US20110214452A1 - Integrated Air-Separating And Water-Heating Apparatus Intended For A Boiler - Google Patents

Integrated Air-Separating And Water-Heating Apparatus Intended For A Boiler Download PDF

Info

Publication number
US20110214452A1
US20110214452A1 US13/128,173 US200913128173A US2011214452A1 US 20110214452 A1 US20110214452 A1 US 20110214452A1 US 200913128173 A US200913128173 A US 200913128173A US 2011214452 A1 US2011214452 A1 US 2011214452A1
Authority
US
United States
Prior art keywords
air
exchanger
water
compressor
feeding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/128,173
Other languages
English (en)
Inventor
Richard Dubettier-Grenier
Jean-Pierre Tranier
Stephane Gree
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SIEMENS VAI METALS TECHNOLOGIES GmbH
Primetals Technologies Austria GmbH
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Siemens VAI Metals Technologies GmbH Austria
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens VAI Metals Technologies GmbH Austria, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Siemens VAI Metals Technologies GmbH Austria
Publication of US20110214452A1 publication Critical patent/US20110214452A1/en
Assigned to L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE reassignment L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DUBETTIER-GRENIER, RICHARD, GREE, STEPHANE, TRANIER, JEAN-PIERRE
Assigned to SIEMENS VAI METALS TECHNOLOGIES GMBH, L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE reassignment SIEMENS VAI METALS TECHNOLOGIES GMBH CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY PREVIOUSLY RECORDED ON REEL 027122 FRAME 0585. ASSIGNOR(S) HEREBY CONFIRMS THE RICHARD DUBETTIER-GRENIER JEAN-PIERRE TRANIER STEPHANE GREE. Assignors: DUBETTIER-GRENIER, RICHARD, GREE, STEPHANE, TRANIER, JEAN-PIERRE
Abandoned legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04163Hot end purification of the feed air
    • F25J3/04169Hot end purification of the feed air by adsorption of the impurities
    • F25J3/04181Regenerating the adsorbents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K27/00Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
    • F01K27/02Plants modified to use their waste heat, other than that of exhaust, e.g. engine-friction heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D25/00Pumping installations or systems
    • F04D25/02Units comprising pumps and their driving means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D29/00Details, component parts, or accessories
    • F04D29/58Cooling; Heating; Diminishing heat transfer
    • F04D29/582Cooling; Heating; Diminishing heat transfer specially adapted for elastic fluid pumps
    • F04D29/5826Cooling at least part of the working fluid in a heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/04018Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04109Arrangements of compressors and /or their drivers
    • F25J3/04115Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
    • F25J3/04121Steam turbine as the prime mechanical driver
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04157Afterstage cooling and so-called "pre-cooling" of the feed air upstream the air purification unit and main heat exchange line
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04612Heat exchange integration with process streams, e.g. from the air gas consuming unit
    • F25J3/04618Heat exchange integration with process streams, e.g. from the air gas consuming unit for cooling an air stream fed to the air fractionation unit
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04812Different modes, i.e. "runs" of operation
    • F25J3/04824Stopping of the process, e.g. defrosting or deriming; Back-up procedures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/60Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • F25J2205/66Regenerating the adsorption vessel, e.g. kind of reactivation gas
    • F25J2205/70Heating the adsorption vessel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/06Adiabatic compressor, i.e. without interstage cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/70Steam turbine, e.g. used in a Rankine cycle

