US20140251794A1 - Method and system for electrolysis - Google Patents
Method and system for electrolysis Download PDFInfo
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- US20140251794A1 US20140251794A1 US13/787,662 US201313787662A US2014251794A1 US 20140251794 A1 US20140251794 A1 US 20140251794A1 US 201313787662 A US201313787662 A US 201313787662A US 2014251794 A1 US2014251794 A1 US 2014251794A1
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/60—Constructional parts of cells
- C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- the present invention relates to a system and apparatus for electrolysis.
- Carbon based fuels such as so-called fossil fuels, are in high demand. However, the supply is finite. As such, industry is seeking for ways to maximize or increase the efficiency of these fossil fuels. Consequently, it is desirable to have a method to produce a fuel which does not originate from fossil fuels.
- FIG. 1 is a depiction of a system in one embodiment
- FIG. 2A is a perspective view of a two cell electrolytic unit in one embodiment
- FIG. 2B is a perspective view of a chamber in one embodiment
- FIG. 3 is a cross-sectional view of the electrolytic unit in FIG. 2A ;
- FIG. 4 is a cross-sectional view of the electrolytic unit in FIG. 2A ;
- FIG. 5 is a top view of a plate with a neutral orientation
- FIG. 6 is a top view of a plate with an anode orientation
- FIG. 7 is a top view of a plate with a cathode orientation.
- electrolysis is utilized to produce a hydrogen based fuel.
- a hydrogen based fuel refers to a fuel whose primary element is hydrogen.
- the fuel produced can vary depending upon the materials utilized.
- the hydrogen based fuel produced can comprise hydrogen gas, ortho-hydrogen, para-hydrogen, and combinations thereof.
- the hydrogen based fuel can be fed to an engine for power or collected and stored.
- the hydrogen based fuel produced is provided as the primary source of fuel.
- the fuel produced is used to supplement a primary fuel source.
- an engine's primary fuel source may comprise gasoline or diesel, but the engine can be supplemented with hydrogen based fuel.
- the supplemental fuel can result in increased power, increased efficiency, for example in terms of miles per gallon of fuel, and combinations thereof.
- FIG. 1 is a depiction of a system in one embodiment.
- the system 100 comprises a reservoir 107 coupled to an engine 110 .
- the engine can comprise a diesel engine, gasoline engine, natural gas engine, and virtually any type of engine which burns carbon based fuels.
- the reservoir 107 comprises a level of liquid.
- the liquid comprises water and electrolytes.
- the water comprises distilled water.
- An electrolyte is a substance containing free ions which are the carriers of electric current. Pure distilled water is not electrically conductive, and thus impurities or other solids are needed to make water electrically conductive. Electrolytes within the water make water electrically conductive.
- electrolytes include, but are not limited to, potassium hydroxide, sodium hydroxide, acids, bases, and salts.
- electrolysis the bond between the oxygen and hydrogen in the water molecule is broken with electrical energy, releasing hydrogen gas, oxygen gas, hydrogen based fuels, and combinations thereof.
- the amount of water in the system decreases over time as the water is converted into a gas.
- the electrolytes provided there are no leaks in the system, do not otherwise leave the system. Accordingly, electrolytes, once added to the reservoir, do not require frequent replacement.
- the fluid comprising electrolytes is acidic.
- the concentration of the electrolytes within the fluid can vary.
- the amount of electrolytes is related to the amps being drawn by the electrolytic cell from the power source.
- the unit draws about 35 amps.
- the amps can be as high as between 85 and about 105 amps. In such embodiments, there is virtually unlimited available power coming from an on-site mega watt generator.
- the electrolyte concentration, the pH, and the temperature of the fluid all have an effect on electrolysis. Consequently, in one embodiment, one or more of these factors are monitored and/or controlled.
- the material which makes contact with the liquid in the reservoir 107 can comprise a variety of materials as discussed above.
- the reservoir 107 , the pump 108 housing, and the connecting lines comprise polypropylene or other material which is impervious to the acidic conditions of the liquid.
- the reservoir 107 is coupled to a pump 108 .
- the size of the reservoir can vary depending on relative space as well as fuel requirements. In one embodiment the reservoir ranges from about 3 quarts to about 50 gallons.
- the pump 108 can comprise any type of pump known in the art. In one embodiment the pump 108 comprises a 12 or 24 Volt DC pump. In one embodiment the pump 108 comprises housing and an impeller made from polypropylene which is impervious to acid. In one such embodiment, the pump 108 comprises a magnet which connects the impeller to the motor so that the motor will not be subject to the liquid within the pump housing. In one embodiment, no electrical parts of the pump 108 come into contact with the liquid in the pump housing.
- the pump 108 is located upstream of the chamber 101 , and downstream of the reservoir 107 .
- the flow rates of the pump 108 can vary depending on the application.
- the flow rates can range from 0.5 gallons per minute to about 6 gallons per minute. In one embodiment the flow rates range from about 1.3 gallons per minute to about 3.5 gallons per minute.
- the system 100 further comprises a cooler 109 . Electrolysis produces heat, and that heat must be removed to prevent overheating the system 100 . Overheating the system 100 increases part degradation.
- the cooler 109 can be located upstream or downstream of the pump 108 .
- the cooler 109 can comprise virtually any type of cooler including but not limited to a radiator fin cooler, a single or double pass heat exchanger, a chiller, etc.
- the cooler 109 moderates and maintains a desired temperature. In one embodiment the temperature of the liquid ranges from between about 80° to about 200° F. or greater. In one embodiment the temperature of the liquid ranges from between about 95° to about 120° F.
- Fluid is pumped into the chamber 101 via a chamber inlet 106 .
- the chamber inlet 106 can couple with the chamber 101 at any point. In one embodiment the chamber inlet 106 couples to the bottom of the chamber 101 whereas in other embodiments the chamber inlet 106 couples to the side of the chamber 101 .
- the chamber 101 discussed in detail below, is the location wherein the electrolysis occurs. In one embodiment the chamber 101 is filled with liquid. In one embodiment the chamber 101 is completely filled with liquid such that all parts are submerged.
- the chamber 101 is connected to a power source 102 .
- the power source 102 can comprise virtually any power source including a battery or even AC power.
- the power source 102 is coupled to the chamber 101 via a cathode electrode 103 and an anode electrode 104 .
- the chamber outlet 105 Downstream of the chamber 101 is the chamber outlet 105 .
- the chamber outlet 105 couples the chamber 101 to the reservoir 107 .
- the system flows clockwise from the reservoir 107 to the pump 108 , to the cooler 109 , to the chamber 101 , and back to the reservoir 107 .
- an object clockwise of an object will be referred to as downstream.
- the pump 108 is downstream of the reservoir 107 .
- the pump 108 is upstream of the chamber 101 .
- the chamber outlet 105 can couple to the reservoir 107 at virtually any location including the bottom, top, and side.
- the gas and liquid separate and the gas raises to the top of the reservoir 107 through the gas outlet 133 .
- the reservoir 107 can withstand pressures as high as 30 psi.
- the gas outlet 133 is connected to an engine 110 .
- the gas outlet 133 is coupled to a storage container wherein the hydrogen based fuel is stored.
- the system 100 further comprises a filter (not shown).
- a filter (not shown). Degradation of materials, solids in the water, electrolytes, etc. result in fine solid particles which are present in the fluid. In one embodiment, if these solids are not removed, they can plug the plates resulting in decreased efficiency.
- a filter helps remove these fine particles.
- the filter comprises a 2 micron or less filter. In another embodiment, the filter comprises a 0.5 micron polypropylene filter. Such a filter is impervious to the often acidic conditions and thus does not degrade. The filter traps these small impurities so they can be removed from the system.
- FIG. 2A is a perspective view of a two-cell electrolytic unit in one embodiment.
- FIG. 2B is a perspective view of a chamber in one embodiment.
- the electrolytic unit 232 of FIG. 2A fits within the chamber cover 229 .
- the electrolytic unit 232 comprises a cathode electrode 103 and an anode electrode 104 .
- Virtually any type of electrode can be utilized.
- the cathode electrode 103 comprises titanium steel and the anode electrode 104 comprises stainless steel.
- the types of materials utilized during electrolysis dictate, in part, which hydrogen-based fuel is produced. Titanium results in ortho-hydrogen, a very powerful fuel, being produced. Further, titanium is not susceptible to the acidic properties of the electrolyte and does not become sacrificial.
