of the hydrophilic regions (namely, the hydrophilic portions 62 a ).
  • the air cell C 9 can not only increase the liquid injection rate and further shorten the startup time due to the hydrophilic portions 62 a but also prevent the electrolyte liquid from remaining on the peripheries of the respective liquid injection holes 22 due to the water-repellent portions 61 c after the injection of the electrolyte liquid. Accordingly, a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid can be prevented.
  • An air cell C 10 shown in FIG. 12A and FIG. 12B includes the plural electrode structures 1 , the electrode housing portion 2 having a plurality of housing compartments individually housing the plural electrode structures 1 , and the liquid supply unit 3 for supplying the electrolyte liquid to the plural electrode structures 1 , each electrode structure 1 including the air electrode 11 , the metal negative electrode 12 and the filling chamber 13 for the electrolyte liquid interposed between the respective electrodes.
  • the electrode housing portion 2 includes, at the upper portion thereof, a plurality of water-repellent portions 61 d having water repellency, instead of the plural liquid junction prevention portions 51 .
  • the respective water-repellent portions 61 d are located between the liquid injection holes 22 adjacent to each other.
  • the water-repellent portions 61 d are each formed in a manner such that an arbitrary water-repellent agent is applied to a portion between the liquid injection holes 22 adjacent to each other on the upper surface of the electrode housing portion 2 .
  • the contact angle of each water-repellent portion 61 d with respect to the electrolyte liquid is at least 50 degrees or greater, preferably 80 degrees or greater.
  • the electrode housing portion 2 is further provided, at the upper portion thereof, with water-repellent portions 61 d placed towards the end portions in the arrangement direction with respect to the liquid injection holes 22 for injecting the electrolyte liquid into the filling chambers 13 of the electrode structures 1 located at the end portions in the arrangement direction.
  • the water-repellent portions 61 d are also placed on both sides of each liquid injection hole 22 .
  • the air cell C 10 can remove the electrolyte liquid from the respective water-repellent portions 61 d so as to prevent the electrolyte liquid remaining on the upper portion of the electrode housing portion 2 from connecting the liquid injection holes 22 adjacent to each other. Accordingly, the air cell C 10 can reliably prevent a liquid junction between the electrode structures (the single cells) 1 adjacent to each other, namely, a short circuit via the electrolyte liquid. Therefore, the air cell C 10 can be applied appropriately to an air cell with high output power and high capacity using an electrolysis solution having high resistance, such as a strong alkaline electrolysis solution, in which any liquid junction should be prevented. The air cell C 10 is thus remarkably suitable for an onboard power supply for a vehicle or the like which is required to have high output power and high capacity.
  • the air cell C 10 includes the liquid injection devices 32 each being located at a position vertically separate from the electrode housing portion 2 , a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid on the liquid supply unit 3 side can be prevented at the time of and after injecting the electrolyte liquid.
  • FIG. 13A to FIG. 15B are views for explaining air cells C 11 to C 13 according to the first to third modified examples of the second embodiment of the present invention. It should be noted that the same elements as those of the air cell C 10 are indicated by the same reference numerals in the respective modified examples, and specific explanations thereof are omitted as appropriate.
  • the air cell C 11 includes, on the upper surface of the electrode housing portion 2 , the plural liquid injection holes 22 corresponding to the respective electrode structures 1 , a plurality of water-repellent portions 61 e, and a plurality of hydrophilic portions 62 b provided on peripheries of the openings of the respective liquid injection holes 22 . Therefore, the electrode housing portion 2 is provided, on the upper surface thereof, with the water-repellent portions 61 e and the hydrophilic portions 62 b including the liquid injection holes 22 alternately arranged.
  • the hydrophilic portions 62 b are formed by the application of an arbitrary hydrophilic agent.
  • the contact angle of each hydrophilic portion 62 b with respect to the electrolyte liquid is at least less than 80 degrees, preferably less than 50 degrees.
  • the air cell C 11 configured as described above can not only achieve the same functions and effects for liquid junction prevention as the air cell C 10 due to the water-repellent portions 61 e but also allow the electrolyte liquid to easily flow into the respective liquid injection holes 22 due to the hydrophilic portions 62 b so as to further shorten the startup time in association with an increase of the liquid injection rate.
