US20090117243A1 - Process for wholegrain-conditioning of brewer's cereal grains used in beer production - Google Patents
Process for wholegrain-conditioning of brewer's cereal grains used in beer production Download PDFInfo
- Publication number
- US20090117243A1 US20090117243A1 US12/300,083 US30008306A US2009117243A1 US 20090117243 A1 US20090117243 A1 US 20090117243A1 US 30008306 A US30008306 A US 30008306A US 2009117243 A1 US2009117243 A1 US 2009117243A1
- Authority
- US
- United States
- Prior art keywords
- brewer
- wetting
- process according
- wholegrain
- grains
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000004464 cereal grain Substances 0.000 title claims description 7
- 235000013405 beer Nutrition 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 235000013339 cereals Nutrition 0.000 claims abstract description 22
- 230000001143 conditioned effect Effects 0.000 claims abstract 2
- 238000009736 wetting Methods 0.000 claims description 16
- 230000016507 interphase Effects 0.000 claims description 7
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 2
- 240000005979 Hordeum vulgare Species 0.000 claims description 2
- 238000009837 dry grinding Methods 0.000 claims 1
- 238000001238 wet grinding Methods 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 abstract description 5
- 238000005360 mashing Methods 0.000 abstract description 5
- 235000020985 whole grains Nutrition 0.000 abstract description 3
- 239000010903 husk Substances 0.000 description 14
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000000227 grinding Methods 0.000 description 7
- 239000000470 constituent Substances 0.000 description 4
- 235000012054 meals Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 244000052616 bacterial pathogen Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 238000013124 brewing process Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002352 surface water Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C7/00—Preparation of wort
- C12C7/01—Pretreatment of malt, e.g. malt grinding
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C7/00—Preparation of wort
- C12C7/04—Preparation or treatment of the mash
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C1/00—Preparation of malt
- C12C1/02—Pretreatment of grains, e.g. washing, steeping
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C1/00—Preparation of malt
- C12C1/16—After-treatment of malt, e.g. malt cleaning, detachment of the germ
Definitions
- the invention relates to a process for wholegrain conditioning, especially of brewer's grains, such as malted barley, and the processing of these wholegrain-conditioned cereal grains in the brewing technology.
- Brewer's grains are mechanically broken up, e.g. by crushing in roller, hammer or corundum-disk mills or in rotor-stator systems, prior to further processing in the brewing process.
- roller mills are used, a wetting of the brewer's grains in conditioning screw conveyors to a max. of 2% moisture content, for improving the milling result, is likewise known to prior art; while in the case of so-called ‘soft conditioning’ mills (Weichkondition réelle), a water component of up to 16% is introduced to the malt in a so-called softening shaft.
- soft conditioning Weichkonditionierung
- This holding time is not sufficient to allow the malt to fully absorb the water, and at least part of the introduced water is left still clinging to the husk in its free state. Because of this short holding time, and also the naturally occurring dissimilar grain sizes of the cereal grain, a homogenous water uptake in the charge is not ensured.
- the resulting solution (mash) is separated into the liquid phase (wort) and the solid substances (draff).
- a lauter tun or a mash filter is used for the separation of solid/liquid.
- the solid, water-insoluble parts of the cereal grain, the husks form a filter layer, through which the liquid (wort) is drawn downwards and filtered. If due to insufficient elasticity the husks and germ are broken up into too small a size in the coarse grinding, then firstly, an increased dissolution can lead to unwanted constituents such as polyphenols, lipids etc. getting into the wort, and furthermore it results in a pronounced negative effect on the structure of the filter layer, leading to a slowing down of the lautering of the wort.
- a coarse grinding mill for malt with a continuous monitoring of the grinding (DE-A-10218424), a wet coarse grinding (DE-A-10255504 among others), an enclosed, airless coarse grinding (DE-A-19740036), or an extrusion of malt grist (DE-A-3212390).
- the invention is based on the intended aim of developing a process for wholegrain conditioning of brewer's grain used in beer production which improves the standard of the wetting of the brewer's grain, as preparation for the coarse grinding process, and therefore by a homogenous wetting of each individual grain of up to 20% water content, without free surface water, there is a very good tender crumbliness of the endosperm and at the same time the elasticity of husks and germ is increased to such an extent that the husks and germ emerge from the coarse grinding process almost without any mechanical damage, and thus the subsequent stages in the brewing process, the mashing, the lautering, the boiling of the wort and the fermentation, can be configured with optimal raw material and process parameters.
- the copious bulk of the coarse meal produced by the inventive process allows a c. 10 to 15% higher volume throughput in the solid/liquid separation stage of the process as compared to coarse meal produced by the described methods of prior art, and this means shorter cycle times.
- a further technological advantage results from the great number of germs retained whole and therefore fully separable, if required, as this means the harmful constituents in the germ, such as lipids and others, are less likely to get extracted in the mash.
- the high portion of whole germs allows a fractioning of the coarse meal into husks, germ and endosperm by the known mechanical processes, where all or some portion of the husks can be fed back into the process at a later stage. If the unfractioned coarse meal is mashed in, then at the time of the mashing in one can already observe how the germs, kept unbroken, swim on the mash as a surface layer and can be separated from there.
- a further process advantage due to the optimised homogenous wetting of the endosperm is an accelerated reaction kinetics in the enzymatic metabolism during the mashing process.
- the wetting of the brewer's grain according to the invention is carried out in at least one stage, by using moist air, or in two stages by a pre-wetting with small quantities of water of 1-3%, then letting it stand for a while (resting phase), followed by a second wetting and where needed a second resting phase, until the desired final humidity is achieved.
- a pre-wetting with small quantities of water of 1-3% then letting it stand for a while (resting phase), followed by a second wetting and where needed a second resting phase, until the desired final humidity is achieved.
- the brewer's grains which are optimally prepared in this way for the mechanical crushing process are then led to a mechanical crushing. This can be done using the mills known from prior art in the brewing technology, and here the wholegrain-conditioned brewer's grains can be either dry-milled or wet-milled.
- the brewer's grains wetted by the inventive process can, however, also be crushed and mashed in-line, using dry crushing mills with high throughput rates which are specially adapted to the requirements of this malt.
- An additional advantage of the inventive process in the milling of the wholegrain-conditioned malt lies in the field of explosion protection, for the degree of wetting of the malt markedly reduces the risk of a dust explosion and therefore it is possible to use rollermills as found in bread grain mills.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Disintegrating Or Milling (AREA)
- Alcoholic Beverages (AREA)
- Cereal-Derived Products (AREA)
Abstract
The invention relates to a process for whole-grain conditioning, in particular of native and malted brewing cereals. To improve the mashing process and to increase the number of brews and product quality, the brewing cereals are conditioned and subsequently fed to a hulling and/or mechanical comminution process.
Description
- The invention relates to a process for wholegrain conditioning, especially of brewer's grains, such as malted barley, and the processing of these wholegrain-conditioned cereal grains in the brewing technology.
- Brewer's grains are mechanically broken up, e.g. by crushing in roller, hammer or corundum-disk mills or in rotor-stator systems, prior to further processing in the brewing process. Where roller mills are used, a wetting of the brewer's grains in conditioning screw conveyors to a max. of 2% moisture content, for improving the milling result, is likewise known to prior art; while in the case of so-called ‘soft conditioning’ mills (Weichkonditionierung), a water component of up to 16% is introduced to the malt in a so-called softening shaft. In both systems the holding time of the malt in the wetting zone is somewhere around 60 sec. This holding time is not sufficient to allow the malt to fully absorb the water, and at least part of the introduced water is left still clinging to the husk in its free state. Because of this short holding time, and also the naturally occurring dissimilar grain sizes of the cereal grain, a homogenous water uptake in the charge is not ensured.
- As the proportion of introduced water increases, there is an increased danger of the rollers of the mills sticking and/or of problems arising in connection with hygiene.
- In the subsequent mashing process, there takes place the enzymatic conversion of water-insoluble, large molecular weight constituents such as starches and proteins to smaller molecular weight, water-soluble substances, e.g. sugar and amino acids. In order to convert and extract these from the cereal grains, the mechanical preparation of the brewer's grains has have been done sufficiently.
- In the subsequent lautering process, the resulting solution (mash) is separated into the liquid phase (wort) and the solid substances (draff).
