US20110193046A1 - Phase change memory device, manufacturing method thereof and operating method thereof - Google Patents
Phase change memory device, manufacturing method thereof and operating method thereof Download PDFInfo
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- US20110193046A1 US20110193046A1 US13/090,043 US201113090043A US2011193046A1 US 20110193046 A1 US20110193046 A1 US 20110193046A1 US 201113090043 A US201113090043 A US 201113090043A US 2011193046 A1 US2011193046 A1 US 2011193046A1
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- 238000011017 operating method Methods 0.000 title description 2
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000004065 semiconductor Substances 0.000 claims description 4
- 239000012212 insulator Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 238000009413 insulation Methods 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 18
- 101100520094 Methanosarcina acetivorans (strain ATCC 35395 / DSM 2834 / JCM 12185 / C2A) pcm2 gene Proteins 0.000 description 12
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 10
- 238000012986 modification Methods 0.000 description 3
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- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- 229910000763 AgInSbTe Inorganic materials 0.000 description 1
- 101100519160 Arabidopsis thaliana PCR4 gene Proteins 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 229910052798 chalcogen Inorganic materials 0.000 description 1
- 150000004770 chalcogenides Chemical class 0.000 description 1
- 150000001787 chalcogens Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
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- 101150033318 pcm2 gene Proteins 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
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- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
- G11C13/0004—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements comprising amorphous/crystalline phase transition cells
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
- G11C13/0021—Auxiliary circuits
- G11C13/003—Cell access
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
- G11C13/0021—Auxiliary circuits
- G11C13/0061—Timing circuits or methods
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
- G11C13/0021—Auxiliary circuits
- G11C13/0069—Writing or programming circuits or methods
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B63/00—Resistance change memory devices, e.g. resistive RAM [ReRAM] devices
- H10B63/20—Resistance change memory devices, e.g. resistive RAM [ReRAM] devices comprising selection components having two electrodes, e.g. diodes
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B63/00—Resistance change memory devices, e.g. resistive RAM [ReRAM] devices
- H10B63/80—Arrangements comprising multiple bistable or multi-stable switching components of the same type on a plane parallel to the substrate, e.g. cross-point arrays
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/011—Manufacture or treatment of multistable switching devices
- H10N70/061—Shaping switching materials
- H10N70/063—Shaping switching materials by etching of pre-deposited switching material layers, e.g. lithography
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/20—Multistable switching devices, e.g. memristors
- H10N70/231—Multistable switching devices, e.g. memristors based on solid-state phase change, e.g. between amorphous and crystalline phases, Ovshinsky effect
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/821—Device geometry
- H10N70/826—Device geometry adapted for essentially vertical current flow, e.g. sandwich or pillar type devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/881—Switching materials
- H10N70/882—Compounds of sulfur, selenium or tellurium, e.g. chalcogenides
- H10N70/8828—Tellurides, e.g. GeSbTe
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- G11—INFORMATION STORAGE
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- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
- G11C13/0021—Auxiliary circuits
- G11C13/0069—Writing or programming circuits or methods
- G11C2013/009—Write using potential difference applied between cell electrodes
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- G—PHYSICS
- G11—INFORMATION STORAGE
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- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
- G11C13/0021—Auxiliary circuits
- G11C13/0069—Writing or programming circuits or methods
- G11C2013/0092—Write characterized by the shape, e.g. form, length, amplitude of the write pulse
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- G—PHYSICS
- G11—INFORMATION STORAGE
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- G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
- G11C2213/70—Resistive array aspects
- G11C2213/72—Array wherein the access device being a diode
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
- G11C2213/70—Resistive array aspects
- G11C2213/74—Array wherein each memory cell has more than one access device
Definitions
- the present invention generally relates to phase change memory devices, more particularly, to phase change memory device capable of increasing a write current flowing in a phase change resistor for improving the cells driving capacity.
- Nonvolatile memory devices that include magnetic memory devices and phase change memory (PCM) devices have data processing speeds similar to those of volatile Random Access Memory (RAM) devices. Furthermore nonvolatile memory devices enjoy the advantage associated with conserving data even after the power is turned off.
- PCM phase change memory
- FIGS. 1 a and 1 b are diagrams illustrating a conventional phase change resistor (PCR) 4 .
- the PCR 4 comprises a phase change material (PCM) 2 inserted between a top electrode 1 and a bottom electrode 3 .
- PCM phase change material
- an elevated temperature can be generated in the PCM 2 so that the electric conductive state of the PCR 4 can be controlled or changed depending on whether or not the heated PCM 2 can be slowly cooled as a crystalline lattice structure or rapidly cooled as an amorphous lattice structure. That is the resistance of the crystalline lattice of the PCM 2 exhibits a lower resistance than the resistance of the amorphous lattice of the PCM 2 .
- PCM 2 of interest includes AgLnSbTe.
- the PCM 2 includes chalcogenide having chalcogen elements (S, Se, Te) as a main ingredient.
- Another PCM 2 of interest includes the germanium antimonic tellurium (Ge2Sb2Te5).
