US20070110609A1 - Iron-chromium-aluminum alloy - Google Patents
Iron-chromium-aluminum alloy Download PDFInfo
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- US20070110609A1 US20070110609A1 US10/552,310 US55231004A US2007110609A1 US 20070110609 A1 US20070110609 A1 US 20070110609A1 US 55231004 A US55231004 A US 55231004A US 2007110609 A1 US2007110609 A1 US 2007110609A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
- B01D2258/012—Diesel engines and lean burn gasoline engines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the invention relates to an iron-chromium-aluminium alloy having good oxidation resistance.
- U.S. Pat. No. 5,366,139 discloses a method whereby foils of iron-chromium-aluminium alloys are produced by way of suitable iron-chromium steel being coated on both sides with aluminium or aluminium alloys by way of roll cladding. This composite metal is processed exclusively by cold deformation and is subjected to diffusion annealing to produce a homogeneous structure.
- a further method whereby the coating is achieved by way of hot dip aluminizing is disclosed in DE-A 198 34 552.
- the latter foil has the following chemical composition (all details in % by weight): 18-25% Cr, 4-10% Al, 0.03-0.08% Y, max. 0.01% Ti, 0.01-0.05% Zr, 0.01-0.05% Hf, 0.5-1.5% Si, residual iron and method-associated impurities. Foils fabricated with this alloy were to date used in four-stroke-combustion engines.
- the solution to the task set is provided by an iron-chromium-aluminium alloy having good oxidation resistance, with (in % by weight) 2.5 to 5.0% Al and 10 to 25% Cr and 0.05-0.8% Si as well as additions of >0.01 to 0.1% Y and/or >0.01 to 0.1% Hf and/or >0.01 to 0.2% Zr and/or >0.01 to 0.2% Cerium mischmetal (Ce, La, Nd) (i.e., at least two of Ce, La, or Nd) as well as production-associated impurities.
- Cerium mischmetal Ce, La, Nd
- a preferred iron-chromium-aluminium alloy having good oxidation resistance has the following composition (in % by weight): 2.5-5% Al and 13 to 21% Cr as well as alternative additions of:
- One method for the fabrication of semi-finished articles from this alloy is characterised in that the semi-finished article following melting of the alloy by way of ingot casting or continuous casting as well as hot and cold deformation may be required to undergo one (or more) intermediate annealing processes.
- the production of a foil of 50 ⁇ m or even 20 ⁇ m thickness is possible in the conventional manner in such compositions.
- the slabs can even be produced by way of the particularly inexpensive continuous casting process which in the presence of higher aluminium contents is, as a rule, connected with high losses.
- Aluchrom ISE, Hf3 and Hf4 represent comparative alloys and Aluchrom Hf1 and Hf2 are the subject of the present invention.
- the examples in accordance with the invention were produced by melting in the electric arc furnace, continuous casting or ingot casting, hot rolling to a thickness of about 3 mm, with intermediate annealing at end thicknesses of 0.02 to 0.05 and cold rolling on a 20 roller scaffold.
- the exact tuning of the oxygen affine reactive elements is of predominant importance.
- the alloys according to the present invention Aluchrom Hf1 and Aluclirom Hf2 in spite of their comparatively low Al-content of around 3%, show an extremely good oxidation resistance, which is similar to the comparative alloys Aluclirom ISE and Aluchrom Hf4.
- Aluchrom Hf3 in spite of its high Al— content of 5.36%, has lower values which can be attributed to the Y content being too low. In this instance therefore additions of Y or Cerium mischmetal result in a markedly improved oxidation resistance. (compare Aluchrom ISE and Aluchrom Rf4).
- a further important aspect for the construction of metallic catalytic converter substrates for Diesel engines and two-stroke engines is the dimensional stability of the foil during the useful life of the foil.
- a respective characteristic feature in this regard is the linear deformation which should, if possible, not exceed 4%.