Definitions

  • the present invention relates to an integrated air-separating and water-heating apparatus intended for a boiler.
  • U.S. Pat. No. 4,461,154 discloses the use of an adiabatic compressor for compressing air and recovering the heat generated at the outlet of the compressor to heat the water which is supplied to a boiler, with the aim of improving the overall efficiency of the air-separating device fed by the compressed air and also of the boiler (for the purpose of reducing the fuel consumption of the boiler).
  • WO-A-2006/131283 describes a device in which the air from a compressor is heated by flue gases and is then used to heat the water in two separate exchangers.
  • DE-C-19837251 describes an air-separating device integrated with a gas turbine.
  • the steam is extracted from a turbine and is then used to preheat the water intended for a boiler.
  • the present invention enables the heat recovery from an air compressor to be optimized by preheating the boiler feed water.
  • the water supplied to a boiler is sent to a degasser to separate the oxygen dissolved in it, typically in order to reduce the oxygen content to less than 10 ppb by direct steam stripping of the water.
  • this degassing must take place at a pressure of less than 20 bar, and preferably less than 10 bar.
  • the air When a compressor is used to compress all the air intended for a cryogenic air-separating device, the air must typically be produced at 6 bar abs and therefore at a temperature of 230° C. to 300° C. for an adiabatic compressor.
  • the boiler feed water could be heated to between 220° C. and 295° C. (allowing for the fact that a temperature difference of less than 5° C. would entail significant additional costs).
  • the relation between the flow of water intended for the boiler (and obtained from the turbine condenser) and the flow of air is 380 kg of water per 1000 Nm 3 /h of air.
  • the air leaves the compressor at 273° C.
  • the water leaves the condenser at 45° C.
  • the minimum temperature difference in the exchanger where the water is heated by the air is 10° C.
  • the water can only be heated to 224° C., whereas a temperature of at least 250° C. would be desirable.
  • another heat source is used to complement the heat received from the air compressor, in order to raise the temperature of the water intended for the boiler.
  • the invention proposes an integrated apparatus, including an air compressor, a steam turbine which drives the air compressor, a first heat exchanger, means for feeding water to the first heat exchanger and from there to a boiler, means for feeding compressed air from the compressor to the first heat exchanger and an air-separating device supplied with air compressed in the compressor, heating means for heating the water downstream from the first exchanger, a second exchanger, means for feeding water from the first exchanger to the heating means, from the heating means to the second exchanger, and from the second exchanger to the boiler, and means for feeding air from the compressor to the second exchanger upstream from the first exchanger, without preheating means between the compressor and the second exchanger, and from the second exchanger to the first exchanger.
  • the air from the compressor heats the water without having been preheated by flue gases as in the prior art.
  • the invention also proposes a method of heating water intended for a boiler in which water is heated in a first heat exchanger by an exchange of heat with air from a compressor driven by a steam turbine, after which the air cooled in this first exchanger is fed to an air-separating device, characterized in that the water from the first exchanger is reheated and fed to a second exchanger, preferably without having been reheated, where it exchanges heat with air from the compressor, the air from the compressor not being preheated between the compressor and the second exchanger, the air cooled in the second exchanger is fed to the first exchanger, and the water heated in the second exchanger is fed to the boiler.
  • the air compressor produces air at a first pressure and the air is fed to the air-separating device at this first pressure, without compression downstream from the air compressor.
  • all the air from the compressor is fed to the air-separating device.
  • FIGS. 1 and 4 show apparatus according to the invention and FIGS. 2 and 3 are Q-T diagrams of an exchanger of the apparatus.
  • water 27 is extracted from a condenser 23 at 45° C. and is pumped to 15 bar by a pump 25 .
  • This pumped water is heated by indirect exchange in a first exchanger 29 to a first temperature of at least 100° C., preferably at least 130° C., possibly at least 150° C., or even at least 170° C., for example 175° C. in this case.
  • the water recovers heat from the air 35 from an air compressor 31 .
  • the compressor can be adiabatic or can have cooling means between the stages.
  • the hot water is fed to a degasser 3 which receives water vapor 5 at 14 bar from a boiler 1 . The water is thus heated from its first temperature to 196° C.
  • the water 7 at 196° C. is pumped by the pump 9 to 150 bar, creating the flow 11 , and is fed to a second exchanger 13 where it exchanges heat with air 33 from the air compressor 31 . After passing through the two exchangers, the air 37 is fed to an air-separating device which is illustrated in FIG. 4 .
  • the flow of water at high pressure 15 is fed to the boiler 1 .
  • the water vapor 19 from the boiler 1 is fed to a steam turbine 17 which drives the air compressor 31 .
  • the steam 21 is then fed to the condenser 23 .
  • the air is not compressed between the outlet of the compressor 31 and the inlet of the air-separating device 49 .
  • FIG. 2 illustrates the heat exchange in the two exchangers 13 and 29 . This configuration permits good utilization of the heat from the compressor and efficient degassing at medium pressure.
  • FIG. 4 is an illustration of a version of FIG. 1 , showing the air-separating device in greater detail.
  • the air 37 from the compressor 31 is fed to a purification device 41 , and from there to a cryogenic distillation air-separating device 49 .
  • a liquid product from the separating device 49 is vaporized in an auxiliary vaporizer 51 .
  • the purification device is regenerated by a flow of nitrogen 43 from the air-separating device 49 .
  • This nitrogen flow can be preheated by water vapor from the boiler 1 and/or by water vapor 55 from the degasser 3 and/or from the boiler blow-offs.
  • the water vapor from the boiler 1 is a fraction of the flow 5 to be sent to the degasser 3 .
  • a part 57 of the water heated to approximately 150° C. in the first exchanger 29 can be used to heat the regeneration nitrogen 43 .
  • This water can be drawn off continuously and stored in a thermally insulated store (not shown) and sent when required to heat the regeneration nitrogen.
  • Water vapor 53 from the degasser 3 can be used to vaporize a cryogenic liquid of the air-separating device in an auxiliary vaporizer 51 .
  • Part of the water vapor 5 and/or of the water 57 and/or of the water vapor 45 and/or of the water vapor 55 can also be used to heat an absorption cooling unit of the air-separating device 49 .
  • the air is not compressed by any compressor means between the air compressor 31 and the air-separating device 49 , and all the air from the air compressor 31 is fed to the air-separating device 49 .

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Physical Water Treatments (AREA)
  • Air Supply (AREA)
US13/128,173 2008-11-10 2009-11-06 Integrated Air-Separating And Water-Heating Apparatus Intended For A Boiler Abandoned US20110214452A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0857631 2008-11-10
FR0857631A FR2938320B1 (fr) 2008-11-10 2008-11-10 Installation integree de separation d'air et de chauffage d'eau destinee a une chaudiere
PCT/FR2009/052145 WO2010052437A2 (fr) 2008-11-10 2009-11-06 Installation integree de separation d'air et de chauffage d'eau destinee a une chaudiere

Publications (1)

Publication Number Publication Date
US20110214452A1 true US20110214452A1 (en) 2011-09-08

Family

ID=40842757

Family Applications (1)

Application Number Title Priority Date Filing Date
US13/128,173 Abandoned US20110214452A1 (en) 2008-11-10 2009-11-06 Integrated Air-Separating And Water-Heating Apparatus Intended For A Boiler

Country Status (6)

Country Link
US (1) US20110214452A1 (ko)
EP (1) EP2344822A2 (ko)
KR (1) KR20110086591A (ko)
CN (1) CN102209873B (ko)
FR (1) FR2938320B1 (ko)
WO (1) WO2010052437A2 (ko)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9435229B2 (en) 2012-01-26 2016-09-06 Linde Ag Process and device for air separation and steam generation in a combined system
WO2020160844A1 (de) 2019-02-07 2020-08-13 Linde Gmbh Verfahren und anordnung zur bereitstellung eines ersten verfahrensprodukts und eines zweiten verfahrensprodukts
US20210300788A1 (en) * 2020-03-29 2021-09-30 Chaac Holdings, Inc. Atmospheric water and power generation compression apparatus, system and method

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2957408B1 (fr) 2010-03-09 2015-07-17 Air Liquide Procede et appareil de chauffage d'un gaz de l'air provenant d'un appareil de separation d'air
FR2984474A1 (fr) * 2011-12-16 2013-06-21 Air Liquide Procede et appareil de separation d'air par distillation cryogenique
DE102012001606A1 (de) 2012-01-26 2013-08-01 Linde Aktiengesellschaft Verfahren und Vorrichtung zur Luftzerlegung und Dampferzeugung in einem kombinierten System
DE102012004048A1 (de) 2012-03-02 2013-09-05 Linde Ag Verfahren und Vorrichtung zur Luftzerlegung und Dampferzeugung in einem kombinierten System
CN103234213B (zh) * 2013-04-27 2015-10-14 东南大学 一种富氧燃烧热量利用的方法及装置

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4461154A (en) * 1981-06-18 1984-07-24 Air Products And Chemicals, Inc. Method and apparatus for compressing gas
JPH11182263A (ja) * 1997-10-17 1999-07-06 Hitachi Ltd ガスタービン発電プラント
US20010022077A1 (en) * 1998-08-17 2001-09-20 Frank Hannemann Gas turbine and steam turbine installation
US6662594B2 (en) * 2001-12-14 2003-12-16 Linde Aktiengesellschaft Apparatus and process for producing gaseous oxygen under elevated pressure
US20040069016A1 (en) * 2000-10-30 2004-04-15 Alain Guillard Process and installation for separation of air by cryogenic distillation integrated with an associated process
US20060137393A1 (en) * 2004-12-27 2006-06-29 Bot Patrick L Integrated air compression, cooling, and purification unit and process

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4934148A (en) * 1989-05-12 1990-06-19 Union Carbide Corporation Dry, high purity nitrogen production process and system
FR2681416B1 (fr) * 1991-09-13 1993-11-19 Air Liquide Procede de refroidissement d'un gaz dans une installation d'exploitation de gaz de l'air, et installation.
DE102005026534B4 (de) * 2005-06-08 2012-04-19 Man Diesel & Turbo Se Dampferzeugungsanlage
US8065879B2 (en) * 2007-07-19 2011-11-29 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Thermal integration of oxygen plants

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4461154A (en) * 1981-06-18 1984-07-24 Air Products And Chemicals, Inc. Method and apparatus for compressing gas
JPH11182263A (ja) * 1997-10-17 1999-07-06 Hitachi Ltd ガスタービン発電プラント
US20010022077A1 (en) * 1998-08-17 2001-09-20 Frank Hannemann Gas turbine and steam turbine installation
US6301873B2 (en) * 1998-08-17 2001-10-16 Siemens Aktiengesellschaft Gas turbine and steam turbine installation
US20040069016A1 (en) * 2000-10-30 2004-04-15 Alain Guillard Process and installation for separation of air by cryogenic distillation integrated with an associated process
US6662594B2 (en) * 2001-12-14 2003-12-16 Linde Aktiengesellschaft Apparatus and process for producing gaseous oxygen under elevated pressure
US20060137393A1 (en) * 2004-12-27 2006-06-29 Bot Patrick L Integrated air compression, cooling, and purification unit and process
US7225637B2 (en) * 2004-12-27 2007-06-05 L'Air Liquide Société Anonyme á´ Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude Integrated air compression, cooling, and purification unit and process

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9435229B2 (en) 2012-01-26 2016-09-06 Linde Ag Process and device for air separation and steam generation in a combined system
WO2020160844A1 (de) 2019-02-07 2020-08-13 Linde Gmbh Verfahren und anordnung zur bereitstellung eines ersten verfahrensprodukts und eines zweiten verfahrensprodukts
US20210300788A1 (en) * 2020-03-29 2021-09-30 Chaac Holdings, Inc. Atmospheric water and power generation compression apparatus, system and method

Also Published As

Publication number Publication date
WO2010052437A3 (fr) 2011-06-03
CN102209873B (zh) 2014-02-26
FR2938320B1 (fr) 2013-03-15
CN102209873A (zh) 2011-10-05
EP2344822A2 (fr) 2011-07-20
FR2938320A1 (fr) 2010-05-14
WO2010052437A2 (fr) 2010-05-14
KR20110086591A (ko) 2011-07-28

Similar Documents

Publication Publication Date Title
US20110214452A1 (en) Integrated Air-Separating And Water-Heating Apparatus Intended For A Boiler
RU2611499C2 (ru) Способ и установка для дистилляции метанола с регенерацией тепла
US8065879B2 (en) Thermal integration of oxygen plants
WO2008116727A3 (en) Process and apparatus for the separation of air by cryogenic distillation
US11607622B2 (en) Low energy ejector desalination system
EP2806956B1 (en) Process and plant for distillation of methanol with heat recovery.
WO2011074048A1 (ja) ガスタービンコンバインドサイクル発電設備および方法
WO2012159194A1 (en) High pressure oxy-fuel combustion system (hiprox) bottoming cycle
CN103097842B (zh) 用于分离空气并加热源自空气分离装置的空气气体的方法和一体装置
US20120301834A1 (en) High pressure oxy-fired combustion system
KR20150128591A (ko) 열 통합형 공기 분리 유닛을 갖는 순산소 보일러 발전소
JP5866193B2 (ja) 高圧窒素を製造するための方法および装置
EP2559866B1 (en) Power plant heat integration
US20210040509A1 (en) Dehydration energy recycling system and method
US20160010511A1 (en) Power generation system and method to operate
TW201927401A (zh) 排放控制系統
US20180163571A1 (en) Oxyfuel power plant process
FR2960555A1 (fr) Installation integree comprenant un appareil de separation d'air et au moins un haut fourneau et son procede d'operation
CA2741100C (en) High pressure oxy-fuel combustion system (hiprox) bottoming cycle
TW201339406A (zh) 發電廠之熱整合

Legal Events

Date Code Title Description
AS Assignment

Owner name: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'E

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:DUBETTIER-GRENIER, RICHARD;TRANIER, JEAN-PIERRE;GREE, STEPHANE;REEL/FRAME:027122/0585

Effective date: 20110427

Owner name: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'E

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY PREVIOUSLY RECORDED ON REEL 027122 FRAME 0585. ASSIGNOR(S) HEREBY CONFIRMS THE RICHARD DUBETTIER-GRENIER JEAN-PIERRE TRANIER STEPHANE GREE;ASSIGNORS:DUBETTIER-GRENIER, RICHARD;TRANIER, JEAN-PIERRE;GREE, STEPHANE;REEL/FRAME:027123/0001

Effective date: 20110427

Owner name: SIEMENS VAI METALS TECHNOLOGIES GMBH, AUSTRIA

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY PREVIOUSLY RECORDED ON REEL 027122 FRAME 0585. ASSIGNOR(S) HEREBY CONFIRMS THE RICHARD DUBETTIER-GRENIER JEAN-PIERRE TRANIER STEPHANE GREE;ASSIGNORS:DUBETTIER-GRENIER, RICHARD;TRANIER, JEAN-PIERRE;GREE, STEPHANE;REEL/FRAME:027123/0001

Effective date: 20110427

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION