US20120118013A1 - Apparatus and method for separating air by cryogenic distillation - Google Patents

Apparatus and method for separating air by cryogenic distillation Download PDF

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Publication number
US20120118013A1
US20120118013A1 US13/321,993 US201013321993A US2012118013A1 US 20120118013 A1 US20120118013 A1 US 20120118013A1 US 201013321993 A US201013321993 A US 201013321993A US 2012118013 A1 US2012118013 A1 US 2012118013A1
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United States
Prior art keywords
column
condenser
pressure
vaporizer
head
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Abandoned
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US13/321,993
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English (en)
Inventor
Richard Dubettier-Grenier
Marie Cognard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Application filed by LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Assigned to L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE reassignment L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: COGNARD, MARIE, DUBETTIER-GRENIER, RICHARD
Publication of US20120118013A1 publication Critical patent/US20120118013A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04187Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
    • F25J3/04193Division of the main heat exchange line in consecutive sections having different functions
    • F25J3/04206Division of the main heat exchange line in consecutive sections having different functions including a so-called "auxiliary vaporiser" for vaporising and producing a gaseous product
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/0409Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04406Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
    • F25J3/04418Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system with thermally overlapping high and low pressure columns
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04872Vertical layout of cold equipments within in the cold box, e.g. columns, heat exchangers etc.
    • F25J3/04878Side by side arrangement of multiple vessels in a main column system, wherein the vessels are normally mounted one upon the other or forming different sections of the same column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04872Vertical layout of cold equipments within in the cold box, e.g. columns, heat exchangers etc.
    • F25J3/04884Arrangement of reboiler-condensers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04896Details of columns, e.g. internals, inlet/outlet devices
    • F25J3/04915Combinations of different material exchange elements, e.g. within different columns
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/34Processes or apparatus using separation by rectification using a side column fed by a stream from the low pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/50Processes or apparatus using separation by rectification using multiple (re-)boiler-condensers at different heights of the column
    • F25J2200/54Processes or apparatus using separation by rectification using multiple (re-)boiler-condensers at different heights of the column in the low pressure column of a double pressure main column system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2235/00Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
    • F25J2235/50Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/02Bath type boiler-condenser using thermo-siphon effect, e.g. with natural or forced circulation or pool boiling, i.e. core-in-kettle heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/04Down-flowing type boiler-condenser, i.e. with evaporation of a falling liquid film

Definitions

  • the present invention relates to an apparatus and a method for separating air by cryogenic distillation.
  • the first arrangement makes it possible to obtain improved energy performance as it saves loss of pressure in the gas return pipes (predominant effect) and energy from the liquid return pumps.
  • the difference in pressure between the average pressure column and the low pressure column is typically less than 2 bar absolute pressure, which necessitates the installation of a pump for raising liquid in the case where sections of the low pressure column are installed above the average pressure column.
  • an apparatus for separating air comprising a first distillation column capable of operating at an average pressure, a second distillation column capable of operating at a low pressure, a third distillation column capable of operating at a low pressure or at the low pressure, a first condenser-vaporizer, a second condenser-vaporizer arranged in the bottom of the second column, a pipe for supplying air at least to the first column, a pipe for supplying a nitrogen-enriched liquid from the head of the first column to the head of the third column, at least one pipe for supplying liquid from the bottom of the third column to the first condenser-vaporizer, a pipe for supplying a liquid from the bottom of the first column to the third column, a pipe for supplying liquid from the first condenser-vaporizer to the second column, a pipe for supplying overhead gas from the second column to the bottom of the third column, the first, second and third columns being arranged side-by-side, possibly all being arranged on a floor surface
  • the second column contains at least a third condenser-vaporizer placed above the second condenser-vaporizer.
  • An apparatus element for example a liquid oxygen vaporizer, capable of operating at a cryogenic temperature, may be arranged below one of the columns and wherein the two other columns and the element are placed directly on the floor surface.
  • Pressurization means may be connected to the bottom of the second column and to the liquid oxygen vaporizer.
  • the first condenser-vaporizer may be above the first column and connected to the head of the first column to permit reboiling by a gas from the first column.
  • the apparatus comprises just one pump connected to two of the columns.
  • the pump may be connected to the two pipes for supplying liquid from the bottom of the second column to the first condenser-reboiler.
  • a gas pipe may connect the first condenser to the bottom of the third column.
  • the head of the second column and/or the third column may be at a lower level than the first condenser-reboiler and preferably lower than the head of the first column.
  • the packing densities in the first column may be lower than the packing densities of the second column and/or of the third column.
  • the third column does not contain a condenser-reboiler.
  • the second column may also contain a third condenser-reboiler in addition to means for exchanging heat and material arranged above the third condenser-reboiler.
  • the pipe for supplying overhead gas from the second column to the bottom of the third column may be connected to a pipe for gas vaporized in the first condenser-reboiler.
  • the apparatus element is preferably a liquid oxygen vaporizer, arranged below the third column.
  • the difference in pressure between the operating pressure of the first column and the pressure of at least one of the second and third columns is preferably less than 3 bar, preferably 2.5 bar, preferably 2 bar.
  • the difference in pressure between the operating pressure of the top of the second column and the bottom of the third column may be less than 1 bar, preferably less than 0.5 bar, preferably less than 0.2 bar.
  • the apparatus comprises a first column 1 operating at an average pressure, a second column 2 operating at a low pressure and a third column 3 operating at a low pressure which is slightly less than that of the second column 2 , the low pressure columns preferably operating at a difference in pressure of less than 500 mbar (and preferably 200 mbar) measured between the bottom of the column 3 and the top of the column 2 .
  • the difference in pressure between the average pressure column 1 and the low pressure column 2 or 3 , measured in the middle of each column is less than 3 bar, preferably 2.5 bar, preferably 2 bar.
  • the three columns 1 , 2 , 3 are placed on the floor surface 27 , but the third column 3 is raised as a product vaporizer 11 is placed below said column. It is naturally possible to place the vaporizer 11 elsewhere and to place the column 3 directly on the floor surface 27 .
  • the floor surface 27 consists of a concrete base or other planar surface.
  • a compressed air flow 33 which is purified and cooled is passed into the bottom of the first column 1 where it is separated, forming an oxygen-enriched flow 25 and a nitrogen-enriched flow.
  • the oxygen-enriched flow 25 is passed to a lower level of the third column 3 .
  • the nitrogen-enriched flow condenses in the overhead condenser 9 of the first column.
  • Said condenser 9 is cooled by a flow of liquid 23 pumped from the bottom of the third column 3 and pressurized by a pump 13 which is also placed on the floor surface 27 .
  • the vaporized liquid 17 from the condenser 9 is mixed with an overhead gas 15 of the second column 2 to form a gaseous flow 19 which supplies the bottom of the third column 3 .
  • the head of the column of the second column 2 is supplied by a liquid 21 from the condenser 9 .
  • the second column 2 contains one or two, or more, reboilers, including a bottom reboiler 5 and possibly an intermediate reboiler 7 .
  • Said reboilers may be heated up by any suitable means, including an air flow, whether cold compressed or not, or a nitrogen flow, whether cold compressed or not.
  • a flow of gaseous or liquid oxygen 29 is withdrawn at a low level of the second column 2 .
  • Said flow of liquid may be pressurized by a pump (not shown) and passed to the vaporizer 11 to form a pressurized gaseous flow.
  • a liquid nitrogen flow 35 is expanded in a valve and passed to the head of the third column 3 and a nitrogen-enriched gaseous flow 31 is withdrawn at the head of the third column 3 .
  • the head of the third column 3 is lower than the head of the first column 1 , thus facilitating this transfer by gravitational flow.
  • FIG. 1 shows a condenser 9 which is a bath vaporizer
  • FIG. 2 shows a film vaporizer 9
  • the flow 21 withdrawn from the condenser is a two-phase flow and passed to the head of the second column as in FIG. 1 . No flow 17 is produced.
  • FIGS. 3 and 4 are variants of FIGS. 1 and 2 , respectively showing the case where the vaporizer 11 is absent or placed elsewhere other than below one of the columns. In this case, the three columns rest directly on the floor surface 27 .
  • FIGS. 5 and 6 respectively show variants of FIGS. 1 and 2 , where the second column contains just one reboiler, the bottom reboiler 5 .
  • the second column is naturally shorter.
  • the bottom reboiler 5 may be heated by nitrogen or air, which is possibly compressed, or possibly cold compressed.
  • the first pump is the pump 13 used for raising liquid from the bottom of the third column to the overhead condenser of the first column.
  • the second pump used in the case where the oxygen is required in pressurized form, is used to pressurize the liquid oxygen.
  • the difference in pressure between the columns should suffice to entrain the liquid.
  • the first column 1 contains relatively low packing densities (for example a density of 250 to 500 m 2 /m 3 ) and the second and/or third column contains relatively high packing densities (600 to 1000 m 2 /m 3 ) in order to achieve the highest possible first column 1 , and the lowest possible second and/or third column 2 , 3 so that the flow may take place by gravitational force between the vaporizer located above the first column to the second and/or to the third column.
  • the passage of the liquids in the pipes 21 , 35 is facilitated in this manner.
US13/321,993 2009-06-12 2010-06-04 Apparatus and method for separating air by cryogenic distillation Abandoned US20120118013A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0953935 2009-06-12
FR0953935A FR2946735B1 (fr) 2009-06-12 2009-06-12 Appareil et procede de separation d'air par distillation cryogenique.
PCT/FR2010/051101 WO2010142894A2 (fr) 2009-06-12 2010-06-04 Appareil et procédé de séparation d'air par distillation cryogénique

Publications (1)

Publication Number Publication Date
US20120118013A1 true US20120118013A1 (en) 2012-05-17

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US13/321,993 Abandoned US20120118013A1 (en) 2009-06-12 2010-06-04 Apparatus and method for separating air by cryogenic distillation

Country Status (9)

Country Link
US (1) US20120118013A1 (fr)
EP (1) EP2440871A2 (fr)
JP (1) JP5823385B2 (fr)
CN (1) CN102667383B (fr)
AU (1) AU2010258490B2 (fr)
CA (1) CA2762315A1 (fr)
FR (1) FR2946735B1 (fr)
WO (1) WO2010142894A2 (fr)
ZA (1) ZA201108764B (fr)

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JP2012529616A (ja) * 2009-06-12 2012-11-22 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード 低温蒸留による空気分離のための装置及び方法
US20170030637A1 (en) * 2015-07-31 2017-02-02 Air Liquide Global E&C Solutions Us Inc Method for the production of low pressure gaseous oxygen
US20170030636A1 (en) * 2015-07-31 2017-02-02 AIR LIQUIDE GLOBAL E&C SOLUTIONS US Inc. Apparatus for the production of low pressure gaseous oxygen
CN111787988A (zh) * 2017-12-19 2020-10-16 Ifp 新能源公司 用于海上气/液接触塔的具有相同形状的隔室和气体提升管的分配器塔盘

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US20150316317A1 (en) * 2012-12-27 2015-11-05 Linde Aktiengesellschaft Method and device for low-temperature air separation
CN105026862B (zh) * 2013-03-06 2018-03-27 林德股份公司 空气分离设备、获得含氩产品的方法及构建空气分离设备的方法

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EP2440871A2 (fr) 2012-04-18
CA2762315A1 (fr) 2010-12-16
AU2010258490B2 (en) 2014-09-04
JP2012529616A (ja) 2012-11-22
CN102667383A (zh) 2012-09-12
AU2010258490A1 (en) 2012-01-19
WO2010142894A3 (fr) 2012-11-15
CN102667383B (zh) 2015-04-08
FR2946735A1 (fr) 2010-12-17

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