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- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Fuel Cell (AREA)
- Soft Magnetic Materials (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
The invention relates to an iron-chromium-aluminum alloy having a good oxidation resistance, comprising (in % by mass) 2.5 to 5.0% Al, 10 to 25% Cr, 0.05 0.8% Si, and additions of >0.01 to 0.1% Y and/or >0.01 to 0.1% Hf and/or >0.01 to 0.2% Zr and/or >0.01 to 0.2% Cerium mischmetal (Ce, La, Nd) as well as production-associated impurities.
Description
- 1. Field of the Invention
- The invention relates to an iron-chromium-aluminium alloy having good oxidation resistance.
- 2. Description of Related Art
- Although the catalytic converter is the rule in four-stroke-engines today, the development of catalytic converters for Diesel and two-stroke engines is still in its beginnings. In four-stroke-engines, alloys are used which are similar to those described in EP-A 0387 670: with (in % by weight) 20-25% Cr, 5-8% Al, max. 0.01% P, max. 0.01% Mg, max. 0.5% Mn, max. 0.005% S, residual iron and unavoidable impurities and, if required, alloying elements, such as 0.03-0 08% Y, 0.004-0.008% N, 0.02-0.04% C, 0.035-0.07% Ti, 0.035-0.07% Zr. Since production by traditional methods, namely conventional pouring of the alloy and subsequent hot and cold deformation, is very difficult where aluminium contents of below 6% by weight are concerned and in cases of higher aluminium contents is no longer workable in large-scale productions, alternative production methods have been developed.
- U.S. Pat. No. 5,366,139, for instance, discloses a method whereby foils of iron-chromium-aluminium alloys are produced by way of suitable iron-chromium steel being coated on both sides with aluminium or aluminium alloys by way of roll cladding. This composite metal is processed exclusively by cold deformation and is subjected to diffusion annealing to produce a homogeneous structure.
- A further method whereby the coating is achieved by way of hot dip aluminizing is disclosed in DE-A 198 34 552. The latter foil has the following chemical composition (all details in % by weight): 18-25% Cr, 4-10% Al, 0.03-0.08% Y, max. 0.01% Ti, 0.01-0.05% Zr, 0.01-0.05% Hf, 0.5-1.5% Si, residual iron and method-associated impurities. Foils fabricated with this alloy were to date used in four-stroke-combustion engines.
- It is the object of the present invention to produce an alloy for applications in the temperature range of 250° C. to 1000° C. having an adequate oxidation resistance which is also achievable in large scale productions.
- The solution to the task set is provided by an iron-chromium-aluminium alloy having good oxidation resistance, with (in % by weight) 2.5 to 5.0% Al and 10 to 25% Cr and 0.05-0.8% Si as well as additions of >0.01 to 0.1% Y and/or >0.01 to 0.1% Hf and/or >0.01 to 0.2% Zr and/or >0.01 to 0.2% Cerium mischmetal (Ce, La, Nd) (i.e., at least two of Ce, La, or Nd) as well as production-associated impurities.
- A preferred iron-chromium-aluminium alloy having good oxidation resistance has the following composition (in % by weight): 2.5-5% Al and 13 to 21% Cr as well as alternative additions of:
-
- >0.01 to 0.1% Y and >0.01 to 0.1% Hf;
- >0.01% to 0.1% Y and >0.01 to 0.1% Hf and >0.01% to 0.2% Zr;
- >0.01 to 0.2% Cerium mischmetal (Ce, La, Nd);
- >0.01 to 0.2% Zr and >0.01 to 0.2% Cerium mischmetal (Ce, La, Nd)
as well as production-associated impurities.
- Surprisingly, it has been found that, in Diesel engines and two-stroke engines, aluminium contents above 5% are not required. 2.5 to 5.0% by weight are quite sufficient to guarantee an adequate oxidation resistance in the temperature range of 250° C. to 1000° C. which is of interest in this regard, as the examples presented below will show. Indispensable in this situation are the additions of reactive elements to guarantee the oxidation resistance. Particularly proven are 0.01-0.1% Y and/or 0.01-0.1% Hf, where, in the presence of both elements, the sum of both these elements must not exceed 0.15% by weight, because at this level the positive effect of the oxidation resistance will be reversed to a negative. However, also by adding other oxygen-affine reactive elements, such as for instance Zr, Cerium mischmetal and La, positive effects can be achieved in relation to the oxidation resistance of the alloy.
- One method for the fabrication of semi-finished articles from this alloy is characterised in that the semi-finished article following melting of the alloy by way of ingot casting or continuous casting as well as hot and cold deformation may be required to undergo one (or more) intermediate annealing processes.
- Advantageous embodiments of the method are described in the disclosure.
- The production of a foil of 50 μm or even 20 μm thickness is possible in the conventional manner in such compositions. The slabs can even be produced by way of the particularly inexpensive continuous casting process which in the presence of higher aluminium contents is, as a rule, connected with high losses.
- Preferred applications for this alloy are:
-
- components in exhaust systems of Diesel engines in vessels, Diesel engines and two-stroke engines of motor vehicles (cars, trucks) or motorbikes;
- substrate foils in metallic catalytic converters of Diesel engines and two-stroke engines;
- components in Diesel engine glow plugs;
- knitted metal fabrics and mats for exhaust cleaning systems used in for instance motorcycles, brush cutters, lawn mowers and power saws;
- components for exhaust cleaning systems for fuel cells;
- spraying wires for surface coatings of components employed in exhaust systems of diesel and two-stroke systems;
- heating conductors or resistance materials for electrical preheating of exhaust cleaning systems in Diesel and two-stroke systems.
- The subject of the invention is described in greater detail in the following examples.
- (Aluchrom ISE, Hf3 and Hf4 represent comparative alloys and Aluchrom Hf1 and Hf2 are the subject of the present invention).
- Chemical Compositions
Chemische Zusammensetzungen Element/ Aluchrom Aluchrom Aluchrom Aluchrom Aluchrom Masse % ISE Hf 1 Hf 2 Hf 3 Hf4 Cr 20.45 17.25 18.20 21.05 20.15 Ni 0.19 0.14 0.16 0.17 0.16 Mn 0.25 0.28 0.15 0.11 0.21 Si 0.43 0.54 0.29 0.30 0.22 Tl 0.01 <0.01 <0.01 <0.01 0.01 Cu 0.03 0.05 0.02 0.03 0.07 S 0.002 0.002 0.002 0.002 0.002 P 0.011 0.009 0.013 0.009 0.012 Al 5.27 2.78 3.30 5.36 5.70 Mg 0.008 0.004 0.009 0.009 0.009 Zr 0.003 0.05 0.01 0.02 0.05 V 0.04 0.05 0.03 0.04 0.03 C 0.006 0.032 0.023 0.051 0.023 N 0.004 0.005 0.004 0.002 0.005 Hf — 0.04 0.05 0.03 0.05 Y — 0.03 0.05 <0.01 0.06 Cer MM 0.015 — — — (Ce, La, Nd) - The examples in accordance with the invention were produced by melting in the electric arc furnace, continuous casting or ingot casting, hot rolling to a thickness of about 3 mm, with intermediate annealing at end thicknesses of 0.02 to 0.05 and cold rolling on a 20 roller scaffold.
- Oxidation Test
- As the examples show, besides the Al content, the exact tuning of the oxygen affine reactive elements is of predominant importance. For instance, the alloys according to the present invention, Aluchrom Hf1 and Aluclirom Hf2, in spite of their comparatively low Al-content of around 3%, show an extremely good oxidation resistance, which is similar to the comparative alloys Aluclirom ISE and Aluchrom Hf4. By comparison, Aluchrom Hf3, in spite of its high Al— content of 5.36%, has lower values which can be attributed to the Y content being too low. In this instance therefore additions of Y or Cerium mischmetal result in a markedly improved oxidation resistance. (compare Aluchrom ISE and Aluchrom Rf4).
- A further important aspect for the construction of metallic catalytic converter substrates for Diesel engines and two-stroke engines is the dimensional stability of the foil during the useful life of the foil. A respective characteristic feature in this regard is the linear deformation which should, if possible, not exceed 4%.