- In the brewing technology generally a lauter tun or a mash filter is used for the separation of solid/liquid.
- In the lauter tun, the solid, water-insoluble parts of the cereal grain, the husks, form a filter layer, through which the liquid (wort) is drawn downwards and filtered. If due to insufficient elasticity the husks and germ are broken up into too small a size in the coarse grinding, then firstly, an increased dissolution can lead to unwanted constituents such as polyphenols, lipids etc. getting into the wort, and furthermore it results in a pronounced negative effect on the structure of the filter layer, leading to a slowing down of the lautering of the wort.
- In the mash filter, the effect that unbroken whole husks have on the speed of lautering is of little importance due to the low height of the filter layer.
- In DE-A-4440481 the suggestion was therefore made to first wet the malt, then subject it to a pressure treatment in the milling gap, and also to separate the husks and endosperm by sieving. For this the malt mill used is fitted with at least one sieve. The separated husks are then subjected to an impact treatment so that any extract still adhering to them can be removed.
- By impacting, not only can a gain in extract be obtained, it also increases the volume of the husk fraction. This increased fraction produces an optimised filter bed in the lauter tun which in turn ensures an improved lautering; or conversely it is possible to use a smaller portion of the husks as filter material, by which means the possible entry of polyphenols is reduced.
- Also known are a coarse grinding mill for malt with a continuous monitoring of the grinding (DE-A-10218424), a wet coarse grinding (DE-A-10255504 among others), an enclosed, airless coarse grinding (DE-A-19740036), or an extrusion of malt grist (DE-A-3212390).
- The invention is based on the intended aim of developing a process for wholegrain conditioning of brewer's grain used in beer production which improves the standard of the wetting of the brewer's grain, as preparation for the coarse grinding process, and therefore by a homogenous wetting of each individual grain of up to 20% water content, without free surface water, there is a very good tender crumbliness of the endosperm and at the same time the elasticity of husks and germ is increased to such an extent that the husks and germ emerge from the coarse grinding process almost without any mechanical damage, and thus the subsequent stages in the brewing process, the mashing, the lautering, the boiling of the wort and the fermentation, can be configured with optimal raw material and process parameters.
- The copious bulk of the coarse meal produced by the inventive process allows a c. 10 to 15% higher volume throughput in the solid/liquid separation stage of the process as compared to coarse meal produced by the described methods of prior art, and this means shorter cycle times. A further technological advantage results from the great number of germs retained whole and therefore fully separable, if required, as this means the harmful constituents in the germ, such as lipids and others, are less likely to get extracted in the mash.
- If one desires to completely eliminate the extraction of these unwanted constituents, the high portion of whole germs allows a fractioning of the coarse meal into husks, germ and endosperm by the known mechanical processes, where all or some portion of the husks can be fed back into the process at a later stage. If the unfractioned coarse meal is mashed in, then at the time of the mashing in one can already observe how the germs, kept unbroken, swim on the mash as a surface layer and can be separated from there.
- A further process advantage due to the optimised homogenous wetting of the endosperm is an accelerated reaction kinetics in the enzymatic metabolism during the mashing process.
- The wetting of the brewer's grain according to the invention is carried out in at least one stage, by using moist air, or in two stages by a pre-wetting with small quantities of water of 1-3%, then letting it stand for a while (resting phase), followed by a second wetting and where needed a second resting phase, until the desired final humidity is achieved. By the pre-wetting and the resting phase, it is ensured that the entire quantity of water is taken up by the husks and their permeability is decisively increased for the second wetting. By this means, in the second wetting the quantities of water necessary for the required tender crumbliness of the endosperm and also for the required elasticity of husk and germ can be very rapidly taken up by the grain, so that no free surface water, which would have a negative effect on the process, is left remaining.
- It is also possible to wetten the cereal grains by means of an air-moistening, i.e. by a variable relative humidity of the air, where the relative (initial) humidity of the air should be at least 95%.
- The brewer's grains which are optimally prepared in this way for the mechanical crushing process are then led to a mechanical crushing. This can be done using the mills known from prior art in the brewing technology, and here the wholegrain-conditioned brewer's grains can be either dry-milled or wet-milled.
