US20080121360A1 - Method For Making A Layered Paper Or Board Web - Google Patents

Method For Making A Layered Paper Or Board Web Download PDF

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Publication number
US20080121360A1
US20080121360A1 US10/572,977 US57297704A US2008121360A1 US 20080121360 A1 US20080121360 A1 US 20080121360A1 US 57297704 A US57297704 A US 57297704A US 2008121360 A1 US2008121360 A1 US 2008121360A1
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stock
fraction
diluted
water
stock fraction
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Abandoned
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US10/572,977
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Matti Hietaniemi
Kari Kokkonen
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Valmet Technologies Oy
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Metso Paper Oy
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Assigned to METSO PAPER, INC. reassignment METSO PAPER, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KOKKONEN, KARI, HIETANIEMI, MATTI
Publication of US20080121360A1 publication Critical patent/US20080121360A1/en
Assigned to VALMET TECHNOLOGIES, INC. reassignment VALMET TECHNOLOGIES, INC. CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: METSO PAPER, INC.
Abandoned legal-status Critical Current

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/06Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type
    • D21F11/08Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type paper or board consisting of two or more layers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/02Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type
    • D21F11/04Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type paper or board consisting on two or more layers

Definitions

  • the invention relates to a method for making a layered paper or board web, in which method thick stock delivered to a paper machine is diluted with tail water and the diluted stock is fractionated to produce two different stock fractions of which, the first stock fraction, containing on an average finer material than the second stock fraction, is conducted into the surface layer or layers of the paper or board web, and the second stock fraction, containing on an average coarser material than the first stock fraction, is conducted into the middle layer or layers of the paper or board web.
  • a stock feed system for a multi-layer headbox is disclosed in the U.S. Pat. No. 5,746,889, in which different stock concepts are produced out of the same fresh stock to be fed into different layers of the multi-layer headbox.
  • the stock feed system contains at least one screen for transferring long fibers out of the stock that is destined to form the surface layer of the paper into the stock that is destined to form a layer placed in the interior of the paper.
  • the system may also contain another screen for transferring short fibers out of the stock that is destined to form the layer placed in the interior of the paper into the stock that is destined to form the surface layer of the paper.
  • accept fibers separated during the fractionating of the stock are on an average shorter, thinner and more pliable, and the accept contains more fines and filler than the reject.
  • the accept from fractionation will be referred to as the fine stock fraction and the reject from fractionation will be referred to as the coarse stock fraction.
  • the object of the invention is to provide an improved method for manufacturing a web from a stock by layering the different fractions thereof. Especially, the object is to maintain the different properties of the stock fractions produced by fractionating, whereupon the objectives set for the layering of the stock are easier to reach.
  • the method according to the invention is characterized by what is defined in the characterizing part of claim 1 .
  • the coarse stock fraction is diluted with water that contains less solids originating from the stock than normal tail water, the different properties of the stock fractions used for different layers of the paper or board web can be maintained better than before, which improves the result of layering in paper or board manufacturing.
  • Tail water is a filtrate removed from the web being formed on the wire section, which water is collected into a wire pit or the like and which contains fines and filler originating from the paper stock. A major part of the solids contained in the primary tail water is returned into the process by using tail water for diluting the thick stock in the short circulation of the paper machine.
  • Water suitable for diluting the coarse stock fraction is characterized by the fact that the consistency of the water is substantially lower than the consistency of the tail.
  • water used for diluting the thick stock before fractionating Preferably, the consistency of the diluting water is less than 60% of the consistency of the primary tail water.
  • Examples of possible water fractions suitable for diluting the reject are cloudy and clear filtrate from the recovery of fibers, water coming from suction flatboxes, separately collected paper machine spray water, water coming from the press section and tail water fractioned by clarification or some other method.