- Dimensional Stability
- This also shows that the alloys in accordance with the present invention, Aluchrom Hf1 and Aluchrom Hf2, having an al content of around 3%, achieve a dimensional stability of <4% as do the comparative alloys Aluchrom ISE and Aluchrom Hf4 having an al content of >5%. Also in this case, in spite of their comparatively high Al content of 5.36% but too low a Y content, the comparative alloy Aluchrom Hf3 does not meet the requirements, since the linear deformation after 400 h, being about 5%, is clearly too great.
- Thus it is surprisingly found that with a suitable tuning of the oxygen-affine reactive elements, even where Al contents clearly below 5% are present, a dimensional stability necessary for the production of metallic catalytic converters can be achieved.
- A cost-effective production, based on the comparatively low Al contents, by way of ingot casting, continuous casting or even strip casting whilst observing the application-specific parameters is thus achieved.
Claims (24)
1.-19. (canceled)
20. Iron-chromium-aluminium alloy having good oxidation resistance, comprising, in % by weight, as follows:
2.5 to 5.0% Al;
10 to 25% Cr;
0.05-0.8% Si; and
>0.01 to 0.1% of a total weight of Y, Sc, Ti, Nd, Ta, V, and/or one or more rare earth metal elements; and/or
>0.01 to 0.1% of a total weight of Hf, Sc, Ti, Nd, Ta, V, and/or one or more rare earth metal elements; and/or
>0.01 to 0.2% of a total weight of Zr, Sc, Ti, Nd, Ta, V, and/or one or more rare earth metal elements; and/or
>0.01 to 0.2% of a total weight of Cerium mischmetal (Ce, La, Nd), Sc, Ti, Nd, Ta, V, and/or one or more rare earth metal elements, said Cerium mischmetal (Ce, La, Nd) comprising at least two of Ce, La, or Nd.
21. The alloy in accordance with claim 20 , comprising:
>0.01 to 0.1% Y and/or >0.01 to 0.1% Hf and/or >0.01 to 0.2% Zr and/or >0.01 to 0.2% Cerium mischmetal (Ce, La, Nd).
22. The alloy in accordance with claim 20 , comprising, in % by weight,
2.5 to <5% Al;
13 to 21% Cr;
>0.01 to 0.1% Y; and
>0.01 to 0.1% Hf.
23. The alloy in accordance with claim 20 , comprising, in % by weight,
2.5 to <5% Al;
13 to 21% Cr;
>0.01 to 0.1% Y;
>0.01 to 0.1% Hf; and
>0.01 to 0.2% Zr.
24. The alloy in accordance with claim 20 , comprising, in % by weight,
2.5 to 5% Al;
13 to 21% Cr; and
>0.01 to 0.2% Cerium mischmetal (Ce, La, Nd).
25. The alloy in accordance with claim 20 , comprising, in % by weight,
2.5 to 5% Al;
13 to 21% Cr;
>0.01 to 0.2% Zr; and
>0.01 to 0.2% Cerium mischmetal (Ce, La, Nd).
26. The alloy in accordance with claim 20 , comprising, in % by weight,
max. 0.06% C;
max. 0.6% Si;
max. 0.6% Mn;
max. 0.04% P;
max. 0.01% S;
max. 0.02% N;
max. 0.1% Ti; and
in total max. 0.5% Nb, Mo, Cu and/or W.
27. The alloy in accordance with claim 20 , comprising Sc, Ti, Nd, Ta, V and/or one or more rare earth metal elements.
28. The alloy in accordance with claim 20 , comprising, in % by weight,
Cr between 14 and 19%; and
Al between 2.5 and 4.5%, wherein
the total content, in % by weight, of Y, Hf, Zr, Cerium mischmetal (Ce, La, Nd), Sc, Ti, Nb, Ta, V and/or one or more rare earth metals does not exceed 0.6%.
29. The alloy in accordance with claim 28 , wherein, in % by weight, the Cr content is >17.5% and <19% and the Al content is >3% and <4%.
30. The alloy in accordance with claim 20 , wherein, in % by weight, the Y content is >0.02% and <0.08% and the Hf content is >0.02% and <0.06%.
31. The alloy in accordance with claim 20 , wherein said Cerium mischmetal (Ce, La, Nd) comprises Ce, La, and Nd.
32. The alloy in accordance with claim 21 , wherein said Cerium mischmetal (Ce, La, Nd) comprises Ce, La, and Nd.
33. Components comprising the alloy in accordance with claim 20 , wherein said components, after being annealed at 1100° C. for 400 h at a thickness of 50 μm, show a linear deformation of <4%.
34. A method for the fabrication of semi-finished articles comprising the alloy in accordance with claim 20 , comprising
melting the alloy; and
performing ingot casting, continuous casting or strip casting; and/or
hot and/or cold deformation; and/or
performing one or more intermediate annealing processes.
35. A component in Diesel vehicles and two-stroke devices, said component comprising the alloy in accordance with claim 20 .
36. The component in accordance with claim 35 , wherein said Diesel vehicles and two-stroke devices comprise Diesel and two-stroke engines.
37. The component in accordance with claim 36 , wherein said component is a substrate foil in metallic catalytic exhaust converters.
38. Exhaust cleaning systems, comprising the component in accordance with claim 36 , wherein said component is formed in a shape of a wire.
39. Diesel engine glow cells comprising the component in accordance with claim 36 .
40. Components employed in exhaust systems of Diesel or two-stroke engines comprising a surface coating, said surface coating formed by applying said surface coating from a spraying wire comprising the alloy in accordance with claim 20 .
41. The component in accordance with claim 36 , wherein said component is a heating conductor or resistance material for electrical preheating of exhaust cleaning systems of Diesel or two-stroke engines.
42. Exhaust cleaning systems of fuel cells comprising a component comprising the alloy in accordance with claim 20.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10310865.3 | 2003-03-11 | ||
DE10310865A DE10310865B3 (en) | 2003-03-11 | 2003-03-11 | Use of an iron-chromium-aluminum alloy containing additions of hafnium, silicon, yttrium, zirconium and cerium, lanthanum or neodymium for components in Diesel engines and two-stroke engines |
PCT/DE2004/000454 WO2004081247A2 (en) | 2003-03-11 | 2004-03-08 | Iron-chromium-aluminum alloy |
Publications (1)
Publication Number | Publication Date |
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US20070110609A1 true US20070110609A1 (en) | 2007-05-17 |
Family
ID=32185994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US10/552,310 Abandoned US20070110609A1 (en) | 2003-03-11 | 2004-03-08 | Iron-chromium-aluminum alloy |
Country Status (14)
Country | Link |
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US (1) | US20070110609A1 (en) |
EP (1) | EP1601804B1 (en) |
JP (1) | JP2006519929A (en) |
KR (1) | KR20050109545A (en) |
AU (1) | AU2004219941B2 (en) |
BR (1) | BRPI0409579B1 (en) |
CA (1) | CA2529720A1 (en) |
DE (2) | DE10310865B3 (en) |
ES (1) | ES2445584T3 (en) |
MX (1) | MXPA05009519A (en) |
RU (1) | RU2341581C2 (en) |
UA (1) | UA81021C2 (en) |
WO (1) | WO2004081247A2 (en) |
ZA (1) | ZA200506916B (en) |
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US20100092749A1 (en) * | 2007-01-29 | 2010-04-15 | Thyssenkrupp Vdm Gmbh | Use of an iron-chromium-aluminum alloy with long service life and minor changes in heat resistance |
US20140186540A1 (en) * | 2011-10-17 | 2014-07-03 | Ford Global Technologies, Llc | Plasma spraying process |
US9624563B2 (en) | 2011-04-01 | 2017-04-18 | Jfe Steel Corporation | Stainless steel foil and catalyst carrier for exhaust gas purifying device using the foil |
US10151020B2 (en) | 2013-07-30 | 2018-12-11 | Jfe Steel Corporation | Ferritic stainless steel foil |
US10196721B2 (en) | 2011-06-21 | 2019-02-05 | Vdm Metals International Gmbh | Heat-resistant iron-chromium-aluminum alloy with low chromium vaporization rate and elevated thermal stability |
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CN113337783A (en) * | 2021-06-01 | 2021-09-03 | 钢铁研究总院淮安有限公司 | Production method of barium-cleaned iron-chromium-aluminum alloy |
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EP1970461A1 (en) * | 2007-03-14 | 2008-09-17 | Siemens Aktiengesellschaft | Turbine part with heat insulation layer |
DE102010002864A1 (en) | 2009-03-18 | 2010-09-23 | Behr Gmbh & Co. Kg | Layer structured heat-exchanger for high temperature fuel cell system of electricity supply arrangement in motor vehicle, has layer plates and/or cover plates manufactured from iron-chromium-aluminum alloy |
DE202011106778U1 (en) | 2011-06-21 | 2011-12-05 | Thyssenkrupp Vdm Gmbh | Heat-resistant iron-chromium-aluminum alloy with low chromium evaporation rate and increased heat resistance |
KR101446688B1 (en) * | 2013-04-11 | 2014-10-07 | (주)칩타시너지코리아 | Iron-chromium-aluminum alloy showing durability and corrosion resistance in high temperature and wire and metalfiber manufactured by the alloy |
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DE102023104526A1 (en) | 2022-04-25 | 2023-10-26 | Vdm Metals International Gmbh | Process for producing a carrier film for catalysts |
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- 2004-03-08 AU AU2004219941A patent/AU2004219941B2/en not_active Expired
- 2004-03-08 US US10/552,310 patent/US20070110609A1/en not_active Abandoned
- 2004-03-08 JP JP2006504254A patent/JP2006519929A/en active Pending
- 2004-03-08 MX MXPA05009519A patent/MXPA05009519A/en unknown
- 2004-03-08 BR BRPI0409579-0B1A patent/BRPI0409579B1/en active IP Right Grant
- 2004-03-08 KR KR1020057016835A patent/KR20050109545A/en active Search and Examination
- 2004-03-08 DE DE112004000857T patent/DE112004000857D2/en not_active Expired - Fee Related
- 2004-03-08 CA CA002529720A patent/CA2529720A1/en not_active Abandoned
- 2004-03-08 RU RU2005131433/02A patent/RU2341581C2/en active
- 2004-03-08 ES ES04718262.1T patent/ES2445584T3/en not_active Expired - Lifetime
- 2004-03-08 EP EP04718262.1A patent/EP1601804B1/en not_active Expired - Lifetime
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US5366139A (en) * | 1993-08-24 | 1994-11-22 | Texas Instruments Incorporated | Catalytic converters--metal foil material for use therein, and a method of making the material |
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US20100092749A1 (en) * | 2007-01-29 | 2010-04-15 | Thyssenkrupp Vdm Gmbh | Use of an iron-chromium-aluminum alloy with long service life and minor changes in heat resistance |
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CN113122778A (en) * | 2021-03-31 | 2021-07-16 | 江苏大学 | High-cleanness low-brittleness Fe-Cr-Al-Y-La alloy material and preparation method thereof |
CN113337783A (en) * | 2021-06-01 | 2021-09-03 | 钢铁研究总院淮安有限公司 | Production method of barium-cleaned iron-chromium-aluminum alloy |
Also Published As
Publication number | Publication date |
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MXPA05009519A (en) | 2006-03-10 |
EP1601804B1 (en) | 2013-11-20 |
UA81021C2 (en) | 2007-11-26 |
DE112004000857D2 (en) | 2006-02-09 |
BRPI0409579B1 (en) | 2013-09-03 |
RU2005131433A (en) | 2006-03-10 |
ES2445584T3 (en) | 2014-03-04 |
AU2004219941B2 (en) | 2008-08-07 |
ZA200506916B (en) | 2006-06-28 |
WO2004081247A2 (en) | 2004-09-23 |
KR20050109545A (en) | 2005-11-21 |
WO2004081247A3 (en) | 2004-11-18 |
CA2529720A1 (en) | 2004-09-23 |
JP2006519929A (en) | 2006-08-31 |
DE10310865B3 (en) | 2004-05-27 |
RU2341581C2 (en) | 2008-12-20 |
AU2004219941A1 (en) | 2004-09-23 |
BRPI0409579A (en) | 2006-04-18 |
EP1601804A2 (en) | 2005-12-07 |
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