- The brewer's grains wetted by the inventive process can, however, also be crushed and mashed in-line, using dry crushing mills with high throughput rates which are specially adapted to the requirements of this malt.
- An additional advantage of the inventive process in the milling of the wholegrain-conditioned malt, lies in the field of explosion protection, for the degree of wetting of the malt markedly reduces the risk of a dust explosion and therefore it is possible to use rollermills as found in bread grain mills.
- As a result it should be possible to achieve an increase in the number of brews to about 20.
Claims (7)
1. Process for wholegrain-conditioning of brewer's grains used in beer production, such as virgin or malted brewer's grains, especially of malted barley, by homogenous wetting of the cereal grains for up to 20% effective moisture content and a related resting phase, as well as a subsequent dry and/or wet milling of the wholegrain-conditioned brewer's grains.
2. Process according to claim 1 , characterized in that the brewer's grain is shelled prior to wetting.
3. Process according to claim 1 , characterized in that the moistening/wetting and the resting phase are carried out in at least one stage.
4. Process according to claim 3 , characterized in that the wetting and the resting phase are carried out in two stages.
5. Process according to claim 1 , characterized in that the homogenous conditioned brewer's grain is crushed twice without an intermediate sifting.
6. Process according to claim 1 , characterized in that the time of the resting phase amounts to max. 30 minutes per stage.
7. Process according to claim 1 , characterized in that the brewer's grain is moistened slowly by means of moist air, with it being possible to vary the relative humidity of the air.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006021777A DE102006021777A1 (en) | 2006-04-21 | 2006-05-09 | Procedure for complete conditioning of brewing grains from barley malt, comprises peeling the brewing grains, homogeneous moistening cereal grains, sticking out and dry- and/or wet milling the brewing grain |
| DE102006021777.2 | 2006-06-09 | ||
| DE102006021777 | 2006-06-09 | ||
| PCT/CH2006/000552 WO2007140630A1 (en) | 2006-05-09 | 2006-10-09 | Process for whole-grain conditioning of brewing cereals used in brewing beer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20090117243A1 true US20090117243A1 (en) | 2009-05-07 |
| US8141799B2 US8141799B2 (en) | 2012-03-27 |
Family
ID=37680660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US12/300,083 Expired - Fee Related US8141799B2 (en) | 2006-05-09 | 2006-10-09 | Process for wholegrain-conditioning of brewer's cereal grains used in beer production |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8141799B2 (en) |
| EP (1) | EP2029720B1 (en) |
| JP (1) | JP4868551B2 (en) |
| KR (1) | KR101309606B1 (en) |
| AT (1) | ATE449158T1 (en) |
| BR (1) | BRPI0621759A2 (en) |
| CA (1) | CA2654766C (en) |
| DE (2) | DE102006021777A1 (en) |
| DK (1) | DK2029720T3 (en) |
| MX (1) | MX2008014152A (en) |
| WO (1) | WO2007140630A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4903511B2 (en) * | 2006-07-12 | 2012-03-28 | アサヒビール株式会社 | Method for producing malt from which young buds have been removed |
| US9844783B2 (en) * | 2012-07-26 | 2017-12-19 | John Bihn | Grain crushing apparatuses and processes |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4165388A (en) * | 1977-12-09 | 1979-08-21 | Grain Processing Corporation | Torrefied barley for brewer's mashes |
| US4255456A (en) * | 1978-11-22 | 1981-03-10 | Peavey Company | Roasted ground wheat coating |
| US4504514A (en) * | 1981-10-22 | 1985-03-12 | Asahi-Matsu Foods Inc. | Soybean-based fibrous or granular food material having improved texture |
| US6613371B2 (en) * | 1997-07-23 | 2003-09-02 | Cargill, Incorporated | Method for malting seeds |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE440481C (en) * | 1924-08-12 | 1927-02-08 | Jakob Spanjaard | Device for shutting down electrically driven textile machines, in particular spinning machines |
| DE7106561U (en) * | 1971-02-20 | 1971-07-15 | Bolick F | DEVICE FOR CONDITIONING MALT BEFORE SCRAPPING |
| BE786777A (en) * | 1971-07-26 | 1973-01-26 | Grandes Malteries Modernes | MUST MANUFACTURING PROCESS FOR THE FOOD INDUSTRIES, ESPECIALLY FOR THE BREWERY |
| DE2844827C2 (en) * | 1978-10-14 | 1984-09-20 | Bernhard Dipl.-Braum. 8710 Kitzingen Lenz | Device for soaking brewing materials |
| DE3515816A1 (en) * | 1985-05-02 | 1986-11-06 | Steinecker Maschinenfabrik GmbH, 8050 Freising | METHOD AND DEVICE FOR SOFTING AND WET-SCRAPING Brewing Materials |
| JPH0626508B2 (en) * | 1985-12-04 | 1994-04-13 | 日清製粉株式会社 | Method of manufacturing cereal flakes |
| JPS6368068A (en) * | 1986-09-08 | 1988-03-26 | Nisshin Eng Kk | Milling device for malt |
| JPS63178852A (en) * | 1987-01-17 | 1988-07-22 | 株式会社 サタケ | Wheat milling apparatus |
| DE4440481A1 (en) * | 1994-11-12 | 1996-05-15 | Buehler Gmbh | Process and plant for processing the husks and optimizing the refining process |
| DE19740209C1 (en) * | 1997-09-12 | 1998-08-13 | Steinecker Maschf Anton | Beer brewing method and assembly |
| JP2005261374A (en) * | 2004-03-22 | 2005-09-29 | Kamine Seiki Kogyo Kk | Method for treating fermenting raw material and method for fermenting the treated fermenting raw material |
-
2006
- 2006-05-09 DE DE102006021777A patent/DE102006021777A1/en not_active Withdrawn
- 2006-10-09 WO PCT/CH2006/000552 patent/WO2007140630A1/en active Application Filing
- 2006-10-09 CA CA2654766A patent/CA2654766C/en not_active Expired - Fee Related
- 2006-10-09 EP EP06790935A patent/EP2029720B1/en not_active Not-in-force
- 2006-10-09 AT AT06790935T patent/ATE449158T1/en active
- 2006-10-09 US US12/300,083 patent/US8141799B2/en not_active Expired - Fee Related
- 2006-10-09 MX MX2008014152A patent/MX2008014152A/en active IP Right Grant
- 2006-10-09 KR KR1020087025024A patent/KR101309606B1/en not_active IP Right Cessation
- 2006-10-09 DK DK06790935.8T patent/DK2029720T3/en active
- 2006-10-09 DE DE502006005433T patent/DE502006005433D1/en active Active
- 2006-10-09 BR BRPI0621759-1A patent/BRPI0621759A2/en not_active Application Discontinuation
- 2006-10-09 JP JP2009513528A patent/JP4868551B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4165388A (en) * | 1977-12-09 | 1979-08-21 | Grain Processing Corporation | Torrefied barley for brewer's mashes |
| US4255456A (en) * | 1978-11-22 | 1981-03-10 | Peavey Company | Roasted ground wheat coating |
| US4504514A (en) * | 1981-10-22 | 1985-03-12 | Asahi-Matsu Foods Inc. | Soybean-based fibrous or granular food material having improved texture |
| US6613371B2 (en) * | 1997-07-23 | 2003-09-02 | Cargill, Incorporated | Method for malting seeds |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0621759A2 (en) | 2011-12-20 |
| EP2029720B1 (en) | 2009-11-18 |
| MX2008014152A (en) | 2008-11-20 |
| JP4868551B2 (en) | 2012-02-01 |
| CA2654766A1 (en) | 2007-12-13 |
| DE102006021777A1 (en) | 2007-10-25 |
| KR101309606B1 (en) | 2013-09-17 |
| JP2009539356A (en) | 2009-11-19 |
| DE502006005433D1 (en) | 2009-12-31 |
| US8141799B2 (en) | 2012-03-27 |
| CA2654766C (en) | 2014-04-29 |
| DK2029720T3 (en) | 2010-02-01 |
| KR20090024105A (en) | 2009-03-06 |
| ATE449158T1 (en) | 2009-12-15 |
| WO2007140630A1 (en) | 2007-12-13 |
| EP2029720A1 (en) | 2009-03-04 |
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