US20100275808A1 - Gas generator containing a flash suppressant - Google Patents
Gas generator containing a flash suppressant Download PDFInfo
- Publication number
- US20100275808A1 US20100275808A1 US12/661,671 US66167110A US2010275808A1 US 20100275808 A1 US20100275808 A1 US 20100275808A1 US 66167110 A US66167110 A US 66167110A US 2010275808 A1 US2010275808 A1 US 2010275808A1
- Authority
- US
- United States
- Prior art keywords
- gas
- gas generating
- flame
- flame suppressant
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
- B60R21/26—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow
- B60R21/264—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow using instantaneous generation of gas, e.g. pyrotechnic
- B60R21/2644—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow using instantaneous generation of gas, e.g. pyrotechnic using only solid reacting substances, e.g. pellets, powder
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/04—Compositions characterised by non-explosive or non-thermic constituents for cooling the explosion gases including antifouling and flash suppressing agents
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R22/00—Safety belts or body harnesses in vehicles
- B60R22/18—Anchoring devices
- B60R22/195—Anchoring devices with means to tension the belt in an emergency, e.g. means of the through-anchor or splitted reel type
- B60R22/1954—Anchoring devices with means to tension the belt in an emergency, e.g. means of the through-anchor or splitted reel type characterised by fluid actuators, e.g. pyrotechnic gas generators
Definitions
- a solid or powdered flame suppressing additive selected from the group including manganese dioxide/copper oxide catalyst, palladium or other transitional metal catalysts and oxides thereof, and mixtures thereof, is added to a propellant bed inside a typical micro gas generator or any other gas generator.
- the propellant bed therefore contains a primary propellant, and the flame or flash suppressing agent is essentially sprinkled or comingled amidst the propellant in heterogeneous relationship therewith.
- any known propellant may incorporate a flame suppressant additive within the propellant bed wherein the propellant and the additive constitute distinct solid phases within the propellant bed given that the flame suppressant is added separately from the gas generant. There is no mixing of the flame suppressant and the gas generant.
- the flame suppressant is simply sprinkled in juxtaposed relationship to the gas generant wherein the gas generant is preferably in tablet form.
- the flame suppressant may be added to the gas generant bed to thereby result in the flame suppressant being distributed about the gas generant tablets in juxtaposed relationship therewith.
- any gas generator may include the additive contained in the propellant bed and added during manufacture of the gas generator.
- the additive is applied directly over and within the propellant or nitrocellulose bed thereby mitigating the flame and flash front propagation of the propellant upon combustion thereof.
- the additive may be heterogeneously interspersed about the nitrocellulose or any other propellant suitable for use within a gas generator for vehicle occupant protection systems whereby the primary propellant and the additive are essentially different contiguous phases of a solid mixture.
- FIG. 1 is a typical airbag inflator system comprising a propellant bed, a gas generant, and a flame suppressant in accordance with the present invention.
- FIG. 2 is a gas generating system comprising an inflator, wherein the gas generating system is a vehicle occupant protection system in this embodiment.
- FIG. 3 is a sectional view of a typical seatbelt pretensioner containing a micro gas generator, the gas generator containing a propellant and a flame suppressant in accordance with the present invention.
- FIG. 4 is a view of a seatbelt pretensioner of FIG. 3 mechanically coupled to a seatbelt reel wherein the seatbelt pretensioner contains a propellant and a flame suppressant in accordance with the present invention.
- FIG. 5 is a schematic view of a gas generating system containing a seatbelt pretensioner in accordance with the present invention, wherein the gas generating system is a seatbelt assembly in this embodiment.
- a gas generant known for its utility in various safety systems within automobiles, aircraft, and/or sea crafts for example is housed within a gas generator also known for its utility in the respective application.
- a vehicle occupant protection system exemplifies a typical environment or gas generating system that houses one or more gas generators or inflators employing the present invention.
- a typical airbag inflator as exemplified in U.S. Pat. Nos. 5,934,705, 6,422,601, 6,547,277, or any other known airbag inflator may incorporate any known gas generant also recognized for its utility in an airbag inflator.
- FIG. 1 exemplifies a typical airbag inflator 10 containing a primary gas generant 12 and a flame suppressant 14 in heterogeneous relation therewith.
- FIG. 2 exemplifies a gas generating system 16 including the airbag inflator 10 and an airbag 18 inflated upon gas generator 10 activation. Although not hereby limited, the gas generating system 16 is representative of a typical vehicle occupant protection system as otherwise known in the art.
- FIG. 3 exemplifies a typical seatbelt pretensioner 20 containing a micro gas generator 22 containing a propellant 24 and a flame suppressant and/or carbon monoxide reducing catalyst 26 .
- FIG. 4 illustrates a seatbelt assembly 28 containing the seatbelt pretensioner 20 of FIG.
- FIG. 5 exemplifies a gas generating system 32 including the seatbelt assembly 28 .
- the gas generating system 32 is representative of a typical seatbelt assembly 28 or in the alternative, a vehicle occupant protection system 34 containing the seatbelt assembly 28 wherein the vehicle occupant protection system is otherwise manufactured as known in the art.
- a solid or powdered flame suppressing additive such as manganese dioxide/copper oxide catalyst available as Hopcalite®, provided by Drager of Germany for example, is added to a propellant bed inside a typical micro gas generator or any other gas generator.
- Other solid flame suppressants include powdered, granulated, extruded, or crushed transitional metals selected from the group including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an oxide of a transitional metal selected from the group including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an alkali metal such as sodium or potassium and a mixture containing two or more constituents selected from one or more of the groups including transitional metals, oxides of transitional metals, and alkali metals.
