US20100032337A1 - Multi-layer receptacle and residue removal method therefor - Google Patents

Multi-layer receptacle and residue removal method therefor Download PDF

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Publication number
US20100032337A1
US20100032337A1 US12/527,568 US52756808A US2010032337A1 US 20100032337 A1 US20100032337 A1 US 20100032337A1 US 52756808 A US52756808 A US 52756808A US 2010032337 A1 US2010032337 A1 US 2010032337A1
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US
United States
Prior art keywords
container
layer
inner layer
interior
receptacle according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/527,568
Other languages
English (en)
Inventor
Timothy Cotter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syngenta Crop Protection LLC
Original Assignee
Syngenta Crop Protection LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Crop Protection LLC filed Critical Syngenta Crop Protection LLC
Priority to US12/527,568 priority Critical patent/US20100032337A1/en
Publication of US20100032337A1 publication Critical patent/US20100032337A1/en
Assigned to SYNGENTA CROP PROTECTION, INC. reassignment SYNGENTA CROP PROTECTION, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: COTTER, TIMOTHY
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/40—Details of walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • B65D1/0207—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
    • B65D1/0215—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features multilayered
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00—Methods preventing fouling
    • B08B17/02—Preventing deposition of fouling or of dust
    • B08B17/04—Preventing deposition of fouling or of dust by using removable coverings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B65D23/02—Linings or internal coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/46—Applications of disintegrable, dissolvable or edible materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/82—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for poisons