  • One option is to dilute tail water with a substantially cleaner water fraction such that the consistency of water used for diluting the coarse stock fraction is substantially lower than the original consistency of the tail water.
  • FIG. 1 shows a schematic view of manufacturing of layered paper using fractionating of the stock and a multi-layer headbox.
  • FIG. 2 shows manufacture of a multi-layer web using fractionating of the stock and two different web-forming units.
  • thick stock M is delivered into the paper machine via a wire pit 10 , where it is diluted with tail water originating from the wire section.
  • the diluted stock Ml is conducted with a pump P 1 into a first centrifugal cleaning step 11 of a centrifugal cleaner equipment, where the stock is fractionated into two stock fractions A and B. Fractionating is performed so, that the first stock fraction will contain fibers that on an average are thinner, shorter and more pliable and also more fines and filler than the second stock fraction B. Because of this, the stock fractions are in the following referred to as the fine stock fraction A and the coarse stock fraction B.
  • the fine stock fraction A from fractionation is conducted as two component flows Al and A 2 through pumps P A1 and P A2 and machine screens 13 A1 and 13 A2 into two layers 14 A1 and 14 A2 of a multi-layer headbox 15 that are used to form the top and bottom layers of the manufactured paper or board web.
  • the coarse stock fraction B from fractionation is diluted and the diluted stock flow B 1 is conducted through a pump P 2 into a second centrifugal cleaning step 12 of the centrifugal cleaner equipment, where impurities are extracted from the stock.
  • the accept B 2 from the centrifugal cleaning step 12 is conducted through a pump P B and a machine screen 13 B into a layer 14 B of the multi-layer headbox that is used for forming the middle layer of the paper and board web.
  • tail water D 1 taken from the wire pit 10 containing substantial amount of fibers, fines and filler, is used for dilution.
  • a water flow D 0 whose consistency is lower than the consistency of the tail water D 1 taken from the wire pit 10 , is conducted into diluting the coarse stock fraction B.
  • This water can, for example, be taken from fiber recovery screen, spray water recovery or from suction flatboxes.
  • water from the wire pit 10 can be used as dilution water, provided that enough solids have been extracted from it in a separate process stage (not shown). Dilution water, which is substantially cleaner than the tail water, can also be obtained by diluting water from the wire pit with a cleaner water fraction.
  • FIG. 2 illustrates another solution according to the invention.
  • the diluted stock M 1 is fractioned in the first centrifugal cleaning step 11 of the centrifugal cleaner equipment into two stock fractions A and B.
  • the fine stock fraction A from fractionation is conducted into a headbox 16 , which feeds the stock on a fourdrinier wire 18 for forming a first web W 1 .
  • the coarse stock fraction B from fractionation is diluted with a water flow D 0 , whose consistency is lower than that of the tail water D 1 from the wire pit 10 , and it is conducted into a second centrifugal cleaning step 12 of the centrifugal cleaner equipment.
  • the cleaned stock B 2 is conducted through a pump P B and a machine screen 13 B into a headbox 17 , which feeds the stock on a second fourdrinier wire 19 for forming a second web W 2 .
  • the second web W 2 is carried by the wire 19 on top of the first web W 1 on the wire 18 and the webs W 1 and W 2 are joined together to form a two-layered board web.
  • the web forming units may comprise besides a fourdrinier wire also a gap former.
  • fractionation can also be carried out in a manner known per se by using pressure screens.
  • fractionating techniques and the reject ratio By adapting the fractionating techniques and the reject ratio, different types of properties can be obtained for the different layers of the web. There can naturally be more than one fractionating stage.

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Abstract

A method for manufacturing a layered paper or board web, in which method thick stock (M) delivered to the paper machine is diluted with tail water and the diluted stock (M1) is fractioned in order to produce two different stock fractions (A,B). The first stock fraction (A), with finer material, is conducted into the surface layer or layers of the web, and the second stock fraction (B), containing coarser material, is conducted into the middle layer or layers of the web. Before feeding into a headbox (15), the coarse stock fraction (B) is diluted with water whose consistency is substantially lower than the consistency of the water added into the thick stock (M) before fractionating. When water containing less solids than the normal tail water dilutes the coarse stock fraction, the stock fractions used for different web layers can better maintain their different properties, which improves the result of layering.

Description

  • The invention relates to a method for making a layered paper or board web, in which method thick stock delivered to a paper machine is diluted with tail water and the diluted stock is fractionated to produce two different stock fractions of which, the first stock fraction, containing on an average finer material than the second stock fraction, is conducted into the surface layer or layers of the paper or board web, and the second stock fraction, containing on an average coarser material than the first stock fraction, is conducted into the middle layer or layers of the paper or board web.
  • A stock feed system for a multi-layer headbox is disclosed in the U.S. Pat. No. 5,746,889, in which different stock concepts are produced out of the same fresh stock to be fed into different layers of the multi-layer headbox. The stock feed system contains at least one screen for transferring long fibers out of the stock that is destined to form the surface layer of the paper into the stock that is destined to form a layer placed in the interior of the paper. The system may also contain another screen for transferring short fibers out of the stock that is destined to form the layer placed in the interior of the paper into the stock that is destined to form the surface layer of the paper.
  • Fractionating methods that apply centrifugal cleaning are disclosed in WO published applications Nos. 0 129 311 A1 and 0 222 947 A1, in which accept from the first centrifugal cleaning step is transferred into the surface layers of the web to be formed, and the accept from a second or lower step is transferred into the middle layers of the web to be formed. By fractionating the stock, lower fines contents and higher average fiber length can be achieved in the middle layers of the web than in the surface layers of the web. On the other hand, higher fines and filler contents can be achieved in the surface layers of the web than in the middle layers, which, among other things, improves the printing properties of the paper.
  • The accept fibers separated during the fractionating of the stock are on an average shorter, thinner and more pliable, and the accept contains more fines and filler than the reject. For simplicity's sake, the accept from fractionation will be referred to as the fine stock fraction and the reject from fractionation will be referred to as the coarse stock fraction.
  • It is typical for fractionating that the consistency of the accept is decreased and the consistency of the reject is increased compared to the consistency of the feed. Because of this, the reject often has to be diluted before it can be conducted into the headbox of the paper machine. In WO 0 222 947, the rejects from the fractionating stages are diluted with tail water taken from a wire pit before they are transferred into. the next stage. In WO 0 129 311, the same tail water is being used for diluting both the accept and the reject before they are fed into the different layers of the multi-layer headbox. When the coarse stock fraction intended for the middle layers of the web is diluted with “impure” tail water, i.e. containing plenty of fines and filler, at least some of the advantages obtained with fractionating are lost. Because of the tail water, the drainability of the reject can go down almost to the level of the accept and the filler content can go up to near the filler content of the accept.
  • The object of the invention is to provide an improved method for manufacturing a web from a stock by layering the different fractions thereof. Especially, the object is to maintain the different properties of the stock fractions produced by fractionating, whereupon the objectives set for the layering of the stock are easier to reach.
  • In order to obtain these and other objects that will become evident later, the method according to the invention is characterized by what is defined in the characterizing part of claim 1.
  • When the coarse stock fraction is diluted with water that contains less solids originating from the stock than normal tail water, the different properties of the stock fractions used for different layers of the paper or board web can be maintained better than before, which improves the result of layering in paper or board manufacturing.
  • Tail water is a filtrate removed from the web being formed on the wire section, which water is collected into a wire pit or the like and which contains fines and filler originating from the paper stock. A major part of the solids contained in the primary tail water is returned into the process by using tail water for diluting the thick stock in the short circulation of the paper machine.
  • Water suitable for diluting the coarse stock fraction is characterized by the fact that the consistency of the water is substantially lower than the consistency of the tail. water used for diluting the thick stock before fractionating. Preferably, the consistency of the diluting water is less than 60% of the consistency of the primary tail water.
  • Examples of possible water fractions suitable for diluting the reject are cloudy and clear filtrate from the recovery of fibers, water coming from suction flatboxes, separately collected paper machine spray water, water coming from the press section and tail water fractioned by clarification or some other method. One option is to dilute tail water with a substantially cleaner water fraction such that the consistency of water used for diluting the coarse stock fraction is substantially lower than the original consistency of the tail water.
  • In the following, the invention will be described with reference to the examples in the appended figures, but the intention is not to limit the invention to these only.
  • FIG. 1 shows a schematic view of manufacturing of layered paper using fractionating of the stock and a multi-layer headbox.
  • FIG. 2 shows manufacture of a multi-layer web using fractionating of the stock and two different web-forming units.
  • According to FIG. 1, thick stock M is delivered into the paper machine via a wire pit 10, where it is diluted with tail water originating from the wire section. The diluted stock Ml is conducted with a pump P1 into a first centrifugal cleaning step 11 of a centrifugal cleaner equipment, where the stock is fractionated into two stock fractions A and B. Fractionating is performed so, that the first stock fraction will contain fibers that on an average are thinner, shorter and more pliable and also more fines and filler than the second stock fraction B. Because of this, the stock fractions are in the following referred to as the fine stock fraction A and the coarse stock fraction B.
  • The fine stock fraction A from fractionation is conducted as two component flows Al and A2 through pumps PA1 and PA2 and machine screens 13 A1 and 13 A2 into two layers 14 A1 and 14 A2 of a multi-layer headbox 15 that are used to form the top and bottom layers of the manufactured paper or board web.
  • The coarse stock fraction B from fractionation is diluted and the diluted stock flow B1 is conducted through a pump P2 into a second centrifugal cleaning step 12 of the centrifugal cleaner equipment, where impurities are extracted from the stock. The accept B2 from the centrifugal cleaning step 12 is conducted through a pump PB and a machine screen 13 B into a layer 14 B of the multi-layer headbox that is used for forming the middle layer of the paper and board web.
  • As the fractionating increases the consistency of the coarse stock fraction B, the stock B must be diluted before conducting it into the headbox 15. Conventionally, tail water D1 taken from the wire pit 10, containing substantial amount of fibers, fines and filler, is used for dilution. In the solution according to the invention, a water flow D0, whose consistency is lower than the consistency of the tail water D1 taken from the wire pit 10, is conducted into diluting the coarse stock fraction B. This water can, for example, be taken from fiber recovery screen, spray water recovery or from suction flatboxes. Also water from the wire pit 10 can be used as dilution water, provided that enough solids have been extracted from it in a separate process stage (not shown). Dilution water, which is substantially cleaner than the tail water, can also be obtained by diluting water from the wire pit with a cleaner water fraction.
  • FIG. 2 illustrates another solution according to the invention. There, the diluted stock M1 is fractioned in the first centrifugal cleaning step 11 of the centrifugal cleaner equipment into two stock fractions A and B. The fine stock fraction A from fractionation is conducted into a headbox 16, which feeds the stock on a fourdrinier wire 18 for forming a first web W1. The coarse stock fraction B from fractionation is diluted with a water flow D0, whose consistency is lower than that of the tail water D1 from the wire pit 10, and it is conducted into a second centrifugal cleaning step 12 of the centrifugal cleaner equipment. The cleaned stock B2 is conducted through a pump PB and a machine screen 13 B into a headbox 17, which feeds the stock on a second fourdrinier wire 19 for forming a second web W2. The second web W2 is carried by the wire 19 on top of the first web W1 on the wire 18 and the webs W1 and W2 are joined together to form a two-layered board web.
  • When manufacturing multi-layer web, there naturally can be more than two separate web forming units and the web forming units may comprise besides a fourdrinier wire also a gap former.
  • Instead of the above-described centrifugal cleaning device, fractionation can also be carried out in a manner known per se by using pressure screens. By adapting the fractionating techniques and the reject ratio, different types of properties can be obtained for the different layers of the web. There can naturally be more than one fractionating stage.
  • In the following the patent claims will be given, and the details of the invention may show variation within the scope of the inventive idea defined in said claims and differ from the details given above for the sake of example only.