- the flame suppressant may also be carried by a substrate such as on ceramic beads.
- the metal materials may be in their normal metal form or ionic form.
- the propellant bed therefore contains a primary propellant otherwise characterized as a gas generant or gas generating composition, and the flame or flash suppressing agent is essentially sprinkled amidst the propellant in heterogeneous relationship with the propellant.
- the additive is not combined or mixed with the propellant into one composition, but instead augments the propellant to reduce the flame front without adversely affecting the gas generated.
- gas generating composition is defined to be a compound or a fuel/oxidizer combination that when combusted can independently sustain combustion to produce adequate amounts of gas to activate a gas generator or other gas generating system or device, for example.
- Nitrocellulose exemplifies a compound that may be independently combusted as a gas generating composition to activate a seatbelt pretensioner.
- Other well known gas generating compositions contain at least a fuel and an oxidizer that must be homogeneously mixed or combined to form a homogeneous mixture that will uniformly and independently combust when ignited.
- composition when used in this context (e.g. gas generating composition) therefore indicates and requires that the constituents of a “composition” be mixed in a homogeneous, uniform, and non-heterogeneous manner.
- composition is defined to be a homogeneous, uniform, and well-mixed combination of the constituents that make up the composition.
- a primary propellant composition would typically include at least a fuel and an oxidizer homogeneously mixed to ensure a uniform combination, and a substantially complete and uniform combustion upon activation thereof.
- the simple placement of the flash suppressing agent in juxtaposed relationship to the primary propellant in the propellant bed therefore does not result in one composition, but results in: (1) either two separate and distinct compounds such as nitrocellulose as a gas generating composition and molybdenum as a flash suppressing agent; or, (2) a gas generating composition separate and distinct from a flash suppressing compound such as a gas generating composition containing a fuel and an oxidizer, and molybdenum as a flash suppressing compound; or, (3) a gas generating composition separate and distinct from a flash suppressing composition such as a gas generating composition containing a fuel and an oxidizer, and a molybdenum dioxide/cupric oxide flash suppressing composition.
- homogeneous when used in the context of a “homogeneous composition” is defined as having a substantially uniform distribution of the constituents that make up the composition, throughout the composition. Accordingly, in a homogeneous composition in accordance with the present invention, the constituents are well-mixed or otherwise combined to form an intimate and substantially uniform distribution of the constituents of the composition, throughout the composition. It will be appreciated that as known in the art, gas generanting compositions are known to be well-mixed or otherwise combined to have a uniform or homogeneous distribution of the constituents throughout the gas generating composition. This is particularly important given the need to have consistent burn rates and consistent combustion profiles associated with each gas generating composition, thereby ensuring the predictability of the performance of the respective gas generating composition.
- heterogeneous when used in the context of “heterogeneous relationship” is defined as having a substantially non-uniform distribution of the constituents that are in heterogeneous relationship (or that make up an associated poorly mixed mixture described as being in heterogeneous relationship), throughout the associated poorly mixed mixture.
- the respective gas generating composition and the respective flash suppressing agent are operably separate and distinct, and are employed to individually produce gas and to suppress the combustion flash, respectively.
- any known propellant within a propellant bed may incorporate a flame suppressant additive within the propellant bed wherein the propellant and the additive constitute distinct solid phases within the propellant bed, in juxtaposed or heterogeneous relationship to each other, but not in a homogeneous relationship to each other. Accordingly, gas generating compositions need not be tailored to address customer requirements of flame propagation reduction. Rather, a flame suppressant additive may be added to a gas generator in any respective application thereby avoiding the need to redesign the gas generant responsive to customer requirements.
- the amount or quantity of the flash suppressant additive generally ranges from 50-300 mg and eliminates or reduces the intensity of flash and/or flame output from the device in which the gas generator is installed.
- the gas generant is provided at about 65-98% by weight, and the additive is provided at about 2-35% by weight, whereby the weight percents are calculated with regard to the combined weight of the gas generant and additive combined within the propellant bed.
- any gas generant contemplated for use within a gas generator is first evaluated for flame propagation. Flame propagation may be determined as given in Examples 1-11, or as given in Examples 12-15, but may also be determined as otherwise known in the art. Certain evaluations are a normal part of the development or design of gas generators as used in various contexts prior to customer approval. For example, the various characteristics of the combustion profile such as gas exit temperature, effluent content, total solids produced, and so forth are routinely determined as part of an airbag inflator gas generant development. Flame evaluation is also easily included in the evaluation, or, may alternatively be evaluated separately on an iterative basis depending on the type of gas generant composition.
- the need for a flame suppressant additive may be determined as defined by customer requirements.
- the present invention therefore provides for addition of a flame suppressant as needed and as determined by preliminary evaluations that are a normal and well understood part of the design process.
- seatbelt pretensioners often included in a vehicle occupant protection system, realize particular benefit from the present invention.
- a seatbelt is automatically tensioned to tighten the slack of the seatbelt found during normal operating conditions.
- the housing of the seatbelt pretensioner is preferably designed to be relatively small, thereby reducing the overall weight of the seatbelt assembly and also reducing the raw materials and cost of each assembly. As such, the housing is not necessarily as robust and therefore may be damaged upon pretensioner activation.
- a more cost-effective gas generant or propellant is preferably used for relatively less complicated applications, within a micro gas generator in a seatbelt pretensioner, for example.
- U.S. Pat. Nos. 6,419,177, 6,460,794, and 6,520,443 are herein incorporated by reference and exemplify typical seatbelt pretensioners useful in vehicle occupant protection systems. Nitrocellulose exemplifies one typical propellant useful in seatbelt pretensioners. Exemplary benefits of the present application are illustrated in the examples given.