Definitions

  • the present invention broadly concerns receptacles for the storage and transportation of selected items or materials. More specifically, the present invention concerns containers suited for holding liquid substances such as agrochemicals, which can be rinsed with a suitable solvent to remove residue in the interior of the container. The present invention also concerns a method of removing residue from the interior of a receptacle.
  • Packaging is a fundamental need in modern society. At its very essence, packaging enables goods to be distributed over large geographical areas while both protecting and preserving the quality of the goods during their distribution and storage. Typically, packaging provides important information about the goods it contains, such as an explanation of the product, how the product is to be used, and legally pertinent information. Importantly, packaging can also provide a significant commercial advantage to companies who sell competing products. For example, the shape of a product's packaging and colors or illustrations appearing on the packaging can be a significant marketing tool, especially when consumers identify certain packaging characteristics with a particular source or brand of goods.
  • packaging solutions must continue to satisfy the economic, social and governmental requirements of existing and emerging products. Since the product and its packaging are so interdependent, meeting these demands requires more than just combining available materials to contain the goods. Rather, in today's commercial environment, a well-designed package requires the appropriate integration of structure, aesthetics, style, communication and legal elements specific to each product. Moreover, successful packaging solutions should be cost efficient and environmentally responsible.
  • Packaging solutions that are environmentally responsible will continue to be an important driver in the discovery of new packaging materials and designs.
  • environmentally responsible packaging for hazardous materials such as agrochemicals, heavy metals, and organic chemicals, which is strictly regulated by governments and agencies in various countries, including the United States of America.
  • environmental, safety, and commercial pressures have triggered stringent regulatory requirements designed to reduce soil and groundwater contamination resulting from the disposal of partially filled containers or residue left in improperly rinsed containers.
  • stringent regulatory requirements designed to reduce soil and groundwater contamination resulting from the disposal of partially filled containers or residue left in improperly rinsed containers.
  • the agrochemical industry has developed strategies and programs in effort to reduce the impact of their products on the environment. For example, agrochemical companies have made substantial advancements to place their products in reusable packaging as well as to create recycling programs to systematically and efficiently refill the containers as incentives to use these programs. While these programs do lessen the amount of containers that need to be disposed, these containers cannot be used indefinitely. For example, the integrity of the packaging can deteriorate after sufficient use, rendering it unusable. Additionally, and perhaps even more common, the names of agrochemical manufacturers change over time for a variety of reasons such as mergers or acquisitions. Also, product names change and even the packaging dimensions or configurations are typically modified over time. As a result, potentially vast quantities of containers with the incorrect names, sizes, or configurations are no longer useable and are eventually disposed.
  • a receptacle having an interior that is sized and adapted to receive and hold a selected substance.
  • the receptacle comprises a container body surrounding the interior and having a mouth in communication therewith.
  • the container body includes an inner layer formed of a first material that is soluble in the presence of a selected solvent and having a first thickness.
  • the container also includes an outer layer supported by said inner layer and formed of a second material that is insoluble in the selected solvent of a selected second thickness.
  • the first thickness of said inner layer may be greater than the second thickness of said outer layer.
  • the inner layer is preferably substantially continuous and surrounds a majority of the container interior and may be formed of a material that is either hot water soluble or cold water soluble and that is also impervious to hazardous substances.
  • the inner layer maybe formed of polyvinyl alcohol.
  • the outer layer may be formed of polypropylene, polyvinylchloride, high density polyethylene, low density polyethylene, or polyethylene terephthalate.
  • the container may further be provided with a middle layer or tie layer interposed between the inner layer and the outer layer.
  • the middle layer may be formed of a material selected from the group consisting of polyvinyl acetate, ethylene polyvinyl acetate, polyamide, and ethylene vinyl alcohol.
  • Also contemplated herein is a method of removing chemical residue from the interior of a container wherein the container interior is surrounded by an inner sidewall layer formed of a water soluble material, said method comprising contacting the container interior with a sufficient quantity of water to dissolve said inner sidewall layer.
  • FIG. 1 is a perspective view of a representative receptacle having a sidewall according to the present invention
  • FIG. 2 is a perspective view, partially broken away, of the receptacle in FIG. 1 , showing the inner and outer sidewall layers;
  • FIG. 3 is a cross-section of the receptacle shown in FIG. 2 taken about lines 3 - 3 of FIG. 2 ;
  • FIG. 4 is a perspective view, partially broken away, of an alternate embodiment of the according to the present invention.
  • FIG. 5 is a cross-section of the receptacle shown in FIG. 4 , taken about lines 5 - 5 of FIG. 4 .
  • the present invention generally relates to a receptacle or container adapted for the storage and transportation of selected materials or items, including liquid, gel, or solid substances. These selected items or materials can be either hazardous or non-hazardous substances.
  • the container has particular utility for the storage and transportation of liquid hazardous substances such as agrochemicals.
  • a hazardous substance or dangerous goods generally refers to a substance that is potentially toxic or detrimental to human health or the environment.
  • hazardous materials can be in the form of solids, liquids, or gels and include agrochemicals, poisons, radioactive materials, explosives, flammable or nonflammable gases, to name a few.
  • agrochemicals generally refers to pesticides, such as herbicides, insecticides, fungicides and other types of agricultural chemicals that are often potentially harmful materials and are commonly made in concentrated form as a solid, a liquid, a dispersion or a gel, for example.
  • the container is the multilayer construction of the container body, which is adapted to both safely contain hazardous substances and facilitate the removal of residue from the container interior prior to its disposal.
  • the multilayer construction is versatile and may be incorporated into a variety of containers of selected configurations including both reusable and one-way containers.
  • the container disclosed herein and shown in the accompanying figures is in the configuration of a conventional jug and described in the context of liquid agrochemical products.
  • the utility of the container is not limited to this configuration nor is it limited to the transportation and storage of the liquid agrochemical products.
  • Other container configurations are also contemplated, such as trays, blister packages, tubes, bulk or mini-bulk tanks, or any suitable container for transportation and storage for the product selected.
  • a first representative receptacle is shown in the form of container 10 having the configuration of a conventional 2.5 gallon jug typically used as a one-way container to transport and store a variety of liquid agrochemical products.
  • Container 10 includes container body 20 surrounding container interior 18 , which is sized and adapted to receive and hold a selected substance, such as a liquid agrochemical product.
  • Container 10 also includes a bottle finish or mouth (not shown), which communicates with interior 18 that is sealable in a conventional manner with removable cap 14 , as is known in the art.
  • Container 10 may further be provided with handle 12 that is adapted to be grasped by a user's hand.
  • container body 20 has a multilayer construction including an inner sidewall or inner layer 22 and an outer sidewall or outer layer 24 .
  • inner layer 22 may be a continuous layer that is coextensive with outer layer 24 , but the container body is not limited to this construction.
  • the inner layer need not be fully coextensive with the outer layer.
  • the inner layer is in direct contact with the agrochemical product once it is received in the container, it is preferably at least substantially continuous and surrounds at least a majority of the container interior.
  • Inner layer 22 may be formed of a material that dissolves or deteriorates when in contact with a suitable solvent such as water, or when in contact with a cleaning solution comprising surfactants, soap, or combinations thereof.
  • a suitable solvent such as water
  • a cleaning solution comprising surfactants, soap, or combinations thereof.
  • the solvent used to dissolve or deteriorate inner layer 22 is either hot water or cold water.
  • An inner layer material that is hot water soluble material generally dissolves or otherwise disintegrates in water having a temperature above about 50° C.
  • a selected inner layer material that is cold water soluble dissolves or otherwise disintegrates in water having a temperature below about 50° C. and preferably at a temperature between about 5° C. and 35° C.
  • Representative materials which may be used to form the inner layer include polyvinyl alcohol; polyethylene oxide; polyoxyethylene; cellulose derivatives; sodium polyacrylate; polylactic acid; lactic acid esters and ethers of polyvinyl alcohol; lactic esters and ethers of cellulosics; carrageenan; pectin; combinations of the above; and combinations of the above with starches.
  • the cellulose derivative group could consist of: methyl cellulose; methylhydroxyethyl cellulose; methylhydroxypropyl cellulose; hydroxypropyl cellulose; cellulose; cellulose monoacetate and hydrophobically modified cellulose derivatives.
  • the outer layer is formed of a material that does not dissolve or disintegrate when in contact with the solvent selected to dissolve the inner layer and is preferably not water soluble.
  • Representative materials which may be used to form the outer layer include polypropylene, polyvinylchloride, high density polyethylene, low density polyethylene, and polyethylene terephthalate.
  • Inner layer 22 and outer layer 24 each should have a thickness suitable to provide the container with the necessary structural integrity to hold the container's selected configuration during normal rigors of the transportation. Further, outer layer 24 should be of suitable thickness to shield the inner layer from exposure to the environment as well as water or other solvents that would cause it to deteriorate. Inner layer 22 may have a thickness between about 0.01 mm and 4.0 mm, while outer layer 24 may have a thickness between about 1.0 mm and 4.0 mm.
  • inner layer 22 is thicker than outer layer 24 . More particularly, inner layer 22 has a selected first thickness “d 1 ” sufficient to be freestanding and hold the container's selected configuration during normal rigors of the transportation and storage of the product it contains. Outer layer 24 is bonded to and supported by inner layer 22 and has a selected second thickness “d 2 ” that is less than that of “d 1 ”. Outer layer 24 provides additional rigidity to the overall container, while protecting inner layer 22 during shipment and storage of the agrochemical product.
  • outer layer 24 is frangible or otherwise lacks sufficient structural integrity to retain the selected configuration of the container and deforms under pressure without the support of the inner layer. Generally, then, outer layer forms a continuous protective shell about inner layer 22 . Additionally, outer layer 24 provides a substrate on which product labels may be adhered or otherwise provided to identify the product and any required legal information.
  • container 10 facilitates the removal of residue that collects or otherwise builds up during the course of contact with the product.
  • the container must be properly rinsed prior to disposal, particularly of the container is used for a hazardous substance.
  • the inner layer is water soluble, it will begin to deteriorate or dissolve when in contact with water. Accordingly, if one chooses to employs, for example, the EPA triple rinsing procedure described in the Background, at least some of the inner layer will dissolve while performing triple rinsing steps.
  • the layer, along with the residue adhered thereto will be flushed through the mouth or finish of the container. It is anticipated that the removal of the inner layer will achieve the effective removal of the residue thereon, and preferably at least 99.9999% of the chemical residue in the container interior.
  • the outer layer or shell of the container will remain and ultimately be disposed of in the landfill. Since the outer layer is frangible and no longer supported by the inner layer, it will easily deform or collapse under an insignificant amount of pressure, thereby reducing its size so as to take up less space in the disposal site than its original configuration prior to removal of the inner layer.
  • container 10 described above may be used for the storage and transportation of a herbicide containing mesotrione, which is the active ingredient for example, in a product marketed under the trademark Callisto® registered to Syngenta Crop Protection, Inc. located in Greensboro, N.C.
  • a container having an inner layer formed of suitable material that is cold water soluble would preferably be used. This is because mesotrione would not impair or damage in the inner layer while stored therein.
  • an inner layer formed of a hot water soluble material would be useful for storing a seed treatment product having thiamethoxam as an active ingredient such as the seed treatment product marketed under the trademark Cruiser® also registered to Syngenta Crop Protection, Inc.
  • container 110 has a multilayer container body 120 that surrounds container interior 118 .
  • container body 120 is formed of three layers: inner layer 122 , outer layer 124 , and tie layer or middle layer 126 located therebetween.
  • Middle layer 126 may be formed of a material suitable to assist in keeping the inner layer and the outer layer together.
  • middle layer 126 may be formed of polyvinyl acetate, ethylene polyvinyl acetate, polyamide, and ethylene vinyl alcohol.
  • the multilayer container body can be formed of a plurality layers, and is not limited to the exemplary embodiments described above with reference to the figures.
  • the container body could be provided with multiple inner or outer layers and tie layers as needed to form a suitable receptacle or container for the selected material.
  • the inner layer or layers are formed of a material that will dissolve or disintegrate in the presence of a suitable solvent to effectively remove residue in the interior of the container.
  • the container contemplated herein may be formed by ordinary processes known in the art such as co-extrusion, blow molding, injection molding, or any suitable process.
  • the present invention contemplates a method of removing residue located in the interior of a container that may be accomplished by the steps inherent in the described structure.
  • the method includes contacting the interior of a container with a selected solvent adapted to dissolve or otherwise disintegrate at least a portion of the inner layer or sidewall that surrounds the container interior.
  • the method includes repeated rinsing of the container interior sufficient to flush a portion of the inner layer of the container body and cause removal of the residue.
  • This method can also cause accomplish the step of removing the interior support of the overall container configuration such that the remaining outer layer of the container body is collapsible under an insignificant amount of pressure.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Packages (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Wrappers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Laminated Bodies (AREA)
US12/527,568 2007-02-19 2008-02-18 Multi-layer receptacle and residue removal method therefor Abandoned US20100032337A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/527,568 US20100032337A1 (en) 2007-02-19 2008-02-18 Multi-layer receptacle and residue removal method therefor

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US89050407P 2007-02-19 2007-02-19
US12/527,568 US20100032337A1 (en) 2007-02-19 2008-02-18 Multi-layer receptacle and residue removal method therefor
PCT/US2008/054194 WO2008103624A1 (en) 2007-02-19 2008-02-18 Multi-layer receptacle and residue removal method therefor

Publications (1)

Publication Number Publication Date
US20100032337A1 true US20100032337A1 (en) 2010-02-11

Family

ID=39710447

Family Applications (1)

Application Number Title Priority Date Filing Date
US12/527,568 Abandoned US20100032337A1 (en) 2007-02-19 2008-02-18 Multi-layer receptacle and residue removal method therefor

Country Status (12)

Country Link
US (1) US20100032337A1 (ja)
EP (1) EP2112984A4 (ja)
JP (1) JP2010519139A (ja)
KR (1) KR20090113333A (ja)
CN (1) CN101641266B (ja)
AU (1) AU2008218794A1 (ja)
BR (1) BRPI0807891A2 (ja)
CA (1) CA2678809A1 (ja)
MX (1) MX2009008869A (ja)
RU (1) RU2459756C2 (ja)
WO (1) WO2008103624A1 (ja)
ZA (1) ZA200905777B (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2028138B1 (en) * 2021-05-04 2022-11-10 Composite Production Tech B V Method for handling a water-sensitive and/or temperature-sensitive compound

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130256237A1 (en) * 2010-12-20 2013-10-03 Linna Wang Water soluble package films for acidic high water content product and method of producing the same
CN105035451B (zh) * 2015-06-24 2017-12-01 云南中烟工业有限责任公司 一种烟用复合膜储水或水溶液小袋的制备方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5280835A (en) * 1990-05-02 1994-01-25 Rhone-Poulenc Inc. Laminated bags for containerization of toxic and hazardous materials
US5328025A (en) * 1990-07-18 1994-07-12 Rhone-Poulenc Inc. Containerization system for agrochemicals and the like
US5429874A (en) * 1991-05-14 1995-07-04 W. R. Grace & Co.-Conn. Water soluble film
US5464097A (en) * 1988-06-15 1995-11-07 May & Baker Limited Shock protection packaging for liquids
US5827586A (en) * 1993-06-15 1998-10-27 Ciba-Geigy Japan Limited Packaging material comprising a water-soluble film
US6089374A (en) * 1988-06-15 2000-07-18 May & Baker, Ltd. Package having particular humidity for liquid products
US20040031717A1 (en) * 1991-04-05 2004-02-19 Edwards David Brian Water soluble package
US6783006B1 (en) * 1994-02-24 2004-08-31 Syngenta Investment Corp. Container for chemicals
US20050065051A1 (en) * 2000-11-27 2005-03-24 The Procter & Gamble Company Detergent products, methods and manufacture
US20060105130A1 (en) * 2004-11-12 2006-05-18 Brown Michael J Articles incorporating sulfoisophthalic acid-modified polyester multilayer coextruded structures