  • the liquid injection device 32 of the liquid supply unit 3 provided in the air cell C 11 includes the switching body 42 instead of the switching body 41 (the switching valve) of the air cell C 11 .
  • the switching body 42 is placed to allow the electrolyte liquid to flow into the plural liquid injection holes 22 .
  • the switching body 42 of this modified example is a partitioning plate.
  • the electrode housing portion 2 is provided with ribs 24 on both sides or on the periphery of the upper surface thereof. The ribs 24 prevent the electrolyte liquid from flowing out of the air cell C 12 at the time of injecting the electrolyte liquid.
  • the air cell C 12 opens the switching body 42 so as to allow the electrolyte liquid to immediately flow onto the upper surface of the electrode housing portion 2 and thereby inject the electrolyte liquid into the plural electrode structures 1 . Therefore, the air cell C 12 can greatly shorten the time interval between the injection of the electrolyte liquid and the startup.
  • the air cell C 12 can remove the electrolyte liquid from the water-repellent portions 61 e after the injection of the electrolyte liquid so as to prevent the electrolyte liquid from connecting the liquid injection holes 22 adjacent to each other. Accordingly, the air cell C 12 can reliably prevent a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid.
  • An air cell C 13 according to the third modified example shown in FIG. 15A and FIG. 15B includes, on the upper surface of the electrode housing portion 2 , the liquid injection holes 22 , the water-repellent portions 61 e and the hydrophilic portions 62 b, and further includes the water-repellent portions 61 a provided at least on peripheral surfaces of the respective liquid injection devices 32 .
  • the electrode housing portion 2 is provided, on the upper surface thereof, with ribs 25 in contact with the storage tank 31 of the liquid supply unit 3 .
  • the ribs 25 function to prevent the electrolyte liquid from flowing out of the air cell C 13 at the time of injecting the electrolyte liquid as in the case of the air cell C 12 , and function to position the liquid supply unit 3 appropriately.
  • the air cell C 13 can achieve the same functions and effects as the air cell C 12 and also prevent the electrolyte liquid from adhering to the peripheries of the respective liquid injection devices 32 due to the water-repellent portions 61 a on the storage tank 31 side. Accordingly, the air cell C 13 having a configuration in which the storage tank 31 is in contact with the ribs 25 , can prevent a liquid junction between the electrode structures (the single cells) 1 via the electrolyte liquid on the storage tank 31 side.
  • the air cell according to the present invention is not limited to the first or second embodiment, and specific configurations such as shapes, numbers and materials of the respective elements can be modified as appropriate without departing from the scope of the present invention.
  • the first embodiment exemplified the liquid junction prevention portions having predetermined lengths such as ribs, other liquid junction prevention portions formed, for example, in such a manner as to surround the respective liquid injection holes may be applicable.
  • the second embodiment exemplified the water-repellent portions having predetermined lengths, other water-repellent portions provided, for example, in regions surrounding the respective liquid injection holes may be applicable.
  • the first to eighth modified examples of the first embodiment and the first to third modified examples of the second embodiment may be combined as appropriate.
  • the injection-type air cell according to the present invention including a plurality of electrode structures arranged in series, can reliably prevent a liquid junction between the electrode structures via the electrolyte liquid.
  • the air cell can be applied to an air cell with high output power and high capacity using a strong alkaline electrolysis solution, and is remarkably suitable for an onboard power supply for a vehicle or the like.

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  • Electrochemistry (AREA)
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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
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JP2012-085301 2012-04-04
JP2012-085303 2012-04-04
JP2012085301A JP5999316B2 (ja) 2012-04-04 2012-04-04 空気電池
JP2012085303A JP5999317B2 (ja) 2012-04-04 2012-04-04 空気電池
PCT/JP2013/056753 WO2013150865A1 (ja) 2012-04-04 2013-03-12 空気電池

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KR102429170B1 (ko) * 2017-09-04 2022-08-03 현대자동차주식회사 리튬 공기 배터리 장치
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EP2835858B1 (en) 2016-11-09
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CN104205479A (zh) 2014-12-10
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EP3125359A1 (en) 2017-02-01
TWI508354B (zh) 2015-11-11
WO2013150865A1 (ja) 2013-10-10
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TW201401628A (zh) 2014-01-01
EP2835858A4 (en) 2015-07-01

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