Claims (14)

1-10. (canceled)
11. A method for manufacturing a layered paper or board web, comprising the steps of:
delivering thick stock to a paper machine;
diluting the thick stock with tail water of a consistency;
fractionating the diluted thick stock to produce two different stock fractions comprised of a first stock fraction and a second stock fraction, wherein the first stock fraction contains on average finer material than the second stock fraction, and wherein the second stock fraction contains on average coarser material than the first stock fraction; and
diluting the second stock fraction with dilution water having a consistency that is substantially lower than the consistency of the tail water added into the thick stock before fractionating, wherein the first stock fraction and the diluted second stock fraction are each fed into a headbox, and the first stock fraction is conducted into a surface layer or layers of the paper or board web, and the diluted second stock fraction is conducted into a middle layer or layers of the paper or board web.
12. The method of claim 11, wherein the dilution water has a consistency which is at the most 60 percent of the consistency of the tail water used for diluting the thick stock before fractionating.
13. The method of claim 11, wherein the dilution water is water from fiber recovery, suction flatboxes and/or a press section and/or separately collected fabric conditioning water and/or cleaned tail water.
14. The method of claim 11, wherein the dilution water is tail water that has been diluted with a water type substantially cleaner than the tail water itself.
15. The method of claim 11, further comprising the step of conducting the second stock fraction into the headbox through a cleaning device, wherein the second stock fraction is diluted before it is fed into said cleaning device.
16. The method of claim 11, wherein the step of fractionating the diluted thick stock to produce two different stock fractions, comprises fractionating the diluted thick stock in centrifugal cleaners.
17. The method of claim 11, wherein the step of fractionating the diluted thick stock to produce two different stock fractions, comprises fractionating the diluted thick stock by screens.
18. The method of claim 11, wherein the step of fractionating the diluted thick stock to produce two different stock fractions, comprises fractionating the diluted thick stock in two or more stages.
19. The method of claim 11, wherein the first stock fraction and the diluted second stock fraction are fed into the same headbox which is a multi-layer headbox, the first stock fraction being used for forming a surface layer of the paper or board web, and the second stock fraction being used for forming a middle layer of the paper or board web.
20. The method of claim 11 wherein the first stock fraction is conducted into at least one headbox used for forming a surface layer of the multi-layer web, and the second stock fraction is conducted into at least one other headbox used for forming a middle layer of the multi-layer web.
21. A method for manufacturing a layered paper or board web, comprising the steps of:
delivering thick stock to a paper machine;
diluting the thick stock with tail water of a consistency;
fractionating the diluted thick stock to produce two different stock fractions comprised of a first stock fraction and a second stock fraction, wherein the first stock fraction contains on average finer material than the second stock fraction, and wherein the second stock fraction contains on average coarser material than the first stock fraction;
feeding the first stock fraction into a first headbox and conducting the first stock fraction into a surface layer or layers of the paper or board web;
taking dilution water from a recovery screen, or a spray water recovery, or suction flatboxes, or from a wire pit and extracting solids therefrom in a separate process stage, or from the wire pit and diluting with a cleaner water fraction, said dilution water having a consistency that is substantially lower than the consistency of the tail water added into the thick stock before fractionating; and
diluting the second stock fraction with the dilution water, and then feeding the diluted second stock fraction into the first headbox or a second headbox and conducting the diluted second stock fraction into a middle layer or layers of the paper or board web.
22. The method of claim 21, wherein the step of diluting the second stock fraction with dilution water comprises diluting the second stock fraction with water whose consistency is at the most 60 percent of the consistency of the tail water used for diluting the thick stock before fractionating.
23. The method of claim 21, wherein the first stock fraction is conducted into at least one layer of a multi-layer headbox used for forming a surface layer of the paper or board web, and the second stock fraction is conducted into at least one other layer of the same multi-layer headbox used for forming a middle layer of the paper or board web.
US10/572,977 2003-09-24 2004-09-20 Method For Making A Layered Paper Or Board Web Abandoned US20080121360A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI20031376 2003-09-24
FI20031376A FI115234B (en) 2003-09-24 2003-09-24 A process for making a laminated paper or board web
PCT/FI2004/000549 WO2005028747A1 (en) 2003-09-24 2004-09-20 Method for making a layered paper or board web

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US20080121360A1 true US20080121360A1 (en) 2008-05-29

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US10/572,977 Abandoned US20080121360A1 (en) 2003-09-24 2004-09-20 Method For Making A Layered Paper Or Board Web

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US (1) US20080121360A1 (en)
CN (1) CN1856617A (en)
DE (1) DE112004001766T5 (en)
FI (1) FI115234B (en)
WO (1) WO2005028747A1 (en)

Cited By (3)

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Publication number Priority date Publication date Assignee Title
US20090173463A1 (en) * 2006-04-07 2009-07-09 Gruppo Cordenons S.P.A. Security paper material, in particular for labelling and packaging, and manufacturing method thereof
US8871059B2 (en) * 2012-02-16 2014-10-28 International Paper Company Methods and apparatus for forming fluff pulp sheets
US11441268B2 (en) * 2018-01-05 2022-09-13 International Paper Company Paper products having increased bending stiffness and cross-direction strength and methods for making the same

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CN103015267B (en) * 2012-12-17 2016-03-02 金红叶纸业集团有限公司 The using method of paper grade (stock) softener
CN104213455A (en) * 2014-08-18 2014-12-17 湖北欧华达纤维科技有限公司 Automatic environment-friendly regenerated fiber board production system
CN107460764B (en) * 2017-09-13 2020-10-27 临泉鹏成机电技术有限公司 High-quality paper web papermaking process
EP3502348B1 (en) * 2017-12-21 2020-06-24 BillerudKorsnäs AB Fibre fractionation

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US5639349A (en) * 1994-01-22 1997-06-17 Voith Sulzer Papiermaschinen Gmbh Method and device for quality improvement in multilayer and multiply papers
US6210529B1 (en) * 1998-06-10 2001-04-03 Valmet Corporation Method for regulating the surface level and consistency in a tank for metering component stock
US6210535B1 (en) * 1995-06-01 2001-04-03 Valmet Corporation Stock feed system for a multi-layer headbox and method in the operation of a multi-layer headbox
US6267845B1 (en) * 1998-06-10 2001-07-31 Valmet Corporation Process arrangement for the short circulation in a paper or board machine

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FI111391B (en) * 2001-04-23 2003-07-15 Metso Paper Inc Process and process arrangement in the short circulation of a paper machine

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Publication number Priority date Publication date Assignee Title
US5639349A (en) * 1994-01-22 1997-06-17 Voith Sulzer Papiermaschinen Gmbh Method and device for quality improvement in multilayer and multiply papers
US6210535B1 (en) * 1995-06-01 2001-04-03 Valmet Corporation Stock feed system for a multi-layer headbox and method in the operation of a multi-layer headbox
US6210529B1 (en) * 1998-06-10 2001-04-03 Valmet Corporation Method for regulating the surface level and consistency in a tank for metering component stock
US6267845B1 (en) * 1998-06-10 2001-07-31 Valmet Corporation Process arrangement for the short circulation in a paper or board machine

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090173463A1 (en) * 2006-04-07 2009-07-09 Gruppo Cordenons S.P.A. Security paper material, in particular for labelling and packaging, and manufacturing method thereof
US8691051B2 (en) * 2006-04-07 2014-04-08 Gruppo Cordenons S.P.A. Security paper material, in particular for labelling and packaging, and manufacturing method thereof
US8871059B2 (en) * 2012-02-16 2014-10-28 International Paper Company Methods and apparatus for forming fluff pulp sheets
US9347182B2 (en) 2012-02-16 2016-05-24 International Paper Company Methods and apparatus for forming fluff pulp sheets
US20170081802A1 (en) * 2012-02-16 2017-03-23 International Paper Company Methods and apparatus for forming fluff pulp sheets
US11441268B2 (en) * 2018-01-05 2022-09-13 International Paper Company Paper products having increased bending stiffness and cross-direction strength and methods for making the same

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Publication number Publication date
FI115234B (en) 2005-03-31
DE112004001766T5 (en) 2006-08-03
CN1856617A (en) 2006-11-01
FI20031376A0 (en) 2003-09-24
WO2005028747A1 (en) 2005-03-31

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