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE787361A (fr) * 1971-08-10 1973-02-09 Ilikon Corp Recipient en matiere plastique
EP0069296B1 (de) * 1981-07-08 1988-03-16 RB Kunststoffpatent-Verwertungs AG Verbundfolie
IL90585A (en) * 1988-06-15 1996-05-14 May & Baker Ltd Package releases software by touching with water
MA21572A1 (fr) * 1988-06-15 1989-12-31 Rhone Poulenc Agriculture Emballage pour les liquides .
GB2239443B (en) * 1989-10-23 1993-11-24 Rhone Poulenc Ltd Improvements in or relating to containers
GB8925472D0 (en) * 1989-11-10 1989-12-28 Ici Plc Container
US5429242A (en) * 1990-07-18 1995-07-04 Rhone-Poulenc Agriculture Ltd. Laminated bags for containerization of toxic or hazardous materials
DE4023909A1 (de) * 1990-07-27 1992-01-30 Wild Rudolf Gmbh & Co Wiederverwendbarer behaelter aus kunststoff sowie seine herstellung und verwendung
US20080041751A1 (en) * 2006-07-05 2008-02-21 The Proctor & Gamble Company Article comprising an indicator

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5464097A (en) * 1988-06-15 1995-11-07 May & Baker Limited Shock protection packaging for liquids
US6089374A (en) * 1988-06-15 2000-07-18 May & Baker, Ltd. Package having particular humidity for liquid products
US5280835A (en) * 1990-05-02 1994-01-25 Rhone-Poulenc Inc. Laminated bags for containerization of toxic and hazardous materials
US5328025A (en) * 1990-07-18 1994-07-12 Rhone-Poulenc Inc. Containerization system for agrochemicals and the like
US20040031717A1 (en) * 1991-04-05 2004-02-19 Edwards David Brian Water soluble package
US5429874A (en) * 1991-05-14 1995-07-04 W. R. Grace & Co.-Conn. Water soluble film
US5827586A (en) * 1993-06-15 1998-10-27 Ciba-Geigy Japan Limited Packaging material comprising a water-soluble film
US6783006B1 (en) * 1994-02-24 2004-08-31 Syngenta Investment Corp. Container for chemicals
US20050065051A1 (en) * 2000-11-27 2005-03-24 The Procter & Gamble Company Detergent products, methods and manufacture
US20060105130A1 (en) * 2004-11-12 2006-05-18 Brown Michael J Articles incorporating sulfoisophthalic acid-modified polyester multilayer coextruded structures

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2028138B1 (en) * 2021-05-04 2022-11-10 Composite Production Tech B V Method for handling a water-sensitive and/or temperature-sensitive compound
WO2022233941A1 (en) 2021-05-04 2022-11-10 Composite Production Technology B.V. Method for handling a water-sensitive and/or temperature-sensitive compound

Also Published As

Publication number Publication date
WO2008103624A1 (en) 2008-08-28
JP2010519139A (ja) 2010-06-03
RU2459756C2 (ru) 2012-08-27
CN101641266B (zh) 2013-05-29
MX2009008869A (es) 2009-08-28
EP2112984A1 (en) 2009-11-04
BRPI0807891A2 (pt) 2017-05-16
EP2112984A4 (en) 2011-06-29
CA2678809A1 (en) 2008-08-28
AU2008218794A1 (en) 2008-08-28
RU2009134797A (ru) 2011-03-27
CN101641266A (zh) 2010-02-03
KR20090113333A (ko) 2009-10-29
ZA200905777B (en) 2012-01-25

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