- a seatbelt pretensioner as described in U.S. Pat. No. 6,213,513, herein incorporated by reference, was mounted on a rigid structure and fired open air, either unrestrained to permit pretensioning action or fixed for zero pretensioning. High speed video was used to detect and evaluate flaming external of the devices during pretensioner activation.
- the micro gas generator of the pretensioner was charged with about 700 mg of nitrocellulose.
- the amount of flame suppressing additive employed in each example, that is Manganese dioxide/copper oxide or Hopcalite®, is indicated in the table given below.
- a combustion flame is always apparent when the flame suppressing additive is not employed. However, when a flame suppressing additive is employed, a combustion flame does not result about the exterior of the pretensioner.
- Micro Gas Generator Vented Bomb Test The micro gas generators of examples 12-15 are typically employed in pretensioners as described in Examples 1-11. Each micro gas generator of examples 12-15 was installed in a 10 cc bomb with a hole in the side, the hole sized to control the combustion pressure, such that it emulates the combustion environment typically found within a seatbelt pretensioner. The hole also functions to vent the combustion gases.
- the bomb was mounted to a rigid structure and fired open air. High speed video was used to detect and evaluate the flame emitted from the bomb vent, flame normally attendant to the combustion of the gas generant. The flame length is expressed in relative units as determined from the video. Accordingly, the examples show the relative lengths of the flame for comparative purposes.
- Example MnO 2 /CuO Nitrocellulose (mg) Flame Length 12 0 700 76 13 0 700 71 14 150 700 59 15 150 700 53
- Examples 12-15 indicate that the use of the flame suppressant results in a flame length about 24% shorter than indicated without the flame suppressant. Stated another way, examples 12-15 illustrate the ability to mitigate or reduce the flame front propagation normally attendant to combustion of the gas generator propellant.
- the present invention may also be defined as a gas generating system to include the vehicle occupant protection systems defined above.
- the present invention includes a gas generator including a gas generant, wherein actuation of the gas generator results in a flame front upon actuation and combustion of the gas generant.
- the addition of the flame suppressant additive may either reduce the total combustible products resulting from the combustion reaction, or may also function by reducing the gas exit temperature of the inflator thereby ultimately reducing the flame front resulting from combustion of the gas generant.
- examples 16 and 17 illustrate the reduction of carbon monoxide by adding Hopcalite to a bed of nitrocellulose.
- Each micro gas generator of examples 16 and 17 was installed in a 10 cc bomb with a hole in the side, the hole sized to control the combustion pressure, such that it emulates the combustion environment typically found within a seatbelt pretensioner. The hole also functions to vent the combustion gases.
- the bomb was placed inside a 100 cubic foot chamber and fired. Effluents were measured using. FTIR.
- the addition of the catalyst/flame suppressant Hopcalite results in a 15 to 20% reduction in carbon monoxide over time and at least 25% reduction at peak combustion. It is therefore believed that the reduction in carbon monoxide through catalytic oxidation of the same results in not only safer levels of carbon monoxide, but also a reduction in the flame propagation.
- a preferred gas generating system includes a seatbelt pretensioner within a vehicle occupant protection system wherein the gas generant includes nitrocellulose and the additive includes the crushed or powdered Manganese dioxide/copper oxide catalyst as provided by Drager of Germany having the trade name Hopcalite®.
- the gas generant includes nitrocellulose and the additive includes the crushed or powdered Manganese dioxide/copper oxide catalyst as provided by Drager of Germany having the trade name Hopcalite®.
- Other manufacturers of powdered, crushed, or pulverized manganese dioxide and copper oxide includes Carus Chemical Co. at www.caruschem.com (Carulite® 300 Granular), and Molecular Products Limited at www.molecularproducts.co.uk (Moleculite®).
- Another preferred flash suppressant includes platinum, palladium, and tin oxide produced by Molecular Products Limited (Sofnocat).
- Yet another preferred flash suppressant includes manganese dioxide, copper oxide, and aluminum oxide also produced by Carus Chemical Co. (Carulite® 300 Extruded).
- the nitrocellulose is provided at about 650 to 750 milligrams within the gas generator propellant bed and the flash suppressant is sprinkled or distributed about the nitrocellulose within the propellant bed at about 30 to 150 milligrams.
- a method of reducing the flame front and/or reducing carbon monoxide typically resulting upon actuation of a gas generating system includes loading a gas generator, one typically used within a vehicle occupant protection system or seatbelt assembly, for example.
- a propellant or gas generating composition is inserted within a propellant chamber of the gas generator.
- a catalyst is distributed within the propellant chamber either before or after inserting the propellant within the propellant chamber, wherein the catalyst is selected from the group consisting of transitional metals, transitional metal oxides, and mixtures thereof.
- the catalyst is provided in an amount determined to reduce the carbon monoxide produced upon activation of the gas generator, wherein the catalyst or flame suppressant is comingled amidst the propellant in heterogeneous relationship with the propellant.
- the flame suppressant is preferably selected from the group consisting of transitional metals including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; transitional metal oxides selected from the group of oxides formed with metals selected from the group consisting of copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an alkali metal selected from the group consisting of sodium or potassium; and a mixture containing two or more constituents selected from one or more of the groups selected from the group consisting of transitional metals, oxides of transitional metals, and alkali metals.
- transitional metals including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum,
- the catalyst or flame suppressant preferably constitutes about 2 to 35% by weight and the gas generant preferably constitutes about 65 to 98% by weight, the weight percents based on the combined weight of the gas generant and the catalyst.
