US20090123322A1 - High-Speed Steel for Saw Blades - Google Patents
High-Speed Steel for Saw Blades Download PDFInfo
- Publication number
- US20090123322A1 US20090123322A1 US12/226,614 US22661407A US2009123322A1 US 20090123322 A1 US20090123322 A1 US 20090123322A1 US 22661407 A US22661407 A US 22661407A US 2009123322 A1 US2009123322 A1 US 2009123322A1
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- United States
- Prior art keywords
- speed steel
- maximum
- saw blades
- accordance
- vanadium
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Links
- 229910000997 High-speed steel Inorganic materials 0.000 title claims abstract description 51
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 80
- 239000000956 alloy Substances 0.000 claims abstract description 80
- 239000010955 niobium Substances 0.000 claims abstract description 49
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 46
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 39
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 39
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 28
- 239000010937 tungsten Substances 0.000 claims abstract description 26
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 25
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- 229910052710 silicon Inorganic materials 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000010703 silicon Substances 0.000 claims abstract description 19
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- 229910052799 carbon Inorganic materials 0.000 claims abstract description 13
- 239000011651 chromium Substances 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 8
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 98
- 239000010959 steel Substances 0.000 claims description 98
- 238000005520 cutting process Methods 0.000 claims description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
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- 239000011572 manganese Substances 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 6
- 238000003754 machining Methods 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 238000009749 continuous casting Methods 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 238000003801 milling Methods 0.000 claims description 4
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- 239000007788 liquid Substances 0.000 claims description 3
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- 238000004663 powder metallurgy Methods 0.000 claims description 2
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- 238000005266 casting Methods 0.000 claims 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 3
- 229910052748 manganese Inorganic materials 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
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- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- 150000001247 metal acetylides Chemical class 0.000 description 41
- 238000005496 tempering Methods 0.000 description 23
- 229910052750 molybdenum Inorganic materials 0.000 description 22
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 20
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- 101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 2
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
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- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 241000490229 Eucephalus Species 0.000 description 1
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- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/24—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for saw blades
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/30—Ferrous alloys, e.g. steel alloys containing chromium with cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Definitions
- the present invention is about a kind of steel to be used in cutting tools and machining of metals and other materials.
- the steel at issue has a composition which classifies it as a high speed-type tool steel, with its main feature being the use of a lower content of noble alloy elements, such as vanadium, tungsten and molybdenum, but with properties either equivalent or higher than those of less alloyed conventional high-speed steels and slightly inferior to those of more alloyed conventional high-speed steels.
- noble alloy elements such as vanadium, tungsten and molybdenum
- Cutting tools are applied in a large number of cutting and machining operations. Some examples are cutting operations in tape, automatic or manual saws, drilling, turning, tapping, milling, among other forms of machining steel, nonferrous alloys or other solid-materials.
- An important example of operation for which the present invention is intended are saws, used in machines or saws for manual cutting, and both can be used under the hard form, entirely in high-speed steel, or bimetallic, with only the areas of high-speed steel teeth and the others made of low alloy mechanical construction steel.
- Other cutting tools typically employ high-speed steels and they may be made of the steel in the present invention, among them: helicoidal drills, top millings, profile tools, tacks, bit and special drills for high-resistance materials.
- thin cutting tools such as taps, dies and special mills.
- the same high-speed steels employed on those tools may be used as conforming tools.
- Examples are punches, tools for cold forging, blanking dies and plate cutting, coining dies, dies for conforming of postmetallic or ceramic, inserts and other tools for hot and warm forging, as well as tools in other applications in cold, warm or hot conforming, in which the conformed material has temperatures reaching up to 1300° C.
- Steels traditionally used in cutting tools are high-speed steels, whose main feature is high resistance to wear and preservation of hardness at high temperatures.
- Typical examples are the steels of series AISI M or AISI T, being steels AISI M2, M7 and TI highlighted.
- Less alloyed steels may be used for less demanded tools; the main steels are DIN 1.3333 and steels AISI M50 and M52.
- the chemical composition of such steels is shown in Table 1, in which emphasis must be placed on tungsten, molybdenum and vanadium, which contribute with a large share to the final cost of the alloy.
- the effect of these elements on the cost is presented in Table 2, as normalized by the cost of alloys in December 2005.
- the advantage of less alloyed steels over conventional steels is clear according to these amounts, in terms of alloy cost.
- the steel of the present invention meets such requirements.
- the objective of the invention was first of all to study the influence of silicon, aluminum and niobium elements in a composition with a low content of vanadium, molybdenum and tungsten.
- the important effect of niobium was identified in this study, however not sufficient to evolve hardness towards the levels necessary.
- Aluminum and especially silicon elements were then employed in the steel of the present invention, showing a significant effect.
- the definition of the contents of these elements and their adequate working range promotes, therefore, the reduction of costs and the achievement of the properties intended in the material. Such ranges are described and the effect of each element is outlined below.
- the steel of the present invention has a composition of alloy elements that, in mass percentage, consists of:
- Nb 0.5 to 3.0 Nb, preferably 0.8-1.8 Nb, typically 1.2 Nb, and Nb may be partially or fully replaced with Zr, Ti, Ta or V, in a relation in which 1.0% of Nb corresponds to 0.5% V or Ti, and 1.0% Nb corresponds to 1.0% Zr or Ta.
- V 0.3 to 2.0 V, preferably 0.5-1.0 V, typically 0.7 V, and V may be partially or fully replaced with Nb, in a ratio in which 1.0%. Nb corresponds to 0.5% V.
- the content of the final Nb in the alloy must be calculated through this relation and added to the already specified content for the alloy.
- Si 0.3 to 3.5 Si, preferably 0.7 to 2.0 V, typically 1.0 Si, and Si may be partially or fully replaced with Nb, at the 1:1 ratio.
- aluminum may be added to the steel of the present invention, promoting property advantages.
- compositions with no addition of aluminum can also be employed in the steel of the present invention, since it is easier in terms of alloy manufacture. Therefore, the aluminum content should be dosed as follows:
- Al at maximum, preferably 0.5 Al at maximum, typically 0.2 Al at maximum for compositions with Al as residual element. In this case, Al should be treated as impurity.
- 1.5 Mn at maximum preferably 0.8 Mn at maximum, typically 0.5 Mn at maximum.
- 0.10 S at maximum preferably 0.020 S at maximum, typically 0.008 S at maximum.
- 0.1 N at maximum preferably 0.05 N at maximum, typically 0.5 N at maximum.
- the elements of the lanthanoid or actinoid families in the periodic table, as well as La, Ac, Hf and Rf elements are considered rare-earth elements.
- the Ce content should be preferably lower than 0.1 and typically lower than 0.06.
- Carbon is the main responsible for the response to heat treatment and the formation of primary carbides. Its content should be lower than 1.5%, preferably 1.1% at maximum, so that the presence of austenite retained is not very high after quenching. This is important in less alloyed steels, as the one of the present invention, because carbon tends to form less carbides of alloy elements, in the form of primaries and eutectics; thus, a higher content of free carbon is obtained after quenching, contributing to a significant increase in the fraction of retained austenite.
- the carbon content should be sufficient to form primary carbides, especially in combination with niobium, as well as secondary carbides during tempering and promote the hardening of martensite after quenching. Thus, the carbon content should not be lower than 0.5%, being carbon higher than 0.8% preferable.
- the chromium content should be higher than 1%, preferably higher than 3%, because this element contributes to quenching characteristics and precipitation of secondary carbides during tempering and annealing. Together with carbon, chromium also determines the formation of M 7 C 3 -type primary carbides, which are not desirable for high-speed steels, since they reduce rectification capacity and toughness. Thus, the chromium content should be limited to 10%, preferably lower than 7%.
- W and Mo Tungsten and molybdenum have analog effects on high-speed steels, present especially in M2C- or M6C-type primary carbides and secondary carbides of the same type, being the latter formed during tempering or under gross solidification condition. Thus, they may be jointly specified through the equivalent tungsten relation (W eq ), given by the sum W+2Mo, that normalizes the differences of atomic weight of both elements.
- W eq equivalent tungsten relation
- W eq equivalent tungsten relation
- W eq equivalent tungsten relation
- W eq the content of W eq should be lower than 10.0%, preferably lower than 8.0%.
- vanadium should have a function equivalent to the one described for molybdenum and tungsten-action on the secondary hardening, forming thin carbides at tempering. Vanadium also can form primary carbides, but this is not the main purpose of its addition to the steel in the present invention. Vanadium also has, further, a significant influence on the control of growth of austenitic grains, during austenitization. For such effects, vanadium should be higher than 0.3%, preferably higher than 0.5%. Since this is also an important agent in the alloy cost, the content of vanadium in the present invention should be lower than 2.0%, preferably lower than 1.0%.
- Niobium has an important effect for the steel of the present invention. This element forms mainly MC-type highly hard eutectic carbides and, therefore, they are important for resistance to the wear of the tools produced. Another interesting effect of niobium is that the MC carbides formed dissolve a little tungsten, molybdenum and vanadium, enabling these elements to be free, after austenitization and quenching, for secondary precipitation. Thus, the high-speed steel linked to niobium allows for the use of a lower amount of molybdenum, tungsten and vanadium and, therefore, this element operates significantly to reduce the alloy cost. However, its performance is ensured by the fraction of thin and highly hard MC carbides, formed by niobium.
- the content of niobium cannot be higher than 3%, because it forms primary and coarse carbides under these situations, hardly refined by the hot conforming process. So, an excessive content of niobium may harm toughness and rectification capacity of the alloy, in addition to increasing its cost. Therefore, the niobium content in the steel of the present invention should be between 0.5 and 3.0%, preferably between 0.8 and 1.8%.
- Si Silicon is one of the main element for the steel of the present invention.
- This element has an usually undesirable effect on both primary and secondary carbides of more alloyed high-speed steels.
- the increase in the volume of primary carbides is one of the main effects, harming the rectification capacity and the response to heat treatment, and the decrease in the resistance to tempering. This occurs for the effect of silicon on the volume of delta ferrite during solidification, and the reduction in the volume of high-stability MC- and MC2-type secondary carbides. So, it is not added higher than 0.5% in usual compositions.
- the steel of the present invention does not have negative problems as for the introduction of silicon, since it is a less alloyed steel. On the contrary, this element causes a significant increase in the temper hardness.
- the increase in silicon content in the steel of the present invention promotes the recovery and elevation of hardness, until values acceptable for high-speed steels.
- the content of silicon must be higher than 0.3%, preferably higher than 0.7%.
- the content of this element must be lower than 3.5%, since it reduces the austenitization range and causes an expressive hardening of ferrite when annealed.
- the content of silicon must be preferably lower than 2.0%
- Al The addition of aluminum is optional for the steel of the present invention. Slight property gains, such as resistance to tempering, may be achieved with content higher than 0.3%, preferably higher than 0.7%.
- Slight property gains such as resistance to tempering, may be achieved with content higher than 0.3%, preferably higher than 0.7%.
- aluminum in order to promote high hardening of ferrite, high reactivity in liquid steel and increase of AC 1 and AC 3 temperatures, aluminum must be lower than 3.5%, preferably lower than 2.0%. Even in content close to 1.0%, aluminum still causes these undesirable effects.
- the variation of AC 1 and AC 3 temperatures makes the conditions for annealing of material especially difficult, requiring significantly higher temperatures.
- the reactivity of the liquid metal makes the works of steel mills and cleaning difficult, in term of nonmetallic inclusions of the end steel obtained.
- the steel of the present invention can be also produced with residual contents of aluminum. In this case, aluminum must be lower than 1.0%, preferably lower than 0.5%.
- Residuals Other elements, such as manganese, nickel and copper and those usually obtained as typical residuals from the preparation process of liquid steel, must be regarded as impurities, related to the process of deoxidation in steel mill or inherent to manufacturing processes. Therefore, the content of manganese, nickel and copper is limited to 1.5%, preferably lower than 1.0%. Elements such as phosphorus and sulfur segregate on grain contours and other interfaces. Thus, phosphorus must be lower than 0.10%, preferably lower than 0.5%, and sulfur must be lower than 0.050%, preferably 0.020% at maximum.
- the alloy can be produced in the form of products rolled or forged by whether conventional or special processes, such as powder metallurgy, spray conforming or continuous casting, in products such as wire rod, bars, wire, plates and strips.
- FIG. 1 shows the fusion gross microstructure of the alloy in the art, ET1, showing the X-ray mappings of vanadium, tungsten and molybdenum elements. At the mapping, the higher the density of points, the higher the relative concentration of the chemical element. Microstructure obtained through scanning electronic microscopy (SEM), secondary electrons; X-ray mapping obtained through WDS.
- SEM scanning electronic microscopy
- FIG. 2 shows the fusion gross microstructure of the alloy in the art, ET2, showing the X-ray mappings of vanadium, tungsten and molybdenum elements. At the mapping, the higher the density of points, the higher the relative concentration of the chemical element. Microstructure obtained through scanning electronic microscopy (SEM), secondary electrons; X-ray mapping obtained through WDS.
- SEM scanning electronic microscopy
- FIG. 3 shows the fusion gross microstructure of the alloy in the present invention, PI1, showing the X-ray mappings of vanadium, tungsten, molybdenum and niobium elements. At the mapping, the higher the density of points, the higher the relative concentration of the chemical element. Microstructure obtained through scanning electronic microscopy (SEM), secondary electrons; X-ray mapping obtained through WDS.
- SEM scanning electronic microscopy
- FIG. 4 shows the fusion gross microstructure of the alloy in the present invention, PI2, showing the X-ray mappings of vanadium, tungsten, molybdenum and niobium elements. At the mapping, the higher the density of points, the higher the relative concentration of the chemical element. Microstructure obtained through scanning electronic microscopy (SEM), secondary electrons; X-ray mapping obtained through WDS.
- SEM scanning electronic microscopy
- FIG. 5 shows the fusion gross microstructure of the alloy in the present invention, PI3, showing the X-ray mappings of vanadium, tungsten, molybdenum and niobium elements. At the mapping, the higher the density of points, the higher the relative concentration of the chemical element. Microstructure obtained through scanning electronic microscopy (SEM), secondary electrons; X-ray mapping obtained through WDS.
- SEM scanning electronic microscopy
- FIG. 6 shows the alloy tempering curves.
- ET2 PI1, PI2 and PI3 alloys
- curves for two austenitization temperatures were studied, identified at the right upper corner of each curve.
- ET1 alloy was compared to austenitization at 1200° C., since this is its usual austenitization temperature.
- FIG. 7 compares the size distributions of carbides for ET2, PI1, PI2 and PI2 alloys, in a) absolute values and b) percentage. Results obtained with analysis of 12 fields with 1000 ⁇ magnification, totaling 0,15 mm 2 of area analyzed in each alloy.
- Table 2 shows the significant reduction in the elements of steel alloy of the present invention, which are converted into a lower cost alloy—as compared in Table 3, calculated for amounts of December 2005.
- the reduction which occurs from the steel of art ET1 to ET2 can be observed, as well as the reduction at the same proportion of steel ET2, since this is a less alloyed steel, for the steels of the present invention.
- the steel of this invention is a second step towards the reduction of alloy costs, concerning already existing less alloyed steels, such as steel ET2.
- steel ET1 the difference in alloy cost is twice as large.
- the ingot fusion was made at a close procedure for such five alloys, in a vacuum induction oven, and poured into iron cast moulds, resulting in a 55-kg ingot. After solidification, the ingots were subcritically annealed and such five compositions were initially classified concerning the fusion gross microstructure. Firstly, one can see the higher quantity of primary carbides in ET1 alloy, a result from its higher content of alloy elements. Secondly, the concentration of vanadium, molybdenum and tungsten elements is clear, in accordance with the density of points in the X-ray image, and it is significantly higher at primary carbides in ET1 and ET2 alloys, concerning PI1, PI2 and PI2 alloys.
- niobium carbides are MC type, and highly hard: therefore, they can replace well carbides of higher cost elements, such as tungsten, molybdenum and vanadium. And, added to such effect, niobium carbides have an interesting feature: they do not have expressive amounts of other elements, especially molybdenum, tungsten and vanadium.
- FIGS. 1 through 5 show that the primary carbides of PI1, PI1 and PI3 alloys are predominantly MC type and rich in niobium. They consume lower amounts of tungsten, molybdenum and vanadium than primary carbides of the steels of the art and, thus, they allow for the reduction in the total content of such elements in the alloy, what is intended through the steel of the present invention.
- the hardness after the heat treatment is essential for high-speed steels. Therefore, the experimental ingots were rolled for 34-mm diameter round bars and annealed, with level at 850° C. for ET1, ET2 and ET3 alloys, and level at 980° C. for PI3 alloy. Afterwards, they were submitted to quenching treatment, with austenitization between 1185 and 1200° C. for 5 minutes and two temperings, between 450 and 600° C. for 2 hours each.
- TABLE 3 Cost of metallic load that is, the alloy metal contained in ET1, ET2, PI1, PI2 and PI3 alloy.
- T1 T2 T3 I2 I3 Cost of the metal contained 00 9.2 3.4 3.4 3.6 in the alloy, normalized in two manners. 69 00 6.4 6.4 6.8 Values normalized by the cost of the metallic load of alloy ET1 and for ET2. The calculations were related to production through electric steel mill, in December 2005.
- Table 4 shows hardness after quenching and tempering of ET1, ET2, PI1, PI2 and PI3 steels, which, in form of a chart, is presented in FIG. 6 .
- ET1 only the usual austenitization temperature for this material was used, namely 1200° C.
- the size of austenitic grains for ET2, PI1, PI2 and PI3 alloys was also evaluated for several austenitization temperatures. The results are shown in Table 5. Steels PI1, PI2 and PI3 have grain size slightly larger than steel ET2, because it has a high vanadium content—quite efficient to control the growth of the size of austenitic grains. However, PI1, PI2 and PI3 alloys have grain size still refined, especially until 1185° C., and considering that 33-mm gauge is relatively large for high-speed steels. Therefore, this austenitization temperature seems the most suitable for the steel of the present invention.
- Steel ET2 has a total volumetric fraction of carbides equivalent to the one of steels PI1 and PI3; steel PI1 has a slightly higher volumetric fraction. As for size, steel ET2 has fewer total carbides, but it has a higher number of coarse carbides (over 8 ⁇ m).
- thinner carbides are interesting, because they promote larger points of resistance and wear, and they operate in order to increase toughness.
- Thin carbides are also important to promote better machining capacity, making high-speed steel easier to be processed when manufacturing tools. Therefore, more refined carbides obtained at steels PI1, PI2 and PI3 are very interesting for application in cutting tools. They result especially from niobium eutectics which, after hot conforming, have thinner morphology than primary carbides of ET2 alloy, especially those rich in vanadium.
- the properties of the steel of the present invention allows for its use as replacement for steels such as ET2 in all of such applications, with equivalent properties and a significant cost reduction (see Table 3).
- the steel of the present invention can also replace more alloyed steels, herein represented by steel ET1, probably with lower performance, but the cost reduction is extremely significant.
- the steel of the present invention were tested in performance tests.
- Cutting tools of the “hard manual saws” type were manufactured and cutting tests were carried out.
- Such testes were performed in accordance with standard BS 1919, in three blades of each one of ET2, PI1, PI2 and PI3 alloys.
- the alloys of the present invention were produced from 55-kg experimental ingots, hot rolled until 2.8 ⁇ 12 mm 2 dimensions and, then, rolled again for the final dimension of the saw.
- Steel ET2 was obtained from an industrial batch for reference purposes. Alloy ET2 was chosen for comparison purposes, because this is the material traditionally employed in manual saw blades.
- the test consisted of 10 cuts per blade on a bundle of stainless steel UNSS304,00, with dimensions of 2.60 ⁇ 25.00 mm 2 , 180-HV hardness. The speed was constant, 70 strokes per minute, and the cutting powers were precalibrated equally for all the saw blades. The tests were carried out in a proper machine.
- the performance indicators were: average wear rate and total average cutting time.
- the wear rate is characterized by the evolution in the number of strokes required to make each cut. It is calculated through the first order derivative of the chart on number of strokes per cut in view of the number of cuts. A lower rate of wear means that the saw cuts with fewer strokes, what is felt by users as better performance. The same thing occurs for cutting time—the shorter, the better the saw blade performance.
- Table 7 The results obtained at the performance test are shown in Table 7, for the materials under two tempering conditions.
- the most important condition is 540° C., since this is the most used in saws produced currently.
- the results achieved are interesting for the alloys of the present invention, once they show results either equivalent or even higher than those of the steel of the art (ET2), especially for PI2 and PI3 alloys.
- ET2 steel of the art
- the alloy with PI3 has the lowest wear rate; and, as well as PI2 alloy, it results in shorter cutting time than ET2 alloy.
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BRPI0601679-0B1A BRPI0601679B1 (pt) | 2006-04-24 | 2006-04-24 | Aço rápido para lâminas de serra |
BRPI0601679-0 | 2006-04-24 | ||
PCT/BR2007/000023 WO2007121542A1 (en) | 2006-04-24 | 2007-02-02 | High-speed steel for saw blades |
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US20090123322A1 true US20090123322A1 (en) | 2009-05-14 |
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US12/226,614 Abandoned US20090123322A1 (en) | 2006-04-24 | 2007-02-02 | High-Speed Steel for Saw Blades |
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US (1) | US20090123322A1 (es) |
EP (1) | EP2010688A4 (es) |
JP (1) | JP2009534536A (es) |
KR (1) | KR20080111101A (es) |
CN (1) | CN101426944A (es) |
BR (1) | BRPI0601679B1 (es) |
MX (1) | MX2008013467A (es) |
RU (1) | RU2440437C2 (es) |
WO (1) | WO2007121542A1 (es) |
ZA (1) | ZA200809962B (es) |
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US20130186159A1 (en) * | 2010-09-30 | 2013-07-25 | Danieli & C. Officine Meccaniche S.P.A | Shear for shearing products and associated production process |
US20140013915A1 (en) * | 2011-03-25 | 2014-01-16 | Nisshin Steel Co., Ltd. | Steel plate with excellent durability for band-shaped die-cutting blade, and band-shaped die-cutting blade |
CN107427893A (zh) * | 2015-03-26 | 2017-12-01 | 日立金属株式会社 | 冷作工具及其制造方法 |
CN108044188A (zh) * | 2017-12-22 | 2018-05-18 | 湖北大帆金属制品有限公司 | 一种65Mn圆盘锯片加工工艺 |
WO2024118682A1 (en) * | 2022-12-03 | 2024-06-06 | Reardon Arthur Craig | High speed steel composition |
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- 2007-02-02 KR KR1020087026156A patent/KR20080111101A/ko not_active Application Discontinuation
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- 2007-02-02 RU RU2008146047/02A patent/RU2440437C2/ru not_active IP Right Cessation
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Cited By (7)
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US20130186159A1 (en) * | 2010-09-30 | 2013-07-25 | Danieli & C. Officine Meccaniche S.P.A | Shear for shearing products and associated production process |
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US20140013915A1 (en) * | 2011-03-25 | 2014-01-16 | Nisshin Steel Co., Ltd. | Steel plate with excellent durability for band-shaped die-cutting blade, and band-shaped die-cutting blade |
CN107427893A (zh) * | 2015-03-26 | 2017-12-01 | 日立金属株式会社 | 冷作工具及其制造方法 |
US10844456B2 (en) * | 2015-03-26 | 2020-11-24 | Hitachi Metals, Ltd. | Cold work tool and method for manufacturing same |
CN108044188A (zh) * | 2017-12-22 | 2018-05-18 | 湖北大帆金属制品有限公司 | 一种65Mn圆盘锯片加工工艺 |
WO2024118682A1 (en) * | 2022-12-03 | 2024-06-06 | Reardon Arthur Craig | High speed steel composition |
Also Published As
Publication number | Publication date |
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CN101426944A (zh) | 2009-05-06 |
JP2009534536A (ja) | 2009-09-24 |
BRPI0601679B1 (pt) | 2014-11-11 |
KR20080111101A (ko) | 2008-12-22 |
RU2008146047A (ru) | 2010-05-27 |
EP2010688A1 (en) | 2009-01-07 |
RU2440437C2 (ru) | 2012-01-20 |
ZA200809962B (en) | 2009-11-25 |
WO2007121542A1 (en) | 2007-11-01 |
MX2008013467A (es) | 2009-02-11 |
BRPI0601679A (pt) | 2007-12-18 |
EP2010688A4 (en) | 2010-08-04 |
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