- FIGS. 2 a and 2 b are diagrams illustrating a principle of the is conventional PCR 4 .
- the PCM 2 can be crystallized when relatively low currents of less than a threshold pass through the PCM R. As a result, the PCM 2 can be crystallized to exhibit a low resistant material.
- the PCM 2 has a temperature of a more than a melting point when a high current of more than a threshold passes through the PCR 4 .
- the PCM 2 can become an amorphous lattice that exhibits a relatively high resistance.
- the PCR 4 can be configured to store nonvolatile data corresponding to the two resistance states. For instance, a logical data state of “1” can be assigned to correspond to the PCR 4 when at a low resistance state. Likewise, a logical data state of “0” can be assigned to correspond to the PCR 4 when at a high resistance state. In this way, the logic states of the two data can be stored.
- FIG. 3 is a diagram illustrating a write operation of a conventional phase change resistant cell.
- Heat is generated when a current flows between the top electrode 1 and the bottom electrode 3 of the PCR 4 for a given amount of time.
- a state of the PCM 2 can be changed to be either crystalline or amorphous depending upon what temperature was applied between the top electrode 1 and the bottom electrode 3 .
- the PCM When a low current flows for a given time, the PCM can become crystalline during a low temperature heating state so that the PCR 4 can be set to a low resistive set state. On the other hand, when a high current flows for a given amount of time, the PCM can become amorphous due to the generated high temperature heating state so that the PCR 4 can be set to a high resistive reset state. A difference between two phases is representive of an electric resistance change.
- a low voltage can be applied to the PCR 4 for a relatively long time period in order to write the set state in a write mode.
- a high voltage can be applied to the PCR 4 for a relatively short time period in order to write the reset state in the write mode.
- Various embodiments of the present invention are directed at providing a phase change memory device comprising a phase change resistor connected in parallel to two diodes in order to increase a write current flowing in a phase change resistor by two fold, thereby improving cell driving capacity.
- Various other embodiments of the present invention are directed at providing a phase change memory device comprising a phase change resistor connected in parallel to two diodes to reduce the cell size.
- Various other embodiments of the present invention are directed at applying a set voltage with a step-type waveform so that a phase change resistor may be crystallized.
- Various other embodiments of the present invention are directed at forming a phase change resistance cell over a SOT (Silicon On Insulator) substrate to insulate a silicon layer from the substrate with an oxide film without the need of using an additional process for insulating the silicon layer from the substrate.
- SOT Silicon On Insulator
- a manufacturing method of a phase change memory device comprises: forming a first impurity region in a semiconductor substrate; forming a first insulating layer including a bottom electrode over the semiconductor substrate; forming a phase change layer and a top electrode connected to the bottom electrode over the first insulating layer; and forming a second impurity region in the first impurity region with the top electrode as an ion-implanting mask.
- an operating method of a phase change memory device which comprises: a cell array including a phase change resistor connected to a word line and a phase change resistance cell having first and second diodes connected between the phase change resistor and a bit line; and a write driving unit configured to supply a write voltage corresponding to data to be written to the cell array unit, comprises: activating a selected word line in a write mode; applying the write signal to a selected bit line. When the data corresponds to a reset state, the write signal has a reset voltage imposed at a reset time period.
- the write signal When the data corresponds to a set state, the write signal has a first set voltage imposed at a first set time period, followed by a second set voltage imposed at a second set time period, and followed by a third set voltage imposed at a third set time period.
- the phase change memory device comprises: a first impurity region and a second impurity region formed alternately over a substrate; a phase change resistor connected to a top portion of the first impurity region; a bit line contact plug formed over the second impurity region; and a bit line connected in common to the bit line contact plug.
- FIGS. 1 a and 1 b are diagrams illustrating a conventional phase change resistor.
- FIGS. 2 a and 2 b are diagrams illustrating a principle of the conventional phase change resistor.
- FIG. 3 is a diagram illustrating a write operation of a conventional phase change resistant cell.
- FIGS. 4 a to 4 h are cross-sectional diagrams illustrating a manufacturing method of a phase change memory device according to an embodiment of the present invention.
- FIG. 5 is a diagram illustrating a cell array of a phase change memory device according to an embodiment of the present invention.
- FIG. 6 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention.
- FIG. 7 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention.
- FIG. 8 is a timing diagram illustrating a read operation of a phase change memory device according to an embodiment of the present invention.
- FIG. 9 is a diagram illustrating a current level between sensing currents in a read mode.
- FIGS. 4 a to 4 h are cross-sectional diagrams illustrating a manufacturing method of a phase change memory device according to an embodiment of the present invention.
- a N-type substrate 10 which is a bare wafer is formed.
- An insulating layer 12 is shown formed over the N-type substrate 10 .
- the insulating layer 12 can include an oxide film.
- a silicon layer 14 is formed over the insulating layer 12 .
- a silicon-on-insulator (SOT) type substrate is prepared.
- the insulator layer 12 of the SOI type substrate may provide the is advantage of insulating the silicon layer 14 from the N-type substrate 10 without the need for implementing any additional processes for insulating the silicon layer 14 from the N-type substrate 10 .
- N+ type impurity ions are implanted into the silicon layer 14 to form a N+ region 14 a.
- the N+ region 14 a is positioned to form a structure of a PN diode D.
- the N+ region 14 a may be obtained by ion-implanting N-type impurities such as As and P with high concentration.
- an insulating layer 16 is formed over the N+ region 14 a.
- the insulating layer 16 is selectively etched to form a plurality of contact holes (not shown) for exposing the N+ region 14 a which are separated with a given interval.
- a conductive film for bottom electrode is filled in the contact holes to form a bottom electrode 18 .
- phase change layer 20 is formed over the insulating layer 16 and the bottom electrode 18 .
- the phase change layer 20 can be any phase change material. Some preferred phase change materials are those selected from one of AgInSbTe and Ge2Sb2Te5
- a conductive film for top electrode is formed over the phase change layer 20 .
- the conductive film for forming the top electrode is selectively etched to form a top electrode 22 .
- the phase change layer 20 is selectively etched with the top electrode 22 as an etching mask to form a phase change layer 20 a overlapped with the bottom electrode 18 .
- phase change resistor PCR is formed which includes the bottom electrode 18 , the phase change layer 20 a and the top electrode 22 .
- P+ type impurity ions are implanted into the N+ region 14 a by using the top electrode 22 as an ion-implanting mask to form a P+ region 24 .
- the P+ region 24 may be formed in a local bit line contact region connected to a bit line contact plug.
- a PN diode D includes the P+ region 24 and the N+ region 14 a.
- the P+ regions 24 are formed to be connected serially to the N+ regions 14 a in the same layer. That is, there is no space between the P+ region 24 and the N+ region 14 a to reduce a cell size.
- an insulating layer 26 is formed over the resulting structure.
- the insulating layers 16 and 26 are selectively etched to form a plurality of contact holes (not shown) for exposing the P+ region 24 .
- the insulating layers 16 and 26 are etched except a region where the phase change resistor PCR is formed.
- a conductive film for bit line contact is filled in the contact holes to form a bit line contact plug 28 .
- a bit line 30 connected to the bit line contact plug 28 is formed over the insulating layer 26 and the bit line contact plug 28 .
- a phase change resistance cell C including the phase change resistor PCR and the PN diode D is formed.
- the top electrodes 22 of the phase change resistors PCR are connected to a plurality of word lines WL 0 ⁇ WL 3 , and the bottom electrodes 18 are connected to the N type regions 14 a of the PN diodes D.
- the P type regions 24 of the PN diodes D are connected to the bit line 30 through the bit line contact plug 28 .
- the N type regions 14 a of the PN diodes D 1 , D 2 are connected in common to the bottom electrodes 18 .
- the PN diodes D 1 , D 2 are connected in parallel between the bottom electrode 18 and the bit line 30 of the phase change resistor PCR.
- FIG. 5 is a diagram illustrating a cell array of a phase change memory device according to an embodiment of the present invention.
- the phase change memory device includes a plurality of bit lines BL 0 ⁇ BL 3 arranged in a column direction and a plurality of word lines WL 0 ⁇ WL 3 arranged in a row direction.
- a plurality of unit cells C are arranged at intersections of the bit lines BL 0 ⁇ BL 3 and the word lines WL 0 ⁇ WL 3 .
- the unit cell C includes a phase change resistor PCR and PN diodes D 1 , D 2 .
- the phase change resistor PCR has one terminal connected to the word line WL and the other terminal connected in common to a N type region of the PN diodes D 1 , D 2 .
- the PN diodes D 1 , D 2 are arranged in parallel to the bit line BL.
- the PN diodes D 1 , D 2 each have a P-type region connected in common to the bit line BL and each N type region connected to the other terminal of the phase change resistor PCR.
- a phase of the phase change resistor PCR is changed depending on a set current Iset and a reset current Ireset flowing in the bit line BL to write data.
- the phase change resistor PCR includes the two diodes D 1 , D 2 connected in parallel.
- the set current Iset or the reset Ireset flowing through each bit line BL is applied to the phase change resistor PCR through the two PN diodes D 1 , D 2 .
- a current flowing through the phase change resistor PCR is increased by twice which results in doubling the cell driving capacity.
- the sense amplifier S/A senses a cell data received through the bit line BL and compares the cell data with a reference voltage ref to distinguish a set data from a reset data.
- the reference current Iref flows in a reference voltage ref receiving terminal.
- FIG. 6 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention.
- the word line WL 0 of the word lines WL 0 ⁇ WL 3 is selected.
- the word line WL 0 is activated by transitioning from a high level to a low level during a write enable period T 1 .
- the other reset word lines WL 1 ⁇ WL 3 remain inactivated at a high level.
- the write driving unit W/D applies a write voltage to the corresponding bit line BL of the bit lines BL 0 ⁇ BL 3 .
- a set write voltage Vset is applied to the corresponding bit line BL for a set period T 2 .
- the set write voltage Vset is applied to the phase change resistor PCR through the PN diodes D 1 , D 2 of the phase change resistance cell C. As a result, the set data is written in the phase change resistance cell C.
- a reset write voltage Vreset is applied to the corresponding bit line BL for a reset period T 3 .
- the reset write voltage Vreset is applied to the phase change resistor PCR through the PN diodes D 1 , D 2 of the phase change resistance cell C. As a result, the reset data is written in the phase change resistance cell C.
- the set write voltage Vset and the reset write voltage Vreset can be applied as a single pulse.
- the set write voltage Vset has a voltage level lower than that of the reset write voltage Vreset.
- the set period T 2 may be longer than the reset period T 3 .
- FIG. 7 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention.
- the corresponding word line WL 0 of the word lines WL 0 ⁇ WL 3 is selected.
- the word line WL 0 is activated by transitioning from a high level to a low level during a write enable period T 11 .
- the other reset word lines WL 1 ⁇ WL 3 remain inactivated at a high level.
- the write driving unit W/D applies a write voltage to the is corresponding bit line BL of the bit lines BL 0 ⁇ BL 3 .
- set write voltages Vset_ 1 ⁇ Vset_ 3 are sequentially applied to the corresponding bit line BL for a set period T 12 .
- the set write voltages Vset_ 1 ⁇ Vset_ 3 are series of step pulses which decrease discretely.
- the first set voltage Vset_ 1 is applied to the bit line BL for a first write time t 1 .
- the second set voltage Vset_ 2 is applied to the bit line BL for a second write time t 2 .
- the third set voltage Vset_ 3 is applied to the bit line BL for a third write time t 3 .
- the first set voltage Vset_ 1 has the same voltage level as that of the reset write voltage Vreset.
- the second set voltage Vset_ 2 has a voltage level lower than that of the first set voltage Vset_ 1 .
- the third set voltage Vset_ 3 has a voltage level lower than that of the second set voltage Vset_ 2 .
- a reset write voltage Vreset is applied to the corresponding bit line BL for a reset period T 13 .
- the reset write voltage Vreset is applied to the phase change resistor PCR through the PN diodes D 1 , D 2 of the phase change resistance cell C. As a result, the reset data is written in the phase change resistance cell C.
- the reset write voltage Vreset is applied as a single pulse.
- the set period T 12 may be longer than the reset period T 13 .
- FIG. 8 is a timing diagram illustrating a read operation of a phase change memory device according to an embodiment of the present invention.
- the word line WL 0 of the word lines WL 0 ⁇ WL 3 is selected.
- the word line WL 0 is activated by transiting from a high level to a low level during a read enable period T 21 .
- the other reset word lines WL 1 ⁇ WL 3 remain inactivated at a high level.
- a read voltage Vread is applied to the corresponding bit line BL of the bit lines BL 0 ⁇ BL 3 for a sensing period T 22 .
- the set current Iset or the reset current Ireset flows toward the selected word line WL 0 through the bit line BL, the phase change resistor PCR and the PN diodes D 1 , D 2 .
- the sense amplifier S/A senses a cell data received through the bit line BL and compares the reference current Tref with the set current Iset or the reset current Ireset to distinguish data “0” from data “1.”
- FIG. 9 is a diagram illustrating a current level between sensing currents in a read mode.
- the set current Iset has the largest current value
- the reset current Ireset has the smallest current value in a current level of the sensing current.
- the reference current Iref has a middle value of the values of the set current Iset and the reset current Ireset.
- a phase change memory device comprises a phase change resistor connected in parallel to two diodes to increase a write current substantially doubles by flowing in a phase change resistor
- the phase change memory device comprises a phase change resistor connected in parallel to two diodes results in decreasing the cell size.
- phase change memory device In the phase change memory device, a set voltage is applied with a step-type waveform so that a phase change resistor may be crystallized.
- phase change resistance cell is formed over a SOI-type substrate that insulates a silicon layer from the substrate with an oxide film without the need for an additional fabrication process for insulating the silicon layer from the substrate.
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Abstract
A phase change memory (PCM) device, a manufacturing technique of making the PCM device, and a way of operating the PCM device is presented. The PCM device is structured to have a silicon on insulator type substrate that provides an advantage of thermally insulating the active area of the PCM device without the need for an additional insulation layer. The PCM device has a phase change resistor PCR that has one terminal connected to a word line and the other terminal connected in common to the N-terminals of two PN diodes in which the P-terminals are connected in common to the bit line. As a result, a current flowing through the phase change resistor PCR is doubled which results in doubling the cell driving capacity.
Description
- This application is a division of U.S. patent application Ser. No. 12/134,388 filed on Jun. 6, 2008, which claims priority of Korean patent application number 10-2007-0090559 filed on Sep. 6, 2007. The disclosure of each of the foregoing applications is incorporated herein by reference in its entirety.
- The present invention generally relates to phase change memory devices, more particularly, to phase change memory device capable of increasing a write current flowing in a phase change resistor for improving the cells driving capacity.
- Nonvolatile memory devices that include magnetic memory devices and phase change memory (PCM) devices have data processing speeds similar to those of volatile Random Access Memory (RAM) devices. Furthermore nonvolatile memory devices enjoy the advantage associated with conserving data even after the power is turned off.
-
FIGS. 1 a and 1 b are diagrams illustrating a conventional phase change resistor (PCR) 4. - The
PCR 4 comprises a phase change material (PCM) 2 inserted between atop electrode 1 and abottom electrode 3. When an electrical signal having a voltage and a current is transmitted through thePCM 2, an elevated temperature can be generated in thePCM 2 so that the electric conductive state of the PCR4 can be controlled or changed depending on whether or not theheated PCM 2 can be slowly cooled as a crystalline lattice structure or rapidly cooled as an amorphous lattice structure. That is the resistance of the crystalline lattice of thePCM 2 exhibits a lower resistance than the resistance of the amorphous lattice of thePCM 2. - One
PCM 2 of interest includes AgLnSbTe. ThePCM 2 includes chalcogenide having chalcogen elements (S, Se, Te) as a main ingredient. AnotherPCM 2 of interest includes the germanium antimonic tellurium (Ge2Sb2Te5). -
FIGS. 2 a and 2 b are diagrams illustrating a principle of the isconventional PCR 4. - As shown in
FIG. 2 a, thePCM 2 can be crystallized when relatively low currents of less than a threshold pass through the PCM R. As a result, the PCM2 can be crystallized to exhibit a low resistant material. - As shown in
FIG. 2 b, thePCM 2 has a temperature of a more than a melting point when a high current of more than a threshold passes through thePCR 4. As a result, the PCM 2 can become an amorphous lattice that exhibits a relatively high resistance. - In this way, the
PCR 4 can be configured to store nonvolatile data corresponding to the two resistance states. For instance, a logical data state of “1” can be assigned to correspond to thePCR 4 when at a low resistance state. Likewise, a logical data state of “0” can be assigned to correspond to thePCR 4 when at a high resistance state. In this way, the logic states of the two data can be stored. -
FIG. 3 is a diagram illustrating a write operation of a conventional phase change resistant cell. - Heat is generated when a current flows between the
top electrode 1 and thebottom electrode 3 of thePCR 4 for a given amount of time. As a result, a state of thePCM 2 can be changed to be either crystalline or amorphous depending upon what temperature was applied between thetop electrode 1 and thebottom electrode 3. - When a low current flows for a given time, the PCM can become crystalline during a low temperature heating state so that the
PCR 4 can be set to a low resistive set state. On the other hand, when a high current flows for a given amount of time, the PCM can become amorphous due to the generated high temperature heating state so that thePCR 4 can be set to a high resistive reset state. A difference between two phases is representive of an electric resistance change. - A low voltage can be applied to the
PCR 4 for a relatively long time period in order to write the set state in a write mode. On the other hand, a high voltage can be applied to thePCR 4 for a relatively short time period in order to write the reset state in the write mode. - Various embodiments of the present invention are directed at providing a phase change memory device comprising a phase change resistor connected in parallel to two diodes in order to increase a write current flowing in a phase change resistor by two fold, thereby improving cell driving capacity.
- Various other embodiments of the present invention are directed at providing a phase change memory device comprising a phase change resistor connected in parallel to two diodes to reduce the cell size.
- Various other embodiments of the present invention are directed at applying a set voltage with a step-type waveform so that a phase change resistor may be crystallized.
- Various other embodiments of the present invention are directed at forming a phase change resistance cell over a SOT (Silicon On Insulator) substrate to insulate a silicon layer from the substrate with an oxide film without the need of using an additional process for insulating the silicon layer from the substrate.
- According to an embodiment of the present invention, a manufacturing method of a phase change memory device comprises: forming a first impurity region in a semiconductor substrate; forming a first insulating layer including a bottom electrode over the semiconductor substrate; forming a phase change layer and a top electrode connected to the bottom electrode over the first insulating layer; and forming a second impurity region in the first impurity region with the top electrode as an ion-implanting mask.
- According to an embodiment of the present invention, an operating method of a phase change memory device, which comprises: a cell array including a phase change resistor connected to a word line and a phase change resistance cell having first and second diodes connected between the phase change resistor and a bit line; and a write driving unit configured to supply a write voltage corresponding to data to be written to the cell array unit, comprises: activating a selected word line in a write mode; applying the write signal to a selected bit line. When the data corresponds to a reset state, the write signal has a reset voltage imposed at a reset time period. When the data corresponds to a set state, the write signal has a first set voltage imposed at a first set time period, followed by a second set voltage imposed at a second set time period, and followed by a third set voltage imposed at a third set time period.
- According to another embodiment of the present invention, the phase change memory device comprises: a first impurity region and a second impurity region formed alternately over a substrate; a phase change resistor connected to a top portion of the first impurity region; a bit line contact plug formed over the second impurity region; and a bit line connected in common to the bit line contact plug.
-
FIGS. 1 a and 1 b are diagrams illustrating a conventional phase change resistor. -
FIGS. 2 a and 2 b are diagrams illustrating a principle of the conventional phase change resistor. -
FIG. 3 is a diagram illustrating a write operation of a conventional phase change resistant cell. -
FIGS. 4 a to 4 h are cross-sectional diagrams illustrating a manufacturing method of a phase change memory device according to an embodiment of the present invention. -
FIG. 5 is a diagram illustrating a cell array of a phase change memory device according to an embodiment of the present invention. -
FIG. 6 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention. -
FIG. 7 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention. -
FIG. 8 is a timing diagram illustrating a read operation of a phase change memory device according to an embodiment of the present invention. -
FIG. 9 is a diagram illustrating a current level between sensing currents in a read mode. -
FIGS. 4 a to 4 h are cross-sectional diagrams illustrating a manufacturing method of a phase change memory device according to an embodiment of the present invention. - Referring to
FIG. 4 , a N-type substrate 10 which is a bare wafer is formed. Aninsulating layer 12 is shown formed over the N-type substrate 10. Theinsulating layer 12 can include an oxide film. - A
silicon layer 14 is formed over the insulatinglayer 12. As a result, a silicon-on-insulator (SOT) type substrate is prepared. Theinsulator layer 12 of the SOI type substrate may provide the is advantage of insulating thesilicon layer 14 from the N-type substrate 10 without the need for implementing any additional processes for insulating thesilicon layer 14 from the N-type substrate 10. - Referring to
FIG. 4 b, N+ type impurity ions are implanted into thesilicon layer 14 to form aN+ region 14 a. TheN+ region 14 a is positioned to form a structure of a PN diode D. TheN+ region 14 a may be obtained by ion-implanting N-type impurities such as As and P with high concentration. - Referring to
FIG. 4 c, aninsulating layer 16 is formed over theN+ region 14 a. Theinsulating layer 16 is selectively etched to form a plurality of contact holes (not shown) for exposing theN+ region 14 a which are separated with a given interval. A conductive film for bottom electrode is filled in the contact holes to form abottom electrode 18. - Referring to
FIG. 4 d, aphase change layer 20 is formed over the insulatinglayer 16 and thebottom electrode 18. Thephase change layer 20 can be any phase change material. Some preferred phase change materials are those selected from one of AgInSbTe and Ge2Sb2Te5 - Referring to
FIG. 4 e, a conductive film for top electrode is formed over thephase change layer 20. The conductive film for forming the top electrode is selectively etched to form atop electrode 22. Thephase change layer 20 is selectively etched with thetop electrode 22 as an etching mask to form aphase change layer 20 a overlapped with thebottom electrode 18. - As a result, a phase change resistor PCR is formed which includes the
bottom electrode 18, thephase change layer 20 a and thetop electrode 22. - Referring to
FIG. 4 f, P+ type impurity ions are implanted into theN+ region 14 a by using thetop electrode 22 as an ion-implanting mask to form aP+ region 24. TheP+ region 24 may be formed in a local bit line contact region connected to a bit line contact plug. - A PN diode D includes the
P+ region 24 and theN+ region 14 a. In the PN diode D, theP+ regions 24 are formed to be connected serially to theN+ regions 14 a in the same layer. That is, there is no space between theP+ region 24 and theN+ region 14 a to reduce a cell size. - Referring to
FIG. 4 g, an insulatinglayer 26 is formed over the resulting structure. The insulating layers 16 and 26 are selectively etched to form a plurality of contact holes (not shown) for exposing theP+ region 24. The insulating layers 16 and 26 are etched except a region where the phase change resistor PCR is formed. - A conductive film for bit line contact is filled in the contact holes to form a bit
line contact plug 28. - Referring to
FIG. 4 h, abit line 30 connected to the bitline contact plug 28 is formed over the insulatinglayer 26 and the bitline contact plug 28. A phase change resistance cell C including the phase change resistor PCR and the PN diode D is formed. - The
top electrodes 22 of the phase change resistors PCR are connected to a plurality of word lines WL0˜WL3, and thebottom electrodes 18 are connected to theN type regions 14 a of the PN diodes D. TheP type regions 24 of the PN diodes D are connected to thebit line 30 through the bitline contact plug 28. - That is, the
N type regions 14 a of the PN diodes D1, D2 are connected in common to thebottom electrodes 18. As a result, the PN diodes D1, D2 are connected in parallel between thebottom electrode 18 and thebit line 30 of the phase change resistor PCR. -
FIG. 5 is a diagram illustrating a cell array of a phase change memory device according to an embodiment of the present invention. - The phase change memory device includes a plurality of bit lines BL0˜BL3 arranged in a column direction and a plurality of word lines WL0˜WL3 arranged in a row direction. A plurality of unit cells C are arranged at intersections of the bit lines BL0˜BL3 and the word lines WL0˜WL3. The unit cell C includes a phase change resistor PCR and PN diodes D1, D2.
- The phase change resistor PCR has one terminal connected to the word line WL and the other terminal connected in common to a N type region of the PN diodes D1, D2. The PN diodes D1, D2 are arranged in parallel to the bit line BL. The PN diodes D1, D2 each have a P-type region connected in common to the bit line BL and each N type region connected to the other terminal of the phase change resistor PCR. In the phase change resistance cell C, a phase of the phase change resistor PCR is changed depending on a set current Iset and a reset current Ireset flowing in the bit line BL to write data.
- That is, the phase change resistor PCR includes the two diodes D1, D2 connected in parallel. The set current Iset or the reset Ireset flowing through each bit line BL is applied to the phase change resistor PCR through the two PN diodes D1, D2. As a result, a current flowing through the phase change resistor PCR is increased by twice which results in doubling the cell driving capacity.
- The sense amplifier S/A senses a cell data received through the bit line BL and compares the cell data with a reference voltage ref to distinguish a set data from a reset data. The reference current Iref flows in a reference voltage ref receiving terminal. When writing a data in the phase change resistance cell C, the write driving unit W/D supplies a write voltage corresponding to a data state to the bit line BL.
-
FIG. 6 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention. - In a write mode, the word line WL0 of the word lines WL0˜WL3 is selected. The word line WL0 is activated by transitioning from a high level to a low level during a write enable period T1. The other reset word lines WL1˜WL3 remain inactivated at a high level.
- The write driving unit W/D applies a write voltage to the corresponding bit line BL of the bit lines BL0˜BL3.
- When data is to be written as a set data, a set write voltage Vset is applied to the corresponding bit line BL for a set period T2. The set write voltage Vset is applied to the phase change resistor PCR through the PN diodes D1, D2 of the phase change resistance cell C. As a result, the set data is written in the phase change resistance cell C.
- When data is to be written as a reset data, a reset write voltage Vreset is applied to the corresponding bit line BL for a reset period T3. The reset write voltage Vreset is applied to the phase change resistor PCR through the PN diodes D1, D2 of the phase change resistance cell C. As a result, the reset data is written in the phase change resistance cell C.
- The set write voltage Vset and the reset write voltage Vreset can be applied as a single pulse. The set write voltage Vset has a voltage level lower than that of the reset write voltage Vreset. The set period T2 may be longer than the reset period T3.
-
FIG. 7 is a timing diagram illustrating a write operation of a phase change memory device according to an embodiment of the present invention. - In a write mode, the corresponding word line WL0 of the word lines WL0˜WL3 is selected. The word line WL0 is activated by transitioning from a high level to a low level during a write enable period T11. The other reset word lines WL1˜WL3 remain inactivated at a high level.
- The write driving unit W/D applies a write voltage to the is corresponding bit line BL of the bit lines BL0˜BL3.
- When a data to be written as a set data, set write voltages Vset_1˜Vset_3 are sequentially applied to the corresponding bit line BL for a set period T12. The set write voltages Vset_1˜Vset_3 are series of step pulses which decrease discretely.
- In the set period T12, the first set voltage Vset_1 is applied to the bit line BL for a first write time t1. The second set voltage Vset_2 is applied to the bit line BL for a second write time t2. The third set voltage Vset_3 is applied to the bit line BL for a third write time t3.
- The first set voltage Vset_1 has the same voltage level as that of the reset write voltage Vreset. The second set voltage Vset_2 has a voltage level lower than that of the first set voltage Vset_1. The third set voltage Vset_3 has a voltage level lower than that of the second set voltage Vset_2.
- When data to be written is a reset data, a reset write voltage Vreset is applied to the corresponding bit line BL for a reset period T13. The reset write voltage Vreset is applied to the phase change resistor PCR through the PN diodes D1, D2 of the phase change resistance cell C. As a result, the reset data is written in the phase change resistance cell C.
- The reset write voltage Vreset is applied as a single pulse. The set period T12 may be longer than the reset period T13.
-
FIG. 8 is a timing diagram illustrating a read operation of a phase change memory device according to an embodiment of the present invention. - In a read mode, the word line WL0 of the word lines WL0˜WL3 is selected. The word line WL0 is activated by transiting from a high level to a low level during a read enable period T21. The other reset word lines WL1˜WL3 remain inactivated at a high level.
- A read voltage Vread is applied to the corresponding bit line BL of the bit lines BL0˜BL3 for a sensing period T22. The set current Iset or the reset current Ireset flows toward the selected word line WL0 through the bit line BL, the phase change resistor PCR and the PN diodes D1, D2.
- The sense amplifier S/A senses a cell data received through the bit line BL and compares the reference current Tref with the set current Iset or the reset current Ireset to distinguish data “0” from data “1.”
-
FIG. 9 is a diagram illustrating a current level between sensing currents in a read mode. - In the read mode, the set current Iset has the largest current value, and the reset current Ireset has the smallest current value in a current level of the sensing current. The reference current Iref has a middle value of the values of the set current Iset and the reset current Ireset.
- As described above, according to an embodiment of the present invention, a phase change memory device comprises a phase change resistor connected in parallel to two diodes to increase a write current substantially doubles by flowing in a phase change resistor Thereby the present invention can enjoy an improved cell driving capacity.
- The phase change memory device comprises a phase change resistor connected in parallel to two diodes results in decreasing the cell size.
- In the phase change memory device, a set voltage is applied with a step-type waveform so that a phase change resistor may be crystallized.
- In the phase change memory device, a phase change resistance cell is formed over a SOI-type substrate that insulates a silicon layer from the substrate with an oxide film without the need for an additional fabrication process for insulating the silicon layer from the substrate.
- Although a number of illustrative embodiments consistent with the invention have been described, it should be understood that numerous other modifications and embodiments can be devised by those skilled in the art that will fall within the spirit and scope of the principles of this disclosure. More specifically, a number of variations and modifications are possible in the component parts and/or arrangements of the subject combinations arrangement within the scope of the disclosure, the drawings and the appended claims. In addition to variations and modifications in the component parts and/or arrangements, alternative uses will also be apparent to those skilled in the art.
Claims (4)
1. A phase change memory device comprising:
a first impurity region and a second impurity region formed alternately over a semiconductor substrate;
a phase change resistor connected to a top portion of the first impurity region;
a bit line contact plug formed over the second impurity region; and
a bit line connected in common to the bit line contact plug.
2. The phase change memory device according to claim 1 , wherein the phase change resistor includes:
a bottom electrode connected to the first impurity region;
a phase change layer formed over the bottom electrode; and
is a top electrode formed over the phase change layer.
3. The phase change memory device according to claim 2 , wherein the top electrode is connected to a word line.
4. The phase change memory device according to claim 1 , wherein the semiconductor substrate has a SOI structure comprising a first silicon layer, an insulating layer and a second silicon layer.
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US12/134,388 US7939365B2 (en) | 2007-09-06 | 2008-06-06 | Phase change memory device, manufacturing method thereof and operating method thereof |
US13/090,043 US20110193046A1 (en) | 2007-09-06 | 2011-04-19 | Phase change memory device, manufacturing method thereof and operating method thereof |
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KR101490429B1 (en) * | 2008-03-11 | 2015-02-11 | 삼성전자주식회사 | Resistive memory device and method for forming thereof |
KR101661306B1 (en) | 2010-02-23 | 2016-09-30 | 삼성전자 주식회사 | Semiconductor device, methods of fabrication the same |
CN101907785B (en) * | 2010-06-11 | 2015-09-16 | 上海华虹宏力半导体制造有限公司 | A kind of method for making of photomodulator PN junction |
US8885399B2 (en) * | 2011-03-29 | 2014-11-11 | Nxp B.V. | Phase change memory (PCM) architecture and a method for writing into PCM architecture |
JP2018163718A (en) * | 2017-03-24 | 2018-10-18 | 東芝メモリ株式会社 | Storage device and control method thereof |
FR3117258B1 (en) * | 2020-12-07 | 2023-12-22 | Commissariat Energie Atomique | SELECTOR DEVICE, RESISTIVE TYPE MEMORY DEVICE AND ASSOCIATED MANUFACTURING METHOD |
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US20030132501A1 (en) * | 2000-12-27 | 2003-07-17 | Manzur Gill | Phase-change memory cell using silicon on insulator |
US20050135140A1 (en) * | 2003-12-22 | 2005-06-23 | Hynix Semiconductor Inc. | Serial diode cell and nonvolatile memory device using the same |
US20060243973A1 (en) * | 2002-04-10 | 2006-11-02 | Micron Technology, Inc. | Thin film diode integrated with chalcogenide memory cell |
US20080277643A1 (en) * | 2007-05-11 | 2008-11-13 | Heon Yong Chang | Phase change memory device using pnp-bjt for preventing change in phase change layer composition and widening bit line sensing margin |
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US6903361B2 (en) * | 2003-09-17 | 2005-06-07 | Micron Technology, Inc. | Non-volatile memory structure |
KR100583115B1 (en) * | 2003-12-13 | 2006-05-23 | 주식회사 하이닉스반도체 | Phase change resistor cell, non-volatile memory device and contol method using the same |
KR20060001060A (en) * | 2004-06-30 | 2006-01-06 | 주식회사 하이닉스반도체 | Phase change ram device using pn diode and method of manufacturing the same |
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US20030132501A1 (en) * | 2000-12-27 | 2003-07-17 | Manzur Gill | Phase-change memory cell using silicon on insulator |
US20060243973A1 (en) * | 2002-04-10 | 2006-11-02 | Micron Technology, Inc. | Thin film diode integrated with chalcogenide memory cell |
US20050135140A1 (en) * | 2003-12-22 | 2005-06-23 | Hynix Semiconductor Inc. | Serial diode cell and nonvolatile memory device using the same |
US20080277643A1 (en) * | 2007-05-11 | 2008-11-13 | Heon Yong Chang | Phase change memory device using pnp-bjt for preventing change in phase change layer composition and widening bit line sensing margin |
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