- gas generant constituents and the catalysts of the present invention are provided by known suppliers or manufactured as known in the art.
- the present inflator is described as preferably including a nitrocellulose-based propellant within a micro gas generator of a seatbelt pretensioner, the principles of the present invention are applicable in other gas generating environments such as within an airbag inflator system as known in the art. It is therefore contemplated that the use of the additives characterized above could be employed in a vehicle occupant protection system by iteratively determining desired design criteria such as flame length or flame duration, the composition of the gas effluent, and other criteria as the amount of additive is varied in an otherwise identical airbag inflator. The amount of additive may be varied based on the required design criteria. Thus, those skilled in the art will appreciate that various modifications could be made to the presently disclosed embodiments without departing from the scope of the present invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Air Bags (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
Flame suppressants or catalysts, independent of the gas generant composition, reduce the flame front and carbon monoxide produced by combustion of gas generating compositions employed within gas generating systems such as vehicle occupant restraint systems, for example. Heterogeneous distribution of the flash suppressant and the gas generant within the gas generant bed facilitates, upon gas generator activation, a reduction in flame front of any known gas generant without reformulating the gas generating composition.
Description
- This application is a continuation-in-part of co-pending U.S. application Ser. No. 10/940,395 filed on Sep. 13, 2004 which claims the benefit of U.S. Provisional Application Ser. No. 60/591,314 filed on Jul. 27, 2004.
- Micro gas generators useful in vehicle occupant protection systems, within seatbelt pretensioners for example, typically use nitrocellulose or other pyrotechnic gas generants or propellants to generate gas for activating devices such as seatbelt pretensioners. When actuated, gas generators often produce a flame front potentially resulting in damage to the surrounding housing and gas generating assembly. Seatbelt pretensioners, for example, are often damaged beyond repair or, damaged and thereby substantially reducing the salvage value of the seatbelt assembly. Accordingly, after a crash event, the seatbelt pretensioner or seatbelt assembly may require overall replacement rather than simple replacement of selected parts. Other gas generator applications including airbag inflators, and lifeboat or aircraft inflatables also may exhibit the same flame front combustion phenomenon. Because of potential disadvantages relative to the existence of flame, such as the integrity of the seal in an inflatable lifeboat for example, other applications would benefit from gas generant compositions that did not result in the flame front propagation normally attendant when many known gas generant compositions are combusted.
- Yet another concern is the production of carbon monoxide upon gas generant combustion, particularly with regard to the use of carbon-containing propellants such as nitrocellulose. Although desirable because of its cost and because of its ability to produce required amounts of gas, nitrocellulose and other gas generants may produce undesirable amounts of carbon monoxide in certain gas generant applications.
- In accordance with the present invention, a solid or powdered flame suppressing additive, selected from the group including manganese dioxide/copper oxide catalyst, palladium or other transitional metal catalysts and oxides thereof, and mixtures thereof, is added to a propellant bed inside a typical micro gas generator or any other gas generator. The propellant bed therefore contains a primary propellant, and the flame or flash suppressing agent is essentially sprinkled or comingled amidst the propellant in heterogeneous relationship therewith. Stated another way, any known propellant may incorporate a flame suppressant additive within the propellant bed wherein the propellant and the additive constitute distinct solid phases within the propellant bed given that the flame suppressant is added separately from the gas generant. There is no mixing of the flame suppressant and the gas generant. Rather, the flame suppressant is simply sprinkled in juxtaposed relationship to the gas generant wherein the gas generant is preferably in tablet form. As a result, the flame suppressant may be added to the gas generant bed to thereby result in the flame suppressant being distributed about the gas generant tablets in juxtaposed relationship therewith.
- In practice, any gas generator may include the additive contained in the propellant bed and added during manufacture of the gas generator. The additive is applied directly over and within the propellant or nitrocellulose bed thereby mitigating the flame and flash front propagation of the propellant upon combustion thereof. Accordingly, in a preferred embodiment, the additive may be heterogeneously interspersed about the nitrocellulose or any other propellant suitable for use within a gas generator for vehicle occupant protection systems whereby the primary propellant and the additive are essentially different contiguous phases of a solid mixture.
-
FIG. 1 is a typical airbag inflator system comprising a propellant bed, a gas generant, and a flame suppressant in accordance with the present invention. -
FIG. 2 is a gas generating system comprising an inflator, wherein the gas generating system is a vehicle occupant protection system in this embodiment. -
FIG. 3 is a sectional view of a typical seatbelt pretensioner containing a micro gas generator, the gas generator containing a propellant and a flame suppressant in accordance with the present invention. -
FIG. 4 is a view of a seatbelt pretensioner ofFIG. 3 mechanically coupled to a seatbelt reel wherein the seatbelt pretensioner contains a propellant and a flame suppressant in accordance with the present invention. -
FIG. 5 is a schematic view of a gas generating system containing a seatbelt pretensioner in accordance with the present invention, wherein the gas generating system is a seatbelt assembly in this embodiment. - In accordance with the present invention, a gas generant known for its utility in various safety systems within automobiles, aircraft, and/or sea crafts for example, is housed within a gas generator also known for its utility in the respective application. A vehicle occupant protection system exemplifies a typical environment or gas generating system that houses one or more gas generators or inflators employing the present invention. A typical airbag inflator as exemplified in U.S. Pat. Nos. 5,934,705, 6,422,601, 6,547,277, or any other known airbag inflator may incorporate any known gas generant also recognized for its utility in an airbag inflator. U.S. Pat. Nos. 5,035,757, 6,074,502, 6,210,505, 6,306,232, and other known airbag inflator propellants exemplify, but do not limit the gas generant compositions believed useful in the context of the present invention. Each patent discussed herein is incorporated by reference in its entirety.