- Other materials which can be utilized include, but are not limited to, gold, platinum, nickel, and silver.
- the chamber cover 229 can comprise any non-conductive material.
- a non-conductive material is a material that resists the flow of electric charge, also called a dielectric, as is well known to one skilled in the art.
- Non-conductive materials include plastics such as ABS plastics, nylon, polypropylene etc. Virtually any material which can withstand temperatures of 200° F. and which are impervious to acid can be utilized as the non-conductive material.
- the outlet adapter 134 also seen is the outlet adapter 134 .
- the outlet adapter 134 couples with the chamber outlet 105 . In one embodiment the outlet adapter 134 is non-conductive.
- FIG. 2B also illustrates a non-conductive washer 113 which sits between the top of the chamber cover 229 and the electrodes.
- the electrodes are on the right side of the chamber 101 .
- the side closest to the electrodes will be referred to as the front side.
- the side opposite of the front side is referred to as the back side.
- the buffer plate 212 serves as a buffer between the electrodes and the first plate 214 .
- the buffer plate 212 is non-conductive, and in one embodiment comprises a thickness of about 1 ⁇ 8 of an inch and two holes each with a diameter of about 3 ⁇ 8 of an inch through which one cathode screw and one anode screw will be inserted.
- the electrolytic unit 232 comprises 14 plates and two cells. This will be discussed in more detail below and should not be deemed limiting.
- FIG. 3 is a cross-sectional view of the electrolytic unit in FIG. 2A .
- the neutral plates 215 can comprise virtually any conductive material including but not limited to stainless steel, 304 , 316 , 440 and other grades of stainless steel. Stainless steel, and the various grades, have a benefit of not degrading in the electrolyte solution.
- the neutral plates 215 are not connected to any conductive piece.
- the neutral plates 215 serve to control the rate of electrolysis, control the amperage within the system 100 , minimize temperature, and minimize degradation.
- the first plate is a neutral plate 215 .
- the first plate 215 is the plate which is closest in proximity to the cathode 218 and anode 219 screws.
- the first plate is the plate closest to the front side.
- the plates are numbered numerically beginning at the plates closest to the location of the electrodes, the front side.
- the first two plates are neutral plates 215 .
- the first plate, or first two plates are neutral plates 215 , this allows a buffer between the first conductive plate, either titanium or stainless steel as depicted, and the cathode screw 218 and anode screw 219 .
- the neutral plates 215 creates a buffer so that the electrolysis is isolated and occurs only where it is designed and desired to occur, namely, between two conductive plates. Minimizing or eliminating unwanted electrolysis, or any electrolysis which does not occur between two conductive plates, maximizes the efficiency of the desired electrolysis and reduces erosion of materials. If the first plate were not neutral, then even with the electrode buffer plate 212 , undesirable electrolysis occurs between conductive plates and parts such as the cathode screw 218 , for example, causing wear on the cathode screw 218 . Thus, in one embodiment one or more neutral plates 215 are adjacent to the front side. As noted, this improves electrolysis efficiency while minimizing part degradation.
- FIG. 5 is a top view of a plate in a neutral orientation in one embodiment.
- the plate 214 comprises four holes 535 a - c , 536 which are adjacent to the corners of the plate.
- the plate is six inches long, 3.5 inches wide, and between about 0.01-0.06 inches thick. In another embodiment the plate is between about 0.028 and 0.032 inches thick.
- the thickness and other dimensions are provided for illustrative purposes only and should not be deemed limiting. Additionally, while the shape is provided as rectangular other shapes can be utilized.
- the plate comprises three large holes 535 a - c of the same diameter and one small hole 536 of a smaller different diameter.
- the large holes 535 a - c comprise a diameter of about 5 ⁇ 8 0 of an inch.
- the small hole 536 comprises a diameter of about 1 ⁇ 4 inch. While specific diameters are discussed, it should be understood that this is for illustrative purposes as other diameters can be successfully utilized.
- the anode insert 222 and cathode insert 221 which passes perpendicular through the plates comprise a diameter of about 1 ⁇ 4 inch, and this is why, in the embodiment discussed, the small hole 536 has a diameter of 1 ⁇ 4 inch. If the diameter of the anode insert 222 and cathode insert 221 changes, so too would the diameter of the small hole 536 .
- the plate is oriented such that there are two large holes 535 a,b located at the top of the plate. If the plate is installed vertically into the electrolytic unit 232 of FIG. 2A so that the two large holes 535 a,b are at the top, the plate will function as a neutral plate. Thus, the orientation depicted in FIG. 5 is referred to as the neutral orientation.
- the neutral orientation is that, in the embodiment discussed, the anode insert 222 and cathode insert 221 which pass through the top of the plates are 1 ⁇ 4 inch in diameter and the large holes 535 a,b comprise a diameter of 5 ⁇ 8 of an inch. As such, the 1 ⁇ 4 inch diameter anode insert 222 or cathode insert 221 cannot make contact with the plate because the large holes 535 a,b are too large. Thus, the plate is a neutral plate.
- FIG. 6 is a top view of a plate with an anode orientation in one embodiment. If the plate of FIG. 5 is flipped around a horizontal axis such that the top becomes the bottom, the orientation depicted in FIG. 6 results.
- the anode orientation is an embodiment wherein the small hole 536 is located at the top and is on the right side of the plate.
- the two large holes 535 a,b are located on the bottom of the plate. If the plate is installed into the electrolytic unit 232 in FIG. 2A , the plate will make contact with the anode insert 222 and/or the anode spacers 226 , 225 .
- the small hole 536 has a diameter, in one embodiment of about 1 ⁇ 4 of an inch.
- the anode insert 222 has a diameter of 1 ⁇ 4 inch, the anode insert 222 and or the anode spacers 225 , 226 are sufficiently close to the 1 ⁇ 4 inch small hole 536 to make electrical contact with the plate.
- Electrical contact is sufficient contact to allow electricity to be conducted through the contacting surfaces. In one embodiment, electrical contact is sufficient contact to avoid any shorts.
- the spacers are solidly cinched tightly by the insert to provide electrical contact. Thus, in one embodiment the insert is tightened to allow the spacers to pinch down upon the plate. This electrical contact makes this plate an anode plate. The remaining large holes 535 a - c are too large to make contact with the cathode insert 221 or anything else.
- the only conductive material which makes contact with the anode plate is the anode insert 222 and/or the anode spacers 226 , 225 , discussed below.
- the same plate can be used for both the neutral and the anode plates.
- the same material which acts as a neutral plate also acts as an anode plate.
- the neutral plate and the anode plate comprise stainless steel.
- the neutral plate and the anode plate are indistinguishable. This is a significant advantage during manufacturing as it reduces costs. Because the same plate can be used as a neutral plate and an anode plate, a smaller number of custom parts must be designed and built. Further, having uniform parts has several other benefits including ease and consistency of manufacturing. When manufacturing the electrolytic unit 232 the plates simply need to be oriented in the desired position prior to installation.
- FIG. 7 is a top view of a plate with a cathode orientation in one embodiment.
- the cathode orientation has two large holes 535 a,b at the bottom and a small hole 536 located at the top left. This is the cathode orientation because, in the embodiment depicted, the cathode is on the left. If, however, the cathode was on the right side of the electrolysis unit 232 , then the cathode orientation would depict the small hole 636 being located on the right side. If the plate is installed into the electrolytic unit 232 in FIG. 2A , the plate will make contact with the cathode insert 221 and or the cathode spacers 224 , 223 .
- the small hole 536 has a diameter, in one embodiment of about 1 ⁇ 4 of an inch. Because the cathode insert 221 has a diameter of 1 ⁇ 4 inch, the cathode insert 221 and or the cathode spacers 224 , 223 are sufficiently close to the 1 ⁇ 4 inch small hole 536 to make electrical contact with the plate. This makes this plate a cathode plate. The remaining large holes 535 a - c are too large to make contact with the anode insert 221 or anything else. The only conductive material which makes electrical contact with the cathode plate is the cathode insert 221 and/or the cathode spacers 224 , 223 . As noted above, in one embodiment the cathode plate comprises titanium steel.
- all plates including neutral, cathode, and anode plates, have approximately the same dimensions. This provides uniformity and efficiency to the electrolytic unit 232 . Further, such uniformity simplifies the manufacturing process.
- the cathode 103 and anode 104 electrodes are depicted.
- the cathode 103 and anode 104 electrodes are coupled respectively via a cathode screw 218 and an anode screw 219 .
- the same material is used in both the plates and the screws.
- the cathode screw 218 comprises titanium steel whereas the anode screw 219 comprises stainless steel. This is not limiting as any conductive material can be utilized.
- the cathode 218 and anode 219 screws have a diameter of about 1 ⁇ 4 inch.
- the cathode screw 218 is shorter than the anode screw 219 .
- the cathode screw 218 and the anode screw 219 have different lengths. The reason for this is that this ensures the cathode side is offset from the anode side. This will be discussed in more detail below.
- Adjacent to the cathode 218 and anode 219 screws is a non-conductive flat washer 227 .
- the same type of non-conductive flat washer 227 is used for both the cathode side and the anode side.
- the non-conductive flat washer 227 provides an additional buffer for the electrodes.
- the non-conductive flat washer 227 has hole with a diameter of about 3 ⁇ 8 of an inch.
- the non-conductive flat washer 227 fits around the cathode short spacer 224 which is coupled to the cathode screw 218 .
- the cathode short spacer 224 is the same material as the cathode screw 218 .
- the cathode short spacer 224 has internal threads and an outer diameter of 3 ⁇ 8 of an inch.
- the cathode insert 221 couples to the cathode short spacer 224 .
- the cathode insert 221 comprises the same material as the cathode screw 218 .
- the cathode insert 221 comprises external threads and a diameter of about 1 ⁇ 4 of an inch.
- the cathode insert 221 comprises an Allen screw. An Allen screw can be tightened to shorten the distance between the cathode short spacer 224 and a cathode long spacer 223 , which is similar to the cathode short spacer 224 just longer.
- the cathode insert 221 By closing the gap between the cathode short 224 and long 223 spacers, the cathode insert 221 causes the spacers to pinch and make electrical contact with the cathode plate 216 a . This contact makes the cathode plate 216 a conductive to allow for electrolysis.
- the cathode long spacer 223 is coupled to an additional cathode insert 221 , which couples to an additional cathode long spacer 223 .
- the second cathode insert 221 causes the second cathode plate 216 b to make electrical contact with either the cathode insert 221 , the cathode long spacers 223 , or combinations thereof. This causes the second cathode plate 216 b to become conductive.
- the anode side works in a similar fashion with the anode inserts 222 , the anode long spacer 226 , and the anode short spacer 225 .
- the short and long anode spacers are arranged to ensure that they meet at a conductive plate.
- the anode short 225 and the anode long 226 spacers meet at the anode plates 217 a,b.
- the neutral plate 215 does not make contact with either the cathode or anode spacers, inserts, or screws.
- the first neutral plate 215 makes contact with a non-conducting stepped washer 228 .
- the non-conducting stepped washer 228 can comprise any non-conductive material.
- the stepped washer 228 comprises a hole with a diameter of 3 ⁇ 8 of an inch so that it can fit around the spacers.
- the stepped washer comprises two dissimilar outer diameters: a first outer diameter on top and a second outer diameter at a lower portion. In one embodiment the second outer diameter is smaller than the first outer diameter.
- the second outer diameter is about 5 ⁇ 8 of an inch whereas the first outer diameter is greater than 5 ⁇ 8 of an inch.
- the stepped washer 228 acts as an insulating barrier preventing the neutral plate from making contact with the screw, insert, or spacer.
- the stepped washer 228 operates in the same fashion on the anode side.
- above each neutral plate is a stepped washer 228 .
- the stepped washer 228 also has an advantage of increasing stability of the plates. For example, refer to the stepped washer 228 above the first neutral plate on the cathode side.
- the top portion of the stepped washer 228 fits around the cathode short spacer 224 .
- the second lower portion due to the shorter outer diameter, fits within the hole in the neutral plate.
- the stepped washer 228 fills the void that would otherwise exist in the space between the neutral plate and the non-conducting rod 230 at the location of the large hole 535 a,b,c . Filling the voids prevents the neutral plate from having the space to move.
- the stepped washer 228 increases the stability of the plates. Increasing the stability of the plates helps maintain the desired spacing between plates.
- the stepped washer 228 comprises a thickness of about 1 ⁇ 8 of an inch. Such a thickness results in a separation between plates of about 1 ⁇ 8 of an inch. As noted, uniformity increases efficiency of electrolysis and efficiency of manufacturing. In other embodiments the separation between plates ranges from about 1/16 of an inch to 1 ⁇ 4 of an inch. A spacing of about 1 ⁇ 8 of an inch controls the amperage draw at each junction. If the spacing it too low, the plates use too much power to make the optimal amount of gas and the effectiveness of the dampening neutral plates is decreased. If the spacing is too great, the plates fail to utilize the energy correctly and production of gas decreases.
- the second neutral plate also has a stepped washer 228 preventing the neutral plate from making contact with any other conducting material.
- the third plate is the first cathode plate 216 a .
- the cathode plate 216 a makes electrical contact with the cathode spacers 223 , 224 and/or the cathode insert 221 .
- the small hole 536 is located on the cathode side such that electrical contact is made.
- a stepped washer 228 is not utilized as a stepped washer 228 would not fit within the small hole 536 .
- a stepped washer 228 is not utilized. Instead, a flat washer 227 is utilized above the first cathode plate 216 a .
- the flat washer 227 comprises a thickness of about 1 ⁇ 8 of an inch resulting in a separation of about 1 ⁇ 8 of an inch between the third plate, the first cathode plate 216 a , and the fourth plate, a neutral plate.
- the fourth and fifth plates are neutral plates.
- a cathode plate 216 a,b and an anode plate 217 a,b are separated by two neutral plates.
- the number of neutral plates has several effects on the electrolysis.
- the number and spacing of the neutral plates can be adjusted to control these factors.
- the every neutral plate, with a 1 ⁇ 8 of an inch spacing results in a drop of between about 2-2.5 Amps.
- additional neutral plates can be utilized, in one embodiment, this results in decreased gas production.
- the fourth and fifth plates are assembled as previously discussed with each being topped by a stepped washer 228 .
- the sixth plate is the first anode plate 217 a . Due to its orientation, the small hole 536 is positioned so that it is located where the two anode long spacers 226 meet. Above the first anode plate 217 a is a flat washer 227 .
- the remainder of the electrolytic unit 232 is assembled as discussed.
- the spacers are capped with a non-conducting screw 220 which screws into the spacer.
- the non-conducting screw 220 is coupled to a non-conducting stepped washer 228 . If a conducting screw were utilized as a cap, undesirable electrolysis could occur.
- the non-conducting screw 220 helps prevent unwanted electrolysis.
- non-conducting screws 220 and electrode buffer plate 212 which serve to ensure that unwanted electrolysis is minimized or eliminated.
- the desirable electrolysis occurs only between cathode and anode plates.
- the electrolysis is confined between the third plate, the first cathode plate 216 a , and the twelfth plate, the second anode plate 217 b .
- the electrolysis occurs between the first cathode plate 216 a and the first anode plate 217 a . It also occurs between the first anode plate 217 a and the second cathode plate 216 b . Finally, it also occurs between the second cathode plate 216 b and the second anode plate 217 b .
- all other electrolysis is minimized or eliminated. In one embodiment greater than 95% of all electrolysis occurs in the desired location.
- FIG. 4 is a cross-sectional view of the electrolytic unit in FIG. 2A .
- Perpendicular to the plates is the non-conducting rod 230 .
- the non-conducting rod comprises a diameter of about 1 ⁇ 4 of an inch.
- the non-conducting rod 230 as depicted, is at the bottom of the plate whereas the cathodes and anodes are at the top of the plate.
- the non-conducting rod 230 serves to support the plates and maintain the desired separation.
- the non-conducting rod 230 is optional, and in some embodiments is not utilized. While FIG. 4 depicts two non-conducting rods 230 this is not limiting. In some embodiments a single non-conductive rod 230 is utilized, or as noted above, in some embodiments no non-conductive rods 230 are utilized.
- the front end of the non-conducting rod 230 is secured to the outside of the first plate by a non-conducting nut 231 and a non-conducting flat washer 239 .
- a non-conducting flat washer 239 with an opening of 1 ⁇ 4 of an inch is utilized.
- the back end of the non-conducting rod 230 is secured to the outside of the final neutral plate by a non-conducting nut 231 and a non-conducting stepped washer 237 .
- the non-conducting stepped washer 237 acts similar to the non-conducting stepped washer 228 previously discussed.
- the non-conducting stepped washer 237 used for the non-conducting rod 230 comprises a hole of about 1 ⁇ 4 of an inch so as to fit around the non-conducting rod 230 .
- the stepped washer 237 increases the stability of the plates and helps maintain uniform separation. While stepped washers 237 have been discussed, in other embodiments flat washers can also be utilized.
- each neutral plate on the anode side will comprise a flat non-stepped washer 239 .
- the flat non-stepped washer 239 is similar to the flat washer 227 previously discussed.
- the flat non-stepped washer 239 comprises a hole of about 1 ⁇ 4 of an inch so as to fit around the non-conducting rod 230 .
- each cathode plate and each anode plate has a large hole 235 a,b at the location of the non-conducting rod 230 . This is a result of the cathode and anode orientation which ensure the small hole 236 aligns with either the anode insert 222 or cathode insert 221 .
- FIGS. 2-4 show a two cell, fourteen plate embodiment, this is for illustrative purposes and should not be deemed limiting.
- a single cell electrolytic unit 232 is utilized.
- the single cell unit comprises 8 plates: one anode plate, one cathode plate, and six neutral plates.
- the first two plates are neutral, followed by a cathode plate, followed by two neutral plates, followed by an anode plate, and finally capped with two neutral plates.
- a five cell unit is utilized.
- the five cell unit comprises
- 30 total plates This includes five cathode plates, five anode plates, and twenty neutral plates.
- the number of cells and plates is limited only by the size in which the unit can be utilized as well as the power which can be delivered to the unit.
- a spacing of about 1 ⁇ 8 of an inch with two neutral plates between conducting plates provides efficient gas production. If the quantity of neutral plates is increased, the amp draw and cell temperature decreases, and accordingly, so does the gas production. With two neutral plates, the temperature is increased, compared to two, but the increased temperature can be decreased with a cooler as discussed above.
- the amount of hydrogen based fuel produced by the system is dependent upon several factors including number of cells, number of plates, materials of the plates, power supplied to the system, etc.
- the system produces between about 5-6 L of gas per minute.
- a majority of the gas produced comprises ortho-hydrogen.
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Abstract
A method and system for electrolysis. The system includes an electrolytic cell which has a front end and a back end. The front end has a cathode electrode coupled to a cathode screw, and an anode electrode coupled to an anode screw. The screws are coupled to a spacer, which is coupled to an insert. Each insert is further coupled to a second insert. The coupling results in the plate being conductive. The plates each have at least two holes, a large hole and a small hole. The small hole makes contact with a spacer and/or an insert.
Description
- This application claims the benefit of U.S. Provisional Application No. 61/773,686 entitled “Method and System for Electrolysis,” filed Mar. 6, 2013, the entirety of which is incorporated herein by reference.
- 1. Techinical Field
- The present invention relates to a system and apparatus for electrolysis.
- 2. Description of Related Art
- Carbon based fuels, such as so-called fossil fuels, are in high demand. However, the supply is finite. As such, industry is seeking for ways to maximize or increase the efficiency of these fossil fuels. Consequently, it is desirable to have a method to produce a fuel which does not originate from fossil fuels.
- The novel features believed characteristic of the invention are set forth in the appended claims. The invention itself, however, as well as a preferred mode of use, further objectives and advantages thereof, will be best understood by reference to the following detailed description of illustrative embodiments when read in conjunction with the accompanying drawings, wherein:
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FIG. 1 is a depiction of a system in one embodiment; -
FIG. 2A is a perspective view of a two cell electrolytic unit in one embodiment; -
FIG. 2B is a perspective view of a chamber in one embodiment; -
FIG. 3 is a cross-sectional view of the electrolytic unit inFIG. 2A ; -
FIG. 4 is a cross-sectional view of the electrolytic unit inFIG. 2A ; -
FIG. 5 is a top view of a plate with a neutral orientation; -
FIG. 6 is a top view of a plate with an anode orientation; -
FIG. 7 is a top view of a plate with a cathode orientation. - Several embodiments of Applicant's invention will now be described with reference to the drawings. Unless otherwise noted, like elements will be identified by identical numbers throughout all figures. The invention illustratively disclosed herein suitably may be practiced in the absence of any element which is not specifically disclosed herein.
- In one embodiment, electrolysis is utilized to produce a hydrogen based fuel. A hydrogen based fuel, as used herein, refers to a fuel whose primary element is hydrogen. The fuel produced can vary depending upon the materials utilized. For example, the hydrogen based fuel produced can comprise hydrogen gas, ortho-hydrogen, para-hydrogen, and combinations thereof.
- The hydrogen based fuel can be fed to an engine for power or collected and stored. In one embodiment the hydrogen based fuel produced is provided as the primary source of fuel. In other embodiments, however, the fuel produced is used to supplement a primary fuel source. For example, an engine's primary fuel source may comprise gasoline or diesel, but the engine can be supplemented with hydrogen based fuel. The supplemental fuel can result in increased power, increased efficiency, for example in terms of miles per gallon of fuel, and combinations thereof.
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FIG. 1 is a depiction of a system in one embodiment. As depicted thesystem 100 comprises areservoir 107 coupled to anengine 110. As noted above, the engine can comprise a diesel engine, gasoline engine, natural gas engine, and virtually any type of engine which burns carbon based fuels. - The
reservoir 107 comprises a level of liquid. In one embodiment the liquid comprises water and electrolytes. In one embodiment the water comprises distilled water. An electrolyte is a substance containing free ions which are the carriers of electric current. Pure distilled water is not electrically conductive, and thus impurities or other solids are needed to make water electrically conductive. Electrolytes within the water make water electrically conductive. - Virtually any type of electrolyte can be utilized. Possible electrolytes include, but are not limited to, potassium hydroxide, sodium hydroxide, acids, bases, and salts. During hydrolysis, the bond between the oxygen and hydrogen in the water molecule is broken with electrical energy, releasing hydrogen gas, oxygen gas, hydrogen based fuels, and combinations thereof. Thus, the amount of water in the system decreases over time as the water is converted into a gas. However, the electrolytes, provided there are no leaks in the system, do not otherwise leave the system. Accordingly, electrolytes, once added to the reservoir, do not require frequent replacement. In one embodiment, the fluid comprising electrolytes is acidic.
- The concentration of the electrolytes within the fluid can vary. In one embodiment, the amount of electrolytes is related to the amps being drawn by the electrolytic cell from the power source. In one embodiment with a small engine and a limited alternator, the unit draws about 35 amps. In other embodiments utilizing an oil field generator or a ship engine, as an example, the amps can be as high as between 85 and about 105 amps. In such embodiments, there is virtually unlimited available power coming from an on-site mega watt generator. The electrolyte concentration, the pH, and the temperature of the fluid all have an effect on electrolysis. Consequently, in one embodiment, one or more of these factors are monitored and/or controlled.
- The material which makes contact with the liquid in the
reservoir 107 can comprise a variety of materials as discussed above. In one embodiment, thereservoir 107, thepump 108 housing, and the connecting lines comprise polypropylene or other material which is impervious to the acidic conditions of the liquid. - The
reservoir 107 is coupled to apump 108. The size of the reservoir can vary depending on relative space as well as fuel requirements. In one embodiment the reservoir ranges from about 3 quarts to about 50 gallons. Thepump 108 can comprise any type of pump known in the art. In one embodiment thepump 108 comprises a 12 or 24 Volt DC pump. In one embodiment thepump 108 comprises housing and an impeller made from polypropylene which is impervious to acid. In one such embodiment, thepump 108 comprises a magnet which connects the impeller to the motor so that the motor will not be subject to the liquid within the pump housing. In one embodiment, no electrical parts of thepump 108 come into contact with the liquid in the pump housing. Thepump 108, as depicted, is located upstream of thechamber 101, and downstream of thereservoir 107. The flow rates of thepump 108 can vary depending on the application. The flow rates can range from 0.5 gallons per minute to about 6 gallons per minute. In one embodiment the flow rates range from about 1.3 gallons per minute to about 3.5 gallons per minute. - In one embodiment the
system 100 further comprises a cooler 109. Electrolysis produces heat, and that heat must be removed to prevent overheating thesystem 100. Overheating thesystem 100 increases part degradation. The cooler 109 can be located upstream or downstream of thepump 108. The cooler 109 can comprise virtually any type of cooler including but not limited to a radiator fin cooler, a single or double pass heat exchanger, a chiller, etc. The cooler 109 moderates and maintains a desired temperature. In one embodiment the temperature of the liquid ranges from between about 80° to about 200° F. or greater. In one embodiment the temperature of the liquid ranges from between about 95° to about 120° F. - Fluid is pumped into the
chamber 101 via achamber inlet 106. Thechamber inlet 106 can couple with thechamber 101 at any point. In one embodiment thechamber inlet 106 couples to the bottom of thechamber 101 whereas in other embodiments thechamber inlet 106 couples to the side of thechamber 101. Thechamber 101, discussed in detail below, is the location wherein the electrolysis occurs. In one embodiment thechamber 101 is filled with liquid. In one embodiment thechamber 101 is completely filled with liquid such that all parts are submerged. - The
chamber 101 is connected to apower source 102. Thepower source 102 can comprise virtually any power source including a battery or even AC power. Thepower source 102 is coupled to thechamber 101 via acathode electrode 103 and ananode electrode 104. - Downstream of the
chamber 101 is thechamber outlet 105. Thechamber outlet 105 couples thechamber 101 to thereservoir 107. As depicted, in one embodiment the system flows clockwise from thereservoir 107 to thepump 108, to the cooler 109, to thechamber 101, and back to thereservoir 107. For ease of reference an object clockwise of an object will be referred to as downstream. Thus, as depicted, thepump 108 is downstream of thereservoir 107. Conversely, as depicted, thepump 108 is upstream of thechamber 101. - As noted, during electrolysis in the
chamber 101, a mixture of gas is produced. The gas and liquid mixture exits thechamber 101 through thechamber outlet 105. Thechamber outlet 105 can couple to thereservoir 107 at virtually any location including the bottom, top, and side. - Once within the
reservoir 107, the gas and liquid separate and the gas raises to the top of thereservoir 107 through thegas outlet 133. In one embodiment there is no pressure in thereservoir 107. In other embodiments, however, thereservoir 107 can withstand pressures as high as 30 psi. As noted, in one embodiment thegas outlet 133 is connected to anengine 110. In other embodiments thegas outlet 133 is coupled to a storage container wherein the hydrogen based fuel is stored. - In one embodiment the
system 100 further comprises a filter (not shown). Degradation of materials, solids in the water, electrolytes, etc. result in fine solid particles which are present in the fluid. In one embodiment, if these solids are not removed, they can plug the plates resulting in decreased efficiency. A filter helps remove these fine particles. In one embodiment the filter comprises a 2 micron or less filter. In another embodiment, the filter comprises a 0.5 micron polypropylene filter. Such a filter is impervious to the often acidic conditions and thus does not degrade. The filter traps these small impurities so they can be removed from the system. -
FIG. 2A is a perspective view of a two-cell electrolytic unit in one embodiment.FIG. 2B is a perspective view of a chamber in one embodiment. Theelectrolytic unit 232 ofFIG. 2A fits within thechamber cover 229. As can be seen from bothFIG. 2A andFIG. 2B , theelectrolytic unit 232 comprises acathode electrode 103 and ananode electrode 104. Virtually any type of electrode can be utilized. In one embodiment thecathode electrode 103 comprises titanium steel and theanode electrode 104 comprises stainless steel. As noted above, the types of materials utilized during electrolysis dictate, in part, which hydrogen-based fuel is produced. Titanium results in ortho-hydrogen, a very powerful fuel, being produced. Further, titanium is not susceptible to the acidic properties of the electrolyte and does not become sacrificial. Other materials which can be utilized include, but are not limited to, gold, platinum, nickel, and silver. - As seen in
FIG. 2B , the electrodes stick up out of thechamber cover 229. This allows the power source to couple to thechamber 101. Thechamber cover 229 can comprise any non-conductive material. As used herein, a non-conductive material is a material that resists the flow of electric charge, also called a dielectric, as is well known to one skilled in the art. Non-conductive materials include plastics such as ABS plastics, nylon, polypropylene etc. Virtually any material which can withstand temperatures of 200° F. and which are impervious to acid can be utilized as the non-conductive material. Also seen is theoutlet adapter 134. Theoutlet adapter 134 couples with thechamber outlet 105. In one embodiment theoutlet adapter 134 is non-conductive. -
FIG. 2B also illustrates anon-conductive washer 113 which sits between the top of thechamber cover 229 and the electrodes. - As depicted, the electrodes are on the right side of the
chamber 101. For reference purposes, the side closest to the electrodes will be referred to as the front side. The side opposite of the front side is referred to as the back side. - Turning back to
FIG. 2A , the figure illustrates theelectrode buffer plate 212. Thisbuffer plate 212 serves as a buffer between the electrodes and thefirst plate 214. Thebuffer plate 212 is non-conductive, and in one embodiment comprises a thickness of about ⅛ of an inch and two holes each with a diameter of about ⅜ of an inch through which one cathode screw and one anode screw will be inserted. - As depicted the
electrolytic unit 232 comprises 14 plates and two cells. This will be discussed in more detail below and should not be deemed limiting. -
FIG. 3 is a cross-sectional view of the electrolytic unit inFIG. 2A . As can be seen inFIG. 3 , there are 14 plates. As depicted, there are tenneutral plates 215. Theneutral plates 215 can comprise virtually any conductive material including but not limited to stainless steel, 304, 316, 440 and other grades of stainless steel. Stainless steel, and the various grades, have a benefit of not degrading in the electrolyte solution. In one embodiment theneutral plates 215 are not connected to any conductive piece. Theneutral plates 215 serve to control the rate of electrolysis, control the amperage within thesystem 100, minimize temperature, and minimize degradation. - In one embodiment, and as depicted, the first plate is a
neutral plate 215. Thefirst plate 215 is the plate which is closest in proximity to thecathode 218 andanode 219 screws. Thus, the first plate is the plate closest to the front side. The plates are numbered numerically beginning at the plates closest to the location of the electrodes, the front side. In one embodiment, and as depicted, the first two plates areneutral plates 215. When the first plate, or first two plates, areneutral plates 215, this allows a buffer between the first conductive plate, either titanium or stainless steel as depicted, and thecathode screw 218 andanode screw 219. Theneutral plates 215 creates a buffer so that the electrolysis is isolated and occurs only where it is designed and desired to occur, namely, between two conductive plates. Minimizing or eliminating unwanted electrolysis, or any electrolysis which does not occur between two conductive plates, maximizes the efficiency of the desired electrolysis and reduces erosion of materials. If the first plate were not neutral, then even with theelectrode buffer plate 212, undesirable electrolysis occurs between conductive plates and parts such as thecathode screw 218, for example, causing wear on thecathode screw 218. Thus, in one embodiment one or moreneutral plates 215 are adjacent to the front side. As noted, this improves electrolysis efficiency while minimizing part degradation. - Turning briefly to
FIG. 5 ,FIG. 5 is a top view of a plate in a neutral orientation in one embodiment. As can be seen theplate 214 comprises fourholes 535 a-c, 536 which are adjacent to the corners of the plate. In one embodiment the plate is six inches long, 3.5 inches wide, and between about 0.01-0.06 inches thick. In another embodiment the plate is between about 0.028 and 0.032 inches thick. The thickness and other dimensions are provided for illustrative purposes only and should not be deemed limiting. Additionally, while the shape is provided as rectangular other shapes can be utilized. - As depicted the plate comprises three
large holes 535 a-c of the same diameter and onesmall hole 536 of a smaller different diameter. In one embodiment thelarge holes 535 a-c comprise a diameter of about ⅝0 of an inch. In one embodiment thesmall hole 536 comprises a diameter of about ¼ inch. While specific diameters are discussed, it should be understood that this is for illustrative purposes as other diameters can be successfully utilized. Further, as will be discussed, in one embodiment theanode insert 222 andcathode insert 221 which passes perpendicular through the plates comprise a diameter of about ¼ inch, and this is why, in the embodiment discussed, thesmall hole 536 has a diameter of ¼ inch. If the diameter of theanode insert 222 andcathode insert 221 changes, so too would the diameter of thesmall hole 536. - As depicted, the plate is oriented such that there are two
large holes 535 a,b located at the top of the plate. If the plate is installed vertically into theelectrolytic unit 232 ofFIG. 2A so that the twolarge holes 535 a,b are at the top, the plate will function as a neutral plate. Thus, the orientation depicted inFIG. 5 is referred to as the neutral orientation. The reason for this is that, in the embodiment discussed, theanode insert 222 andcathode insert 221 which pass through the top of the plates are ¼ inch in diameter and thelarge holes 535 a,b comprise a diameter of ⅝ of an inch. As such, the ¼ inchdiameter anode insert 222 orcathode insert 221 cannot make contact with the plate because thelarge holes 535 a,b are too large. Thus, the plate is a neutral plate. - Turning to
FIG. 6 ,FIG. 6 is a top view of a plate with an anode orientation in one embodiment. If the plate ofFIG. 5 is flipped around a horizontal axis such that the top becomes the bottom, the orientation depicted inFIG. 6 results. The anode orientation is an embodiment wherein thesmall hole 536 is located at the top and is on the right side of the plate. The twolarge holes 535 a,b are located on the bottom of the plate. If the plate is installed into theelectrolytic unit 232 inFIG. 2A , the plate will make contact with theanode insert 222 and/or theanode spacers small hole 536 has a diameter, in one embodiment of about ¼ of an inch. Because theanode insert 222 has a diameter of ¼ inch, theanode insert 222 and or theanode spacers small hole 536 to make electrical contact with the plate. Electrical contact, as used herein, is sufficient contact to allow electricity to be conducted through the contacting surfaces. In one embodiment, electrical contact is sufficient contact to avoid any shorts. In one embodiment, the spacers are solidly cinched tightly by the insert to provide electrical contact. Thus, in one embodiment the insert is tightened to allow the spacers to pinch down upon the plate. This electrical contact makes this plate an anode plate. The remaininglarge holes 535 a-c are too large to make contact with thecathode insert 221 or anything else. The only conductive material which makes contact with the anode plate is theanode insert 222 and/or theanode spacers - It can be seen that the same plate can be used for both the neutral and the anode plates. Thus, in one embodiment the same material which acts as a neutral plate also acts as an anode plate. In one embodiment, the neutral plate and the anode plate comprise stainless steel.
- In one embodiment, aside from the orientation, the neutral plate and the anode plate are indistinguishable. This is a significant advantage during manufacturing as it reduces costs. Because the same plate can be used as a neutral plate and an anode plate, a smaller number of custom parts must be designed and built. Further, having uniform parts has several other benefits including ease and consistency of manufacturing. When manufacturing the
electrolytic unit 232 the plates simply need to be oriented in the desired position prior to installation. - Turning to
FIG. 7 ,FIG. 7 is a top view of a plate with a cathode orientation in one embodiment. As depicted, the cathode orientation has twolarge holes 535 a,b at the bottom and asmall hole 536 located at the top left. This is the cathode orientation because, in the embodiment depicted, the cathode is on the left. If, however, the cathode was on the right side of theelectrolysis unit 232, then the cathode orientation would depict the small hole 636 being located on the right side. If the plate is installed into theelectrolytic unit 232 inFIG. 2A , the plate will make contact with thecathode insert 221 and or thecathode spacers small hole 536 has a diameter, in one embodiment of about ¼ of an inch. Because thecathode insert 221 has a diameter of ¼ inch, thecathode insert 221 and or thecathode spacers small hole 536 to make electrical contact with the plate. This makes this plate a cathode plate. The remaininglarge holes 535 a-c are too large to make contact with theanode insert 221 or anything else. The only conductive material which makes electrical contact with the cathode plate is thecathode insert 221 and/or thecathode spacers - In one embodiment all plates, including neutral, cathode, and anode plates, have approximately the same dimensions. This provides uniformity and efficiency to the
electrolytic unit 232. Further, such uniformity simplifies the manufacturing process. - Turning back to
FIG. 3 , thecathode 103 andanode 104 electrodes are depicted. Thecathode 103 andanode 104 electrodes are coupled respectively via acathode screw 218 and ananode screw 219. In one embodiment, the same material is used in both the plates and the screws. For example, in one embodiment thecathode screw 218 comprises titanium steel whereas theanode screw 219 comprises stainless steel. This is not limiting as any conductive material can be utilized. In one embodiment thecathode 218 andanode 219 screws have a diameter of about ¼ inch. - It can be seen that the
cathode screw 218 is shorter than theanode screw 219. Thus, in one embodiment thecathode screw 218 and theanode screw 219 have different lengths. The reason for this is that this ensures the cathode side is offset from the anode side. This will be discussed in more detail below. - Adjacent to the
cathode 218 andanode 219 screws is a non-conductiveflat washer 227. In one embodiment the same type of non-conductiveflat washer 227 is used for both the cathode side and the anode side. The non-conductiveflat washer 227 provides an additional buffer for the electrodes. - In one embodiment the non-conductive
flat washer 227 has hole with a diameter of about ⅜ of an inch. Thus, as depicted, the non-conductiveflat washer 227 fits around the cathodeshort spacer 224 which is coupled to thecathode screw 218. In one embodiment the cathodeshort spacer 224 is the same material as thecathode screw 218. In one embodiment the cathodeshort spacer 224 has internal threads and an outer diameter of ⅜ of an inch. - Coupled to the cathode
short spacer 224 is acathode insert 221. Thecathode insert 221, in one embodiment, comprises the same material as thecathode screw 218. In one embodiment thecathode insert 221 comprises external threads and a diameter of about ¼ of an inch. In one embodiment thecathode insert 221 comprises an Allen screw. An Allen screw can be tightened to shorten the distance between the cathodeshort spacer 224 and a cathodelong spacer 223, which is similar to the cathodeshort spacer 224 just longer. By closing the gap between the cathode short 224 and long 223 spacers, thecathode insert 221 causes the spacers to pinch and make electrical contact with thecathode plate 216 a. This contact makes thecathode plate 216 a conductive to allow for electrolysis. - Because the depicted
electrolysis unit 232 is a two cell unit, the cathodelong spacer 223 is coupled to anadditional cathode insert 221, which couples to an additional cathodelong spacer 223. Thesecond cathode insert 221 causes thesecond cathode plate 216 b to make electrical contact with either thecathode insert 221, the cathodelong spacers 223, or combinations thereof. This causes thesecond cathode plate 216 b to become conductive. - The anode side works in a similar fashion with the anode inserts 222, the anode
long spacer 226, and the anodeshort spacer 225. The short and long anode spacers are arranged to ensure that they meet at a conductive plate. Thus, the anode short 225 and the anode long 226 spacers meet at theanode plates 217 a,b. - Starting again at the first
neutral plate 215, as noted because of thelarge holes 535 a,b, the neutral plate does not make contact with either the cathode or anode spacers, inserts, or screws. Referring to the cathode side, the firstneutral plate 215 makes contact with a non-conducting steppedwasher 228. The non-conducting steppedwasher 228 can comprise any non-conductive material. In one embodiment the steppedwasher 228 comprises a hole with a diameter of ⅜ of an inch so that it can fit around the spacers. In one embodiment the stepped washer comprises two dissimilar outer diameters: a first outer diameter on top and a second outer diameter at a lower portion. In one embodiment the second outer diameter is smaller than the first outer diameter. In one embodiment the second outer diameter is about ⅝ of an inch whereas the first outer diameter is greater than ⅝ of an inch. These dimensions allow the washer to both sit above theneutral plate 215 and sit adjacent to the firstneutral plate 215 between the firstneutral plate 215 and a spacer. In this fashion, the steppedwasher 228 acts as an insulating barrier preventing the neutral plate from making contact with the screw, insert, or spacer. The steppedwasher 228 operates in the same fashion on the anode side. In one embodiment, above each neutral plate is a steppedwasher 228. The steppedwasher 228 also has an advantage of increasing stability of the plates. For example, refer to the steppedwasher 228 above the first neutral plate on the cathode side. The top portion of the steppedwasher 228, the portion with the larger outer diameter, fits around the cathodeshort spacer 224. The second lower portion, due to the shorter outer diameter, fits within the hole in the neutral plate. Thus, the steppedwasher 228 fills the void that would otherwise exist in the space between the neutral plate and thenon-conducting rod 230 at the location of thelarge hole 535 a,b,c. Filling the voids prevents the neutral plate from having the space to move. As such, the steppedwasher 228 increases the stability of the plates. Increasing the stability of the plates helps maintain the desired spacing between plates. - The various washers dictate the separation between plates. Thus, in one embodiment the stepped
washer 228 comprises a thickness of about ⅛ of an inch. Such a thickness results in a separation between plates of about ⅛ of an inch. As noted, uniformity increases efficiency of electrolysis and efficiency of manufacturing. In other embodiments the separation between plates ranges from about 1/16 of an inch to ¼ of an inch. A spacing of about ⅛ of an inch controls the amperage draw at each junction. If the spacing it too low, the plates use too much power to make the optimal amount of gas and the effectiveness of the dampening neutral plates is decreased. If the spacing is too great, the plates fail to utilize the energy correctly and production of gas decreases. - As can be seen, the second neutral plate also has a stepped
washer 228 preventing the neutral plate from making contact with any other conducting material. The third plate, however, is thefirst cathode plate 216 a. As previously noted, thecathode plate 216 a makes electrical contact with thecathode spacers cathode insert 221. Because of the cathode orientation, thesmall hole 536 is located on the cathode side such that electrical contact is made. As contact is encouraged in this scenario to make thecathode plate 216 a conductive, a steppedwasher 228 is not utilized as a steppedwasher 228 would not fit within thesmall hole 536. Put differently, there is no gap like the gap at the location of thelarge hole 535 a-c as discussed above. Because there is not a gap, a steppedwasher 228 is not utilized. Instead, aflat washer 227 is utilized above thefirst cathode plate 216 a. As noted, in one embodiment theflat washer 227 comprises a thickness of about ⅛ of an inch resulting in a separation of about ⅛ of an inch between the third plate, thefirst cathode plate 216 a, and the fourth plate, a neutral plate. - The fourth and fifth plates, as depicted, are neutral plates. Thus, in one embodiment, a
cathode plate 216 a,b and ananode plate 217 a,b are separated by two neutral plates. As previously noted, the number of neutral plates has several effects on the electrolysis. The number and spacing of the neutral plates can be adjusted to control these factors. In one embodiment, the every neutral plate, with a ⅛ of an inch spacing, results in a drop of between about 2-2.5 Amps. Thus, while additional neutral plates can be utilized, in one embodiment, this results in decreased gas production. - The fourth and fifth plates are assembled as previously discussed with each being topped by a stepped
washer 228. The sixth plate is thefirst anode plate 217 a. Due to its orientation, thesmall hole 536 is positioned so that it is located where the two anodelong spacers 226 meet. Above thefirst anode plate 217 a is aflat washer 227. - The remainder of the
electrolytic unit 232 is assembled as discussed. At the back side of theelectrolytic unit 232, the spacers are capped with anon-conducting screw 220 which screws into the spacer. Thenon-conducting screw 220 is coupled to a non-conducting steppedwasher 228. If a conducting screw were utilized as a cap, undesirable electrolysis could occur. Thenon-conducting screw 220 helps prevent unwanted electrolysis. - As previously noted, there are several features, including
non-conducting screws 220 andelectrode buffer plate 212, which serve to ensure that unwanted electrolysis is minimized or eliminated. In one embodiment the desirable electrolysis occurs only between cathode and anode plates. Thus, inFIG. 3 , the electrolysis is confined between the third plate, thefirst cathode plate 216 a, and the twelfth plate, thesecond anode plate 217 b. The electrolysis occurs between thefirst cathode plate 216 a and thefirst anode plate 217 a. It also occurs between thefirst anode plate 217 a and thesecond cathode plate 216 b. Finally, it also occurs between thesecond cathode plate 216 b and thesecond anode plate 217 b. In one embodiment, all other electrolysis is minimized or eliminated. In one embodiment greater than 95% of all electrolysis occurs in the desired location. -
FIG. 4 is a cross-sectional view of the electrolytic unit inFIG. 2A . Perpendicular to the plates is thenon-conducting rod 230. In one embodiment the non-conducting rod comprises a diameter of about ¼ of an inch. Thenon-conducting rod 230, as depicted, is at the bottom of the plate whereas the cathodes and anodes are at the top of the plate. - The
non-conducting rod 230 serves to support the plates and maintain the desired separation. Thenon-conducting rod 230 is optional, and in some embodiments is not utilized. WhileFIG. 4 depicts twonon-conducting rods 230 this is not limiting. In some embodiments a singlenon-conductive rod 230 is utilized, or as noted above, in some embodiments nonon-conductive rods 230 are utilized. - The front end of the
non-conducting rod 230 is secured to the outside of the first plate by anon-conducting nut 231 and a non-conducting flat washer 239. In an embodiment wherein thenon-conducting rod 230 comprises a diameter of ¼ of an inch, a non-conducting flat washer 239 with an opening of ¼ of an inch is utilized. - The back end of the
non-conducting rod 230 is secured to the outside of the final neutral plate by anon-conducting nut 231 and a non-conducting steppedwasher 237. The non-conducting steppedwasher 237 acts similar to the non-conducting steppedwasher 228 previously discussed. In one embodiment, the non-conducting steppedwasher 237 used for thenon-conducting rod 230 comprises a hole of about ¼ of an inch so as to fit around thenon-conducting rod 230. As previously discussed the steppedwasher 237 increases the stability of the plates and helps maintain uniform separation. While steppedwashers 237 have been discussed, in other embodiments flat washers can also be utilized. - Turning back to the front end, and specifically to the first neutral plate, it can be seen that a stepped
washer 237 is utilized above the neutral plate on the cathode side. However, on the anode side on the first neutral plate, a flat non-stepped washer 239 is utilized. This is because this is the location of thesmall hole 536 in the neutral plate orientation. Thus, as depicted, each neutral plate on the anode side will comprise a flat non-stepped washer 239. The flat non-stepped washer 239 is similar to theflat washer 227 previously discussed. In one embodiment the flat non-stepped washer 239 comprises a hole of about ¼ of an inch so as to fit around thenon-conducting rod 230. - Each plate is added as discussed above and a washer, either stepped or flat, is inserted between to ensure a desired separation between plates. It can be noted that as depicted, each cathode plate and each anode plate has a large hole 235 a,b at the location of the
non-conducting rod 230. This is a result of the cathode and anode orientation which ensure the small hole 236 aligns with either theanode insert 222 orcathode insert 221. - While
FIGS. 2-4 show a two cell, fourteen plate embodiment, this is for illustrative purposes and should not be deemed limiting. In other embodiments a single cellelectrolytic unit 232 is utilized. In one such embodiment the single cell unit comprises 8 plates: one anode plate, one cathode plate, and six neutral plates. In one embodiment the first two plates are neutral, followed by a cathode plate, followed by two neutral plates, followed by an anode plate, and finally capped with two neutral plates. - In one embodiment a five cell unit is utilized. In one such embodiment, the five cell unit comprises
- 30 total plates. This includes five cathode plates, five anode plates, and twenty neutral plates. The number of cells and plates is limited only by the size in which the unit can be utilized as well as the power which can be delivered to the unit.
- As noted above, a spacing of about ⅛ of an inch with two neutral plates between conducting plates, in one embodiment, provides efficient gas production. If the quantity of neutral plates is increased, the amp draw and cell temperature decreases, and accordingly, so does the gas production. With two neutral plates, the temperature is increased, compared to two, but the increased temperature can be decreased with a cooler as discussed above.
- The amount of hydrogen based fuel produced by the system is dependent upon several factors including number of cells, number of plates, materials of the plates, power supplied to the system, etc. In one embodiment utilizing a 12 V car battery, the system produces between about 5-6 L of gas per minute. In one embodiment, a majority of the gas produced comprises ortho-hydrogen.
- While the invention has been particularly shown and described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention.
- The following clauses are offered as further description of the disclosed invention.
- 1. A system for electrolysis, said system comprising an electrolytic unit, wherein said electrolytic unit comprises:
- a front end and a back end;
- a cathode electrode coupled a cathode screw at said front end;
- an anode electrode coupled to an anode screw at said front end;
- a first cathode spacer coupled to said cathode screw;
- a first anode spacer coupled to said anode screw;
- a first cathode insert coupled to said first cathode spacer, said first cathode insert further coupled to a second cathode spacer;
- a first anode insert coupled to said first anode spacer, said first anode insert further coupled to a second anode spacer;
- a first cathode plate comprising at least two holes, wherein said at least two holes comprise at least one large hole and at least one small hole, wherein one of said large holes aligns with but does not make electrical contact with said first anode spacer, wherein said large hole comprises a diameter greater than the diameter of said first anode spacer, wherein said at least one small hole aligns with said first cathode insert so as to make electrical contact with said first cathode insert;
- a first anode plate comprising at least two holes, wherein said at least two holes comprise at least one large hole and at least one small hole, wherein one of said large holes aligns with but does not make electrical contact with said first cathode spacer, wherein said large hole comprises a diameter greater than the diameter of said first cathode spacer, wherein said at least one small hole aligns with said first anode insert so as to make electrical contact with said first anode insert.
- 2. The system according to clause 1 wherein said electrolytic unit comprises a neutral plate, wherein said neutral plate is approximately perpendicular to said cathode screw and said anode screw, wherein said neutral plate is approximately parallel with said first anode plate and said first cathode plate, wherein said neutral plate comprises at least two holes, wherein said first cathode spacer and said first anode spacer are located within said at least two holes.
- 3. The system according to clause 2 wherein said electrolytic unit comprises two neutral plates in front of said first anode plate.
- 4. The system according to clause 2 wherein said electrolytic unit comprises two neutral plates between said first anode plate and said first cathode plate.
- 5. The system according to clause 2 wherein said electrolytic unit comprises first and second neutral plates at the front end, wherein said two neutral plates are followed by said first cathode plate, wherein said first cathode plate is followed by a third and fourth neutral plates, and wherein said third and fourth neutral plates are followed by said first anode plate.
- 6. The system according to clause 5 wherein said first and second neutral plates are separated by a stepped washer, wherein said stepped washer comprises a thickness of about ⅛ of an inch.
- 7. The system according to clause 5 wherein each plate is separated by at least one stepped washer and at least one flat washer, wherein said flat washer is located at said small hole.
- 8. The system according to clause 2 wherein said electrolytic unit comprises two neutral plates at the front end, wherein said two neutral plates are followed by said first anode plate, wherein said first anode plate is followed by two additional neutral plates, and wherein said two additional neutral plates are followed by said first cathode plate.
- 9. The system according to any preceding clause wherein said cathode plate comprises titanium steel.
- 10. The system according to any preceding clause wherein said anode plate comprises stainless steel.
- 11. The system according to clause 2 wherein said plates are separated by about ⅛ of an inch.
- 12. The system according to clause 2 wherein said electrolytic unit further comprises a top end and a bottom end, and a left non-conducting rod and a right non-conducting rod, wherein said cathode screw and said anode screw are located at a top end, and wherein said left non-conducting rod and a right non-conducting rod are located at said bottom end.
- 13. The system according to clause 12 wherein each plate comprises four holes, three large holes and one small hole.
- 14. The system according to clause 12 wherein said first cathode plate comprises four holes, three large holes and one small hole, wherein one of said large holes aligns with said left non-conducting rod, wherein one of said large holes aligns with said right non-conducting rod, wherein one of said large holes aligns with but does not make electrical contact with said first anode spacer.
- 15. The system according to any preceding clause wherein said electrolytic unit is upstream of a reservoir, wherein said electrolytic unit is downstream of a cooler, and wherein said electrolytic unit is downstream of a pump, and wherein said electrolytic unit is electrically coupled to a power source.
- 16. The system according to clause 15 further comprising a filter upstream of said electrolytic unit.
- 17. The system according to clause 16 wherein said filter comprises a 0.5 micron polypropylene filter.
- 18. The system according to clause 15 wherein gas is removed from said reservoir.
- 19. The system according to clause 18 wherein said gas comprises ortho-hydrogen gas.
- 20. The system according to clause 18 wherein 5-6 L/minute of gas is removed from said reservoir.
Claims (20)
1. A system for electrolysis, said system comprising an electrolytic unit, wherein said electrolytic unit comprises:
a front end and a back end;
a cathode electrode coupled a cathode screw at said front end;
an anode electrode coupled to an anode screw at said front end;
a first cathode spacer coupled to said cathode screw;
a first anode spacer coupled to said anode screw;
a first cathode insert coupled to said first cathode spacer, said first cathode insert further coupled to a second cathode spacer;
a first anode insert coupled to said first anode spacer, said first anode insert further coupled to a second anode spacer;
a first cathode plate comprising at least two holes, wherein said at least two holes comprise at least one large hole and at least one small hole, wherein one of said large holes aligns with but does not make electrical contact with said first anode spacer, wherein said large hole comprises a diameter greater than the diameter of said first anode spacer, wherein said at least one small hole aligns with said first cathode insert so as to make electrical contact with said first cathode insert;
a first anode plate comprising at least two holes, wherein said at least two holes comprise at least one large hole and at least one small hole, wherein one of said large holes aligns with but does not make electrical contact with said first cathode spacer, wherein said large hole comprises a diameter greater than the diameter of said first cathode spacer, wherein said at least one small hole aligns with said first anode insert so as to make electrical contact with said first anode insert.
2. The system of claim 1 wherein said electrolytic unit comprises a neutral plate, wherein said neutral plate is approximately perpendicular to said cathode screw and said anode screw, wherein said neutral plate is approximately parallel with said first anode plate and said first cathode plate, wherein said neutral plate comprises at least two holes, wherein said first cathode spacer and said first anode spacer are located within said at least two holes.
3. The system of claim 2 wherein said electrolytic unit comprises two neutral plates in front of said first anode plate.
4. The system of claim 2 wherein said electrolytic unit comprises two neutral plates between said first anode plate and said first cathode plate.
5. The system of claim 2 wherein said electrolytic unit comprises first and second neutral plates at the front end, wherein said two neutral plates are followed by said first cathode plate, wherein said first cathode plate is followed by a third and fourth neutral plates, and wherein said third and fourth neutral plates are followed by said first anode plate.
6. The system of claim 5 wherein said first and second neutral plates are separated by a stepped washer, wherein said stepped washer comprises a thickness of about ⅛ of an inch.
7. The system of claim 5 wherein each plate is separated by at least one stepped washer and at least one flat washer, wherein said flat washer is located at said small hole.
8. The system of claim 2 wherein said electrolytic unit comprises two neutral plates at the front end, wherein said two neutral plates are followed by said first anode plate, wherein said first anode plate is followed by two additional neutral plates, and wherein said two additional neutral plates are followed by said first cathode plate.
9. The system of claim 1 wherein said cathode plate comprises titanium steel.
10. The system of claim 1 wherein said anode plate comprises stainless steel.
11. The system of claim 2 wherein said plates are separated by about ⅛ of an inch.
12. The system of claim 2 wherein said electrolytic unit further comprises a top end and a bottom end, and a left non-conducting rod and a right non-conducting rod, wherein said cathode screw and said anode screw are located at a top end, and wherein said left non-conducting rod and a right non-conducting rod are located at said bottom end.
13. The system of claim 12 wherein each plate comprises four holes, three large holes and one small hole.
14. The system of claim 12 wherein said first cathode plate comprises four holes, three large holes and one small hole, wherein one of said large holes aligns with said left non-conducting rod, wherein one of said large holes aligns with said right non-conducting rod, wherein one of said large holes aligns with but does not make electrical contact with said first anode spacer.
15. The system of claim 1 wherein said electrolytic unit is upstream of a reservoir, wherein said electrolytic unit is downstream of a cooler, and wherein said electrolytic unit is downstream of a pump, and wherein said electrolytic unit is electrically coupled to a power source.
16. The system of claim 15 further comprising a filter upstream of said electrolytic unit.
17. The system of claim 16 wherein said filter comprises a 0.5 micron polypropylene filter.
18. The system of claim 15 wherein gas is removed from said reservoir.
19. The system of claim 18 wherein said gas comprises ortho-hydrogen gas.
20. The system of claim 18 wherein 5-6 L/minute of gas is removed from said reservoir.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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US13/787,662 US20140251794A1 (en) | 2013-03-06 | 2013-03-06 | Method and system for electrolysis |
US14/788,693 US11268197B2 (en) | 2013-03-06 | 2015-06-30 | System and method for producing hydrogen and oxygen gas |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US201361773686P | 2013-03-06 | 2013-03-06 | |
US13/787,662 US20140251794A1 (en) | 2013-03-06 | 2013-03-06 | Method and system for electrolysis |
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US14/788,693 Continuation-In-Part US11268197B2 (en) | 2013-03-06 | 2015-06-30 | System and method for producing hydrogen and oxygen gas |
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US20140251794A1 true US20140251794A1 (en) | 2014-09-11 |
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US13/787,662 Abandoned US20140251794A1 (en) | 2013-03-06 | 2013-03-06 | Method and system for electrolysis |
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EP3699323A1 (en) * | 2019-02-20 | 2020-08-26 | Hymeth ApS | Electrode system |
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