US2011613A - Magnesium duplex metal - Google Patents

Magnesium duplex metal Download PDF

Info

Publication number
US2011613A
US2011613A US747153A US74715334A US2011613A US 2011613 A US2011613 A US 2011613A US 747153 A US747153 A US 747153A US 74715334 A US74715334 A US 74715334A US 2011613 A US2011613 A US 2011613A
Authority
US
United States
Prior art keywords
metal
magnesium
coating
base
magnesium alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US747153A
Inventor
Robert H Brown
Lowell A Willey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MAGNESIUM DEV CORP
MAGNESIUM DEVELOPMENT Corp
Original Assignee
MAGNESIUM DEV CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MAGNESIUM DEV CORP filed Critical MAGNESIUM DEV CORP
Priority to US747153A priority Critical patent/US2011613A/en
Application granted granted Critical
Publication of US2011613A publication Critical patent/US2011613A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9265Special properties
    • Y10S428/933Sacrificial component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12674Ge- or Si-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12708Sn-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12729Group IIA metal-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12806Refractory [Group IVB, VB, or VIB] metal-base component
    • Y10T428/12812Diverse refractory group metal-base components: alternative to or next to each other

Definitions

  • This invention relates to duplex metal articles and is particularly concerned with the production of improved duplex metals comprising a base of magnesium alloy provided on one or more of its surfaceswith a coating of a magnesium metal (magnesium or magnesium alloy).
  • magnesium base alloy sheet and tubing has been considerably restricted because of their relatively low resistance to corrosion, particularly in salt atmospheres.
  • Various types of paint and chemical coatings have been used to overcome this dimculty. Coatings of more corrosion resistant metals, such as zinc and aluminum, have also been suggested for this purpose. These coatings have not, however, provided entirely satisfactory protection, particularly under severe corrosion conditions, such as in the presence of chloride solutions.
  • the protection afforded the magnesium base metal by such coatings is a purely mechanical protection which prevents contact of the corrosion medium with the base metal. Consequently, at any point where the corrosion medium penetrates the coating, the corrosion of the magnesium base metal may proceed unrestricted under the coating. In such case the structural properties of the article may be substantially impaired, thus creating an undesirable and at times dangerous condition where the utility of the article is dependent upon the retention of its structural properties.
  • an object 5 of this invention to provide a duplex metal article in which the coating metal is magnesium or a magnesium base alloy and the base metal is a magnesium base alloy having an electrode potential less than that of the magnesium metal 10 v coating.
  • Another object of this invention is to provide a method for the production of a duplex metal article of improved corrosion resistance consisting of a magnesium alloy base provided with a coating consisting of magnesium or a magnesium alloy having an electrode potential greater than that of the magnesium alloy base.
  • This invention is based upon the discovery that certain metals have the property, when incorporated in magnesium or a magnesium base alloy, of producing a. magnesium alloy of lower electrode potential than the magnesium or magnesium alloy to which it has been added. More particularly we have found that by the addition to magnesium or a magnesium alloy of one or more of the class of metals comprising sodium, potassium, barium, calcium, tin, aluminum, zinc, lithium, cadmium, manganese, copper, strontium, bismuth, silver, cobalt, nickel and silicon, an alloy may be obtained having a lower electrode 30 potential without deleteriously modifying the other properties oi. the alloy, which recommend it as a base metal for a duplex metal article.
  • a duplex metal article may be formed of such magnesium alloy base and a magnesium or magnesium alloy coating which will have substantially improved corrosion-resisting properties, the coating being attacked in preference to the base metal when exposed to corrosive agents in electrolytic contact, thus preventing direct corrosive attack on the base metal and preserving its structural properties.
  • intermetallic compounds which may not have the property of lowering the electrode potential of the magnesium alloy.
  • the choice of the proper alloys to be used in combination in forming the duplex metal articles of our invention depends upon a predetermined knowledge of the electrode potential of magnesium and its various alloys. These diiferent potentials are readily measured in accordance with the methods long known in the art against a standard electrode; If the electrode potential of the magnesium metal coating is electronegative with respect to the standard electrode, it is not necessary that the magnesium alloy base be electropositive with respect to the standard electrode but only that the coating metal be more electronegative than the base metal. Therefore, throughout this specification and the appended claims, when it is said that the electrode potential of. the base metal should be lower than that of the coating metal, it is meant that the base metal should be less electronegative with respect to the standard electrode than is the coating metal.
  • the coating metal While no fixed potential difference is required between the magnesium alloy base and the coating metal, it is desirable that there be a relatively wide difference in the electrode potential of the two layers, since with greater differences in electrode potential there usually occurs less attack on the magnesium alloy base, and by suitable vin which the coating metal has an electrode potential of the order of 0.01 to 0.1. volts greater than the electrode potential of the magnesium alloy base are particularly resistant to galvanic corrosive action.
  • a convenient standard electrode for measuring the potential diiference may be readily selected from those now in regular use for similar measurements.
  • a calomel electrode has been selected as a standard.
  • the magnesium metal to be tested is made one element of an electrolytic cell; the calomel electrode is made the other 1 element.
  • electrolyte a normal solution of sodium chloride containing 0.3 per cent by "weight of hydrogen peroxide may be used. 'The circuit is closed and the potential difference of the elements "is measured on a potentiometer. The calomel.
  • electrode used is made up in the usual way of mercury in contact with mercurous chloride, and in contact with this a it; normal potassium chloride solution saturated with mercurous chloride.
  • duplex metal article any of the known methods of forming such duplex metal articles may be used.
  • One method which we have found particularly useful is to roll together the coating alloy and the base alloy in sheet or slab form. It is satisfactory to cast the-base'metal in an ingot mold lined with the coating alloy.
  • duplex metal article-desired such as sheet, I
  • Duplex material may also be produced by spraying or otherwise placing the coating metal on the base metal. This method may be used to advantage where irregular shapes, such as castings, are to be coated.
  • duplex metal articles of our invention may be provided on any one or all exposed surfaces with the protective coating alloy, as, for example,
  • FIG. 1 shows a duplex metal article comprising a base of magnesium metal I provided on its top and bottom surfaces with a magnesium alloy coating 2 a d 2 a base 3 of a magnesium metal provided on. its inner surface with a magnesium coating metal t.
  • This type of material is useful, for example, in'the manufacture of pipe used to conduct a material corrosive to the structural alloy.
  • Aduplex metal article consisting of a base of a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium,-nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc copper, lithium, cadmium and silicon, and provided with' a coating of a magnesium metal, said magnesium alloy base having an electrode potential lower than that of the magnes'ium metal coating, 'as determined by reference to a standard electrode.
  • a duplex metal article consisting of a base of a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc, copper, lithium, cadmium and silicon, and provided with a-coating of a magnesium metal, said base having ane'lectrode potential lower than that of the magnesium metal coating and lower than that of magnesium, as determined by reference to standard electrode.
  • a duplex metal article consisting of a'base of a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc, copper, lithium, cadmium and silicon, and provided with a coating of magnesium, said base having an electrode potential lower than 'magnesium, as determined by reference to a standard electrode.
  • a duplex metal article consisting of a base of a magnesium alloy containing at least one of the metals of the class consisting of sodium,
  • a duplex metal article consisting of a base of a magnesium alloy containingat least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese,
  • a duplex metal article in tubular form comprising tin, zinc, copper, lithium, cadmium and silicon, and provided with a coating or a magnesium alloy, said base having an electrodepotential lower than that oi the magnesium alloy coating, and said coating having an electrode potential lower than that of magnesium, as determined byreierence to a standard electrode.
  • a duplex metal article consisting of a base oi a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc, copper, lithium, cadmium and silicon, and provided with a coating 01' a magnesium metal, said magnesium alloy base having an electrode potential 0.01 to 0.1 volts lower than that of the mgnesium metal coating, as determined by reference to a standard electrode.

Landscapes

  • Laminated Bodies (AREA)

Description

Aug. 20, 1935. R. H, BROWN r AL MAGNESIUM DUPLEX METAL Filed Oct. 6, 1954 9 4 H "H mm. 0 V. T m fl 1 My WW B Patented Aug. 20, 1935 PATENT OFFICE monssmm DUPLEX METAL Robert H. Brown and Lowell A. Willey, New
Kensington, Pa assignors, by mesne assign- -ments, to Magnesium Development Corporation, a corporation of Delaware 7 Application October 6, 1934, Serial Nb. 147,153
7 Claims. (01. 29-181) This invention relates to duplex metal articles and is particularly concerned with the production of improved duplex metals comprising a base of magnesium alloy provided on one or more of its surfaceswith a coating of a magnesium metal (magnesium or magnesium alloy).
The commercial application of magnesium base alloy sheet and tubing has been considerably restricted because of their relatively low resistance to corrosion, particularly in salt atmospheres. Various types of paint and chemical coatings have been used to overcome this dimculty. Coatings of more corrosion resistant metals, such as zinc and aluminum, have also been suggested for this purpose. These coatings have not, however, provided entirely satisfactory protection, particularly under severe corrosion conditions, such as in the presence of chloride solutions. The protection afforded the magnesium base metal by such coatings is a purely mechanical protection which prevents contact of the corrosion medium with the base metal. Consequently, at any point where the corrosion medium penetrates the coating, the corrosion of the magnesium base metal may proceed unrestricted under the coating. In such case the structural properties of the article may be substantially impaired, thus creating an undesirable and at times dangerous condition where the utility of the article is dependent upon the retention of its structural properties.
This difficulty is particularly pronounced in duplex metal articles having a magnesium alloy base provided with a coating of a more corrosion resistant metal, such as aluminum or zinc. It has been found that at any point where the magnesium alloy base metal is exposed in contact with the coating metal, as, for example, along a cut edge of the material, or where the coating has been perforated, an electrolytic type of corrosion is set up which causes a preferential and accelerated corrosion of the magnesium alloy base metal, This preferential or selective attack of the core metal results from the fact that the core metal has an electrode potential greater than that of the coating metal, whereby galvanic action is set up between the two metals in contact with the corroding medium, thus causing a flow of current which tends to dissolve the core metal. I
It is a primary object of this invention to pro-' vide a duplex metal article consisting of a magnesium alloy base and a metallic coating in which the magnesium alloy base has an electrode potential lower than that of the coating metal, so
that in addition to the mechanical type of protection afforded by the coating metal, the selective attack of the base metal exposed to the corroding medium in contact with the coating metal iseliminated. More particularly it is an object 5 of this invention to provide a duplex metal article in which the coating metal is magnesium or a magnesium base alloy and the base metal is a magnesium base alloy having an electrode potential less than that of the magnesium metal 10 v coating. Another object of this invention is to provide a method for the production of a duplex metal article of improved corrosion resistance consisting of a magnesium alloy base provided with a coating consisting of magnesium or a magnesium alloy having an electrode potential greater than that of the magnesium alloy base.
This invention is based upon the discovery that certain metals have the property, when incorporated in magnesium or a magnesium base alloy, of producing a. magnesium alloy of lower electrode potential than the magnesium or magnesium alloy to which it has been added. More particularly we have found that by the addition to magnesium or a magnesium alloy of one or more of the class of metals comprising sodium, potassium, barium, calcium, tin, aluminum, zinc, lithium, cadmium, manganese, copper, strontium, bismuth, silver, cobalt, nickel and silicon, an alloy may be obtained having a lower electrode 30 potential without deleteriously modifying the other properties oi. the alloy, which recommend it as a base metal for a duplex metal article. Thus a duplex metal article may be formed of such magnesium alloy base and a magnesium or magnesium alloy coating which will have substantially improved corrosion-resisting properties, the coating being attacked in preference to the base metal when exposed to corrosive agents in electrolytic contact, thus preventing direct corrosive attack on the base metal and preserving its structural properties.
, While these elements have the common property of lowering the electrode potential of magnesium and magnesium alloys, they do so in varying degrees, depending upon the particular mettal or metals used, as well as upon the amount in which they are used. The addition of these elements may be made in any amount necessary other elements of the base metal should be such as will not prevent the action of these metals in lowering the electrode potential, as, for example,
by combining with them to form intermetallic compounds which may not have the property of lowering the electrode potential of the magnesium alloy.
The choice of the proper alloys to be used in combination in forming the duplex metal articles of our invention depends upon a predetermined knowledge of the electrode potential of magnesium and its various alloys. These diiferent potentials are readily measured in accordance with the methods long known in the art against a standard electrode; If the electrode potential of the magnesium metal coating is electronegative with respect to the standard electrode, it is not necessary that the magnesium alloy base be electropositive with respect to the standard electrode but only that the coating metal be more electronegative than the base metal. Therefore, throughout this specification and the appended claims, when it is said that the electrode potential of. the base metal should be lower than that of the coating metal, it is meant that the base metal should be less electronegative with respect to the standard electrode than is the coating metal.
While no fixed potential difference is required between the magnesium alloy base and the coating metal, it is desirable that there be a relatively wide difference in the electrode potential of the two layers, since with greater differences in electrode potential there usually occurs less attack on the magnesium alloy base, and by suitable vin which the coating metal has an electrode potential of the order of 0.01 to 0.1. volts greater than the electrode potential of the magnesium alloy base are particularly resistant to galvanic corrosive action.
A convenient standard electrode for measuring the potential diiference may be readily selected from those now in regular use for similar measurements. For the purpose of this description of thednvention, a calomel electrode has been selected as a standard. In measuring the electrode potential in question, the magnesium metal to be tested is made one element of an electrolytic cell; the calomel electrode is made the other 1 element. As electrolyte, a normal solution of sodium chloride containing 0.3 per cent by "weight of hydrogen peroxide may be used. 'The circuit is closed and the potential difference of the elements "is measured on a potentiometer. The calomel.
electrode used is made up in the usual way of mercury in contact with mercurous chloride, and in contact with this a it; normal potassium chloride solution saturated with mercurous chloride.
In .forming the duplex metal article, any of the known methods of forming such duplex metal articles may be used. One method which we have found particularly useful is to roll together the coating alloy and the base alloy in sheet or slab form. It is satisfactory to cast the-base'metal in an ingot mold lined with the coating alloy. The
article may then, if desired, be mechanically worked, as, for example, by rolling or drawing or other suitable operation to form the particular type of duplex metal article-desired, such as sheet, I
rod or other form of material. The working with intermediate heating incident to such forming operation generally tends to improve the bond between the coating metal and the base metal. Duplex material may also be produced by spraying or otherwise placing the coating metal on the base metal. This method may be used to advantage where irregular shapes, such as castings, are to be coated.
. The duplex metal articles of our invention may be provided on any one or all exposed surfaces with the protective coating alloy, as, for example,
. i shown inFigs. 1 and 2 of the drawing. Fig. 1
shows a duplex metal article comprising a base of magnesium metal I provided on its top and bottom surfaces with a magnesium alloy coating 2 a d 2 a base 3 of a magnesium metal provided on. its inner surface with a magnesium coating metal t. This type of material is useful, for example, in'the manufacture of pipe used to conduct a material corrosive to the structural alloy.
We claim:
' l. Aduplex metal article consisting of a base of a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium,-nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc copper, lithium, cadmium and silicon, and provided with' a coating of a magnesium metal, said magnesium alloy base having an electrode potential lower than that of the magnes'ium metal coating, 'as determined by reference to a standard electrode. 1 w
2. A duplex metal article consisting of a base of a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc, copper, lithium, cadmium and silicon, and provided with a-coating of a magnesium metal, said base having ane'lectrode potential lower than that of the magnesium metal coating and lower than that of magnesium, as determined by reference to standard electrode.
3, A duplex metal article consisting of a'base of a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc, copper, lithium, cadmium and silicon, and provided with a coating of magnesium, said base having an electrode potential lower than 'magnesium, as determined by reference to a standard electrode.
4. A duplex metal article consisting of a base of a magnesium alloy containing at least one of the metals of the class consisting of sodium,
potassium, nickel, cobalt, barium, calcium, bis muth, strontium, silver, aluminum, manganese,
tin, zinc, copper, lithium, cadmium and silicon,
and provided with a coating of a magnesium al- 10y, said base having an electrode potential lower than that of the magnesium alloy coating, and said magnesium alloy coating having an electrode potential less than that of magnesium, as determined by reference to a standard electrode. V
' 5. A duplex metal article consisting of a base of a magnesium alloy containingat least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese,
In Fig. 2 is shown, in cross section, a duplex metal article in tubular form comprising tin, zinc, copper, lithium, cadmium and silicon, and provided with a coating or a magnesium alloy, said base having an electrodepotential lower than that oi the magnesium alloy coating, and said coating having an electrode potential lower than that of magnesium, as determined byreierence to a standard electrode.
6. A duplex metal article consisting of a base oi a magnesium alloy containing at least one of the metals of the class consisting of sodium, potassium, nickel, cobalt, barium, calcium, bismuth, strontium, silver, aluminum, manganese, tin, zinc, copper, lithium, cadmium and silicon, and provided with a coating 01' a magnesium metal, said magnesium alloy base having an electrode potential 0.01 to 0.1 volts lower than that of the mgnesium metal coating, as determined by reference to a standard electrode.
electrode potential about 991 to 0.1 volts lower 10 than that o! the magnesium coating metal as measured by reference to a standard electrode.
ROBERT H, BROWN,
LOWELL A. WILLEY. 15
US747153A 1934-10-06 1934-10-06 Magnesium duplex metal Expired - Lifetime US2011613A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US747153A US2011613A (en) 1934-10-06 1934-10-06 Magnesium duplex metal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US747153A US2011613A (en) 1934-10-06 1934-10-06 Magnesium duplex metal

Publications (1)

Publication Number Publication Date
US2011613A true US2011613A (en) 1935-08-20

Family

ID=25003864

Family Applications (1)

Application Number Title Priority Date Filing Date
US747153A Expired - Lifetime US2011613A (en) 1934-10-06 1934-10-06 Magnesium duplex metal

Country Status (1)

Country Link
US (1) US2011613A (en)

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE741507C (en) * 1937-04-16 1943-11-12 Georg Von Giesche S Erben Magnesium alloy
US2459123A (en) * 1946-03-21 1949-01-11 Cleveland Heater Co Water heating device with corrosion protective anode
US2478478A (en) * 1947-02-03 1949-08-09 Dow Chemical Co Potential gradient anode for galvanic protection
US2478479A (en) * 1947-02-03 1949-08-09 Dow Chemical Co Cored magnesium anode in galvanic protection
US2651835A (en) * 1948-07-21 1953-09-15 Olin Mathieson Clad magnesium base alloys
US2674789A (en) * 1948-08-27 1954-04-13 Olin Mathieson Method of cladding magnesium-lithium base alloys
US2692213A (en) * 1951-04-11 1954-10-19 Chicago Dev Corp Electrical conductor
US2712564A (en) * 1952-11-26 1955-07-05 Dow Chemical Co Primary cell
US2746134A (en) * 1953-05-22 1956-05-22 Ohio Commw Eng Co Duplex metal sheet or article
US3162511A (en) * 1963-07-18 1964-12-22 Dow Chemical Co Composite alloy
US4036602A (en) * 1975-11-26 1977-07-19 Chromalloy American Corporation Diffusion coating of magnesium in metal substrates
WO1986003343A1 (en) * 1984-11-19 1986-06-05 Revere Copper And Brass Incorporated Laminated lead alloy strip for battery grid application and electrochemical cells utilizing same
US4761356A (en) * 1985-02-26 1988-08-02 Matsushita Electric Industrial Co., Ltd. Grid for lead storage batteries
US5059390A (en) * 1989-06-14 1991-10-22 Aluminum Company Of America Dual-phase, magnesium-based alloy having improved properties
US5494538A (en) * 1994-01-14 1996-02-27 Magnic International, Inc. Magnesium alloy for hydrogen production
US6143428A (en) * 1997-01-28 2000-11-07 Daimlerchrysler Ag Anti-corrosion coating for magnesium materials
US20080078521A1 (en) * 2006-09-28 2008-04-03 Gm Global Technology Operations, Inc. Galvanic corrosion protection for magnesium components using cast-in-place isolators
US20080096036A1 (en) * 2006-10-19 2008-04-24 Gm Global Technology Operations, Inc. Sacrificial coatings for magnesium components
US9707739B2 (en) 2011-07-22 2017-07-18 Baker Hughes Incorporated Intermetallic metallic composite, method of manufacture thereof and articles comprising the same
US9816339B2 (en) 2013-09-03 2017-11-14 Baker Hughes, A Ge Company, Llc Plug reception assembly and method of reducing restriction in a borehole
US9926766B2 (en) 2012-01-25 2018-03-27 Baker Hughes, A Ge Company, Llc Seat for a tubular treating system
US10240419B2 (en) 2009-12-08 2019-03-26 Baker Hughes, A Ge Company, Llc Downhole flow inhibition tool and method of unplugging a seat
US10301909B2 (en) 2011-08-17 2019-05-28 Baker Hughes, A Ge Company, Llc Selectively degradable passage restriction
US10378303B2 (en) 2015-03-05 2019-08-13 Baker Hughes, A Ge Company, Llc Downhole tool and method of forming the same
US11090719B2 (en) 2011-08-30 2021-08-17 Baker Hughes, A Ge Company, Llc Aluminum alloy powder metal compact
US11167343B2 (en) 2014-02-21 2021-11-09 Terves, Llc Galvanically-active in situ formed particles for controlled rate dissolving tools
US11365164B2 (en) 2014-02-21 2022-06-21 Terves, Llc Fluid activated disintegrating metal system
US11649526B2 (en) 2017-07-27 2023-05-16 Terves, Llc Degradable metal matrix composite
US12018356B2 (en) 2014-04-18 2024-06-25 Terves Inc. Galvanically-active in situ formed particles for controlled rate dissolving tools

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE741507C (en) * 1937-04-16 1943-11-12 Georg Von Giesche S Erben Magnesium alloy
US2459123A (en) * 1946-03-21 1949-01-11 Cleveland Heater Co Water heating device with corrosion protective anode
US2478478A (en) * 1947-02-03 1949-08-09 Dow Chemical Co Potential gradient anode for galvanic protection
US2478479A (en) * 1947-02-03 1949-08-09 Dow Chemical Co Cored magnesium anode in galvanic protection
US2651835A (en) * 1948-07-21 1953-09-15 Olin Mathieson Clad magnesium base alloys
US2674789A (en) * 1948-08-27 1954-04-13 Olin Mathieson Method of cladding magnesium-lithium base alloys
US2692213A (en) * 1951-04-11 1954-10-19 Chicago Dev Corp Electrical conductor
US2712564A (en) * 1952-11-26 1955-07-05 Dow Chemical Co Primary cell
US2746134A (en) * 1953-05-22 1956-05-22 Ohio Commw Eng Co Duplex metal sheet or article
US3162511A (en) * 1963-07-18 1964-12-22 Dow Chemical Co Composite alloy
US4036602A (en) * 1975-11-26 1977-07-19 Chromalloy American Corporation Diffusion coating of magnesium in metal substrates
WO1986003343A1 (en) * 1984-11-19 1986-06-05 Revere Copper And Brass Incorporated Laminated lead alloy strip for battery grid application and electrochemical cells utilizing same
US4761356A (en) * 1985-02-26 1988-08-02 Matsushita Electric Industrial Co., Ltd. Grid for lead storage batteries
US5059390A (en) * 1989-06-14 1991-10-22 Aluminum Company Of America Dual-phase, magnesium-based alloy having improved properties
US5494538A (en) * 1994-01-14 1996-02-27 Magnic International, Inc. Magnesium alloy for hydrogen production
US6143428A (en) * 1997-01-28 2000-11-07 Daimlerchrysler Ag Anti-corrosion coating for magnesium materials
US20080078521A1 (en) * 2006-09-28 2008-04-03 Gm Global Technology Operations, Inc. Galvanic corrosion protection for magnesium components using cast-in-place isolators
US7845388B2 (en) * 2006-09-28 2010-12-07 Gm Global Technology Operations, Inc. Galvanic corrosion protection for magnesium components using cast-in-place isolators
US7713618B2 (en) * 2006-10-19 2010-05-11 Gm Global Technology Operations, Inc. Sacrificial coatings for magnesium components
US20080096036A1 (en) * 2006-10-19 2008-04-24 Gm Global Technology Operations, Inc. Sacrificial coatings for magnesium components
US10240419B2 (en) 2009-12-08 2019-03-26 Baker Hughes, A Ge Company, Llc Downhole flow inhibition tool and method of unplugging a seat
US10669797B2 (en) 2009-12-08 2020-06-02 Baker Hughes, A Ge Company, Llc Tool configured to dissolve in a selected subsurface environment
US10697266B2 (en) 2011-07-22 2020-06-30 Baker Hughes, A Ge Company, Llc Intermetallic metallic composite, method of manufacture thereof and articles comprising the same
US9707739B2 (en) 2011-07-22 2017-07-18 Baker Hughes Incorporated Intermetallic metallic composite, method of manufacture thereof and articles comprising the same
US10301909B2 (en) 2011-08-17 2019-05-28 Baker Hughes, A Ge Company, Llc Selectively degradable passage restriction
US11090719B2 (en) 2011-08-30 2021-08-17 Baker Hughes, A Ge Company, Llc Aluminum alloy powder metal compact
US9926766B2 (en) 2012-01-25 2018-03-27 Baker Hughes, A Ge Company, Llc Seat for a tubular treating system
US9816339B2 (en) 2013-09-03 2017-11-14 Baker Hughes, A Ge Company, Llc Plug reception assembly and method of reducing restriction in a borehole
US11167343B2 (en) 2014-02-21 2021-11-09 Terves, Llc Galvanically-active in situ formed particles for controlled rate dissolving tools
US11365164B2 (en) 2014-02-21 2022-06-21 Terves, Llc Fluid activated disintegrating metal system
US11613952B2 (en) 2014-02-21 2023-03-28 Terves, Llc Fluid activated disintegrating metal system
US12031400B2 (en) 2014-02-21 2024-07-09 Terves, Llc Fluid activated disintegrating metal system
US12018356B2 (en) 2014-04-18 2024-06-25 Terves Inc. Galvanically-active in situ formed particles for controlled rate dissolving tools
US10378303B2 (en) 2015-03-05 2019-08-13 Baker Hughes, A Ge Company, Llc Downhole tool and method of forming the same
US11649526B2 (en) 2017-07-27 2023-05-16 Terves, Llc Degradable metal matrix composite
US11898223B2 (en) 2017-07-27 2024-02-13 Terves, Llc Degradable metal matrix composite

Similar Documents

Publication Publication Date Title
US2011613A (en) Magnesium duplex metal
US1997165A (en) Duplex metal article
US3505043A (en) Al-mg-zn alloy coated ferrous metal sheet
US2746134A (en) Duplex metal sheet or article
US1997166A (en) Duplex metal article
US2982017A (en) Method of protecting magnesium with a coating of titanium
US2023512A (en) Duplex metal article
US3364057A (en) Metal hydroxide intermediate coating for metal
US3567943A (en) Radioactive plating for radioactive foils
US3033775A (en) Anode for cathodic protection
US2100545A (en) Welding electrode
US3321306A (en) Galvanic anode alloy and products produced therefrom
Walker Triazole, benzotriazole, and naphthotriazole as corrosion inhibitors for brass
Klein et al. Microstructure‐based characterization of the corrosion behavior of the creep resistant Mg–Al–Ba–Ca alloy DieMag422
US1144106A (en) Sheet metal and method for its production.
Abdelaal et al. Anodic polarization of tin, nickel, and a 65/35 tin-nickel alloy in alkaline media containing halide ions
US3057049A (en) Alloy and composite stock
US2222471A (en) Nickel base alloy
US2031113A (en) Alloys
US1938172A (en) Copper-base alloys
US2003685A (en) Aluminum brass alloy
US2230236A (en) Manganese alloy
US1801808A (en) Process for covering metals or alloys with layers of metallic beryllium
US2359813A (en) Protective covering for welding rods
US2041867A (en) Multiple alloys