-
FIG. 1 exemplifies atypical airbag inflator 10 containing a primary gas generant 12 and a flame suppressant 14 in heterogeneous relation therewith.FIG. 2 exemplifies a gas generating system 16 including theairbag inflator 10 and anairbag 18 inflated upongas generator 10 activation. Although not hereby limited, the gas generating system 16 is representative of a typical vehicle occupant protection system as otherwise known in the art.FIG. 3 exemplifies atypical seatbelt pretensioner 20 containing amicro gas generator 22 containing apropellant 24 and a flame suppressant and/or carbonmonoxide reducing catalyst 26.FIG. 4 illustrates aseatbelt assembly 28 containing theseatbelt pretensioner 20 ofFIG. 3 mechanically coupled to aseatbelt reel 30.FIG. 5 exemplifies agas generating system 32 including the seatbeltassembly 28. Although not hereby limited, thegas generating system 32 is representative of atypical seatbelt assembly 28 or in the alternative, a vehicle occupant protection system 34 containing theseatbelt assembly 28 wherein the vehicle occupant protection system is otherwise manufactured as known in the art. - As shown in the figures, a solid or powdered flame suppressing additive, such as manganese dioxide/copper oxide catalyst available as Hopcalite®, provided by Drager of Germany for example, is added to a propellant bed inside a typical micro gas generator or any other gas generator. Other solid flame suppressants include powdered, granulated, extruded, or crushed transitional metals selected from the group including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an oxide of a transitional metal selected from the group including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an alkali metal such as sodium or potassium and a mixture containing two or more constituents selected from one or more of the groups including transitional metals, oxides of transitional metals, and alkali metals. The flame suppressant may also be carried by a substrate such as on ceramic beads. The metal materials may be in their normal metal form or ionic form.
- The propellant bed therefore contains a primary propellant otherwise characterized as a gas generant or gas generating composition, and the flame or flash suppressing agent is essentially sprinkled amidst the propellant in heterogeneous relationship with the propellant. As such, the additive is not combined or mixed with the propellant into one composition, but instead augments the propellant to reduce the flame front without adversely affecting the gas generated. In accordance with the present invention, the term “gas generating composition” is defined to be a compound or a fuel/oxidizer combination that when combusted can independently sustain combustion to produce adequate amounts of gas to activate a gas generator or other gas generating system or device, for example. Nitrocellulose exemplifies a compound that may be independently combusted as a gas generating composition to activate a seatbelt pretensioner. Other well known gas generating compositions contain at least a fuel and an oxidizer that must be homogeneously mixed or combined to form a homogeneous mixture that will uniformly and independently combust when ignited.
- The term “composition” when used in this context (e.g. gas generating composition) therefore indicates and requires that the constituents of a “composition” be mixed in a homogeneous, uniform, and non-heterogeneous manner. Stated another way, in accordance with the present invention, the term “composition” is defined to be a homogeneous, uniform, and well-mixed combination of the constituents that make up the composition. For example, a primary propellant composition would typically include at least a fuel and an oxidizer homogeneously mixed to ensure a uniform combination, and a substantially complete and uniform combustion upon activation thereof. The simple placement of the flash suppressing agent in juxtaposed relationship to the primary propellant in the propellant bed therefore does not result in one composition, but results in: (1) either two separate and distinct compounds such as nitrocellulose as a gas generating composition and molybdenum as a flash suppressing agent; or, (2) a gas generating composition separate and distinct from a flash suppressing compound such as a gas generating composition containing a fuel and an oxidizer, and molybdenum as a flash suppressing compound; or, (3) a gas generating composition separate and distinct from a flash suppressing composition such as a gas generating composition containing a fuel and an oxidizer, and a molybdenum dioxide/cupric oxide flash suppressing composition.
- The term “homogeneous” when used in the context of a “homogeneous composition” is defined as having a substantially uniform distribution of the constituents that make up the composition, throughout the composition. Accordingly, in a homogeneous composition in accordance with the present invention, the constituents are well-mixed or otherwise combined to form an intimate and substantially uniform distribution of the constituents of the composition, throughout the composition. It will be appreciated that as known in the art, gas generanting compositions are known to be well-mixed or otherwise combined to have a uniform or homogeneous distribution of the constituents throughout the gas generating composition. This is particularly important given the need to have consistent burn rates and consistent combustion profiles associated with each gas generating composition, thereby ensuring the predictability of the performance of the respective gas generating composition.
- The term “heterogeneous” when used in the context of “heterogeneous relationship” is defined as having a substantially non-uniform distribution of the constituents that are in heterogeneous relationship (or that make up an associated poorly mixed mixture described as being in heterogeneous relationship), throughout the associated poorly mixed mixture.
- In each variant, the respective gas generating composition and the respective flash suppressing agent, whether they be compositions or compounds, are operably separate and distinct, and are employed to individually produce gas and to suppress the combustion flash, respectively.
- Stated another way, any known propellant within a propellant bed may incorporate a flame suppressant additive within the propellant bed wherein the propellant and the additive constitute distinct solid phases within the propellant bed, in juxtaposed or heterogeneous relationship to each other, but not in a homogeneous relationship to each other. Accordingly, gas generating compositions need not be tailored to address customer requirements of flame propagation reduction. Rather, a flame suppressant additive may be added to a gas generator in any respective application thereby avoiding the need to redesign the gas generant responsive to customer requirements.
- Given a basis of about 650 to 750 mg of gas generant or nitrocellulose, the amount or quantity of the flash suppressant additive generally ranges from 50-300 mg and eliminates or reduces the intensity of flash and/or flame output from the device in which the gas generator is installed. Stated another way, the gas generant is provided at about 65-98% by weight, and the additive is provided at about 2-35% by weight, whereby the weight percents are calculated with regard to the combined weight of the gas generant and additive combined within the propellant bed.
- In practice, any gas generant contemplated for use within a gas generator is first evaluated for flame propagation. Flame propagation may be determined as given in Examples 1-11, or as given in Examples 12-15, but may also be determined as otherwise known in the art. Certain evaluations are a normal part of the development or design of gas generators as used in various contexts prior to customer approval. For example, the various characteristics of the combustion profile such as gas exit temperature, effluent content, total solids produced, and so forth are routinely determined as part of an airbag inflator gas generant development. Flame evaluation is also easily included in the evaluation, or, may alternatively be evaluated separately on an iterative basis depending on the type of gas generant composition. Accordingly, as the gas generant composition varies, the need for a flame suppressant additive may be determined as defined by customer requirements. The present invention therefore provides for addition of a flame suppressant as needed and as determined by preliminary evaluations that are a normal and well understood part of the design process.
- In particular, seatbelt pretensioners, often included in a vehicle occupant protection system, realize particular benefit from the present invention. During a crash event, a seatbelt is automatically tensioned to tighten the slack of the seatbelt found during normal operating conditions. The housing of the seatbelt pretensioner is preferably designed to be relatively small, thereby reducing the overall weight of the seatbelt assembly and also reducing the raw materials and cost of each assembly. As such, the housing is not necessarily as robust and therefore may be damaged upon pretensioner activation.
- Oftentimes, a more cost-effective gas generant or propellant is preferably used for relatively less complicated applications, within a micro gas generator in a seatbelt pretensioner, for example. U.S. Pat. Nos. 6,419,177, 6,460,794, and 6,520,443 are herein incorporated by reference and exemplify typical seatbelt pretensioners useful in vehicle occupant protection systems. Nitrocellulose exemplifies one typical propellant useful in seatbelt pretensioners. Exemplary benefits of the present application are illustrated in the examples given.
- For each example tabulated below, a seatbelt pretensioner as described in U.S. Pat. No. 6,213,513, herein incorporated by reference, was mounted on a rigid structure and fired open air, either unrestrained to permit pretensioning action or fixed for zero pretensioning. High speed video was used to detect and evaluate flaming external of the devices during pretensioner activation. The micro gas generator of the pretensioner was charged with about 700 mg of nitrocellulose. The amount of flame suppressing additive employed in each example, that is Manganese dioxide/copper oxide or Hopcalite®, is indicated in the table given below.
-
Flame Example MnO2/CuO (mg) Nitrocellulose (mg) Duration (ms) 1 0 700 2 2 0 700 2 3 0 700 1 4 0 700 13 5 0 700 1 6 0 700 1 7 0 700 1 8 0 700 1 9 150 700 0 10 150 700 0 11 150 700 0 - As shown, a combustion flame is always apparent when the flame suppressing additive is not employed. However, when a flame suppressing additive is employed, a combustion flame does not result about the exterior of the pretensioner.
- Micro Gas Generator Vented Bomb Test—The micro gas generators of examples 12-15 are typically employed in pretensioners as described in Examples 1-11. Each micro gas generator of examples 12-15 was installed in a 10 cc bomb with a hole in the side, the hole sized to control the combustion pressure, such that it emulates the combustion environment typically found within a seatbelt pretensioner. The hole also functions to vent the combustion gases. The bomb was mounted to a rigid structure and fired open air. High speed video was used to detect and evaluate the flame emitted from the bomb vent, flame normally attendant to the combustion of the gas generant. The flame length is expressed in relative units as determined from the video. Accordingly, the examples show the relative lengths of the flame for comparative purposes.
-
Example MnO2/CuO (mg) Nitrocellulose (mg) Flame Length 12 0 700 76 13 0 700 71 14 150 700 59 15 150 700 53
Examples 12-15 indicate that the use of the flame suppressant results in a flame length about 24% shorter than indicated without the flame suppressant. Stated another way, examples 12-15 illustrate the ability to mitigate or reduce the flame front propagation normally attendant to combustion of the gas generator propellant. - The present invention may also be defined as a gas generating system to include the vehicle occupant protection systems defined above. In essence, the present invention includes a gas generator including a gas generant, wherein actuation of the gas generator results in a flame front upon actuation and combustion of the gas generant. It is believed that the addition of the flame suppressant additive may either reduce the total combustible products resulting from the combustion reaction, or may also function by reducing the gas exit temperature of the inflator thereby ultimately reducing the flame front resulting from combustion of the gas generant. To illustrate, examples 16 and 17 illustrate the reduction of carbon monoxide by adding Hopcalite to a bed of nitrocellulose.
- Each micro gas generator of examples 16 and 17 was installed in a 10 cc bomb with a hole in the side, the hole sized to control the combustion pressure, such that it emulates the combustion environment typically found within a seatbelt pretensioner. The hole also functions to vent the combustion gases. The bomb was placed inside a 100 cubic foot chamber and fired. Effluents were measured using. FTIR.
-
CO ppm CO ppm, Example MnO2/CuO (mg) NC (mg) 30 min TWA peak *16 0 700 75 83 17 150 700 60 61 *average of six tests - As shown above, the addition of the catalyst/flame suppressant Hopcalite results in a 15 to 20% reduction in carbon monoxide over time and at least 25% reduction at peak combustion. It is therefore believed that the reduction in carbon monoxide through catalytic oxidation of the same results in not only safer levels of carbon monoxide, but also a reduction in the flame propagation.
- In accordance with the present invention, a preferred gas generating system includes a seatbelt pretensioner within a vehicle occupant protection system wherein the gas generant includes nitrocellulose and the additive includes the crushed or powdered Manganese dioxide/copper oxide catalyst as provided by Drager of Germany having the trade name Hopcalite®. Other manufacturers of powdered, crushed, or pulverized manganese dioxide and copper oxide includes Carus Chemical Co. at www.caruschem.com (Carulite® 300 Granular), and Molecular Products Limited at www.molecularproducts.co.uk (Moleculite®). Another preferred flash suppressant includes platinum, palladium, and tin oxide produced by Molecular Products Limited (Sofnocat). Yet another preferred flash suppressant includes manganese dioxide, copper oxide, and aluminum oxide also produced by Carus Chemical Co. (Carulite® 300 Extruded). The nitrocellulose is provided at about 650 to 750 milligrams within the gas generator propellant bed and the flash suppressant is sprinkled or distributed about the nitrocellulose within the propellant bed at about 30 to 150 milligrams.
- In yet another aspect of the invention, a method of reducing the flame front and/or reducing carbon monoxide typically resulting upon actuation of a gas generating system is provided. The method includes loading a gas generator, one typically used within a vehicle occupant protection system or seatbelt assembly, for example. A propellant or gas generating composition is inserted within a propellant chamber of the gas generator. Additionally, a catalyst is distributed within the propellant chamber either before or after inserting the propellant within the propellant chamber, wherein the catalyst is selected from the group consisting of transitional metals, transitional metal oxides, and mixtures thereof. Further, the catalyst is provided in an amount determined to reduce the carbon monoxide produced upon activation of the gas generator, wherein the catalyst or flame suppressant is comingled amidst the propellant in heterogeneous relationship with the propellant.
- The flame suppressant is preferably selected from the group consisting of transitional metals including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; transitional metal oxides selected from the group of oxides formed with metals selected from the group consisting of copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an alkali metal selected from the group consisting of sodium or potassium; and a mixture containing two or more constituents selected from one or more of the groups selected from the group consisting of transitional metals, oxides of transitional metals, and alkali metals.
- Further, the catalyst or flame suppressant preferably constitutes about 2 to 35% by weight and the gas generant preferably constitutes about 65 to 98% by weight, the weight percents based on the combined weight of the gas generant and the catalyst.
- Finally, the gas generant constituents and the catalysts of the present invention are provided by known suppliers or manufactured as known in the art.
- The present description is for illustrative purposes only, and should not be construed to limit the breadth of the present invention in any way. Although the present inflator is described as preferably including a nitrocellulose-based propellant within a micro gas generator of a seatbelt pretensioner, the principles of the present invention are applicable in other gas generating environments such as within an airbag inflator system as known in the art. It is therefore contemplated that the use of the additives characterized above could be employed in a vehicle occupant protection system by iteratively determining desired design criteria such as flame length or flame duration, the composition of the gas effluent, and other criteria as the amount of additive is varied in an otherwise identical airbag inflator. The amount of additive may be varied based on the required design criteria. Thus, those skilled in the art will appreciate that various modifications could be made to the presently disclosed embodiments without departing from the scope of the present invention.
Claims (14)
1. A gas generating system comprising:
a gas generator for generating gas;
a propellant chamber within said gas generator;
a gas generating composition within said propellant chamber combustible to produce gas and a flame front; and
a flame suppressant distributed about said gas generating composition within said propellant chamber in heterogeneous, separate, and distinct relationship to said gas generating composition;
wherein said gas generating composition and said flame suppressant each define a first and a second solid phase, respectively, said first and second solid phases distinct from each other wherein the flame suppressant and the gas generating composition are not combined into one composition.
2. The gas generating system of claim 1 wherein said gas generating composition comprises nitrocellulose.
3. The gas generating system of claim 1 comprising a pretensioner.
4. The gas generating system of claim 1 comprising an airbag inflator.
5. The gas generating system of claim 1 wherein said gas generating system is a vehicle occupant protection system.
6. The gas generating system of claim 1 wherein said flame suppressant is selected from at least one member of the group selected from transition metals, transition metal oxides, and mixtures thereof.
7. The gas generating system of claim 1 wherein said flame suppressant comprises about 2 to 35% by weight and said gas generating composition comprises about 65 to 98% by weight, said weight percents based on the combined weight of the gas generating composition and the flame suppressant.
8. The gas generating system of claim 1 wherein said flame suppressant is selected from the group consisting of transitional metals including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; transitional metal oxides selected from the group of oxides formed with metals selected from the group consisting of copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an alkali metal such as sodium or potassium and a mixture containing two or more constituents selected from one or more of the groups including transitional metals, oxides of transitional metals, and alkali metals.
9. A gas generating system comprising:
a gas generator for generating gas;
a propellant chamber within said gas generator;
a gas generating composition comprising nitrocellulose, said gas generant contained within said propellant chamber and said gas generant combustible to produce gas; and
a flame suppressant distributed about said gas generating composition within said propellant chamber, said flame suppressant selected from one or more of the group consisting of transitional metals, transitional metal oxides, and mixtures thereof;
wherein said gas generating composition and said flame suppressant each define a first and a second solid phase, respectively, said first and second solid phases distinct from each other wherein the flame suppressant and the gas generant are not combined into one composition, and, said flame suppressant reduces the flame front otherwise produced by the gas generator in the absence of said flame suppressant.
10. The gas generating system of claim 9 wherein said flame suppressant is selected from the group consisting of transitional metals including copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; transitional metal oxides selected from the group of oxides formed with metals selected from the group consisting of copper, iron, cerium, platinum, vanadium, zinc, zirconium, barium, lanthanum, manganese, nickel, molybdenum, rhodium, and palladium; an alkali metal selected from the group consisting of sodium or potassium; and a mixture containing two or more constituents selected from one or more of the groups selected from the group consisting of transitional metals, oxides of transitional metals, and alkali metals.
11. The gas generating system of claim 9 wherein said flame suppressant comprises about 2 to 35% by weight and said gas generating composition comprises about 65 to 98% by weight, said weight percents based on the combined weight of the gas generating composition and said flame suppressant.
12. A gas generating system comprising:
a gas generator for generating gas;
a propellant chamber within said gas generator;
a gas generating composition within said propellant chamber combustible to produce gas and a flame front; and
a flame suppressant distributed about said gas generating composition within said propellant chamber in juxtaposed, separate, and heterogeneous relationship to said gas generating composition;
wherein said gas generating composition and said flame suppressant each define a first and a second solid phase, respectively, said first and second solid phases distinct from each other wherein the flame suppressant and the gas generating composition are not combined into one homogeneous composition.
13. The gas generating system of claim 12 wherein said gas generating composition is provided in a tablet or extruded form, and that said flame suppressant is distributed about the tablets within said propellant chamber.
14. The gas generating system of claim 12 wherein said flame suppressant is a molybdenum dioxide/copper oxide catalyst.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/661,671 US20100275808A1 (en) | 2004-07-27 | 2010-03-22 | Gas generator containing a flash suppressant |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US59131404P | 2004-07-27 | 2004-07-27 | |
US10/940,395 US20060022443A1 (en) | 2004-07-27 | 2004-09-13 | Gas generator containing a flash suppressant |
US12/661,671 US20100275808A1 (en) | 2004-07-27 | 2010-03-22 | Gas generator containing a flash suppressant |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/940,395 Continuation-In-Part US20060022443A1 (en) | 2004-07-27 | 2004-09-13 | Gas generator containing a flash suppressant |
Publications (1)
Publication Number | Publication Date |
---|---|
US20100275808A1 true US20100275808A1 (en) | 2010-11-04 |
Family
ID=43029433
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/661,671 Abandoned US20100275808A1 (en) | 2004-07-27 | 2010-03-22 | Gas generator containing a flash suppressant |
Country Status (1)
Country | Link |
---|---|
US (1) | US20100275808A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9457761B2 (en) * | 2014-05-28 | 2016-10-04 | Raytheon Company | Electrically controlled variable force deployment airbag and inflation |
US20200027103A1 (en) * | 2018-07-23 | 2020-01-23 | Adobe Inc. | Prioritization System for Products Using a Historical Purchase Sequence and Customer Features |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6287400B1 (en) * | 1999-03-01 | 2001-09-11 | Automotive Systems Laboratory, Inc. | Gas generant composition |
US20020023699A1 (en) * | 1994-12-21 | 2002-02-28 | Daicel Chemical Industries, Ltd. | Gas generant composition |
-
2010
- 2010-03-22 US US12/661,671 patent/US20100275808A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020023699A1 (en) * | 1994-12-21 | 2002-02-28 | Daicel Chemical Industries, Ltd. | Gas generant composition |
US6287400B1 (en) * | 1999-03-01 | 2001-09-11 | Automotive Systems Laboratory, Inc. | Gas generant composition |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9457761B2 (en) * | 2014-05-28 | 2016-10-04 | Raytheon Company | Electrically controlled variable force deployment airbag and inflation |
US10220809B2 (en) | 2014-05-28 | 2019-03-05 | Raytheon Company | Electrically operated propellants with elevated self-sustaining threshold pressures |
US20200027103A1 (en) * | 2018-07-23 | 2020-01-23 | Adobe Inc. | Prioritization System for Products Using a Historical Purchase Sequence and Customer Features |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100462342C (en) | Alkali metal perchlorate-containing gas generants | |
US5466313A (en) | Gas-producing material | |
EP0659715B1 (en) | Gas generant compositions | |
EP0794164B1 (en) | Substantially smoke-free and particulate free inflator for inflatable safety restraint system | |
US6287400B1 (en) | Gas generant composition | |
US3901747A (en) | Pyrotechnic composition with combined binder-coolant | |
US6142518A (en) | Dual inflator apparatus including pyrotechnic inflator | |
US20060022443A1 (en) | Gas generator containing a flash suppressant | |
WO1997007080A1 (en) | Propellant composition for automotive safety applications | |
US20140332125A1 (en) | Autoignition Compositions | |
CN101528642A (en) | Extrudable gas generant | |
US20050067076A1 (en) | Ammonium perchlorate-containing gas generants | |
WO2007016594A2 (en) | Autoignition/booster composition | |
US6620269B1 (en) | Autoignition for gas generators | |
US6007647A (en) | Autoignition compositions for inflator gas generators | |
US7959749B2 (en) | Gas generating composition | |
US6550808B1 (en) | Guanylurea nitrate in gas generation | |
US20100275808A1 (en) | Gas generator containing a flash suppressant | |
EP1171404B1 (en) | Gas-generating substances | |
JP2009120424A (en) | Granular firing powder composition for igniter and igniter using the same | |
US20040216820A1 (en) | Pyrotechnic compositions for gas generant apllications | |
JP2008174441A (en) | Gas generating system and composition | |
EP1194392B1 (en) | Composite gas-generating material for gas-actuated car safety devices | |
EP0944562B1 (en) | Autoignition compositions for inflator gas generators | |
US20040231770A1 (en) | Gas-generating substances |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |